INTRODUCTION EO lig 3 THERMODYNAMICS Oval hastrales Fourth Edition David R. Gaskell _S nee ae SP eeBY oO ee) ee Me MS Meee se MOLEC LOA OCU eae M Re CME SR MSS CCar LS a ona eu eee cee MSA See Cece a Re Le a ee eM aCe msn emea cei ete Cut tem eae ae ema eng ele CO mM ane NC UC MRE cement me Mune Re Cee ene teen cM Mice alec cae ere ie tec ae ene a nice Meta Un ay este eeu meet nicer ett eine mmc Lm COUT RCCL CLM Me Lele emu SLT eC CO Lo Pe Cena Get mace Ue cee mel amc ter ee een ee CC Mere ne mL ere ame Uc PCM IEC Re seen RM ce ee cca eas ame Cote me CRUE eR TE aCe nce tec meer CC mee aC Mec am Um eMC DM Mec kc book Composition Space * Two new appendices: Exact Differential Equations and Genetation of Auxiliary ae ae Moa CMe Ce *A CD containing thermodynamic properties of 50 commonly used compounds Pei eel 2) ee David R. Gaskell received a 8.5c. in Metallurgy and Technical Chemistry from the rd Mel: Me Mae APM COMME ume La Voli Some eam (elem tce faculty of the University of Pennsylvania in 1967 and later moved to Purdue PR eco mc Mere cocoon Coe ar Sco ee ee eines Taylor & Francis ae LAM So en 1A | | 356090012679 Uv wires nn xa ’ eH al 737Preface Introduction and Definition of Terms WA 1.2 13 14 15 1.6 V7 Introduction The Concept of State Simple Equilibrium The Equation of State of an Ideal Gas The Units of Energy and Work Extensive and Intensive Properties Phase Diagrams and Thermodynamic Components The First Law of Thermodynamics 21 2.2 23 24 25 26 ag 28 29 2.10 Introduction The Relationship between Heat and Work Internal Energy and the First Law of Thermedynamics Constant-Volume Processes Constant-Pressure Processes and the Enthalpy H Heat Capacity Reversible Adiabatic Processes Reversible Isothermal Pressure or Volume Changes of an Ideal Gas Summary Numerical Examples Problems: The Second Law of Thermodynamics 3A 32 3.3 a4 3.5 3.6 37 38 Introduction Spontaneous or Natural Processes Entropy and the Quantification of Irreversibility Reversible Processes An Illustration of Irreversible and Reversible Processes Entropy and Reversible Heat The Reversible Isothermal Compression of an Ideal Gas The Reversible Adiabatic Expansion of an Ideal Gas o {Contents