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ALDEHYDES AND KETONES

Contain carbonyl group C=O Carbonyl group is polar because oxygen has a high electronegativity Can have alkyl and aryl groups Aldehydes have a hydrogen bonded to the carbon of the carbonyl group (RCH=O) and use the suffix al for naming Ketones have two carbons bonded to the carbon of the carbonyl group (RC=OR) and use the suffix one for naming
PROPANONE PROPANAL

PHYSICAL PROPERTIES
Carbonyl group can only take part in hydrogen bonding if in aqueous solution Permanent dipole-dipole attractions in carbonyl compounds Straight chain isomers have higher boiling points than branched chain isomers

SOLUBILITY IN WATER
Carbonyl group has a highly electronegative oxygen, so hydrogen bonding can occur when carbonyl compounds are mixed with water

Solubility decreases as molar mass increases

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