D) Non CHEMISTRY 5) 1) One mole of CH4 contains: N2 gas occupies a volume of 50 dm at 25 Co.

At what temp its volume will be 100 dm3.

3

A) 5 moles of atoms B) One Avogadros NO of C atoms C) 6.02 1023 number of empirical formulas of CH4 D) All * A) 50 Co B) 323 Co * C) 12.5 Co D) 100 Co

2)

KO2 is:

6)

The intermolecular forces in a molecule always explain:

A) Anionic formula B) Empirical formula C) Chemical formula D) All of these * A) Chemical properties * B) Physical properties C) Both D) Non 3) CH4 burns in oxygen as follows: CH4(g) + 2O2(g) 2H2O(l) CO2(g) +

If 8.0 g methane is burnt in 32 g of oxygen, the limiting reactant is

7)

A) CH4 B) O2 C) Both D) Non *

An element X belongs to the fourth period of the periodic table. Dr. folo asked her student how many orbitals X contains? Student answered

A) 16 * B) 8

4)

Maaz cola separated a mixture of amino acids by paper chromatography. This phenomena of chromatography is called: 8) A) Partion B) Adsorption C) Both *

C) 32 D) 18

Students were discussing radiations in the class. Teacher asked which statement is correct?

A) The velocity of red colour is greater than violet B) The velocity of violet is greater than green C) Orange and blue light travel with the same velocity * D) All are wrong

12)

Hydrogen burns in oxygen forming water as given below H2(g) + 12 O2(g) -286 kj/mole H2O(l) H=

The enthalpy change -286 kj/mole is the

9)
11

The elements of period III are Na

12

Mg

13

Al

14

Si

15

16

17

Cl

18

Ar

A) Enthalpy of combustion of hydrogen B) Enthalpy of formation of water C) Enthalpy of reaction D) All *

Which one of the following i.e., Mg, Al, P, and S after completing their outermost orbit under ordinary condition has the biggest ionic size

A) Mg B) S C) P * D) Al

13)

For which of the following processes the enthalpy change is always negative

A) Enthalpy of hydration * B) Enthalpy of solution

10)

Pick up the correct statement

C) Enthalpy of atomization D) Enthalpy of formation

A) Pi bond is more energetic and less stable than sigma bond B) Pi bond is less energetic and more stable than sigma bond C) Sigma bond is more stable and more energetic than pi-bond D) Pi-bond is less stable and more energetic than sigma bond *

14)

2SO2(g) + O2(g)

2SO3(g)

Under the given conditions and states of reactants, the unit of the equilibrium constant is

A) atm-1

B) mol/dm3 11) When carbon atom is bonded to three other atoms, hybridization is SP2. Nitrogen in Ammonia is bonded to three H atoms the hybridization in Ammonia is C) atm2 D) mol2/dm6

15)

Which of the following pairs cannot be used as a buffer solution

A) SP3 * B) SP2 C) SP D) dSP2 A) NH4OH/NH4Cl B) H3PO4/Na H2 PO4 C) Hl/Kl *

D) H2CO3/NaHCO3

19)

The ion with greater enthalpy of hydration is

16)

We have two beakers A and B. each having 500g distilled water. In a beaker A 84.9g AgNO3 (Mr=169.8) and in a beaker B 26.75g NH4Cl (Mr= 53.5) is dissolved. Both the solution were heated to boiling the beaker in which the solution will boil first is 20) A) A B) B C) Both will start boiling at the same time * D) NH4Cl sublime and is insoluble in water to form solution

A) Li+ B) Mg++ * C) Ca++ D) S-2

Which one of the following is not the properties of an electrolyte

A) It is always in solution form B) It is always in liquid form

C) It always contain freely movable ions D) It is never in solid form

21) 17) Maaz folo added 55.5g of CaCl2 (Mr=lll) to 1000g distilled water and put in a freezer for freezing. The temperature at which the solution freeze is

A Daniell cell composed of Al and Sn. If the standard reduction potential of the two electrode is

Al+++ + 3e Sn+++ + 2e

Al Sn

-1.66 -0.14

A) -100Co B) 0Co C) -1.86Co * D) -186Co

Then by using the formula Eocell = Eored + Eooxd the cell potential is

A) +1.52 volts B) -1.52 volts

18)

The addition of water into a compound with out breaking is known as

C) +1.80 volts D) -1.80 volts

A) Hydration * B) Hydrolysis C) Electrolysation D) Dehydration

22)

The oxidation number of oxygen in RbO2 is

A) -2 B) -1 C) +1

D) -1/2 *

B) 3rd order C) 2nd order *

23)

In the laboratory a student was titrating 25cm3 solution of Mohars salt against 0.1M KMnO4 solution. If the solution of KMnO4 used against 25cm3 Mohars salt is 10cm3 the number of moles of KMnO4 is

D) 4th order

27)

If the Activation energy for a reaction is very high the reaction

A) 0.01 mole B) 0.001 mole * C) 0.25 mole D) 0.025 mole

A) Will occur fastly B) Will occur slowly * C) Will occur moderately D) Will occur slowly first than fastly later

24)

In a redox reaction, the cell potential Eocell will be equal to zero if

28)

In a one mole aqueous solution of methanol, the mole fraction of methanol is roughly

A) The reaction is spontaneous B) The reaction is non-spontaneous C) The reaction is irreversible D) The reaction is reversible * A) 32 B) 0.98 C) 0.0177 * D) 18 25) Order of reaction is always determined from

29)

20 ml methanol was added to 20ml water. The over all volume of the two miscible component is

A) Stoichiometric method B) Limiting reactant method C) Experimental method * D) Balance chemical equation method A) 40 ml B) More than 40 ml C) Less than 40 ml * D) Exactly 43 ml 26) For a reaction 3H2(g) + N2(g) 2NH3(g) The rate law is given as rate = K[H2]2[N2] The order of reaction with respect to hydrogen is

30)

According to n+l rule, the orbital which will be filled first is

A) 4S * B) 4P

A) 1st order

C) 4d D) 3d

31)

The total number of possible isomers of C3H6Cl2 are

iv) CH3

CH3 CH2 Cl + OHCH2 OH + Cl-

The reaction in which nucleophilic addition occurs is

A) 4 * B) 3 C) 5 D) 2 A) B) C) D) 32) Carbocyclic compound are also called i only i, ii only ii only iv only *

35)

A) Homocyclic B) Aliphatic C) Alicyclic D) All *

Maaz cola asked his mother Dr folo what reagent I should add to hexene to find the position of double bond? She answered

A) Aqueous KMnO4 B) Aqueous K2Cr2O7 C) Bromine water

33)

Which one of the following is used for the lengthening of hydrocarbon chain

D) Allotrope of O2 * 36) The compound which can donate proton to strong bases is

A) Wartz reaction B) Frankland reaction C) Kolbes electrolysis D) All * A) CH3 B) CH3 C) (CH3)3 C D) CH2 CH CH C C C CH2 C CH3 CH * C CH3

34)

Four reaction are given below i) CH2 CH2 ii) CH3 OH l iii)O + Cl2 + HCl CH2 + H-OH OH CH3 CH CHO + HCN CN C 37) CH3

The most reactive aromatic compound among the following is

A) C6 H6 B) C6 H5 NH2 * o C) C6 H5 C Cl D) C6H5 CH3

B) NaNO3 38) Which of the following groups shows +ive inductive effect when attached to benzene ring C) KOH * D) Mg(NO3)2

A) Cl B) C) D) 39) C
+

42) N

Which one of the following is a weak monobasic acid that ionizes to small extent in water

NH3 A) H3PO4 B) H3BO3 * C) HNO3 D) HI

C2 H5 *

The seven ionization energies of an element X in Kj/mole is given by 1 7th

st

nd

rd

th

th

th

1402 2857 4578 7475 9445 53265 64358 The element X belongs to which group of the periodic table

43)

CH3 CH2 CH2 Br + NH3 CH3 CH2 CH2 NH2 + HBr The reaction given above is

A) Nucleophilic addition A) 3rd B) 5th C) 6th D) 7th 44) In the reaction given below:
H H H C H C H OH + H C C Br H +H2o +Br

B) Nucleophilic substitution * * C) Electrophilic addition D) Dehydrohalogination

40)

The compound which is more ionic in nature is A) B) C) D)

OH acts as: Nucleophile * base ligand all

A) AlCl3 B) CCl4 C) PbCl4 D) PbCl2 *

45) The controlled addition of phosphorous or Arsenic or Boron into Silicon or Germenium to make them semi conductor is called: A) B) C) D) Droping Driping Doping Diping

41)

The compound which more stable towards heat is

A) CaCO3

46) The element among the following which do not show inert pair electron effect in: A) B) C) D) Boron B * Phosphorous P Bismuth Bi Nitrogen

C) alcohol and fatty acids * D) all 54) Esters, Amides and acylhalides are the derivatives of: A) B) C) D) Alcohols Carboxylic acids Ketones All *

47) Whenever alcohol reacts with carboxylic acid the resulting component so formed is called: A) B) C) D) Ketone Ether Ester * acetyle halide

55) The monomer of polystyrene is: A) CH2 B) CH2 C) CH2 D) CH2 CH Cl CH C6H5 CH C6H6 CH CH3 56) Tertiary undergo: A) B) C) D) alkylehalides can *

48) Transition elements having partially filled 4d orbitals is called: A) B) C) D) 2nd transition series* 3rd transition series 4th transition series 5th transition series

49) The highest oxidation state for transition element is +7 which is of: A) B) C) D) Cr Cd Fe Mn

SN2 mechanism E1 mechanism SN1 mechanism Both B and C

57) Which nucleophilic substitution reaction is not possible: * A) CH3 CH2 Br + OH

CH3 CH2 CH3 CH2 CH3 CH2 CH3 CH2 OH + Br B) CH3 CH2 Br + CN CN + Br C) CH3 CH2 F + Cl Cl + F * D) CH3 CH2 I + OH OH + I

50) The co-ordination number of Cu in [Cu(NH3)4]SO4 is: A) B) C) D) 4 5 3 zero *

51) The fossil following is: A) B) C) D) gasoline coal Natural gas All *

fuel

among

the

58) Four unlabelled beakers containing alcohol, aldehyde benzene and phenol are lying on the table through which reagent a student can check phenol: A) B) C) D) 59) Fehling solution Tollens reagent Bromine water * Silver nitrate solution

52) When hot water from factories and power stations is discharged in to the streams it is called: A) B) C) D) physical pollution * chemical pollution biological pollution all

CH2 CH2 CH3 (propyle benzene) on oxidation by means KMnO 4 or K2Cr2O7 gives: A) B) C) D) Benzoic acid Propyle benzoic acid Phenol Ethyl benzoic acid

53) Complex lipids are esters of fatty acid. These on hydrolysis give: A) Fatty acids and ketones B) aldehyde and alcohol

60) When carbon atom is bonded to three other carbon atoms and bearing negative charge is called: A) B) C) D) Carbonium ion Carbonion * Oxonium ion Zwitter ion