CPP

FIITJEE

ATOMIC STRUCTURE

Name:__________________________________Batch:______________ Date: _____________ Enrollment No.:__________________________Faculty ID: SECTIONI (SINGLE CHOICE MCQ TYPE QUESTION) 1. An electron in a hydrogen atom in its ground state absorbs 1.5 times as much energy as the minimum required for it to escape from the atom. What is the wave length of the emitted electron? (a) 47 nm (b) 42 nm (c) 0.47 nm (d) 0.42 nm
1 g The angular momentum of an electron in a Bohrs orbit of H + is 3.1652 10 34 k . m 2 . s . e What is the wave number in terms of Rydbergs constant R H of the spectral line emitted when an 3 6 2 1 electron falls from this level to the first excited state. ( h = .6 6 0 4 j.sec) 5R H (a) 3 RH (b) 9 8R H 3R H (c) (d) 9 4

Dept. of Chemistry

2.

3.

For a 3S orbital
(3S ) 1 1 = 9 3 a0
3 2

(6 6 + ) e
2

; where =

2 r.z 3a 0

What is the maximum radial distance of node from nucleus? (a)

(3 + 3 ) a
z

(b)

(3 3 ) a
z

(c) 4.

3 3+ 3 a0 2z

(d)

3 a0 2z

If Rutherford would have used particles instead of particles in his gold-leaf experiment, which of the following observations would definitely not have been made. (a) particles get condensed or concentrated (b) very few particles getting absorbed (c) Majority of particles passing undeflected through the foil (d) Wave nature of electron would be established

5.

Which statement among the following concerning Bohrs model is not true? (a) It introduces the idea of stationary orbits (b) It explains the line spectrum of H-like species (c) Angular momentum of electron in H-atom is
nh 2

(d) It predicts that probability of finding the electron near the nucleus is more. 6. Select the correct statement among the following: (a) The electron density in the XY plane of 3 dx 2 y 2 orbital is zero. (b) The energy of 3d-orbitals is less than 4S-orbital (c) the 3d-orbitals are far away from the nucleus than 4S orbital (d) Wave function of atomic orbitals represents an orbital.

SECTIONII (MUTLTICHOICE MCQ TYPE QUESTION) 7. Select the correct statements (a) An electron is in orbit can absorb only one photon and that too equivalent in energy to the energy difference between two orbits. (b) 3d sub-shell penetrates more towards nucleus than 4S (c) Green light is never emitted in black body radiations (d) The energy change between two successive orbitals increases with increasing value of n The radii of two of the 1st four Bohrs orbits of the H-atom are in the ratio of 1 : 4. The energy between them may be (a) 12.09 ev (b) 2.55 ev (c) 3.4 ev 9.
E 3 2 1 n n n = = = 3 2 1

8.

(d) 10.2 ev

For the above transitions in H-like species, select the correct relations v1 + v 2 (a) 3 = v1 + v 2 (b) 3 = v1 + v 2 (c) 3 = 1 + 2 10. Select the correct curves, If V = velocity of electron in Bohrs orbit r = Radius of e in Bohrs orbit P.E. = Potential energy of electron in Bohrs orbit k.E = Kinetic energy of electron in Bohrs orbit (d) 3 =

1 2 1 + 2

/ n K 1 / n E

. E
O

SECTIONIII (COLUMN MATCHING) 11. ColumnI (A) (B) (C) (D) Electrons can not exist in the nucleus (p) Microscopic particles in motion are (q) associated with No medium is required for propagation (r) Concept of orbit was replaced by orbital (s)

ColumnII De Broglie wave Electro-magnetic wave Uncertainty principle Transverse wave

SECTIONIV (INTEGER TYPE QUESTION) 12. An electron is allowed to move freely in a closed cubic box of length of side 10 cm. The maximum

1 uncertainty in its velocity is 3.35 0

msc e

. Find the value of n.

ATOMIC STRUCTURE ANSWER KEY: 1. 5. 9. C D AC 2. 6. 10. B D AB 3. 7. 11. C ABC AR BP CQ,S DR 4. 8. 12. A BD 3