Organic Class Sheet

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Choose the correct option/s. one or more options may be correct 1. Which of the following statements is true about a homologous series? (a) Adjacent numbers of a group differ by a mass of 14 (b) Adjacent numbers of a group differ by one group (c) Members of a homologous series can be prepared by the same general methods (d) Members of a homologous series have the same physical and chemical properties 2. The large number of organic compounds is due to (a) The valency of carbon (b) The small size of carbon (c) A special property of carbon, known as catenation (d) None of the above 3. How many isomers are possible for the alkyl group (a) two (a) pentane (c) 2, 3-dimethylbutane (a) propane (c) 2-methylpropane (a) 2-methylpentane (b) three (c) four (b) 2-methylbutane (d) 2-bromo-2-methylpropane (b) 2,2,3-trimethylpentane (d) n-propylbromide (b) 2,2-dimethylpentane (c) 2,2,3,3-tetramethylpentane (d) five 4. Which of the following compounds will have only primary and tertiary carbon?

5. Which of the following compounds will have only primary and secondary carbon?

6. Which of the following compounds has an isopropyl group? (d) 2,2,3-trimethylpenatane 7. The general molecular formula of an alkyne is (a) (b) (c) (d) 8. The IUPAC name of

Is (a) 1,2-dichloropropane (c) 1,1-dichloropropane 9. The IUPAC name of (a) 1,1,2,2-tetramethylethane (d) 2,3,3-trimethylbutane 10. The IUPAC name of (a) propoxymethane is (b) methoxypropane (c) methylpropyl ether (d) propylmethyl ether (b) 3,3-dichloropropane (d) dichloropropane is (b) 1,2-diisopropylethane (c) 2,3-dimethylbutane

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11. The IUPAC name of (a) 1,2,3-trichloropropane (b) 1,2-dichloropropyl chloride (c) 1,1-dichoroisopropyl chloride 12. The IUPAC name of (a) acetaldehyde 13. The IUPAC name of 14. The IUPAC name of (a) 5-methylheptane (b) 3-methylheptane (c) 1-methyl-1-ethylpenatene 15. The IUPAC name of (a) 2-pentanone 16. The IUPAC name of (a) 1,1,1-trichloroethanal (d) chloral 17. The IUPAC name of (b) 4-pentanone is (b) 2,2,2-trichloroethanal (c) trichloroacetalehyde (d) 2-ethxyhexane is (c) methylpropylketone is (b) formyl methane is (c) ethylformic acid (D) propanoic acid (c) ethanol (d) methylaldehyde (d) propane trichloride

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(a) ethane carboxylic acid (b) ethanoic acid

(d) ethylacetone

(a) 2-methylpentane (c) 2-hexene 18. The IUPAC name of (a) 1-isopropylethylene (c) 3-methyl-1-butene 19. The IUPAC name of (a) 3-methylbutene-1 (c) vinylmethylethane 20. The IUPAC name of

(b) 4-methylpentene-2 (d) 2,4-dimethylbutene is (b) 1,1-dimethyl-2-propane (d) 2-vinylpropane

(b) 2-methylbutene-1 (d) propylethene-1

(a) 2-ethyl-2-pentene (c) 3-methyl-3-hexene 21. The IUPAC name of (a) 1,1-dimethyl-3-butene (c) 3,3,3-trimethyl-1-propene

(b) 4-ethyl-2-pentene (d) 3-methyl-2-pentene is (b) 3,3,-dimethyl-1-butene (d) 1,1,1-trimethyl-2propene

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Organic Class Sheet

22. The IUPAC name of the compound (a) 2-methylpent-1-ene-3-yne (b) 4-methylpent-4-ene-2-yne (c) 2-methylpent-2-ene-3-y ne (d) 2-methylpent-3-yne-2-ene 23. The IUPAC name of

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(a) 3-methyl-2-ethylbutene-1 (b) 3-ethyl-3-methylnutene-1 (c) 2-ethyl-3-methylbutene-1 (d) ethylisopropylethene 24. The IUPAC name of (a) 2-methylbutanal (c) 2-ethylpropanal 25. The IUPAC name of (b) butan-2-aldehyde (d) 3-methylisobutyradelhyde

(a) pentanol (c) 2-methyl-4-butanol 26. The IUPAC name of

(b) 1-pentanol (d) 3-methyl-1-butanol

(a) 2-methyl-1-pentanol (c) 2-ethylpentanol -1 27. The IUPAC name for

(b) 2-ethylbutanol -1 (d) 3-ethylbutanol -1

(a) 2-methyl-2,4-pentanediol (b) 1,1-dimethyl-1,3-butanediol (d) 4-methyl-2,4-pentadiol 28. The IUPAC name for (c) 1,3,3-trimethyl-1,3-propanedoil

(a)

5-carboxy-2-methylpentene (d) none of these

(b)

4-isopropyl-3-butanoic acid (c) 5-methyl-4-hexanoic acid

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Organic Class Sheet

29. The structure of 4-methylpentete-2 is (a) (c) 30. 2-methyl-2-butene is represented as (b) (d)

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31. The IUPAC name of (a) tertiary butylbromide (b) isobutylbromide (c) 2-bromo-2-methylpropane (d) 2-methyl-2-propylbromide 32. The IUPAC name of (a) 1-bromo-3-butene (c) 2-butene-1-bromide 33. The IUPAC name of (a) tert.butylalcohol (c) 2-methyl-1-butanol 34. The IUPAC name of (a) methyl-n-propylketone (c) 3-pentanone 35. The IUPAC name of is (b) 2-pentanone (b) n-propylmethylketone is (b) 2-methyl-2-propanol (d) 2-propanol is (b) 1-bromo-2-butene (d) 4-bromo-2-butene

(a) 3-ethyl-2,2,3-trimethylheptane (b) 2,2,3-trimethyl-3-n-butylpentane (c) 3-methyl-3-isopropylheptane (d) 2,2-dimethyl-3-ethyl-3-n-butylbutane

36. The IUPAC name of (a) 2-ethyl-4-methylhexane

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(b) 3,5-dimethylheptane (c) 5-ethyl-3-methylhexane (d) 2,4-diethylpentane 37. The IUPAC name of (a) 1,1,2-trimethyl-1,3-butanediol (b) 1,2-dimethyl-2,4-pentanediol (c) 2,3-dimethyl-2,4-pentanediol (d) 1,2,3,4-tetramethyl-1,3-propanediol 38. The IUPAC name of (a) 4-methyl-2-pentyne (c) 4,4-dimethyl-2-butyne (a) (c) (a) (b) (c) (d) 41. The IUPAC name of (a) 2,2-dimethylpent-4-ene (c) 4,4-dimethylpent-1-ene (a) (c) (a) (c) (a) (c) 45. In the reaction (a) (a) (b) (b) (d) (d) is (b) (d) (b) (b) 2,2-dimethylhex-4-ene (d) hex-1-ene -hybridized? (b) (b) methylisopropylacetylene (d) 2-methyl-4-pentyne (b) (d) (5-methyl-1-hexanal) (5-methyl-2-hexanoic acid) (2-methylhexanoic acid) (3-hexen-5-one)

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39. The structure of 4-methyl-2-penten-1-ol is

40. Which of the following compounds are named correctly?

42. In which of the following are all carbon atoms

43. The hybridization of carbon atoms in the C-C single bond of

44. Which of the following compound have only one type of hybrid carbon?

, the hybridization state of the carbon atom changes from (c) (c) (d) (d)

46. Which of the following have zero dipole moment? 47. Arrange the following resonating structures of vinyl chloride in order of decreasing stability

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(a) (c)

(b) (d)

48. Arrange the following resonating structures of formic acid in order of decreasing stability

(a) (c) (a) CO (b) (c) NO

(b) (d) (d)

49. Which of the following molecules show resonance? 50. Arrange the following free radicals in order of stability

(a) (c) Benzyl, allyl, methyl, vinyl I (a) (c) II III IV (b) (d)

(b) (d)

51. Arrange the following free radicals in order of stability

52. Arrange the following carbonium ions in order of decreasing stability

(a) (c)

(b) (d)

53. Which of the following compounds will produce the most stable carbonium ion?

54.

The (a) C-C

bond

that

undergoes (b) C-O

heterolytic cleavage most readily is (c) C-H (d) O-H

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Organic Class Sheet

55. Hydrogen bonding is maximum in (a) triethylamine (c) ethyl alcohol (a) 2-butene (c) 1-butene (b) ethyl chloride (d) diethyl ether (b) 2-butyne (d) 2-butanol

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56. Which of the following compounds will exhibit cis-trans isomerism?

57. Which of the following compounds will exhibit geometrical isomerism?

58. Which of the following compounds exhibit optical isomerism? (a) (c) 59. (b) (d)

The IUPAC name of this compound is (a) 2,2,6-trimethyl-4-(1-methylpropyl) nonane (b) 4,8,8-trimethyl-6-(1-methylpropyl) nonane (c) 3,6-dimethyl-4-(methylene tertiary butyl) nonane (d) 6,6-dimethyl-2-propyl-4-(1-methylpropyl) heptane 60.

The IUPAC name of this compound is (a) 3-ethyl-4-chloro-1,4-pentadiene (b) 2-chloro-3-ethyl-1,4-pentadiene (c) 4-chloroethenyl-1-pentene (d) 61. 3ethenyl-4-chloro-4-pentene

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The IUPAC name of this compound is (a) 2-ethoxy-4-methoxypentan-3-one (b) 2-methoxy-4-ethoxy-pentan-3-one (c) 2-ethoxy-4-methoxy-pentan-3-one (d) none of these 62. The IUPAC name of

(a) 2,3-dimethylpentanal (c) 3,4,4-trimethylbutanal 63. The IUPAC name of

(b) 3,4-dimethylpentanal (d) 3-isopropylbutanal

(a) 2-methyl-2,4-dihydroxypropane (c) 2-methyl-2,4-pentanediol 64. The IUPAC name of

(b) 2,2-dimethyl-4-hydroxybutanol (d) 2-hydroxy-4,4-dimethylbutanol -4

(a) 2-bromomethyl-3-oxohexanamide (c) 1-bromo-2-amido-n-propylketone 65. The IUPAC name of

(b) 1-bromo-2-amido-3-oxohexane (d) 3-bromo-2-propnyl propanamide

(a) 2-ethyl-ethylacetate (c) ethyl-2-methylbutanoate 66. The IUPAC name of

(b) ethyl-3-methylbutanoate (d) 2-methylbutanoic acid ethlyester

(a) N-methyl-N-ethylamine (b) diethylmethylamine 67. (c) N-ethyl-N-methylaminoethane (d) methyldiethylamine

The IUPAC name of this compound is (a) 2-isopropylbutanal (b) 2-ethyl-3-methylbutanal (c) 3-ethyl-2-methylbutanal

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(d)2-methylpentane-3-aldehyde 68. The IUPAC name of

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(a) 1,1,1-trichloro-3,3-diphenylpropane (c) both (a) and (b) 69. The IUPAC name of (a) cinammic acid (c) 3-phenylprop-2-enoic acid 70. The IUPAC name of (a) 1-propyn-ethene (c) pent-4-yne-1-ene 71. The IUPAC name of is

(b) 1,1-diphenyl-3,3,3-trichloropropane (d) none of these (b) 1-phenyl-2-carboxyethene (d) dihydroxy-3-phenylpropionoic acid is (b) propeneacetylene (d) pent-1-en-4-yne

(a) 1-cyclohexyl-3-methyl-1-pentene (b) 3-methyl-5-cyclohexyl-pent-1-ene (c) 1-cyclohexal-3-ethyl-but-1-ene (d) 1-cyclohexyl-3,4-dimethyl-but-1-ene 72.

The IUPAC name of this compound is (a) 3,3-dimethyl-2-pentanol (b) 3-methyl-3-ethyl-2-butanol (c) 3,3-dimethyl-3-ethyl-isopropanol (d) 3,3-dimethyl-3-ethyl-2hy droxypropane 73.

The IUPAC name of this compound is (a) 2-fluoro-4-chloro-2,4-diethylpentane (b) 3-fluoro-5-chloro-3-methyl-5-ethylhexane (c) 3-chloro-5-fluoro-3,5-dimethylheptane (d) 3,5-dimethyl-5-fluoro-3-chloroheptane 74. The effect of decreases in the order

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(a) (c) 75. The +I effect of (a) (c) (a) (b) (c) (d) 77. Give the IUPAC name of (b) (d) (b) (d)

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decreases in the order

76. The inductive effect of the alkyl groups on a saturated carbon chain follows the order

(a) 4-isopropyl-5-ter. butyloctane (b) 4-ter. butyl-5-isopropyloctane (c) 2-methyl-3-propyl-4-ter, buytlheptane (d) 2,2-dimethyl-3-propyl-4-isopropylheptane 78. The IUPAC name of

(a) 4-ethyl-3-methyl-trans-3-heptane (b) 4-ethyl-5-methyl-trans -4-heptane (c) 3-ethyl-4-propyl-3-hexene (d) 3-propyl-4-ethyl-3-pentene 79. The IUPAC name of

(a) 5-chloro-3-penten-3-carbi nol (b) 1-chloro-3-penten-3-carbi nol (c) 4-chloro-2-ethyl-2-buten-1-ol (d) 1-chloro-3-ethyl-2-buten-4-ol 80. The IUPAC name of

(a) methacrolein (c) 2-methylpropenal 81. The IUPAC name of (a) phenylethanone

(b) methacryaldehyde (d) propenaldehyde (b) methylphenylketone

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(c) acetophenone 82. The IUPAC name of (a) 5-ethy-1, 3, 5-heptatriyne (c) 5-ethenyl-1, 3-heptatriyne 83. The IUPAC name of (b) 3-ethyl-2, 4, 5-heptatriyne (d) 3-ethenyl-4, 6-heptatriyne (d) phenylemethylketone

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(a) elaidic acid (c) dihydrosteric acid 84. The IUPAC name of

(b) trans-octadec-9-enoic acid (d) oleic acid

(a) cis-cis-9, 12-octadecadienoic acid (c) 9,10- octadecadienoic acid 85. The IUAC name of

(b) cis-trans-9, 2- octadecadienoic acid (d) 9,14- octadecadienoic acid

(a) 6-(1-methylbutyl)-8-(2-methylbutyl) tetradecane (b) 6-(2-methylbutyl)-8-(1-methylbutyl) tetradecane (c) 4-methyl-5- -pentyl-7-(2-methylbutyl) tridecane (d) 3-methyl-5- -hexyl-7-(1-methylbutyl) didecane 86. The IUPAC name of

(a) 4,4-di(formylmethyl) butanal (b) 2-(formylmethal) butane-1, 4-dicarbandehyde (c) hexane-3-acetal-1, 6-dial (d) 3-(formylmethyl) hexane-1, 6-dial 87. The IUPAC name of

(a)

2-

chlorocarbonyl

ethylbenzoate (b) 2-carboxyethyl benzoayl chloride

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(c) ethyl-2-(chlorocarbonyl) benzoate (d) ethyl-1-(chlorocarbonyl) benzoate 88. The IUPAC name of

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(a) 2-chlorocarbonyl ethylbenzoate (b) 2-carbonxyethyl benzoyl chloride (c) ethyl-2-(chlorocarbonyl) benzoate(d) ethyl-1-(chlorocarbonyl) benzoate 89. The IUPAC name of (a) phenyl cyanide (c) benzene cyanide 90. The IUPAC name of (a) phenylethylamine (c) 2-phenylethanamine 91. The IUPAC name of (a) 2-(N-methylamino)-4-methypentane (b) N,4-dimethypentan-2-amine (c) 2-(N-methylamino)-3-isopropylpropane (d) 2-(N-methylamino)-1,4, 4-trimethylbutane is (b) 2-phenylaminoethane (d) benzyl methylamine is (b) phenylacetonitrile (D) benzonitrile

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