H.S.

C
Batch :
Date : 29/12/2012

SHRI CHANDRA TUTORIALS

SCIENCE DEPARTMENT
PRILIMINARY EXAMINATION

MARKS : 70 TIME : 3.00 HRS

CHEMISTRY

Note :

1) Answers to the two sections must be written on same answer book. 2) Give balanced equation and draw neat labeled diagrams must be drawn whenever necessary. 3) Answer to every question must be written on a new page. 4) Use of only logarithms table is allowed. 5) Figures to the right indicate full marks. SECTION - I

Q.1) Select and write most appropriate answer from the given alternative for each sub question : (7) 1) The percentage of free space in a body centered cubic cell is a) 29% b) 32% c) 42% d) 34% 2) Boiling point of water is 373.11K. What is of water, if 0.15 molal aqueous solution of a substance boils at 373.20K? a) 0.09 b) 0.6 c) d) 60 3) For the given reaction, a) decreases b) increases entropy of the system. c) zero d) constant

4) Relative lowering of vapour pressure depends on. a) Nature of solvent b) nature of solute c) Nature of solute & solvent d) Mole fraction of solute 5) S.I unit for conductivity is a) b) c) d) 6) The half life of zero-order reaction is given by a)

b)

c)

d)

7) The chemical formula of oil of vitriol is a) H2S2O2 b) H2SO3 c) SO2(OH)2 Q.2) Attempt any six from the following : 1) Explain the solubility of noble gases in water.

d) H2S2O3 (12)

2) Write the features of Ellingham diagram for oxide formation 3) What is Arrhenius equation? Explain the variation of ln K with graphically. 4) Using conventions, represent the electrochemical cells from the given cell reactions a)

b)

5) For a certain reaction, the system absorbs 12000 J of heat energy and performs 3.5KJ of work on its surrounding. Calculate the change occurring in internal energy and enthalpy of the system. 6) Write any four statements of law of conservation of energy. 7) Write all the equation in which the colligative properties are related to the molecular masses of the solutes. 8) Explain the following magnetic properties on the basis of spinning of electrons. a) Diamagnetism b) Para magnetism Q.3) Attempt any THREE from the following : (9) 1) Explain with the help of diagram the process of smelting in the extraction of zinc metal. 2) What would be the concentration of the reactant after 35 minutes from 0.62M concentration, if the rate constant of the given first order reaction is 3) Write the preparation of following allotropic modifications of sulphur. a) Milk of sulphur b) Colloidal sulphur 4) 0.02 modal aqueous solution of potassium ferricynide, 0.124 , Calculate percentage dissociation of solute ( Q.4) A) Write the reactions between : i) Phosphorus trichloride and silver cyanide ii) Hot finely divided tin and phosphorus pentachloride iii) Aluminum phosphide and dil H2SO4 iv) Phosphine and Hydrogenbromide Write any two important application of Hesss law. freezes at -

Find the

of acetylene from the following data,

(7) OR Q.4) B) Find the atomic radius of metal with fcc structure and mass of unit cell 130.8 g. Density of metal is 19.03 of g & atomic mass 197g What is electromotive series? What are the conventions used in its construction? (7)

SECTION - II Q.5) Select and write most appropriate answer from the given alternative for each sub question : (7) 1) Lanthanides and actinide resemble in a) Ionization potential b) formation of complexes c) oxidation state d) electronic configuration 2) The compound and exhibit. a) Chain isomerism b) Geometrical isomerism c) Optical isomerism d) Metamerism 3) Which of the following compounds is achira a) b) c) d) 4) Methanal and methanoic acid can be distinguished by a) Washing soda b) Felling solution c) Tollens reagent d) Starch solution 5) Glucose cannot be classified as a) aldose b) hexose c) oligosaccaride d) carbohydrate 6) The chemical present in iodex is a) methyl benzoate b) methyl salicylate c) ethyl propanoate d) methyl ehtanoate 7) The organic compound, with molecular weight of 3.5:1:9, by weight. Then the ratio of 3.5:1:9, by weight. Then the molecular formula of the compound is a) b) c) d) Q.6) Attempt any six from the following : (12) 1) Prepare potassium permanganate, using potassium permanganate, using : Potassium chloride and chlorine 2) What is effective atomic number(EAN)? 3) Explain the optical activity in case of lactic acid. 4) What are phenols ? Write a chemical test to distinguish between phenol and alcohol. 5) Using mono carboxylic acids, prepare a) methane b) 2-Bromo-2-phenylacetic acid. 6) What is action of (a) bromine water at 25 (b) conc. H2SO4, on phenyl amine.

7) How are vitamins classified, according to their chemical structures ? Q.7) Attempt any THREE from the following : (9) 1) What are chemical twines? Explian the effects of lanthanoid contraction on The (a) basicity (b) Ionic radii of lanthanoids . 2) How is 2-Bromopropane prepared from (a) an alcohol (b) an alkene ? Write the structural formula and IUPAC name of neopentyl chloride. 3) Explain giving examples of following isomerisms exhibited by ethers, (a) Chain (b) Functional group (c) Metamerism

4) What are carbohydrates? How is dextrose prepared in laboratory? Q.8) A) i) Write a note on aldol condensation. ii) Write any six isomeric structures and of names the amines with molecular formula C4H11N. (3) OR B) Explain the following types of isomerisms, with reference tocoordination compounds; (i) lonisation isomerism (2) (ii) Linkage isomerism Write the preparation of Nylon 6, 6 polymer. (2) What are the physical methods used in the preservation of food materials. ? (2)