Polymers Synthesis and Property Analysis Chemistry Project Atul Singh Arora Class: Roll No.

: Teachers Signature XII-D

CONTENTS Acknowledgements Aim of the Project General Overview Brief Theory, Synthesis and Analysis of 1. Bakelite 2. Polystyrene 3. Epoxy Resin Result References * 3 7 1 1 15 16 iii 1 1 CAUTION: Some experiments require hazardous and/or potentially hazardous chemica ls. * This refers to the level of caution required for each individual experimen t.

Acknowledgments I am very greatful to my chemistry teacher, Ms. Sadhana Bhargava, who has been a constant source of inspiration and guidance. She supported me with all my ideas and helped me to the maximum extend possible. She also gave me enough extra tim e to find all the required information to turn my ideas into a single project. E ven though what I initially wanted to make (conductive Polymers) wasnt possible t o do with our existing lab apparatus, yet she encouraged me to search for someth ing similar, yet interesting enough for me. This project would never have existe d, if it wasnt for her passion to teach. I would also like to thank our lab assis tant, Mr. Babu Lal for all the timely help he provided. Apart from this, I would like to thank all those people whove published their useful work on the internet , without which, I perhaps wouldnt even have enough information to make even a si ngle polymer.

Polymers Synthesis and Property Analysis Aim of the Project The aim of this project is to find out the optimum conditions for synthesis of t he following polymers, 1. Bakelite* 2. Polystyrene** 3. Epoxy Resin** and to stu dy their physical properties like flexibility, strength, bounciness, color etc. [* Synthesized using chemicals available in the school laboratory] [** Synthesiz ed using Industrial Reagents] General Overview A polymer is a large molecule (macromolecule) composed of repeating structural u nits typically connected by covalent chemical bonds. While polymer in popular us age suggests plastic, the term actually refers to a large class of natural and s ynthetic materials with a variety of properties. Due to the extraordinary range of properties accessible in polymeric materials, they have come to play an essen tial and ubiquitous role in everyday life - from plastics and elastomers on the one hand to natural biopolymers such as DNA and proteins that are essential for life on the other. A simple example is polyethylene, whose repeating unit is bas ed on ethylene (IUPAC name ethene) monomer (Image 2.1). Most commonly, as in thi s example, the continuously linked backbone of a polymer consists mainly of carb on atoms. However, other structures do exist; for example, elements such as sili con form familiar materials such as silicones, examples being silly putty and wa terproof plumbing sealant. The backbone of DNA is in fact based on repeating uni ts of polysaccharides (e.g. cellulose) which are joined together by glycosidic b onds via oxygen atoms. Image 2.1 Page 1

Chemistry Project Natural polymers (from the Greek poly meaning many and meros meaning parts) are foun d in many forms such as horns of animals, tortoise shell, rosin (from pine trees ), and from distillation of organic materials. One of the most useful of the nat ural polymers was rubber, obtained from the sap of the hevea tree. (Rubber was n amed by a chemist found that a piece of solidified latex gum was good for rubbin g out pencil marks on paper. In Great Britain, erasers are still called rubbers.) Natural rubber had only limited use as it became brittle in the cold and melted when warmed. In 1839, Charles Goodyear discovered, through a lucky accident, tha t by heating the latex with sulfur, the properties were changed making the rubbe r more flexible and temperature stable. That process became known as vulcanizati on. Image 2.2 Image 2.3 The first synthetic polymer, a phenol-formaldehyde polymer, was introduced under the name Bakelite (Image 2.2 & 2.3), by Leo Baekeland in 1909. Its original use w as to make billiard balls. Rayon, the first synthetic fiber was developed as a r eplacement for silk in 1911. Although many polymers were made in the following y ears, the technology to mass produce them was not developed until World War II, when there was a need to develop synthetic rubber for tires and other wartime ap plications and nylon for parachutes. Since that time, the polymer industry has g rown and diversified into one of the fastest growing industries in the world. To day, polymers are commonly used in thousands of products as plastics, elastomers , coatings, and adhesives. They make up about 80% of the organic chemical indust ry with products produced at approximately 150 kg of polymers per person annuall y in the United States. Furthermore, conductive polymers are organic polymers that conduct electricity. Such compounds may be true metallic conductors or semiconductors. It is generall y accepted that metals conduct electricity well and that organic compounds are i nsulating, but this class of materials combines the properties of both. The bigg est advantage of conductive polymers is their processibility. Conductive polymer s are also plastics (which are organic polymers) and therefore can combine the m echanical properties (flexibility, toughness, malleability, elasticity, etc.) of plastics with high electrical conductivities. Their properties can be fine-tune d using the exquisite methods of organic synthesis. Page 2

Polymers Synthesis and Property Analysis Level of Caution 1. Bakelite Brief Description Bakelite is a material based on the thermosetting phenol formaldehyde resin, dev eloped in 19071909 by Belgian Dr. Leo Baekeland. Formed by the reaction under hea t and pressure of phenol (a toxic, colourless crystalline solid) and formaldehyd e (a simple organic compound), generally with a wood flour filler, it was the fi rst plastic made from synthetic components. It was used for its electrically non conductive and heat-resistant properties in radio and telephone casings and elec trical insulators, and was also used in such diverse products as kitchenware, je wellery, pipe stems, and children s toys. In 1993 Bakelite was designated an ACS National Historical Chemical Landmark in recognition of its significance as the world s first synthetic plastic. The retro appeal of old Bakelite products and labor intensive manufacturing has made them quite collectible in recent years. I mage 6.1 shows the structure of bakelite. Image 3.1 Page 3

Chemistry Project Precautions 1. Wear safety goggles at all times in the laboratory. 2. Formalin is an irritan t to the skin, eyes, and mucous membranes. 3. Phenol is toxic via skin contact. It is listed as a carcinogen. 4. Glacial acetic acid is an irritant and can caus e burns on contact. 5. Work under a hood and wear gloves and protective clothing when working with these materials. Materials Needed Chemicals: 1. 25g 40% formaldehyde 2. 20 g phenol 3. 55 mL glacial acetic acid 4 . conc Hydrochloric acid Apparatus: 1. 150-mL beaker 2. stirring rod Procedure First make the Phenol-formaldehyde reaction mixture by mixing 25 g 36-40% formal dehyde + 20 g phenol + 55 mL glacial acetic acid. Under a hood, measure 25 mL of the phenol-formaldehyde reaction mixture into a 150-mL beaker. Place the beaker on a white paper towel. Add 10 mL of concentrated hydrochloric acid, slowly, wi th stirring. Add additional hydrochloric acid, dropwise, with stirring. (You wil l need approximately 2 mL of HCl.) As the polymerization point is reached, a whi te precipitate will form and dissolve. At the point where polymerization begins, the white precipitate will not dissolve. Continue to stir as the plastic forms and becomes pink in color. Wash the plastic well before handling. Page 4

Polymers Synthesis and Property Analysis What actually happened I was slightly nervous to try out something absolutely new and was uncertain of its results. I took the chemicals given to me by Baboolal sir and followed the i nstructions. I took the phenol-formaldehyde reaction mixture in a beaker, placed it over a sheet of paper. Took a test tube full of HCl, and added it to the bea ker slowly with constant stirring. And by slowly I mean I almost emptied the tes t tube in about two minutes. I couldnt figure the polymerization point as no prec ipitate appeared. Thinking theres something wrong with the procedure, I went to a sk for maams advice. She asked me to indirectly heat it. Due to certain reasons, I didnt hear indirectly and heated the beaker over the flame for about 30 seconds . Nothing happened. Depressed, I walked away from it wondering what to do next. And then suddenly there was this loud noise of some kind of explosion. It was th e beaker. All the contents had poured out like foam, except solid. It was light pink in color. It had lots of pours in it and kind of looked like pumice stone. Maam said it happened because Id supplied a lot of heat by direct heating, and it seemed the most plausible explanation to it and so to obtain a proper polymer, I modified the experimental setup after discussing it with maam. I set up a large water filled beaker on a tripod stand with wire gauze and in a boiling tube took the reaction mixture. I fixed this boiling tube using a clamp stand, half dippe d in the beaker so that the contents were evenly heated. I added the same amount HCl as before, except this time, I added a few drops after every 30 seconds. Th is time, after 3 minutes, I could see something suddenly happen in the boiling t ube. I alerted maam but again it exploded. The sudden reaction broke the boiling tube, and caused a crack in the beaker. I collected the polymer and washed it. I ts physical appearance was the same as before. Both these experiments suggested that the reaction was extremely fast, but its activation energy was fairly high. So no matter if its directly heated, or indirectly, the moment it gains suffici ent energy, the polymerization starts rapidly. intermediate High AE energy reactant product reaction progress Page 5

Chemistry Project For determining the optimum conditions for the synthesis of Bakelite, I decided to take a reaction mixture in a beaker, heat it to a certain temperature (indire ctly), and then add HCl to find out the optimum temperature. I chose beaker over boiling tube, because as was apparent by the pores, greater the surface area, s afer it would be to carry out the reaction. Temperature 40-35 *C 50-45 *C 60-55 *C 75-60 *C 30-25 *C Observations No observable changes Turbidity started apearing Roughly Polymeriza tion started Semi Solid appeared at the bottom of the beaker At long standing, t he color changed to dark pink Property Analysis Test Flexibility Strength Bounciness Color Texture Inertness Result Brittle Low Negligible Dark Pink Slightly Porous Stable in air at room temp. Chemistry Behind it Phenol and Formaldehyde react in the following manner to make the polymer. Page 6

Polymers Synthesis and Property Analysis + + The structure below shows the growing molecule of BAKELITE. Level of Caution 2. POLYSTYRENE Brief Description Polystyrene (pronounced / plistarin/) (IUPAC Poly(1-phenylethane-1,2-diyl)), sometimes abbreviated PS, is an aromatic polymer made from the aromatic monomer styrene, a liquid hydrocarbon that is commercially manufactured from petroleum by the che mical industry. Polystyrene is one of the most widely used kinds of plastic. Pol ystyrene is a thermoplastic substance, which is in solid (glassy) state at room temperature, but flows if heated above its glass transition temperature (for mol ding or extrusion), and becoming solid again when cooling off. Pure solid polyst yrene is a colorless, hard plastic with limited flexibility. It can be cast into molds with fine detail. Polystyrene can be transparent or can be made to take o n various colors. Solid polystyrene is used, for example, in disposable cutlery, plastic models, CD and DVD cases, and smoke detector housings. Products made fr om foamed polystyrene are nearly ubiquitous, for example packing materials, insu lation, and foam drink cups. Polystyrene can be recycled, and has the number "6" as its recycling symbol. Polystyrene does not biodegrade, and is often abundant as a form of pollution in the outdoor environment, particularly along shores an d waterways. Page 7

Chemistry Project Precautions 1. Wear safety goggles at all times in the laboratory. 2. Styrene may pose healt h risks if it comes in contact with the body. 3. Styrene resin is sticky, so use gloves. 4. Work under a hood and wear gloves and protective clothing when worki ng with these materials. Materials Needed Chemicals: 1. Vinyl Benzene (Styrene Casting Resin) 2. Methyl ethyl ketone (Cast ing resin catalyst) Apparatus: 1. Test tubes 2. Stirring rod 3. Thermostat 4. Me asuring Cylinder 5. a 5 mL Syringe 6. Stop Watch Procedure Take 4 clean, numbered test tubes and to each add 3mL of Vinyl Benzene. Fill the syringe with methyl ethyl ketone. Start the stop watch. Make the volume of Viny l Benzene in test tube one equal to 5 mL. Now note the time as you add 5 divisio ns of the syringe, i.e. 0.5 mL to test tube one and stir it well. Repeat the abo ve 2 steps with 4.5 mL of Vinyl Benzene and 1.0 mL of methyl ethyl ketone, in th e second test tube and so one. Place these in the thermostat with temperature se t to 40 *C. Page 8

Polymers Synthesis and Property Analysis What actually happened Concentration of catalyst 0.5 1.0 1.5 2.0 Time taken to cure 3 hours 14 minutes 2 hours 18 minutes 2 hours 10 minutes 2 ho urs 3 minutes 3.5 3 2.5 2 Time 1.5 1 0.5 0 0 0.5 1 1.5 2 2.5 Concentration Page 9

Chemistry Project Property Analysis Test Flexibility Strength Bounciness Color Texture Inertness Result Low Medium N egligible Yellowish, Transparent Smooth Stable in air at room temp. Chemistry Behind it The chemical makeup of polystyrene is a long chain hydrocarbon with every other carbon connected to a phenyl group (the name given to the aromatic ring benzene, when bonded to complex carbon substituents). Polystyrene s chemical formula is (C8H8)n; it contains the chemical elements carbon and hydrogen. Because it is an aromatic hydrocarbon, it burns with an orange-yellow flame, giving off soot, as opposed to nonaromatic hydrocarbon polymers such as polyethylene, which burn wi th a light yellow flame (often with a blue tinge) and no soot. Complete oxidatio n of polystyrene produces only carbon dioxide and water vapor. This addition pol ymer of styrene results when vinyl benzene styrene monomers (which contain doubl e bonds between carbon atoms) attach to form a polystyrene chain (with each carb on attached with a single bond to two other carbons and a phenyl group). Page 10

Polymers Synthesis and Property Analysis Level of Caution 3. EPOXY RESIN Brief Description Epoxy or polyepoxide is a thermosetting polymer formed from reaction of an epoxi de "resin" with polyamine "hardener". Epoxy has a wide range of applications, in cluding fiber-reinforced plastic materials and general purpose adhesives. Credit for the first synthesis of bisphenol-A-based epoxy resins is shared by Dr. Pier re Castan of Switzerland and Dr. S.O. Greenlee of the United States in 1936. The applications for epoxy-based materials are extensive and include coatings, adhe sives and composite materials such as those using carbon fiber and fiberglass re inforcements (although polyester, vinyl ester, and other thermosetting resins ar e also used for glass-reinforced plastic). The chemistry of epoxies and the rang e of commercially available variations allows cure polymers to be produced with a very broad range of properties. In general, epoxies are known for their excell ent adhesion, chemical and heat resistance, good-to-excellent mechanical propert ies and very good electrical insulating properties. Many properties of epoxies c an be modified (for example silver-filled epoxies with good electrical conductiv ity are available, although epoxies are typically electrically insulating). Vari ations offering high thermal insulation, or thermal conductivity combined with h igh electrical resistance for electronics applications, are available. Precautions 1. Wear safety goggles at all times in the laboratory. 2. The hardner, Triethyle netetramine may cause allergic reactions. Wear gloves at all times. 3. Both the chemicals are sticky so avoid contact with bare hands. 4. Work under a hood and wear gloves and protective clothing when working with these materials. Page 11

Chemistry Project Materials Needed Chemicals: 1. Epoxy Resin (formed by reaction between epichlorohydrin and bisphe nol-A) + 2. Hardener (Triethylenetetramine) Procedure Apparatus: 1. Test tubes 2. Stirring rod 3. Thermostat 4. Measuring Cylinder 5. a 5 mL Syringe 6. Stop Watch Take 4 clean, numbered test tubes and to each add 3mL of Resin. Fill the syringe with Triethylenetetramine . Start the stop watch. Make the volume of Resin in t est tube one equal to 5 mL. Now note the time as you add 5 divisions of the syri nge, i.e. 0.5 mL to test tube one and stir it well. Repeat the above 2 steps wit h 4.5 mL of Resin and 1.0 mL of Triethylenetetramine , in the second test tube a nd so one. Place these in the thermostat with temperature set to 40 *C. Repeat a ll the steps and keep this set at room temperature. (7 *C) What actually happened at 40 *C Concentration of catalyst 0.5 1.0 1.5 2.0 Time taken to cure 28 minutes 20 minutes 12 minutes 10 minutes Appearance almost clear, yellowish slightly fr othy, yellowish frothy, yellowish very frothy, yellowish Page 12

Polymers Synthesis and Property Analysis at 40 *C 30 25 20 Time (min) 15 10 5 0 0 0.5 1 1.5 2 2.5 Concentration at 7 *C 180 160 140 120 Time (min) 100 80 60 40 20 0 0 0.5 1 1.5 2 2.5 Concentration Page 13

Chemistry Project at 7 *C Concentration of catalyst 0.5 1.0 1.5 2.0 Time taken to cure 170 minutes 150 minutes 130 minutes 95 minutes Appearance almost clear almost clear, starry f ewer bubbles, transparent bubbles, almost transparent Property Analysis Test Flexibility Strength Bounciness Color Texture Inertness Result Low High Neg ligible Transparent Smooth Stable in air at room temp. Unreactive to Acids Chemistry Behind it Epoxy is a copolymer; that is, it is formed from two different chemicals. These are referred to as the "resin" and the "hardener". The resin consists of monomer s or short chain polymers with an epoxide group at either end. Most common epoxy resins are produced from a reaction between epichlorohydrin and bisphenol-A, th ough the latter may be replaced by similar chemicals. The hardener consists of p olyamine monomers, for example Triethylenetetramine (TETA). When these compounds are mixed together, the amine groups react with the epoxide groups to form a co valent bond. Each NH group can react with an epoxide group, so that the resultin g polymer is heavily crosslinked, and is thus rigid and strong. The process of p olymerization is called "curing", and can be controlled through temperature and choice of resin and hardener compounds; the process can take minutes to hours. S ome formulations benefit from heating during the cure period, whereas others sim ply require time, and ambient temperatures. Page 14

Polymers Synthesis and Property Analysis + + RESULT Bakelite Its optimum synthesis temperature range was found to be 70-80 *C. Its sy nthesis requires high activation energy but the reaction is kinetically very fas t. Polystyrene It cures faster at higher concentrations of the catalyst. The str ength of the polymer was independent of the concentration ratio of the resin and catalyst. Its kinetics are complex as its concentration v/s curing time graph w as found to be irregular. The optimum temperature range for synthesis of this po lymer was found to be over 40 *C at the tested concentrations of the catalyst. E poxy Resin It cures faster at high concentrations of its catalyst. It also cures faster at higher temperature. The strength of the polymer was independent of th e concentration ratio of the resin and catalyst. The reaction may be following f irst order kinetics as the concentration v/s curing time graph was found to be c lose to linear. The optimum temperature range for synthesis of this polymer was found to be 5-10 *C at the tested concentrations of the catalyst. Page 15

Chemistry Project REFERENCES http://www.google.co.in/webhp?hl=en http://en.wikipedia.org/wiki/Polystyrene htt p://en.wikipedia.org/wiki/Styrene http://en.wikipedia.org/wiki/Epoxy http://en.w ikipedia.org/wiki/Bakelite http://papers.ssrn.com/sol3/papers.cfm?abstract_id=14 20502 http://answers.yahoo.com/question/index?qid=20090717144012AAKmCyb http://i nventors.about.com/od/pstartinventions/a/plastics.htm http://www.barrule.com/wor kshop/images/info/foams/index.htm http://www.ncbi.nlm.nih.gov/pmc/articles/PMC24 30229/ http://www.pslc.ws/mactest/styrene.htm http://www.americanchemistry.com/s _plastics/sec_pfpg.asp?CID=1421&DID=5213 Page 16

Polymers Synthesis and Property Analysis Chemistry Project for any further details or clarification, suggestions etc., contact me Email: to atularora@gmail.com ~ Cell: +91 9818055646 ~ Landline: +91 011 65683657