QUIZ

Time-90 minutes GASEOUS STATE Max. Marks-97

SINGLE CORRECT OPTION (+3,-1)
1. Two vessels of volume 2V and 3V contains two gases A and B separately at 1.5 and 4 atm
respectively. If the vessels are at constant temperature connected through a tube (negligible
volume). The total pressure of gaseous mixture is
(A) 3 atm (B)
15
atm
2
(C) 5 atm (D) 6 atm
2. The density of a gaseous substance at 1 atm pressure and 750 K is 0.30 g/litre. If the molecular
weight of the substance is 27, the forces existing among gas molecules is
(A) Attractive (B) Repulsive
(C) Both (D) None
3. Under identical conditions of temperature, the density of a gas X is two times that of gas Y while
molecular mass of gas Y is three times that of X. The ratio of pressure of X and Y will be:
(A)
2
3
(B)
3
2
(C) 6 (D) 3
4. 3 moles of the same gas are enclosed in two containers A and B at 25
o
C and at pressure 1.5
and 3 atm respectively. The rms velocity
(A) Will be same in both the containers A and B
(B) Will be more in container B
(C) Will be more in container A
(D) Cant be determined
5. If saturated vapours are compressed slowly at constant temperature to half the initial volume,
the vapour pressure will
(A) Becomes double (B) Becomes 4 times
(C) Becomes half (D) Remains unchanged
6. Equal masses of H2, He and CH4 are mixed in empty container at 300 K, when total pressure is
2.6 atm. The partial pressure of H2 in the mixture is:
(A) 0.5 atm (B) 1.6 atm
(C) 0.8 atm (D) 0.2 atm
7. When 100 ml of ozonised oxygen is passed through turpentine oil, there was a reduction of
volume by 20 ml. If 100 ml of such mixture is heated, what will be the increase in volume?
(A) 10 ml (B) 20 ml
(C) 40 ml (D) No change
8. In van der Waals equation of state for a nonideal gas the term that accounts for intermolecular
force is
(A) (Vb) (B) RT
(C)
2
a
P
V
_
+

,
(D)
1
RT
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9. Let the most probable velocity of hydrogen molecules at a temperature t
o
C is Vo. Suppose all
the molecules dissociate into atoms when temperature is raised to (27 + 273)
o
C then the new
rms velocity is
(A)
o
2
V
3
(B) 2Vo
(C)
o
2 3 V (D)
o
6 V
10. A mixture of H2 and He in 1 : 1 mass ratio is allowed to diffuse through a porous pot. The mole
ratio of H2 to He in the initially effused mixture will be
(A) 2 : 2 (B) 2 2: 1
(C) 1 : 2 (D) 1 : 1
11. The rate of diffusion of methane at a given temperature is twice that of a gas X. The molecular
weight of X is
(A) 64.0 (B) 32.0
(C) 4.0 (D) 8.0
12. A gas behaves most like an ideal gas under conditions of
(A) High pressure and low temperature
(B) High temperature and high pressure
(C) Low pressure and high temperature
(D) Low pressure and low temperature
13. If
1 2 3
C , C , C , ............
represent the speeds of
1 2 3
n ,n ,n ,...........
molecules, then the root mean
square speed is
(A)
1/ 2
2 2 2
1 1 2 2 3 3
1 2 3
n C n C n C ...........
n n n .........
1
+ + +
1
+ + +
]
(B)
1/ 4
2 2 2
1 1 2 2 3 3
1 2 3
n C n C n C ...........
n n n .........
1
+ + +
1
+ + +
]
(C)
2 1/ 2 2 1/ 2 2 1/ 2
3 3 1 1 2 2
1 2 3
(n C ) (n C ) (n C )
....
n n n
+ + +
(D)
1/ 2
2
1 1 2 2 3 3
1 2 3
(n C n C n C ...........)
(n n n .........)
1
+ + +
1
+ + +
]
14. A gas is heated from
o o
0 C to 100 C at 1.0 atm pressure. If the initial volume of the gas is 10L,
its final volume would be :
(A) 7.32 L (B) 10.0 L
(C) 13.66 L (D) 20.0 L
15. The root mean square velocity of an ideal gas at constant pressure varies with density (d) as
(A)
2
d (B) d
(C) d (D)
1
d
ARUN SHARMA/ CHEMISTRY/ FIITJEE LIMITED BHILAI CENTRE (C.G.)
MULTIPLE CORRECT OPTIONS (+4,-1)
16. Under similar conditions which of the following gases have same value of Crms as of CO2 ?
(A) NO2 (B) C3H8
(C) N2O (D) N2
17. If gas expands at constant temperature.
(A) the pressure decreases (B) K.E. of molecules remains the same
(C) K.E. of molecules decreases (D) the number of molecules increases
18. Which of the following statements are correct?
(A) the ratio Cp/Cv for He is more than that of hydrogen.
(B) the pressure of real gas is more than pressure of ideal gas.
(C) all gases show ideal behavior at critical temperature.
(D) Compressibility factor is zero for ideal gases.
19. Molecule of gas A is moving four times faster than molecules of gas B. Which of the following
are correct?
(A) The ratio MA/MB = (B) The ratio MA/MB = 1/16
(C) The ratio dA/dB = 1/8 (D) The ratio dA/dB = 1/16
20. The root mean square velocity of a gas is doubled, which of the following is/are correct?
(A) Its temperature is doubled (B) Its pressure is made four times
(C) Its temperature is increased four times (D) Its pressure is doubled.

ASSERTION AND REASON (+5,-1)
Directions: The questions (21 - 24) given below consists of an Assertion (A) and Reason (R). Use
the following key to choose the appropriate answer.
(A) Both A and R are true and R is correct explanation of A
(B) Both A and R are true but R is not correct explanation of A.
(C) A is true, R is false .
(D) A is false, R is true.
21. A. The vander Waals constant a is larger for NH3 than PH3.
R. Hydrogen bond is present in NH3.
22. A. Different gases at the same temperature and pressure have same value of Crms.
R. Average kinetic energy of gases is directly proportional to the absolute temperature.
23. A. On increasing temperature fraction of gaseous molecules having most probable velocity
also increases.
R. Most probable velocity is the velocity possessed by the maximum number of molecules.
24. A. Daltons law of partial pressure is applicable for the mixture of non reacting gases.
R. Daltons law is obeyed by ideal gases only.
ARUN SHARMA/ CHEMISTRY/ FIITJEE LIMITED BHILAI CENTRE (C.G.)
MATRIX- MATCHING (+6,-0)
25.
COLUMN I COLUMN II
A High temperature P Z 1
B Extremely low pressure Q Pb < a/V
C Very high pressure R Z=1
D Low pressure S Pb > a/V

26.
COLUMN I COLUMN II
A Tc/Pc P 8/27
B Tc/Vc Q a/Rb
C Tb R 8b/R
D Tc/Tb S 8a/81Rb
2
ARUN SHARMA/ CHEMISTRY/ FIITJEE LIMITED BHILAI CENTRE (C.G.)