BIRLA INSTITUTE OF TECHNOLOGY & SCIENCE, PILANI K.K.

.BIRLA GOA CAMPUS INSTRUCTION DIVISION FIRST SEMESTER 2010-2011 Course Handout (Part - II) Date: 01/08/2010 In addition to part-I (General Handout for all courses appended to the time table) this portion gives further specific details regarding the course. Course No. : CHEM C141 Course Title : Chemistry I Instructor-in-charge : Anjan Chattopadhyay Instructors: N.N.Ghosh, P.Bhavana, R.N.Panda, Ranjan Dey, K.P.Jayadevan, Sujit Kumar Ghosh, Halan Prakash, Mainak Banerjee Scope and Objective of the Course: The course provides a comprehensive survey of the concepts involved in the study of the electronic structure of atoms and molecules, spectroscopy, phase and chemical equilibrium, electrochemistry, and chemical kinetics,.: Text Book: The Elements of Physical Chemistry, (Oxford University Press, Oxford 2009). P.W. Atkins & Julio de Paula, Fifth edition

Reference Book: Atkins Physical Chemistry, P.W. Atkins & Julio de Paula, eighth edition. Course Plan : LN Topic 1-4 Quantum Theory 5-6 Atomic Structure: and Spectra Learning Objectives Photoelectric effect, Wave function, Schrodinger Equation, Uncertainty, Simple Applications Hydrogenic Atom: Energy Levels and Wavefunctions, Orbitals, Spectral Transitions, Many-electron Atoms: Pauli Principle, Orbital Approximation, Aufbau Principle, Periodic Trends Lewis Theory, VSEPR Model, VB Theory: Electron Pair Bond, Hybridization, Resonance, MO Theory: LCAO, Bonding and Antibonding Orbitals, Diatomic Molecules General Features, Diatomic Rotational and Vibrational Energy Levels and Spectra; Electronic Spectra: Franck-Condon Principle, Types of Transition, Fluorescence & Phosphorescence Thermodynamic Systems, State Functions, Thermal Equilibrium and Temperature, Work, Internal Energy and Heat Capacity Application of the Ist Law to Physical and Chemical Changes, Lattice Enthalpy Natural and Reversible Processes, Entropy and Second Law, Calculation of Entropy Changes, Absolute Entropies, Spontaneity and Equilibrium, Gibbs Energy Text 12.1-12.9 13.1-13.9 13.10-13.16 SS

7-9

Chemical Bonding: Valence Bond and Molecular Orbital Theories Spectroscopy: Rotational, Vibrational, and Electronic

A4.2, A4.3 14.1-14.14

10-14

19.1-19.3, 19.519.8, 19.10-19.13 20.2 20.6 2.1-2.9 3.1-3.4 SS 3.5-3.7 4.1-4.13

15 - 16

Thermodynamics: the First Law, Internal Energy and Enthalpy

Thermochemistry Thermodynamics: the Second Law, Entropy, Gibbs Energy, the Third Law

17 18 - 21

22 - 24 25 - 27

28 - 29 30 32 33-35

Phase Equilibria: Pure Substances, Phase Rule and Phase Diagrams Mixtures: Thermodynamic Description, Colligative Properties, Phase Equilibrium Chemical Reaction Thermodynamics Equilibria in Aqueous Solution Electrochemistry: Solution Conductivity, Electrochemical Cells and Applications, Electrode Processes Chemical Kinetics: Experimental Methods, Reaction Rates, Temperature Dependence Chemical Kinetics: Reaction Mechanisms and Rate Laws

Conditions of Stability, Gibbs Energy and Thermodynamics of Phase Transition, Phase boundaries, Phase Rule Partial Molar Properties, Ideal, Ideal-dilute and Real Solutions, Boiling and Freezing points, Osmosis Reaction Gibbs Energy, Reaction Quotient, Equilibrium Constant, Coupled Reactions, Response to Conditions Proton Transfer Equilibria, Acid-Base Titration, Buffers, Solubility Ionic Mobility and Conductivity, Electrodes and Half-reactions, Cells, Cell Reactions and Potentials, Standard Potentials, Electrochemical Series Rate Laws, Order, Rate Constants, Arrhenius Equation Elementary Process, Rate-determining Step, Steady-state Approximation, Reactions on Surfaces, Unimolecular Reactions, Reactions in Solution, Catalysis Homogeneous, Heterogeneous, and Enzyme, Chain Reactions, Photochemical Processes Date, Day &Time 20.09.2010 (8:30AM-9:30AM) 01.11.2010 (8:30AM-9:30AM) 06.12.2010(FN) Remarks Closed Book Open Book Closed Book

5.1 5.7 6.1 6.7

7.1 7.9 8.1 8.10 9.1-9.2 SS 9.3 9.13

36 - 37

10.3-10.11

38 - 40

11.4-11.9, 11.12-11.15

Evaluation Scheme: Component Duration Test I 60 mts Test II Comprehensive Examination 60 mts 3 hrs.

Weightage% 30% 30% 40%

Chamber Consultation Hours: To be announced in the tutorial class. Notices: Notices concerning the course will be displayed on the Students Notice Board C-wing and/or on ftp. Instructor-in-Charge CHEM C141