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EQUAO DE ANTOINE

de vapor, mmHg
B pT == presso
temperatura, C
log p = A A, B, C = constantes
C+T
Substncia

Frmula
C3H6O

A
7.02447

B
1161.00

C2H4O2

7.18807

1416.70

H2O

7.96681

1668.21

C6H7N

7.24179

1675.30

5 Benzeno

C8H6

6.90565

1211.03

6 i-Butano

C4H10

6.74808

882.80

7 n-Butano

C4H10

6.83029

945.90

8 Estireno

C8H8

6.92409

1420.00

C2H6O

8.04494

1554.30

10 ter dietlico

C4H10O

6.78574

994.20

11 Etilbenzeno
12 Etilenoglicol
13 n-Heptano

C8H10
C7H16

6.95719
7.88080
6.90240

1424.26
1957.00
1268.12

14 n-Hexano

C6H14

6.87776

1171.53

15 n-Octano

C8H18

6.92370

1355.13

16 i-Pentano

C5H12

6.78967

1020.01

17 n-Pentano

C5H12

6.85221

1064.63

18 Tolueno

C7H8

6.95464

1344.80

19 o-Xileno

C8H10

6.99891

1474.68

20 m-Xileno

C8H10

7.00908

1462.27

21 p-Xileno

C8H10

6.99052

1453.43

1 Acetona
2 cido actico
3 gua
4 Anilina

9 Etanol

OINE

vapor, mmHg

C
224.00
211.00
228.00
200.00
220.79
240.00
240.00
206.00
222.65
220.00
213.21
193.80
216.90
222.37
209.52
233.10
232.00
219.48
213.69
215.11
215.31

Presso = 1500

SUBST. A =
CTE. A =
CTE. B =
CTE. C =
Teb =

Temp. (C)
120.2171
116.9776
113.7381
110.4986
107.2591
104.0196
100.7801
97.5406
94.3011
91.0616
87.8221
84.5826
81.3431
78.1036
74.8641
71.6246
68.3851
65.1456
58.6666
55.4271

gua

7.9668
1668.2100
228.0000
120.2

pA
1500.00
1352.40
1216.93
1092.82
979.32
875.74
781.40
695.63
617.84
547.42
483.83
426.53
375.02
328.84
287.54
250.69
217.92
188.84
140.43
120.49

Curva de equilbrio:
gua

(mmHg)

pB
7303.02
6845.58
6408.73
5992.01
5594.94
5217.02
4857.76
4516.66
4193.21
3886.91
3597.23
3323.66
3065.68
2822.76
2594.38
2380.01
2179.13
1991.21
1652.17
1500.00
/

x
1.0000
0.9731
0.9455
0.9169
0.8872
0.8562
0.8237
0.7895
0.7533
0.7148
0.6736
0.6295
0.5819
0.5304
0.4744
0.4133
0.3463
0.2725
0.1007
0.0000
ter dietlico

SUBST. B =
CTE. A =
CTE. B =
CTE. C =
Teb =

y
1.0000
0.8774
0.7671
0.6680
0.5792
0.4999
0.4291
0.3661
0.3103
0.2608
0.2173
0.1790
0.1455
0.1163
0.0909
0.0691
0.0503
0.0343
0.0094
0.0000

ter dietlico

6.7857
994.1950
220.0000
55.4

a
0.1976
0.1899
0.1824
0.1750
0.1679
0.1609
0.1540
0.1473
0.1408
0.1345
0.1283
0.1223
0.1165
0.1108
0.1053
0.1000
0.0948
0.0850
0.0803

10

Curva de equilbrio: ter dietlico-Etanol (1500 mmHg)


1.0

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0.0
0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0

Diagrama das temperaturas de ebulio


100
96
92
88
84

80
76
72
68
64
60
56
52
0.0

0.1

0.2

0.3

0.4

0.5

0.6

0.7

0.8

0.9

1.0