Control NO.

: RBN-ML100-2

Material Safety Data Sheet

Ink Ribbon

For : ML100S ML184 ML280 ML3320/1 ML320/1T

Oki Data Corporation

SAFETY DATA SHEET RBN-ML100 1. Identification of the substance/preparation and of the company/undertaking
Product name Code Manufacturer : : : ML100'S ML184 ML280 ML3320/1 ML320/1T 4PB4025-1310P009 4PB4025-1309P001 Oki Data Corporation 4-11-22, Shibaura, Minato-ku,TOKYO,108-8551 JAPAN Tel. +81-3-5445-6106. Fax +81-3-5445-6177 Oki (Europe) Ltd. 1 Oki Way, Wardpark , Cumbernauld G68 0FQ, SCOTLAND, UK Tel. +44(0) 1236 502502 Tel. +44(0) 1236 502502 MSDSQuestions@okieurope.com

Supplier

Emergency telephone number Emergency e-mail contact

: :

2. Hazards identification
GHS classification
PHYSICAL HAZARDS Explosives Flammable gases Flammable aerosols Oxidizing gases Gases under pressure Flammable liquid Flammable solid Self-reactive substances and mixtures Self-igniting liquids Self-igniting solids Self-heating substances and mixtures Substances and mixtures which emit flammable gases when they come in contact with water Oxidizing liquids Oxidizing solids Organic peroxides Substances corrosive metals to HEALTH HAZARDS Acute toxicity (oral) Acute toxicity (dermal) Acute toxicity (respiratory: gases) Acute toxicity (respiratory: vapors) Acute toxicity (dust) Acute toxicity (mist) Skin corrosion/irritation Serious eye damage/irritation Respiratory sensitization Skin sensitization Germ cell mutagenicity Carcinogenicity Reproductive toxicity Specific target organ systemic toxicity (Single exposure) Specific target organ systemic toxicity (Repeated exposure) Aspiration hazard ENVIRONMENTAL HAZARDS Acute toxicity to aquatic environment Chronic toxicity to aquatic environment

: : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : : :

No classification Not applicable Not applicable Not applicable Not applicable No classification No classification No classification Not applicable Outside category No classification Outside category

No classification No classification No classification No classification

No classification No classification Not applicable No classification No classification No classification No classification No classification No classification No classification Category 2 Category 2 No classification No classification Category2(lungs) No classification

No classification No classification

Date of issue : 11/7/2007

Date of modification : 16/11/2009

Page : 1/4

RBN-ML100
LABEL ELEMENT
Pictogram or symbol

Signal word Danger/toxicity information

: :

Warning Suspected of causing genetic defects. Suspected of causing carcinogenesis. Causes damage to internal organs (lungs) through prolonged or repeated exposure. Should be stored in cool, dark places. Wear protective gloves when required. Avoid ingestion.

Notes

3. Composition/information on ingredients
Distinction between single products and mixtures Generic name Chemical name
Ingredients Carbon black Other coloring materials Oils Additives Nylon 6-6 fabric PSM fiber

Mixtures

: :

Ink ribbon

Content (%) 5 Confidential Confidential Confidential Confidential Confidential

Chemical Substances Control Law No. Not applicable

CAS No. 1333-86-4

4. First aid measures

Contact with skin Contact with eyes Inhalation Drink

: : : :

Wash with soap and lots of water. Flush eyes with lots of water and seek advice of a physician. Not applicable Seek advice of a physician.

5. Fire-fighting measures
Suitable extinguishing media Prohibited extinguishing media Special hazard Special fire-fighting procedure Special protective equipment

: : : : :

Water, foam, dry powder, CO2 gas, others None None None Use suitable respiratory equipment and wear protective clothing as required.

6. Accidental release measures

Personal precautions, protective equipment and emergency procedures Environmental precautions Recovery/neutralization Method/equipment for cordoning and cleaning Prevention of secondary disasters

: : : : :

None

Mistakenly unwound ribbons that cannot be rewound and used ribbons must be recovered and properly disposed of. Mistakenly unwound ribbons must be rewound. Not applicable Not applicable

Date of issue : 11/7/2007

Date of modification : 16/11/2009

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RBN-ML100 7. Handling and storage

Handling
Technical measures Local and general ventilation Safety/handling precautions Avoid contact

: : : :

Wear protective gloves when required. Not applicable Must not be ingested. Wash hands after handling. None

Storage
Technical measures Incompatibility with other materials Storage conditions Packaged Materials/materials stored in containers

: : : :

Not applicable No data Should be stored in cool, dark places. Not applicable

8. Exposure controls/personal protection

Controlled concentration Allowable concentration Facility measures Personal protection
Respiratory protection Hand protection Eye protection Skin and bodily protection : : : : : : : : Not established Not established as a product ACGIH Carbon black TLV-TWA 3.5 mg/m3 Not applicable Not applicable Wear protective gloves when required. Not applicable Not applicable Wash hands after handling.

Personal hygiene

9. Physical and chemical properties

Appearance, physical state Odor pH Freezing/melting point Boiling point, initial boiling point and boiling point range Flash point Explosive range Vapor pressure Vapor density Specific gravity Solubility Octanol/water partition coefficient Autoignition temperature Decomposition temperature Odor threshold level Evaporation rate (butyl acetate = 1) Combustibility (solids, gases) Viscosity : : : : : : : : : : : : : : : : : : Nylon 6-6 fabric impregnated with liquid black ink Odorless No data No data No data Min. 150C No data No data No data No data Insoluble in water No data No data No data No data Not applicable Not applicable No data

10. Stability and reactivity

Stability Dangerous/toxic reaction potential Conditions that must be avoided Incompatibility with other materials Hazardous decomposition products : : : : : Stable under ordinary conditions No data No data No data No data

Date of issue : 11/7/2007

Date of modification : 16/11/2009

Page : 3/4

RBN-ML100 11. Toxicological information

Acute toxicity Skin corrosion/irritation Serious eye damage/irritation

: : : : : : : :

No data No data No data No data Carbon black is Category 2. Category 2 was decided upon because each contains a minimum of 1%. Carbon black is Category 2. Category 2 was decided upon because each contains a minimum of 1%. No data Carbon black is Category 1. Category 1 was decided upon because each contains a minimum of 10%. Due to the form and the way the product is used, however, the probability of carbon black or ink contained splashing is considered low. No data

Respiratory sensitization/ skin sensitization Germ cell mutagenicity Carcinogenicity Specific target organ systemic toxicity (Single exposure) Specific target organ systemic toxicity (Repeated exposure) Aspiration hazard

12. Ecological information

None

13. Disposal considerations

Must be disposed of in accordance with pertinent laws and local standards.

14. Transport information

UN regulations
UN category UN No. : : : : Not applicable Not applicable None None

JP regulations Special safety measures

15. Regulatory information

Industrial Safety and Health Law Fire Service Law
: Hazardous substances that must be named (Ordinance Article 57, No. 2; implementation No. 18, Article 2, Table 9) Carbon black (government ordinance No. 130) Specified combustible materials, combustible solids

16. Other information

None Handling of contents Not all materials and sources were investigated, and some information may consequently be left out. Contents are subject to change in the case of new findings or correction of existing descriptions. If used for important decisions, etc., we recommend proving by testing, etc. The figures given for content, physicochemical properties, etc., are not guaranteed. The precautions contained herein apply to ordinary handling. This should be considered in the case of special handling.

Date of issue : 11/7/2007

Date of modification : 16/11/2009

Page : 4/4