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Composto HMD HMI DCH ACN Imina do BHT BHT ADN CHL AdOH GlOH SuOH Cicloexano Fenol Cicloexanona Dextrose Frmula C 6 6 6 6 12 12 6 6 6 5 4 6 6 6 6 H 16 13 14 12 27 29 8 12 10 8 6 12 6 11 12 O N 2 1 2 2 3 3 2
Composto MM
C 12.011
1 4 4 4 1 1 6
MM (g/mol) DQO (kg O2/ kg) 116.2 2.34 99.2 2.74 114.2 2.24 112.2 2.14 213.4 2.47 215.4 2.53 108.1 1.92 100.2 2.72 146.1 1.42 132.1 1.21 118.1 0.95 84.2 3.42 94.1 2.38 99.2 2.66 180.2 1.07 #DIV/0!
Massa molar do composto Clculo terico considerando oxidao total do composto (formao de H2O, CO2 e NH3) em kg O2 por kg pro Nitrognio total do composto Nitrognio amoniacal: quantidade de nitrognio contada em amnia DQO necessria para abater o NTK. A Rhodia adota proporo de 1.5 : 100 entre NTK e DQO Preencher onde estiver em amarelo
This is a set of four equations for four unknowns so we can solve them all : b=m d=r c = (n - 3*d)/2 = *n 3/2*r a = (2*b + c p)/2 = m + *n *r *p Theoretical oxygen demand due to carbonaceous oxidation
The carbonaceous oxidation uses a = m + *n *r *p moles of O2 per mole of CmHnOpNr. We can convert this molar ratio to a mass ratio by using the molecular weights of O2 (32 g/mol) and CmHnOpNr (12*m + n + 16
ThOD =
(m + 14 n - 3 4 r - 12 p )mol
1mol C m H n O p N r
32 g O 2 mol O 2
1mol C m H n O p N r
(12m + n + 16 p + 14r )g C
ThOD = 8
4m + n - 2 p - 3r g O / g Cm H nO p N r 12m + n + 16 p + 14r 2
Total theoretical oxygen demand (carbonaceous + nitrogenous) No utilizado na Rhodia. Apenas para conhecimento. A further 2 moles of oxygen to oxidize each of the d = r moles of NH3 produced during the carbonaceous step. CmHnOpNr + a O2 = b CO2 + c H2O + d NH3 NH3 + 2 O2 = NO3- + H2O + H+ The total number of moles of oxygen used per mole of CmHnOpNr is then (m + *n *r *p) + 2*r.
( m + 1 n - 3 r - 1 p + 2r )mol 4 4 2 ThOD =
1molCm H nO p N r
ThOD = 8
O2
32 g O2 molO2
(12m + n + 16 p + 14r )g C H O N
m n p
1molCm H nO p N r
4 m + n - 2 p + 5r g O / g Cm H nO p N r 12m + n + 16 p + 14r 2
H 1.0079
O 15.9994
N 14.00675
NTK (kg N/ kg) N-NH3 (kg NH3/kg) DQO p/ NTK (kg O2/kg) 0.24 0.29 16.07 0.14 0.17 9.42 0.25 0.30 16.35 0.25 0.30 16.65 0.20 0.24 13.13 0.20 0.24 13.01 0.26 0.31 17.27
#DIV/0!
#DIV/0!
#DIV/0!
r mole of CmHnOpNr. hts of O2 (32 g/mol) and CmHnOpNr (12*m + n + 16*p + 14*r, in g/mol)
mol C m H n O p N r
16 p + 14r )g C m H n O p N r
(m + *n *r *p) + 2*r.
1molCm H nO p N r
+ 16 p + 14r )g Cm H nO p N r