Report No.

51220

Report generated by:

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CRUDE OIL ASSAY REPORT

TITLE

UMM SHAIF (UNITED ARAB EMIRATES) CRUDE OIL

JANUARY 2000

DATE

GENERATED BY

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BP Oil Inc

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Page 1 of 27

Page 2 of 27

Crude Name
Report no.
PPEFA pack number
Sample Date
Total crude oil
Density
kg/l
API
Sulphur
%wt
Pour point
C
KV @ 20C
cSt
KV @ 40C
cSt
Acidity
mg KOH/g
Yields
Gas to C4
Total to 95C
149C
175C
232C
342C
369C
509C
550C
585C
15-95
Density
RON (C)

Umm Shaif
51220
PPEF881C
17.1.2000
0.8385
37.2
1.31
-18
5.96
3.54
0.05

%wt
1.5
10.1
20.1
25.35
36.2
57.45
62.3
82.3
86.45
kg/l

0.6734
62.0000

kg/l

0.7106

Kerosine 149-232
Density
Sulphur
Freeze
Naphthalenes
Acidity
Smoke point
Cetane Index

kg/l
%wt
C
% vol
mg KOH/g
mm

0.7899
0.097
-56
0.46
0.015
26
42.8

Gas Oil 232-342

Density
Sulphur
Pour point
Acidity
Cetane Index

kg/l
%wt
C
mg KOH/g

0.8439
0.88
-15
<0.05
51.5

kg/l
%wt
ppm wt
%wt
cSt

0.9139
2.02
680
0.1
1.4899
5.96

kg/l
%wt
ppm wt
%wt
ppm wt
ppm wt
cSt

1.00
3.61
2500.00
15.10
6.00
20.00
346.00

Light Distillate 15 to 149

Density

Vacuum Gas Oil 369-509

Density
Sulphur
Nitrogen
CCR
RI @ 70C
KV @ 100C
>550
Density
Sulphur
Nitrogen
CCR
Nickel
Vanadium
KV @ 100C

Page 3 of 26

MIDDLE EAST
UNITED ARAB EMIRATES
UMM SHAIF

PPEF881C
SOURCE OF SAMPLE
Reference

CRUDE DATA

A05200

ASSAY SUMMARY/TBP DATA

Gravity

37.2

Light Hydrocarbon
Analysis
Field

DAS ISLAND

Export
Terminal
Source

H2S
Methane
Ethane
Propane
Isobutane
n-Butane

UMM SHAIF

sample taken during

DISCHARGE OF mv OLYMPIC
SYMPHONY AT KWINANA

Sample Date

17-Jan-00

Date Rec'd

26-Apr-00

ppm wt
%wt
%wt
%wt
%wt
%wt

31.0
0.01
0.16
0.23
1.1

Total C1 - C4

1.5

Isopentane %wt
n-Pentane %wt

1.01
1.66

Yield on Crude

%wt

%vol

Gas to C4 (corrected)
Light Distillate to 149C (API)
Kerosine 149 - 232C
Gas oil 232 - 342C
Residue above 342C

1.50
18.60
16.10
21.25
42.55

2.32
21.70
17.08
21.06
37.85

Gas to C4 (corrected)

1.50

Total to 95C (API)

149C
175C
232C
342C
369C
509C
550C
585C

2.32

10.10
20.10
25.35
36.20
57.45
62.30
82.30
86.45
-

12.75
24.01
29.74
41.09
62.15
66.73
85.03
88.69
91.10

Volume expansion of 0.3 per cent vol on

crude distributed across whole distillation
DISTILLATES

TBP cut point C

API

Yield on crude
Yield on crude

Total
Crude
%wt
%vol

Density at 15C

C5-95 **

100.0
100.00

kg/litre

95-175
(C)

8.60
10.43

C5-149
(C)

15.25
16.99

18.6
21.70

149-232
16.1
17.08

232-342

342-369

21.25
21.06

4.85
4.58

369-509
20.0
18.30

509-550
4.15
3.66

0.8385

0.6734

0.7562

0.7106

0.7899

0.8439

0.8864

0.9139

0.9475

Sulphur
Mercaptan sulphur

%wt
%wt

1.31
-

0.095
0.0801

0.067
0.0441

0.077
0.0612

0.097
0.0387

0.880
-

2.010
-

2.020
-

2.550
-

Viscosity at 20C
30C
40C
50C
60C
100C
Cloud point
Pour point
Wax (NMR)
Wax (BP237)

cSt

5.96
4.46
3.54
-18
-

1.05
0.84
-

0.05
2.1
0.11

0.015
-

C
C
%wt
%wt

Total nitrogen
Basic nitrogen
Organic oxygen
Acidity
Carbon residue
Asphaltenes
Vanadium
Nickel
Iron

ppm wt
ppm wt
%wt
mgKOH/g
%wt
%wt
ppm wt
ppm wt
ppm wt

Arsenic
Cadmium
Copper
Lead
Mercury

ppb
ppb
ppb
ppb
ppb

wt
wt
wt
wt
wt

3
<2
3
<4
72
<10
50
<1

Aromatics
%vol
Smoke point
mm
Freezing point
C
Cetane Index ASTM D976
Cetane Index IP380
CsubA
%
Refractive index at 70C

Hydrogen content
Paraffins
Naphthenes
Aromatics
n-Paraffins
Colour stability

%wt
%wt
%wt
%wt
%wt
%vol

Naphthalenes
Salt
Water

lb/1000bbl
%vol

34

320
<0.05
-

22.0
26
- 56.0
42.8
45.0
-

27.0
18
- 10.5
51.5
55.4
16.2
1.4502

84.0
12.3
3.7
46.0
-

64.0
15.0
21.0
28.8
-

73.3
15.0
11.7
37.5
-

14.0
Stable

29.8
Stable

0.46

<0.05

9.01

Research Octane Number (C)

Selenium
ppb wt

62.0
-

H2S Evolved @ 160C

Calcium (unwashed)
Calcium (washed)
Chlorine (unwashed)
Chlorine (washed)

ppm wt
ppm wt
ppm wt
ppm
ppm

(C) = Calculated
** = Analysis carried out on 15-95C fraction
These acidities may have been subject to thermal degradation
* = Summation of the poly-aromatic data from Table 18

Crude Dry Density at 15C (kg/l)

Crude API (from Dry Density)

Page 4 of 26

6.80
2.43
12
12
16.2
-

<0.05
-

2.64
1.26
-15
-15
3.6
-

0.8385
37.2

47.1
19.7
1.475

18.00
5.96
33
14.7
680
175
0.15
<0.05
0.1
19.5
1.4899

369 - 509 DWO

Density at 15C
kg/l
Viscosity at 40C cSt
60C cSt
100C cSt
Viscosity index
Pour point
C
-

106.00
20.90
13.8
1300
290
<0.05
1.9
21.1
1.511
0.9281
55.7
22.6
6.71
61
-18
-

Table 1
Umm Shaif Crude Oil
Properties of Residues
RESIDUES
TBP Cut point (API)

Yield on crude oil

Yield on crude oil

%wt
%vol

Density at 15C

kg/litre

342
(C)
42.55
37.85

369

509

550

37.7
33.27

17.7
14.98

13.55
11.31

0.9400

0.9475

0.9885

1.0020

Sulphur

%wt

2.58

2.65

3.36

3.61

Viscosity at 50C
60C
80C
100C
120C
150C

cSt
cSt
cSt
cSt
cSt
cSt

106.0
-

152.0
90.5
38.6
19.9
11.7
-

153
67
25.6

346
134
44.9

>500
19.2
-

>500
24.0
-

Penetration at 25C mm/10

Softening point
C
Viscosity at 60C (Vac Cap) Pa.s
Pour point
Wax content (BP237)
Wax content (NMR)
Total nitrogen
Basic nitrogen
Acidity

Carbon residue
Asphaltenes
Vanadium
Nickel
Iron

Xylene equivalent
CsubA

Saturates
Aromatics
Resins A
Resins B

C
%wt
%wt

ppm wt
ppm wt
mgKOH/g

%wt *
%wt *
ppm wt
ppm wt
ppm wt

27
12.5
1280
-

30
12.0
1400
390
<0.05

5.1
0.27
6
2
6

%wt
%wt
%wt
%wt

2220
635

8.0
2500
740

5.7
0.3
7
2
7

12.0
0.6
15
5
15

15.1
0.8
20
6
20

0
21.2

8
81
9
2

28
66
5
1

(C) = calculated value

( ) = extrapolated value
* = balanced within the reproducibility of the method
These acidities may have been subject to thermal degradation

Page 5 of 26

27
9.0

Table 2
Umm Shaif Crude Oil
Individual Hydrocarbons in the 15 - 95C Cut

TBP Cut point

15 - 95

Yield on crude oil

15 - 95

8.60

Position in Crude
Hydrocarbons

1.5
% wt
On Cut

ethane
propane
iso-butane
n-butane
neo-pentane
iso-pentane
n-pentane
2,2-dimethylbutane
cyclopentane
2,3-dimethylbutane
2-methylpentane
3-methylpentane
n-hexane
2,2-dimethylpentane
methylcyclopentane
2,4-dimethylpentane
2,2,3-trimethylbutane
benzene
3,3-dimethylpentane
cyclohexane
2-methylhexane
2,3-dimethylpentane
1,1-dimethylcyclopentane
3-methylhexane
1,cis-3-dimethylcyclopentane
1,trans-3-dimethylcyclopentane
3,ethylpentane
1,trans-2-dimethylcyclopentane
2,2,4-trimethylpentane
n-heptane
1,cis-2-dimethylcyclopentane
methylcyclohexane
2,2,3,3-tetramethylbutane
1,1,3-trimethylcyclopentane
2,2-dimethylhexane
ethylcyclopentane
2,5-dimethylhexane
2,2,3-trimethylpentane
2,4-dimethylhexane
1,trans-2-cis-4-trimethylcyclopentane
3,3-dimethylhexane
1,trans-2,cis-3-trimethylcyclopentane
2,3,4-trimethylpentane
2,3,3-trimethylpentane
toluene
higher boiling non-aromatics
Total

10.43
10.1
% wt
On Crude

2.32
% vol
On Cut

0.01
0.49
0.02
11.42
19.19
0.29
1.45
1.10
9.09
5.66
19.07
0.20
4.10
0.60
0.03
2.24
0.11
2.75
3.86
1.11
0.24
3.66
0.54
0.48
0.23
0.80
0.01
7.43

trace
0.04
trace
0.98
1.65
0.02
0.12
0.09
0.78
0.49
1.64
0.02
0.35
0.05
trace
0.19
0.01
0.24
0.33
0.10
0.02
0.31
0.05
0.04
0.02
0.07
trace
0.64

0.01
0.56
0.02
12.30
20.56
0.30
1.29
1.10
9.31
5.61
19.35
0.20
3.66
0.60
0.03
1.71
0.11
2.37
3.81
1.07
0.21
3.57
0.46
0.41
0.22
0.69
0.01
7.28

trace
0.06
trace
1.28
2.15
0.03
0.13
0.11
0.97
0.59
2.02
0.02
0.38
0.06
trace
0.18
0.01
0.25
0.40
0.11
0.02
0.37
0.05
0.04
0.02
0.07
trace
0.76

1.64

0.14

1.40

0.15

0.06
0.01
0.16
0.08
0.10
0.04
0.03
0.01
1.47
0.24

0.01
trace
0.01
0.01
0.01
trace
trace
trace
0.13
0.02

0.05
0.01
0.14
0.08
0.09
0.03
0.03
0.01
1.14
0.21

0.01
trace
0.01
0.01
0.01
trace
trace
trace
0.12
0.02

100.02

8.59

100.01

10.42

Page 6 of 26

12.75
% vol
On Crude

Table 3
Umm Shaif Crude Oil
Individual Aromatic Components in the 15 - 175C Range

TBP Cut point C

15 - 95*

95 - 149

Yield on crude oil

%wt

Position in Crude

%wt

Hydrocarbons

%wt

On Cut

On Crude

benzene
toluene
ethylbenzene
p-xylene
m-xylene
isopropylbenzene
o-xylene
n-propylbenzene
1-methyl-3-ethylbenzene
1-methyl-4-ethylbenzene
tert-butylbenzene
isobutylbenzene
1,3,5-trimethylbenzene
sec-butylbenzene
1-methyl-3-isopropylbenzene
1-methyl-2-ethylbenzene
1-methyl-4-isopropylbenzene
1,2,4-trimethylbenzene
1,4-diethylbenzene
1-methyl-3-n-propylbenzene
1-methyl-2-iso-propylbenzene
1-methyl-4-n-propylbenzene
1,3-diethylbenzene
n-butylbenzene
1,3-dimethyl-5-ethylbenzene
1,2-diethylbenzene
1-methyl-2-n-propylbenzene
1,2,3-trimethylbenzene
1,4-dimethyl-2-ethylbenzene
1,3-dimethyl-4-ethylbenzene
1,2-dimethyl-4-ethylbenzene
indane
C11 aromatics

2.24
1.47
-

0.19
0.12
-

Total

%wt

8.45
1.5

149 - 175

10.00
10.1

10.1

20.1

20.1

25.35

On Crude

On Cut

0.31
6.76
2.28
1.43
3.68
0.26
2.22
0.29

0.03
0.68
0.23
0.14
0.37
0.03
0.22
0.03

0.00
0.19
0.86
0.73
1.99
0.54
1.94
1.19

trace
0.01
0.05
0.04
0.10
0.03
0.10
0.06

0.65

0.07

4.10

0.22

0.14

0.01

1.75

0.09

0.27

0.03

3.16

0.17

0.21
-

0.02
-

4.27
0.51

0.22
0.03

0.50

0.03

0.25

0.01

0.03
-

trace
-

0.37
0.05
0.21
1.73
0.31
0.27
0.10
0.25
0.32

0.02
trace
0.01
0.09
0.02
0.01
0.01
0.01
0.02

3.71

0.31

18.53

1.85

25.59

1.34

Note:- *Summation of individual components from Table 2.

Page 7 of 26

On Cut

5.25

On Crude

Table 3A
Umm Shaif Crude Oil
Individual Aromatic Components in the 15 - 175C Range

TBP Cut point C

Yield on crude oil

%vol

Position in Crude

%vol

Hydrocarbons

%vol

benzene
toluene
ethylbenzene
p-xylene
m-xylene
isopropylbenzene
o-xylene
n-propylbenzene
1-methyl-3-ethylbenzene
1-methyl-4-ethylbenzene
tert-butylbenzene
isobutylbenzene
1,3,5-trimethylbenzene
sec-butylbenzene
1-methyl-3-isopropylbenzene
1-methyl-2-ethylbenzene
1-methyl-4-isopropylbenzene
1,2,4-trimethylbenzene
1,4-diethylbenzene
1-methyl-3-n-propylbenzene
1-methyl-2-iso-propylbenzene
1-methyl-4-n-propylbenzene
1,3-diethylbenzene
n-butylbenzene
1,3-dimethyl-5-ethylbenzene
1,2-diethylbenzene
1-methyl-2-n-propylbenzene
1,2,3-trimethylbenzene
1,4-dimethyl-2-ethylbenzene
1,3-dimethyl-4-ethylbenzene
1,2-dimethyl-4-ethylbenzene
indane
C11 aromatics
Total

%vol

15 - 95*

95 - 149

10.55

11.25

2.32

12.75

On Cut

On Crude

1.71
1.14
-

0.18
0.12
-

12.75

5.65
24.01

24.01

29.74

On Crude

On Cut

On Crude

0.26
5.79
1.95
1.23
3.16
0.22
1.87
0.25

0.03
0.65
0.22
0.14
0.36
0.02
0.21
0.03

0.17
0.77
0.65
1.78
0.48
1.70
1.07

0.01
0.04
0.04
0.10
0.03
0.10
0.06

0.56

0.06

3.67

0.21

0.12

0.01

1.56

0.09

0.23

0.03

2.77

0.16

0.18
-

0.02
-

3.76
0.46

0.21
0.03

0.44

0.02

0.22

0.01

0.02
-

trace
-

0.33
0.04
0.19
1.49
0.27
0.23
0.09
0.20
0.27

0.02
trace
0.01
0.08
0.02
0.01
0.01
0.01
0.02

2.85

0.30

15.84

1.78

22.61

1.28

Note:- *Summation of individual components from Table 2.

Page 8 of 26

On Cut

149 - 175

Table 4
Umm Shaif Crude Oil
Hydrocarbon Type Analysis By Gas Chromatography in the 15 - 175C Range

TBP Cut point

Yield on crude oil
Position in Crude

C
%wt
%wt

Hydrocarbons

%wt

c2 n-paraffin
c3 n-paraffin
c4 isoparaffin
c4 n-paraffin
c5 naphthenes
c5 isoparaffin
c5 n-paraffin
c6 naphthenes
c6 isoparaffin
c6 n-paraffin
c7 naphthenes
c7 isoparaffin
c7 n-paraffin
c8 naphthenes
c8 isoparaffin
c8 n-paraffin
c9 naphthenes
c9 isoparaffin
c9 n-paraffin
c10 naphthenes
c10 isoparaffin
c10 n-paraffin
c11 naphthenes
c11 isoparaffin
c11 n-paraffin
total
total
total
total

isoparaffin
n-paraffin
naphthenes
aromatics

c6 aromatics
c7 aromatics
c8 aromatics
c9 aromatics
c10+ aromatics

15 - 95*
8.60
1.5
10.1
On Cut
0.01
0.49
1.45
11.42
19.19
6.85
16.14
19.07
3.86
9.80
7.43
0.27
0.31
-

On Crude
trace
0.04
0.12
0.98
1.65
0.59
1.39
1.64
0.33
0.84
0.64
0.02
0.03
-

37.68
46.18
12.43
3.71
2.24
1.47
-

3.24
3.97
1.07
0.32
0.19
0.13
-

Note:- *Summation of individual components from Table 2.

Page 9 of 26

95 - 149
10.00
10.1
On Cut
1.11
0.30
0.89
5.98
4.72
9.71
7.67
14.32
13.04
2.38
12.61
6.03
0.13
2.04
0.54
33.99
30.21
17.27
18.53
0.31
6.76
9.92
1.54
0.00

20.1
On Crude
0.11
0.03
0.09
0.60
0.47
0.97
0.77
1.43
1.30
0.24
1.26
0.60
0.01
0.20
0.05
3.40
3.02
1.73
1.85
0.03
0.68
0.99
0.15
trace

149 - 175
5.25
20.1
25.35
On Cut
0.08
0.09
1.34
0.54
1.35
4.12
9.45
11.32
4.38
21.95
11.72
0.87
5.48
1.72
37.42
26.20
10.79
25.59
0.00
0.19
6.15
15.42
3.83

On Crude
trace
trace
0.07
0.03
0.07
0.22
0.50
0.59
0.23
1.15
0.62
0.05
0.29
0.09
1.96
1.37
0.56
1.34
trace
0.01
0.32
0.81
0.20

Table 4A
Umm Shaif Crude Oil
Hydrocarbon Type Analysis By Gas Chromatography in the 15 - 175C Range

TBP Cut point

Yield on crude oil
Position in Crude

C
%vol
%vol

Hydrocarbons

%vol

15 - 95*
10.55
2.32
12.75
On Cut

c2 n-paraffin
c3 n-paraffin
c4 isoparaffin
c4 n-paraffin
c5 naphthenes
c5 isoparaffin
c5 n-paraffin
c6 naphthenes
c6 isoparaffin
c6 n-paraffin
c7 naphthenes
c7 isoparaffin
c7 n-paraffin
c8 naphthenes
c8 isoparaffin
c8 n-paraffin
c9 naphthenes
c9 isoparaffin
c9 n-paraffin
c10 naphthenes
c10 isoparaffin
c10 n-paraffin
c11 naphthenes
c11 isoparaffin
c11 n-paraffin

0.01
0.56
1.29
12.30
20.56
6.03
16.32
19.35
3.31
9.61
7.28
0.24
0.28
-

total
total
total
total

38.52
47.75
10.87
2.86

isoparaffin
n-paraffin
naphthenes
aromatics

c6 aromatics
c7 aromatics
c8 aromatics
c9 aromatics
c10 aromatics

On Crude
trace
0.06
0.14
1.30
2.17
0.64
1.72
2.04
0.35
1.01
0.77
0.03
0.03
4.06
5.04
1.15
0.30

1.71
1.14
-

0.18
0.12
-

Note:- *Summation of individual components from Table 2.

Page 10 of 26

95 - 149
11.25
12.75
24.01
On Cut
1.08
0.34
1.00
5.86
5.11
10.54
7.38
15.00
13.78
2.27
12.85
6.24
0.12
2.04
0.55
35.34
32.11
16.71
15.84
0.26
5.79
-

On Crude
0.12
0.04
0.11
0.66
0.57
1.19
0.83
1.69
1.55
0.26
1.45
0.70
0.01
0.23
0.06
3.98
3.61
1.88
1.78
0.03
0.65
-

149 - 175
5.65
24.01
29.74
On Cut
0.08
0.10
1.34
0.59
1.48
4.08
10.00
12.16
4.20
22.75
12.39
0.83
5.57
1.79
38.91
27.92
10.53
22.64
0.17
-

On Crude
trace
0.01
0.08
0.03
0.08
0.23
0.57
0.69
0.24
1.29
0.70
0.05
0.31
0.10
2.20
1.58
0.59
1.28
0.01
-

Table 5
Umm Shaif Crude Oil
Properties of 369 - 550C Cut

TBP Cut point (API)

369 - 550
(C)

Yield on crude oil

%wt

24.15

Yield on crude oil

%vol

21.96

Density at 15C

kg/litre

0.9195

Sulphur

%wt

2.11

Viscosity at 60C
Viscosity at 100C

cSt
cSt

23.20
7.15

Wax content (BP237)

Wax content (NMR)
Total nitrogen

%wt
%wt
ppm wt

14.5
790

Basic nitrogen

ppm wt

195

Acidity

mgKOH/g

Carbon Residue

%wt

Refractive index at 70C

<0.01
0.41
1.4935

(C) = calculated value

These acidities may have been subject to thermal degradation

Page 11 of 26

Table 6
Umm Shaif Crude Oil
TBP data

TBP Cut point (API)

Total distillate

C
%wt
%vol

50
4.64
6.13

55
5.11
6.13

60
5.61
6.26

65
6.14
7.87

70
6.70
9.93

75
7.30
10.35

80
7.94
10.38

85
8.62
10.99

90
9.34
11.34

95
10.10
12.75

TBP Cut point (API)

Total distillate

C
%wt
%vol

100
10.90
14.71

105
11.72
15.36

110
12.59
15.61

115
13.48
16.51

120
14.40
18.26

125
15.34
18.71

130
16.30
20.38

135
17.28
20.97

140
18.28
22.29

145
19.29
23.19

TBP Cut point (API)

Total distillate

C
%wt
%vol

150
20.30
24.22

155
21.33
25.42

160
22.35
26.55

165
23.37
27.64

170
24.37
28.70

175
25.35
29.74

180
26.30
30.76

185
27.23
31.76

190
28.15
32.75

195
29.07
33.72

TBP Cut point (API)

Total distillate

C
%wt
%vol

200
30.00
34.70

205
30.95
35.69

210
31.91
36.68

215
32.88
37.69

220
33.86
38.69

225
34.84
39.70

230
35.81
40.70

235
36.78
41.69

240
37.74
42.67

245
38.69
43.64

TBP Cut point (API)

Total distillate

C
%wt
%vol

250
39.64
44.61

255
40.59
45.58

260
41.55
46.56

265
42.52
47.53

270
43.49
48.50

275
44.47
49.48

280
45.45
50.46

285
46.43
51.43

290
47.40
52.40

295
48.37
53.36

TBP Cut point (API)

Total distillate

C
%wt
%vol

300
49.33
54.30

305
50.29
55.24

310
51.25
56.19

315
52.22
57.13

320
53.18
58.06

325
54.15
59.00

330
55.12
59.93

335
56.10
60.86

340
57.07
61.79

345
58.02
62.70

TBP Cut point (API)

Total distillate

C
%wt
%vol

350
58.96
63.59

355
59.87
64.45

360
60.76
65.29

365
61.63
66.10

370
62.46
66.88

375
63.27
67.64

380
64.06
68.37

385
64.83
69.09

390
65.60
69.81

395
66.38
70.53

TBP Cut point (API)

Total distillate

C
%wt
%vol

400
67.16
71.26

410
68.74
72.71

420
70.31
74.16

430
71.88
75.60

440
73.40
76.98

450
74.85
78.30

460
76.19
79.52

470
77.47
80.69

480
78.73
81.84

490
79.99
82.97

TBP Cut point (API)

Total distillate

C
%wt
%vol

500
81.23
84.07

510
82.42
85.13

520
83.53
86.12

525
84.06
86.59

530
84.57
87.04

540
85.54
87.90

550
86.45
88.69

600
90.20
91.98

650
93.00
94.35

700
95.15
96.02

Page 12 of 26

Table 7
Umm Shaif Crude Oil
Properties of 550-585C and Residue >585C fractions
Cut Point
TBP Cut point (API)

Yield on crude oil

Yield on crude oil

550-585

>585

%wt
%vol

2.41

8.90

kg/litre

Sulphur

%wt

Viscosity at 50C
60C
80C
100C
120C
150C

cSt
cSt
cSt
cSt
cSt
cSt

Penetration at 25C 10/mm

Softening point
C
Viscosity at 60C (Vac Cap)

Wax content (BP237)

Wax content (NMR)

%wt
%wt

Total nitrogen
Basic nitrogen
Acidity

ppm wt
ppm wt
mgKOH/g

Carbon residue
Asphaltenes
Vanadium
Nickel
Iron

%wt
%wt
ppm wt
ppm wt
ppm wt

Density at 15C

Xylene equivalent
Saturates
Aromatics
Resins A
Resins B

%wt
%wt
%wt
%wt

(C) = calculated value

( ) = extrapolated value
These acidities may have been subject to thermal degradation

Page 13 of 26

Table 8
Umm Shaif Crude Oil
Crude Oil SIMDIS Results

Total Crude

% wt
Temp C

Recovery

C1-C7

10.1

Recovery

149

20.3

Recovery

175

26.5

Recovery

232

37.0

Recovery

342

58.6

Recovery

369

63.3

Recovery

509

83.9

Recovery

550

87.8

Recovery

600

91.8

Recovery

720

97.2

Recovery >720

2.8

Page 14 of 26

Table 9
Umm Shaif Crude Oil
Hydrocarbon Type Analysis By Gas Chromatography in the 175 - 200C Range

TBP Cut point

Yield on crude oil
Position in Crude
Hydrocarbons

c6 naphthenes
c6 isoparaffin
c6 n-paraffin
c6 aromatics
c7 naphthenes
c7 isoparaffin
c7 n-paraffin
c7 aromatics
c8 naphthenes
c8 isoparaffin
c8 n-paraffin
c8 aromatics
c9 naphthenes
c9 isoparaffin
c9 n-paraffin
c9 aromatics
c10 naphthenes
c10 isoparaffin
c10 n-paraffin
c10 aromatics
c11 naphthenes
c11 isoparaffin
c11 n-paraffin
c11 aromatics

175 - 200

175 - 200
4.96

% wt
On Cut

25.35 - 30.
% wt
On Crude

29.74 - 34.7
% vol
% vol
On Cut
On Crude

isoparaffin
n-paraffin
naphthenes
aromatics

0.00
0.00
0.00
0.00

0.00
0.00
0.00
0.00

0.00
0.00
0.00
0.00

0.00
0.00
0.00
0.00

High Boiling Aromatics

High Boiling Saturates
Polynaphthene

total
total
total
total

Page 15 of 26

Table 10
Umm Shaif Crude Oil
Residue Metals Analysis (raw experimental data)
Cut Point
TBP Cut point (API)

Yield on crude oil

Yield on crude oil

Aluminium
Barium
Boron
Calcium
Chromium
Copper
Lead
Magnesium
Manganese
Molybdenum
Potassium
Silicon
Silver
Sodium
Tin
Titanium
Zinc
Phosphorus

%wt
%vol

mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg
mg/kg

>369

37.70
33.27

>509

>550

>585

On Crude
Average

17.70
14.98

13.55
11.31

8.90

100.00
100.00

(C) = Calculated

Page 16 of 26

Table 11
Umm Shaif Crude Oil
Properties of 15-232 distillates

TBP cut point

API

95-149

149-175

Yield on crude oil

%wt

10.00

5.25

Yield on crude oil

%vol

11.26

5.73

Density at 15C

175-232

15-175

15-200

11.35

27.43

32.39

kg/litre

Sulphur

%wt

Mercaptan sulphur

%wt

IP342 Hydrogen Sulphide

%wt

IP342 Elemental Sulphur

%wt

Total Nitrogen

%wt

Acidity

mgKOH/g

Pour point

Freezing point

ppb wt

%vol

ppm

Mercury
Naphthalenes
Chlorine

Page 17 of 26

Table 12
Umm Shaif Crude Oil
ASTM D86 distillation data in the 149 - 342C range

TBP Cut point

Yield on crude oil
Yield on crude oil

Initial Boiling point

5% recovered
10% recovered
20% recovered
30% recovered
40% recovered
50% recovered
60% recovered
70% recovered
80% recovered
90% recovered
95% recovered
Final Boiling Point
Loss
Residue
Recovery

C
%wt
%vol

149 - 232
16.10
17.08

232 - 342
21.25
21.06

On Cut

On Cut

C
C
C
C
C
C
C
C
C
C
C
C
C
%vol
%vol
%vol

Page 18 of 26

Table 13
Umm Shaif Crude Oil
TAN and Betz NAN Analysis

Assay Distillation

Crude
15-95C
95-149C
149-232C
232-342C
342-369C
15-369C (C)
>369 (calc from crude and (IBP-369))
>369C
369-509
509-550
>550
Atmospheric stage (IBP-369 & >369) balanced on
crude
Atmospheric stage % Recovery >369
Vacuum stage (369-550 & >550) balanced on >369
Vacuum stage % Recovery >550
% recovery of vac dist 369 vs target 369

Minimum Residence Distillation

>369C

Total Acid
Number
(mgKOH/g)

Betz NAN
Number
(mgKOH/g)

Percent Betz Nan

of TAN

0.05

0.02
<0.05
<0.05
<0.05
<0.05
<0.05
-

0.00
0.0
0.00
-

0.00
0.00
-

Total Acid
Number
(mgKOH/g)

Betz NAN
Number
(mgKOH/g)

Percent Betz Nan

of ACI

15-369C
(Calc from vac dist'n)
369-509C
509-550C
>550C

>369 calc from crude - (IBP-369)

Vac dist >369
vs Atmos
dist& >369
recovery on
Atmospheric
stage
(IBP-550
>550)% balanced
crude
% Recovery
Final Flask temperature = 335 C
These calculations assume that <0.05 = 0
(C) = Calculated

Page 19 of 26

Table 14
Umm Shaif Crude Oil
Asphaltene Solvency
Software version 2.0b
Solvent used for CSPa

Solvent Power (SP)

Asphaltene Critical Solvent Power (CSPa)

Insolubles at Zero solvent power (PSN)

Crude Solids Number (CSN)

Asphaltenes
Solvent %

Solvent Power

Insolubles
wt% on crude

Notes: table for asphaltene crudes

Page 20 of 26

Table 15
Umm Shaif Crude Oil
Asphaltene and Wax Solvency
Software version 2.0b
Solvent used for CSPw

Solvent used for CSPa (UV)

Solvent Power (SP)

Asphaltene Critical Solvent Power (CSPa)

Wax Critical Solvent Power (CSPw)

Insolubles at Zero solvent power (PSN)

Crude Solids Number (CSN)

Wax + Asphaltenes
Solvent %

Solvent Power

Insolubles
wt% on crude

UV Asphaltenes
Solvent %

Solvent Power

Insolubles
wt% on crude

Page 21 of 26

Table 16
Umm Shaif Crude Oil
C1- C8
methane
ethane
propane
iso-butane
n-butane
iso-pentane
n-pentane
2,2-Dimethylbutane
Cyclopentane + 2,3-Dimethylbutane
2-Methylpentane
3-methylpentane
n-hexane
2,2-dimethylpentane
methylcyclopentane
2,4-dimethylpentane
2,2,3-trimethylbutane
Benzene
3,3-dimethylpentane
cyclohexane
2-methylhexane + 2,3-dimethylpentane
1,1-dimethylcyclopentane
3-methylhexane
trans-1,3-dimethylcyclopentane
cis-1,3-dimethylcyclopentane
1,2-dimethylcyclopentane + 3-ethylpentane
n-heptane
Methylcyclohexane
1,1,3-trimethylcyclopentane
2,2-dimethylhexane
ethylcyclopentane
2,5-dimethylhexane
2,4-dimethylhexane
trans,cis-1,2,4-trimethylcyclopentane
3,3-dimethylhexane
trans,cis-1,2,3-trimethylcyclopentane
2,3,4-trimethylpentane
toluene
2,3-dimethylhexane
2-methyl-3-ethylpentane +
1,1,2-trimethylcyclopentane
2-methylheptane
4-methylheptane
cis-1,3-dimethylcyclohexane
trans-1,4-dimethylcyclohexane +
3-methylheptane
3-ethylhexane
1,1-dimethylcyclohexane
1,3-ethylmethylcyclopentane
2,2,5-trimethylhexane
trans-1,3-ethylmethylcyclopentane
trans-1,2-ethylmethylcyclohexane
trans-1,2-dimethylcyclohexane
trans-1,3- & cis-1,4-dimethylcyclohexane
n octane

% WT
0.01
0.16
0.23
1.10
1.01
1.66
0.22
0.80
0.51
1.71
0.02
0.40
0.07
0.00
0.23
0.02
0.33
0.67
0.04
0.54
0.08
0.07
0.00
1.66
0.00
0.00
0.00
-

Page 22 of 26

Table 17
Umm Shaif Crude Oil
100pt SIMDIS data

BP Distribution table
Recovered
BP
mass%
C
0.5
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
34
35
36
37
38
39
40
41
42
43
44
45
46
47
48
49
50
51
52
53
54
-

Percent

Page 23 of 26

55
56
57
58
59
60
61
62
63
64
65
66
67
68
69
70
71
72
73
74
75
76
77
78
79
80
81
82
83
84
85
86
87
88
89
90
91
92
93
94
95
96
97
98
99
99.5

Page 24 of 26

Table 18
Umm Shaif Crude Oil
poly-aromatic data

Aromatics

1 ring
2 ring
3 ring+

175-232

175-232

%wt

%vol
-

*232-342
%wt
16.8
12.2
0.8

Page 25 of 26

*232-342
%vol
16.3
10.1
0.6

*342-369
%wt
-

*342-369
%vol
-

Page 26 of 26