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31. Which of the following complex species is not
expected to exhibit optical isomerism ?
(1) [Co(en)
3
]
3+
(2) [Co(en)
2
Cl
2
]
+
(3) [Co(NH
3
)
3
Cl
3
] (4) [Co(en) (NH
3
)
2
Cl
2
]
+
Ans. (3)
Sol. (1) (Optically active)
(2)
(3)
(4) Exist in three G.I.

Co
Cl
NH
3
Cl
NH
3
(Inactive)
en
32. Which one of the following molecules is
expected to exhibit diamagnetic behaviour ?
(1) C
2
(2) N
2
(3) O
2
(4) S
2
Ans. (2)
Sol.
C
2
= o1s
2
, o
*
1s
2
, o2s
2
, o
*
2s
2

2
y
2
z
2p
2p
t

(Diamagnetic)
PART B CHEMISTRY
N
2
= o1s
2
, o
*
1s
2
, o2s
2
, o
*
2s
2

2
y
2
z
2p
2p
t

2
x
2p o
(Diamagnetic)
O
2
: o1s
2
, o
*
1s
2
, o2s
2
, o
*
2s
2
, o2p
x
2

2
y
2
z
2p
2p
t

,
* 1
y
* 1
z
2p
2p
t

,
(Paramagnatic)
S
2
= KK, LL, o3s
2
, o
*
3s
2
, o3p
x
2
2
y
2
z
3p
3p
t

,
* 1
y
* 1
z
3p
3p
t

(Paramagnetic)
C
2
& N
2
both are diamegnatic actully, but
according to the language of question,
expected to be diamegnatic.
If we consider energy leval diagram of C
2
and
N
2
similar to O
2
then C
2
become paramagnetic
& N
2
remain diamegnatic so best answer of
Question is N
2
.
33. A solution of () 1chloro1phenylethane
in toluene racemises slowly in the presence of
a small amount of SbCl
5
, due to the formation
of :-
(1) carbanion (2) Carbene
(3) carbocation (4) free radical
Ans. (3)
Sol.
JEE(MAIN) 2013 TEST PAPER WITH SOLUTION
(HELD ON SUNDAY 07
th
APRIL, 2013)

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34. Given :
0
3
Cr / Cr
E 0.74V
+
= ;
0
2
MnO / Mn
4
E 1.51 V
+
=
0
2 3
Cr O / Cr
2
7
E 1.33 V
+
= ;
0
Cl / Cl
E 1.36 V

=
Based on the data given above, strongest
oxidising agent will be :
(1) Cl

(2) Cr
3+
(3) Mn
2+
(4) MnO
4

Ans. (4)
Sol. Oxidising power is directly proprotional to
reduction potential.
35. A piston filled with 0.04 mol of an ideal gas
expands reversibly from 50.0 mL to 375 mL
at a constant temperature of 37.0C. As it does
so, it absorbs 208 J of heat. The values of q and
w for the process will be :-
(R = 8.314 J/mol K) (ln 7.5 = 2.01)
(1) q = + 208 J, w = 208 J
(2) q = 208 J, w = 208 J
(3) q = 208 J, w = + 208 J
(4) q = + 208 J, w = + 208 J
Ans. (1)
Sol.
q = + 208 Joule
for isothermal process
AU = 0
from I
st
law of thermodynamics
AU = q + w
0 = q + w
w = q = 208 Joule
36. The molarity of a solution obtained by mixing
750 mL of 0.5(M)HCl with 250 mL of 2(M)HCl
will be :-
(1) 0.875 M (2) 1.00 M
(3) 1.75 M (4) 0.975 M
Ans. (1)
Sol.
1 1 2 2
resul tant
total
M V M V
M
V
+
=

0.5 750 2 250
1000
+
=
375 500
0.875 M
1000
+
= =
37. Arrange the following compounds in order of
decreasing acidity :
(I) (II) (III) (IV)
OH OH
Cl CH
3
OH
NO
2
OH
OCH
3
; ; ;
(1) II > IV > I > III
(2) I > II > III > IV
(3) III > I > II > IV
(4) IV > III > I > II
Ans. (3)
Sol. Stability order of conjugate base of phenol due
to following groups as follows
NO
2
> Cl > CH
3
> OCH
3
(R effect) (I effect) (+H effect) (+R effect)

Stabilised
_

Destabilised
_
38. For gaseous state, if most probable speed is
denoted by C*, average speed by
C
and mean
square speed by C, then for a large number of
molecules the ratios of these speeds are :-
(1) C* : C : C = 1.225 : 1.128 : 1
(2) C* : C : C = 1.128 : 1.225 : 1
(3) C* : C : C = 1 : 1.128 : 1.225
(4) C* : C : C = 1 : 1.225 : 1.128
Ans. (3)
Sol. U
mp
: U
av
: U
rms
=
8
2 : : 3
t
1 : 1.128 : 1.224
C* : C : C = 1.128 : 1.225
39. The rate of a reaction doubles when its
temperature changes from 300 K to 310 K.
Activation energy of such a reaction will be
(R = 8.314 JK
1
mol
1
and log 2 = 0.301)
(1) 53.6 kJ mol
1
(2) 48.6 kJ mol
1
(3) 58.5 kJ mol
1
(4) 60.5 kJ mol
1
Ans. (1)

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Sol.
a 2 2 1
1 1 2
E K T T
log
K 2.303R T T
| |
=
|
\ .

T
2
T
1
r
2
r
=

T
2
T
1
K
2
K
=

a
10
E 10
log 2
2.303 8.314 310 300
| |
=
|
\ .
a
0.3010 2.303 8.314 310 300 Joule
E
10 mole

=
= 53.598 kJ/mol
E
a
= 53.6 kJ/mol.
40. A compound with molecular mass 180 is
acylated with CH
3
COCl to get a compound with
molecular mass 390. The number of amino
groups present per molecule of the former
compound is :-
(1) 2 (2) 5
(3) 4 (4) 6
Ans. (2)
Sol.
180 molecular mass after acylation gives
compound of molecular mass 390.
Change in molecular mass = 390 180 = 210
so number of NH
2
group =
210
42
= 5
41. Which of the following arrangements does not
represent the correct order of the property stated
against it ?
(1) V
2+
< Cr
2+
< Mn
2
< Fe
2+
: paramagnetic
behaviour
(2) Ni
2+
< Co
2+
< Fe
2+
< Mn
2+
: ionic size
(3) Co
3+
< Fe
3+
< Cr
3+
< Sc
3+
:
stability in aqueous solution
(4) Sc < Ti < Cr < Mn : number of oxidation
states
Ans. (1)
Sol. (i)
Correct order of Paramagnetic behaviour
Mn
2+
> Fe
+2
= Cr
2+
> V
2+
42. The order of stability of the following
carbocations :
CH =CHCH ; CH CH CH ;
2 2 3 2 2
+
I II
CH
2
+
III
is :-
(1) III > II > I (2) II > III > I
(3) I > II > III (4) III > I > II
Ans. (4)
Ans.
CH =CHCH
2 2
+
CH CH=CH
2 2
+
(I)
Stablised by resonance.
CH CH CH
3 2 2
+
(II)
is stablised by hyperconjugation.
(III) CH
2
+
CH
2
+
CH
2
+
CH
2
+
Highly resonance stablised
III > I > II.
43. Consider the following reaction:
+
+ +
2
4 2 4
xMnO yC O zH
xMn
2+
+ 2yCO
2
+
z
2
H
2
O
The values of x, y and z in the reaction are
respectively :-
(1) 5,2 and 16 (2) 2,5 and 8
(3) 2, 5 and 16 (4) 5,2 and 8
Ans. (3)

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Sol. (i) MnO
4

+8H
+
+ 5e

Mn
+2
+ 4H
2
O
(ii) C
2
O
4
2
2CO
2
+ 2e

(i) 2 + (ii) 5
________________________________________________________________
2MnO
4

+ 16H
+
+ 5C
2
O
4
2
2Mn
+2
+ 8H
2
O + 10CO
2
________________________________________________________________
Given equation :
xMnO
4

+ yC
2
O
4
2
+ zH
+
xMn
+2
+ 2yCO
2
+
z
2
H
2
O
On comparing with balanced equation
we get ; x = 2, y = 5, z = 16.
44. Which of the following is the wrong statement?
(1) ONCl and ONO

are not isoelectronic

(2) O
3
molecule is bent
(3) Ozone is violet-black in solid state
(4) Ozone is diamagnetic gas
Ans. (1)
Sol.
(i) Some times, two species having same
valence shell electrons are considered as
isolectronic species. Accordingly ONCl
and ONO

are isoelectronic to each other.

[Otherwise all four statements are
correct and no answer is available in the
given options].
(ii) sp
2
, bent shaped
(iii) O
3
(g) = Blue
O
3
(/) = Dark blue
O
3
(s) = violet - black
(iv) All electrons are paired in structure of O
3
.
Hence it is diamagnetic.
45. A gaseous hydrocarbon gives upon
combustion 0.72 g of water and 3.08 g of CO
2
.
The empirical formula of the hydrocarbon is
(1) C
2
H
4
(2) C
3
H
4
(3) C
6
H
5
(4) C
7
H
8
Ans. (4)
Sol.
x y 2 2(g) 2 ( )
y y
C H x O xCO H O
4 2
| |
+ + +
|
\ .
/
moles of H
2
O =
.72
18
0
= 0.04
moles of CO
2
=
3.08
44
= 0.07
x :
y
2
= 0.07 : 0.04
x : y = 0.07 : 0.08 7 : 8
Ratio of C & H is x : y
C : H = 7 : 8
Therefore empirical formula of hydrocarbon
should be C
7
H
8
.
46. In which of the following pairs of molecules/
ions, both the species are not likely to exist ?
(1)
2
2 2
H , He
+
(2)
2
2 2
H , He

(3)
2
2 2
H , He
+
(4)
2
2 2
H , He
+
Ans. (3)
Sol. According to M.O.T. species which has zero
B.O., they do not exist.
Energy order of M.O. in H
2
and He
2
= o
1s
, o
*
1s

2
2
H
+
have zero electron ; B.O. = zero
He
2
have two bonding electron & Two
antibonding electrons ; B.O. = zero
47. Which of the following exists as covalent
crystals in the solid stae ?
(1) Iodine (2) Silicon
(3) Sulphur (4) Phosphorus
Ans. (2)
Sol. (i) I
2
is molecular solid in which I
2
molecules
are interacted by weak London forces.
(ii) Silicon exists in diamond like structure in
which atoms of Si are bonded by covalent
bond. Hence it is a covalent solid.
(iii) Sulphur is molecular solid in which S
8
molecules are interacted by London force.
(iv) White phosphorous is a molecular solid in
which P
4
molecules are interacted by
London force.
48. Synthesis of each molecule of glucose in
photosynthesis involves :-
(1) 18 molecules of ATP
(2) 10 molecules of ATP
(3) 8 molecules of ATP
(4) 6 molecules of ATP
Ans. (1)
Sol. Six rounds of the Calvin cycle are required,
because one carbon atom is reduced in each
round. Twelve molecules of ATP are expended.
An additional six molecular of ATP are spent
in regenerating ribulose-1, 5-biphosphate
6CO
2
+ 18ATP + 12NADPH + 12H
2
O

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C
6
H
12
O
6
+ 18ADP + 18P
i
+ 12NADP + 6H

Reference : NCERT 11
th
class chapter-13
(Photosynthesis Pg. 217, 218 in higher plants.
Calvin cycle where sugar is synthesised is as
follows :
The Calvin cycle proceeds in three stages (1)
carboxylation, during which CO
2
combines
with ribulose-1.5-bisphosphate (2) reduction,
during which carbohydrate is formed at the
expense of the photochemically made ATP and
NADPH and (3) regeneration during which the
CO
2
acceptor ribulose-1,5-bisphosphate is
formed again so that the cylcle continues.
It might help you to understand all of this if we
look at what goes in and what comes out of the
Calvin cycle.
In Out
Six CO
2
One glucose
18 ATP 18 ADP
12 NADPH 12 NADP
49. The coagulating power of electrolytes having
ions Na
+
, Al
3+
and Ba
2+
for aresenic sulphide
sol increases in the order :-
(1) Al
3+
< Ba
2+
< Na
+
(2) Na
+
< Ba
2+
< Al
3+
(3) Ba
2+
< Na
+
< Al
3+
(4) Al
3+
< Na
+
< Ba
2+
Ans. (2)
Sol. As
2
S
3
is ive sol.
& According Hardy-Schulze rule
coagulation power is proportional to valency
of active ion
Al
+3
> Ba
+2
> Na
+
50. Which of the following represents the correct
order of increasing first ionization enthalpy for
Ca, Ba, S, Se and Ar ?
(1) Ca < S < Ba < Se < Ar
(2) S < Se < Ca < Ba < Ar
(3) Ba < Ca < Se < S < Ar
(4) Ca < Ba S < Se < Ar
Ans. (3)
Sol. (i) In a group the I.E. decreases.
Hence Ca > Ba
and S > Se
(ii) In a period, I.E. increases from left to
right in general.
Hence Ar > S and Se > Ca
Hence the order is Ar > S > Se > Ca > Ba and
the answer is (3).
51. Energy of an electron is given by
E = 2.178 10
18
J
2
2
Z
n
| |
|
\ .
. Wavelength of light
required to excite an electron in an hydrogen atom
from level n = 1 to n = 2 will be :-
(h = 6.62 10
34
Js and c = 3.0 10
8
ms
1
)
(1) 1.214 10
7
m (2) 2.816 10
7
m
(3) 6.500 10
7
m (4) 8.500 10
7
m
Ans. (1)
Sol.
1

= R
H
Z
2
2 2
1 2
1 1
n n

`
)
1

= R
H
1
2

{ } 2 2
1 1
1 2

= R
H

3
4
=
H
4 1
3 R

=
4
3
912
= 4 304
= 1216
= 1216 10
10
m
= 1.216 10
7
m

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52. Compound (A), C
8
H
9
Br, gives a white
precipitate when warmed with alcoholic
AgNO
3
. Oxidation of (A) gives an acid (B),
C
8
H
6
O
4
. (B) easily forms anhydride on heating.
Identify the compound (A) :
(1)
CH Br
2
CH
3
(2)
C H
2 5
Br
(3)
CH Br
2
CH
3
(4)
CH Br
2
CH
3
Ans. (4)
Sol.
since B on heating gives anhydride so B is 1,2
dicarboxylic acid. It contains two Benzylic
carbon at 1, 2 position so on oxidation it
produces 1, 2-dicarboxylic acid
CH Br
2
CH
3
AgNO
3
(alc)
AgBr (ppt) +
[O]
COH
COH
O
O
A
H O
2
C
C
O
O
O
53. Four successive members of the first row
transition elements are listed below with atomic
numbers. Which one of them is expected to
have the highest
3 2
0
M / M
E
+ +
value ?
(1) Cr(Z = 24)
(2) Mn(Z = 25)
(3) Fe (Z = 26)
(4) Co(Z = 27)
Ans. (4)
54. How many litres of water must be added to 1
litre of an aqueous solution of HCl with a pH of
1 to create an aqueous solution with pH of 2 ?
(1) 0.1 L (2) 0.9 L
(3) 2.0 L (4) 9.0 L
Ans. (4)
Sol. (p
H
)
1
= 1 (H
+
)
1
= 10
1
M
(p
H
)
2
= 2 (H
+
)
2
= 10
2
M
from dilution law.
M
1
V
1
= M
2
V
2
10
1
1 = 10
2
V
2
V
2
= 10 litre
Added water = 10 1 = 9 litre
55. The first ionisation potential of Na is 5.1 eV.
The value of electron gain enthalpy of Na
+
will
be :-
(1) 2.55 eV (2) 5.1 eV
(3) 10.2 eV (4) + 2.55 eV
Ans. (2)
Sol. Na
e.g
I.E.
H
+
A

Na
+
+ e

e.g.
I.E. H = A Hence
AH
e.g.
of Na
+
= 5.1 eV
56. An organic compound A upon reacting with
NH
3
gives B. On heating, B gives C. C in
presence of KOH reacts with Br
2
to give
CH
3
CH
2
NH
2
. A is :-
(1) CH
3
COOH
(2) CH
3
CH
2
CH
2
COOH
(3) CH CHCOOH
3
CH
3
(4) CH
3
CH
2
COOH
Ans. (4)
Sol. CH CH CO H
3 2 2
(A)
NH
3
CH CH CO NH
3 2 2 4
+
A
(B)
CH CH CONH
3 2 2
Br
2
KOH
CH CH NH
3 2 2
(C)

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th
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57. Stability of the species Li
2
,
2
Li

and
2
Li
+
increases in the order of :-
(1) Li
2
<
2
Li
+
<
2
Li

(2)
2
Li

<
2
Li
+
< Li
2
(3) Li
2
<
2
Li

<
2
Li
+
(4)
2
Li

< Li
2
<
2
Li
+
Ans. (2)
Sol. Stability depends upon bond order
B.O. of Li
2
, Li
2
+
and Li
2

are 1, 0.5 and 0.5

respectively.
Hence Li
2
>
2
Li
+
Li
2
> Li
2

while
2
Li
+
>
2
Li

due to higher interelectronic

repulsion in
2
Li

which makes it least stable.

Hence the order is Li
2
>
2
Li
+
>
2
Li

58. An unknown alcohol is treated with the "Lucas

reagent' to determine whether the alcohol is
primary, secondary or tertiary. Which alcohol
reacts fastest and by what mechanism :-
(1) secondary alcohol by SN1
(2) tertiary alcohol by SN1
(3) secondary alcohol by SN2
(4) tertiary alcohol by SN2
Ans. (2)
Sol. Its 3 (Tertiary alcohol) which reacts fastest by
SN
1
mechanism.
59. The gas leaked from a storage tank of the
Union Carbide plant in Bhopal gas tragedy
was:-
(1) Methylisocyanate
(2) Methylamine
(3) Ammonia
(4) Phosgene
Ans. (1)
Sol. Methyl isocynate is highly toxic compound
which was behind the Bhopal disaster of 1984.
60. Expermentally it was found that a metal oxide
has formula M
0.98
O. Metal M, is present as M
2+
and M
3+
in its oxide. Fraction of the metal which
exists as M
3+
would be :-
(1) 7.01% (2) 4.08%
(3) 6.05% (4) 5.08
Ans. (2)
Sol. Let no. of oxygen atom = 100
no. of metal atom = 98
if no. of M
+2
ion = x
then no. of M
+3
ion = (98 x)
Since compound is electrically neutral
x (12) + (98 x)x + 3 + 100 (2) = 0
2x + 98 3 3x 200 = 0
294 200 x = 0
x = 94
No. of M
+2
ion = 94
No. of M
+3
ion = 98 94 = 4
Fraction of metal which exists as M
+3
would be =
4
100
98
= 4.08%