Answer Key Trad 2010 Exam

Mathematics and Science & Technology Committee
June 2010

SECONDARY 5 CHEMISTRY

551-534

ANYONE WHO RECEI VES A COPY OF THI S EXAMI NATI ON HAS

UNDERTAKEN TO USE IT ON THE FOLLOWING DATE:

June 14
th
, 2010

NOTE: This date was established by the DEEN and the Mathematics and Science &
Technology Committee



JUNE 2010

CHEMISTRY 534

551-534

-EXAMINATION-

Guide

Chemistry 551-534 Guide Page 1

1. GENERAL INFORMATION

1.1 Program Chemistry, Secondary V

1.2 Origin Mathematics and Science & Technology Committee, 2010

Computerization by Martine Sanscartier, BIM, Socit
GRICS

Revision: Patricia Juliano, BIM, Socit GRICS
Cheryl Cantin, BIM, Socit GRICS

1.3 Time allotted 3 hours

1.4 Number of questions 29 questions distributed as follows
14 multiple-choice questions
15 constructed response (students select 11)

Structure of the Exam:

Part A: Fourteen (14) multiple-choice questions worth 4 marks each for a total
of 56%.

Part B: Four (4) questions on the gases and their applications of which the
student is required to answer three (3). Each question is worth 4 marks
for a total of 12%.

Part C: Four (4) questions on energy in chemical reactions of which the
student is required to answer three (3). Each question is worth 4 marks
for a total of 12%.

Part D : Three (3) questions on rate of chemical reactions (kinetics) of which
the student is required to answer two (2). Each question is worth 4
marks for a total of 8%.

Part E : Four (4) questions on chemical equilibrium of which the student is
required to answer three (3). Each question is worth 4 marks for a total
of 12%.

1.5 Authorized material drawing instruments, graph paper
scientific calculator with or without graphic display
list of formulas and quantities included in the
examination booklet
periodic table of the elements included in the
examination booklet
a table of reduction potentials included in the
examination booklet

2. DESCRIPTION OF THE EXAM

The following table matches each of the examination questions with the corresponding
dimension of the definition of the domain that was used for the examination.
Exam Specifications

Topics

Gases and their
Applications
28%

Energy in
Chemical
Reactions
28%

Rate of
Chemical
Reactions
16%

Equilibrium in
Chemical
Reactions
28% Skill

Mastery of
Concepts
24% 28%*

1, 3, 4, 15

7, 19

9, 23

11, 12, 26

Mastery of
Applications
36% 52%*

2, 17

5, 6, 8

10

13, 14, 29

Mastery of
Problem- Solving
Techniques
28% 36%*

16, 18

20, 21, 22

24, 25

27, 28
The numbers on the centre of each box above represent the question numbers in the examination.
*Depending on questions chosen.

The examination consists of the following types of questions:
14 multiple-choice questions (numbers 1 - 14) that test the student's mastery of concepts and
applications.
11 of 15 constructed-response questions (numbers 15 - 29) that test the student's mastery of concepts,
applications and problem solving.

Student selection of problems
When a student answers more than the number of questions required, without indicating which
ones are to be corrected, only the first ones are to be corrected. Thus, for example, if a student
is to choose two out of three questions and answers all three, only the first two are to be
corrected.

Item Specifications

Question MOD.TO.IO T S D

Part A
1 [2299] M02.03 M C E
2 [2300] M02.02.01 M A M-D
3 [2301] M02.02.05 M C M
4 [2302] M02.03.02 M C E
5 [2303] M03.02 M A D
6 [2304] M03.02.03 M A M
7 [2305] M03.01 M C E-M
8 [2306] M03.02.05 M A D
9 [2307] M04.02.02 M C M
10 [2308] M04.02.03 M A M
11 [2309] M05.01.02 M C E
12 [2310] M05.01.01 M C E
13 [2311] M05.03.02 M A M
14 [2312] M05.03 M A M

Part B
15 [2313] M02.02 E C E
16 [2314] M02.02.06 E P M
17 [2315] M02.02.04 E A E
18 [2316] M02.02.09 E P M

Part C
19 [2317] M03.01.01 E C E
20 [2318] M03.02.06 E P D
21 [2319] M03.02.04 E P M
22 [2320] M03.02.02 E P M

Part D
23 [2321] M04.02.01 E C E
24 [2322] M04.01.02 E P D
25 [2323] M04.01.02 E P M

Part E
26 [2324] M05.01.03 E C M
27 [2325] M05.02.06 E P M
28 [2326] M05.02.06 E P D
29 [2327] M05.03 E A M

Legend:
MOD : Modules
M02: Gases and Their Applications
M03: Energy in Chemical Reactions
M04: Rate of Chemical Reactions
M05: Equilibrium in Chemical Reaction
TO: Terminal objective
IO: Intermediate objective

T : Type
M : multiple-choice
C : short-answer
E : extended-answer (constructed response)

S : Skill
C : Mastery of Concepts
A : Mastery of Application
P : Mastery of Problem-Solving Techniques

D : Level of difficulty
E: Easy
M: Medium
D: Difficult

1
2
3
4
5
6
7
8
9
10
11
12
13
14
3. CORRECTION KEY

Part A
4 marks or 0 marks

C

C

D

A

B

D

C

D

B

B

A

D

C

A

GUIDELINES FOR CORRECTING CONSTRUCTED-RESPONSE QUESTIONS

Below is an explanation of the terms found in the marking scale to be used for scoring the
answers to the constructed response questions in the examination.

It is IMPORTANT that the teacher read this information carefully before correcting the
examination.

Constructed-response questions usually consist of two parts: the procedure used to solve the
problem and the answer. Thus, a constructed-response question should be corrected in two steps.

Step 1

Analyze the work to understand the procedure used by the student, and then decide if the
procedure is appropriate or not.

A procedure is appropriate if the steps presented could lead to the correct answer.

A procedure is partially appropriate if the steps presented do not lead to the correct answer,
but include at least one step that is relevant and correct.

A procedure is inappropriate if none of the steps presented are relevant or if the student has
not shown any work.

Step 2

If the procedure is deemed appropriate, then evaluate the answer. If the answer is incorrect,
identify the type of error made.

The error is considered minor if it is an error in calculation or transcription, if the unit of
measurement is incorrect or missing, or if the student has rounded off a number incorrectly.

The error is considered major if a law, rule, or formula has been applied incorrectly.

No marks are allotted for a correct answer when the procedure used is inappropriate.

All extended answers have been worked out using significant figures. However, do not
penalize students if they do not consider significant figures.

15
/4

Part B

Example of an appropriate and complete solution

Graph A Graph B

Graph C Graph D

Allot 1 mark per correct graph. Axes must be labelled.

Do not penalize a student who has drawn a solid line in graph C.

Do not penalize student who has not shown negative values in graph A.


16
/4 Example of an appropriate and complete solution

V = 5000.0 L
P = 250.0

kPa
T = 2.0C + 273 = 275 K

n Cl
2(g)
=
RT
PV

=
K 275
K mol
kPa 314 . 8
L 0 . 5000 kPa 0 . 250

n Cl
2(g)
= 5.47 10
2
mol

5.47 10
2
mol Cl
2
70.90 g/mol = 3.88 10
4
g Cl
2

D =
V
m

=
L 0 . 5000
g 10 88 . 3
4

D =
L
g 76 7.

Answer: The density of the chlorine gas is
L
g 76 7.
or 0.00776 g/mL

4 marks Appropriate and complete procedure.

3 marks Appropriate procedure with a minor error such as calculation or transcription error.

2 marks Appropriate procedure with a major error such as an incorrect application of a law,
formula or rule.

1 mark Partially appropriate and correctly completed procedure.

0 marks Inappropriate procedure or did not show the procedure, regardless of the answer.


17

Determine mol of H
2

x mol =
mass molar
mass

=
g/mol 2.02
g 000 860 18

= 9 337 000 mol

Therefore the number of moles of Helium is 9 337 000 mol

Mass of Helium

9 337 000 mol =
g/mol 00 . 4
g x

= 37 400 000 g or 37 350 kg helium

Answer: The mass of helium, He
(g)
, required to fill the Hindenburg at the same temperature
and pressure is 37 400 000 g or 37 400 kg.

4 marks Appropriate and correct answer.

3 marks Appropriate procedure with minor error such as calculation or transcription error

2 marks Appropriate procedure with a major error such as the incorrect application of a law,
formula, or rule.




18
/4

Number of moles of CO
2

moles 9 . 26
Fe 2
CO 3
g/mol 55.85
Fe of g 1000
2
=

Volume of CO
2

L 6 89
kPa 0 . 98
K 393 K kPa/mol 8.31 moles 9 26.
=
-
=
P
nRT

Answer: The volume of CO
2
gas released for each kilogram of iron produced is 896 L.

4 marks Appropriate and correct answer.

3 marks Appropriate procedure with minor error such as calculation or transcription error

formula, or rule.




19
/4

Part C


Possible explanations

A. The graph given could represent this change.

Explanation: Photosynthesis requires sunlight as an energy source to assemble simple
molecules into more complex structures. Since energy is being absorbed
during the process, enthalpy is increasing as indicated on the graph.

B. The graph given could not represent this change.

Explanation: As bonds are formed to change liquid water into ice, energy will be
released to the surroundings. Therefore the ice that forms will have less
enthalpy than the liquid water. The graph shows an increase in enthalpy.

Note Simply identifying the change as endothermic or exothermic is not an appropriate
explanation.

Allot 1 mark for each correct answer with an appropriate explanation.

Allot 1 sole mark for each correct explanation.

20
/4

4623 kJ released per 1 mole of AlCl
3
.

kJ/mol 4623
kJ 116
= 0.02501 mol of AlCl
3
.

NH
4
ClO
4(s)
and AlCl
3(s)
in a 3:1 mol ratio

So 0.0251 mol of AlCl
3(s)
is produced from 0.0753 mol of NH
4
ClO
4(s)

0.0753 mol 117.5 g/mol = 8.85 g of NH
4
ClO
4(s)

Answer: 8.85 g of NH
4
ClO
4(s)
were used.


3 marks Appropriate procedure with a minor error such as calculation or transcription error, or
units of measurement missing.

formula, or rule.



21
/4

Reverse Equation 1, multiply by 16 and reverse sign for H:

16 H
2
S
(g)
16 H
2(g)
+ 2 S
8(g)
H = +321.6 kJ

Reverse Equation 2, multiply by 8 and reverse sign for H:

8 SO
2(g)
S
8(s)
+ 8 O
2(g)
H = +2368.8 kJ

Select Equation 4 and not 3 since the former contains the needed gaseous H
2
O. Multiply by 16.

16 H
2(g)
+ 8 O
2(g)
16 H
2
O
(g)
H = -4572.8 kJ

________________________________________________________________________

Sum: 16 H
2
S
(g)
+ 8 SO
2(g)
3 S
8(s)
+ 16 H
2
O
(g)
H = -1882.4 kJ

Answer: The heat reaction, H is -1882.4 kJ.



2 marks Appropriate procedure with a major error such as an incorrect application of a law,
formula or rule.




22
/4

Density of water is 1.00 g/mL therefore, mass of water used is 200.0 g.
Specific heat capacity of water is 4.19 J/g-C

Q = mcT
Q = 200.0 g 4.19 (7.0C 18.0C)
Q = -9220 J

H = -
n
Q

therefore, n =
H
Q -

=
kJ 34.9
kJ) (-9.22 -
+

= 0.264 mol of KNO
3

Molar mass of KNO
3
= 101.11 g/mol

0.264 mol 101.11 g/mol = 27 g of KNO
3

Answer: The mass of solid KNO
3
that was added is 27 g.



formula, or rule.




23
/4

Part D


Possible explanations

A. Required Action: Use a rubber stopper with a valve so that the pressure in the bottle can be
lowered.

Explanation: Lowering the pressure reduces the concentration of the oxygen resulting in
fewer collisions between the molecules producing a reduced reaction rate.

B. Required Action: Stand the sealed wine bottle upright.

Explanation: Standing the sealed bottle upright would reduce the surface area of the
wine exposed to oxygen resulting in fewer collisions between the
molecules producing a reduced reaction rate.

Allot 2 marks for each correct answer with an appropriate explanation; 1 mark for the choice of
action and 1 mark for the explanation.

24
/4
Example of appropriate and complete responses

The change in temperature during the first 120 seconds

100C 25C = 75C

Mass of butane used

C 10.0
g 1 C 75

= 7.5 g

Mass of oxygen consumed

g 7 2 g/mol 32.00
H C 2
O 13
g/mol 58.14
g 7.5
10 4
2
=

Rate of consumption of oxygen gas

g/s 23 . 0
s 120
g 27
=

Answer: The average rate of consumption of oxygen gas, O
2
, in the first 120 seconds is 0.23 g/s.



formula, or rule.




25

Rate of consumption of N
2
O
5

At 100 minutes: 0.00094 mol N
2
O
5

At 40 minutes: 0.00531 mol N
2
O
5

5 2
5 -
O N mol/min 10 7.3 -
min 40.0 min 100.0
mol) 0.00531 mol (0.00094
=

-7.3 10
-5
mol/min N
2
O
5
2 mol NO
2
/-1 mol N
2
O
5
= 1.5 10
-4
mol/min NO
2

Answer: The average rate of production of nitrogen dioxide, NO
2
, is 1.5 10
4
mol/min NO
2



formula, or rule.



26
/4

Part E


A) Reactants (reverse reaction) are favoured. According to Le Chateliers Principle, the
system will shift in such a direction to reduce excess heat to re-establish equilibrium. In
order to reduce the excess heat the endothermic direction is favoured. This is the reverse
reaction.

B) No shift occurs. Only changes in concentration affect change in an equilibrium system
(based on the rate laws). Since the water is in a liquid state, increasing the amount of water
does not change its concentration. No shift will occur.

C) Reactants (reverse reaction) are favoured. The removal of hydrogen decreases its
concentration. According to LeChateliers Principle the reverse reaction will speed up in
order to replace the hydrogen removed until a new equilibrium is established.

D) Reactants (reverse reaction) are favoured. As the volume is increased the gas pressure is
decreased. There are a greater number of moles of gas molecules on the reactant side than
there are on the product side. According to le Chateliers Principle, the equilibrium will
shift in a direction that will increase pressure lost. This means the equilibrium will shift
toward the side with the greater number moles of gas, which is the reactant side.

Allot 1 mark for each correct answer with an appropriate explanation.

Allot 1 sole mark to students who correctly stated how the equilibrium system would or would
not shift, but provided inadequate or no explanation.


27
/4

Eliminate the solid.

4 HF UF
4
2 H
2
O
I 0.25 mol/L 0 0
C -0.20 +0.05 +0.10
E 0.05 0.05 0.10

Solve for K
c

K
c
=
| || |
| |
4
(g)
2
(g) 2 4(g)
HF
O H UF

=
( ) ( )
( )
4
2
05 . 0
10 . 0 05 . 0

= 80

Answer: The equilibrium constant is 80.



formula, or rule.




28

Citric acid

[H
+
] = 10
3.70

= 2.0 10
4
mol/L

K
a
=
( )
( )
4
2
4
10 0 . 2 12 . 0
10 0 . 2

= 3.3 10
7

Boric acid

K
a
=
( )
( )
5
2
5
10 1 . 2 75 . 0
10 1 . 2

= 5.9 10
10

Answer: The strongest acid is citric acid.

Note: A student who uses percent ionization should be given full marks.



formula, or rule.



29

a) 3 Cu
+
(aq)
+ Cr
(s)
3 Cu
(s)
+ Cr
3+
(aq)
1 mark

b) 1.26 V 1 mark

c) Increase the concentration of CuNO
3(aq)
or decrease the concentration of Cr(NO
3
)
3(aq)
.
1 mark

d) It allows the anions to move towards the anode, and the cations to move towards the
cathode. It prevents the build up of excess anions and cations in the electrochemical cell.
1 mark

Allot1 mark for each correct answer.

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