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Question 1: FeS2 is roasted to Fe3O4 and SO2 in a flash roaster. FeS2 occurs in a pyrite ore, which in
this case analyses 48%S. If the air supply is controlled at 10kg air/kg ore, calculate the expected exit
gas analysis.
Pyrite ore
Air
Waste Gas
Fe3O4
O2 in 10kg air:
10000g=2330g
N2 in 10kg air:
10000g =7670g
Waste Gas:
SO2: 959.03g
Fe3O4+6SO2
y
9.29% SO2
O2: 2330g-638.72g=1691.28g
16.39% O2
Total: 7670+1691.28+959.03=10320.31g
Process
1
PbO
Pb-Sb alloy
in W2
For Sb:
((
For Pb:
((
+
g
Mass of O:
- :
=143.369kg
- :
Check:
2106g =
2106g =
2106g=143.369kg
2106g=1856.651kg
=727.358kg
, hence some PbO does take place in the reaction.
thermal stress
E
modulus of elasticity
initial temperature difference between cooling medium and melting point of metal
L
characteristic linear dimension of ingot
h
heat transfer coefficient of cooling medium at surface of ingot
k
thermal conductivity of ingot
C
thermal capacity of ingot
density of metal
t
time from start of cooling (i.e. distance from mould/downward velocity of ingot)
LH
Latent heat of metal
2) Choose primary quantities: M, L, T, , Q;
m= 5
Number of group p= n-m= 11-5= 6
ML-1T-2
ML-1T-2
-1
L
-2 -1 -1
QL T
QL-1T-1-1
QL-3-1
ML-3
T
QM-1
3) Two subsets
Basis:
, L, k, t
Residual: ,
h, C, , LH
4) Forming group
Rayleigh indices
M
L
T
Q
3
a1
E
1
-1
-2
b1
-1
c1
L
d1
k
-1
-1
-1
1
f1
t
: ML-1T-2= Q0M1L-1T-2 0
a1=-1; b1=0; c1=0; d1=0; f1=0
____________________________________________________________________________________
Rayleigh indices
M
L
T
a2
b2
E
1
-1
-2
c2
d2
-1
-1
-1
1
-1
f2
t
: = Q0M0L0T01
a2=0; b2=1; c2=0; d2=0 ; f2=0
____________________________________________________________________________________
Rayleigh indices
M
L
T
a3
b3
E
1
-1
-2
c3
d3
-1
-1
-1
1
-1
f3
t
h: QL-2T-1-1= Q1M0L-2T-1-1
a3=0; b3=0; c3=1; d3=-1; f3=0
____________________________________________________________________________________
Rayleigh indices
M
L
T
a4
E
1
-1
-2
b4
c4
L
d4
k
-1
-1
-1
1
-1
f4
t
: QL-3-1= Q1M0L-3T0-1
a4=0; b4=0; c4=2; d4=-1; f4=-1
____________________________________________________________________________________________
Rayleigh indices
M
L
T
a5
E
1
-1
-2
b5
-1
c5
L
d5
k
-1
-1
-1
1
f5
t
: ML-3= Q0M1L-3T00
a5=-1; b5=0; c5=2; d5=0; f5=-2
____________________________________________________________________________________________
4
Rayleigh indices
M
L
T
a6
E
1
-1
-2
b6
c6
L
d6
k
-1
-1
-1
1
-1
f6
t
: QM-1= Q1M-1L0T00
a6=1; b6=1; c6=0; d6=-1; f6=1
____________________________________________________________________________________________
variable
L
h
k
C
t
LH
ingot
6 inch=0.1524m
h
k
C
4min=240s
LH
mould
Dmould
h
0.9k
C
tmould
LH
=216s
Question 4: A model of a soaking pit (or reheat) furnace has been proposed so that gas flow patterns
generated in a new one-way fired pit design can be optimized for uniform convective heat flow to the
reheating ingots.
Develop an expression showing how the gas velocity at any given point within the system is related to the
length L, and width W, of the pit, the combusted gas (i.e. burnt oxygen fuel mixture) flow rate G0, and the
mean density and viscosity of these combusted gases.
In order to model the system at the one-fifth scale, it is proposed that water, rather than cold air, be used as
the fluid medium. Comment on this proposal and recommend the inlet gas and water flows and other
dimensions that would be required to simulate the following set of conditions expected for the prototype.
G0
T
L
W
H
h
w
N
Flow rate
density
viscosity
velocity
Temperature
Soaking pit length
Soaking pit width
Soaking pit height
Ingots height
Ingots width
Number of ingots
L3T-1
ML-3
ML-1T-1
LT-1
L
L
L
L
L
24
1) n=12;
2) Choose primary quantities: M, L, T, ;
Number of group p= n-m= 11-4= 7
3) Two subsets
Basis: L, T, , G0
Residual: , , W, H, h, w, N
m= 4
4) Forming group
Rayleigh indices
M
L
T
a1
L
b1
T
c1
1
-3
d1
G0
3
-1
: LT-1= M0L1T-10
a2
b2
c2
d2
1
-3
G0
3
-1
: ML-1T-1= M1L-1T-10
a3
b3
c3
d3
1
-3
G0
3
-1
: L= M L T
0 1 0 0
Rayleigh indices
M
L
T
a4
L
b4
T
c4
1
-3
d4
G0
3
-1
H: L= M0L1T00
a5
L
b5
T
c5
1
-3
d5
G0
3
-1
h: L= M0L1T00
a2
b2
c2
d2
1
-3
G0
3
-1
w: L= M0L1T00
a6
L
b6
T
c6
1
-3
d6
G0
3
-1
N: M0L0T00
24 ingots