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General reference materials for food,

industry and occupational hygiene

2003/2004

LGC Promochem offices

United Kingdom

Italy

LGC Promochem
Queens Road
Teddington
Middlesex
TW11 0LY
United Kingdom

LGC Promochem S.R.L


Via Venezia, 23
20099 Sesto San Giovanni
Milan
Italy
Tel:
+39 02 2412 6830
Fax:
+39 02 2412 6831
Email: it@lgcpromochem.com

Tel:
+44 (0)20 8943 7565
Fax:
+44 (0)20 8943 7554
Email: uksales@lgcpromochem.com

France

Poland

LGC Promochem SARL


6, Rue Alfred Kastler
B.P.83076
67123 Molsheim
France

LGC Promochem Sp. z o.o


ul. M. Konopnickiej 1
Dziekanw Lesny
05-092 Lomianki
Poland

Tel:
+33 (0)3 88 04 82 82
Fax:
+33 (0)3 88 04 82 90
Email: fr@lgcpromochem.com

Tel:
+48 (0)22 751 31 40
Fax:
+48 (0)22 751 58 45
Email: pl@lgcpromochem.com

Germany

Spain

LGC Promochem GmbH


Mercatorstrasse 51
46485 Wesel
Germany

LGC Promochem SL
Per, 104 - Nave 3
08018 Barcelona
Spain

Tel:
+49 (0)281 9887 250
Fax:
+49 (0)281 9887 259
Email: de@lgcpromochem.com

Tel:
+34 93 308 4181
Fax:
+34 93 307 3612
Email: es@lgcpromochem.com

India

Sweden

LGC Promochem India Private Limited


PO Box 8061
No. 142, 3rd Floor, 5th Cross
Rajmahal Vilas Extension
Bangalore 560 080
India

LGC Promochem AB
Box 1737
SE-501 17 Bors
Sweden

Tel:
+91 080 2361 4774 1256
Fax:
+91 080 2361 3859
Email: in@lgcpromochem.com

Tel:
+46 (0)33 20 90 65
Fax:
+46 (0)33 20 90 79
Email: se@lgcpromochem.com

If you are unsure of your local office, please email: askus@lgcpromochem.com

Edition 2003/2004

Contents

Contents
Introduction
Introduction
Einleitung
Introduction
Introduccin
About the reference materials producers
About reference materials
About reference materials applications
About Quality Control Materials (QCRMs)
About proficiency testing (PT)
Relevant literature
Relevant training courses
General ordering information

4
5
6
7
8
9
9
9
10
11
11
12

Food and agriculture


Dairy products

13

Meat

17

Fish
Shellfish
Shellfish toxins: Diarrhetic (DSP), Paralytic (PSP), Amnesic (ASP)
Fish

22
22
26
28

Cereals and crops


Wheat
Corn
Rye
Rice
Rapeseed
Genetically modified crops

32
32
33
33
33
34
35

Vegetable matter
Fruit and vegetables
Vegetable oils

36
36
38

Mycotoxins
Single compounds
Multicomponent standard solutions

39
39
40

Quality control reference materials from LGC

41

Food Authenticity

42

Lipid Standards

43

Food and drink products


Processed food
Drinks
Food additives
Dye standards
Alcoholic and low alcohol beverage
Alcohol

49
49
51
52
53
54
54

Animal food products

55

Fertilizers

56

Plants
Trees and bushes
Grasses and crops
Aquatic plants
Miscellaneous

58
58
60
61
62

www.lgcpromochem.com

Edition 2003/2004

Contents
Industrial raw materials and products
Solid fuels

64

Oils and liquid fuels

68

Conostan Oil Analysis Standards


Single element standards in oil
Multi-element standards in oil
Sulphur in mineral oil
Chlorine in oil
Element blank oils
PremiSolvTM ICP solvent
PartiStanTM particle standards- Compliant with ISO 11171:1999
FTIR Operational Test Standard
Proficiency test program - Oil analysis

CONOSTAN D-Series Element (metallo-organic) Standards: D-3, D-12, D-19 (JOAP)

Conostan elements in oil custom standard request form

75
75
77
80
80
81
81
81
82
82
83
85

Ores

86

Refractories and carbides

91

Cement

92

Glass and ceramics

94

Plastics

99

Metals

99

Miscellaneous

105

Occupational hygiene
Filter media

106

Paint and industrial sludges

108

Asbestos

110

Ash and particulate

111

Dust and Fumes

114

Aldehydes/Ketones-DNPH standards

116

Pure materials
Elemental analysis

119

Stochiometry

121

Organo-metallic compounds

122

Speciation

122

Isotopes

123

Standards for spectroscopy

NIST Standard Reference Materials (SRMs )


ULTRA Scientifics certified ICP/AA standards
TM
ULTRA Scientific's EnviroConcentrate kits for ICP
ULTRA Scientifics certified standards for atomic absorption spectroscopy
TM
ULTRA Scientific's EnviroConcentrates for atomic absorption spectroscopy

125
125
125
134
136
140

Multielement standards
EPA Method 200.7
EPA Method 6010A
Standards for ICP/MS

144
144
146
147

Ion chromatography standards

148

CERTAN - The ampoule in the bottle


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Introduction

Introduction
About the catalogue
Reference materials for food, industry and occupational hygiene 2003/2004 is the first catalogue
from LGC Promochem offering a comprehensive selection of more than 1000 reference materials and
standards exclusively intended for these diverse fields of analysis
For food analysts the range includes food and beverage matrices certified for nutritional and other
analytes as well as pure standards such as food additives and colourings. Of particular interest is the
new selection of mycotoxins standards.
The industrial chapter features materials for a wide spectrum of industries from mining to textiles and

from plastics to cement. For the first time Conostan Oil Analysis Standards, focussed on lubricant/oil
analysis and condition monitoring is included.
The products described in this catalogue are sourced from national and international bodies, as well
as commercial organisations. A certificate of analysis normally accompanies each sample. However
the appearance and content of these certificates will vary according to producer.

About LGC Promochem


LGC Promochem is Europes leading supplier of reference materials. We work closely with leading
manufacturers worldwide to offer laboratories across Europe improved access to reference materials
designed to suit an increasingly large range of analyses.
Our network of offices in Europe and India together with our long experience in selling reference
materials allows LGC Promochem to work in partnership with our customers to provide fast delivery
together with good technical advice as well as dealing with complicated import and export regulations.

LGC Promochem is an authorised distributor of BCR reference materials. We currently stock more

than 2000 units of certified BCR reference materials under controlled conditions.

Edition 2003/2004

www.lgcpromochem.com

Einleitung

Einleitung
ber den Katalog
Reference materials for food, industry and occupational hygiene 2003/2004 ist der erste Katalog von
LGC Promochem mit einer umfassenden Auswahl von mehr als 1000 Referenzmaterialien fr die
Bereiche Lebensmittel, Industrie und Arbeitshygiene.
Fr den Bereich der Lebenmittelanalytik reicht die Produktpalette von Matrixreferenzmaterialien wie
Lebensmittel und Getrnke, bis hin zu reinen Verbindungen wie Fettsuren oder auch Zusatzstoffe fr
Lebensmittel. Besonders interessant sind einige neue Mykotoxin-Standards.
Die Referenzmaterialien fr die Industrie umfassen Matrixmaterialien aus dem Bergbau, sowie

Textilien, Kunststoffe, Zement und viele mehr. Neu in unserem Lieferprogramm sind die Conostan
l-Standards.
Die in diesem Katalog beschriebenen Produkte stammen von nationalen und internationalen
Einrichtungen, wie auch von kommerziellen Anbietern. Jedes Produkt wird in der Regel mit einem
Zertifikat geliefert. Aussehen und Inhalte der Zertifikate sind je nach Hersteller unterschiedlich

ber LGC Promochem


LGC Promochem ist der fhrende Lieferant von Referenzmaterialien in Europa. Wir arbeiten eng mit
den weltweit fhrenden Herstellern zusammen, um den europischen Laboratorien einen leichten
Zugriff auf Referenzmaterialien zu ermglichen.
Das Netzwerk an Niederlassungen in Europa und Indien verbunden mit langjhriger Erfahrung im
Vertrieb von Referenzmaterialien hat LGC Promochem zum Partner unserer Kunden werden lassen,
der neben optimierter Lieferzeit und technischer Beratung auch komplizierte Einfuhrvorgnge
bernimmt.

LGC Promochem ist autorisierter Distributor fr BCR -Referenzmaterialien. Zur Zeit lagern bei uns

unter kontrollierten Bedingungen mehr als 2000 Einheiten zertifizierter BCR -Referenzmaterialien.

www.lgcpromochem.com

Edition 2003/2004

Introduction

Introduction
Au sujet du catalogue
Le catalogue intitul : Reference materials for food, industry and occupational hygiene 2003/2004 de
LGC Promochem est la premire version regroupant une slection complte de plus de 1000
matriaux de rfrence et standards exclusivement destins aux analyses dans ces domaines.
En ce concerne la gamme qui se destine aux analyses alimentaires, celle-ci comprend des matrices
alimentaires et des boissons certifies en analytes et nutriments ainsi que des substances pures de
rfrence comme des additifs et des colorants.
Le chapitre comprenant des rfrences se destinant lanalyse industrielle se caractrise par un trs
large ventail dindustries, savoir de lextraction minire au domaine textile ou de lindustrie du
plastique celle des ciments. Nous prsentons pour la premire fois la gamme de standards

analytiques dhuiles de base Conostan .


Les produits dcrits dans ce catalogue sont issus dorganismes nationaux et internationaux reconnus
ainsi que de socits commerciales. Un certificat danalyses est gnralement fourni avec chaque
chantillon. Cependant selon le producteur, la prsentation du certificat et son contenu peuvent
varier.

Au sujet de LGC Promochem


LGC Promochem est le principal fournisseur europen de matriaux de rfrence. Nous travaillons en
troite collaboration avec les principaux producteurs mondiaux afin doffrir aux laboratoires europens
le meilleur accs possible tout type de matriaux de rfrence destins correspondre un
nombre grandissant danalyses.
Le rseau europen de bureaux LGC Promochem ainsi que notre exprience dans la distribution de
matriaux de rfrence permettent dassurer des livraisons plus rapides, un support technique en
direct sans oublier une assistance lors dimportations soumises contrles.

LGC Promochem est un distributeur officiel des matriaux de rfrence du BCR . Nous stockons

actuellement plus de 2000 units de matriaux de rfrence certifis du BCR dans des conditions
contrles.

Edition 2003/2004

www.lgcpromochem.com

Introduccin

Introduccin
Acerca de este catlogo
Materiales de referencia para la alimentacin, la industria y la higiene en el trabajo 2003/2004 es el
primer catlogo de LGC Promochem, que ofrece una amplia seleccin de ms de 1000 materiales y
normas de referencia destinados exclusivamente a estos campos de anlisis.
Para los analistas de alimentos, la variedad incluye matrices de referencia de comida y bebida
certificadas para anlisis nutricionales y de otro tipo, adems de normas de pureza, como los
colorantes y los aditivos alimentarios. Cabe destacar la nueva seleccin de normas de micotoxinas.
El captulo industrial describe materiales para una amplio segmento de industrias, desde la minera a

la textil, y desde el plstico a las cementeras. Se incluye por primera vez la gama Conostan de
normas analticas basadas en el aceite.
Los productos descritos en este catlogo se han obtenido de organismos nacionales e
internacionales, as como de organizaciones comerciales. Cada una de las muestras suele ir
acompaada de un certificado de anlisis. Sin embargo, la presentacin y el contenido de estos
certificados variarn segn el fabricante.

Acerca de LGC Promochem


LGC Promochem es el primer proveedor de materiales de referencia en Europa. Trabajamos en
estrecha colaboracin con fabricantes lderes en el mbito internacional para ofrecer a los
laboratorios de toda Europa un mejor acceso a materiales de referencia diseados para adaptarse a
una diversidad de anlisis que se ampla constantemente.
Nuestra red de oficinas en Europa e India, junto con nuestra larga experiencia en la venta de
materiales de referencia, permite a LGC Promochem trabajar conjuntamente con sus clientes para
proporcionar una rpida entrega, adems de un buen asesoramiento tcnico y cumplir con los
complicados reglamentos sobre importacin y exportacin.

LGC Promochem es distribuidor autorizado de materiales de referencia BCR . Actualmente tenemos

almacenadas ms de 2000 unidades de materiales de referencia certificados BCR en condiciones


controladas.

www.lgcpromochem.com

Edition 2003/2004

Reference Materials

Reference Materials
About the reference materials producers
BCR
BCR reference materials are the product of both research funding and direct action programmes of
the European Commission, in which new or improved measurement or testing methods are
developed. These programmes are aimed at improving, harmonising or standardising measurements
and testing in the European Union. BCR is part of the Institute for Reference Materials and
Measurements (IRMM) in Belgium.

LGC
LGC has a long history in the development and validation of analytical methods and the reference
materials production facility at LGC, complements this expertise. In addition LGC offers a range of
chemical and bio-analytical laboratory services across a variety of sectors including: food and
agriculture, environment, life sciences, chemicals and forensic science. LGC plays a pivotal role in a
number of programmes with both government and industry intended improve analytical standards and
performance.

The National Institute of Standards and Technology (NIST)


NIST produces standard reference materials (SRMs). Based in the United States, NIST has provided
reference materials to industry and commerce for nearly 100 years. NIST collaborates with companies
to provide academia and industry with SRMs for expanding areas such as air and water pollution,
which are international issues.

ULTRA ScientificTM
TM

ULTRA Scientific is recognized as a leader in the chemical standards industry and LGC
Promochem is working in close partnership with ULTRA to ensure that the requirements for high
quality environmental standards are satisfied. ULTRAs organic and inorganic calibration standards
are widely used in the analysis of drinking water, waste water, soils, sediments, foods, cosmetics and
other products.
Their manufacturing, quality control and distribution system is registered to the International ISO 9001
standard. ULTRA was among the first standards manufacturers to have its quality control laboratory
accredited to the ISO Guide 25 standard.

CerilliantTM Corporation
TM

Cerilliant Corporation is a leading supplier of chemical standards for environmental analysis and
forensic drug testing and for providing custom chemical synthesis. They were the first to produce 13C
labeled chlorinated Dioxins and Furans in cooperation with Cambridge Isotope Laboratories to meet
the increasing demand for isotope-labeled reference materials. From raw materials analysis to
continuing shelf-life studies, Cerilliants ISO 9001 system requires multiple checks to ensure product
conformance.

CONOSTAN Oil Analysis Standards

CONOSTAN is a pioneer and global leader in the development, manufacturing, and marketing of oil
analysis reference materials/standards. The pioneering innovation continues with introductions of
standards for lubricant product analysis that are benchmarks for quality, accuracy, precision, and
traceability. Their quality program is certified under ISO 9001:2000.

Others
Materials from the following organisations are also included in this catalogue:
- Agricultural Research Centre, Finland
- Institute of Nuclear Chemistry and Technology, Poland
- International Atomic Energy Agency, Austria
- National Research Centre for Certified Reference Materials, China
- National Food Administration, Sweden
- R. T. Corporation, USA
- Swedish Meats R&D, Sweden

Edition 2003/2004

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About reference materials

About reference materials


It is important to differentiate between reference materials and certified reference materials.
Reference materials (RMs) are defined by the International Organisation for Standardisation (ISO)
Guide 30 as: a material or substance, one or more of whose property values are sufficiently
homogeneous and well established to be used for the calibration of an apparatus, the assessment of
a measurement method or for assigning values to materials.
The ISO Guide defines a certified reference material (CRM) as: a reference material accompanied by
a certificate, one or more of whose property values are certified by a procedure which establishes its
traceability to an accurate realisation of the unit in which the property values are expressed, and for
which each certified value is accompanied by an uncertainty at a stated level of confidence.
Reference materials may also be categorised as either pure materials, used to make standard
solutions to calibrate instruments, or as matrix reference materials used to validate test methods (the
matrix should be as similar as possible to the samples being analysed).
A standard solution is required to calibrate the response of a measuring instrument. A matrix
reference material is used to assess the suitability of a complete analytical measurement process. By
using a suitable matrix reference material the problems encountered with routine samples due to
speciation, extraction efficiency, completeness of matrix dissolution and possible interference can be
replicated. With these conditions if the reference material results agree with the certificate value then
the results obtained on the samples will be accurate.
When selecting a reference material for a particular application the analyst must consider the
following factors before selecting a material:
- Matrix match and potential interferences
- Analytes
- Measurement range
- Measurement uncertainties
- Certification procedures used by the producer
- Documentation supplied with the material (e.g. certificate or report)

About reference materials applications


Food safety, product quality, occupational protection and law enforcement are all dependent on
reliable chemical measurements to ensure correct and accurate decisions are made. Reference
materials are instrumental in ensuring the reliability of these measurements and thus avoiding the use
of poor quality data as the basis of decision making.
Reference materials have a wide variety of applications examples including:
- Method validation
- Instrument calibration
- Establishing traceability
- Assistance with quality control
- Qualitative verification
- As check samples to assess the performance of an analyst

About Quality Control Materials (QCRMs)


QCRMs are a new product range from LGC and have been developed for use in routine analysis. The
QCRM range offers the ideal solution for independently produced materials to meet UKAS and ISO
17025 accreditation requirements for traceability and comparability of results. Applications include
checking results for bias, establishing QC charts with traceable reference values and action limits,
estimating the uncertainty of an analytical method, training new analysts, monitoring continuing staff
competence and saving time associated with the production of in-house QC materials.
QCRMs have been priced to allow routine use in the analysis that forms the bulk of daily laboratory
analysis. Full documentation and instructions are provided with each QCRM.
Currently available QCRMs are: Meat Paste (1), Flour (1), Chocolate (1), Fish Paste (1), Fish Paste
(2), Animal Feed (1), Landfill Leachate (1), Landfill Leachate (2), Contaminated Soil (1).
The QCRM range is planned for expansion to meet customers needs for particular materials. If there
are particular materials or applications that you would like developed or if you have any other queries
regarding the QCRM range please contact the production team on:
Tel
www.lgcpromochem.com

+44 (0)20 8943 7514

Fax
Edition 2003/2004

+44 (0)20 8943 7314


9

About proficiency testing (PT)

About proficiency testing (PT)


Proficiency testing (PT) is a powerful quality assurance tool for laboratories undertaking analytical
measurements. A PT scheme provider distributes test materials on a regular basis to participating
laboratories for independent testing.The results are returned to the organiser of the scheme who
makes an analysis of the results and provides a report to all the participants.
There are a number of benefits of taking part in a PT scheme:
- Provides laboratories with a mechanism to compare their measurements with others
- Enables laboratories to demonstrate the quality of their results to third parties e.g. customers,
regulators and accreditation bodies
- Facilitates the monitoring of trends, over time, in the quality of measurements
- Assists the evaluation of methods and instrumentation
- Helps and educates laboratory staff and their customers
The PT group at LGC is an accredited PT scheme provider, offering a range of PT schemes across
different measurement sectors. As international experts in many aspects of PT, LGC can provide a
range of consultancy and training services for PT providers, participants and participant customers.
Current PT schemes available from LGC include:

BAPS
Chemical, microbiological and sensory analysis of a range of beers. Jointly operated with Brewing
Research International.

CONTEST
Analysis of contaminated soils for a wide range of metals and inorganic/organic contaminants.

CRYPTS
Counting of cryptosporidium oocysts in drinking water. Jointly operated with the Scottish Parasite
Detection Laboratory under licence from the UK Drinking Water Inspectorate.

DAPS
Scheme for the alcoholic drinks industry (except beer) for the analysis of alcoholic strength and a wide
range of other parameters in fermented worts, distilled spirits, wine, liquors etc.

LGC PC1
Analysis of raw sugar used in soft drink production in association with PepsiCo Beverages
International.

MAPS
Analysis of malt and barley used by the malting, brewing and distilling industries. Jointly operated with
Greencore Malting Group.

PHARMASSURE
Measurement of a range of parameters in pharmaceutical and medicinal products.

Quartz
Measurement of a range of prescription and illicit drugs in post-mortem human blood.

SODAS
Analysis of carbonated and still soft drinks for a number of different analytes.

OIL ANALYSIS
Analysis of important properties of lubricants (new & used/in-service) such as: wear & additive metals,
particles, viscosity.

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Relevant literature
TOYTEST
Toy safety testing to the European Standard EN71.
Each scheme is run on an international basis. All schemes are managed in accordance with ISO/IEC
Guide 43:1 and ILAC Guide G13:2000. The scientific integrity and content is assured by a Steering
Group for each scheme, consisting of experts in the sector. All schemes are fully confidential, with
participants only being identified by a unique identification number. The operation of each scheme is
documented in a scheme protocol that is available on request.
For further information, please contact:
Proficiency Testing Group
LGC
Queens Road
Teddington, Middlesex
TW11 0LY, UK

Tel:
Fax:
Email:
Web:

+44 (0)20 8943 8494


+44 (0)20 8943 0654
ptgroup@lgc.co.uk
www.lgc.co.uk

Relevant literature
Applications of Reference Materials in Analytical Chemistry VAM
V. Barwick, S. Burke, R. Lawn, P. Roper and R. Walker RSC
Reference Materials in Analytical Chemistry A Guide for Selection and Use
A. Zschunke published by Springer-Verlag
Reference Materials for Chemical Analysis Certification, Availability and Proper Usage
M. Stoeppler, W.R. Wolf, P.J. Jenks published by Wiley-VCH
Proficiency Testing in Analytical Chemistry, R. Lawn, M. Thompson and R. Walker published by The
Royal Society of Chemistry

Relevant training courses


A range of training courses are available from LGC to help laboratory managers and analysts
demonstrate competence in, and keep abreast of, quality assurance issues and practices. LGCs
analytical quality training programme includes a range of training courses:
- Using reference materials in analytical measurements
- Using proficiency testing in the analytical laboratory
- Method validation
- Principles and practice of measurement uncertainty in chemical testing laboratories
- ISO/IEC 17025 implementation
- Quality systems in testing laboratories
- Statistics for analytical chemists
- Further statistical tools for analytical chemists
The majority of the courses are run in South West London at Teddington. In addition, LGC can
provide training for groups of staff at your own site, where the courses can be customised to meet
your exact needs.
For further information, please contact:
Lorraine Didinal
LGC Training Centre
Queens Road
Teddington, Middlesex
TW11 0LY, UK

www.lgcpromochem.com

Tel:
Fax:
Email:
Web:

+44 (0)20 8943 7314


+44 (0)20 8943 7631
training@lgc.co.uk
www.lgc.co.uk

Edition 2003/2004

11

General ordering information

General ordering information


Prices and delivery procedures are shown in the price list that accompanies this catalogue, or are
available from your local LGC Promochem sales office. For products requiring special delivery
procedures (cooled shipping, special licensing, controlled substances, etc) additional charges will be
applied.
Please check with your local LGC Promochem sales office for detailed procedures and transport
charges where applicable.
Unless otherwise agreed in advance and in writing, orders are accepted only against LGC
Promochems standard terms and conditions of sale.
Once delivered to the customer, reference substances are not returnable. For this reason it is very
important for users to be certain that the product ordered meets their needs.
LGC Promochems technical staff is available to advise on the use and suitability of a particular
product. Customers requiring assistance with the use or application of a particular reference
substance should contact their local LGC Promochem office, contact details are provided at the
beginning of this catalogue.

For further information please contact any of the offices listed on page 4 or visit our website
www.lgcpromochem.com.

12

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Dairy products

Dairy products
Code

LGC7104 (RM)

Product

Unit

Sterilised cream - Proximates and nutrient elements

5 x 170 g

Assessed values
Ca ............................. 845 mg/kg
K ............................. 1160 mg/kg
Mg ............................... 84 mg/kg
Na ............................. 505 mg/kg

P ................................823 mg/kg
Zn ...............................3.1 mg/kg
Moisture..................70.2 g/100 g
Nitrogen..................0.40 g/100 g

Total fat.................. 22.7 g/100 g


Ash......................... 0.58 g/100 g

Indicative values for Cl, Lactose

LGC7106 (RM)

Processed cheese - Proximates

5 x 220 g

Assessed values
Moisture ................. 46.1 g/100 g
Nitrogen ................. 2.98 g/100 g

BCR-063R

Total fat ..................27.0 g/100 g


Ash ...........................5.3 g/100 g

Skim milk powder - Major and trace elements

50 g

Natural elemental levels in milk.


Certified values
Ca ............................. 13.49 g/kg
Cl ................................ 9.94 g/kg
Cu .......................... 0.602m g/kg
Fe............................. 2.32m g/kg

I ................................0.81m g/kg
K ................................17.68 g/kg
Mg .............................1.263 g/kg
N (total)........................62.3 g/kg

Na ............................... 4.37 g/kg


P ............................... 11.10 g/kg
Pb .............................. 18.5g/kg
Zn............................. 49.0m g/kg

Indicative values for Mo, N(Kjeldahl), Se

BCR-150

Spiked skim milk powder - Trace elements

23 g

Milk spiked with Cd, Cu, Fe and Hg.


Certified values
Cd ............................. 21.8 g/kg
Cu ............................ 2.23 mg/kg

Fe .............................11.8 mg/kg
Hg................................9.4 g/kg

I ................................ 1.29 mg/kg


Pb ............................ 1.00 mg/kg

Indicative values for Co, Mn, Ni, Se, Tl, Zn

BCR-151

Spiked skim milk powder - Trace elements

23 g

Milk spiked with Cd, Cu, Fe and Hg.


Certified values
Cd ........................... 101.0 g/kg
Cu ............................ 5.23 mg/kg

Fe .............................50.1 mg/kg
Hg...............................101 g/kg

I ................................ 5.35 mg/kg


Pb ........................... 2002 mg/kg

Indicative values for Co, Mn, Ni, Se, Tl, Zn

BCR-421

Milk powder - Vitamins

50 g

Spiked spray-dried powder.


Certified values
B1 (thiamin) .............. 6.51 mg/kg
B2 (riboflavin)............ 14.5 mg/kg
B6 (total pyridoxine) .. 6.66 mg/kg

NIST-1549

B12 ..........................0.034 mg/kg


C (total ascorbate).....769 mg/kg
D3 (cholecalciferol)..0.143 mg/kg

E (tocopherol) ............. 99 mg/kg


Folate (total)............. 1.42 mg/kg
Niacin.......................... 68 mg/kg

Non-fat milk powder - Trace elements

100 g

Certified values
Ca ................................... 1.30 %
Cd ........................ 0.0005 mg/kg
Cl .................................... 1.09 %
Cr ......................... 0.0026 mg/kg
Cu .............................. 0.7 mg/kg
I ................................ 3.38 mg/kg

Fe .............................1.78 mg/kg
Hg.........................0.0003 mg/kg
K ..................................... 1.69 %
Mg ................................ 0.120 %
Mn ............................0.26 mg/kg
Na................................. 0.497 %

P ..................................... 1.06 %
Pb .......................... 0.019 mg/kg
S ................................... 0.351 %
Se ............................ 0.11 mg/kg
Zn............................. 46.1 mg/kg

Indicative values for Ag, Al, As, Br, Co, F, Mo, Rb, Sb, Sn

NIST-RM 8435

Whole milk powder - Trace elements, proximates and nutrients

40 g

Reference values for major, minor and trace constituent elements, proximates, fatty acids, calories and selected
vitamins.
Indicative values for additional elements, fatty acids and vitamins

NIST-1846

Whole milk powder - Trace elements, proximates and nutrients

10 x 30 g

Certified values
Vitamin A (as trans-retinol) ......................5.84 mg/kg
Vitamin E (as tocopherol) .....................271 mg/kg
Vitamin C ................................................1146 mg/kg
Vitamin B2 ................................................17.4 mg/kg

Vitamin B6 ................................................. 8.4 mg/kg


Niacin ...................................................... 63.3 mg/kg
Iodine ...................................................... 1.11 mg/kg

Indicative values for proximates, calories, additional vitamins, minerals and trace elements

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Edition 2003/2004

13

Dairy products
Code

ARC/CL1

Product

Unit

Skim milk powder - Trace elements

50 g

A homogeneous spray-dried milk powder containing 2.0% fat.


Certified values
Ca ............................ 13.00 mg/g
Cd .................................. <5 ng/g
Cu ............................... 0.59 g/g
Fe................................ 4.54 g/g

IAEA-153

Hg...................................<1 ng/g
Mg ..............................1.23 mg/g
Mn ...............................0.44 g/g
Mo ...............................0.49 g/g

Pb .................................. 16 ng/g
Se .................................. 82 ng/g
Zn.............................. 41.68 g/g

Milk powder - Trace elements

50 g

Certified values
Br ............................. 12.3 mg/kg
Ca ......................... 12870 mg/kg
Fe............................. 2.53 mg/kg

K ............................17620 mg/kg
Mg ...........................1060 mg/kg
Na............................4180 mg/kg

P ........................... 10100 mg/kg


Rb ............................... 14 mg/kg
Zn............................. 39.6 mg/kg

Indicative values for Cu, Mn, Mo, Sr

IAEA-155

Whey powder - Trace elements

50 g

Certified values
Br ............................. 39.1 mg/kg
Cd .......................... 0.016 mg/kg
Cl .......................... 69200 mg/kg
Co ........................ 0.0427 mg/kg
Cr ............................. 0.59 mg/kg
Cs .......................... 0.086 mg/kg

Hg.........................0.0026 mg/kg
Mg ...........................3190 mg/kg
Mn ..............................9.3 mg/kg
Na.............................15.8 mg/kg
Ni ..............................0.54 mg/kg
P ............................16210 mg/kg

Pb .......................... 0.104 mg/kg


Rb ............................ 39.2 mg/kg
Sc........................... 0.028 mg/kg
Se .......................... 0.064 mg/kg
Zn............................. 34.3 mg/kg

Indicative values for Al, As, B, Ca, Cu, Fe, K, S, Sr

BCR-282

Whole milk powder - Aflatoxin M1 (very low level)

25 g

Certified value
Aflatoxin M1 ......... <0.05 g/kg (probable content is in the range 0.01 to 0.02 g/kg)

BCR-283

Whole milk powder - Aflatoxin M1 (low level)

25 g

Certified value
Aflatoxin M1 .............. 0.09 g/kg

BCR-187

Natural milk powder - Pesticides


Compound

20 g

Certified value
g/kg

Uncertainty
g/kg

HCB ................................................................... 1.50............................ 0.2


alpha-HCH ........................................................... 1.8.......................... 0.14
gamma-HCH........................................................ 5.7............................ 0.7
4,4'-DDE .............................................................. 6.6............................ 0.6

BCR-188

Milk powder (spiked) - Pesticides


Compound

20 g

Certified value
g/kg

Uncertainty
g/kg

HCB ................................................................... 37.4............................ 2.7


alpha-HCH ......................................................... 20.0............................ 0.9
beta-HCH........................................................... 12.0............................ 1.2
gamma-HCH...................................................... 45.4............................ 2.9
beta-Heptachlor epoxide.................................... 32.0............................ 1.8
4,4'-DDE ............................................................ 51.3............................ 3.5
Dieldrin............................................................... 36.1............................ 2.4
Endrin .................................................................. 6.2............................ 0.9
4,4-DDT ............................................................ 69.0............................ 4.6

BCR-450

Natural milk powder - PCBs


Compound

20 g
Certified value
g/kg

Uncertainty
g/kg

PCB 52 .............................................................. 1.16.......................... 0.17


PCB 118 .............................................................. 3.3............................ 0.4
PCB 153 ............................................................ 19.0............................ 0.7
PCB 156 ............................................................ 1.62............................ 0.2
PCB 170 .............................................................. 4.8............................ 0.6
PCB 180 ............................................................ 11.0............................ 0.7

BCR-532 (RM)

Unspiked milk powder - PCDDs and PCDFs (blank)

60 g

Non certified values

14

ng/kg

ng/kg

ng/kg

2,3,7,8-TCDD...................... 0.10
1,2,3,7,8-PeCDD ................ 0.29
1,2,3,4,7,8-HxCDD ............. 0.17
1,2,3,6,7,8-HxCDD ............. 0.43

1,2,3,7,8,9-HxCDD ..............0.16
2,3,7,8-TCDF.......................0.16
1,2,3,7,8-PeCDF ...................0.1
2,3,4,7,8-PeCDF .................0.67

1,2,3,4,7,8-HxCDF.............. 0.34
1,2,3,6,7,8-HxCDF.............. 0.34
2,3,4,6,7,8-HxCDF.............. 0.39

Edition 2003/2004

www.lgcpromochem.com

Dairy products
Code

Product

Unit

BCR-533 (RM)

Spiked milk powder - PCDDs and PCDFs (lower level)

60 g

Non certified values

BCR-534 (RM)

ng/kg

ng/kg

ng/kg

2,3,7,8-TCDD...................... 0.42
1,2,3,7,8-PeCDD ................ 0.86
1,2,3,4,7,8-HxCDD ............. 0.56
1,2,3,6,7,8-HxCDD ............. 1.27

1,2,3,7,8,9-HxCDD ..............0.47
2,3,7,8-TCDF.......................0.39
1,2,3,7,8-PeCDF ...................0.1
2,3,4,7,8-PeCDF .................1.96

1,2,3,4,7,8-HxCDF.............. 1.06
1,2,3,6,7,8-HxCDF.............. 1.03
2,3,4,6,7,8-HxCDF.............. 1.22

Spiked milk powder - PCDDs and PCDFs (higher level)

60 g

Non certified values

BCR-607

ng/kg

ng/kg

ng/kg

2,3,7,8-TCDD...................... 0.65
1,2,3,7,8-PeCDD ................ 1.44
1,2,3,4,7,8-HxCDD ............. 0.80
1,2,3,6,7,8-HxCDD ............. 1.92

1,2,3,7,8,9-HxCDD ..............0.80
2,3,7,8-TCDF.......................0.65
1,2,3,7,8-PeCDF .................0.15
2,3,4,7,8-PeCDF .................3.16

1,2,3,4,7,8-HxCDF.............. 1.75
1,2,3,6,7,8-HxCDF.............. 1.55
2,3,4,6,7,8-HxCDF.............. 1.90

Natural spray dried milk powder - PCDDs and PCDFs


Compound

Certified value
ng/kg

100 g

Uncertainty
ng/kg

2,3,7,8-TCDD..................................................... 0.25.......................... 0.03


1,2,3,7,8-PeCDD ............................................... 0.79.......................... 0.04
1,2,3,4,7,8-HxCDD ............................................ 0.42.......................... 0.07
1,2,3,6,7,8-HxCDD ............................................ 0.98.......................... 0.11
1,2,3,7,8,9-HxCDD ............................................ 0.34.......................... 0.05
2,3,7,8-TCDF ..................................................... 0.05.......................... 0.03
1,2,3,7,8-PeCDF.............................................. 0.054........................ 0.013
2,3,4,7,8-PeCDF................................................ 1.81.......................... 0.13
1,2,3,4,7,8-HxCDF............................................. 0.94.......................... 0.04
1,2,3,6,7,8-HxCDF............................................. 1.01.......................... 0.09
2,3,4,6,7,8-HxCDF............................................. 1.07.......................... 0.05

IAEA-152

Milk powder - Radioactive isotopes

250 g

Certified values
134

40

137

90

Cs........................... 764 Bq/kg


Cs......................... 2129 Bq/kg

IAEA-321

K ............................. 539 Bq/kg


Sr ............................. 7.7 Bq/kg

Milk powder - Radioactive isotopes

250 g

Certified values
134

40

137

90

Cs.......................... 15.5 Bq/kg


Cs.......................... 72.6 Bq/kg

IAEA-154

K ............................. 552 Bq/kg


S .............................. 3.3 Bq/kg

Whey powder - Radioactive isotopes

250 g

Certified values
134

40

137

90

Cs......................... 1355 Bq/kg


Cs......................... 3749 Bq/kg

BCR-519

K ........................... 1575 Bq/kg


S .............................. 6.9 Bq/kg

Anhydrous butter fat - Triglycerides

2 amp.

Triglyceride contents of an anhydrous butter fat with additional value for free cholesterol.
Compound

Certified value
mass fraction (%)

Uncertainty
mass fraction (%)

Cholesterol.............................................. 0.30......................................................... 0.03


C24 ......................................................... 0.05......................................................... 0.02
C26 ......................................................... 0.25......................................................... 0.03
C28 ......................................................... 0.59......................................................... 0.04
C30 ......................................................... 1.15......................................................... 0.05
C32 ......................................................... 2.43......................................................... 0.12
C34 ......................................................... 5.64......................................................... 0.18
C36 ......................................................... 10.47....................................................... 0.19
C38 ......................................................... 12.53....................................................... 0.22
C40 ......................................................... 10.03....................................................... 0.16
C42 ......................................................... 6.69......................................................... 0.10
C44 ......................................................... 6.11......................................................... 0.08
C46 ......................................................... 6.86......................................................... 0.08
C48 ......................................................... 8.69......................................................... 0.15
C50 ......................................................... 11.40....................................................... 0.24
C52 ......................................................... 10.96....................................................... 0.25
C54 ......................................................... 5.89......................................................... 0.13

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Edition 2003/2004

15

Dairy products
Code

NIST-2387

Product

Unit

Peanut butter - Fat, fatty acids, trace elements and tocopherols

3 x 170 g

This Standard Reference Material (SRM) is intended primarily for use in validating methods for determining
proximates, fatty acids, calories, vitamins, elements, amino acids, and aflatoxins in peanut butter and similar
matrices.
Certified concentrations for fat and selected fatty acids
Mass fraction (%)
51.6 1.4

Fat (extractable)

Fat (sum of fatty acids) ............................. 49.8 1.9


Saturated fat ............................................. 10.4 0.2
Monounsaturated fat ................................. 24.4 0.9
Polyunsaturated fat ................................... 13.2 0.4
Mass fraction (%)
(as the triglyceride)

Mass fraction (%)


(as the fatty acid)

Tetradecanoic acid (C14:0) .................................................................. 0.025 0.002 ..................... 0.024 0.002


(Myristic acid)
Hexadecanoic acid (C16:0) ...................................................................... 5.18 0.15 ......................... 4.94 0.15
(Palmitic acid)
(Z)-9-Hexadecenoic acid (C16:1 n-7) ................................................... 0.046 0.011 ..................... 0.044 0.010
(Palmitoleic acid)
Octadecanoic acid (C18:0) ....................................................................... 2.23 0.08 ......................... 2.13 0.08
(Stearic acid)
(Z)-9-Octadecenoic acid (C18:1 n-9) ...................................................... 24.43 0.94 ....................... 23.38 0.90
(Oleic acid)
(Z)-11-Octadecenoic acid (C18:1 n-7) .................................................. 0.266 0.017 ..................... 0.255 0.016
(Vaccenic acid)
(Z,Z)-9,12-Octadecadienoic acid (C18:2 n-6) ......................................... 13.75 0.43 ....................... 13.15 0.41
(Linoleic acid)
(Z,Z,Z)-9,12,15-Octadecatrienoic acid (C18:3 n-3)............................... 0.031 0.001 ..................... 0.030 0.001
(Linolenic acid)
Eicosanoic acid (C20:0)........................................................................ 0.739 0.030 ..................... 0.710 0.029
(Arachidic acid)
(Z)-11-Eicosenoic acid (C20:1 n-9)....................................................... 0.669 0.032 ..................... 0.643 0.031
(Gondoic acid)
Docosanoic acid (C22:0) .......................................................................... 1.88 0.08 ......................... 1.81 0.08
(Behenic acid)
Tetracosanoic acid (C24:0)................................................................... 0.808 0.045 ..................... 0.781 0.044
Certified concentration values for elements and tocopherol
Mass fraction (mg/kg)

Mass fraction (mg/kg)

Ca ............................................................... 411 18
Cu ........................................................... 4.93 0.15
fe............................................................... 16.4 0.8
Mg ............................................................. 1680 70
Mn ............................................................. 16.0 0.6
P ............................................................... 3378 92

K.............................................................. 6070 200


Na............................................................ 4890 140
Zn .............................................................. 26.3 1.1
-Tocopherol .................................................. 10 3
- + -Tocopherol...................................... 100 19
-Tocopherol.............................................. 108 11

Reference values for proximates, caloric content, fatty acids, amino acids, water-soluble vitamins and aflatoxins

BCR-599

Ewes'/Goats' curd - Adulteration with cow's milk

set (2)

Two freeze dried curd materials made from a mixture of ewes and goats milk intended to detect adulteration by
cows milk in cheeses made from ewes milk, goats milk and mixtures of the two.
Unadulterated material 0% cows milk
Adulterated material 1% cows milk

BCR-122

Margarine - Vitamins

200 g

Certified values
D3 (cholecalciferol).................................0.125 mg/kg
E (tocopherol) ...........................................241 mg/kg

BCR-492-3

Lyophilized skimmed milk powder - Oxytetracycline

set

Set of BCR-492 and BCR-493


BCR-492
Certified value
Oxytetracyline ............ 307 g/kg
BCR-493
Certified value
Oxytetracyline ............ <10 g/kg

16

Edition 2003/2004

www.lgcpromochem.com

Meat

Meat
Code

Product

Unit

LGC7000

Beef/pork meat - Proximates and trace elements

200 g

Composed of 45% beef, 10% pork, 10% rusk, 4% fat, 0.5% emulsifier. Made up to 100% with water.
Certified values
Ca ............................. 253 mg/kg
K ............................. 1590 mg/kg
Na ........................... 1360 mg/kg

LGC7001

Zn .............................14.2 mg/kg
Moisture..................66.5 g/100 g
Fat ..........................12.4 g/100 g

Ash......................... 0.78 g/100 g


Nitrogen ................. 1.96 g/100 g

Pork meat - Proximates and trace elements

200 g

Composed of 50% pork leg, 12% rusk, 4% chicken fat, 0.5% emulsifier. Made up to 100% with water.
Certified values
Ca ............................. 319 mg/kg
K ............................. 1860 mg/kg
Na ........................... 1510 mg/kg

LGC7112

Zn .............................12.2 mg/kg
Moisture..................68.6 g/100 g
Fat ............................7.8 g/100 g

Ash......................... 0.90 g/100 g


Nitrogen ................. 1.97 g/100 g

Pig liver paste - Trace elements

150 g

Composed of 99.5% pig's liver and 0.5% stabiliser.


Certified values
Ca ............................ 48.9 mg/kg
Cd ............................ 0.25 mg/kg
Co .......................... 0.061 mg/kg
Cu ............................. 117 mg/kg

LGC7150 (RM)

K ..............................2770 mg/kg
Mg .............................167 mg/kg
Mn ............................3.04 mg/kg
Na..............................822 mg/kg

P ............................. 3430 mg/kg


Se ............................ 0.19 mg/kg
Zn............................. 43.0 mg/kg

Processed meat - Proximates and hydroxyproline

5 x 250 g

A pork based processed meat.


Assessed values
Moisture ................. 65.3 g/100 g
Nitrogen ................. 1.78 g/100 g

LGC7151 (RM)

Total fat ...................15.0 g/100g


Ash .........................3.37 g/100 g

Hydroxyproline ....... 0.17 g/100 g

Processed meat - Proximates, salt and nitrate

5 x 250 g

A pork-based processed meat.


Assessed values
Moisture ................................................ 63.6 g/100 g
Nitrogen ................................................ 1.93 g/100 g
Total fat................................................. 14.6 g/100 g

LGC7152 (RM)

Ash........................................................ 5.18 g/100 g


Salt (calculated from chloride content).. 4.32 g/100 g
Nitrate....................................................... 185m g/kg

Processed meat - Proximates, soya and casein

5 x 250 g

Assessed values
Moisture ................. 61.0 g/100 g
Nitrogen ................. 2.38 g/100 g

LGC7200 (RM)

Total Fat .................15.0 g/100 g


Ash .........................4.67 g/100 g

Beef, raw - Meat species

30 g

Rump steak from Scottish Aberdeen Angus cattle, aged 20 months, purchased from an organic farm. The cattle
had been fed grass rich in clover.
This material is intended for use as a reference standard for species identification analytical methods.
The species content of the material was checked using both an immunoassay test and DNA analysis.
Assessed value
Beef - raw.................100 % Beef
Indicative value for moisture

LGC7201 (RM)

Beef, cooked - Meat species

30 g

Rump steak from Scottish Aberdeen Angus cattle, aged 20 months, purchased from an organic farm. The cattle
had been fed grass rich in clover.
This material is intended for use as a reference standard for species identification analytical methods.
The species content of the material was checked using both an immunoassay test and DNA analysis.
Assessed value
Beef - cooked...........100 % Beef
Indicative value for moisture

LGC7202 (RM)

Lamb, raw - Meat species

30 g

Suffolk-cross leg of lamb, aged 9 months, was purchased from an organic meat supplier.
This material is intended for use as a reference standard for species identification analytical methods.
The species content of the material was checked using both an immunoassay test and DNA analysis.
Assessed value
Lamb - raw............. 100 % Lamb
Indicative value for moisture

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Edition 2003/2004

17

Meat
Code

LGC7203 (RM)

Product

Unit

Lamb, cooked - Meat species

30 g

Suffolk-cross leg of lamb, aged 9 months, was purchased from an organic meat supplier.
This material is intended for use as a reference standard for species identification analytical methods.
The species content of the material was checked using both an immunoassay test and DNA analysis.
Assessed value
Lamb - cooked ....... 100 % Lamb
Indicative value for moisture

LGC7204 (RM)

Pork, raw - Meat species

30 g

'Free range' Land Race/Large White Cross pork leg steak, aged approximately 5 months at slaughter, was
purchased from an organic meat supplier.
This material is intended for use as a reference standard for species identification analytical methods.
The species content of the material was checked using both an immunoassay test and DNA analysis.
Assessed value
Pork - raw ............... 100 % Pork
Indicative value for moisture

LGC7205 (RM)

Pork, cooked - Meat species

30 g

'Free range' Land Race/Large White Cross pork leg steak, aged approximately 5 months at slaughter, was
purchased from an organic meat supplier.
This material is intended for use as a reference standard for species identification analytical methods.
The species content of the material was checked using both an immunoassay test and DNA analysis.
Assessed value
Pork - cooked.......... 100 % Pork
Indicative value for moisture

LGC7206 (RM)

Chicken, raw - Meat species

30 g

'Free range' Ross whole chickens, aged 42 to 45 days at slaughter, were purchased from an organic meat
supplier.
This material is intended for use as a reference standard for species identification analytical methods.
The species content of the material was checked using both an immunoassay test and DNA analysis.
Assessed value
Chicken - raw.....100 % Chicken
Indicative value for moisture

LGC7207 (RM)

Chicken, cooked - Meat species

30 g

'Free range' Ross whole chickens, aged 42 to 45 days at slaughter, were purchased from an organic meat
supplier.
This material is intended for use as a reference standard for species identification analytical methods.
The species content of the material was checked using both an immunoassay test and DNA analysis.
Assessed value
Chicken - cooked.............................. 100 % Chicken
Indicative value for moisture

LGC7208 (RM)

Turkey, raw - Meat species

30 g

Organic turkeys were purchased from a local butcher's shop.


This material is intended for use as a reference standard for species identification analytical methods.
The species content of the material was checked using both an immunoassay test and DNA analysis.
Assessed value
Turkey - raw ........................................ 100 % Turkey
Indicative value for moisture

LGC7209 (RM)

Turkey, cooked - Meat species

30 g

Organic turkeys were purchased from a local butcher's shop.


This material is intended for use as a reference standard for species identification analytical methods.
The species content of the material was checked using both an immunoassay test and DNA analysis.
Assessed value
Turkey - cooked .................................. 100 % Turkey
Indicative value for moisture

BCR-185R

Bovine liver - Trace elements

15 g

Certified values
As.............................. 33.0 g/kg
Cd .............................. 544 g/kg
Cu ............................. 277 mg/kg

18

Mn ..........................11.07 mg/kg
Pb ...............................172 g/kg
Se .............................1680 g/kg

Edition 2003/2004

Zn........................... 138.6 mg/kg

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Meat
Code

BCR-186

Product

Unit

Pig kidney - Trace elements

15 g

Certified values
As................................. 63 g/kg
Cd ............................ 2710 g/kg
Cu ............................ 31.9 mg/kg

Fe ..............................299 mg/kg
Hg.............................1970 g/kg
Mn ..............................8.5 mg/kg

Pb .............................. 306 g/kg


Se .......................... 10300 g/kg
Zn.............................. 128 mg/kg

Indicative values for Ca, Cl, Cr, I, K, Mg, Na, Ni, P

BCR-384

Pork muscle - Major nutrients

50 g

Certified values
K ................................. 15.5 g/kg
Mg ............................... 1.00 g/kg

Na.............................2.8 g/100 g
N (Kjeldahl).............13.7 g/100 g

Fat.......................... 10.8 g/100 g


Ash at 550C............ 4.6 g/100 g

Indicative values for Ca, Cl, P

BCR-487

Pig liver - Vitamins

15 g

Certified values
B1 (thiamin) ................................................8.6 mg/kg
B2 (riboflavin) .........................................106.8 mg/kg
B6 (total pyridoxine)..................................19.3 mg/kg

BCR-411

B12 ........................................................... 1.12 mg/kg


Folate (total) ............................................ 13.3 mg/kg

Bovine muscle - Diethylstilbestrol

5g

Certified value
Diethylstilbestrol.......... >0.5 g/L

BCR-412

Bovine muscle - Diethylstilbestrol

5g

Certified value
Diethylstilbestrol.......... >0.1 g/L

BCR-474/475

Bovine liver - Trenbolone

set

Set of 2 x 2.8 g lyophylised liver powder


Certified values
BCR-474
17alpha-Trenbolone.. <0.5 g/kg
BCR-475
17alpha-Trenbolone.... 7.6 g/kg

BCR-648-9

Bovine liver - Clenbuterol

set

Set of 2 x 10 g lyophilised bovine liver


Certified values
BCR-648
Clenbuterol ............... <0.5 g/kg
BCR-649
Clenbuterol ................. 1.2 g/kg

NIST-1577b

Bovine liver - Trace elements

50 g

Certified values
Ag .......................... 0.039 mg/kg
Cd ............................ 0.50 mg/kg
Ca ............................. 116 mg/kg
Cl .................................. 0.278 %
Cu ............................. 160 mg/kg
Fe.............................. 184 mg/kg

K ................................... 0.994 %
Mg .............................601 mg/kg
Mn ............................10.5 mg/kg
Mo ..............................3.5 mg/kg
Na................................. 0.242 %
P ..................................... 1.10 %

Pb .......................... 0.129 mg/kg


Rb ............................ 13.7 mg/kg
S ................................... 0.785 %
Se ............................ 0.73 mg/kg
Sr ........................... 0.136 mg/kg
Zn.............................. 127 mg/kg

Indicative values for Al, As, Br, Co, Hg, Sb, V

NIST-RM 8414

Bovine muscle powder - Trace elements (not certified)

2 x 25 g

Reference values for Al, As, B, Br, Ca, Cd, Cl, Co, Cr, Cu, Fe, Hg, I, K, Mg, Mn, Mo, N, Na, Ni, P, Pb, Rb, S, Se,
Sr, Zn
Indicative values for Ba, Cs, F, Sb, V

NIST-1546

Meat homogenate - Nutrients

4 x 85 g

Certified values
Ca .............................................................323 mg/kg
Fe.............................................................11.4 mg/kg
Na ...........................................................9990 mg/kg
Decanoic acid (C10:0) ..............................0.171 g/kg
Dodecanoic acid (C12:0) ..........................0.133 g/kg
Tetradecanoic acid (C14:0) ........................2.53 g/kg

Hexadecanoic acid (C16:0)........................ 45.6 g/kg


Octadecenoic acid (C18:1) ........................ 21.7 g/kg
(Z)-9-Octadecanoic acid (C18:0)................ 21.7 g/kg
Eicosanoic acid ....................................... 0.31 5 g/kg
Cholesterol ............................................... 0.750 g/kg

Indicative values for additional fatty acids, proximates, calories, water-soluble vitamins, sucrose, minerals, trace
elements

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Edition 2003/2004

19

Meat
Code

Product

NRMGBW08551

Pork liver - Trace elements

Unit

25 g

Certified values
Al............................... 0.044 g/g
Cd ............................. 0.067 g/g
Ca ................................ 197 g/g
Cu ............................... 17.2 g/g
Fe.................................. 0.105 %

K ..................................... 1.15 %
Mg ................................747 g/g
Mn ...............................8.32 g/g
Mo .................................3.8 g/g
N................................... 10.86 %

Na ................................. 0.233 %
Pb ............................... 0.54 g/g
Se ............................... 0.94 g/g
Zn................................. 172 g/g

Indicative values for Co, Cr, P

NRMGBW08552

Pork muscle - Trace elements

20 g

Certified values
Br .................................. 6.2 g/g
Ca ................................ 147 g/g
Cl .................................. 0.187 %
Cu ............................... 3.88 g/g
Fe................................ 43.6 g/g

K ................................... 0.813 %
Mg ................................988 g/g
Mn ...............................0.48 g/g
N................................... 12.27 %
Na................................. 0.202 %

P ................................... 0.813 %
Rb ............................... 42.7 g/g
Se ............................... 0.49 g/g
Zn................................ 94.2 g/g

Indicative values for Ba, Co, Cr, Cs, Hg, Mo, Pb, Sr

SMRD 2000

Fresh meat - Proximates and trace elements

190 g

Certified values
Ash......................... 2.65 g/100 g
Moisture ................. 68.8 g/100 g
Fat.......................... 14.3 g/100 g
Nitrogen ................. 1.63 g/100 g

SMRD 2000
BCR-430

Hydroxyproline......0.133 g/100 g
Starch .....................3.85 g/100 g
NaCl .......................2.19 g/100 g
Na............................8533 mg/kg

K ............................. 1859 mg/kg


Ca ............................ 70.3 mg/kg
Fe............................. 6.33 mg/kg
P ............................. 1075 mg/kg

Fresh Meat - Proximates and trace elements

6 x 190 g

Pork fat - Organochlorine pesticides

3g

The sample is a homogeneous pork fat obtained from pigs fed with organochlorine pesticides.
Compound

Certified value
g/g

Uncertainty
g/g

HCB ................................................................. 0.392........................ 0.026


alpha-HCH ....................................................... 0.140........................ 0.012
beta-HCH......................................................... 0.259........................ 0.021
gamma-HCH...................................................... 0.50.......................... 0.03
beta-Hepo ........................................................ 0.109........................ 0.009
Dieldrin............................................................. 0.124........................ 0.011
Endrin .............................................................. 0.020........................ 0.004

BCR-163

Beef/pork fat blend - Fatty acids

2 amp.

The entire fatty acid (methyl ester) profile was determined but certified values are only given for the major
components (>2%) and indicative values are given for all minor components.
Methyl esters
(mass fraction fatty acid methyl ester/total fatty acid methyl ester)
Certified values
14:0 n-Tetradecanoic acids .................. 2.29 g/100 g
16:0 n-Hexadecanoic acid .................. 25.96 g/100 g
16:1 n-Hexadecanoic acids .................. 2.58 g/100 g
18:0 n-Octadecenoic acids ................. 18.29 g/100 g

18:1 n-Octadecenoic acids ................. 38.34 g/100 g


18:2 n-Octadecadienoic acids............... 7.05 g/100 g
18:3 n-Octadecatrienoic acids ............... 0.86 g/100g

Sterols
(mass fraction in fat)
Certified value
Cholesterol........ 133.6 mg/100 g
Indicative values for additional methyl esters of fatty acids

IRMM-444

Pork fat - PCBs (blank)

5g

Certified values
PCB 28 ........................ <2 g/kg
PCB 52 ........................ <2 g/kg
PCB 101 ...................... <2 g/kg

IRMM-445

PCB 118.......................<2 g/kg


PCB 138.......................<2 g/kg
PCB 153.......................<2 g/kg

Pork fat - PCBs (low level)


Compound

PCB 180 ...................... <2 g/kg


PCB sum.................... <14 g/kg

5g
Certified value
g/kg

Uncertainty
g/kg

PCB 28 .............................................................. 14.8............................ 1.3


PCB 52 .............................................................. 12.9............................ 0.9
PCB 101 ............................................................ 12.5............................ 1.2
PCB 118 ............................................................ 12.7............................ 1.3
PCB 138 ............................................................ 14.6............................ 1.6
PCB 153 ............................................................ 13.1............................ 1.1
PCB 180 ............................................................ 12.6............................ 0.9
PCB sum............................................................... 93............................... 7

20

Edition 2003/2004

www.lgcpromochem.com

Meat
Code

Product

IRMM-446

Pork fat - PCB (high level)


Compound

Unit

5g
Certified value
g/kg

Uncertainty
g/kg

PCB 28 .............................................................. 29.6............................ 2.1


PCB 52 .............................................................. 25.5............................ 1.8
PCB 101 ............................................................... 30............................... 4
PCB 118 ............................................................ 30.2............................ 2.7
PCB 138 ............................................................... 32............................... 4
PCB 153 ............................................................ 30.8............................ 2.4
PCB 180 ............................................................ 29.8............................ 2.5
PCB sum............................................................. 207............................. 11

BCR-444

Porcine muscle - Chloramphenicol (blank)

7g

Certified value
Chloramphenicol....... <0.2 g/kg

BCR-445

Porcine muscle - Chloramphenicol (positive)

7g

Certified value
Chloramphenicol......... 8.9 g/kg

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Edition 2003/2004

21

Fish

Fish
Code

Product

Unit

Shellfish
LGC7160

Crab paste - Trace elements

200 g

Prepared from frozen crab meat with 40% brown crab meat, 40% white crab meat, 0.5% stabiliser and water.
Certified values
As................................ 11 mg/kg
Ca ........................... 2150 mg/kg
Cd ............................ 1.85 mg/kg
Co .......................... 0.059 mg/kg
Cr ............................. 0.29 mg/kg

Cu.............................10.4 mg/kg
Hg...........................0.096 mg/kg
K ..............................1980 mg/kg
Mg .............................348 mg/kg
Mn ............................1.77 mg/kg

Na ........................... 2170 mg/kg


Ni ............................. 0.23 mg/kg
P ............................. 2965 mg/kg
V ............................ 0.084 mg/kg
Zn............................. 53.6 mg/kg

Indicative values for Al, Mo, Pb, Se, Sr

BCR-278R

Mussel tissue - Trace elements

8g

Certified values
As............................. 6.07 mg/kg
Cd .......................... 0.348 mg/kg
Cr ............................. 0.78 mg/kg

BCR-668

Cu.............................9.45 mg/kg
Hg...........................0.196 mg/kg
Mn ............................7.69 mg/kg

Pb ............................ 2,00 mg/kg


Se ............................ 1.84 mg/kg
Zn............................. 83.1 mg/kg

Mussel tissue - Trace elements

10 g

Certified values
Ce ............................ 88.7 mg/kg
Dy............................. 8.88 mg/kg
Er ............................. 4.47 mg/kg
Eu ............................ 2.79 mg/kg
Gd .......................... 12.95 mg/kg

La .............................80.3 mg/kg
Lu ...........................0.389 mg/kg
Nd.............................54.5 mg/kg
Pr..............................12.3 mg/kg
Sm ............................11.2 mg/kg

Tb............................. 1.62 mg/kg


Th............................. 10.7 mg/kg
Tm.......................... 0.480 mg/kg
U .............................. 55.9 mg/kg
Y............................... 58.9 mg/kg

Indicative values for : As, Cd, Co, Cr, Cr, Cs, Ho, Fe, Mo, Sc, Yb and Zn

BCR-682

Mussel tissue - PCBs

70 g

Certified values
PCB 28 ..................... 0.30 g/kg
PCB 52 ..................... 0.78 g/kg
PCB 118 ..................... 2.6 g/kg

BCR-477

PCB 138......................4.6 g/kg


PCB 149......................5.7 g/kg
PCB 153......................9.2 g/kg

PCB 170 ................... 0.17 g/kg


PCB 180 ................... 0.77 g/kg

Mussel tissue - Butyltin compounds


Compound

Certified value
mg/kg

14 g
Uncertainty
mg/kg

Tributyltin (TBT) ................................................. 2.20.......................... 0.19


Dibutyltin (DBT) ................................................. 1.54.......................... 0.12
Monobutyltin (MBT)............................................ 1.50.......................... 0.28

NIST-2976

Mussel tissue -Trace elements and methylmercury

25 g

Certified values
As.............................................................13.3 mg/kg
Cd ............................................................0.82 mg/kg
Cu ............................................................4.02 mg/kg
Fe..............................................................171 mg/kg

Pb............................................................ 1.19 mg/kg


Se............................................................ 1.80 mg/kg
Zn ............................................................. 137 mg/kg
Methylmercury (total)................................ 61.0 g/kg

Indicative values for: Ag, Al, Br, Ca, Ce, Cl, Co, Cr, Cs Eu, K, Mg, Mn, Na, Ni, P, Pb, Rb, S, Sc, Sn, Sr, Th, Tl

NRMGBW08571

Mussel - Trace elements

12 g

Certified values
As.................................. 6.1 g/g
Ca ................................. 0.111 %
Cd ................................. 4.5 g/g
Co ............................... 0.94 g/g
Cr ................................ 0.57 g/g
Cu ................................. 7.7 g/g

F ...................................221 g/g
Hg..............................0.067 g/g
K ................................... 0.424 %
Mg ................................ 0.197 %
Mn ...............................10.2 g/g
Na................................. 0.582 %

Ni ................................ 1.03 g/g


Pb ............................... 1.96 g/g
Se ............................... 3.65 g/g
Sr ................................ 12.8 g/g
Zn................................. 138 g/g

Indicative values for Al, Au, Mo, P

22

Edition 2003/2004

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Fish
Code

NIST-2977

Product

Unit

Mussel tissue - Organics and trace elements

10 g

Standard Reference Material NIST-2744 is intended for use in evaluating analytical methods for the
determination of selected polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyl (PCB) congeners,
chlorinated pesticides, methylmercury, and inorganic constituents in marine bivalve mollusk tissue and similar
matrices. All the constituents for which certified and reference values are provided are naturally present in the
freeze-dried mussel tissue homogenate.
Certified concentrations for selected PAHs
Mass fraction
g/kg (dry mass basis)

Mass fraction
g/kg (dry mass basis)

Fluorene................................................ 10.24 0.43


Phenanthrene ........................................... 35.1 3.8
Fluoranthene............................................. 38.7 1.0
Pyrene....................................................... 78.9 3.5
Benzo(a)anthracene ............................. 20.34 0.78
Benzo(b)fluoranthene ........................... 11.01 0.28
Benzo(e)pyrene ........................................ 13.1 1.1

Benzo(a)pyrene....................................... 8.35 0.72


Perylene .................................................. 3.50 0.76
Benzo(ghi)perylene ................................. 9.53 0.43
Indeno(1,2,3-cd)pyrene ........................... 4.84 0.81
Dibenzo(a,h)anthracene.......................... 1.41 0.19
Benzo(b)chrysene ................................... 1.07 0.15
Picene ..................................................... 2.29 0.27

Certified concentrations for selected PCB congeners

PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB

Mass fraction
g/kg (dry mass basis)
8................2,4'-Dichlorobiphenyl ..................................................... 2.1 0.15
18..............2,2,5-Trichlorobiphenyl ............................................... 2.65 0.30
28..............2,4,4'-Trichlorobiphenyl ............................................... 5.37 0.44
31..............2,4',5-Trichlorobiphenyl ............................................... 3.92 0.24
44..............2,2',3,5'-Tetrachlorobiphenyl ....................................... 3.25 0.63
52..............2,2',5,5'-Tetrachlorobiphenyl ....................................... 8.37 0.54
66..............2,3',4,4'-Tetrachlorobiphenyl ....................................... 3.64 0.32
87..............2,2',3,4,5'-Pentachlorobiphenyl ................................... 2.15 0.10
95..............2,2',3,5,6'-Pentachlorobiphenyl ................................... 5.39 0.59
99..............2,2,4,4,5-Pentachlorobiphenyl ................................... 1.59 0.20
101............2,2',4,5,5'-Pentachlorobiphenyl+
90..............2,2,3,4,5-Pentachlorobipheny..................................... 11.2 1.2l
105............2,3,3',4,4-Pentachlorobiphenyl .................................... 3,76 0.49
110............2,3,3',4',6-Pentachlorobiphenyl .................................. 4.03 .0.20
118............2,3',4,4',5-Pentachlorobiphenyl ..................................... 10.5 1.0
128............2,2',3,3,4,4'-Hexachlorobiphenyl ................................. 2.49 0.28
138............2,2',3,4',5'-Hexachlorobiphenyl+
163............2,3,3',4',5,6-Hexachlorobiphenyl+
164............2,3,3',4',5',6-Hexachlorobiphenyl................................... 16.6 1.6
149............2,2',3,4',5',6-Hexachlorobiphenyl................................. 9.23 0.12
151............2,2',3,4,4',5-Hexachlorobiphenyl ................................. 3.07 0.18
153............2,2',4,4',5,5'-Hexachlorobiphenyl................................... 14.1 1.0
156............2,3,3',4,4',5-Hexachlorobiphenyl ............................. 0.960 0.085
170............2,2',3,3',4,4',5-Heptachlorobiphenyl ............................ 2.95 0.23
180............2,2',3,4,4',5,5'-Heptachlorobiphenyl ............................ 6.79 0.67
183............2,2',3,4,4',5',6-Heptachlorobiphenyl ............................ 1.33 0.10
187............2,2',3,4,5,5',6-Heptachlorobiphenyl+
159............2,3,3',4,5,5'-Hexachlorobiphenyl+
182............2,2',3',4,4',5,6'-Hexachlorobiphenyl ............................. 4.76 0.38
194............2,2',3,3',4,4',5,5'-Octachlorobiphenyl....................... 0.897 0.042

Certified concentrations for selected chlorinated pesticides


Mass fraction
g/kg (dry mass basis)

Mass fraction
g/kg (dry mass basis)

cis-Chlordane (alpha-Chlordane)............ 1.42 0.13


trans-Nonachlor ...................................... 1.43 0.10
Dieldrin.................................................... 6.04 0.52
4,4-DDE ................................................... 12.5 1.6

2,4'-DDD ................................................. 3.32 0.29


4,4-DDD ................................................. 4.30 0.38
4,4'-DDT.................................................. 1.28 0.18

Certified concentration of methylmercury


Mass fraction
g/kg (dry mass basis)
Methylmercury........................................... 36.2 1.7

Certified concentration for trace elements


Mass fraction
mg/kg (dry mass basis)

Mass fraction
mg/kg (dry mass basis)

Mass fraction
mg/kg (dry mass basis)

Cd ........................ 0.179 0.003


Cu ............................ 9.42 0.52

Pb .............................2.27 0.13
Mn ..........................23.93 0.29

Ni ........................... 46.06 0.24


Sr ............................... 69.3 4.2

Reference concentrations for PAHs.


Reference concentrations and informational values for inorganic constituents.

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Edition 2003/2004

23

Fish
Code

NIST-2978

Product

Unit

Mussel tissue - Organics and trace elements

10 g

Standard Reference Material NIST-2978 is intended for use in evaluating analytical methods for the
determination of selected polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyl (PCB) congeners
and chlorinated pesticides in marine bivalve mollusk tissue and similar matrices. All the constituents for which
certified and reference values are provided are naturally present in the freeze-dried mussel tissue.
Certified concentrations for selelcted PAHs
Mass fraction
g/kg (dry mass basis)

Mass fraction
g/kg (dry mass basis)

Fluoranthene............................................... 166 12
Pyrene......................................................... 256 21
Benzo(k)fluoranthene ............................... 24.1 3.4
Benzo(e)pyrene ........................................ 89.3 6.3

Perylene .................................................. 4.09 0.32


Benzo(ghi)perylene .................................. 19.7 .4.4
Indeno(1,2,3-cd)pyrene ............................. 12.2 2.9

Certified concentrations for selected PCB congeners


PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB

Mass fraction
(g/kg (dry mass basis)

28..............2,4,4'-Trichlorobiphenyl ............................................... 7.91 0.90


31..............2,4',5-Trichlorobiphenyl ............................................. 21.40 0.43
44..............2,2',3,5'-Tetrachlorobiphenyl ..................................... 11.80 0.64
49..............2,2,4,5-Tetrachlorobiphenyl ..................................... 16.84 0.86
52..............2,2',5,5'-Tetrachlorobiphenyl ......................................... 17.7 2.8
66..............2,3',4,4'-Tetrachlorobiphenyl ......................................... 18.4 1.5
87..............2,2',3,4,5'-Pentachlorobiphenyl ................................... 10.2 0.29
95..............2,2',3,5,6'-Pentachlorobiphenyl ..................................... 20.8 2.1
99..............2,2,4,4,5-Pentachlorobiphenyl ................................. 18.84 0.44
101............2,2',4,5,5'-Pentachlorobiphenyl+
90..............2,2,3,4,5-Pentachlorobiphenyl ..................................... 35.9 1.6
105............2,3,3',4,4-Pentachlorobiphenyl .................................. 10.85 0.45
110............2,3,3',4',6-Pentachlorobiphenyl ................................. 35.34 0.71
118............2,3',4,4',5-Pentachlorobiphenyl ..................................... 35.1 1.0
128............2,2',3,3,4,4'-Hexachlorobiphenyl ................................. 5.25 0.17
138............2,2',3,4,4',5'-Hexachlorobiphenyl+
163............2,3,3',4',5,6-Hexachlorobiphenyl+
164............2,3,3',4',5',6-Hexachlorobiphenyl................................... 35.7 1.5
149............2,2',3,4',5',6-Hexachlorobiphenyl............................... 34.73 0.69
151............2,2',3,4,4',5-Hexachlorobiphenyl ............................... 10.92 0.25
153............2,2',4,4',5,5'-Hexachlorobiphenyl................................... 56.9 3.5
156............2,3,3',4,4',5-Hexachlorobiphenyl ................................. 1.97 0.11
180............2,2',3,4,4',5,5'-Heptachlorobiphenyl ............................ 7.81 0.63
183............2,2',3,4,4',5',6-Heptachlorobiphenyl ............................ 5.25 0.15
187............2,2',3,4,5,5',6-Heptachlorobiphenyl+
159............2,3,3',4,5,5'-Hexachlorobiphenyl+
182............2,2',3',4,4',5,6'-Heptachlorobiphenyl.............................. 16.7 1.3

Certified concentrations for selected chlorinated pesticides


Mass fraction
g/kg (dry mass basis)

Mass fraction
g/kg (dry mass basis)

Oxychlordane.......................................... 2.13 0.27


cis-Chlordane (alpha-Chlordane).......... 15.56 0.83
trans-Chlordane (gamma-Chlordane)... 11.38 0.56
cis-Nonachlor.......................................... 8.23 0.56
trans-Nonachlor ........................................ 11.5 1.0
Dieldrin...................................................... 6.3 0.67

2,4-DDE ................................................. 4.41 0.56


4,4-DDE ................................................... 37.5 1.5
2,4'-DDD ................................................... 10.5 1.0
4,4-DDD ................................................... 38.8 2.3
2,4'-DDT...................................................... 9.2 1.6
4,4'-DDT.................................................. 3.84 0.28

Reference concentrations PAHs and PCBs

BCR-542

Mussel - dc-Saxitoxin
Compound

15 g
Certified value
(mg/kg)

Uncertainty
(mg/kg)

Saxitotin2HCl .................................................. <0.07


DC-Saxitoxin2HCl............................................. 1.59.......................... 0.20
These reference materials are dual usage materials and require special export/import documents under the
authority of IRMM.

BCR-543

Mussel - dc-Saxitoxin

15 g

Mussel material BCR-543 is intended to serve as an analytical blank or as a material enriched with the saxitoxin
enrichment solution (*BCR-663). As an analytical blank it may serve
- to establish recovery values for a method of analysis at various levels of contamination
- to check the specific background level of the laboratories methods.
BCR-543 enriched with saxitoxin enrichent solution (*BCR-663) may be used to validate the laboratorys own
methods.
Compound

Certified value
(mg/kg)

Uncertainty
(mg/kg)

Saxitoxin2HCl ................................................. <0.07


Saxitoxin2HCl ................................................... 0.48.......................... 0.06
DC-Saxitoxin2HCl........................................... <0.04
These reference materials are dual usage materials and require special export/ import documents under the
authority of IRMM.
*BCR-663 cannot yet be sold as it is restricted by the Chemical Weapon Convention.

24

Edition 2003/2004

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Fish
Code

NRCCRM-MUS-b

Product

Unit

Mussel tissue - Domoic acid (amnesic toxin)

8g

A homogenized slurry of mussel tissue (Mytilus edulis).


Certified values
Domoic acid ................... 36 g/g
Epidomoic acid ............. 3.0 g/g

NRCCRM-MUS-b

Mussel tissue - Domoic acid (amnesic toxin)

NRMGBW08572

Prawn - Trace elements

4x8g
8g

Certified values
Al................................... 0.131 %
As................................ 1.42 g/g
Ba ............................... 4.29 g/g
Ca ................................. 0.304 %
Cd ............................. 0.023 g/g
Cr ................................ 0.24 g/g
Cu ............................... 4.66 g/g

F ..................................5.31 g/g
Fe ................................19.8 g/g
Hg..............................0.201 g/g
K ................................... 0.597 %
Mg ................................ 0.160 %
Mn ...............................1.96 g/g
N..................................... 14.3 %

Na ................................. 0.381 %
P ................................... 0.845 %
Pb ............................. 0.298 g/g
Se ............................... 1.52 g/g
Sr ................................ 40.6 g/g
Zn................................ 60.8 g/g

Indicative values for Br, Co, S, Ti

NIST-1566b

Oyster Tissue - Trace elements and methyl mercury

25 g

This Standard Reference Material (SRM) is intended primarily for use in evaluating analytical methods and
instruments used for the determination of the concentrations of selected elements and proximates, selected fatty
acids, total dietary fiber, as well as the calorific content in marine bivalve tissue, foods, or similar materials. A unit
of NIST-1566b contains approximately 25 g of freeze-dried oyster tissue.
Certified values
Ca ............................................... 0.0838 0.0020 %
Cl ................................................... 0.514 0.010 %
Mg ............................................... 0.1085 0.0023 %
K ..................................................... 0.652 0.009 %
Na ............................................... 0.3297 0.0053 %
S ................................................. 0.6887 0.0140 %
Al...................................................197.2 6.0 mg/kg
As..................................................7.65 0.65 mg/kg
Cd .................................................2.48 0.08 mg/kg
Co .............................................0.371 0.009 mg/kg
Cu ...................................................71.6 1.6 mg/kg
Fe..................................................205.8 6.8 mg/kg

Pb............................................. 0.308 0.009 mg/kg


Mn .................................................. 18.5 0.2 mg/kg
Hg (total) .............................. 0.0371 0.0013 mg/kg
Methylmercury (as Hg) ......... 0.0132 0.0007 mg/kg
Ni.................................................. 1.04 0.09 mg/kg
Rb............................................. 3.262 0.145 mg/kg
Se................................................. 2.06 0.15 mg/kg
Ag............................................. 0.666 0.009 mg/kg
Th......................................... 0.0367 0.0043 mg/kg
V............................................... 0.577 0.023 mg/kg
Zn .................................................. 1 424 46 mg/kg

Indicative values for proximates, nitrogen, total dietary fiber, selected fatty acids (as triglycerides) and calories

NRCLUTS-1

Non-defatted Lobster Hepatopancreas - Trace elements and methyl mercury

6 x 10 g

Prepared from edible grade lobster tomalley. Except for the addition of some water and a small quantity of
antioxidant the sample is natural biological material containing 55 % lipids on a dry weight basis.
Certified values (As bottled)
Ag ..........................................................0.580 mg/kg
As.............................................................2.83 mg/kg
Ca .............................................................203 mg/kg
Cd ............................................................2.12 mg/kg
Co ..........................................................0.051 mg/kg
Cr ...........................................................0.079 mg/kg
Cu ............................................................15.9 mg/kg
Fe.............................................................11.6 mg/kg
Hg ........................................................0.0167 mg/kg

K............................................................... 948 mg/kg


Mg ........................................................... 89.5 mg/kg
Mn ........................................................... 1.20 mg/kg
Ni........................................................... 0.200 mg/kg
Pb.......................................................... 0.010 mg/kg
Se.......................................................... 0.641 mg/kg
Sr............................................................. 2.46 mg/kg
Zn ............................................................ 12.4 mg/kg
Methylmercury (as Hg) ........................ 0.0094 mg/kg

Certified values (Dry weight)


Ag ............................................................3.89 mg/kg
As.............................................................19.0 mg/kg
Ca ...........................................................1360 mg/kg
Cd ............................................................14.2 mg/kg
Co ............................................................0.34 mg/kg
Cr .............................................................0.53 mg/kg
Cu .............................................................107 mg/kg
Fe.............................................................77.8 mg/kg
Hg ..........................................................0.112 mg/kg

NRCTORT-2

K............................................................. 6360 mg/kg


Mg ............................................................ 601 mg/kg
Mn ........................................................... 8.02 mg/kg
Ni............................................................. 1.34 mg/kg
Pb.......................................................... 0.069 mg/kg
Se............................................................ 4.30 mg/kg
Sr............................................................. 16.5 mg/kg
Zn ............................................................ 82.9 mg/kg
Methylmercury (as Hg) .......................... 0.063 mg/kg

Lobster hepatopancreas - Trace elements and methyl mercury

35 g

Partially defatted lobster (Homarus americanus) hepatopancreas prepared from edible grade lobster tomalley.
Certified values
As.............................................................21.6 mg/kg
Cd ............................................................26.7 mg/kg
Co ............................................................0.51 mg/kg
Cr .............................................................0.77 mg/kg
Cu .............................................................106 mg/kg
Fe..............................................................105 mg/kg
Hg ............................................................0.27 mg/kg
Mn ............................................................13.6 mg/kg

Mo ........................................................... 0.95 mg/kg


Ni............................................................. 2.50 mg/kg
Pb............................................................ 0.35 mg/kg
Se............................................................ 5.63 mg/kg
Sr............................................................. 45.2 mg/kg
V.............................................................. 1.64 mg/kg
Zn ............................................................. 180 mg/kg
Methylmercury (as Hg) .......................... 0.152 mg/kg

Indicative values for Sn

www.lgcpromochem.com

Edition 2003/2004

25

Fish
Code

Product

Unit

Shellfish toxins
Not all hazardous substances found in foodstuffs are anthropogenic, and the shellfish toxins are a
case in point. These toxins, which are produced by algae, accumulate in various seafoods, and are
generally classified as follows:
Paralytic shellfish poisoning (PSP), has been known for centuries, and has caused many fatalities.
The toxins, a mixture of tetrahydropurines are named Saxitoxins after the basic toxin first isolated in
1957. They cause respiratory paralysis.
The toxins Okadaic acid and Dinophysistoxin are less dangerous and are known as Diarrehtic
shellfish poisons or DSP toxins.
In 1989 Quilliam and Wright reported on the difficulties of isolating and identifying the cause of the
Prince-Edward-Island-Disease. In this case more than 100 people became violently ill after eating
mussels. The survivors suffered from loss of memory. The toxin - Domoic acid - is known to be an
Amnesic shellfish poison (ASP).

Diarrhetic shellfish poisons (DSP)


NRCCRM-OA-b

Okadaic acid standard solution certified

0.5 mL

Each ampoule contains approximately 0.5 mL of solution with 30.0 0.9 moles/L (at 20 C) of Okadaic acid in
methanol.

NRCCRM-OA-b

Okadaic acid standard solution certified

4 x 0.5 mL

Paralytic shellfish poisons (PSP)


NRCCRM-STXdiAc Saxitoxin diacetate solution

0.2 mL

Each ampoule contains approximately 0.2 mL of solution with 480 20 moles/L of saxitoxin diacetate in filtered
and aqueous 0.1M acetic acid.

NRCCRM-STXdiAc Saxitoxin diacetate solution


NRCCRM-STX-d

4 x 0.2 mL

Saxitoxin dihydrochloride solution

0.5 mL

Each ampoule contains approximately 0.5 mL of solution with 65 3 moles/L (at 20C) of saxitoxin in filtered and
aqueous 0.003 M hydrochloric acid.

NRCCRM-STX-d
NRCCRM-dcSTX

Saxitoxin dihydrochloride solution

4 x 0.5 mL

Decarbamoylsaxitoxin solution

0.5 mL

Each ampoule contains approximately 0.5 mL of solution with 65 2 moles/L (at 20C) of decarbamoylsaxitoxin
in filtered and aqueous 0.003 M hydrochloric acid.

NRCCRM-dcSTX
NRCCRM-NEO-b

Decarbamoylsaxitoxin solution

4 x 0.5 mL

Neosaxitoxin solution

0.5 mL

Each ampoule contains approximately 0.5 mL of solution with 65 2 moles/L (at 20C) of neosaxitoxin in filtered
and aqueous 0.003 M hydrochloric acid.

NRCCRM-NEO-b

Neosaxitoxin solution

4 x 0.5 mL

NRCCRM-GTX14b Gonyautoxins-1 and -4 solution

0.5 mL

Each ampoule contains approximately 0.5 mL of solution with 106 5 moles/L (at 20C) of GTX1 and 35 2
moles/L (at 20C) of GTX4 in filtered and aqueous 0.003 M hydrochloric acid plus 0.01 M acetic acid.

NRCCRM-GTX14b Gonyautoxins-1 and -4 solution

4 x 0.5 mL

NRCCRM-GTX23b Gonyautoxins-2 and -3 solution

0.5 mL

Each ampoule contains approximately 0.5 mL of solution with 118 5 moles/L (at 20C) of GTX2 and 39 2
moles/L (at 20C) of GTX3 in filtered and aqueous 0.003 M hydrochloric acid plus 0.01 M acetic acid.

NRCCRM-GTX23b Gonyautoxins-2 and -3 solution


NRCCRM-GTX5b

4 x 0.5 mL

Gonyautoxins-5 solution

0.5 mL

Each ampoule contains approximately 0.5 mL of solution with 65 3 moles/L (at 20C) of GTX5 in filtered and
aqueous acetic acid.

NRCCRM-GTX5b

26

Gonyautoxins-5 solution

4 x 0.5 mL

Edition 2003/2004

www.lgcpromochem.com

Fish
Code

Product

Unit

Amnesic shellfish poisons (ASP)


NRCCRM-DA-d

Domoic acid solution

0.5 mL

Solvent: Acetonitrile/Water (1:9, v/v)


Certified values
Domoic acid +............. 89 0.9 g/g............... 87.7 0.9 g/mL (at 22C)............ moles/L (at 22C)
Epidomoic acid
Pure domoic acid in solution has been found to gradually isomerize, especially to the C5-diastereomer, epidomoic
acid; therefore, a mixture will inevitably result on long-term storage of any standard.
The densitiy of the solution is 0.9853 at 22C.

NRCCRM-DA-d

www.lgcpromochem.com

Domoic acid solution

4 x 0.5 mL

Edition 2003/2004

27

Fish
Code

Product

Unit

Fish
LGC7101

Mackerel paste - Proximates and nutrients

200 g

Prepared from whole mackerel fillets (including skin) mixed with water and 2% sodium caesinate.
Certified values
Cl ............................ 1500 mg/kg
K ............................. 1850 mg/kg
Na ........................... 1320 mg/kg

Moisture...................64.5 g/100g
Nitrogen...................2.25 g/100g
Total fat ...................20.4 g/100g

Ash......................... 0.83 g/100 g

Indicative values for Ca, Mg, P, Zn

BCR-422

Cod muscle - Trace elements and methyl mercury

7g

Certified values
As............................. 21.1 mg/kg
Cd .......................... 0.017 mg/kg
Cu ............................ 1.05 mg/kg
Fe............................. 5.46 mg/kg

BCR-463

Hg...........................0.559 mg/kg
I ................................4.95 mg/kg
Mn ..........................0.543 mg/kg
Pb ...........................0.085 mg/kg

Se ............................ 1.63 mg/kg


Zn............................. 19.6 mg/kg

Tuna fish - Total mercury and methyl mercury

15 g

Certified values
Methylmercury.......... 3.04 mg/kg
Total mercury........... 2.85 mg/kg

BCR-464

Tuna fish - Total mercury and methyl mercury

15 g

Certified values
Methylmercury.......... 5.50 mg/kg
Total mercury........... 5.24 mg/kg

BCR-349

Cod liver oil - PCBs


Compound

2g
Certified value
g/kg

Uncertainty
g/kg

PCB 28 ................................................................. 68............................... 7


PCB 52 ............................................................... 149............................. 20
PCB 101 ............................................................. 370............................. 17
PCB 118 ............................................................. 454............................. 31
PCB 153 ............................................................. 938............................. 40
PCB 180 ............................................................. 280............................. 22
Indicative values for PCB 44, PCB 128, PCB 138+PCB 163, PCB 194

BCR-598

Cod liver oil - Organochlorine pesticides


Compound

Certified Value
g/kg

5g
Uncertainty
g/kg

Hexachlorobenzene ........................................... 55.7............................... 2


alpha-HCH ............................................................ 42............................... 3
beta-HCH.............................................................. 16............................... 3
gamma-HCH......................................................... 23............................... 4
gamma-Chlordane ............................................... 6.9............................ 1.6
alpha-Chlordane ................................................ 24.4............................ 1.8
Oxychlordane........................................................ 11............................ 1.8
trans-Nonachlor .................................................... 39............................... 4
Dieldrin.................................................................. 59............................... 4
4,4-DDE ................................................... 0.61 x 103................. 0.04 x 103
2,4-DDD ............................................................... 30............................... 4
4,4-DDD ................................................... 0.40 x 103................. 0.03 x 103
4,4-DDT ................................................. 0.179 x 103............... 0.018 x 103

BCR-350

Mackerel oil - PCBs


Compound

2g
Certified value
g/kg

Uncertainty
g/kg

PCB 28 .............................................................. 22.5............................ 4.0


PCB 52 ................................................................. 62............................... 9
PCB 101 ............................................................. 164............................... 9
PCB 118 ............................................................. 142............................. 20
PCB 153 ............................................................. 317............................. 20
PCB 180 ............................................................... 73............................. 13
Indicative values for PCB44, PCB128, PCB138+PCB163

BCR-719

Canned fresh chub - PCBs

70 g

The material consists of approx. 70 g of minced sterilised muscle of chub to which butylhydroxy toluene (BHT)
was added as an antioxidant.
Certified values
PCB 77 .......... 0.196 x 103 ng/kg
PCB 81 ..................... 13.6 ng/kg

28

PCB 126....................20.0 ng/kg


PCB 169....................1.80 ng/kg

Edition 2003/2004

www.lgcpromochem.com

Fish
Code

BCR-718

Product

Unit

Canned fresh herring - PCBs

70 g

The material consists of approx. 70 g of minced sterilised muscle of herring to which butylhydroxy toluene (BHT)
was added as an antioxidant.
Certified values
PCB 28 ..................... 0.41 g/kg
PCB 52 ..................... 1.00 g/kg
PCB 101 ................... 2.12 g/kg
PCB 105 ................... 0.63 g/kg

BCR-627

PCB 118....................1.78 g/kg


PCB 128....................0.62 g/kg
PCB 138....................2.97 g/kg
PCB 149....................2.58 g/kg

PCB 153 ................... 4.62 g/kg


PCB 156 ................... 0.19 g/kg
PCB 170 ................... 0.35 g/kg
PCB 180 ................... 0.80 g/kg

Tuna fish tissue - As species

10 g

Certified values
Arsenobetaine..........................................52 mol/kg
Dimethylarsinic acid...................................2 mol/kg

total As ...................................................... 4.8 mg/kg

see also arsenobetaine standard solution (BCR-626)

MURST-ISS-A2

Antarctic krill - Trace elements

0.5 g

Prepared from three catches made by Italian, American and Japanese expeditions.
Certified values
As............................. 5.02 mg/kg
Cd ............................ 0.73 mg/kg
Co .......................... 0.110 mg/kg
Cu ............................ 65.2 mg/kg

Fe .............................56.6 mg/kg
Mn ............................4.12 mg/kg
Ni ..............................1.28 mg/kg
Pb .............................1.11 mg/kg

Se ............................ 7.37 mg/kg


Zn............................. 66.0 mg/kg

Indicative values for Ag, Al, Br, Ca, Cl, Cr, Hg, I, K, Mg, Na, Rb, Sc, Sn, Sr, V

NIST-1588a

Cod liver oil - Organics

set (5)

Set of 5 x 1.2 mL
This Standard Reference Material (SRM) is intended for use in developing and validating analytical methods for
the determination of chlorinated biphenyls and chlorinated pesticides in cod liver oil or in other similar lipophilic
matrices. The certified values for the PCB congeners and the chlorinated pesticides are based on the agreement
of results from two or more independent analytical techniques. NIST-1588 was analysed for selected PCB
congeners and chlorinated pesticides using gas chromatography with electron capture detector (GC-ECD) on two
columns with different selectivity and using GC with mass spectrometry (GC/MS). The concentration of alphatocopherol was determined using two methods based on normal-phase and reversed phase liquid
chromatography. Fluorescence detection was used for both methods.
Certified concentrations (mass fractions) for selected PCB congeners
g/kg
PCB 28 ................2,4,4'-Trichlorobiphenyl ............................................. 28.32 0.55
PCB 31 ................2,4',5-Trichlorobiphenyl ............................................... 8.33 0.28
PCB 44 ................2,2',3,5'-Tetrachlorobiphenyl ......................................... 35.1 1.4
PCB 49 ................2,2',4,5'-Tetrachlorobiphenyl ..................................... 29.90 0.84
PCB 52 ................2,2',5,5'-Tetrachlorobiphenyl ......................................... 83.3 2.3
PCB 66 ................2,3',4,4'-Tetrachlorobiphenyl ......................................... 54.7 1.5
PCB 87 ................2,2',3,4,5'-Pentachlorobiphenyl ..................................... 56.3 1.1
PCB 95 ................2,2',3,5,6'-Pentachlorobiphenyl ..................................... 36.5 1.1
PCB 101 ..............2,2',4,5,5'-Pentachlorobiphenyl ................................... 126.5 4.3
PCB 105 ..............2,3,3',4,4-Pentachlorobiphenyl ...................................... 60.2 2.3
PCB 110 ..............2,3,3',4',6-Pentachlorobiphenyl ..................................... 76.0 2.0
PCB 118 ..............2,3',4,4',5-Pentachlorobiphenyl ................................... 176.3 3.8
PCB 128 ..............2,2',3,3,4,4'-Hexachlorobiphenyl ................................... 47.0 2.4
PCB 138 ..............2,2',3,4',5'-Hexachlorobiphenyl+
PCB 163 ..............2,3,3',4',5,6-Hexachlorobiphenyl+
PCB 164 ..............2,3,3',4',5',6-Hexachlorobiphenyl................................... 263.59.1
PCB 149 ..............2,2',3,4',5',6-Hexachlorobiphenyl................................. 105.7 3.6
PCB 151 ..............2,2',3,4,4',5-Hexachlorobiphenyl ................................... 54.8 2.1
PCB 153 ..............2,2',4,4',5,5'-Hexachlorobiphenyl................................. 273.8 7.7
PCB 156 ..............2,3,3',4,4',5-Hexachlorobiphenyl ................................... 27.3 1.8
PCB 170 ..............2,2',3,3',4,4',5-Heptachlorobiphenyl .............................. 46.5 1.1
PCB 180 ..............2,2',3,4,4',5,5'-Heptachlorobiphenyl ............................ 105.0 5.2
PCB 183 ..............2,2',3,4,4',5',6-Heptachlorobiphenyl .......................... 31.21 0.62
PCB 187 ..............2,2',3,4,5,5',6-Heptachlorobiphenyl+
PCB 159 ..............2,3,3',4,5,5'-Hexachlorobiphenyl+
PCB 182 ..............2,2',3',4,4',5,6'-Hexachlorobiphenyl ........................... 35.23 0.83
PCB 194 ..............2,2',3,3',4,4',5,5'-Octachlorobiphenyl......................... 15.37 0.61
PCB 201 ..............2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl..................... 12.18 0.46
Certified concentrations (mass fractions) for selected chlorinated pesticides
g/kg

g/kg

2,4'-DDE ................................................... 22.0 1.0


4,4'-DDE ..................................................... 651 11
2,4'-DDD ................................................... 36.3 1.4
4,4'-DDD ..................................................... 254 11
2,4'-DDT.................................................. 156.0 4.4
4,4'-DDT...................................................... 524 12
Hexachlorobenzene ................................ 157.8 5.0

gamma-HCH ............................................. 24.9 1.7


alpha-HCH ................................................ 85.3 3.4
Heptachlor epoxide ................................... 31.6 1.5
cis-Chlordane.......................................... 167.0 5.0
cis-Nonachlor ............................................ 94.8 2.8
trans-Nonachlor....................................... 214.6 7.9
Dieldrin.................................................... 155.9 4.5

Reference concentration (mass fraction) for alpha-tocopherol and additional PCB congeners.
Information concentrations (mass fractions) for dibenzo-p-dioxins and octachlorodibenzofuran.

www.lgcpromochem.com

Edition 2003/2004

29

Fish
Code

NIST-1946

Product

Unit

Lake Superior fish tissue - Organic contaminants

5 x 10 g

This Standard Reference Material (SRM) is a frozen fish tissue homogenate, which was prepared from lake
trout (Salvelinus namaycush namaycush) collected from Lake Superior (U.S./Canada), and is intended primarily
for use in evaluating analytical methods for the determination of polychlorinated biphenyl (PCB) congeners,
chlorinated pesticides, fatty acids (including omega-3 fatty acids), extractable fat, methylmercury, total mercury
and selected trace elements in fish tissue and similar matrices.
Certified concentrations for selected PCB congeners
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB

Mass fraction
g/kg (dry mass basis)

44..............2,2',3,5'-Tetrachlorobiphenyl ....................................... 4.66 0.86


49..............2,2',4,5'-Tetrachlorobiphenyl ........................................ 3.80 0.39
52..............2,2',5,5'-Tetrachlorobiphenyl ........................................... 8.1 1.0
66..............2,3',4,4'-Tetrachlorobiphenyl ......................................... 10.8 1.9
70..............2,3',4',5-Tetrachlorobiphenyl ......................................... 14.9 0.6
74..............2,4,4',5-Tetrachlorobiphenyl ........................................ 4.83 0.51
77..............3,3',4,4'-Tetrachlorobiphenyl ................................... 0.327 0.025
87..............2,2',3,4,5'-Pentachlorobiphenyl ....................................... 9.4 1.4
95..............2,2',3,5',6-Pentachlorobiphenyl ..................................... 11.4 1.3
99..............2,2',4,4',5-Pentachlorobiphenyl ..................................... 25.6 2.3
101............2,2',4,5,5'-Pentachlorobiphenyl ..................................... 34.6 2.6
105............2,3,3',4,4'-Pentachlorobiphenyl ..................................... 19.9 0.9
110............2,3,3',4',6-Pentachlorobiphenyl ..................................... 22.8 2.0
118............2,3',4,4',5-Pentachlorobiphenyl ..................................... 52.1 1.0
126............3,3',4,4',5-Pentachlorobiphenyl ............................... 0.380 0.017
128............2,2',3,3',4,4'-Hexachlorobiphenyl................................... 22.8 1.9
138............2,2',3,4,4',5'-Hexachlorobiphenyl..................................... 115 13
146............2,2',3,4',5,5'-Hexachlorobiphenyl................................... 30.1 3.5
149............2,2',3,4',5',6-Hexachlorobiphenyl................................... 26.3 1.3
153............2,2',4,4',5,5'-Hexachlorobiphenyl....................................... 170 9
156............2,3,3',4,4',5-Hexachlorobiphenyl ................................. 9.52 0.51
169............2,2',3,4,4',5'-Hexachlorobiphenyl............................. 0.106 0.014
170............2,2',3,3',4,4',5-Heptachlorobiphenyl .............................. 25.2 2.2
180............2,2',3,4,4',5,5'-Heptachlorobiphenyl .............................. 74.4 4.0
183............2,2',3,4,4',5',6-Heptachlorobiphenyl .............................. 21.9 2.5
187............2,2',3,4',5,5',6-Heptachlorobiphenyl .............................. 55.2 2.1
194............2,2',3,3',4,4',5,5'-Octachlorobiphenyl............................. 13.0 1.3
195............2,2',3,3',4,4',5,6-Octachlorobiphenyl ........................... 5.30 0.45
206............2,2',3,3',4,4',5,5',6-Nonachlorobiphenyl....................... 5.40 0.43
209............Decachlorobiphenyl..................................................... 1.30 0.21

Certified concentrations for selected chlorinated pesticides


Mass fraction
g/kg (wet- mass basis)

Mass fraction
g/kg (wet- mass basis)

Hexachlorobenzene ................................ 7.25 0.83


alpha-HCH .............................................. 5.72 0.65
gamma-HCH........................................... 1.14 0.18
Heptachlor epoxide................................. 5.50 0.23
Oxychlordane............................................ 18.9 1.5
cis-Chlordane (alpha-Chlordane).............. 32.5 1.8
trans-Chlordane ...................................... 8.36 0.91
cis-Nonachlor............................................ 59.1 3.6

trans-Nonachlor......................................... 99.6 7.6


Dieldrin...................................................... 32.5 3.5
Mirex ....................................................... 6.47 0.77
4,4'-DDE...................................................... 373 48
2,4'-DDD ................................................. 2.20 0.25
4,4'-DDD ................................................... 17.7 2.8
4,4'-DDT.................................................... 37.2 3.5

Certified concentrations for fat and selected fatty acids

Mass fraction (%)


(wet- mass basis)

Fat (Extractable) ............................................................................................ 10.17 0.48


Fat (Sum of Fatty Acids) .................................................................................. 8.76 0.17
Mass fraction (%) (as the triglycerdide) (wet- mass basis)
Tetradecanoic acid (C14:0) ......................................................................... 0.316 0.009
(Myristic acid)
Hexadecanoic acid (C16:0) ............................................................................. 1.22 0.04
(Palmitic acid)
(Z)-9-Hexadecenoic acid (C16:1)................................................................. 0.816 0.026
(Palmitoleic acid)
Octadecanoic acid (C18:0) .......................................................................... 0.263 0.011
(Stearic acid)
(Z)-9-Octadecenoic acid (C18:1) ..................................................................... 2.64 0.08
(Oleic acid)c
(Z,Z)-9,12-Octadecadienoic acid (C18:2) .................................................... 0.348 0.023
(Linoleic acid)
(Z,Z,Z)-9,12,15-Octadecatrienoic acid (C18:3)............................................ 0.221 0.025
(Linolenic acid)
Eicosanoic acid (C20:0)........................................................................... 0.0100 0.0012
(Arachidic acid)
(Z)-11-Eicosenoic acid (C20:1).................................................................... 0.132 0.012
(Z,Z)-11,14-Eicosadienoic acid (C20:2)................................................... 0.0990 0.0043
(Z,Z,Z,Z,Z)-5,8,11,14,17-Eicosapentaenoic acid (C20:5) (EPA) ................. 0.296 0.019
(Z,Z,Z,Z,Z)-7,10,13,16,19-Docosapentaenoic acid (C22:5) (DPA).............. 0.335 0.026
(Z,Z,Z,Z,Z,Z)-4,7,10,13,16,19-Docosahexaenoic acid (C22:6) (DHA)............. 0.92 0.10
Certified concentrations for methylmercury, total mercury, arsenic and iron
Mass fraction
mg/kg (wet- mass basis)

Mass fraction
mg/kg (wet- mass basis)

Methylmercury..................................... 0.394 0.015


Hg (Total)............................................ 0.433 0.009

As ........................................................ 0.277 0.010


Fe ............................................................ 4.00 0.32

Reference concentrations for PCBs, pesticides, fatty acids, proximates and caloric content.

30

Edition 2003/2004

www.lgcpromochem.com

Fish
Code

IAEA-352

Product

Unit

Tuna fish - Radioactive isotopes

100 g

Certified values
137

210

40

210

Cs............................ 2.7 Bq/kg


K.............................. 391 Bq/kg

IAEA-MA-B3/R

Pb ........................... 0.6 Bq/kg


Po ........................... 2.2 Bq/kg

90

Sr.............................. 0.2 Bq/kg

Fish flesh - Radioactive isotopes

50 g

Certified values
137

Cs.......................... 14.2 Bq/kg

NRCDOLT-3

40

K ............................. 272 Bq/kg

Dogfish liver - Trace elements

25 g

Certified values
Ag ................. 1.20 0.07 mg/kg
Al..................... 24.7 1.9 mg/kg
As.................... 10.2 0.5 mg/kg
Cd ................... 19.4 0.6 mg/kg

Cu....................31.2 1.0 mg/kg


Fe ....................1484 57 mg/kg
Hg..................3.37 0.14 mg/kg
Ni ...................2.72 0.35 mg/kg

Pb ............. 0.319 0.045 mg/kg


Se ................. 7.06 0.48 mg/kg
Zn.................... 86.6 2.4 mg/kg

Indicative value for Cr, Sn, Methylmercury

NRCDORM-2

Dogfish muscle - Trace elements

40 g

Certified values
Ag .......................... 0.041 mg/kg
Al.............................. 10.9 mg/kg
As............................. 18.0 mg/kg
Cd .......................... 0.043 mg/kg
Co .......................... 0.182 mg/kg

Cr..............................34.7 mg/kg
Cu.............................2.34 mg/kg
Fe ..............................142 mg/kg
Hg.............................4.64 mg/kg
Mn ............................3.66 mg/kg

Ni ............................. 19.4 mg/kg


Pb .......................... 0.065 mg/kg
Se ............................ 1.40 mg/kg
Zn............................. 25.6 mg/kg
Methylmercury.......... 4.47 mg/kg

Indicative values for Sn, Tl

NRCCARP-2

Fish (common carp) - Dioxins, furans and PCBs

6 x 10 g

Prepared from common carp (Cyprinus carpio) collected near the warm water discharge of the Consumers Power
Plant in Saginaw Bay, Lake Huron, Canada
Certified values
PCB18 ...................... 27.3 g/kg
PCB28 ...................... 34.0 g/kg
PCB44 ...................... 86.6 g/kg
PCB52 ....................... 138 g/kg

PCB118......................148 g/kg
PCB128.....................20.4 g/kg
PCB153......................105 g/kg
PCB180.....................53.3 g/kg

PCB194 .................... 10.9 g/kg


PCB206 ...................... 4.4 g/kg

Reference Values
2,3,7,8-TCDF ............................................18.2 ng/kg
1,2,3,7,8-PCDF...........................................5.6 ng/kg
2,3,7,8-TCDD..............................................7.4 ng/kg
1,2,3,7,8-PCDD ..........................................5.3 ng/kg
1,2,3,4,7,8-HxCDD .....................................1.6 ng/kg

1,2,3,6,7,8-HxCDD..................................... 5.8 ng/kg


1,2,3,7,8,9-HxCDD................................... 0.78 ng/kg
1,2,3,4,6,7,8-HpCDD ................................. 6.4 ng/kg
OCDD ........................................................ 9.4 ng/kg

Other reference concentrations for selected PCB congeners and pesticides are given in the certificate.

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31

Cereals and crops

Cereals and crops


Code

Product

Unit

Wheat
LGC7003

White bread flour - Nutrients and trace elements

25 g

Certified values
Ash................................... 0.84%
Fat...................................... 1.7%
N ...................................... 2.43%

BCR-189

Ca............................1120 mg/kg
Fe ................................23 mg/kg
K ..............................1720 mg/kg

Na ............................... 39 mg/kg
Zn................................ 12 mg/kg

Wholemeal flour - Trace elements

25 g

Certified values
Cd ............................. 71.3 g/kg
Cu .............................. 6.4 mg/kg
Fe............................. 68.3 mg/kg

Mn ............................63.3 mg/kg
Pd ...............................379 g/kg
Se ...............................132 g/kg

Zn............................. 56.5 mg/kg

Indicative values for Ca, Cl, Cr, Hg, K, Mg, Na, Ni, P

NIST-1567a

Wheat flour - Trace elements

80 g

Milled from a blend of Hard Red Spring and Hard Red Winter wheat.
Certified values
Al................................... 5.7 g/g
Ca ................................. 0.191 %
Cd ............................. 0.026 g/g
Cu ................................. 2.1 g/g
Fe................................ 14.1 g/g

K ................................... 0.133 %
Mg ................................ 0.040 %
Mn .................................9.4 g/g
Mo ...............................0.48 g/g
Na..................................6.1 g/g

P ................................... 0.134 %
Rb ............................... 0.68 g/g
S ................................... 0.165 %
Se ................................. 1.1 g/g
Zn................................ 11.6 g/g

Indicative values for As, Br, Cl, Co, Hg, I, Pb, Sn, U, V, W

NIST-RM 8437

Hard red spring wheat flour - Trace elements

2 x 25 g

Reference concentration values for major, minor and trace elements.


Indicative values for additional elements.

BCR-382

Wheat flour - Major nutrients

100 g

Certified values (percentage by dry mass)


Ash.................................................................... 0.9%
Fat..................................................................... 1.3%

N (Kjeldahl) ....................................................... 2.1%


Dietary fibre (AOAC 1985/1988) ....................... 3.3%

Indicative values for starch, starch & sugars and dietary fibre (Englyst)

BCR-121

Wholemeal flour - Vitamins

50 g

Certified values
B1 (thiamin) .............................................4.63 mg/kg
B6 (total pyridoxine) .................................4.10 mg/kg

BCR-563

Folate (total) .............................................. 0.5 mg/kg

Common wheat flour - Properties

360 g

Certified parameters determined according to ISO and ICC standard: Protein content, Ash content, Falling
number / s, Zeleny sedimentation, Chopin Alveograph, Brabender Farinograph, Brabender Extensograph.

NIST-RM 8436

Durum wheat flour - Trace elements and nutritional properties

50 g

Reference concentration values for major, minor and trace elements, proximates, total dietary fibre and calories.
Indicative values for additional elements and one fatty acid.

NIST-RM 8437

Hard red spring wheat flour - Trace elements

2 x 25 g

Reference concentration values for major, minor and trace elements.


Indicative values for additional elements.

NIST-RM 8438

Soft winter wheat flour - Trace elements

2 x 50 g

Reference concentration values for major, minor and trace elements.


Indicative values for additional elements

NIST-RM 8418

Wheat gluten - Trace elements and nutritional properties

50 g

Reference concentration values for major, minor and trace elements, proximates, calories and fatty acid.
Indicative values for additional elements fatty acids and total dietary fibre.

NRMGBW08503

Wheat flour - Trace elements

20 g

Certified values
As................................ 0.22 g/g
Ca ................................ 441 g/g
Cd ............................. 0.031 g/g
Cu ............................... 4.40 g/g

Fe ................................39.8 g/g
K ................................... 0.198 %
Mg ................................551 g/g
Mn ...............................19.6 g/g

Pb ............................... 0.35 g/g


Zn................................ 22.7 g/g

Indicative values for N, P, Se, Na

32

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Cereals and crops


Code

BCR-396

Product

Unit

Wheat flour - Deoxynivalenol (DON) blank

150 g

Certified value
DON...................... < 0.05 mg/kg

BCR-471

Wheat - Ochratoxin A (blank)

55 g

Certified value
Ochratoxin A ............ < 0.6 g/kg

BCR-472

Wheat - Ochratoxin A (medium level)

55 g

Certified value
Ochratoxin A ............... 8.2 g/kg

NIST-RM 8441

Wheat - Hardness

set (50)

Set of 50 x 20 g
Determination of hardness of bulk or single kernel wheat. Ten separate lots of wheat of varying hardness. Five
samples of each wheat .

Corn
BCR-377

Maize flour - Deoxynivalenol (blank)

150 g

Certified value
DON....................... <0.05 mg/kg

BCR-378

Maize flour - Deoxynivalenol (medium level)

150 g

Certified value
DON......................... 0.43 mg/kg

NIST-RM 8432

Corn starch - Trace elements and nutritional properities

50 g

Reference concentration values for major, minor and trace elements, proximates, total dietary fibre and calories.
Indicative values for additional elements, ash and fatty acids.

NIST-RM 8433

Corn bran - Trace elements and nutritional properties

50 g

Reference concentration values for major, minor and trace elements, proximates, total dietary fibre and calories.
Indicative values for additional elements, fat and fatty acids.

NIST-RM 8412

Corn (Zea Mays) stalk - Trace elements

34 g

Reference concentration values for major, minor and trace elements. Indicative values for additional elements.

NIST-RM 8413

Corn (Zea Mays) kernel - Trace elements

47 g

Reference values for Al, Ca, Cl, Cu, F, I, K, Mg, Mn, N, Se, Zn

Rye
BCR-381

Rye flour - Major nutrients

100 g

Certified values (percentage by dry mass)


Ash.................................................................... 0.9%
Fat..................................................................... 1.1%

N (Kjeldahl) ....................................................... 1.3%


Dietary fibre (AOAC 1985/1988) ....................... 8.2%

Indicative values for starch, starch & sugars, dietary fibre (Englyst)

IAEA-V-8

Rye flour - Trace elements

50 g

Certified values
Br ............................. 0.38 mg/kg
Ca ............................. 149 mg/kg
Cl .............................. 570 mg/kg
Cu ............................ 0.95 mg/kg

Fe ...............................4.1 mg/kg
K ..............................1925 mg/kg
Mg .............................121 mg/kg
Mn ............................2.06 mg/kg

P ............................... 592 mg/kg


Rb ............................ 0.48 mg/kg
Zn............................. 2.53 mg/kg

Indicative values for Cd, Co, Na

Rice
BCR-465

Rice flour - Amylose (low level)

10 g

Certified value
Amylose ................. 15.4 g/100 g

BCR-466

Rice flour - Amylose (medium level)

10 g

Certified value
Amylose ................. 23.1 g/100 g

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Edition 2003/2004

33

Cereals and crops


Code

BCR-467

Product

Unit

Rice flour - Amylose (high level)

10 g

Certified value
Amylose ................. 27.7 g/100 g

NIST-1568a

Rice Flour - Trace elements

80 g

Produced from 100% long grain rice from Arkansas.


Certified values
Al................................... 4.4 g/g
As................................ 0.29 g/g
Ca ............................... 0.0118 %
Cd ............................. 0.022 g/g
Cu ................................. 2.4 g/g
Fe.................................. 7.4 g/g

Hg....................................0.0058
K ................................. 0.1280 %
Mg ............................... 0.056 %
Mn ...............................20.0 g/g
Mo ...............................1.46 g/g
Na..................................6.1 g/g

P ................................... 0.134 %
Rb ............................... 6.14 g/g
S ................................... 0.120 %
Se ............................... 0.38 g/g
Zn................................ 19.4 g/g

Indicative values for Br, Cl, Co, I, Pb, Sb, Sn, U, V, W

NRMGBW08508

Rice - Trace elements

40 g

Certified values
Cu ................................. 3.6 g/g
F.................................. 18.0 g/g

NRMGBW08510

Fe ................................43.2 g/g
Hg..............................0.038 g/g

Mg ............................... 28.4 g/g

Rice - Trace elements

40 g

Certified values
Cu ................................. 3.6 g/g
F.................................. 18.0 g/g

NRMGBW08511

Fe ................................43.2 g/g
Hg..............................0.038 g/g

Mg ............................... 28.4 g/g

Rice - Cadmium (medium level)

40 g

Certified value
Cd ............................. 0.504 g/g

NRMGBW08512

Rice - Cadmium (low level)

40 g

Certified value
Cd ........................... 0.0069 g/g

Rapeseed
BCR-190R

Rapeseed (colza) - Total glucosinolate and sulphur

20 g

Certified values
Total glucosinolate..................................23 mmol/kg

BCR-366R

S................................................................. 4.72 g/kg

Rapeseed (colza) - Total glucosinolate and sulphur

20 g

Certified values
Total glucosinolate...............................11.9 mmol/kg

BCR-367R

S................................................................. 3.31 g/kg

Rapeseed (colza) - Total glucosinolate and sulphur

20 g

Certified values
Total glucosinolate................................102 mmol/kg

S................................................................. 10.5 g/kg

Indicative values for individual glucosinolates

BCR-446

Rapeseed - Oil content (low)

153 g

Certified values
As is oil ............................................. 39.49 g/100 g
Moisture and volatiles ........................... 7.01 g/100 g
Dry basis oil ........................................ 42.48 g/100 g

BCR-447

Rapeseed - Oil content (medium)

153 g

Certified values
As is oil ............................................. 41.99 g/100 g
Moisture and volatiles ........................... 7.42 g/100 g
Dry basis oil ........................................ 45.36 g/100 g

BCR-448

Rapeseed - Oil content (high)

153 g

Certified values
As is oil ............................................. 45.43 g/100 g
Moisture and volatiles ........................... 7.68 g/100 g
Dry basis oil ........................................ 49.21 g/100 g

34

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Cereals and crops


Code

Product

Unit

Genetically modified crops


IRMM-410S0 - IRMM-410S5
TM

Dried soya bean powder with different mass fractions of genetically modified (Roundup Ready )
soya beans, intended for validation of the polymerase chain reaction (PCR) screening method for the
detection of GM food.
IRMM-410S0

Genetically modified soya beans (0%)

1g

Certified mass fraction GMO < 0.03%

IRMM-410S1

Genetically modified soya beans (0.1%)

1g

Certified mass fraction GMO: 0.1 %

IRMM-410S2

Genetically modified soya beans (0.5%)

1g

Certified mass fraction GMO: 0.5%

IRMM-410S3

Genetically modified soya beans (1%)

1g

Certified mass fraction GMO: 1%

IRMM-410S4

Genetically modified soya beans (2%)

1g

Certified mass fraction GMO: 2%

IRMM-410S5

Genetically modified soya beans (5%)

1g

Certified mass fraction GMO: 5%

IRMM-413-0 - IRMM-413-5
Dried maize powder with different mass fractions (<0.02, 0.1, 0.5, 1, 2, 5 %) of genetically modified
maize (MON810), intended for the validation of methods for the detection of genetically modified food.
As DNA and/or protein based GMO quantification may depend on varieties, one has to be careful to
draw quantitative conclusions from measurements of unknown samples.
IRMM-413-0

Genetically modified MON-810 maize powder (0%)

1g

Certified mass fraction GMO <0.02 %

IRMM-413-1

Genetically modified MON-810 maize powder (0.1%)

1g

Certified mass fraction GMO: 0.1% 0.03

IRMM-413-2

Genetically modified MON-810 maize powder (0.5%)

1g

Certified mass fraction GMO: 0.50 % 0.04

IRMM-413-3

Genetically modified MON-810 maize powder (1%)

1g

Certified mass fraction GMO: 1 % 0.05

IRMM-413-4

Genetically modified MON-810 maize powder (2%)

1g

Certified mass fraction GMO: 2% 0.1

IRMM-413-5

Genetically modified MON-810 maize powder (5%)

1g

Certified mass fraction GMO: 5% 0.2

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Edition 2003/2004

35

Vegetable matter

Vegetable matter
Code

Product

Unit

Fruit and vegetables


LGC7111

Potato powder - Sulphur dioxide

200 g

Certified value
SO2 ........................ 357.5 mg/kg

LGC7162

Strawberry leaves - Trace elements

20 g

The raw material was collected from a private farm in the Czech Republic. The mixture was cut and jet milled to
pass a 250 m nylon sieve. The resulting powder was homogenised, separated in 20 g portions and placed in
60mL bottles.
Certified Values
Ca .......................... 1.53 g/100 g
Mg ........................ 0.377 g/100 g
N ............................ 2.01 g/100 g
P .......................... 0.260 g/100 g
K ............................ 1.96 g/100 g
S .......................... 0.174 g/100 g

BCR-515

As .............................0.28 mg/kg
Ba ..............................107 mg/kg
Cd.............................0.17 mg/kg
Co.............................0.47 mg/kg
Cr..............................2.15 mg/kg
Fe ..............................818 mg/kg

Pb .............................. 1.8 mg/kg


Mn ............................. 171 mg/kg
Hg .......................... 0.027 mg/kg
Ni ............................... 2.6 mg/kg
Sr ................................ 64 mg/kg
Zn................................ 24 mg/kg

Carrot - Dietary fibre

25 g

Certified using five different methods of dietary fibre analysis


Certified values
AOAC 1990........................................... 31.1 g/100 g
Englyst (GC) ......................................... 27.1 g/100 g
Uppsala................................................. 29.8 g/100 g

ARC/CL4

AOAC 1992 MES-TRIS......................... 29.5 g/100 g


Englyst (colorimetry) ............................. 25.2 g/100 g

Carrot powder - Total dietary fibre and trace elements

60 g

Prepared from normal commercially available carrot flakes used by the Finnish food industry.
Certified values
Total dietary fibre ........... 10.93%
B ................................. 10.1 g/g
Ca .............................. 1700 g/g
Cd ............................... 68.6 ng/g

BCR-383

Fe ................................12.6 g/g
K .................................10.2 mg/g
Mg ................................350 g/g
Mn ...............................4.90 g/g

Mo ............................... 49.5 ng/g


Na ................................ 485 g/g
Zn.................................. 6.9 g/g

Haricots verts (beans) - Major nutrients

100 g

Certified values
N(Kjeldahl) .............................................. 1.1 g/100 g
Dietary fibre (AOAC 1985/1988)........... 11.9 g/100 g
Ash at 550C............................................ 2.4 g/100g

Ca............................................................ 2.9 g/100 g


K.............................................................. 7.8 g/100 g
Na.......................................................... 0.08 g/100 g

Indicative values for glucose, fructose, sucrose, starch + sugars, dietary fibre (Englyst)

BCR-514

Haricots beans - Dietary fibre

25 g

Certified using five different methods of dietary fibre analysis


Certified values
AOAC 1990........................................... 25.6 g/100 g
Englyst (GC) ......................................... 19.8 g/100 g
Uppsala................................................. 23.7 g/100 g

BCR-431

AOAC 1992 MES-TRIS......................... 25.9 g/100 g


Englyst (colorimetry) ............................. 20.1 g/100 g

Brussels sprout - Vitamins

20 g

Certified values
C (total ascorbate) .. 4830 mg/kg
Niacin.......................... 43 mg/kg

BCR-485

Mixed vegetables - Vitamins

25 g

Certified values
B1 (thiamin) .............. 3.07 mg/kg
B6 (total pyridoxine).... 4.8 mg/kg
folate (total).............. 3.15 mg/kg

BCR-517

trans--carotene.......10.5 mg/kg
trans--carotene .......23.7 mg/kg
total--carotene ..........9.8 mg/kg

total--carotene........ 25.6 mg/kg


lutein ........................ 12.5 mg/kg
lutein+zeaxanthin..... 22.3 mg/kg

Full fat soya - Dietary fibre

25 g

Certified using five different methods of dietary fibre analysis


Certified values
AOAC 1990........................................... 12.6 g/100 g
Englyst (GC) ......................................... 11.9 g/100 g
Uppsala................................................. 12.8 g/100 g

36

AOAC 1992 MES-TRIS......................... 12.4 g/100 g


Englyst (colorimetry) ............................. 12.3 g/100 g

Edition 2003/2004

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Vegetable matter
Code

BCR-516

Product

Unit

Apple - Dietary fibre

25 g

Certified using five different methods of dietary fibre analysis


Certified values
AOAC 1990......................................... 16.46 g/100 g
Englyst (GC) ......................................... 13.7 g/100 g
Uppsala.................................................. 16.2 g/100g

BCR-679

AOAC 1992 MES-TRIS......................... 14.9 g/100 g


Englyst (colorimetry) ............................. 13.4 g/100 g

White cabbage - Trace elements

15 g

Certified values
As................................ 7.0 g/kg
B .............................. 27.7 mg/kg
Ba ............................ 10.3 mg/kg
Cd ............................ 1.66 mg/kg
Cu ............................ 2.89 mg/kg

BCR-401

Fe ..............................55.0 g/kg
Hg................................6.3 g/kg
Mo ............................14.8 mg/kg
Ni ..............................27.0 mg/kg
Sb ..............................20.6 g/kg

Sr ............................. 11.8 mg/kg


Tl............................... 2.98 g/kg
Zn............................. 79.7 mg/kg

Peanut butter (blank) - Aflatoxin B1

50 g

Certified values
Aflatoxin B1............... <0.2 g/kg
Aflatoxin B2............... <0.1 g/kg

BCR-262

Aflatoxin G1...............<0.1 g/kg


Aflatoxin G2...............<0.1 g/kg

Total Aflatoxins ......... <0.5 g/kg

Defatted peanut meal (blank) - Aflatoxin B1

100 g

Certified value
Aflatoxin B1.................. <3 g/kg

BCR-264

Defatted peanut meal (high level) - Aflatoxin B1

150 g

Certified value
Aflatoxin B1................ 206 g/kg

IC-INCT-TL-1

Tea leaves - Trace elements

50 g

The material was prepared from black tea, usually packed in tea bags.
Certified values
Al.............................. 0.229 wt %
As........................... 0.106 mg/kg
Ba ............................ 43.2 mg/kg
Br ............................. 12.3 mg/kg
Ca ............................ 0.582 wt %
Cd .......................... 0.030 mg/kg
Cl .............................. 573 mg/kg
Co .......................... 0.387 mg/kg
Cr ............................. 1.91 mg/kg
Cs ............................ 3.61 mg/kg
Cu ............................ 20.4 mg/kg

Eu ...........................0,050 mg/kg
Hg...........................0.005 mg/kg
K ................................. 1.70 wt %
La .............................1.00 mg/kg
Lu ...........................0.016 mg/kg
Mg ............................ 0.224 wt %
Mn ............................ 0.157 wt %
Na.............................24.7 mg/kg
Ni ..............................6.12 mg/kg
Pb .............................1.78 mg/kg
Rb.............................81.5 mg/kg

Sc........................... 0.266 mg/kg


Sm ......................... 0.177 mg/kg
Sr ............................. 20.8 mg/kg
Tb........................... 0.026 mg/kg
Th........................... 0.034 mg/kg
Tl............................ 0.063 mg/kg
V .............................. 1.97 mg/kg
Yb........................... 0.118 mg/kg
Zn............................. 34.7 mg/kg

Indicative values for B, Fe, Hf, Nd, P, Sb, Se, Ta, Ti and Tm

NRMGBW07605

Tea - Trace elements

35 g

Certified values
As................................ 0.28 g/g
B .................................... 15 g/g
Ba .................................. 58 g/g
Be ............................. 0.034 g/g
Bi............................... 0.063 g/g
Br .................................. 3.4 g/g
Ca ................................... 0.43 %
Cd ............................. 0.057 g/g
Ce ................................. 1.0 g/g
Co ............................... 0.18 g/g
Cr .................................. 0.8 g/g
Cs ............................... 0.29 g/g

Cu................................17.3 g/g
Eu ..............................0.018 g/g
F ...................................320 g/g
Fe .................................264 g/g
K ..................................... 1.66 %
Mg .................................. 0.17 %
Mn ..............................1240 g/g
Mo .............................0.038 g/g
N..................................... 3.32 %
Na...................................44 g/g
Ni ...................................4.6 g/g
P .................................2840 g/g

Pb ................................. 4.4 g/g


Rb .................................. 74 g/g
S ................................... 0.245 %
Sb ............................. 0.056 g/g
Sc.............................. 0.085 g/g
Sm ............................ 0.085 g/g
Sr ................................ 15.2 g/g
Th.............................. 0.061 g/g
Ti.................................... 24 g/g
Y.................................. 0.36 g/g
Yb.............................. 0.044 g/g
Zn................................ 26.3 g/g

Indicative values for Ag, Al, Dy, Gd, Hf, Hg, Ho, Li, Lu, Nd, Pr, Se, Si, Tb, V

SLV FUNGUS

Edible fungus (C.tubaeformis) - Trace elements

7g

Certified values
Cd .......................... 0.437 mg/kg
Co .......................... 0.073 mg/kg
Cr ........................... 0.223 mg/kg

IAEA-359

Cu.............................34.4 mg/kg
Fe ..............................101 mg/kg
Mn ............................49.9 mg/kg

Ni ........................... 0.381 mg/kg


Pb ............................ 1.43 mg/kg
Zn............................. 55.0 mg/kg

Cabbage - Trace elements

30 g

Certified values
Al................................ 0.1 mg/kg
Ba ............................... 11 mg/kg
Ca ......................... 18500 mg/kg
Cd ............................ 0.12 mg/kg
Cr ............................... 1.3 mg/kg
Cu ............................ 5.67 mg/kg

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Fe ..............................148 mg/kg
Hg...........................0.013 mg/kg
K ............................32500 mg/kg
Mg ...........................2160 mg/kg
Mn ............................31.9 mg/kg
Na..............................580 mg/kg

Edition 2003/2004

Ni ............................. 1.05 mg/kg


Se ............................ 0.12 mg/kg
Sr ............................. 49.2 mg/kg
Zn............................. 38.6 mg/kg

37

Vegetable matter
Code

BCR-400

Product

Unit

Red ceramic tile (Tomato paste colour)

tile

100 mm x 100 mm
A ceramic tile the colour of which is defined by Hunter L, a and b values. Each tile is individually certified. The tile
is intended for the purpose of calibration and does not represent a standard tomato paste colour.
Nominal Hunter values: L 26, a 33, b 14.5

Vegetable oils
LGC7120 (RM)

Corn oil - BHA and BHT

5 x 25 mL

Commercial corn oil with added BHA and BHT


Assesed values
BHA ......................... 49.4 mg/kg

LGC7122-23

BHT ..........................49.7 mg/kg

Olive oil - Tocopherol

2 x 25 mL

LGC7122
Certified value
alpha-tocopherol ...... 72.1 mg/kg
LGC7123
Certified value
alpha-tocopherol .... 173.6 mg/kg

BCR-458

Coconut oil - PAHs (doped)


Compound

45 g
Certified value
g/kg

Uncertainty
g/kg

Pyrene.................................................................. 9.4............................ 1.5


Chrysene.............................................................. 4.9............................ 0.4
Benzo(k)fluoranthene ........................................ 1.87.......................... 0.18
Benzo(a)pyrene ................................................. 0.93.......................... 0.09
Benzo(ghi)perylene............................................ 0.97.......................... 0.07
Indeno(1,2,3-cd)pyrene...................................... 1.00.......................... 0.07

BCR-459

Coconut oil - PAHs (blank)


Compound

45 g
Certified value
g/kg

Pyrene................................................................ <0.9
Chrysene............................................................ <0.6
Benzo(k)fluoranthene ........................................ <0.2

NIST-1563

Compound

Certified value
g/kg

Benzo(a)pyrene.................................................. <0.3
Benzo(ghi)perylene ............................................ <0.2
Indeno(1,2,3-cd)pyrene ...................................... <0.2

Coconut oil - Cholesterol and fat-soluble vitamins

set (10)

This Standard Reference Material (SRM) is intended primarily for use in the development and validation of
analytical methods for the determination of cholesterol, fat-soluble vitamins, fat, and fatty acids in a lipid matrix.
NIST-1563 consists of ten ampoules per unit: five ampoules of natural coconut oil (1563-1) and five ampoules of
fortified coconut oil (1563-2). Each ampoule contains approximately 4 mL of oil.
Mass fraction
(mg/kg)

Concentration
(mg/L)

Cholesterol........................................... 638 8 ............................... 585 6


dl-alpha-Tocopheryl acetate ................ 158 6 ............................... 145 6
Reference values for fat and fatty acids, cholesterol and vitamins

BCR-537

Plastic film A - Overall migration in olive oil

film

Total immersion in olive oil for 10 days at 40C


Certified value: 8.3 mg/dm2

BCR-538

Plastic film B - Overall migration in olive oil

film

Single sided cell in olive oil for 10 days at 40C


Certified value: 5.7 mg/dm2

BCR-539

Plastic film C - Overall migration in olive oil

film

Pouch in olive oil for 10 days at 40C


Certified value: 6.1 mg/dm2

BCR-593

Plastic film E

film

120 cm x 20 cm
Directive 90/128/EEC on plastic materials and articles intended for food contact regulates the limits of overall
migration of specific substances into foodstuff. BCR-593 has been prepared to check the performance of the
standard test procedure of film thickness, required for the evaluation of migration tendency.
Certified values
Fat soluble fluorescent additive (1,4-diphenyl-1,3-butadiene) .................................... 12.58 mg/kg
Film thickness ............................................................................................................. 149.7 m

38

Edition 2003/2004

www.lgcpromochem.com

Mycotoxins

Mycotoxins
Code

Product

Unit

Single compounds
B-MYC0340

3-Acetyl-deoxynivalenol (3-AcDON) 100 g/mL in acetonitrile

5 mL

B-MYC0340-C

3-Acetyl-deoxynivalenol

5 mg

B-MYC0360

15-Acetyl-deoxynivalenol (15-AcDON) 100 g/mL in acetonitrile

5 mL

B-MYC0360-C

15-Acetyl-deoxynivalenol

5 mg

CSIR-MYC 024

Acgroclavine

10 mg

CSIR-MYC 025

Acroclavine I

10 mg

B-MYC0200

Aflatoxin B1 2 g/mL in acetonitrile

5 mL

B-MYC0220

Aflatoxin B2 0.5 g/mL in acetonitrile

5 mL

B-MYC0240

Aflatoxin G1 2 g/mL in acetonitrile

5 mL

B-MYC0260

Aflatoxin G2 0.5 g/mL in acetonitrile

5 mL

B-MYC0280

Aflatoxin M2 0.5 g/mL in acetonitrile

5 mL

BCR-423 (RM)

Aflatoxin M1 standard solution

2.5 mL

9.93 g/mL in chloroform

RH36976

Aflatoxin M1 0.5 g/mL in methanol OEKANAL

CSIR-MYC 005

Austdiol

10 mg

CSIR-MYC 006

Austocystin A

10 mg

CSIR-MYC 026

Chanoclavine I

10 mg

CSIR-MYC 007

Cytochalasin B

10 mg

CSIR-MYC 008

Cytochalasin H

10 mg

CSIR-MYC 009

Cytochalasin J

10 mg

B-MYC0320

Deoxynivalenol (DON) 100 g/mL in acetonitrile

5 mL

B-MYC0320-C

Deoxynivalenol

5 mg

CSIR-MYC 027

Dimer epoxyagroclavine-I-tartrate

10 mg

CSIR-MYC 028

Elymoclavine

10 mg

CSIR-MYC 030

Epoxyagroclavine-I-tartrate

10 mg

B-MYC0400

Fumonisin B1 50 g/mL in acetonitrile/water (1:1)

5 mL

B-MYC0400-C

Fumonisin B1

5 mg

B-MYC0420

Fumonisin B2 50 g/mL in acetonitrile/water (1:1)

5 mL

CSIR-MYC 013

Gliotoxin

10 mg

CSIR-MYC 029

Meleagrin

10 mg

B-MYC0480

Nivalenol 100 g/mL in acetonitrile

5 mL

B-MYC0480-C

Nivalenol

5 mg

B-MYC0490

Ochratoxin A 10 g/mL in acetonitrile

5 mL

B-MYC0490-C

Ochratoxin A

5 mg

CSIR-MYC 015

Ochratoxin B

10 mg

B-MYC0500

Patulin 100 g/mL in acetonitrile

www.lgcpromochem.com

2 mL

5 mL

Edition 2003/2004

39

Mycotoxins
Code

Product

Unit

CSIR-MYC 017

Secalonic acid D

10 mg

CSIR-MYC 019

Tenuazonic acid-Ca salt

10 mg

CSIR-MYC 020

Tenuazonic acid-Cu salt

10 mg

CSIR-MYC 021

Verruculogen

10 mg

B-MYC0600

Zearalenon 100 g/mL in acetonitrile

5 mL

B-MYC0600-C

Zearalenone

5 mg

Multicomponent standard solutions


B-MYC0300

Aflatoxin Mixture

5 mL

Aflatoxin B1................... 2 g/mL


Aflatoxin B2................ 0.5 g/mL

B-MYC0440

Aflatoxin G1...................2 g/mL


Aflatoxin G2................0.5 g/mL

Fumonisin Mixture

5 mL

50 mg/L of each analyte in acetonitrile/water (1:1)


Fumonisin B1

B-MYC0700

Fumonisin B2

Trichothecene Mixture

5 mL

100 g/mL of each analyte in acetonitrile


3-Acetyl-deoxynivalenol (3-AcDON)
15-Acetyl-deoxynivalenol (15-AcDON)

40

Deoxynivalenol (DON)
Nivalenol

Edition 2003/2004

www.lgcpromochem.com

Quality control reference materials from LGC

Quality control reference materials from LGC


Code

Product

LGCQC1001

Meat paste 1

Unit

10 x 200 g

This material is a blend of beef and pork meat .


Reference values
Ash......................... 0.78 g/100 g
Moisture ................. 66.5 g/100 g
Total Fat................. 12.4 g/100 g

LGCQC1002

Ca..............................253 mg/kg
K ..............................1590 mg/kg
N.............................1.96 g/100 g

Na ........................... 1360 mg/kg


Zn............................. 14.2 mg/kg

Flour 1

10 x 25 g

This material is a commercially produced white bread flour.


Reference values
Ash......................... 0.84 g/100 g
Fat............................ 1.7 g/100 g
N ............................ 2.43 g/100 g

LGCQC1003

Ca............................1120 mg/kg
K ..............................1720 mg/kg
Na................................39 mg/kg

Fe................................ 23 mg/kg
Zn................................ 12 mg/kg

Chocolate 1

10 x 15 g

This material comprises milk chocolate that has been ground and thoroughly mixed.
Reference values
Lactose ................................................... 7.8 g/100 g
Sucrose................................................. 44.8 g/100 g
Total fat................................................. 29.5 g/100 g

LGCQC1004

N............................................................ 1.25 g/100 g


Butyric Acid in Fat ................................... 0.8 g/100 g

Fish paste 1

10 x 200 g

This material comprises whole mackerel fillets that have been thoroughly blended, after addition of water and
sodium.
Reference values
Ash......................... 0.83 g/100 g
Moisture ................. 64.5 g/100 g
Total Fat................. 20.4 g/100 g

LGCQC1005

N.............................2.25 g/100 g
Na............................1320 mg/kg
K ..............................1850 mg/kg

Cl ............................ 1500 mg/kg

Fish paste 2

10 x 200 g

This material comprises a thoroughly mixed blend of white and brown crab meat.
Reference values
As............................. 11.0 mg/kg
Ca ........................... 2150 mg/kg
Cd .............................. 1.9 mg/kg
Co ............................ 0.06 mg/kg
Cr ............................... 0.3 mg/kg

LGCQC1050

Cu.............................10.4 mg/kg
Hg.............................0.10 mg/kg
K ..............................1980 mg/kg
Mg .............................348 mg/kg
Mn ..............................1.8 mg/kg

Na ........................... 2170 mg/kg


Ni ............................. 0.23 mg/kg
P ............................. 2960 mg/kg
V .............................. 0.08 mg/kg
Zn............................. 53.6 mg/kg

Animal feed 1

10 x 50 g

This material comprises a commercially produced feeding stuff that has been ground to pass a 1mm sieve and
thoroughly mixed.
Reference values
Ash........................... 8.1 g/100 g
Crude fibre ............... 7.5 g/100 g
Moisture ................... 5.8 g/100 g
Oil ............................ 7.8 g/100 g
Ca .......................... 1.05 g/100 g

www.lgcpromochem.com

Cl ............................0.66 g/100 g
Cu................................34 mg/kg
Fe ..............................248 mg/kg
K .............................1.07 g/100 g
Mg ..........................0.60 g/100 g

Edition 2003/2004

Mn ............................. 128 mg/kg


Na .......................... 0.44 g/100 g
N ............................ 2.72 g/100 g
P ............................ 0.72 g/100 g
Zn.............................. 136 mg/kg

41

Food Authenticity

Food Authenticity
Isotopic analyses are now official or standard methods in Europe and beyond for routine use in food
authenticity testing. Thus, the use of nuclear magnetic resonance (NMR) spectrometry based on the
site-specific natural isotope fractionation (SNIF) is prescribed for instance by EC Regulation No.
2676/90 on analytical methods for wine quality control. These methods are based on the
13
18
measurement of stable isotope content (deuterium, C, O, etc.) of the products or of a specific
component such as an ingredient or target molecule of the product. The determinations, carried out
using NMR and/or Isotopic Ratio Mass Spectrometry (IRMS), provide information on the botanical and
geographical orign of the food product. In order to enable a clear comparision of results the following
certified reference materials have been developed.
Code

Product

Unit

BCR-123A and BCR-123B


Quantitative analysis of deuterium in ethanol by NMR spectrometry based on the site-specific natural
isotope fractionation (SNIF) is of considerable importance for the detection of wine enrichment. This
technique is prescribed by EC regulation No. 2676/90 on analytical methods for wine quality control.
BCR-123 consists of a set of 3 sealed NMR tubes containing forms of ethanol with a range of site
specific isotopic ratios, to which tetramethylurea internal standard and the C6F6 lock substance have
been added.
BCR-123A

Ethanol - D/H isotopic determination

3 tubes

BCR-123B

Ethanol - D/H isotopic determination

3 tubes

Alcoholic solution - Isotope ratios

450 mL

BCR-660

Certified values
Parameter

value

uncertainty

(D/H)I by H-NMR................................... 102.90 ppm........................ 0.16


(D/H)II by 2H-NMR .................................. 131.35 ppm........................ 0.23
R by 2H-NMR ................................................... 2.567...................... 0.005
13CVPDB by IRMS ........................................ -2.672%...................... 0.009
(D/H) w of water (IRMS)........................... 148.68ppm........................ 0,14
Alcoholic grade tD.......................................... 11.96%..................... 0.06(1)
(1)

42

in v/v %

Edition 2003/2004

www.lgcpromochem.com

Lipid Standards

Lipid Standards
Code

Product

U-FLSA-098

Arachidonic acid (90%)

100 mg

U-FLSA-101

Arachidonic acid (99%)

100 mg

U-FLSA-107

Arachidonic acid methyl ester (90%)

100 mg

U-FLSA-110

Arachidonic acid methyl ester (99%)

100 mg

U-FLSA-115

Butanedioic acid (Succinic acid)

1g

U-FLSA-132

Butanedioic acid dimethyl ester

1g

U-FLSA-002

Butanoic acid (Butyric acid)

1g

U-FLSA-017

Butanoic acid methyl ester

1g

U-FLSA-121

Decanedioic acid (Sebacic acid)

500 mg

U-FLSA-138

Decanedioic acid dimethyl ester

500 mg

U-FLSA-005

Decanoic acid (Capric acid)

1g

U-FLSA-020

Decanoic acid methyl ester

1g

U-FLSA-100

Docosahexenoic acid

100 mg

U-FLSA-109

Docosahexenoic acid methyl ester

100 mg

U-FLSA-011

Docosanoic acid (Behenic acid)

1g

U-FLSA-026

Docosanoic acid methyl ester

1g

U-FLMS-018

1-Docosanol (Behenyl Alcohol)

U-FLSA-006

Dodecanoic acid (Lauric acid)

1g

U-FLSA-021

Dodecanoic acid methyl ester

1g

U-FLSA-091

11,14-Eicosadienoic acid

100 mg

U-FLSA-094

11,14-Eicosadienoic acid methyl ester

100 mg

U-FLSA-010

Eicosanoic acid (Arachidic acid)

1g

U-FLSA-025

Eicosanoic acid methyl ester

1g

U-FLMS-016

1-Eicosanol (Arachidyl Alcohol)

500 mg

U-FLSA-097

11,14,17-Eicosatrienoic acid

100 mg

U-FLSA-106

11,14,17-Eicosatrienoic acid methyl ester

100 mg

U-FLSA-072

11-Eicosenoic acid

100 mg

U-FLSA-086

11-Eicosenoic acid methyl ester

100 mg

U-FLSA-066

Elaidic acid

100 mg

U-FLSA-080

Elaidic acid methyl ester

100 mg

U-FLSA-073

Erucic acid

100 mg

U-FLSA-087

Erucic acid methyl ester

100 mg

U-FLSA-113

Ethanedioic acid (Oxalic acid)

1g

U-FLSA-130

Ethanedioic acid dimethyl ester

1g

U-FLSA-001

Ethanoic acid (Acetic acid)

1g

U-FLSA-016

Ethanoic acid methyl ester

1g

U-FLSA-036

Hendecanoic acid (Undecylic acid)

www.lgcpromochem.com

Unit

100 mg

Edition 2003/2004

100 mg

43

Lipid Standards
Code

Product

U-FLSA-051

Hendecanoic acid methyl ester

100 mg

U-FLSA-041

Heneicosanoic acid

100 mg

U-FLSA-056

Heneicosanoic acid methyl ester

100 mg

U-FLMS-017

1-Heneicosanol

100 mg

U-FLSA-059

Heptacosanoic acid methyl ester

50 mg

U-FLMS-023

1-Heptacosanol

50 mg

U-FLSA-039

Heptadecanoic acid (Margaric acid)

100 mg

U-FLSA-054

Heptadecanoic acid methyl ester

100 mg

U-FLMS-013

1-Heptadecanol

100 mg

U-FLSA-118

Heptanedioic acid (Pimelic acid)

1g

U-FLSA-135

Heptanedioic acid dimethyl ester

1g

U-FLSA-034

Heptanoic acid (Heptylic acid)

100 mg

U-FLSA-049

Heptanoic acid methyl ester

100 mg

U-FLSA-013

Hexacosanoic acid (Cerotic acid)

100 mg

U-FLSA-028

Hexacosanoic acid methyl ester

100 mg

U-FLMS-022

1-Hexacosanol (Cerotyl Alcohol)

50 mg

U-FLSA-008

Hexadecanoic acid (Palmitic acid)

1g

U-FLSA-023

Hexadecanoic acid methyl ester

1g

U-FLMS-012

1-Hexadecanol (Cetyl Alcohol)

1g

U-FLSA-117

Hexanedioic acid (Adipic acid)

1g

U-FLSA-134

Hexanedioic acid dimethyl ester

1g

U-FLSA-003

Hexanoic acid (Caproic acid)

1g

U-FLSA-018

Hexanoic acid methyl ester

1g

U-FLSA-147

homo gamma-Linolenic acid

100 mg

U-FLSA-148

homo gamma-Linolenic acid methyl ester

100 mg

U-FLSA-089

Linoleic acid

100 mg

U-FLSA-092

Linoleic acid methyl ester

100 mg

U-FLSA-090

Linolelaidic acid

100 mg

U-FLSA-093

Linolelaidic acid methyl ester

100 mg

U-FLSA-095

Linolenic acid

100 mg

U-FLSA-104

Linolenic acid methyl ester

100 mg

U-FLSA-096

gamma Linolenic acid

100 mg

U-FLSA-105

gamma-Linolenic acid methyl ester

100 mg

U-FLSA-031

Methanoic acid (Formic acid)

1g

U-FLSA-046

Methanoic acid methyl ester

1g

U-FLBA-021

2-Methylbutanoic acid (Anteisovaleric acid)

50 mg

U-FLBA-030

2-Methylbutanoic acid methyl ester

50 mg

U-FLBA-034

10-Methyldodecanoic acid methyl ester

50 mg

44

Unit

Edition 2003/2004

www.lgcpromochem.com

Lipid Standards
Code

Product

U-FLBA-038

18-Methyleicosanoic acid methyl ester

25 mg

U-FLBA-004

10-Methylhendecanoic acid (Isolauric acid)

50 mg

U-FLBA-014

10-Methylhendecanoic acid methyl ester

50 mg

U-FLBA-007

16-Methylheptadecanoic acid (Isostearic acid)

10 mg

U-FLBA-017

16-Methylheptadecanoic acid methyl ester

10 mg

U-FLBA-002

6-Methylheptanoic acid (Isocaprylic acid)

50 mg

U-FLBA-012

6-Methylheptanoic acid methyl ester

50 mg

U-FLBA-027

14-Methylhexadecanoic acid (Anteisomargaric acid)

10 mg

U-FLBA-036

14-Methylhexadecanoic acid methyl ester

10 mg

U-FLBA-022

4-Methylhexanoic acid (Anteisoheptylic acid)

50 mg

U-FLBA-031

4-Methylhexanoic acid methyl ester

50 mg

U-FLBA-008

18-Methylnonadecanoic acid (Isoarachidic acid)

25 mg

U-FLBA-018

18-Methylnonadecanoic acid methyl ester

25 mg

U-FLBA-003

8-Methylnonanoic acid (Isocapric acid)

50 mg

U-FLBA-013

8-Methylnonanoic acid methyl ester

50 mg

U-FLBA-028

16-Methyloctadecanoic acid (Anteisononadecylic acid)

25 mg

U-FLBA-037

16-Methyloctadecanoic acid methyl ester

25 mg

U-FLBA-032

6-Methyloctanoic acid methyl ester

50 mg

U-FLBA-006

14-Methylpentadecanoic acid (Isopalmitic acid)

10 mg

U-FLBA-016

14-Methylpentadecanoic acid methyl ester

10 mg

U-FLBA-001

4-Methylpentanoic acid (Isocaproic acid)

50 mg

U-FLBA-011

4-Methylpentanoic acid methyl ester

50 mg

U-FLBA-026

12-Methyltetradecanoic acid (Anteisopentadecylic acid)

10 mg

U-FLBA-035

12-Methyltetradecanoic acid methyl ester

10 mg

U-FLBA-015

12-Methyltridecanoic acid methyl ester

10 mg

U-FLSA-062

Myristoleic acid

100 mg

U-FLSA-076

Myristoleic acid methyl ester

100 mg

U-FLSA-074

Nervonic acid

100 mg

U-FLSA-088

Nervonic acid methyl ester

100 mg

U-FLSA-040

Nonadecanoic acid (Nonadecylic acid)

100 mg

U-FLSA-055

Nonadecanoic acid methyl ester

100 mg

U-FLMS-015

1-Nonadecanol

100 mg

U-FLSA-120

Nonanedioic acid (Azelaic acid)

500 mg

U-FLSA-137

Nonanedioic acid dimethyl ester

500 mg

U-FLSA-035

Nonanoic acid (Pelargonic acid)

100 mg

U-FLSA-050

Nonanoic acid methyl ester

100 mg

U-FLSA-014

Octacosanoic acid (Montanic acid)

100 mg

U-FLSA-029

Octacosanoic acid methyl ester

100 mg

www.lgcpromochem.com

Unit

Edition 2003/2004

45

Lipid Standards
Code

Product

U-FLMS-024

1-Octacosanol

50 mg

U-FLSA-127

Octadecanedioic acid

50 mg

U-FLSA-144

Octadecanedioic acid dimethyl ester

50 mg

U-FLSA-009

Octadecanoic acid (Stearic acid)

1g

U-FLSA-024

Octadecanoic acid methyl ester

1g

U-FLMS-014

1-Octadecanol (Stearyl Alcohol)

1g

U-FLSA-067

cis-11-Octadecenoic acid

100 mg

U-FLSA-081

cis-11-Octadecenoic acid methyl ester

100 mg

U-FLSA-068

trans-11-Octadecenoic acid (Vaccenic acid)

100 mg

U-FLSA-082

trans-11-Octadecenoic acid methyl ester

100 mg

U-FLSA-119

Octanedioic acid (Suberic acid)

500 mg

U-FLSA-136

Octanedioic acid dimethyl ester

500 mg

U-FLSA-004

Octanoic acid (Caprylic acid)

1g

U-FLSA-019

Octanoic acid methyl ester

1g

U-FLSA-065

Oleic acid

100 mg

U-FLSA-079

Oleic acid methyl ester

100 mg

U-FLSA-064

Palmitelaidic acid

100 mg

U-FLSA-078

Palmitelaidic acid methyl ester

100 mg

U-FLSA-063

Palmitoleic acid

100 mg

U-FLSA-077

Palmitoleic acid methyl ester

100 mg

U-FLSA-058

Pentacosanoic acid methyl ester

50 mg

U-FLMS-021

1-Pentacosanol

50 mg

U-FLSA-038

Pentadecanoic acid (Pentadecylic acid)

100 mg

U-FLSA-053

Pentadecanoic acid methyl ester

100 mg

U-FLSA-033

Pentanoic acid (Valeric acid)

100 mg

U-FLSA-048

Pentanoic acid methyl ester

100 mg

U-FLSA-071

Petroselinic acid

100 mg

U-FLSA-085

Petroselinic acid methyl ester

100 mg

U-FLBA-042

Phytanic acid (3,7,11,15-Tetramethylhexadecanoic acid)

25 mg

U-FLBA-043

Phytanic acid methyl ester (Methyl-3,7,11,15-tetramethylhexadecanoate)

25 mg

U-FLMS-035

Phytol (tech) (3,7,11,15-Tetramethyl-2-hexadecen-1-ol )

1g

U-FLSA-114

Propanedioic acid (Malonic acid)

1g

U-FLSA-131

Propanedioic acid dimethyl ester

1g

U-FLSA-032

Propanoic acid (Propionic acid)

1g

U-FLSA-047

Propanoic acid methyl ester

1g

U-FLSA-070

Ricinelaidic acid

100 mg

U-FLSA-084

Ricinelaidic acid methyl ester

100 mg

U-FLSA-069

Ricinoleic acid

100 mg

46

Unit

Edition 2003/2004

www.lgcpromochem.com

Lipid Standards
Code

Product

U-FLSA-083

Ricinoleic acid methyl ester

100 mg

U-FLSA-012

Tetracosanoic acid (Lignoceric acid)

100 mg

U-FLSA-027

Tetracosanoic acid methyl ester

100 mg

U-FLMS-020

1-Tetracosanol (Lignoceryl Alcohol)

U-FLSA-125

Tetradecanedioic acid

100 mg

U-FLSA-142

Tetradecanedioic methyl ester

100 mg

U-FLSA-007

Tetradecanoic acid (Myristic acid)

1g

U-FLSA-022

Tetradecanoic acid methyl ester

1g

U-FLMS-010

1-Tetradecanol (Myristyl Alcohol)

1g

U-FLSA-015

Triacontanoic acid (Mellisic acid)

100 mg

U-FLSA-030

Triacontanoic acid methyl ester

100 mg

U-FLMS-026

1-Triacontanol (Melissyl Alcohol)

50 mg

U-FLSA-057

Tricosanoic acid methyl ester

100 mg

U-FLMS-019

1-Tricosanol

100 mg

U-FLSA-037

Tridecanoic acid (Tridecylic acid)

100 mg

U-FLSA-052

Tridecanoic acid methyl ester

100 mg

U-FLPK-001

Unit

50 mg

Unsaturated fatty acids & methyl esters

kit

Each kit contains 25 mg each of twenty compounds.


cis-9-Tetradecenoic acid (Myristoleic acid)
cis-9-Hexadecenoic acid (Palmitoleic acid)
trans-9-Hexadecenoic acid (Palmitelaidic acid)
cis-9-Octadecenoic acid (Oleic acid)
trans-9-Octadecenoic acid (elaidic acid)
cis-9-cis-12-Octadecadienoic acid (Linoleic acid)
trans-9-trans-12-Octadecadienoic acid (Linolelaidic acid)
cis-9-cis-12-cis-15-Octadecenoate acid (Linolenic acid)
cis-11-Eicosenoic acid (Gondonic acid)
cis-13-Docosenoic acid (Erucic acid)
Methyl cis-9-Tetradecanoate (Methyl myristoleate)
Methyl cis-9-Hexadecenoate (Methyl palmitoleate)
Methyl trans-9-Hexadecenoate (Methyl palmitelaidate)
Methyl cis-9-Octadecenoate (Methyl oleate)
trans-9-Octadecenoate (Methyl eleidate)
Methyl cis-9-cis-12-Octadecadienoate (Methyl linoleate)
Methyl trans-9-cis-12-Octadecadienoate (Methyl linelaidate)
Methyl cis-9-cis-12-cis-15-Octadecatrienoate (Methyl linolenate)
Methyl cis-11-Eicosenoate (Methyl gondonate)
Methyl cis-13-Docosenoate (Methyl erucate)

U-FLPK-003

Fatty acids and methyl esters kit

kit

Each kit contains 25 mg each of sixteen compounds.


Nonanoic acid
Undecanoic acid
Tridecanoic acid
Pentadecanoic acid
Heptadecanoic acid
Nonadecanoic acid (Nonadecylic acid)
Heneicosanoic acid
Tricosanoic acid

U-FLPK-004

Methyl nonanoate
Methyl undecanoate
Methyl tridecanoate
Methyl pentadecanoate
Heptadecanoic acid methyl ester
Nonadecanoic acid methyl ester
Heneicosanoic acid methyl ester
Tricosanoic acid methyl ester

Fatty acids and methyl esters kit

kit

Each kit contains 100 mg each of twenty compounds.


Hexanoic acid (Caproic acid)
Octanoic acid (Caprylic acid)
Decanoic acid (Capric acid)
Dodecanoic acid (Lauric acid)
Tetradecanoic acid (Myristic acid)
Hexadecanoic acid (Palmitic acid)
Stearic acid
Eicosanoic acid (Arachidic acid)
Docosanoic acid (Behenic acid)
Tetracosanoic acid (Lignoceric acid) (25 mg)

www.lgcpromochem.com

Hexanoic acid methyl ester


Octanoic acid methyl ester
Decanoic acid methyl ester
Dodecanoic acid methyl ester
Tetradecanoic acid methyl ester
Hexadecanoic acid methyl ester
Octadecanoic acid methyl ester
Eicosanoic acid methyl ester
Docosanoic acid methyl ester
Tetracosanoic acid methyl ester (25 mg)

Edition 2003/2004

47

Lipid Standards
Code

U-FLPK-005

Product

Unit

Volatile fatty acids

kit

Each kit contains 1 gm each of ten compounds plus 5 mL of a mixture.


Methanoic acid (Formic acid)
Acetic acid
Propanoic acid (Propionic acid)
Butanoic acid (Butyric acid)
Isobutyric acid
Pentanoic acid (Valeric acid)

48

Isovaleric acid
Hexanoic acid (Caproic acid)
Heptanoic acid
Octanoic acid (Caprylic acid)
0.1% C1-C5 Acids test solution in H2O (5 mL)

Edition 2003/2004

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Food and drink products

Food and drink products


Code

Product

Unit

Processed food
LGC7103

Sweet digestive biscuit - Proximates and elements

50 g

Assessed values
Moisture ................... 2.8 g/100 g
Nitrogen ................. 1.06 g/100 g
Total fat.................. 20.9 g/100 g
Ash.......................... 2.08 g/100g

Fructose .................0.24 g/100 g


Sucrose ..................16.6 g/100 g
Chloride ....................0.55 mg/kg
K ..............................1530 mg/kg

Mn .............................. 5.9 mg/kg


Na ........................... 6300 mg/kg
P ............................... 870 mg/kg
Zn............................... 5.8 mg/kg

Indicative values for glucose, starch, Ca and Mg

LGC7107 (RM)

Madeira cake - Proximates

160 g

Lemon Madeira cake were prepared by a UK food company. Each cake, weighing approx. 160 g, was sealed in a
can.
Assessed values
Moisture ................. 25.9 g/100 g
Nitrogen ................. 0.66 g/100 g

Total fat ..................13.4 g/100 g


Ash .........................1.76 g/100 g

Sucrose.................. 28.1 g/100 g


Lactose .................... 0.9 g/100 g

Indicative value for starch content

LGC7105 (RM)

Rice pudding - Proximates and elements

5 x 200 g

Certified values
Moisture ................. 71.3 g/100 g
N ............................ 0.17 g/100 g
Total fat.................... 8.4 g/100 g
Ash......................... 0.22 g/100 g

LGC7016

Sucrose ....................7.2 g/100 g


Ca................................78 mg/kg
K ................................558 mg/kg
Mg ...............................30 mg/kg

Mn .............................. 0.7 mg/kg


Na ............................. 344 mg/kg
P ............................... 346 mg/kg
Zn............................... 1.5 mg/kg

Chocolate confectionery - Sugars, nitrogen and fats

15 g

Certified values
Lactose .................... 7.8 g/100 g
Sucrose.................. 44.8 g/100 g

Total fat ..................29.5 g/100 g


Butyric acid in fat ......0.8 g/100 g

Nitrogen ................. 1.25 g/100 g

Indicative values for fructose and glucose

BCR-518

Bran breakfast cereal - Dietary fibre

25 g

Certified using five different methods of dietary fibre analysis


Certified values
AOAC 1990........................................... 30.2 g/100 g
Englyst (GC) ......................................... 24.1 g/100 g
Uppsala................................................. 27.6 g/100 g

BCR-191

AOAC 1992 MES-TRIS......................... 30.5 g/100 g


Englyst (colorimetry) ............................. 25.0 g/100 g

Brown bread - Trace elements

40 g

Certified values
Cd ............................. 28.4 g/kg
Cu .............................. 2.6 mg/kg

Fe .............................40.7 mg/kg
Mn ............................20.3 mg/kg

Pb .............................. 187 g/kg


Zn............................. 19.5 mg/kg

Indicative values for As,Ca, Cl, Cr, Hg, K, Mg, Na, Ni, P, Se

NIST-1845

Whole egg powder - Cholesterol

35 g

Certified value
Cholesterol................. 19.0 mg/g

NIST-RM 8415

Whole egg powder - Trace elements

35 g

Reference concentration values are given for major, minor and trace constituent elements, proximates, calories
and fatty acids. Information concentration values are given for additional elements, fatty acids and water soluble
vitamins

NIST-2383

Baby food composite - Carotenoids and vitamins

4 x 70 g

Certified values
trans-Retinol ............ 0.80 mg/kg
-Tocopherol ............ 1.51 mg/kg
-Tocopherol ............ 5.51 mg/kg

-Tocopherol ............25.0 mg/kg


Lutein........................1.16 mg/kg
Zeaxanthin................0.86 mg/kg

-Cryptoxanthin........ 1.38 mg/kg


Total -carotene ...... 0.83 mg/kg
Total carotene...... 3.12 mg/kg

Indicative values for other vitamins and carotenoids, proximates, cholesterol, calories, minerals and trace
elements

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Edition 2003/2004

49

Food and drink products


Code

NIST-1548a

Product

Unit

Typical diet - Trace elements

set (2)

A unit of NIST-1548a consists of two bottles, each containing approximately 6.5 g of the freeze-dried homogenate
of mixed diet foods.
Certified values
Al.............................. 72.4 mg/kg
As............................. 0.20 mg/kg
Ca ........................... 1967 mg/kg
Cd .......................... 0.035 mg/kg
Cl .......................... 12078 mg/kg
Cs ........................ 0.0098 mg/kg

Cu.............................2.32 mg/kg
Fe .............................35.3 mg/kg
I ..............................0.759 mg/kg
Mg .............................580 mg/kg
Mn ............................5.75 mg/kg
Na............................8132 mg/kg

Ni ........................... 0.369 mg/kg


P ............................. 3486 mg/kg
S ............................. 1928 mg/kg
Se .......................... 0.245 mg/kg
Sn ............................ 17.2 mg/kg
Zn............................. 24.6 mg/kg

Indicative values for Ash, carbohydrate, fat, N, protein, dietary fibre, calories, B, Ba, Br, Co, Hg, Mo, Sb, Sc, Si,
Sr, Ti

NIST-1544

Diet composite - Fatty acids and cholesterol

4 x 15 g

Certified values
Cholesterol.............. 0.1483 g/kg
Lauric acid .................. 1.31 g/kg
Myristic acid ................ 1.01 g/kg

Palmitic acid ................5.77 g/kg


Stearic acid..................2.00 g/kg
Oleic acid...................11.64 g/kg

Linoleic acid ................ 6.56 g/kg

Indicative values for protein, moisture, total fat, ash, carbohydrate, calories, remaining fatty acids, Ca, K, Na

ARC/CL2

Total diet - Trace elements

20 g

Certified values
Ca .............................. 2.86 mg/g
Cd .................................. 21 ng/g
Cu ............................... 3.18 g/g
Fe................................ 30.4 g/g
Hg ................................. 6.6 ng/g

SLV DIET A

K .................................9.42 mg/g
Mg ................................785 g/g
Mn ...............................12.9 g/g
Mo ................................262 ng/g
Na...............................7.87 mg/g

Ni ................................. 271 ng/g


Pb .................................. 43 ng/g
Se ................................ 181 ng/g
Zn................................ 28.9 g/g

Simulated diet A - Trace elements

10 g

A mixture of rye/wheat flour, potatoes, skim milk powder and lean beef.
Certified values
Ca ........................... 1576 mg/kg
Cd .......................... 0.029 mg/kg
Cu ............................ 2.60 mg/kg
Fe............................. 81.2 mg/kg

K ............................11222 mg/kg
Mg .............................814 mg/kg
Mn ............................5.69 mg/kg
Na............................1613 mg/kg

Pb .......................... 0.041 mg/kg


Zn............................. 95.0 mg/kg

Indicative values for Al, As, Co, Hg, Ni, Rb, S

SLV DIET B

Simulated diet B - Trace elements

10 g

A mixture of rye/wheat flour, pig kidney, skim milk powder and lean beef.
Certified values
Ca ........................... 2018 mg/kg
Cd .......................... 0.099 mg/kg
Cr ........................... 0.149 mg/kg
Cu ............................ 6.64 mg/kg

Fe ..............................111 mg/kg
K ..............................9142 mg/kg
Mg .............................749 mg/kg
Mn ............................6.36 mg/kg

Na ........................... 2365 mg/kg


Pb .......................... 0.059 mg/kg
Zn............................. 91.9 mg/kg

Indicative values for Al, As, Co, Hg, Ni, Rb, Se

SLV DIET C

Simulated diet C - Trace elements

10 g

A mixture of reindeer liver, skim milk powder, lean beef and rye/wheat flour.
Certified values
Ca ........................... 1059 mg/kg
Cd .......................... 0.205 mg/kg
Cr ........................... 0.054 mg/kg
Cu ............................ 20.8 mg/kg

Fe ..............................142 mg/kg
K ..............................4886 mg/kg
Mg .............................620 mg/kg
Mn ............................9.58 mg/kg

Na ............................. 697 mg/kg


Ni ........................... 0.108 mg/kg
Pb .......................... 0.114 mg/kg
Zn............................. 40.6 mg/kg

Indicative values for Al, As, Co, Hg, Rb, Se

SLV DIET D

Simulated diet D - Trace elements

10 g

A mixture of skim milk powder, reindeer liver, rye/wheat flour and potatoes.
Certified values
Ca ............................. 510 mg/kg
Cd .......................... 0.478 mg/kg
Co .......................... 0.072 mg/kg
Cr ........................... 0.036 mg/kg
Cu ............................ 40.8 mg/kg

Fe ..............................199 mg/kg
K ..............................7088 mg/kg
Mg .............................676 mg/kg
Mn ............................10.2 mg/kg
Na..............................485 mg/kg

Ni ........................... 0.100 mg/kg


Pb .......................... 0.218 mg/kg
Zn............................. 37.2 mg/kg

Indicative values for Al, As, Hg, Rb, Se

50

Edition 2003/2004

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Food and drink products


Code

SLV DIET E

Product

Unit

Simulated diet E - Trace elements

10 g

A mixture of white wine, potatoes, reindeer liver and rye/wheat flour.


Certified values
Ca ............................. 268 mg/kg
Cd .......................... 0.536 mg/kg
Co .......................... 0.083 mg/kg
Cr ........................... 0.061 mg/kg
Cu ............................ 46.5 mg/kg

Fe ..............................216 mg/kg
K ..............................5985 mg/kg
Mg .............................649 mg/kg
Mn ............................11.0 mg/kg
Na..............................436 mg/kg

Ni ........................... 0.124 mg/kg


Pb .......................... 0.273 mg/kg
Zn............................. 39.5 mg/kg

Indicative values for Al, As, Hg, Rb, Se

SLV DIET F

Simulated diet F - Trace elements

10 g

A mixture of white wine, potatoes, rye/wheat flour and reindeer liver.


Certified values
Ca ............................. 262 mg/kg
Cd .......................... 0.877 mg/kg
Co .......................... 0.136 mg/kg
Cu ............................ 72.7 mg/kg

Fe ..............................349 mg/kg
K ..............................5966 mg/kg
Mg .............................647 mg/kg
Mn ............................11.1 mg/kg

Na ............................. 758 mg/kg


Ni ........................... 0.102 mg/kg
Pb .......................... 0.439 mg/kg
Zn............................. 55.8 mg/kg

Indicative values for Al, As, Cr, Hg, Rb, Se

Drinks
LGC7130

Soft drink - Sweeteners

5 x 20 mL

Known weights of saccharin and aspartame were added to a simulated soft drink.
Certified values
Saccharin..................... 77 mg/lL

LGC7131

Aspartame...................620 mg/L

Soft drink - Sweeteners

5 x 20 mL

Known weights of saccharin and Acesulfame-K were added to a simulated soft drink.
Certified values
Saccharin...................... 76 mg/L
Acesulfame-K ............. 349 mg/L

LGC7140 (RM)

Soft drink - Colours

5 x 60 mL

Known weights of three food colours were added to a diluted solution of commercial soft drink concentrate.
Certified values
Ponceau 4R (E124) ....................................18.7 mg/l
Sunset yellow (E110) ................................ 19.6 mg/L

LGC7011

Tartrazine (E102) ...................................... 29.9 mg/L

Orange juice

3 mL

Certified values
Degrees Brix ....................... 1.26

LGC7012

Refractive index...............1.3348

Orange juice

3 mL

Certified values
Degrees Brix ..................... 12.72

LGC7013

Refractive index...............1.3521

Orange juice

3 mL

Certified values
Degrees Brix ..................... 22.07

LGC7014

Refractive index...............1.3673

Orange juice

3 mL

Certified values
Degrees Brix ..................... 55.55

LGC7015

Refractive index...............1.4320

Orange juice

3 mL

Certified values
Degrees Brix ..................... 64.73

Refractive index...............1.4529

For refractive index standards see our catalogue Reference materials for physical properties
LGC provides two proficiency testing schemes for the soft drinks industry; SODAS (analysis of soft
drinks) and LGC-PCI (sugar analysis) see section About proficiency testing (PT) of this catalog for
further details.

www.lgcpromochem.com

Edition 2003/2004

51

Food and drink products


Code

Product

Unit

Food additives
LGC7300

2,6-Di-tert-butyl-4-methylphenol (BHT)

500 mg

Certified purity.................. 99.8%

LGC7301

2-tertiary-butyl-4-methoxyphenol

500 mg

Certified purity.................. 99.2%

LGC7302

Saccharin

500 mg

Certified purity................. 99.6 %

LGC7305

Potassium sorbate

500 mg

Certified purity................. 99.8 %

IPO F 010

Benzoic acid

250 mg

IPO F 170

Sorbic acid

250 mg

U-FLPK-007

Antioxidant food additives kit

kit

Each kit contains 1 g each of thirteen compounds.


Ascorbic acid
Ascorbyl palmitate
BHA (2 & 3-t-Butyl-4-methoxyphenol)
BHT (2,6-di-tert-Butyl-4-methylphenol)
t-Butylhydroquinone
Ethoxyquin (1,2-Dihydro-6-ethoxy-2,2,4-trimethylquinoline)
Erythorbic acid (Isoascorbic acid)
Dilaurel thiodipropionate
4-Hydroxymethyl-2,6-di-t-butylphenol
L-Glycine
Propyl gallate
Thiodipropionic acid
THBP (2,4,5-Trihydroxybutyrophenone)

U-FLPK-002

Antimicrobial food additives kit

kit

Each kit contains 1 g each of thirteen compounds.


Acetic acid
Benzoic acid
Butyl paraben
Octanoic acid (Caprylic acid)
Ethyl paraben
Methyl paraben
Potassium sorbate

NRMGBW10001

Propanoic acid (Propionic acid)


Propyl paraben
Sodium benzoate
Sodium nitrate
Sodium nitrite
Sorbic acid

Amaranth colour

300 mg

Certified purity................. 97.2 %

NRMGBW10002

Ponceau 4R

300 mg

Certified purity................. 93.3 %

NRMGBW10003

Tartrazine

300 mg

Certified purity................. 99.3 %

NRMGBW10004

Brilliant Blue

300 mg

Certified purity.................. 97.3%

NRMGBW10005

Sunset Yellow

300 mg

Certified purity................. 97.3 %

52

Edition 2003/2004

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Food and drink products


Code

Product

Unit

Dye standards
IBPO010 - IBPO008
Dye standards from the Institute of Dyes and Organic Products (IBPO) Poland
The following standards of dyes, used in the food and pharmaceutical industry , are listed with
common description, E code and colour index number (C.I.) for an easy assignment.
The IBPO is accredited by the Polish Centre for Testing and Certification according to the standard
PN-EN 45001 and ISO/IEC Guide 25:1990.
Each colour reference standard is supplied with a detailed certificate of analysis which includes dye
content value determined by spectrophotometry and values of impurities.

Black
IBPO010

Brilliant Black PN

1g

C.I.28440 - E 151

Blue
IBPO015

Brilliant Blue FCF

1g

C.I.42090 - E 133

IBPO002

Indigotine

1g

C.I.73015 - E 132

IBPO012

Patent Blue V

1g

C.I.42051 - E 131

Brown
IBPO017

Brown HT

1g

C.I.20285 - E 155

Green
IBPO016

Brilliant Green BS

1g

C.I.44090 - E 142

Red
IBPO014

Allura Red AC

1g

C.I.16035 - E 129

IBPO005

Amaranth

1g

C.I.16185 - E 123

IBPO003

Azorubin

1g

C.I.14720 - E 122

IBPO011

Erythrosine

1g

C.I.45430 - E 127

IBPO004

Ponceau 4R

1g

C.I.16255 - E 124

IBPO013

Red 2 G

1g

C.I.18050 - E 128

Yellow
IBPO007

Quinoline Yellow

1g

C.I.47005 - E 104

IBPO009

Sunset Yellow FCF

1g

C.I.15985 - E 110

IBPO008

Tartrazine

1g

C.I.19140 - E 102

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Edition 2003/2004

53

Food and drink products


Code

Product

Unit

Alcoholic beverage
LGC5000

Brandy - Alcohol

5 x 50 mL

Certified value................ 39.98 mL/100 mL (at 20C)

LGC5100

Whisky - Congeners

5 x 10 mL

Certified values
Methanol ................................................. 8.2 g/100 L
Ethyl acetate ......................................... 27.0 g/100 L
Propan-1-ol ........................................... 67.4 g/100 L
2-Methylpropan-1-ol .............................. 65.0 g/100 L

2-Methylbutan-1-ol ................................ 19.6 g/100 L


3-Methylbutan-1-ol ................................ 51.4 g/100 L
2+3-Methylbutan-1-ol ............................. 70.1g/100 L

Indicative values for acetaldehyde, butan-1-ol, furfural

LGC5001

Wine - Alcohol (5%)

5 x 250 mL

Certified value
Alcohol .............................. 5.04 ml/100 mL (at 20C)

LGC5002

Wine - Alcohol (10 %)

5 x 250 mL

Certified value
Alcohol ..........................................10.25 % (at 20C)

LGC5003

Wine - Alcohol (15 %)

5 x 250 mL

Certified value
Alcohol ..........................................14.66 % (at 20C)

LGC5004

Lager shandy - Alcohol

5 x 330 mL

Certified value.................. 1.02 mL/100 mL (at 20C)

LGC5005

Lager - Alcohol

5 x 440 mL

Certified value.................. 4.75 mL/100 mL (at 20C)

LGC provides three proficiency testing schemes for the alcoholic beverage industry; BAPS (analysis
of beer), MAPS (analysis of malted and unmalted barley) and DAPS (analysis of alcoholic beverages
other than beer) see section About proficiency testing (PT) of this catalog for further details.

Low alcohol beverage


Related to the labelling of 'alcohol free' or 'de-alcoholised' and 'low alcohol' beverages according to
Directive 90/496/EC.
BCR-651

Beer - Alcohol (low level)

10 mL

Certified value
Ethanol................................................. 0.505 % (v/v)

BCR-652

Beer - Alcohol (very low level)

10 mL

Certified value
Ethanol................................................. 0.051 % (v/v)

BCR-653

Wine - Alcohol (low level)

10 mL

Certified value
Ethanol................................................. 0.539 % (v/v)

Alcohol
LGC5404

Ethanol/water - 5% Ethanol

5 x 50 mL

Certified value
Ethanol.................................... 5 mL/100 mL at 20C

LGC5405

Ethanol/water - 15% Ethanol

5 x 50 mL

Certified value
Ethanol.................................. 15 mL/100 mL at 20C

LGC5406

Ethanol/water - 40% Ethanol

5 x 50 mL

Certified value
Ethanol.................................. 40 mL/100 mL at 20C

54

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Animal food products


Code

Product

LGC5407

Ethanol/water - 70% Ethanol

Unit

5 x 50 mL

Certified value
Ethanol.................................. 70 mL/100 mL at 20C

LGC5408

Ethanol/water - 90% Ethanol

5 x 50 mL

Certified value
Ethanol.................................. 90 mL/100 mL at 20C

STA 003

N-N Tetramethyllurea

500 ml

Used as an internal standard in SNIF analysis (see above). D/H nominal values have been determined at 76.7,
61.4 and 45.05 MHz for deuterium.

Animal food products


Code

Product

Unit

LGC7176

Canned pet food - Proximates

200 g

Fish recipe cat food


Certified values
Moisture ................. 84.1 g/100 g
Nitrogen ................. 1.32 g/100 g

Fat ..........................4.46 g/100 g


Ash .........................2.20 g/100 g

Indicative values for Cl, K, Na

LGC7172 (RM)

Dairy cattle feed - Proximates and elements

5 x 50 g

Dairy cattle nuts from a commercial animal feed manufacturer.


Assessed values
Ca .......................... 1.05 g/100 g
Cl ........................... 0.66 g/100 g
Cu ............................... 34 mg/kg
K ............................ 1.07 g/100 g
Fe.............................. 248 mg/kg

LGC7173 (RM)

K .............................1.07 g/100 g
Mg ..........................0.60 g/100 g
Mn .............................128 mg/kg
P .............................0.72 g/100 g
Zn ..............................136 mg/kg

Poultry feed - Proximates and elements

Moisture ................... 5.8 g/100 g


Nitrogen ................. 2.72 g/100 g
Oil ............................ 7.8 g/100 g
Ash........................... 8.1 g/100 g
Crude fibre ............... 7.5 g/100 g

5 x 50 g

Please ask for details.

BCR-115

Animal feed - Pesticides


Compound

30 g
Certified value
mg/kg

Uncertainty
mg/kg

HCB ............................................................... 0.0194...................... 0.0014


beta-HCH......................................................... 0.023........................ 0.003
gamma-HCH.................................................. 0.0218...................... 0.0020
Heptachlor ....................................................... 0.019...................... 0.0015
gamma-Chlordane ........................................... 0.048........................ 0.005
Dieldrin............................................................. 0.018........................ 0.003
alpha-Endosulfan............................................. 0.046........................ 0.004
Endrin .............................................................. 0.046........................ 0.006
2,4'-DDT........................................................... 0.046........................ 0.005
4,4'-DDE .......................................................... 0.047........................ 0.004

BCR-375

Compound feed - Aflatoxin B1 (blank)

50 g

Certified value
Aflatoxin B1.................. <1 g/kg

BCR-376

Compound feed - Aflatoxin B1 (low level)

50 g

Certified value
Aflatoxin B1................. 9.3 g/kg

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Edition 2003/2004

55

Fertilizers

Fertilizers
Code

BCR-032

Product

Unit

Moroccan phosphate rock - Trace elements

100 g

Certified values
As.................................. 9.5 g/g
B ................................. 22.6 g/g
Cd ............................... 20.8 g/g
Co ............................... 0.59 g/g

BCR-033

Cr..................................257 g/g
Cu................................33.7 g/g
Hg...................................55 ng/g
Mn ...............................18.8 g/g

Ni ................................ 34.6 g/g


Ti.................................. 171 g/g
V .................................. 153 g/g
Zn................................. 253 g/g

Super-phosphate - Constituents

100 g

Certified values
P2O5 .......................... 193.4 g/kg
SO4 ........................... 428.0 g/kg
CaO .......................... 314.8 g/kg

BCR-113

SiO2 .............................29.2 g/kg


F ..................................16.5 g/kg
Al2O3 ............................11.0 g/kg

Fe2O3 ............................ 4.0 g/kg


MgO .............................. 2.1 g/kg

Potassium chloride - Elemental composition

100 g

Certified values
Ca ............................... 1.03 g/kg
Cl .............................. 478.0 g/kg

K ................................502.5 g/kg
Mg ...............................0.24 g/kg

Na ............................... 15.3 g/kg

Water soluble
K .............................. 501.3 g/kg

BCR-114

Potassium sulphate - Elemental composition

100 g

Certified values
Ca ................................. 9.4 g/kg
Cl ................................ 18.5 g/kg

K ................................418.0 g/kg
Na................................11.0 g/kg

SO4 .............................. 533 g/kg

Water soluble
K .................................. 17.6g/kg

BCR-178

Calcium ammonium nitrate - Elemental composition

100 g

Certified values
Ca ............................. 88.82 g/kg
NH4-N...................... 130.44 g/kg

BCR-179

NO3-N......................130.15 g/kg
Total-N.....................260.19 g/kg

Urea - Composition

100 g

Certified values
Total-N .................... 465.35 g/kg

NIST-120c

Uric-N ........................460.9 g/kg

Biuret ........................ 10.37 g/kg

Phosphate rock, Florida - Constitutents

90 g

Certified values
Al2O3 ............................... 1.30 %
Fe2O3 .............................. 1.08 %
K2O ............................... 0.147 %

MnO.............................. 0.027 %
Na2O............................... 0.52 %
TiO2 .............................. 0.103 %

U3O8 ............................ 0.0135 %


V2O3 .............................. 0.016 %

Values for the AFPC-method-Dependent concentrations also available

NIST-193

Potassium nitrate - Nitrogen and potassium

90 g

Certified values
K ................................... 38.66 %

NIST-194

N................................... 13.85 %

Ammonium dihydrogen phosphate - Nitrogen and phosphorous

90 g

Certified values
N ................................... 12.15 %

NIST-200a

P ................................... 26.92 %

Potassium dihydrogen phosphate - Phosphorous and potassium

90 g

Certified values
K ................................. 28.375 %

NIST-694

P ............................... 22.7352 %

Phosphate rock, western - Constituents

90 g

Certified values
Al2O3 ................................. 1.8 %
CaO ................................ 43.6 %
CdO .............................. 0.015 %
F........................................ 3.2 %
Fe2O3 .............................. 0.79 %

K2O................................. 0.51 %
MgO................................ 0.33 %
MnO............................ 0.0116 %
Na2O............................. 0.086 %
P2O5................................ 30.2 %

SiO2................................. 11.2 %
U ............................... 0.01414 %
V2O5 .............................. 0.031 %

Indicative values for, Cr2O3 , ZnO, TiO2

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Fertilizers
Code

Product

NRMGBW06501

Urea - Nitrogen

Unit

35 g

Certified values
Biuret ............................... 1.39%

N.................................... 46.30%

Indicative values for B, Ca, Fe, Mn

NRMGBW06502

Ammonium dihydrogen phosphate - Nitrogen and phosphorous

30 g

Certified values
P ................................... 26.85 %

N................................... 12.08 %

Indicative values for Ca, Fe, Mg

NRMGBW06503

Potassium sulphate - Potassium

40 g

Certified values
K ................................... 44.79 %
Indicative values for Ca, Fe, Mg, Mn

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Edition 2003/2004

57

Plants

Plants
Code

Product

Unit

Trees and bushes


BCR-062

Olive leaves (Olea europea) - Trace elements

25 g

Certified values
Al............................... 450 mg/kg
Cd ............................ 0.10 mg/kg
Cu ............................ 46.6 mg/kg

Hg.............................0.28 mg/kg
Mn ............................57.0 mg/kg
Pb .............................25.0 mg/kg

Zn............................. 16.0 mg/kg

Indicative values for Ag, As, Au, B, Br, CaO, Ce, Cl, Co, Cr, Cs, Eu, F, FeeO3, K2O, La, MgO, Mo, N, Na2O, Ni,
P2O5, Rb, S, Sb, Sc, Se, Sn, Tb, TiO2, Tl, U

BCR-100

Beech leaves - Trace elements

30 g

Certified values
Al............................... 0.435 g/kg
Ca ............................... 5.30 g/kg
Cl ................................ 1.49 g/kg

Cr.............................0.0080 g/kg
K ..................................9.94 g/kg
Mg .............................0.878 g/kg

N ............................... 26.29 g/kg


P ................................. 1.55 g/kg
S ................................. 2.69 g/kg

Indicative values for Cd, Cu, Fe, Mn, Mo, Pb, Zn

BCR-101

Spruce needles - Trace elements

30 g

Certified values
Al............................... 0.173 g/kg
Ca ............................... 4.28 g/kg
Cl .............................. 0.688 g/kg

Mg .............................0.619 g/kg
Mn .............................0.915 g/kg
N................................18.89 g/kg

P ................................. 1.69 g/kg


S ................................. 1.70 g/kg
Zn............................ 0.0353 g/kg

Indicative values for Cd, Cr, Cu, Fe, K, Mo, Pb

NIST-1575A

Pine needles - Trace elements and minor constituents

50 g

Certified values
P ................................... 0.107 %
K ................................... 0.417 %
Ca ................................... 0.25 %
Al............................... 580 mg/kg

NIST-1515

Ba ...............................6.0 mg/kg
Cd...........................0.233 mg/kg
Cl ...............................421 mg/kg
Cu.....................................2.g/kg

Fe................................ 46 mg/kg
Hg ........................ 0.0399 mg/kg
Rb ............................ 16.5 mg/kg
Zn................................ 38 mg/kg

Apple leaves - Trace elements

50 g

Dried leaves from Golden Delicious and Rome varieties.


Certified values
Al............................... 286 mg/kg
As........................... 0.038 mg/kg
B ................................. 27 mg/kg
Ba ............................... 49 mg/kg
Ca ................................. 1.526 %
Cd .......................... 0.013 mg/kg
Cl .............................. 579 mg/kg
Cu ............................ 5.64 mg/kg

Fe ................................83 mg/kg
Hg...........................0.044 mg/kg
K ..................................... 1.61 %
Mg ................................ 0.271 %
Mn ...............................54 mg/kg
Mo ..........................0.094 mg/kg
N..................................... 2.25 %
Na.............................24.4 mg/kg

Ni ............................. 0.91 mg/kg


P ................................... 0.159 %
Pb .......................... 0.470 mg/kg
Rb ............................ 10.2 mg/kg
Se .......................... 0.050 mg/kg
Sr ................................ 25 mg/kg
V .............................. 0.26 mg/kg
Zn............................. 12.5 mg/kg

Indicative values for Au, Br, Ce, Co, Cr, Eu, Gd, I, La, Nd, S, Sb, Sc, Sm, Sn, Tb, Th, U, W, Yb

NIST-1547

Peach leaves - Trace elements

50 g

Dried leaves from the Coronet variety.


Certified values
Al............................... 249 mg/kg
As........................... 0.060 mg/kg
B ................................. 29 mg/kg
Ba ............................. 124 mg/kg
Ca ................................... 1.56 %
Cd .......................... 0.026 mg/kg
Cl .............................. 360 mg/kg
Cu .............................. 3.7 mg/kg

Fe ..............................218 mg/kg
Hg...........................0.031 mg/kg
K ..................................... 2.43 %
Mg ................................ 0.432 %
Mn ...............................98 mg/kg
Mo ..........................0.060 mg/kg
N..................................... 2.94 %
Na................................24 mg/kg

Ni ............................. 0.69 mg/kg


P ................................... 0.137 %
Pb ............................ 0.87 mg/kg
Rb ............................ 19.7 mg/kg
Se .......................... 0.120 mg/kg
Sr ................................ 53 mg/kg
V .............................. 0.37 mg/kg
Zn............................. 17.9 mg/kg

Indicative values for Br, Ce, Co, Cr, Eu, Gd, I, La, Nd, S, Sb, Sc, Sm, Sn, Tb, Th, U, Yb

NRMGBW08501

Peach leaves - Trace elements

30 g

Certified values
As................................ 0.34 g/g
Ba ............................... 18.4 g/g
Cd ............................. 0.018 g/g
Cs ............................... 10.4 g/g
Cr ................................ 0.94 g/g

Fe .................................431 g/g
Hg..............................0.046 g/g
K ..................................... 2.17 %
Mg .................................. 0.47 %
Mn ...............................75.4 g/g

Pb ............................... 0.99 g/g


Sr ................................ 61.6 g/g
Zn................................ 22.8 g/g

Indicative values for B, Co, Se

58

Edition 2003/2004

www.lgcpromochem.com

Plants
Code

Product

Unit

NRMGBW07604

Poplar leaves - Trace elements

35 g

Certified values
Al................................... 0.104 %
As................................ 0.37 g/g
B .................................... 53 g/g
Ba .................................. 26 g/g
Be ............................. 0.021 g/g
Bi............................... 0.027 g/g
Br .................................. 7.2 g/g
Ca ................................... 1.81 %
Cd ............................... 0.32 g/g
Ce ............................... 0.49 g/g
Co ............................... 0.42 g/g
Cr ................................ 0.55 g/g
Cs ............................. 0.053 g/g
Cu ................................. 9.3 g/g

Eu ..............................0.009 g/g
F .....................................22 g/g
Fe .................................274 g/g
Hg..............................0.026 g/g
K ..................................... 1.38 %
La ................................0.26 g/g
Li..................................0.84 g/g
Mg .................................. 0.65 %
Mn ..................................45 g/g
Mo ...............................0.28 g/g
N..................................... 2.56 %
Na.................................200 g/g
Ni ...................................1.9 g/g
P .................................1680 g/g

Pb ................................. 1.5 g/g


Rb ................................. 7.6 g/g
S ..................................... 0.35 %
Sb ............................. 0.045 g/g
Sc.............................. 0.069 g/g
Se ............................... 0.14 g/g
Si..................................... 0.71 %
Sm ............................ 0.038 g/g
Sr ................................. 154 g/g
Th................................ 0.07 g/g
Ti................................. 20.4 g/g
Yb.............................. 0.018 g/g
Y................................ 0.145 g/g
Zn................................... 37 g/g

Indicative values for Ag, Cl, Dy, Gd, Hf, Nd, U, V

NRMGBW07602

Bush branches and leaves - Trace elements

35 g

Certified values
Ag ............................. 0.027 g/g
Al................................... 0.214 %
As................................ 0.95 g/g
B .................................... 34 g/g
Ba .................................. 19 g/g
Be ............................. 0.056 g/g
Bi............................... 0.027 g/g
Br .................................. 2.4 g/g
Ca ................................... 2.22 %
Cd ............................... 0.14 g/g
Ce ................................. 2.4 g/g
Co ............................... 0.39 g/g
Cr .................................. 2.3 g/g
Cs ............................... 0.27 g/g
Cu ................................. 5.2 g/g

Eu ..............................0.037 g/g
F .....................................24 g/g
Fe ...............................1020 g/g
Hf.................................0.14 g/g
K ..................................... 0.85 %
La ................................1.23 g/g
Li....................................2.4 g/g
Mg ................................ 0.287 %
Mn ..................................58 g/g
Mo ...............................0.26 g/g
N..................................... 1.20 %
Na................................... 1.10 %
Ni ...................................1.7 g/g
P ...................................830 g/g
Pb ..................................7.1 g/g

Rb ................................. 4.2 g/g


S ..................................... 0.32 %
Sb ............................. 0.045 g/g
Sc................................ 0.31 g/g
Se ............................. 0.184 g/g
Si..................................... 0.58 %
Sm ............................... 0.19g/g
Sr ................................. 345 g/g
Th................................ 0.37 g/g
Ti.................................... 95 g/g
V ................................... 2.4 g/g
Yb.............................. 0.063 g/g
Zn................................ 20.6 g/g

Indicative values for Cl, Nd, Tb, U, W, Y

NRMGBW07603

Bush branches and leaves - Trace elements

35 g

Certified values
Ag ............................. 0.049 g/g
Al..................................... 0.20 %
As................................ 1.25 g/g
B .................................... 38 g/g
Ba .................................. 18 g/g
Be ............................. 0.051 g/g
Bi............................... 0.023 g/g
Br .................................. 3.0 g/g
Ca ................................... 1.68 %
Ce ................................. 2.2 g/g
Co ............................... 0.41 g/g
Cr .................................. 2.6 g/g
Cs ............................... 0.27 g/g
Cu ................................. 6.6 g/g
Eu ............................. 0.039 g/g

F .....................................23 g/g
Fe ..............................1070 g/g
Hf.................................0.14 g/g
K ..................................... 0.92 %
La ................................1.25 g/g
Li....................................2.6 g/g
Mg .................................. 0.48 %
Mn ..................................61 g/g
Mo ...............................0.28 g/g
N..................................... 1.50 %
Na................................... 1.96 %
Nd..................................1.0 g/g
Ni ...................................1.7 g/g
P .................................1000 g/g
Pb ...................................47 g/g

Rb ................................. 4.5 g/g


S ..................................... 0.73 %
Sb ............................. 0.095 g/g
Sc................................ 0.32 g/g
Se ............................... 0.12 g/g
Si..................................... 0.60 %
Sm .............................. 0.19 g/g
Sr ................................. 246 g/g
Tb.............................. 0.025 g/g
Th................................ 0.36 g/g
Ti.................................... 95 g/g
V ................................... 2.4 g/g
Y.................................. 0.68 g/g
Yb.............................. 0.063 g/g
Zn................................... 55 g/g

Indicative values for Cd, Cl, Dy, Gd, Hf, Ho, Lu, Pr, Sn, U, W

IC-CTA-OTL1

Oriental tobacco leaves - Trace elements

50 g

Produced in Poland from oriental tobacco leaves grown in Bulgaria, and air dried before processing.
Certified values
Al................................ 1740 g/g
As.............................. 0.539 g/g
Ba ............................... 84.2 g/g
Br ................................ 9.28 g/g
Ca .............................. 31.7 mg/g
Cd ............................... 1.12 g/g
Ce ............................... 2.69 g/g
Co ............................. 0.879 g/g
Cr ................................ 2.59 g/g
Cs ............................. 0.177 g/g

Cu................................14.1 g/g
Eu ..............................0.038 g/g
La ................................1.44 g/g
Li.....................................23 g/g
K .................................15.6 mg/g
Mg ..............................4470 g/g
Mn ................................412 g/g
Ni .................................6.32 g/g
P .................................2892 g/g
Pb ................................4.91 g/g

Rb ............................... 9.79 g/g


S ................................ 7.32 mg/g
Se ............................. 0.153 g/g
Sm ............................ 0.229 g/g
Sr ................................. 201 g/g
Tb.............................. 0.032 g/g
Th.............................. 0.348 g/g
V ................................. 3.08 g/g
Zn................................ 49.9 g/g

Uncertified values for trace elements Au, CI, Fe, Hf, Hg, Mo, Na, Sb, Sc, U and Yb

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Edition 2003/2004

59

Plants
Code

IC-CTA-VTL2

Product

Unit

Virginia tobacco leaves - Trace elements

25 g

Produced in Poland from Virginia Tobacco leaves grown in Bulgaria, and air dried before processing.
Certified values
As.............................. 0.969 g/g
Ba ............................... 42.7 g/g
Br .................................. 4.3 g/g
Ca .............................. 3.60 wt %
Cd ............................... 1.52 g/g
Ce ............................... 1.91 g/g
Cl ............................. 0.743 wt %
Co ............................. 0.429 g/g
Cr ................................ 1.87 g/g
Cs ............................. 0.515 g/g
Cu ............................... 18.2 g/g

Fe ...............................1083 g/g
Hf...............................0.118 g/g
Hg..............................0.048 g/g
K ................................ 1.03 wt. %
La ................................1.01 g/g
Li..................................23.0 g/g
Mg ........................... 0.510 wt. %
Mn ...............................79.7 g/g
Mo ...............................2.01 g/g
Ni .................................1.98 g/g
P .................................2204 g/g

Pb ............................... 22.1 g/g


Rb ............................... 48.6 g/g
Sb ............................. 0.312 g/g
Sm ............................ 0.157 g/g
Sr ................................. 110 g/g
Tb.............................. 0.022 g/g
Th.............................. 0.378 g/g
U ............................... 0.163 g/g
V ................................. 4.00 g/g
W .............................. 0.233 g/g
Zn................................ 43.3 g/g

Informational values for AI, Eu, Na, S, Sc, Se, Si, Ta, Ti and Yb

IC-INCT-TL-1

Tea leaves - Trace elements

50 g

The material was prepared from black tea, usually packed in tea bags.
Certified values
Al.............................. 0.229 wt %
As........................... 0.106 mg/kg
Ba ............................ 43.2 mg/kg
Br ............................. 12.3 mg/kg
Ca ............................ 0.582 wt %
Cd .......................... 0.030 mg/kg
Cl .............................. 573 mg/kg
Co .......................... 0.387 mg/kg
Cr ............................. 1.91 mg/kg
Cs ............................ 3.61 mg/kg
Cu ............................ 20.4 mg/kg

Eu ...........................0,050 mg/kg
Hg...........................0.005 mg/kg
K ................................. 1.70 wt %
La .............................1.00 mg/kg
Lu ...........................0.016 mg/kg
Mg ............................ 0.224 wt %
Mn ............................ 0.157 wt %
Na.............................24.7 mg/kg
Ni ..............................6.12 mg/kg
Pb .............................1.78 mg/kg
Rb.............................81.5 mg/kg

Sc........................... 0.266 mg/kg


Sm ......................... 0.177 mg/kg
Sr ............................. 20.8 mg/kg
Tb........................... 0.026 mg/kg
Th........................... 0.034 mg/kg
Tl............................ 0.063 mg/kg
V .............................. 1.97 mg/kg
Yb........................... 0.118 mg/kg
Zn............................. 34.7 mg/kg

Indicative values for B, Fe, Hf, Nd, P, Sb, Se, Ta, Ti and Tm

NRMGBW07605

Tea - Trace elements

35 g

Certified values
As................................ 0.28 g/g
B .................................... 15 g/g
Ba .................................. 58 g/g
Be ............................. 0.034 g/g
Bi............................... 0.063 g/g
Br .................................. 3.4 g/g
Ca ................................... 0.43 %
Cd ............................. 0.057 g/g
Ce ................................. 1.0 g/g
Co ............................... 0.18 g/g
Cr .................................. 0.8 g/g
Cs ............................... 0.29 g/g

Cu................................17.3 g/g
Eu ..............................0.018 g/g
F ...................................320 g/g
Fe .................................264 g/g
K ..................................... 1.66 %
Mg .................................. 0.17 %
Mn ..............................1240 g/g
Mo .............................0.038 g/g
N..................................... 3.32 %
Na...................................44 g/g
Ni ...................................4.6 g/g
P .................................2840 g/g

Pb ................................. 4.4 g/g


Rb .................................. 74 g/g
S ................................... 0.245 %
Sb ............................. 0.056 g/g
Sc.............................. 0.085 g/g
Sm ............................ 0.085 g/g
Sr ................................ 15.2 g/g
Th.............................. 0.061 g/g
Ti.................................... 24 g/g
Y.................................. 0.36 g/g
Yb.............................. 0.044 g/g
Zn................................ 26.3 g/g

Indicative values for Ag, Al, Dy, Gd, Hf, Hg, Ho, Li, Lu, Nd, Pr, Se, Si, Tb, V

BCR-683

Wood - PCP and PAHs


Compound

60 g
Certified value
mg/kg

Uncertainty
mg/kg

Pentachlorophenol............................................... 3.6............................ 0.5


Benzo(a)anthracene ............................................ 6.5............................ 0.7
Benzo(a)pyrene ................................................... 3.4............................ 0.4
Benzo(e)pyrene ................................................... 9.3............................ 1.0
Benzo(b)fluoranthene .......................................... 5.8............................ 0.6
Benzo(k)fluoranthene ........................................ 2.58.......................... 0.29

Grasses and crops


BCR-129

Hay powder - Trace elements

30 g

Certified values
Ca ................................. 6.4 g/kg
I .............................. 0.167 mg/kg
K ................................. 33.8 g/kg

Mg ...............................1.45 g/kg
N..................................37.2 g/kg
P ..................................2.36 g/kg

S ................................. 3.16 g/kg


Zn............................ 0.0321 g/kg
Kjeldahl-N ................... 34.2 g/kg

Indicative values for Cu, Fe, Mo, Se

IAEA-V-10

Hay - Trace elements

50 g

Certified values
Ba ................................. 6 mg/kg
Br .................................. 8 mg/kg
Ca ......................... 21600 mg/kg
Cd ............................ 0.03 mg/kg
Co ............................ 0.13 mg/kg
Cr ............................... 6.5 mg/kg

Cu...............................9.4 mg/kg
Fe ..............................185 mg/kg
Hg...........................0.013 mg/kg
Mg ...........................1360 mg/kg
Mo ..............................0.9 mg/kg
Ni ...................................4 mg/kg

P ............................. 2300 mg/kg


Pb .............................. 1.6 mg/kg
Rb .............................. 7.6 mg/kg
Sc........................... 0.014 mg/kg
Sr ................................ 40 mg/kg
Zn................................ 24 mg/kg

Indicative values for Al, K, Mn, Na

60

Edition 2003/2004

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Plants
Code

NIST-2695

Product

Unit

Vegetation - Fluoride

2 x 25 g

Two samples of timothy grass with fluoride concentrations above natural levels.
Low level
Certified value
Fluoride....................... 64.0 g/g
High level
Certified value
Fluoride........................ 277 g/g

IAEA-373

Grass - Radioactive isotopes

200 g

Certified values
134

40

127

90

Cs......................... 1167 Bq/kg


Cs....................... 12350 Bq/kg

NIST-RM 8412

K ............................. 432 Bq/kg


Sr .......................... 1312 Bq/kg

Corn (Zea Mays) stalk - Trace elements

34 g

Reference concentration values for major, minor and trace elements. Indicative values for additional elements.

NIST-RM 8413

Corn (Zea Mays) kernel - Trace elements

47 g

Reference values for Al, Ca, Cl, Cu, F, I, K, Mg, Mn, N, Se, Zn

IAEA-V-9

Cellulose (cotton) - Trace elements

25 g

Certified values
Ba ................................. 9 mg/kg
Ca ............................. 240 mg/kg
Cl .............................. 600 mg/kg
Cr ............................. 0.11 mg/kg
Cu ............................ 0.59 mg/kg

Hg.............................0.06 mg/kg
Mg ...............................53 mg/kg
Mn ............................0.15 mg/kg
Mo ..........................0.034 mg/kg
Na................................56 mg/kg

Ni ............................. 0.09 mg/kg


Pb ............................ 0.25 mg/kg
Sr ............................. 0.65 mg/kg

Indicative values for Al, Br, Fe, V

BCR-402

White clover - Trace elements

25 g

Collected from an area with soil especially rich in selenium, resulting in a high selenium content
Certified values
As........................... 0.093 mg/kg
Co .......................... 0.178 mg/kg

Mo ............................6.93 mg/kg
Se .............................6.70 mg/kg

Indicative values for Cr, Fe, Ni, Zn

IAEA-156

Clover - Radioactive isotopes

250 g

Certified values
134

40

137

90

Cs........................... 132 Bq/kg


Cs........................... 264 Bq/kg

K ............................. 657 Bq/kg


Sr ........................... 14.8 Bq/kg

Aquatic plants
BCR-060

Aquatic plant (Lagarosiphon major) - Trace elements

25 g

Certified values
Al............................. 4180 mg/kg
Cd ............................ 2.20 mg/kg
Cu ............................ 51.2 mg/kg

Hg.............................0.34 mg/kg
Mn ...........................1759 mg/kg
Pb .............................63.8 mg/kg

Zn.............................. 313 mg/kg

Indicative values for Ag, As, Au, B, Br, CaO, Ce, Cl, Co, Cr, Cs, Eu, F, FeeO3, K2O, La, MgO, Mo, N, Na2O, Ni,
P2O5, Rb, S, Sb, Sc, Se, SiO2, Sn, Ta, Tb, TiO2, Tl, U, V, W

BCR-596

Aquatic plant (trapa natans) - Chromium

25 g

Certified value
Cr ............................. 36.3 mg/kg

BCR-279

Sea lettuce (ulva lactuca) - Trace elements

35 g

Certified values
As............................. 3.09 mg/kg
Cd .......................... 0.274 mg/kg

Cu...........................13.14 mg/kg
Pb ...........................13.48 mg/kg

Se .......................... 0.593 mg/kg


Zn............................. 51.3 mg/kg

Indicative values for B, C, Ca, Cl, Cr, Fe, Hg, I, K, Mg, Mn, N, P

BCR-670

Aquatic plant (Lemna minor) - Trace elements

10 g

Certified values
Ce .............................. 987 g/kg
Dy.............................. 78.9 g/kg
Er .............................. 44.0 g/kg
Eu ............................ 23.2 g/kg
Gd ............................. 97.8 g/kg
Ho ............................. 15.8 g/kg

La ...............................487 g/kg
Lu ..............................6.33 g/kg
Nd...............................473 g/kg
Pr................................121 g/kg
Sc ...............................191 g/kg
Sm .............................94.2 g/kg

Tb.............................. 14.0 g/kg


Th............................... 159 g/kg
Tm............................. 5.70 g/kg
U ................................ 81.7g/kg
Y................................. 462 g/kg
Yb.............................. 39.9 g/kg

Indicative values for : As, Cd, Cr, Cs, Cu, Fe, Mo, Ni, Pb, Sb, Se and Zn

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Edition 2003/2004

61

Plants
Code

IAEA-140OC

Product

Unit

Fucus (sea plant homogenate) - Organic contaminants

35 g

Certified values
beta-HCH..................................................... 4.6 ng/g
4,4-DDE ...................................................... 1.2 ng/g
4,4-DDD .................................................... 0.72 ng/g
4,4-DDT ...................................................... 2.2 ng/g
Dieldrin......................................................... 1.7 ng/g
HCB ............................................................. 1.3 ng/g
alpha-HCH ................................................... 1.4 ng/g
gamma-HCH................................................. 11 ng/g
Heptachlor ...................................................... 3 ng/g
Heptachlor epoxide .................................... 0.79 ng/g
Aldrin.......................................................... 0.76 ng/g
Endrin ........................................................ 0.71 ng/g
alpha-Endosulfan......................................... 0.9 ng/g
alpha-Chlordane .......................................... 1.4 ng/g
Aroclor 1254 ................................................. 25 ng/g
Aroclor 1260 ................................................. 12 ng/g
Total Aliphatics ....................................... 27000 ng/g
n-C17 .......................................................... 890 ng/g
Pristane......................................................... 50 ng/g
n-C18 ............................................................ 99 ng/g
Phytane......................................................... 56 ng/g
Sum n Alkanes (C14-C34)...................... 11000 ng/g
Phenanthrene ............................................... 76 ng/g
2-Methylphenanthrene .................................. 19 ng/g
1-Methylphenanthrene .................................. 11 ng/g
Anthracene ................................................... 14 ng/g
Chrysene....................................................... 40 ng/g
Fluoranthene................................................. 88 ng/g
Pyrene........................................................... 67 ng/g
Benzo(k)fluoranthene ................................... 19 ng/g
Benzo(a)anthracene ..................................... 25 ng/g
Benzo(e)pyrene ............................................ 26 ng/g
Benzo(a)pyrene ............................................ 20 ng/g
Naphthalene ................................................. 17 ng/g
Benzo(ghi)perylene....................................... 20 ng/g

IAEA-140TM

Indeno(1,2,3-cd)pyrene ................................. 33 ng/g


UVF equval. Chrysene .............................. 3500 ng/g
UVF equival. ROPME oil......................... 29000 ng/g
Resolved Aliphatics................................. 13000 ng/g
Unresolved Aliphatics ............................. 26000 ng/g
Total Aromatics ......................................... 5800 ng/g
Resolved Aromatics .................................... 350 ng/g
Unresolved Aromatics............................... 8100 ng/g
Fluorene ....................................................... 6.5 ng/g
Benzo(b)fluoranthene.................................... 37 ng/g
Perylene .......................................................... 5 ng/g
1-Methylnaphthalene..................................... 13 ng/g
2-Methylnaphthalene..................................... 16 ng/g
PCB 18......................................................... 1.5 ng/g
PCB 28......................................................... 1.7 ng/g
PCB 31......................................................... 1.8 ng/g
PCB 44............................................................ 2 ng/g
PCB 49......................................................... 1.6 ng/g
PCB 52......................................................... 3.8 ng/g
PCB 66....................................................... 0.89 ng/g
PCB 70......................................................... 1.8 ng/g
PCB 77....................................................... 0.19 ng/g
PCB 87......................................................... 1.6 ng/g
PCB 99......................................................... 0.9 ng/g
PCB 101....................................................... 2.4 ng/g
PCB 105..................................................... 0.49 ng/g
PCB 118.......................................................... 1 ng/g
PCB 138....................................................... 1.7 ng/g
PCB 149....................................................... 1.2 ng/g
PCB 153....................................................... 1.7 ng/g
PCB 156..................................................... 0.17 ng/g
PCB 170..................................................... 0.21 ng/g
PCB 180..................................................... 0.43 ng/g
PCB 187..................................................... 0.38 ng/g

Fucus (sea plant homogenate) - Trace elements and methylmercury

14 g

Certified values
As............................. 44.3 mg/kg
Br .............................. 567 mg/kg
Ca ......................... 12730 mg/kg
Cd .......................... 0.537 mg/kg
Co .......................... 0.876 mg/kg
Cr ............................. 10.4 mg/kg
Cu ............................ 5.05 mg/kg
Fe............................ 1256 mg/kg
Hg .......................... 0.038 mg/kg

K ............................31100 mg/kg
Li...............................2.29 mg/kg
Mg ...........................9070 mg/kg
Mn ............................56.1 mg/kg
Mo ............................2.65 mg/kg
Na..........................32000 mg/kg
Ni ..............................3.79 mg/kg
Pb .............................2.19 mg/kg
Rb.............................16.4 mg/kg

Sb .......................... 0.103 mg/kg


Sr .............................. 750 mg/kg
Th........................... 0.299 mg/kg
U .............................. 0.73 mg/kg
V .............................. 3.67 mg/kg
Zn............................. 47.3 mg/kg
Methylmercury.. 0.000626 mg/kg

Indicative values for Ag, Al, Ba, Ce, Cs, Hf, La, Sc, Se, Sm

NIES03

Chlorella (green algae) - Trace elements

36 g

Certified values
Ca ................................... 0.49 %
Co ............................... 0.87 g/g
Cu ................................. 3.5 g/g

Fe ................................. 0.185 %
K ..................................... 1.24 %
Mg .................................. 0.33 %

Mn .................................. 69 g/g
Sr ................................... 40 g/g
Zn................................ 20.5 g/g

Indicative values for Cd, P, Pb, Sc

Miscellaneous
LGC7162

Strawberry leaves - Trace elements

20 g

The raw material was collected from a private farm in the Czech Republic. The mixture was cut and jet milled to
pass a 250 m nylon sieve. The resulting powder was homogenised, separated in 20 g portions and placed in
60mL bottles.
Certified Values
Ca .......................... 1.53 g/100 g
Mg ........................ 0.377 g/100 g
N ............................ 2.01 g/100 g
P .......................... 0.260 g/100 g
K ............................ 1.96 g/100 g
S .......................... 0.174 g/100 g

62

As .............................0.28 mg/kg
Ba ..............................107 mg/kg
Cd.............................0.17 mg/kg
Co.............................0.47 mg/kg
Cr..............................2.15 mg/kg
Fe ..............................818 mg/kg

Edition 2003/2004

Pb .............................. 1.8 mg/kg


Mn ............................. 171 mg/kg
Hg .......................... 0.027 mg/kg
Ni ............................... 2.6 mg/kg
Sr ................................ 64 mg/kg
Zn................................ 24 mg/kg

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Plants
Code

NIST-1570a

Product

Unit

Spinach leaves - Trace elements

60 g

Certified values
Al............................... 310 mg/kg
As........................... 0.068 mg/kg
B .............................. 37.6 mg/kg
Cd ............................ 2.89 mg/kg
Ca ................................. 1.527 %
Co ............................ 0.39 mg/kg
Cu ............................ 12.2 mg/kg

Hg...........................0.030 mg/kg
K ................................... 2.903 %
Mn ............................75.9 mg/kg
N..................................... 5.90 %
Na................................. 1.818 %
Ni ..............................2.14 mg/kg
P ................................... 0.518 %

Se .......................... 0.117 mg/kg


Sr ............................. 55.6 mg/kg
Th............................. 0.48 mg/kg
V ............................ 0.835 mg/kg
Zn............................. 30.9 mg/kg

Indicative values for Ba, Br, Ce, Cl, Cs, I, La, Mg, Mo, S, Sc, Sm, Sr, U

NIST-1573a

Tomato leaves - Trace elements

50 g

Certified values
Al............................... 598 mg/kg
As........................... 0.112 mg/kg
B .............................. 33.3 mg/kg
Cd ............................ 1.52 mg/kg
Ca ................................... 5.05 %
Co ............................ 0.57 mg/kg
Cr ............................. 1.99 mg/kg

Cu.............................4.70 mg/kg
Hg...........................0.034 mg/kg
K ..................................... 2.70 %
Mn .............................246 mg/kg
N..................................... 3.03 %
Na..............................136 mg/kg
Ni ..............................1.59 mg/kg

P ................................... 0.216 %
Rb .......................... 14.89 mg/kg
Sb .......................... 0.063 mg/kg
Se .......................... 0.054 mg/kg
V .............................. 0.57 mg/kg
Zn................................ 82 mg/kg

Indicative values for Eu, Gd, Mg, Pb, S, Sc, Sm, Sr, Th, U

IC-INCT-MPH-2

Mixed polish herbs - Trace elements

50 g

Fresh herbs collected in a non contaminated rural area were collected, mixed and processed as for drug
production by Herbapol S.A.
Certified values
Al............................... 670 mg/kg
As........................... 0.191 mg/kg
Ba ............................ 32.5 mg/kg
Br ............................. 7.71 mg/kg
Ca .............................. 1.08 wt %
Cd .......................... 0.199 mg/kg
Ce ............................ 1.12 mg/kg
Cl ............................. 0.284 wt %
Co .......................... 0.210 mg/kg
Cr ............................. 1.69 mg/kg
Cs .......................... 0.076 mg/kg
Cu ............................ 7.77 mg/kg

Eu ...........................0.016 mg/kg
Hf............................0.236 mg/kg
Hg...........................0.018 mg/kg
K ................................. 1.91 wt %
La ...........................0.571 mg/kg
Lu ...........................0.009 mg/kg
Mg ............................ 0.292 wt %
Mn .............................191 mg/kg
Nd...........................0.457 mg/kg
Ni ..............................1.57 mg/kg
Pb .............................2.16 mg/kg
Rb.............................10.7 mg/kg

S ............................. 0.241 wt %
Sb .......................... 0.066 mg/kg
Sc........................... 0.123 mg/kg
Sm ......................... 0.094 mg/kg
Sr ............................. 37.6 mg/kg
Ta........................... 0.019 mg/kg
Tb........................... 0.014 mg/kg
Th........................... 0.154 mg/kg
V ............................ 0.952 mg/kg
Yb........................... 0.053 mg/kg

Indicative values for P, Fe, Mo, Na, Ti, Tl, U and W

BCR-482

Lichen - Trace elements

15 g

Certified values
Al............................. 1103 mg/kg
As............................. 0.85 mg/kg
Cd ............................ 0.56 mg/kg

IAEA-336

Cr..............................4.12 mg/kg
Cu.............................7.03 mg/kg
Hg.............................0.48 mg/kg

Ni ............................. 2.47 mg/kg


Pb ............................ 40.9 mg/kg
Zn........................... 100.6 mg/kg

Lichen - Trace elements

20 g

Certified values
As............................. 0.63 mg/kg
Ba .............................. 6.4 mg/kg
Br ............................. 12.9 mg/kg
Ce ............................ 1.28 mg/kg
Co ............................ 0.29 mg/kg
Cs ............................ 0.11 mg/kg
Cu .............................. 3.6 mg/kg

Fe ..............................430 mg/kg
Hg...............................0.2 mg/kg
K ..............................1840 mg/kg
La .............................0.66 mg/kg
Mn ...............................63 mg/kg
Na..............................320 mg/kg
Sb ...........................0.073 mg/kg

Se ............................ 0.22 mg/kg


Sm ......................... 0.106 mg/kg
SR.............................. 9.3 mg/kg
Th............................. 0.14 mg/kg
Zn............................. 30.4 mg/kg

Indicative values for Al, Cd, Cl, Cr, Eu, Lu, Nd, P, Pb, Rb, Sc, Tb, V, Yb

BCR-302

Microcrystalline cellulose (water content above saturated solutions)

20 g

Intended to check the correct application of the COST procedure for determination of water sorption isotherms of
food. Water contents at ten water activities are given.

BCR-273

Single cell protein - Major elements

10 g

Certified value
Ca ............................. 11.97 g/kg
Fe.............................. 156 mg/kg

K ..................................2.22 g/kg
N................................121.6 g/kg

P ................................. 26.8 g/kg

Indicative values for Mg, N(Kjeldahl), Na, S

BCR-274

Single cell protein - Trace elements

10 g

Certified values
As............................... 132 g/kg
Cd ................................ 30 g/kg
Co ................................ 39 g/kg

Cu..............................13.1 g/kg
Mn ............................51.9 mg/kg
Pb .................................44 g/kg

Se ............................ 1.03 mg/kg


Zn................................ 42.7 g/g

Indicative values for F, I, Ni

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Edition 2003/2004

63

Solid fuels

Solid fuels
Code

BCR-180

Product

Unit

Gas coal - Elements, ash and gross calorific value

20 g

A high volatile, weakly coking coal of moderately high ash content.


Certified values
As............................. 4.23 mg/kg
C ............................... 760.1 g/kg
Cd .......................... 0.212 mg/kg
Cl .............................. 593 mg/kg
H ................................. 50.4 g/kg

Hg...........................0.123 mg/kg
Mn ............................34.3 mg/kg
N..................................14.4 g/kg
Pb .............................17.5 mg/kg
Se .............................1.32 mg/kg

V .............................. 19.3 mg/kg


Zn............................. 27.4 mg/kg
Ash.............................. 99.0 g/kg
GCV ........................31.89 MJ/kg

Indicative values for Al, B, Ba, Br, Ce, Co, Cr, Cu, Fe, K, La, Na, Ni, Rb, Sc, Th, Ti, Vol. matter

BCR-181

Coking coal - Elements, ash and gross calorific value

20 g

A high volatile, strongly coking coal of low ash and moderate sulphur content.
Certified values
As............................. 27.7 mg/kg
C ............................... 849.9 g/kg
Cd .......................... 0.051 mg/kg
Cl ................................ 1.38 g/kg
H ................................. 54.0 g/kg

Hg...........................0.138 mg/kg
N..................................17.8 g/kg
Pb .............................2.59 mg/kg
Se .............................1.15 mg/kg
V ...............................12.0 mg/kg

Zn............................... 8.4 mg/kg


Ash.............................. 18.5 g/kg
GCV ........................35.43 MJ/kg

Indicative values for Al, B, Br, Ce, Co, Cr, Cu, Fe, K, La, Mn, Na, Ni, Rb, Sc, Th, Ti, Vol. matter

BCR-182

Steam coal - Elements, ash and gross calorific value

20 g

A medium volatile coal of high ash content.


Certified values
C ............................... 732.9 g/kg
Cd .......................... 0.057 mg/kg
Cl ................................ 3.70 g/kg
Hg .......................... 0.040 mg/kg

Mn .............................195 mg/kg
N................................16.36 g/kg
Se .............................0.68 mg/kg
V ...............................24.3 mg/kg

Zn............................. 33.3 mg/kg


Ash............................ 122.7 g/kg
GCV ........................29.68 MJ/kg

Indicative values for Al, As, B, Br, Ce, Co, Cr, Cu, Fe, H, K, La, Mn, Na, Ni, Pb, Rb, Sc, Th, Ti, Vol. matter

BCR-065

Coal - Sulphur, ash and gross calorific value

150 g

Certified values
S ................................... 8.3 g/kg

BCR-331

Ash ..............................39.1 g/kg

Low volatile steam coal - Sulphur

GCV ......................34.915 MJ/kg

20 g

Certified value
S ................................. 4.99 g/kg

BCR-332

High volatile industrial coal - Sulphur

20 g

Certified value
S ................................. 9.61 g/kg

BCR-333

Coking steam coal - Sulphur

20 g

Certified value
S ............................... 13.44 g/kg

BCR-334

Anthracite - Sulphur

20 g

Certified value
S ............................... 16.09 g/kg

BCR-335

Flame coal - Sulphur

20 g

Certified value
S ................................. 50.8 g/kg

BCR-336

High volatile steam coal - Sulphur

20 g

Certified value
S ............................... 32.90 g/kg

BCR-460

Coal - Fluorine

40 g

Certified value
F................................ 225 mg/kg
Indicative value for Cl

NIST-1630A

Bitiminous coal - Chlorine and sulphur

50 g

Certified values
Cl ............................ 1144 mg/kg
S ................................... 1.462 %
Indicative values for Hg, Furnace ash, HHV2

64

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Solid fuels
Code

NIST-2682b

Product

Unit

Coal (sub-bituminous) - Sulphur, mercury and heat of combustion

50 g

Certified values
S ................................................................ 0.4917 %
Hg ...........................................................108.8 g/kg

Heat of combustion ................................25.66 MJ/kg

Indicative values for Ash content, Gross calorific value

NIST-2683b

Coal (bituminous) - Sulphur

50 g

Certified value
S ................................... 1.955 %
Indicative value for Furnace ash

NIST-2684b

Coal (bituminous) - Sulphur, mercury and heat of combustion

50 g

Certified values
S .................................................................. 3.076 %
Hg .............................................................97.4 g/kg

Heat of combustion ................................28.56 MJ/kg

Indicative values for Ash content, Gross calorific value

NIST-2692b

Coal (bituminous) - Sulphur and mercury

50 g

Certified values
S ................................................. 1.170 % 0.020 %

Hg........................................ 133.3 g/kg 4.1 g/kg

Reference values (dry basis) for ash content (mass fraction) and gross calorific value

NIST-2685

Coal (bituminous) - Sulphur and mercury

50 g

Certified values
S ................................... 4.730 %

Hg............................146.2 g/kg

Indicative values for Ash content, Gross calorific value

NIST-1632c

Coal (bituminous) - Elements

50 g

Certified values
H ...................................... 5.11%
S ................................... 1.462 %
Potassium ................... 0.1100 %
Chlorine ...................... 0.1139 %
Sb .......................... 0.461 mg/kg

Ba .............................41.1 mg/kg
Co.............................3.48 mg/kg
Mn ..........................13.04 mg/kg
Hg.........................0.0938 mg/kg
Rb.............................7.52 mg/kg

Selenium................ 1.326 mg/kg


Sodium................... 298.8 mg/kg
Strontium ................. 63.8 mg/kg
Thorium.................... 1.40 mg/kg
Zinc .......................... 12.1 mg/kg

Indicative values for Carbon (total), N , Si, Al, As, B, Br, Ca, Cd, Ce, Cr, Cs, Co, Eu, Fe, Hf, Mg, Ni, Pb, Sm,
Sc,Ti, U, V, Ash

NIST-1635

Coal - Trace elements

75 g

Certified values
As............................. 0.42 mg/kg
Cd ............................ 0.03 mg/kg
Cr ............................... 2.5 mg/kg
Cu .............................. 3.6 mg/kg
F............................... 25.9 mg/kg

Fe ................................. 0.239 %
Mn ............................21.4 mg/kg
Ni ..............................1.74 mg/kg
Pb ...............................1.9 mg/kg
S ................................. 0.3616 %

Se .............................. 0.9 mg/kg


Th............................. 0.62 mg/kg
U .............................. 0.24 mg/kg
V ................................ 5.2 mg/kg
Zn............................... 4.7 mg/kg

Indicative values for Al, Ce, Co, Eu, Ga, Hf, Hg, Na, Sb, Sc, Ti

NRMGBW11101c Coal - Elements and properties

50 g

Certified values
C .................................................................. 74.33 %
H .................................................................... 4.54 %
N .................................................................... 1.39 %
S .................................................................... 0.49 %

Ash................................................................. 9.23 %
Volatile matter .............................................. 32.88 %
Relative density (20C) ...................................... 1.41
Gross calorific value...............................30.05 MJ/kg

NRMGBW11102c Coal - Elements and properties

50 g

Certified values
C .................................................................. 46.54 %
H .................................................................... 3.05 %
N .................................................................... 0.86 %
S .................................................................... 1.40 %

Ash............................................................... 40.64 %
Volatile matter .............................................. 23.18 %
Relative density (20C) ...................................... 1.73
Gross calorific value...............................18.72 MJ/kg

NRMGBW11103b Coal - Elements and properties

50 g

Certified values
C .................................................................. 76.80 %
H .................................................................... 1.40 %
N .................................................................... 0.54 %
S .................................................................... 0.36 %

www.lgcpromochem.com

Ash............................................................... 17.39 %
Volatile matter ................................................ 6.59 %
Relative density (20C) ...................................... 1.86
Gross calorific value...............................26.84 MJ/kg

Edition 2003/2004

65

Solid fuels
Code

Product

Unit

NRMGBW11104b Coal - Elements and properties

50 g

Certified values
C .................................................................. 68.58 %
H .................................................................... 0.68 %
N .................................................................... 0.21 %
S .................................................................... 1.01 %

Ash............................................................... 26.35 %
Volatile matter ................................................ 5.94 %
Relative density (20C) ...................................... 2.10
Gross calorific value...............................23.03 MJ/kg

NRMGBW11105a Coal - Elements and properties

50 g

Certified values
C .................................................................. 76.45 %
H .................................................................... 3.33 %
N .................................................................... 1.17 %
S .................................................................... 1.73 %

Ash............................................................... 13.88 %
Volatile matter .............................................. 11.80 %
Relative density (20C) ...................................... 1.49
Gross calorific value...............................29.89 MJ/kg

NRMGBW11107b Coal - Elements and properties

50 g

Certified values
C .................................................................. 78.57 %
H .................................................................... 4.54 %
N .................................................................... 1.41 %
S .................................................................... 0.88 %

Ash................................................................. 8.43 %
Volatile matter .............................................. 28.89 %
Relative density (20C) ...................................... 1.39
Gross calorific value...............................31.94 MJ/kg

NRMGBW11108b Coal - Elements and properties

50 g

Certified values
C .................................................................. 72.28 %
H .................................................................... 4.60 %
N .................................................................... 1.32 %
S .................................................................... 1.93 %

Ash............................................................... 11.08 %
Volatile matter .............................................. 33.52 %
Relative density (20C) ...................................... 1.42
Gross calorific value...............................29.61 MJ/kg

NRMGBW11109b Coal - Elements and properties

50 g

Certified values
C .................................................................. 68.69 %
H .................................................................... 4.50 %
N .................................................................... 1.18 %
S .................................................................... 3.04 %

Ash............................................................... 13.89 %
Volatile matter .............................................. 34.08 %
Relative density (20C) ...................................... 1.45
Gross calorific value...............................28.32 MJ/kg

NRMGBW11110b Coal - Elements and properties

50 g

Certified values
C .................................................................. 58.75 %
H .................................................................... 2.64 %
N .................................................................... 0.92 %
S .................................................................... 4.70 %

Ash............................................................... 29.71 %
Volatile matter .............................................. 11.21 %
Relative density (20C) ...................................... 1.72
Gross calorific value...............................23.00 MJ/kg

NRMGBW11111a Coal - Elements and properties

50 g

Certified values
C .................................................................. 78.60 %
H .................................................................... 4.53 %
N .................................................................... 1.37 %
S .................................................................... 1.38 %

Ash................................................................. 9.99 %
Volatile matter .............................................. 25.22 %
Relative density (20C) ...................................... 1.38
Gross calorific value...............................32.12 MJ/kg

NRMGBW11112a Coal - Elements and properties

50 g

Certified values
C .................................................................. 69.05 %
H .................................................................... 3.04 %
N .................................................................... 1.03 %
S .................................................................... 2.20 %

Ash............................................................... 21.26 %
Volatile matter .............................................. 11.86 %
Relative density (20C) ...................................... 1.58
Gross calorific value...............................26.96 MJ/kg

NRMGBW11113a Coal - Elements and properties

50 g

Certified values
C .................................................................. 49.98 %
H .................................................................... 2.22 %
N .................................................................... 0.64 %
S .................................................................... 3.40 %

NIST-2775

Ash............................................................... 40.62 %
Volatile matter .............................................. 10.69 %
Relative density (20C) ...................................... 1.85
Gross calorific value...............................19.21 MJ/kg

Foundry coke - Sulphur

50 g

Certified value
S ................................. 0.5816 %
Indicative values for Furnace ash, Volatile matter

NIST-2776

Foundry coke - Sulphur, ash and volatile matter

50 g

Certified values
S ................................... 0.825 %
Furnace ash.................... 8.06 %
Volatile matter................. 0.98 %

66

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Solid fuels
Code

NIST-2718

Product

Unit

Green petroleum coke - Trace elements

50 g

Certified values
Al.............................. 16.5 mg/kg
Ca ............................. 174 mg/kg

Fe ..............................290 mg/kg
Ni ............................139.1 mg/kg

S ........................... 47032 mg/kg


V ............................... 302 mg/kg

Indicative values for C, Co, H, N, Na, Si, Ash, Volatile matter, Gross calorific value

NIST-2719

Calcinated petroleum coke - Trace elements

50 g

Certified values
Al.............................. 58.9 mg/kg
Ca ............................ 57.7 mg/kg

Fe ...........................201.6 mg/kg
Ni ...............................204 mg/kg

S ............................. 8877 mg/kg


V .............................. 58.6 mg/kg

Indicative values for C, Co, H, N, Na, Si, Ash, Volatile content, Gross calorific value

NRMGBW11106a Metallurgy coke - Phosphorous, sulphur and ash

90 g

Certified values
P ................................... 0.034 %
S ..................................... 0.58 %
Ash............................... 13.05 %,
Indicative values for Volatile matter, Calorific value

NJV 94-1

Energy peat (Carex) - Trace elements

50 g

Milled peat from Sweden with an approximate composition of 80:20 Carex: Sphagnum.
Certified values
Al................................... 0.090 %
Ca ................................... 1.02 %
Cd .......................... 0.062 mg/kg
Cl .................................. 0.028 %
Cu .............................. 2.0 mg/kg

Fe ................................... 0.39 %
Mg ................................ 0.077 %
Mn .............................. 0.0036 %
N..................................... 2.09 %
P ................................... 0.045 %

Pb .............................. 2.4 mg/kg


S ..................................... 0.29 %
Zn.................................. 9 mg/kg
Ash.................................. 4.07 %
Calorific value ...........22.3 MJ/kg

Indicative values for As, C, Cr, H, K, Na, Si, Ti, Volatile matter

NJV 94-2

Energy peat (sphagnum) - Trace elements

50 g

Sod peat from Sweden with an approximate composition of 90:10 Sphagnum: Peat wool.
Certified values
Al................................... 0.095 %
Ca ................................... 0.12 %
Cd ............................ 0.16 mg/kg
Cl .................................. 0.061 %
Cu .............................. 1.7 mg/kg

Fe ................................... 0.13 %
Mg .................................. 0.11 %
Mn .............................. 0.0008 %
N..................................... 1.10 %
P ................................... 0.024 %

Pb ............................ 10.1 mg/kg


S ................................... 0.217 %
Zn.................................. 9 mg/kg
Ash.................................. 1.57 %
Calorific value ...........21.8 MJ/kg

Indicative values for C, Cr, H, K, Na, Si, Ti, Volatile matter

NJV 94-3

Energy forest (salix) - Trace elements

50 g

Salix cultivated in Sweden.


Certified values
Ca ................................... 0.44 %
Cd .............................. 1.8 mg/kg
Cu .............................. 4.0 mg/kg
Fe................................ 0.0026 %
K ..................................... 0.20 %

Mg ................................ 0.034 %
Mn ................................ 0.006 %
N..................................... 0.37 %
P ..................................... 0.05 %
S ................................... 0.028 %

Zn................................ 75 mg/kg
Ash.................................. 1.56 %
Calorific value ...........19.5 MJ/kg

Indicative values for Al, C, Cl, H, Na, Si, Pb, Volatile matter

NJV 94-4

Energy grass (phalaris arudinaceae L.) - Trace elements

50 g

Spring harvested reed canary grass (Phalaris arudinaceae L.) from Sweden.
Certified values
Al..................................... 0.18 %
As............................... 0.4 mg/kg
Ca ................................... 0.21 %
Cd ............................ 0.09 mg/kg
Cl .................................. 0.058 %
Cr ............................... 3.4 mg/kg
Cu .............................. 6.8 mg/kg

Fe ................................. 0.106 %
K ..................................... 0.38 %
Mg ................................ 0.088 %
Mn ................................ 0.016 %
N..................................... 1.04 %
P ................................... 0.109 %
Pb ...............................2.1 mg/kg

S ................................... 0.132 %
Si....................................... 2.1 %
Zn................................ 42 mg/kg
Ash.................................. 6.87 %
Calorific value ...........18.5 MJ/kg

Indicative values for C, H, Na, Ti, Volatile matter

NJV 94-5

Wood fuel - Trace elements

50 g

Pine wood waste from a saw mill in Sweden with a composition of approximately 70:30 bark: chip
Certified values
Al................................... 0.026 %
As............................... 0.8 mg/kg
Ca ................................... 0.35 %
Cd ............................ 0.27 mg/kg
Cr ............................... 0.8 mg/kg
Cu .............................. 2.2 mg/kg

Fe ................................. 0.007 %
K ..................................... 0.09 %
Mg ................................ 0.030 %
Mn ................................ 0.021 %
Na................................. 0.004 %
P ................................... 0.021 %

Pb ............................ 0.68 mg/kg


S ................................... 0.018 %
Zn................................ 38 mg/kg
Ash................................... 1.22%
Calorific value ...........20.6 MJ/kg

Indicative values for C, Cl, H, N, Si, Ti, Volatile matter

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Edition 2003/2004

67

Oils and liquid fuels

Oils and liquid fuels


Code

LGC3000

Product

Unit

Gas oil - Sulphur

50 mL

Certified value
S ................................... 0.010 %

LGC3001

Gas oil - Sulphur

50 mL

Certified value
S ................................... 0.047 %

LGC3002

Gasoline - Benzene

5 x 5 mL

Certified value
Benzene.......................... 0.76 %

LGC3003

Gasoline - Benzene

5 x 5 mL

Certified value
Benzene.......................... 5.37 %

BCR-672 - BCR-107
In addition to national regulations, a Council Directive (93/12/EEC) specifies the maximum permissible
sulphur content of gas oils intended for combustion. These materials provide a means of checking
analytical processes and of calibrating automatic equipment in the range 0.02 to 1.0% S in gas oil.
BCR-672

Gas oil - Sulphur

8 mL

Certified value
S ................................. 0.0203 %

BCR-671

Gas oil - Sulphur

8 mL

Certified value
S ................................. 0.0452 %

BCR-104R

Gas oil - Sulphur

8 mL

Certified value
S ................................. 0.1019 %

BCR-105

Gas oil - Sulphur

25 g

Certified value
S ................................... 0.363 %

BCR-106

Gas oil - Sulphur

25 g

Certified value
S ................................... 0.502 %

BCR-107

Gas oil - Sulphur

25 g

Certified value
S ................................... 1.040 %

BCR-395

Gas oil

jar

Intended for verifying manual and automatic cold filter plugging point (CFPP) apparatus in relation to the method
EN 116
Certified value
CFPP ............................... -5.8C

SS99859-0

Gas oil - Total sulphur

50 mL

ASTM D4294-IP336: D2622, Total S in the range 0.12 to 0.97%m/m

LGC6147

Waste oil - PCBs

5 x 5 mL

Assessed values
PCB 28 .................... 0.27 mg/kg
PCB 52 ...................... 5.8 mg/kg
PCB 101 .................. 10.9 mg/kg
PCB 105 .................... 2.8 mg/kg

BCR-420

PCB 118.....................8.5 mg/kg


PCB 128.....................2.1 mg/kg
PCB 138.....................8.0 mg/kg
PCB 153.....................7.2 mg/kg

PCB 156 .................... 1.5 mg/kg


PCB 170 .................. 0.92 mg/kg
PCB 180 .................... 2.3 mg/kg

Waste mineral oil - PCBs (low level)

7.5 g

Certified values
PCB 28 .................... 0.61 mg/kg
PCB 101 .................. 1.45 mg/kg

68

PCB 118...................1.69 mg/kg


PCB 153...................0.92 mg/kg

Edition 2003/2004

PCB 180 ................ 0.195 mg/kg

www.lgcpromochem.com

Oils and liquid fuels


Code

BCR-449

Product

Unit

Waste mineral oil - PCBs (high level)

50 g

Certified values
PCB 28 ................... 0.80 mg/kg
PCB 52 ..................... 31.4mg/kg
PCB 101 .................. 57.2 mg/kg
PCB 105 .................. 17.4 mg/kg

RTC-CRM920

PCB 118...................46.6 mg/kg


PCB 128...................12.5 mg/kg
PCB 153...................39.0 mg/kg
PCB 156.....................6.9 mg/kg

PCB 170 .................... 6.6 mg/kg


PCB 180 .................. 10.4 mg/kg

Transformer oil - PCBs

10 mL

Certified value
Aroclor 1260 ............ 35.2 mg/kg

NIST-1818a

Lubricating base oil - Chlorine

set (5)

Set of 5 x 20 mL ampoules
Certified values
I Cl............................ 31.6 mg/kg
II Cl........................... 60.0 mg/kg
III Cl.......................... 78.2 mg/kg
IV C ........................ 154.4 mg/kg
V Cl ........................ 234.0 mg/kg

NIST-1819a

Lubricating base oil - Sulphur

set (5)

NIST-1819a consists of five lubricating base oils at different sulphur concentrations.


Certified values
I S........................... 423.5 mg/kg
II S.......................... 741.1 mg/kg
III S.......................... 4022 mg/kg
IV S ......................... 4689 mg/kg
V S .......................... 6135 mg/kg

NIST-1836

Lube base oil - Nitrogen

set (4)

Set of 4 x 5 mL vials
Certified values
I N .............................. 9.0 mg/kg
II N ........................... 50.9 mg/kg
III N ........................ 113.3 mg/kg
IV N ........................ 166.2 mg/kg

SS99863-0

Lube oil - Trace elements

50 mL

I ASTM-IP method ICP, Ca in the range 0.029 to 0.486 % m/m


II ASTM-IP method ICP, Mg in the range 0.001 to 0.124 %m/m
III ASTM-IP method ICP, P in the range 0.026 to 0.131 %m/m
IV ASTM-IP method ICP, Zn in the range 0.030 to 0.149 %m/m

NIST-1848

Lubricating oil additive package

100 g

Certified values
B ................................... 0.137 %
Ca ................................. 0.359 %
Cl ................................ 0.0927 %

Mg ................................ 0.821 %
P ................................... 0.788 %
S ................................. 2.3270 %

Zn..................... 0.873 0.022 %

Indicative values for H, N, Si, total base number by ASTM D 2896, total base number by ASTM D 4739*

NIST-1634c

Fuel oil - Trace elements

100 mL

Certified values
As......................... 0.1426 mg/kg
Co ........................ 0.1510 mg/kg

Ni ............................17.54 mg/kg
Se .........................0.1020 mg/kg

V ............................ 28.19 mg/kg

Indicative values for Ba, Cl, Na, S

SS99860-0

Fuel oil - Vanadium and nickel

50 mL

I ASTM-IP method IP288, V in the range 71.5 to 129.1 g/g


II ASTM-IP method IP288, Ni in the range 26.6 to 44.2 g/g

SS99861-0

Fuel oil - Aluminium and silicon

100 mL

I ASTM-IP method IP377, Al in the range 7.2 to 31.9 mg/kg,


II ASTM-IP method IP377, Si in the range 13.3 to 70.4 mg/kg

SS99862-0

Fuel oil - Total sulphur

50 mL

ASTM D4294-IP336: D2622, Total S in the range 2.04 to 3.27 %m/m

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Edition 2003/2004

69

Oils and liquid fuels


Code

Product

NIST-1580

Shale oil - PAHs

Unit

set (5)

Set of 5 x 2 mL ampoules
Certified values
Benzo[a]pyrene........... 21 mg/kg
Benzo[e]pyrene........... 18 mg/kg
Fluoranthene............... 54 mg/kg

NIST-1582

o-Cresol.....................385 mg/kg
Phenol .......................407 mg/kg
Perylene .....................3.4 mg/kg

Pyrene....................... 104 mg/kg


2,6-Dimethylphenol ... 175 mg/kg
Benzo[f]quinoline ........ 16 mg/kg

Petroleum crude oil - PAHs

set (5)

Set of 5 x 2 mL
Certified values
Benzo[a]anthracene... 3.0 mg/kg
Benzo[e]pyrene.......... 1.1 mg/kg

NIST-2721

Fluoranthene ..............2.5 mg/kg


Perylene ......................31 mg/kg

Crude oil (light-sour) - Sulphur and mercury

Phenanthrene ........... 101 mg/kg


Dibenzothiophene....... 33 mg/kg

5 x 10 mL

Certified values
S ................................. 1.5832 %

NIST-2722

Hg.................................53 ng/kg

Crude oil (heavy-sweet) - Sulphur and mercury

5 x 10 mL

Certified values
S ............................... 0.21037 %

NIST-1616a

Hg...............................144 ng/kg

Kerosine - Sulphur

100 mL

Certified value
S ............................... 0.01462 %

NIST-1617a

Kerosine - Sulphur

100 mL

Certified value
S ............................... 0.17307 %

NIST-2298

Reformulated gasoline - Sulphur

5 x 20 mL

Certified value
S ................................... 4.7 g/g

NIST-2299

Reformulated gasoline - Sulphur

5 x 20 mL

Certified value
S ................................. 13.6 g/g

SS99857-0

Kerosine - Naphthalenes

50 mL

ASTM D1840, Napthalenes in the range 1.69 to 4.23 %vol

SS99858-0

Kerosine - Total sulphur

50 mL

ASTM D429-IP336, Total S in the range 0.02 to 0.15 %m/m

NIST-1623c

Residual fuel oil - Sulphur

100 mL

Certified value
S ................................. 0.3806 %

NIST-1619b

Residual fuel oil - Sulphur

100 mL

Certified value
S ................................. 0.6960 %

NIST-1621e

Residual fuel oil - Sulphur

100 mL

Certified value
S ................................. 0.9480 %

NIST-1622e

Residual fuel oil - Sulphur

100 mL

Certified value
S ................................. 2.1468 %

NIST-2717a

Residual fuel oil - Sulphur

100 mL

Certified value
S ................................. 2.9957 %

NIST-1620c

Residual fuel oil - Sulphur

100 mL

Certified value
S ................................... 4.561 %

70

Edition 2003/2004

www.lgcpromochem.com

Oils and liquid fuels


Code

Product

Unit

IRMM-441 and IRMM-442


High purity n-heptane and isooctane intended for use as a primary standard in the octane rating of
motor and aviation fuels as specified in ASTM test methods (see Volume 05.04, Annual Book of
ASTM Standards) and in evaluating ASTM methods for chemical analysis of fuels by gas
chromatography (D2268).
IRMM-441

n-Heptane

100 mL

n-Heptane
Certified value: Purity by difference 99.985%
Impurities
Certified values
Total organics (other than n-Heptane)......... 0.012 %
Isooctane ..................................................... 0.007 %

IRMM-442

Water ........................................................... 0.003 %


Pb............................................................... <0.5 g/L

Isooctane

100 mL

Isooctane
Certified value: Purity by difference 99.985%
Impurities
Certified values
Total organics (other than Isooctane) ........... 0.011%
n-Heptane .................................................... 0.002 %

NIST-1815a

Water ........................................................... 0.004%,


Pb.................................................................. <1 g/L

n-Heptane

100 mL

Certified purity............. 99.987 %

NIST-1816a

Isooctane (2,2,4-Trimethylpentane)

100 mL

Certified purity............. 99.987 %

NIST-2713

Reference fuel - Lead

6 x 20 mL

Certified value
Pb ............................ 19.4 mg/kg

NIST-2714

Reference fuel - Lead

6 x 20 mL

Certified value
Pb ............................ 28.1 mg/kg

NIST-2724b

Diesel fuel oil - Sulphur

10 x 10 mL

Certified value
S ............................... 0.04265 %

NIST-2890

Water saturated octanol

5 x 2 mL

NIST-2890 is a solution of water saturated 1-octanol which is certified for its water content.
Certified values
Water ......................... 47.3 mg/g

NIST-RM 8505

Water.....................39.24 mg/mL

Crude oil - Vanadium (not certified)

275 mL

Reference value
V ............................... 390 mg/kg

NIST-RM 8506a

Transformer oil - Water (not certified)

set (5)

A unit of NIST-RM 8506a consists of five ampoules with each ampoule containing 9.5 mL of petroleum electrical
insulating oil.
The first coulometric value is the NIST result corrected for the coulometrically detected material present in the oil
that reacts with iodine but is not water (interfering substances). Because the correction is new, two additional
uncorrected values determined by the coulometric method in ASTM Standard D 1533-99 are provided: the NIST
result, and a consensus result obtained from an interlaboratory study conducted among 14 laboratories from
industry. The volumetric reference value, which has not been corrected for interfering substances, is significantly
different from the coulometric results. Applying the coulometrically determined correction for interfering
substances does not resolve this difference. The basis of the difference between coulometric and volumetric
results in this material has not been fully resolved.
Reference values for water content
NIST coulometric mass concentration of water, ASTM method minus interferences ...... 12.1 mg/kg 1.9 mg/kg
(NIST coulometric mass concentration of water, ASTM method..................................... 18.3 mg/kg 1.9 mg/kg)
(Consensus coulometric mass concentration of water, ASTM method: .......................... 21.2 mg/kg 1.7 mg/kg)
NIST volumetric mass concentration of water, modified ASTM method: ......................... 34.5 mg/kg 2.2 mg/kg

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Edition 2003/2004

71

Oils and liquid fuels


Code

NIST-RM 8507

Product

Unit

Mineral oil - Water (not certified)

set (5)

Set of 5 x 10 mL
Reference value
Water .......................... 47 mg/kg

NIST-RM 8509

Methanol - Water

set (5)

Set of 5 x 5 mL
Reference value
Water .......................... 93 mg/kg
Indicative values for Ag, Al, Cr, Cu, Fe, Mg, Mn, Mo, Na, Ni, Pb, S, Si, Sn, Ti, V, Zn

NIST-RM 8510

Methanol - Water

set (5)

Set of 5 x 5 mL
Reference value
Water ........................ 325 mg/kg

NIST-1083

Oil (base oil) - Wear metals

150 mL

Indicative values for Ag, Al, Cr, Cu, Fe, Mg, Mn, Mo, Na, Ni, Pb, S, Si, Sn, Ti, V, Zn

NIST-1084a

Oil - Wear metals

set (5)

Set of 5 x approx. 1.6 g of the oil blend


Certified values
Ag .......................... 101.4 mg/kg
Cr ............................. 98.3 mg/kg
Cu .......................... 100.0 mg/kg
Fe............................. 98.9 mg/kg

Mg ............................99.5 mg/kg
Mo ..........................100.3 mg/kg
Ni ..............................99.7 mg/kg
Pb ...........................101.1 mg/kg

Sn ............................ 97.2 mg/kg


Ti............................ 100.4 mg/kg
V .............................. 95.9 mg/kg

Indicative values for Al, S, Si

NIST-1085b

Oil - Wear metals

5 x 1.2 g

A unit of NIST-1085b consists of 10 ampoules: five 5 mL amber borosilicate ampoules, each containing
approximately 1.2 g of a blend of 21 constituent elements in a base oil at a nominal concentration of 300 mg/kg;
and five ampoules, each containing approximately 1.2 g of a matching base oil intended for use as an analytical
blank and for matrix matching.
Certified values
Ag ......................... 304.6 mg/kg
Ba .......................... 300.1 mg/kg
Cd .......................... 302.9 mg/kg
Cr ........................... 302.9 mg/kg
Cu .......................... 295.6 mg/kg

Mg ..........................297.3 mg/kg
Mn ..........................300.7 mg/kg
Mo ..........................300.6 mg/kg
Na...........................305.2 mg/kg
Ni ............................295.9 mg/kg

Pb .......................... 297.7 mg/kg


Sn .......................... 299.4 mg/kg
V ............................ 297.8 mg/kg
Zn.................. 296.8 6.8 mg/kg

Indicative values for Al, As, Cl, Fe, P, Si, Ti

NIST-1829

Reference fuel - Alcohols

set (6)

Certified values
Methanol ...................................................... 0.335 %
Ethanol......................................................... 11.39 %

NIST-1837

Methanol and t-butanol .....................10.33 + 6.63 %

Reference fuel - Methanol and t-butanol

set (5)

Certified values
Methanol and t-butanol ..................... 10.33 + 6.63 %

NIST-1838

Reference fuel - Ethanol

5 x 20 mL

Certified value
Ethanol.......................... 11.39 %

NIST-1839

Reference fuel - Methanol

set (5)

Certified value
Methanol ....................... 0.335 %

NIST-2286

Ethanol in gasoline - Oxygen and oxygenate

set (3)

Set of 3 x 20 mL
Certified values
Oxygenate....................... 5.73 %

NIST-2287

Oxygen ........................... 2.02 %

Ethanol in gasoline - Oxygen and oxygenate

set (3)

Set of 3 x 20 mL
Certified values
Oxygenate..................... 10.07 %

72

Oxygen ........................... 3.53 %

Edition 2003/2004

www.lgcpromochem.com

Oils and liquid fuels


Code

NIST-2288

Product

Unit

t-Amyl methyl ether in gasoline - Oxygen and oxygenate

set (3)

Set of 3 x 20 mL
Certified values
Oxygenate..................... 12.78 %

NIST-2289

Oxygen ........................... 2.02 %

t-Amyl methyl ether in gasoline - Oxygen and oxygenate

set (3)

Set of 3 x 20 mL
Certified values
Oxygenate..................... 17.30 %

NIST-2290

Oxygen ........................... 2.73 %

Ethyl t-butyl ether in gasoline - Oxygen and oxygenate

set (3)

Set of 3 x 20 mL
Certified values
Oxygenate..................... 12.78 %

NIST-2291

Oygen............................. 2.01 %

Ethyl-t-butyl ether in gasoline - Oxygen and oxygenate

set (3)

Set of 3 x 20 mL
Certified values
Oxygenate..................... 17.18 %

NIST-2292

Oxygen ........................... 2.70 %

Methyl t-butyl ether in gasoline - Oxygen and oxygenate

set (3)

A unit of NIST-2292 consists of two 20 mL ampoules ot the methyl-t-butyl ether in reference gasoline solution
each containing 18 mL, and one 20 ml ampoule containing 18 mL of the reference gasoline, intended for use as a
measurement blank.
Certified values
Oxygenate..................... 10.96 %

NIST-2293

Oxygen ........................... 2.00 %

Methyl t-butyl ether in gasoline - Oxygen and oxygenate

set (3)

A unit of NIST-2292 consists of two 20 mL ampoules ot the methyl-t-butyl ether in reference gasoline solution
each containing 18 mL, and one 20 ml ampoule containing 18 mL of the reference gasoline, intended for use as a
measurement blank.
Certified values
Oxygenate..................... 14.86 %

NIST-2294

Oxygen ........................... 2.71 %

Reformulated gasoline - Sulphur, benzene, MTBE and toluene

2 x 20 mL

Certified values
S (total) .................... 40.9 mg/kg
Benzene.......................... 1.03 %

MTBE ........................... 10.97 %


Toluene .......................... 8.29 %

Indicative values for a wide range of additional constituents

NIST-2295

Reformulated gasoline - Sulphur, benzene, MTBE and toluene

2 x 20 mL

Certified values
S (total) ..................... 308 mg/kg
Benzene......................... .0.99 %

MTBE ........................... 14.54 %


Toluene .......................... 7.89 %

Indicative values for a wide range of additional constituents

NIST-2296

Reformulated gasoline - Sulphur, benzene, MTBE and toluene

2 x 20 mL

Certified values
S (total) .................... 40.0 mg/kg
Benzene.......................... 1.01 %

MTBE ........................... 13.02 %


Toluene .......................... 8.02 %

Indicative values for a wide range of additional constituents

NIST-2297

Reformulated gasoline - Sulphur, benzene, MTBE and toluene

2 x 20 mL

Certified values
S (total) .................. 303.7 mg/kg
Benzene.......................... 1.04 %

MTBE ............................. 9.91 %


Toluene .......................... 8.27 %

Indicative values for a wide range of additional constituents

NRMGBW11201

Petroleum - Trace metals

20 mL

Certified values
Fe.................................. 7.7 g/g
Mg ............................... 1.39 g/g

Mn ...............................2.69 g/g
Na................................11.2 g/g

Ni ................................ 15.4 g/g

Indicative values for As, K

NRMGBW11202

Petroleum -Trace elements

20 mL

Certified values
Ca ............................... 2.57 g/g
Co ............................... 4.87 g/g

Fe ................................19.5 g/g
Ni ....................................99 g/g

V ................................. 2.28 g/g

Indicative value for Pb


www.lgcpromochem.com

Edition 2003/2004

73

Oils and liquid fuels


Code

SS99864-0

Product

Unit

Gasoline - Lead

5 x 5 mL

IP270 Pb in the range 0.0015 to 0.170 g/L, Pb X-ray in the range 0.0013 to 0.175 g/L

SS99865-0

Gasoline - Benzene

5 x 5 mL

ASTM D3606, Benzene in the range 1.82 to 2.94 %vol

Multi-test verification materials (MTVMs)


The Multi-Test Verification Materials (MTVMs) are unique because, unlike most other certified
reference materials, they enable a laboratory to use a single sample to validate different tests and
instrumentation. Each unit is supplied with certified data for multiple types of internationally accepted
test methods.
SS99850-0

SETA MTVM Kerosine

500 mL

Distillation IBP (method D86-IP123) 140-170 C, 100 mL


Distillation 10 % (method D86-IP123) 159-188 C, 100 mL
Distillation 50 % (method D86-IP123) 192-218 C, 100 mL
Distillation 90 % (method D86-IP123) 234-247 C, 100 mL
Distillation FBP (method D86-IP123) 248-263 C, 100 mL
Distillation residue (method D86-IP123) 1.10-1.24 %vol, 100 mL
Distillation loss (method D86-IP123) 0.30-0.49 %vol, 100 mL
Flashpoint (method IP170) 36.7-57.5 C, 85 mL
Freezing point (method D2386-IP16) 51.2 to -43.4C, 25 mL
Aniline point (method D611) 55.0-59.0 C, 10 mL
Aromatics FIA (method D1319-IP156) 18.1-22.7 %vol, 0.75 mL
Smoke rate (method D1322) 20.7-24.2 mm, 20 mL

SS99851-0

SETA MTVM Gas oil

500 mL

Density at 15 C (method D1298-IP160) 0.8252-0.8481 kg/L, 200 mL


Distillation IBP (method D86-IP123) 160-223 C, 100 mL
Distillation 10 % (method D86-IP123) 187-254 C, 100 mL
Distillation 50 % (method D86-IP123) 240-290 C, 100mL
Distillation 90 % (method D86-IP123) 304-341 C, 100 mL
Distillation FBP (method D86-IP123) 347-367 C, 100 mL
Distillation residue (method D86-IP123) 1.27-1.42 %vol, 100 mL
Distillation loss (method D86-IP123) 0.20-0.36 %vol, 100 mL
Flashpoint (method D93-IP34) 51.7-103C, 75 mL
Cloud point (method D2500-IP219) 15.9 to 3.8 C, 38 mL
CFPP (method IP309) 28.0 to 5.4 C, 45 mL
Pour point (method D97-IP15) 26.9 to 7.6 C, 38 mL
Kin. Visc. (40 C) (method D445-IP71) 2.15-3.70 mm2/s, up to 40 mL

SS99852-0

SETA MTVM Fuel oil

500 mL

Density at 15 C (method D1298-IP160) 0.9313-0.9909 kg/L, 200 mL


Pour point (method D97-IP15) 10.7 to 17.2 C, 38 mL
Kin. Visc. (50 C) (method D445-IP71) 38.9-993.3 mm2/s, up to 500 mL
Kin. Visc. (80 C) (method D445-IP71) 13.7-130 mm2/s, up to 500 mL
Kin. Visc. (100 C) (method D445-IP71) 8.4-53.8 mm2/s, up to 500 mL
Conradson carbon (method D189-IP13) 9.3-17.3 %m/m, 5 mL

SS99853-0

SETA MTVM lubricating oil

500 mL
2

Kin. Visc. (40 C) (method D445-IP71) 55.7-111.1 mm /s, up to 500mL


Kin. Visc. (100 C) (method D445-IP71) 7.7-14.7 mm2/s, up to 500mL
Viscosity index (method D2270-IP226) 102.0-149.5, up to 500 mL
Pour point (method D97-IP15) 34.9 to 20.5 C, 38 mL
Flashpoint (method D93-IP34) 198-213 C, 75 mL
Cold cranking sim. (method IP383) 1676-3462 mPa.s, 5 mL

SS99854-0

SETA MTVM motor gasoline

500 mL

Motor octane no. (method D2700) 85.7-87.8


Research octane no. (method D2699) 97-99.9
Density at 15 C (method D1298-IP160) 0.7214-0.7823 kg/L, 200 mL
Distillation IBP (method D86-IP123) 26.0-32.0 C, 100 mL
Distillation 70 C (method D86-IP123) 15.0-48.8 %vol, 100 mL
Distillation 100 C (method D86-IP123) 23.4-71.2 %vol, 100 mL
Distillation 140 C (method D86-IP123) 51.1-90.4 %vol, 100 mL
Distillation FBP (method D86-IP123) 170-218 C, 100mL
Aromatics FIA (method D1319-IP156) 27.7-45.2 %vol, 0.75 mL
Olefins FIA (method D1319-IP156) 7.6-23.6 %vol, 0.75 mL
Saturates FIA (method D1319-IP156) 40.7-55.0 %vol, 0.75 mL

SS99856-0

SETA MTVM bitumen

500 mL

Softening point (method IP58) 36.8-44 C, 7.5 mL


Needle penetration (method IP49) 184-200 C, 130 mL

74

Edition 2003/2004

www.lgcpromochem.com

Conostan Oil Analysis Standards

Conostan Oil Analysis Standards


Reference materials for lubricant/oil analysis include: Element (metallo-organic) standards and
associated blank oils and solvent (for ICP application), Particle Counting (contamination) standards
for Automatic Particle Counters, and FTIR Operational Test Standard. A proficiency test program for
analysis of important properties of lubricants (new & used) such as: wear & additive metals, particles,
and viscosity is offered (see About proficiency testing (PT) section OIL ANALYSIS).
Element (Metallo-organic) Standards (see JOAP Military Spectrometric Standards, page 83)

CONOSTAN Division is the world's leading manufacturer and marketer of Elements (metallo-organic)
in Oil standards and related spectroscopy products. CONOSTAN's industry leading position is derived
from superior product chemistry, manufacturing technology, and blending techniques. CONOSTAN
products are used extensively in the calibration and operation of analytical instruments for the
analysis of elements in oil and other organic fluids. CONOSTAN is the only source of multi-element
metallo-organic standards in the history of the National Institute of Standards & Technology (NIST),
for example, NIST-1085b is CONOSTAN S-21:300, Code CON-S214300 and CON-S218300. The
variety of products afford convenience as reference and routine analytical materials for ICP, DCP,

Rotating Disk Electrode (RDE), XRF, AA, and other analytical spectrometer techniques. CONOSTAN
products are optimized for:
- Compatability: 33 elements can be combined over an extensive concentration range

- Solubility: CONOSTAN element standards are soluble in CONOSTAN PremiSolv ICP solvent,

CONOSTAN base oils, ketones, such as 4-methyl-2-pentanone (MIBK), as well as in paraffinic and
aromatic hydrocarbons, such as mineral oil, xylene, and kerosene.

- Volatility: CONOSTAN element standards are made in ultra-pure, highly processed hydrocarbon oil
only; no solubilizers are used. These element standards are extremely stable to volatile loss.
- Viscosity: Viscosity range at room temperature is ideal for instrumental applications.
- Instrumental Response: Excellent analytical response over a wide range of analytical applications.
- Shelf life: All CONOSTAN element standards and spectroscopy products have a one year minimum
shelf life from the date of shipment.

Single element standards in oil

Single-element CONOSTAN standards are especially useful for atomic absoption and X-ray
fluorescence determinations. The matrix oil for these standards is high purity hydrocarbon oil with a
17 cSt viscosity at 40C and flash point of 175C (20 Base Oil). They are available at the following
metal concentrations.
The 1000 and 5000 ppm standards can be used as a source of single-element calibration standard for
your specific applications using all types of spectroscopic methods of analysis.
Cobalt 1000 & 5000 ppm, yttrium 1000 & 5000 ppm, and scandium 2000 ppm are often used as an
internal standards for inductive coupled plasma (ICP) analysis.
Stock concentrations are listed in the table below. Concentrations not listed in the table below are
available as custom single element standards on request.
Code

Product

CON-Al1000

Aluminium in 20 base oil, 1000 g/g

Al:1000 ppm

50 g

CON-Al5000

Aluminium in 20 base oil, 5000 g/g

Al:5000 ppm

50 g

CON-Sb1000

Antimony in 20 base oil, 1000 g/g

Sb:1000 ppm

50 g

CON-Sb5000

Antimony in 20 base oil, 5000 g/g

Sb:5000 ppm

50 g

CON-As100

Arsenic in 20 base oil, 100 g/g

As:100 ppm

100 g

CON-Ba1000

Barium in 20 base oil, 1000 g/g

Ba:1000 ppm

50 g

CON-Ba5000

Barium in 20 base oil, 5000 g/g

Ba:5000 ppm

50 g

CON-Be1000

Beryllium in 20 base oil, 1000 g/g

Be:1000 ppm

50 g

CON-Be5000

Beryllium in 20 base oil, 5000 g/g

Be:5000 ppm

50 g

CON-Bi1000

Bismuth in 20 base oil, 1000 g/g

Bi:1000 ppm

50 g

CON-Bi5000

Bismuth in 20 base oil, 5000 g/g

Bi:5000 ppm

50 g

www.lgcpromochem.com

Unit

Edition 2003/2004

75

Conostan Oil Analysis Standards


Code

Product

CON-B1000

Boron in 20 base oil, 1000 g/g

B:1000 ppm

50 g

CON-B5000

Boron in 20 base oil, 5000 g/g

B:5000 ppm

50 g

CON-Cd1000

Cadmium in 20 base oil, 1000 g/g

Cd:1000 ppm

50 g

CON-Cd5000

Cadmium in 20 base oil, 5000 g/g

Cd:5000 ppm

50 g

CON-Ca1000

Calcium in 20 base oil, 1000 g/g

Ca:1000 ppm

50 g

CON-Ca5000

Calcium in 20 base oil, 5000 g/g

Ca:5000 ppm

50 g

CON-Cr1000

Chromium in 20 base oil, 1000 g/g

Cr:1000 ppm

50 g

CON-Cr5000

Chromium in 20 base oil, 5000 g/g

Cr:5000 ppm

50 g

CON-Co1000

Cobalt in 20 base oil, 1000 g/g

Co:1000 ppm

50 g

CON-Co5000

Cobalt in 20 base oil, 5000 g/g

Co:5000 ppm

50 g

CON-Cu1000

Copper in 20 base oil, 1000 g/g

Cu:1000 ppm

50 g

CON-Cu5000

Copper in 20 base oil, 5000 g/g

Cu:5000 ppm

50 g

CON-In1000

Indium in 20 base oil, 1000 g/g

In:1000 ppm

50 g

CON-In5000

Indium in 20 base oil, 5000 g/g

In:5000 ppm

50 g

CON-Fe1000

Iron in 20 base oil, 1000 g/g

Fe:1000 ppm

50 g

CON-Fe5000

Iron in 20 base oil, 5000 g/g

Fe:5000 ppm

50 g

CON-La1000

Lanthanum in 20 base oil, 1000 g/g

La:1000 ppm

50 g

CON-La5000

Lanthanum in 20 base oil, 5000 g/g

La:5000 ppm

50 g

CON-Pb1000

Lead in 20 base oil, 1000 g/g

Pb:1000 ppm

50 g

CON-Pb5000

Lead in 20 base oil, 5000 g/g

Pb: 5000 ppm

50 g

CON-Li1000

Lithium in 20 base oil, 1000 g/g

Li:1000 ppm

50 g

CON-Li5000

Lithium in 20 base oil, 5000 g/g

Li:5000 ppm

50 g

CON-Mg1000

Magnesium in 20 base oil, 1000 g/g

Mg:1000 ppm

50 g

CON-Mg5000

Magnesium in 20 base oil, 5000 g/g

Mg:5000 ppm

50 g

CON-Mn1000

Manganese in 20 base oil, 1000 g/g

Mn:1000 ppm

50 g

CON-Mn5000

Manganese in 20 base oil, 5000 g/g

Mn:5000 ppm

50 g

CON-Hg100

Mercury in 20 base oil, 100 g/g

Hg:100 ppm

100 g

CON-Mo1000

Molybdenum in 20 base oil, 1000 g/g

Mo:1000 ppm

50 g

CON-Mo5000

Molybdenum in 20 base oil, 5000 g/g

Mo:5000 ppm

50 g

CON-Ni1000

Nickel in 20 base oil, 1000 g/g

Ni:1000 ppm

50 g

CON-Ni5000

Nickel in 20 base oil, 5000 g/g

Ni:5000 ppm

50 g

CON-P1000

Phosphorus in 20 base oil, 1000 g/g

P:1000 ppm

50 g

CON-P5000

Phosphorus in 20 base oil, 5000 g/g

P:5000 ppm

50 g

CON-K1000

Potassium in 20 base oil, 1000 g/g

K:1000 ppm

50 g

CON-K5000

Potassium in 20 base oil, 5000 g/g

K:5000 ppm

50 g

CON-Sc2000

Scandium in 20 base oil, 2000 g/g

Sc:2000 ppm

50 g

CON-Se100

Selenium in 20 base oil, 100 g/g

Se:100 ppm

100 g

CON-Si1000

Silicon in 20 base oil, 1000 g/g

Si:1000 ppm

50 g

76

Unit

Edition 2003/2004

www.lgcpromochem.com

Conostan Oil Analysis Standards


Code

Product

Unit

CON-Si5000

Silicon in 20 base oil, 5000 g/g

Si:5000 ppm

50 g

CON-Ag1000

Silver in 20 base oil, 1000 g/g

Al:1000 ppm

50 g

CON-Ag5000

Silver in 20 base oil, 5000 g/g

Ag:5000 ppm

50 g

CON-Na1000

Sodium in 20 base oil, 1000 g/g

Na:1000 ppm

50 g

CON-Na5000

Sodium in 20 base oil, 5000 g/g

Na:5000 ppm

50 g

CON-Sr1000

Strontium in 20 base oil, 1000 g/g

Sr:1000 ppm

50 g

CON-Sr5000

Strontium in 20 base oil, 5000 g/g

Sr:5000 ppm

50 g

CON-Sn1000

Tin in 20 base oil, 1000 g/g

Sn:1000 ppm

50 g

CON-Sn5000

Tin in 20 base oil, 5000 g/g

Sn:5000 ppm

50 g

CON-Ti1000

Titanium in 20 base oil, 1000 g/g

Ti:1000 ppm

50 g

CON-Ti5000

Titanium in 20 base oil, 5000 g/g

Ti:5000 ppm

50 g

CON-W1000

Tungsten in 20 base oil, 1000 g/g

W:1000 ppm

50 g

CON-W5000

Tungsten in 20 base oil, 5000 g/g

W:5000 ppm

50 g

CON-V1000

Vanadium in 20 base oil, 1000 g/g

V:1000 ppm

50 g

CON-V5000

Vanadium in 20 base oil, 5000 g/g

V:5000 ppm

50 g

CON-Y1000

Yttrium in 20 base oil, 1000 g/g

Y:1000 ppm

50 g

CON-Y5000

Yttrium in 20 base oil, 5000 g/g

Y:5000 ppm

50 g

CON-Zn1000

Zinc in 20 base oil, 1000 g/g

Zn:1000 ppm

50 g

CON-Zn5000

Zinc in 20 base oil, 5000 g/g

Zn:5000 ppm

50 g

Multi-element standards in oil

Multi-element Conostan standards are especially useful for ICP, RDE, and DCP
analysis of metals in oil. They are available in high purity hydrocarbon oil solutions and
are blended to approximately 70 cSt viscosity at 40C and flash point of 215C (75
Base Oil). They contain equal amounts of each element.
Concentrations not listed are available as custom multi-element standards on
request. You may create your own S-21 and S-12 standards by adding additional
elements to the stocked product standards, listed as follows.
CON-S21410

Multi-element standard in 75 base oil: S-21:10 ppm


Ag .................................. 10 g/g
Al.................................... 10 g/g
B .................................... 10 g/g
Ba .................................. 10 g/g
Ca .................................. 10 g/g
Cd .................................. 10 g/g
Cr ................................... 10 g/g

Cu...................................10 g/g
Fe ...................................10 g/g
Mg ..................................10 g/g
Mn ..................................10 g/g
Mo ..................................10 g/g
Na...................................10 g/g
Ni ....................................10 g/g

100 g
P .................................... 10 g/g
Pb .................................. 10 g/g
Si.................................... 10 g/g
Sn .................................. 10 g/g
Ti.................................... 10 g/g
V .................................... 10 g/g
Zn................................... 10 g/g

CON-S21810

Multi-element standard in 75 base oil: S-21:10 ppm

200 g

CON-S21430

Multi-element standard in 75 base oil: S-21:30 ppm

100 g

Ag .................................. 30 g/g
Al.................................... 30 g/g
B .................................... 30 g/g
Ba .................................. 30 g/g
Ca .................................. 30 g/g
Cd .................................. 30 g/g
Cr ................................... 30 g/g

CON-S21830

www.lgcpromochem.com

Cu...................................30 g/g
Fe ...................................30 g/g
Mg ..................................30 g/g
Mn ..................................30 g/g
Mo ..................................30 g/g
Na...................................30 g/g
Ni ....................................30 g/g

Multi-element standard in 75 base oil: S-21:30 ppm

Edition 2003/2004

P .................................... 30 g/g
Pb .................................. 30 g/g
Si.................................... 30 g/g
Sn .................................. 30 g/g
Ti.................................... 30 g/g
V .................................... 30 g/g
Zn................................... 30 g/g

200 g

77

Conostan Oil Analysis Standards


Code

CON-S21450

Product

Multi-element standard in 75 base oil: S-21:50 ppm


Ag .................................. 50 g/g
Al.................................... 50 g/g
B .................................... 50 g/g
Ba .................................. 50 g/g
Ca .................................. 50 g/g
Cd .................................. 50 g/g
Cr ................................... 50 g/g

CON-S21850
CON-S214100

CON-S214300

CON-S214500

CON-S214900

CON-S12410

CON-S12430

CON-S12450

78

Cu.................................300 g/g
Fe .................................300 g/g
Mg ................................300 g/g
Mn ................................300 g/g
Mo ................................300 g/g
Na.................................300 g/g
Ni ..................................300 g/g

100 g
P .................................. 300 g/g
Pb ................................ 300 g/g
Si.................................. 300 g/g
Sn ................................ 300 g/g
Ti.................................. 300 g/g
V .................................. 300 g/g
Zn................................. 300 g/g

200 g

Cu.................................500 g/g
Fe .................................500 g/g
Mg ................................500 g/g
Mn ................................500 g/g
Mo ................................500 g/g
Na.................................500 g/g
Ni ..................................500 g/g

100 g
P .................................. 500 g/g
Pb ................................ 500 g/g
Si.................................. 500 g/g
Sn ................................ 500 g/g
Ti.................................. 500 g/g
V .................................. 500 g/g
Zn................................. 500 g/g

Multi-element standard in 75 base oil: S-21:500 ppm

200 g

Multi-element standard in 75 base oil: S-21:900 ppm


Cu.................................900 g/g
Fe .................................900 g/g
Mg ................................900 g/g
Mn ................................900 g/g
Mo ................................900 g/g
Na.................................900 g/g
Ni ..................................900 g/g

100 g
P .................................. 900 g/g
Pb ................................ 900 g/g
Si.................................. 900 g/g
Sn ................................ 900 g/g
Ti.................................. 900 g/g
V .................................. 900 g/g
Zn................................. 900 g/g

Multi-element standard in 75 base oil: S-21:900 ppm

200 g

Multi-element standard in 75 base oil: S-12:10 ppm


Fe ...................................10 g/g
Mg ..................................10 g/g
Na...................................10 g/g
Ni ....................................10 g/g

100 g
Pb .................................. 10 g/g
Si.................................... 10 g/g
Sn .................................. 10 g/g
Ti.................................... 10 g/g

Multi-element standard in 75 base oil: S-12:10 ppm

200 g

Multi-element standard in 75 base oil: S-12:30 ppm


Fe ...................................30 g/g
Mg ..................................30 g/g
Na...................................30 g/g
Ni ....................................30 g/g

100 g
Pb .................................. 30 g/g
Si.................................... 30 g/g
Sn .................................. 30 g/g
Ti.................................... 30 g/g

Multi-element standard in 75 base oil: S-12:30 ppm

200 g

Multi-element standard in 75 base oil: S-12:50 ppm


Ag .................................. 50 g/g
Al.................................... 50 g/g
Cr ................................... 50 g/g
Cu .................................. 50 g/g

CON-S12850

200 g

Multi-element standard in 75 base oil: S-21:500 ppm

Ag .................................. 30 g/g
Al.................................... 30 g/g
Cr ................................... 30 g/g
Cu .................................. 30 g/g

CON-S12830

100 g
P .................................. 100 g/g
Pb ................................ 100 g/g
Si.................................. 100 g/g
Sn ................................ 100 g/g
Ti.................................. 100 g/g
V .................................. 100 g/g
Zn................................. 100 g/g

Multi-element standard in 75 base oil: S-21:300 ppm

Ag .................................. 10 g/g
Al.................................... 10 g/g
Cr ................................... 10 g/g
Cu .................................. 10 g/g

CON-S12810

Cu.................................100 g/g
Fe .................................100 g/g
Mg ................................100 g/g
Mn ................................100 g/g
Mo ................................100 g/g
Na.................................100 g/g
Ni ..................................100 g/g

Multi-element standard in 75 base oil: S-21:300 ppm

Ag ................................ 900 g/g


Al.................................. 900 g/g
B .................................. 900 g/g
Ba ................................ 900 g/g
Ca ................................ 900 g/g
Cd ................................ 900 g/g
Cr ................................. 900 g/g

CON-S218900

200 g

Multi-element standard in 75 base oil: S-21:100 ppm

Ag ................................ 500 g/g


Al.................................. 500 g/g
B .................................. 500 g/g
Ba ................................ 500 g/g
Ca ................................ 500 g/g
Cd ................................ 500 g/g
Cr ................................. 500 g/g

CON-S218500

100 g
P .................................... 50 g/g
Pb .................................. 50 g/g
Si.................................... 50 g/g
Sn .................................. 50 g/g
Ti.................................... 50 g/g
V .................................... 50 g/g
Zn................................... 50 g/g

Multi-element standard in 75 base oil: S-21:100 ppm

Ag ................................ 300 g/g


Al.................................. 300 g/g
B .................................. 300 g/g
Ba ................................ 300 g/g
Ca ................................ 300 g/g
Cd ................................ 300 g/g
Cr ................................. 300 g/g

CON-S218300

Cu...................................50 g/g
Fe ...................................50 g/g
Mg ..................................50 g/g
Mn ..................................50 g/g
Mo ..................................50 g/g
Na...................................50 g/g
Ni ....................................50 g/g

Multi-element standard in 75 base oil: S-21:50 ppm

Ag ................................ 100 g/g


Al.................................. 100 g/g
B .................................. 100 g/g
Ba ................................ 100 g/g
Ca ................................ 100 g/g
Cd ................................ 100 g/g
Cr ................................. 100 g/g

CON-S218100

Unit

Fe ...................................50 g/g
Mg ..................................50 g/g
Na...................................50 g/g
Ni ....................................50 g/g

Multi-element standard in 75 base oil: S-12:50 ppm

Edition 2003/2004

100 g
Pb .................................. 50 g/g
Si.................................... 50 g/g
Sn .................................. 50 g/g
Ti.................................... 50 g/g

200 g

www.lgcpromochem.com

Conostan Oil Analysis Standards


Code

CON-S124100

Product

Unit

Multi-element standard in 75 base oil: S-12:100 ppm


Ag ................................ 100 g/g
Al.................................. 100 g/g
Cr ................................. 100 g/g
Cu ................................ 100 g/g

Fe .................................100 g/g
Mg ................................100 g/g
Na.................................100 g/g
Ni ..................................100 g/g

100 g
Pb ................................ 100 g/g
Si.................................. 100 g/g
Sn ................................ 100 g/g
Ti.................................. 100 g/g

CON-S128100

Multi-element standard in 75 base oil: S-12:100 ppm

200 g

CON-S124300

Multi-element standard in 75 base oil: S-12:300 ppm

100 g

Ag ................................ 300 g/g


Al.................................. 300 g/g
Cr ................................. 300 g/g
Cu ................................ 300 g/g

CON-S128300
CON-S124500

CON-S124900

200 g

Multi-element standard in 75 base oil: S-12:500 ppm


Fe .................................500 g/g
Mg ................................500 g/g
Na.................................500 g/g
Ni ..................................500 g/g

100 g
Pb ................................ 500 g/g
Si.................................. 500 g/g
Sn ................................ 500 g/g
Ti.................................. 500 g/g

Multi-element standard in 75 base oil: S-12:500 ppm

200 g

Multi-element standard in 75 base oil: S-12:900 ppm


Ag ................................ 900 g/g
Al.................................. 900 g/g
Cr ................................. 900 g/g
Cu ................................ 900 g/g

CON-S128900

Pb ................................ 300 g/g


Si.................................. 300 g/g
Sn ................................ 300 g/g
Ti.................................. 300 g/g

Multi-element standard in 75 base oil: S-12:300 ppm

Ag ................................ 500 g/g


Al.................................. 500 g/g
Cr ................................. 500 g/g
Cu ................................ 500 g/g

CON-S128500

Fe .................................300 g/g
Mg ................................300 g/g
Na.................................300 g/g
Ni ..................................300 g/g

Fe .................................900 g/g
Mg ................................900 g/g
Na.................................900 g/g
Ni ..................................900 g/g

100 g
Pb ................................ 900 g/g
Si.................................. 900 g/g
Sn ................................ 900 g/g
Ti.................................. 900 g/g

Multi-element standard in 75 base oil: S-12:900 ppm

200 g

AM Special
This multi-element standard is used in determination of additive elements in lubricant
oils by ICP, RDE, and DCP analysis of metals in oil. [Concentrations not listed are
available as custom multi-element standards on request. You may create your own
AM Special standards by adding additional elements to the stocked product standards,
listed as follows]
CON-AM4900

Multi-element standard AM-special in 75 base oil: AM Special 900 ppm


Ba ................................ 900 g/g
Ca ................................ 900 g/g

CON-AM8900
CON-AM41000

100 g

Zn................................. 900 g/g

Multi-element standard AM-special in 75 base oil: AM Special 900 ppm

200 g

Multi-element standard AM-special in 75 base oil: AM Special 1000 ppm

100 g

Ba .............................. 1000 g/g


Ca .............................. 1000 g/g

CON-AM81000

Mg ................................900 g/g
P ...................................900 g/g

Mg ..............................1000 g/g
P .................................1000 g/g

Zn............................... 1000 g/g

Multi-element standard AM-special in 75 base oil: AM Special 1000 ppm

200 g

Custom Multi-Element Standards in Mineral Oil


Customized standards can be prepared if your spectrometric analysis of metals
requires a specific combination of elements and concentrations. Custom standards
allow testing for unusual combinations and concentrations of elements with minimal
spectral interference and repeatable results. Both single element and multi-element
custom standards are available. Any element available (All except S, Cl, As, Hg, and
Se) can be combined to prepare multi-element custom standards. Create your own
S-21, S-12, and AM Special standards by adding additional elements to the stocked
product standards. Popular additions to S-21 are potassium, lithium, and antimony.
Standards are designated, for example, by S-21+K+Sb:100 ppm, AM Special+Fe:
900 ppm, S-12+Mo:100 ppm, etc. Custom standards are available in 100 g, 200 g, and
400 g. Custom standards are prepared and shipped within two business days of order

receipt by CONOSTAN .

www.lgcpromochem.com

Edition 2003/2004

79

Conostan Oil Analysis Standards


Code

Product

Unit

Sulphur in mineral oil


Sulphur and chlorine calibration standards are specifically designed for analysis of sulphur and
chlorine in a wide variety of petroleum products by XRF, ICP and other analytical techniques. All
standards are prepared on a weight/weight basis in high purity hydrocarbon oil with a 70 cSt viscosity
at 40C (75 Base Oil). Stock concentrations are listed in the table below. Concentrations not listed in
the table below are available as custom standards on request.
CON-Sblank

Sulphur in mineral oil, blank

S:blank

100 g

CON-S50

Sulphur in mineral oil, 50 g/g

S:50 ppm; 0.005 wt%

100 g

CON-S100

Sulphur in mineral oil, 100 g/g

S:100 ppm; 0.01 wt%

100 g

CON-S250

Sulphur in mineral oil, 250 g/g

S:250 ppm; 0.025 wt%

100 g

CON-S500

Sulphur in mineral oil, 500 g/g

S:500 ppm; 0.05 wt%

100 g

CON-S750

Sulphur in mineral oil, 750 g/g

S:750 ppm; 0.075 wt%

100 g

CON-S1000

Sulphur in mineral oil, 1000 g/g

S:1000 ppm; 0.1 wt%

100 g

CON-S2500

Sulphur in mineral oil, 2500 g/g

S:2500 ppm; 0.25 wt%

100 g

CON-S5000

Sulphur in mineral oil, 5000 g/g

S:5000 ppm; 0.5 wt%

100 g

CON-S7500

Sulphur in mineral oil, 7500 g/g

S:7500 ppm; 0.75 wt%

100 g

CON-S10000

Sulphur in mineral oil, 10000 g/g

S:10000 ppm; 1.0 wt%

100 g

CON-S15000

Sulphur in mineral oil, 15000 g/g

S:15000 ppm; 1.5 wt%

100 g

CON-S20000

Sulphur in mineral oil, 20000 g/g

S:20000 ppm; 2.0 wt%

100 g

CON-S25000

Sulphur in mineral oil, 25000 g/g

S:25000 ppm; 2.5 wt%

100 g

CON-S30000

Sulphur in mineral oil, 30000 g/g

S:30000 ppm; 3.0 wt%

100 g

CON-S40000

Sulphur in mineral oil, 40000 g/g

S:40000 ppm; 4.0 wt%

100 g

CON-S50000

Sulphur in mineral oil, 50000 g/g

S:50000 ppm; 5.0 wt%

100 g

Cl:blank

100 g

Chlorine in oil
CON-Cl-blank

Chlorine in oil, blank

CON-Cl10

Chlorine in oil, 10 g/g

Cl:10 ppm; 0.001 wt%

100 g

CON-Cl100

Chlorine in oil, 100 g/g

Cl:100ppm; 0.01 wt%

100 g

CON-Cl500

Chlorine in oil, 500 g/g

Cl:500 ppm; 0.05 wt%

100 g

CON-Cl1000

Chlorine in oil, 1000 g/g

Cl:1000 ppm; 0.1 wt%

100 g

CON-Cl5000

Chlorine in oil, 5000 g/g

Cl:5000 ppm; 0.5 wt%

100 g

CON-Cl10000

Chlorine in oil, 10000 g/g

Cl:10000 ppm; 1.0 wt%

100 g

CON-Cl50000

Chlorine in oil, 50000 g/g

Cl:50000 ppm; 5.0 wt%

100 g

80

Edition 2003/2004

www.lgcpromochem.com

Conostan Oil Analysis Standards


Code

Product

Unit

Element blank oils


Blank oils may be used as a zero point standard or for diluting calibration standards for
spectrometric analysis of metals in oil.
CON-EBO204

20 Blank oil

100 g

Viscosity
40 C (104 F).............14-18 cSt

CON-EBO2016
CON-EBO754

100 C (212 F) ............. 3-4 cSt

Any trace metal ......... <0.10 ppm

20 Blank oil

400 g

75 Blank oil

100 g

Viscosity
40 C (104 F).............65-72 cSt

CON-EBO7516

75 Blank oil

TM

ICP solvent

PremiSolv

100 C (212 F) ....... 8.1-8.7 cSt

Any trace metal ......... <0.10 ppm

400 g

PremiSolv ICP solvent is a superior product vs. low odor kerosene or xylene for use
as a diluent and zero point standard in ICP/DCP analysis of metals in oil and other
organic fluids. PremiSolv ICP solvent features:
- Extremely low odour: No sulphur/aromatic odor for increased worker comfort and
less occupational exposure
- Extremely low toxicity compared to kerosene or xylene.
- Non-hazardous for shipping/disposal.
- Supplied with certificate of analysis listing the concentration of 33 different metals
and sulphur.
TM

ICP solvent

3.78 L

TM

ICP solvent

18.9 L

CON-PSOLV4

PremiSolv

CON-PSOLV19

PremiSolv

PartiStanTM particle standards- Compliant with ISO 11171:1999


Automatic particle counters (APC), using a laser source, are used for measurement of contamination
in lubrication products, especially hydraulic fluids. These products are necessary for instrument
calibration and verification of performance, and may, also, be used for non-laser based particle
counting instruments.
PartiStan Particle Standard Features:
- Traceable to NIST SRM 2806.
- ISO 11171 compliant, Per Annex F; uses ISO medium test dust.
- Certificate of analysis for 4-30 um(c) (micrometers, certified).
- Maintain conformance to ISO programs (ISO 4402 is obsolete).
- Independent of APC manufacturer.
Routine Products Usage:
- PartiStan 2806.
- Sizing calibration (Clause 6, ISO 11171).
- Verification fluid for APC performance.
- PartiStan SCF (Super Clean Fluid).
- APC system cleaning.
- Test sample dilution.
- PartiStan Calibration Kits - All fluids for ISO 11171 APC calibration.
- PartiStan UFTD.
- Ultra fine test dust suspensions for ISO 11171 - Annexes A,B,C, & E.
PartiStan

TM

2806 - 2.8 mg/L ISO Medium Test Dust suspension in Super Clean Fluid

400 mL

PartiStan

TM

SCF - Super Clean Fluid

400 mL

CON-PSCK

PartiStan

TM

APC calibration kits

various

CON-PSUFTD

PartiStan

TM

UFTD - Ultra Fine test dust suspension in Super Clean Fluid

CON-PS2806
CON-PSSCF

www.lgcpromochem.com

Edition 2003/2004

400/250 mL

81

Conostan Oil Analysis Standards


Code

Product

Unit

FTIR Operational Test Standard

The CONOSTAN FTIR Operational Test Standard is a petroleum-based fluid similar to routine oil
samples that are analyzed by Fourier Transform Infrared (FTIR) spectroscopy as part of a conditionmonitoring program. The product looks and handles like the used oil samples routinely tested, and
flows through the system to monitor the cell and tubing in addition to providing a known spectrum and

test values. The CONOSTAN FTIR Operational Test Standard validates FTIR instrument
performance and handling procedures to ensure repeatability and reproducibility for fluid condition
monitoring programs. Additionally, it may be used to supplement the ASTM E-1421 FTIR performance
test using polystyrene and is recommended in the pending ATSM draft practice for used oil analysis
by FTIR.
An automated method has been implemented by Digilab (formerly Bio-Rad) for their line of oil
analyzers and oil analysis systems. An installation floppy disk, provided, contains the analytical
methods and information necessary to perform these tests. Automated methods for other FTIR
spectrometers are under development, owners should contact their respective manufacturers or

CONOSTAN for information on availability.


CON-FTIR-OTSPE FTIR operation test standard for Perkin-Elmer FTIR oil analysis systems

100 g

Call for availability

CON-FTIR-OTSBR FTIR operation test standard for Digilab FTIR oil analysis systems

100 g

Call for availability

Proficiency test program - Oil analysis


Programme includes:
- Elemental spectroscopy
- Particle counting
- Viscosity measurement
Get and remain on target with a program that tests your systems and processes. Aim
for an accurately known bulls-eye where you can learn if you are off target and then
advance toward excellence- not a program that tests your ability to be average. Test
sample values are certified and based on NIST traceable measurements. Metals
sample: wear, additive, contaminants-16 each, selected from list of 22. Particle
sample: based on ISO 11171/ISO Medium Test Dust. Viscosity sample: values
determined per D-2162. Monthly and quarterly sample distributions available.
CON-PTSQ-Set

Quarterly proficiency test subscription for metals, particle counting, and viscosity

5 - 15 g

Individual types available please call

CON-PTSM-Set

Monthly proficiency test subscription for metals, particle counting, and viscosity

5 - 15 g

Individual types available please call

82

Edition 2003/2004

www.lgcpromochem.com

Conostan Oil Analysis Standards


Code

Product

Unit

CONOSTAN D-Series Element (metallo-organic) Standards: D-3, D-12, D-19 (JOAP)

The CONOSTAN D-Series standards are specially designed for military laboratories required to
conform to the JOAP (Joint Oil Analysis Program U.S.) program for emission spectrometers. These
standards should not be used unless the laboratory instrument is JOAP certified. Refer to and

use CONOSTAN multi-element standards, otherwise.


D-3 series (Note: U.S. Dept. Of Defense NSN # equivalent shown with product
identity)
CON-D38100

CONOSTAN D-Series Standard: D-3:100 (NSN 9150-01-283-0249)


B .................................. 100 g/g

Mo ................................100 g/g

200 g

Zn................................. 100 g/g

D-12 series (Note: U.S. Dept. Of Defense NSN # equivalent shown with product identity)
CON-D1285

CONOSTAN D-Series Standard: D-12:5 ppm (NSN: 9150-01-307-3343)


Ag .................................... 5 g/g
Al...................................... 5 g/g
Cr ..................................... 5 g/g
Cu .................................... 5 g/g

CON-D12810

Fe .................................100 g/g
Mg ................................100 g/g
Na.................................100 g/g
Ni ..................................100 g/g

Fe .................................300 g/g
Mg ................................300 g/g
Na.................................300 g/g
Ni ..................................300 g/g

200 g

Pb ................................ 100 g/g


Si.................................. 100 g/g
Sn ................................ 100 g/g
Ti.................................. 100 g/g

CONOSTAN D-Series Standard: D-12:300 ppm (NSN: 9150-00-179-5141)


Ag ................................ 300 g/g
Al.................................. 300 g/g
Cr ................................. 300 g/g
Cu ................................ 300 g/g

200 g

Pb .................................. 50 g/g
Si.................................... 50 g/g
Sn .................................. 50 g/g
Ti.................................... 50 g/g

CONOSTAN D-Series Standard: D-12:100 ppm (NSN: 9150-00-179-5142)


Ag ................................ 100 g/g
Al.................................. 100 g/g
Cr ................................. 100 g/g
Cu ................................ 100 g/g

CON-D128300

Fe ...................................50 g/g
Mg ..................................50 g/g
Na...................................50 g/g
Ni ....................................50 g/g

200 g

Pb .................................. 30 g/g
Si.................................... 30 g/g
Sn .................................. 30 g/g
Ti.................................... 30 g/g

CONOSTAN D-Series Standard: D-12:50 ppm (NSN: 9150-00-179-5143)


Ag .................................. 50 g/g
Al.................................... 50 g/g
Cr ................................... 50 g/g
Cu .................................. 50 g/g

CON-D128100

Fe ...................................30 g/g
Mg ..................................30 g/g
Na...................................30 g/g
Ni ....................................30 g/g

200 g

Pb .................................. 10 g/g
Si.................................... 10 g/g
Sn .................................. 10 g/g
Ti.................................... 10 g/g

CONOSTAN D-Series Standard: D-12:30 ppm (NSN: 9150-00-179-5144)


Ag .................................. 30 g/g
Al.................................... 30 g/g
Cr ................................... 30 g/g
Cu .................................. 30 g/g

CON-D12850

Fe ...................................10 g/g
Mg ..................................10 g/g
Na...................................10 g/g
Ni ....................................10 g/g

200 g

Pb .................................... 5 g/g
Si...................................... 5 g/g
Sn .................................... 5 g/g
Ti...................................... 5 g/g

CONOSTAN D-Series Standard: D-12:10 ppm (NSN: 9150-00-179-5145)


Ag .................................. 10 g/g
Al.................................... 10 g/g
Cr ................................... 10 g/g
Cu .................................. 10 g/g

CON-D12830

Fe .....................................5 g/g
Mg ....................................5 g/g
Na.....................................5 g/g
Ni ......................................5 g/g

200 g

Pb ................................ 300 g/g


Si.................................. 300 g/g
Sn ................................ 300 g/g
Ti.................................. 300 g/g

D-19 series (Note: U.S. Dept. Of Defense NSN # equivalent shown with product
identity)
CON-D19-0
CON-D1945

100 g

100 g

CONOSTAN D-Series Standard (blank): D-19:0 (NSN:9150-00-179-5137)


CONOSTAN D-Series Standard: D-19:5 ppm (no NSN number; not offered by U.S.
Dept. Of Defense; see CON-D19 Set, below)
Ag .................................... 5 g/g
Al...................................... 5 g/g
B ...................................... 5 g/g
Ba .................................... 5 g/g
Cd .................................... 5 g/g
Cr ..................................... 5 g/g
Cu .................................... 5 g/g

CON-D19410

Si...................................... 5 g/g
Sn .................................... 5 g/g
Ti...................................... 5 g/g
V ...................................... 5 g/g
Zn..................................... 5 g/g

CONOSTAN D-Series Standard: D-19:10 ppm (no NSN number; not offered by U.S.
Dept. Of Defense; see CON-D19 Set, below)
Ag .................................. 10 g/g
Al.................................... 10 g/g
B .................................... 10 g/g
Ba .................................. 10 g/g
Cd .................................. 10 g/g
Cr ................................... 10 g/g
Cu .................................. 10 g/g

www.lgcpromochem.com

Fe .....................................5 g/g
Mg ....................................5 g/g
Mn ....................................5 g/g
Mo ....................................5 g/g
Na.....................................5 g/g
Ni ......................................5 g/g
Pb .....................................5 g/g

Fe ...................................10 g/g
Mg ..................................10 g/g
Mn ..................................10 g/g
Mo ..................................10 g/g
Na...................................10 g/g
Ni ....................................10 g/g
Pb ...................................10 g/g

Edition 2003/2004

100 g

Si.................................... 10 g/g
Sn .................................. 10 g/g
Ti.................................... 10 g/g
V .................................... 10 g/g
Zn................................... 10 g/g

83

Conostan Oil Analysis Standards


Code

CON-D19430

Product

Unit

CONOSTAN D-Series Standard: D-19:30 ppm (no NSN number; not offered by U.S.
Dept. Of Defense; see CON-D19 Set, below)
Ag .................................. 30 g/g
Al.................................... 30 g/g
B .................................... 30 g/g
Ba .................................. 30 g/g
Cd .................................. 30 g/g
Cr ................................... 30 g/g
Cu .................................. 30 g/g

CON-D19450

Fe .................................700 g/g
Mg ................................700 g/g
Mn ................................700 g/g
Mo ................................700 g/g
Na.................................700 g/g
Ni ..................................700 g/g
Pb .................................700 g/g

100 g

Si.................................. 700 g/g


Sn ................................ 700 g/g
Ti.................................. 700 g/g
V .................................. 700 g/g
Zn................................. 700 g/g

CONOSTAN D-Series Standard: D-19:900 ppm (no NSN number; not offered by U.S.
Dept. Of Defense; see CON-D19 Set, below)
Fe .................................900 g/g
Mg ................................900 g/g
Mn ................................900 g/g
Mo ................................900 g/g
Na.................................900 g/g
Ni ..................................900 g/g
Pb .................................900 g/g

100 g

Si.................................. 500 g/g


Sn ................................ 500 g/g
Ti.................................. 500 g/g
V .................................. 500 g/g
Zn................................. 500 g/g

CONOSTAN D-Series Standard: D-19:700 ppm (no NSN number; not offered by U.S.
Dept. Of Defense; see CON-D19 Set, below)

Ag ................................ 900 g/g


Al.................................. 900 g/g
B .................................. 900 g/g
Ba ................................ 900 g/g
Cd ................................ 900 g/g
Cr ................................. 900 g/g
Cu ................................ 900 g/g

CON-D19 Set

Fe .................................500 g/g
Mg ................................500 g/g
Mn ................................500 g/g
Mo ................................500 g/g
Na.................................500 g/g
Ni ..................................500 g/g
Pb .................................500 g/g

100 g

Si.................................. 300 g/g


Sn ................................ 300 g/g
Ti.................................. 300 g/g
V .................................. 300 g/g
Zn................................. 300 g/g

CONOSTAN D-Series Standard: D-19:500 ppm (no NSN number; not offered by U.S.
Dept. Of Defense; see CON-D19 Set, below)

Ag ................................ 700 g/g


Al.................................. 700 g/g
B .................................. 700 g/g
Ba ................................ 700 g/g
Cd ................................ 700 g/g
Cr ................................. 700 g/g
Cu ................................ 700 g/g

CON-D194900

Fe .................................300 g/g
Mg ................................300 g/g
Mn ................................300 g/g
Mo ................................300 g/g
Na.................................300 g/g
Ni ..................................300 g/g
Pb .................................300 g/g

100 g

Si.................................. 100 g/g


Sn ................................ 100 g/g
Ti.................................. 100 g/g
V .................................. 100 g/g
Zn................................. 100 g/g

CONOSTAN D-Series Standard: D-19:300 ppm (no NSN number; not offered by U.S.
Dept. Of Defense; see CON-D19 Set, below)

Ag ................................ 500 g/g


Al.................................. 500 g/g
B .................................. 500 g/g
Ba ................................ 500 g/g
Cd ................................ 500 g/g
Cr ................................. 500 g/g
Cu ................................ 500 g/g

CON-D194700

Fe .................................100 g/g
Mg ................................100 g/g
Mn ................................100 g/g
Mo ................................100 g/g
Na.................................100 g/g
Ni ..................................100 g/g
Pb .................................100 g/g

100 g

Si.................................... 50 g/g
Sn .................................. 50 g/g
Ti.................................... 50 g/g
V .................................... 50 g/g
Zn................................... 50 g/g

Ag ................................ 300 g/g


Al.................................. 300 g/g
B .................................. 300 g/g
Ba ................................ 300 g/g
Cd ................................ 300 g/g
Cr ................................. 300 g/g
Cu ................................ 300 g/g

CON-D194500

Fe ...................................50 g/g
Mg ..................................50 g/g
Mn ..................................50 g/g
Mo ..................................50 g/g
Na...................................50 g/g
Ni ....................................50 g/g
Pb ...................................50 g/g

CONOSTAN D-Series Standard: D-19:100 ppm (no NSN number; not offered by U.S.
Dept. Of Defense; see CON-D19 Set, below)
Ag ................................ 100 g/g
Al.................................. 100 g/g
B .................................. 100 g/g
Ba ................................ 100 g/g
Cd ................................ 100 g/g
Cr ................................. 100 g/g
Cu ................................ 100 g/g

CON-D194300

Si.................................... 30 g/g
Sn .................................. 30 g/g
Ti.................................... 30 g/g
V .................................... 30 g/g
Zn................................... 30 g/g

CONOSTAN D-Series Standard: D-19:50 ppm (no NSN number; not offered by U.S.
Dept. Of Defense; see CON-D19 Set, below)
Ag .................................. 50 g/g
Al.................................... 50 g/g
B .................................... 50 g/g
Ba .................................. 50 g/g
Cd .................................. 50 g/g
Cr ................................... 50 g/g
Cu .................................. 50 g/g

CON-D194100

Fe ...................................30 g/g
Mg ..................................30 g/g
Mn ..................................30 g/g
Mo ..................................30 g/g
Na...................................30 g/g
Ni ....................................30 g/g
Pb ...................................30 g/g

100 g

100 g

Si.................................. 900 g/g


Sn ................................ 900 g/g
Ti.................................. 900 g/g
V .................................. 900 g/g
Zn................................. 900 g/g

CONOSTAN D-Series Standards: D-19:Set (NSN: 9150-01-355-1178)

set

Each set includes


CON-D19/0A............... 4 x 100 g
CON-D19/5A............... 1 x 100 g
CON-D19/10A............. 1 x 100 g
CON-D19/30A............. 1 x 100 g

84

CON-D19/50A ............. 1 x 100 g


CON-D19/500A ........... 1 x 100 g
CON-D19/700A ........... 1 x 100 g
CON-D19/900A ........... 1 x 100 g

Edition 2003/2004

CON-D19/100A........... 3 x 100 g
CON-D19/300A........... 2 x 100 g

www.lgcpromochem.com

Please photocopy this form for your use

CONOSTAN elements in oil custom standard request form

CONOSTAN custom blends standards are available from LGC Promochem if your spectrometric analysis of metals in oil
requires a combination or concentration of metals not routinely available from stock.

Please request a quotation for any CONOSTAN custom blend standard you require by filling out this form.
Please return the completed form to the LGC Promochem office which is responsible for your country.
You will find the country list on page 3 of this catalogue.
Analyte

Concentration

Analyte

13

14

15

16

17

18

19

20

21

10

22

11

23

12

24

Base oil

20 base oil

75 base oil

Unit size

100 g

200 g

Concentration

400 g

Name
Company / Organisation
Department / Function
Address / P.O. Box
Postcode / Town / Country
Telephone
Fax
e-mail
Customer number

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Edition 2003/2004

85

Ores

Ores
Code

BCR-010

Product

Unit

Tin ore - Tin

225 g

Certified value
Sn ............................. 765.9 g/kg

BCR-026

Zinc ore (blende) - Zinc

10 g

Certified value
Zn.............................. 485.0 g/kg

BCR-027

Zinc ore - Zinc

10 g

Certified value
Zn............................. 440.1 mg/g

BCR-028

Zinc ore (blende) - Zinc

10 g

Certified value
Zn.............................. 511.6 g/kg

BCR-029

Zinc ore (blende) - Zinc

10 g

Certified value
Zn.............................. 351.8 g/kg

BCR-030

Zinc ore (calcined calamine) - Zinc

10 g

Certified value
Zn.............................. 491.0 g/kg

BCR-031

Zinc ore (natural silicate) - Zinc

10 g

Certified value
Zn.............................. 367.3 g/kg

BCR-108

Zinc ore (blende) - Trace elements

200 g

Certified values
Cd ............................... 0.79 g/kg
Cu ............................... 0.73 g/kg
F................................ 0.063 g/kg

BCR-109

Fe ................................72.1 g/kg
Hg............................0.0109 g/kg
Mg ...............................0.75 g/kg

Pb ............................... 9.04 g/kg

Zinc ore (blende) - Trace elements

200 g

Certified values
Cd ................................. 4.6 g/kg
Cu ............................... 9.46 g/kg
F................................ 0.081 g/kg

BCR-110

Fe ..............................145.1 g/kg
Hg..........................0.00096 g/kg
Mg ...............................0.20 g/kg

Pb ............................... 7.38 g/kg

Zinc ore (blende) - Trace elements

200 g

Certified values
Cd ............................. 10.51 g/kg
Cu ............................. 16.28 g/kg
F................................ 0.055 g/kg

NRMGBW07237

Fe ..................................5.5 g/kg
Hg............................0.1484 g/kg
Mg ...............................1.36 g/kg

Zinc ore - Constituents

Pb ............................... 97.8 g/kg

100 g

Certified values for 37 elements, 9 oxides


Indicative values for 4 elements

NIST-79a

Fluorspar, customs grade - Calcium fluoride

120 g

Certified value
CaF2 ............................ 297.39 %

NIST-180

Fluorspar, high grade - Calcium fluoride

120 g

Certified value
CaF2 ............................... 98.80%

NIST-181

Lithium ore, Spodumene - Lithium oxide

45 g

Certified value
Li2O ................................. 6.39 %

NIST-182

Lithium ore, Petalite - Lithium oxide

45 g

Certified value
Li2O ................................. 4.34 %

86

Edition 2003/2004

www.lgcpromochem.com

Ores
Code

NIST-183

Product

Unit

Lithium ore, Lepidolite - Lithium oxide

45 g

Certified value
Li2O ................................. 4.12 %

NIST-RM 8455

Pyrite - Bioleaching rate (not certified)

100 g

Reference value
Bioleaching rate ............................... 12.4 mg Fe/L/hr

NIST-277

Tungsten concentrate - Tungsten oxide

100 g

Certified value
WO3 ................................ 67.4 %
Indicative values for Ca, Fe, Mn, Mo, Nb, O, P, Pb, S, Si, Sn, Ta, Ti

NIST-2430

Scheelite ore - Tunsten oxide

100 g

Certified values
As.................................. 0.002 %
Bi................................... 0.078 %

Mo .................................. 0.22 %
P ................................... 0.017 %

S ..................................... 0.26 %
WO3 ............................................ 70.26 %

Indicative values for Al, Cu, Fe, K, Mg, Mn, Na, Ta

NRMGBW07240

Tungsten ore - Constituents

100 g

Certified values for 38 elements, 9 oxides


Indicative values for 5 elements

NRMGBW07241

Tungsten ore - Constituents

100 g

Certified values for 38 elements, 9 oxides


Indicative values for 5 elements

NIST-330

Copper ore mill heads - Copper, molybdenum and rhenium

100 g

Certified values
Cu ................................... 0.84 %

Mo ................................ 0.018 %

Re ............................ 0.30 mg/kg

Indicative values for Ag, Au

NIST-25d

Manganese ore - Constituents

60 g

Certified values
Mn ................................. 51.78 %
Al2O3 ............................... 5.32 %
Fe2O3 .............................. 3.92 %

K2O................................. 0.93 %
P2O5................................ 0.25 %
SiO2 ................................ 2.52 %

TiO2 ................................. 0.13 %


Available oxygen........... 14.28 %

Indicative values for BaO, CaO, Moisture

NRMGBW07261

Manganese ore - Constituents

100 g

Certified values
Cu ................................. 0.013 %
Fe.................................... 1.22 %
Mn ................................. 45.39 %
Ni .................................. 0.019 %
P ................................... 0.054 %
S ................................... 0.007 %

Zn ................................. 0.027 %
Al2O3 .............................................. 2.20 %
BaO ................................ 0.68 %
CaO ................................ 1.06 %
K2O................................. 1.00 %
MgO................................ 0.64 %

MnO2 ............................. 67.25 %


Na2O ............................. 0.044 %
SiO2............................... 16.16 %
TiO2 ............................... 0.063 %

Indicative value for Mn(SiO32-)

NRMGBW07262

Manganese ore - Constituents

100 g

Certified values
Cu ................................. 0.014 %
Fe.................................... 2.24 %
Mn ................................. 36.99 %
Ni .................................. 0.019 %
P ................................... 0.081 %
S ................................... 0.013 %

Zn ................................. 0.029 %
Al2O3 .............................................. 3.00 %
BaO ................................ 0.47 %
CaO ................................ 3.60 %
K2O................................. 0.46 %
MgO................................ 1.44 %

MnO2 ............................. 54.38 %


Na2O ............................. 0.048 %
SiO2............................... 22.24 %
TiO2 ................................. 0.10 %

Indicative value for Mn(SiO32-)

NRMGBW07263

Manganese ore - Constituents

100 g

Certified values
Cu ................................. 0.036 %
Fe.................................. 11.24 %
Mn ................................. 32.54 %
Ni .................................. 0.099 %
P ................................... 0.207 %
S ................................... 0.019 %

Zn ................................. 0.064 %
Al2O3 .............................................. 8.55 %
BaO ................................ 0.18 %
CaO .............................. 0.083 %
K2O................................. 0.93 %
MgO................................ 0.11 %

MnO2 ............................. 48.01 %


Na2O ............................. 0.039 %
SiO2............................... 14.50 %
TiO2 ................................. 0.43 %

Indicative value for Mn(SiO32-)

www.lgcpromochem.com

Edition 2003/2004

87

Ores
Code

Product

Unit

NRMGBW07264

Manganese ore - Constituents

100 g

Certified values
Cu ................................. 0.028 %
Fe.................................. 20.99 %
Mn ................................. 25.00 %
Ni .................................. 0.073 %
P ................................... 0.275 %
S ................................... 0.032 %

Zn ................................. 0.048 %
Al2O3 .............................................. 8.97 %
BaO ................................ 0.23 %
CaO .............................. 0.051 %
K2O................................. 0.72 %
MgO................................ 0.10 %

MnO2 ............................. 36.93 %


Na2O ............................. 0.030 %
SiO2............................... 10.46 %
TiO2 ................................. 0.54 %

Indicative value for Mn(SiO32-)

NRMGBW07265

Manganese ore - Constituents

100 g

Certified values
Cu ................................. 0.009 %
Fe.................................... 1.40 %
Mn ................................. 22.54 %
Ni .................................. 0.041 %
P ................................... 0.043 %
S ..................................... 0.21 %

Zn ................................. 0.018 %
Al2O3 .............................................. 1.68 %
BaO ................................ 0.13 %
CaO .............................. 14.73 %
K2O................................. 0.46 %
MgO................................ 3.50 %

2-

Mn(CO3 )...................... 22.46 %


Na2O ............................. 0.024 %
SiO2............................... 14.07 %
TiO2 ................................. 0.10 %

Indicative value for Mn(SiO32-)

NRMGBW07266

Manganese ore - Constituents

100 g

Certified values
Cu ................................. 0.014 %
Fe.................................... 2.07 %
Mn ................................. 15.74 %
Ni .................................. 0.050 %
P ................................... 0.061 %
S ..................................... 0.27 %

Zn ................................. 0.020 %
Al2O3 .............................................. 2.49 %
BaO ................................ 0.15 %
CaO .............................. 19.78 %
K2O................................. 0.70 %
MgO................................ 3.82 %

Mn(CO32-)...................... 15.69 %
Na2O ............................. 0.040 %
SiO2............................... 15.82 %
TiO2 ................................. 0.15 %

Indicative value for Mn(SiO32-)

NIST-690

Iron ore, Canada - Constituents

100 g

Certified values
Fe (total)........................ 66.85 %
P ................................... 0.011 %
S ................................... 0.003 %
Al2O3.............................................. 0.18 %

NIST-691

CaO ................................ 0.20 %


K2O............................. 0.0030 %
MgO................................ 0.18 %
MnO................................ 0.23 %

Na2O ............................. 0.003 %


SiO2................................. 3.71 %
TiO2 ............................... 0.022 %

Iron ore, reduced - Constituents

100 g

Certified values
C ..................................... 0.12 %
Co ................................. 0.030 %
Cu ................................. 0.032 %
Fe (total).......................... 90.8 %
P ................................... 0.006 %

NIST-692

S ................................... 0.005 %
Al2O3 ............................... 1.22 %
CaO ................................ 0.63 %
MgO................................ 0.52 %
MnO.............................. 0.043 %

Na2O ............................. 0.186 %


SiO2................................... 3.7 %
TiO2 ................................. 0.27 %

Iron ore, Labrador - Constituents

100 g

Certified values
Fe (total)........................ 59.58 %
P ................................... 0.039 %
S ................................... 0.005 %
Al2O3 ............................... 1.41 %

NIST-693

CaO .............................. 0.023 %


K2O............................... 0.039 %
MgO.............................. 0.035 %
MnO................................ 0.46 %

Na2O ............................. 0.008 %


SiO2................................... 3.7 %
TiO2 ............................... 0.045 %

Iron ore, Nimba - Constituents

100 g

Certified values
Fe (total)........................ 65.11 %
P ................................... 0.056 %
S ................................... 0.005 %
Al2O3 ............................... 1.02 %

NRMGBW07213

CaO .............................. 0.016 %


K2O............................. 0.0028 %
MgO.............................. 0.013 %
MnO.............................. 0.091 %

Na2O ........................... 0.0028 %


SiO2................................. 3.87 %
TiO2 ............................... 0.035 %

Iron ore - Constituents

100 g

Certified values
Fe (total)......................... 67.01%
S ................................... 0.118 %
Al2O3 ............................... 1.23 %

CaO ................................ 0.22 %


MgO................................ 0.71 %
MnO................................ 0.19 %

SiO2................................. 3.16 %
TiO2 ............................... 0.032 %

Indicative values for C, P, CO2, FeO, H2O+

NRMGBW07218a Iron ore - Constituents

100 g

Certified values
Fe (total)........................ 64.88 %
Mn ................................. 0.056 %
P ................................... 0.055 %
S ................................... 0.015 %
Ti................................... 0.044 %

88

Al2O3 ............................... 1.59 %


CaO .............................. 0.080 %
FeO ................................ 0.37 %
K2O............................... 0.085 %
MgO.............................. 0.044 %

Edition 2003/2004

Mn ................................. 0.056 %
Na2O ............................. 0.012 %
SiO2................................. 3.48 %

www.lgcpromochem.com

Ores
Code

NIST-69b

Product

Unit

Bauxite, Arkansas - Constituents

60 g

Certified values
Al2O3 ............................... 48.8 %
CaO ................................ 0.13 %
Cr2O3 ............................. 0.011 %
Fe2O3 .............................. 7.14 %
K2O ............................... 0.068 %

MgO.............................. 0.085 %
MnO.............................. 0.110 %
P2O5.............................. 0.118 %
SO3 ............................... 0.551 %
SiO2 .............................. 13.43 %

TiO2 ................................. 1.90 %


V2O5 .............................. 0.028 %
ZnO ............................. 0.0035 %
ZrO2 ................................ 0.29 %
LOI*................................. 27.2 %

Indicative values for Co, BaO, Na2O


LOI* Loss on Ignition

NIST-600

Bauxite, Australian - Constituents

90 g

Certified values
Al2O3 ............................... 40.0 %
CaO ................................ 0.22 %
Cr2O3 ............................. 0.024 %
Fe2O3 .............................. 17.0 %
K2O ................................. 0.23 %
MgO .................................. 0.055

MnO.............................. 0.013 %
Na2O............................. 0.022 %
P2O5.............................. 0.039 %
SO3 ............................... 0.155 %
SiO2 ................................ 20.3 %
TiO2 ................................ 1.31 %

V2O5 .............................. 0.060 %


ZnO ............................... 0.003 %
ZrO2 .............................. 0.060 %
LOI*................................. 20.5 %

LOI* Loss on Ignition

NIST-696

Bauxite, Surinam - Constituents

60 g

Certified value
Al2O3 ............................... 54.5 %
CaO .............................. 0.018 %
Cr2O3 ............................. 0.047 %
Fe2O3 .............................. 8.70 %
K2O ............................... 0.009 %

MgO.............................. 0.012 %
MnO.............................. 0.004 %
P2O5.............................. 0.050 %
SiO2 ................................ 3.79 %
SO3 ................................. 0.15 %

TiO2 ................................. 2.64 %


V2O5 .............................. 0.072 %
ZnO ............................. 0.0014 %
ZrO2 ................................ 0.14 %
LOI*................................. 29.9 %

Indicative values for Co, BaO, Na2O


LOI* Loss on Ignition

NIST-697

Bauxite, Dominican - Constituents

60 g

Certified value
Al2O3 ............................... 45.8 %
CaO ................................ 0.71 %
Cr2O3 ............................. 0.100 %
Fe2O3 .............................. 20.0 %
K2O ............................... 0.062 %

MgO................................ 0.18 %
MnO................................ 0.41 %
P2O5................................ 0.97 %
SiO2 ................................ 6.81 %
SO3 ............................... 0.077 %

TiO2 ................................. 2.52 %


V2O5 .............................. 0.063 %
ZnO ............................... 0.037 %
ZrO2 .............................. 0.065 %
LOI*................................. 22.1 %

Indicative values for Co, BaO, Na2O


LOI* Loss on Ignition

NIST-698

Bauxite, Jamaican - Constituents

60 g

Certified value
Al2O3 ............................... 48.2 %
CaO ................................ 0.62 %
Cr2O3 ............................. 0.080 %
Fe2O3 ............................ 0.013 %
K2O ............................... 0.010 %

MgO.............................. 0.058 %
MnO................................ 0.38 %
P2O5................................ 0.37 %
SiO2 ................................ 0.69 %
SO3 ............................... 0.143 %

TiO2 ................................. 2.38 %


V2O5 .............................. 0.064 %
ZnO ............................... 0.029 %
ZrO2 ........................... 0.0,061 %
LOI*................................. 27.3 %

Indicative values for Co, BaO, Na2O


LOI* Loss on Ignition

NIST-699

Alumina (reduction grade) - Trace constituents

60 g

Certified values
CaO .............................. 0.036 %
Cr2O3 ........................... 0.0002 %
Fe2O3 ............................ 0.013 %
Ga2O3 ............................ 0.010 %
Li2O ............................... 0.002 %

MgO............................ 0.0006 %
MnO............................ 0.0005 %
P2O5............................ 0.0002 %
SiO2 .............................. 0.014 %
Na2O............................... 0.59 %

V2O5 ............................ 0.0005 %


ZnO ............................... 0.013 %
LOI*................................. 0.69 %

LOI* Loss on Ignition

NRMGBW07235

Lead ore - Constituents

100 g

Certified values for 38 elements, 9 Oxides


Indicative values for 4 elements

NRMGBW07236

Lead ore - Constituents

100 g

Certified values for 38 elements, 9 Oxides


Indicative values for 4 elements

NIST-670

Rutile ore - Constituents

90 g

Certified values
Cr2O3 ............................... 0.23 %
Fe2O3 .............................. 0.86 %

www.lgcpromochem.com

SiO2 ................................ 0.51 %


TiO2 .............................. 96.16 %

Edition 2003/2004

V2O5 ................................ 0.66 %


ZrO2 ................................ 0.84 %

89

Ores
Code

Product

Unit

NRMGBW07238

Molybdenum ore - Constituents

100 g

Certified values for 38, elements, 9 oxides


Indicative values for 3 elements

NRMGBW07239

Molybdenum ore - Constituents

100 g

Certified values for 38, elements, 9 oxides


Indicative values for 3 elements

NIST-886

Gold ore, refractory - Trace elements

200 g

Certified values
S ................................... 1.466 %

Al2O3 .........................8.25 mg/kg

Indicative values for C (total), SO3

NIST-1835

Borate ore - Constituents

60 g

Certified values
F.................................... 0.348 %
Al2O3 ............................. 3.474 %
B2O3 ............................ 18.739 %
BaO............................. 0.0497 %
CaO ............................ 21.622 %

NRMGBW03118

Fe2O3 ............................ 1.141 %


MgO.............................. 3.411 %
MnO............................ 0.0333 %
K2O............................... 1.261 %
SiO2 ............................ 18.408 %

Na2O ............................. 3.484 %


SO3 ............................... 1.477 %
SrO ............................. 0.9418 %
TiO2 ............................. 0.1332 %
LOI*............................... 25.72 %

Graphite ore - Constituents

50 g

Certified values
C (graphite)..................... 2.91 %
Fe (total).......................... 6.73 %
S ..................................... 1.18 %
Al2O3 ............................. 12.93 %
CaO ................................ 9.37 %

NRMGBW03119

CO2 ................................. 3.60 %


H2O+ ............................... 2.60 %
K2O................................. 2.54 %
MgO................................ 6.10 %
MnO.............................. 0.084 %

P2O5 ................................ 0.13 %


Na2O ............................... 1.60 %
SiO2............................... 49.84 %
TiO2 ................................. 0.57 %

Graphite ore - Constituents

50 g

Certified values
C (graphite)..................... 9.91 %
Fe (total).......................... 6.99 %
S ..................................... 2.59 %
Al2O3 ............................. 13.03 %
CaO ................................ 5.34 %

NRMGBW03120

CO2 ................................. 0.67 %


H2O+ ............................... 2.80 %
K2O................................. 2.17 %
MgO................................ 5.35 %
MnO.............................. 0.054 %

P2O5 ................................ 0.14 %


Na2O ............................... 1.56 %
SiO2............................... 49.34 %
TiO2 ................................. 0.64 %

Graphite ore - Constituents

50 g

Certified values
C (graphite)................... 76.50 %
Fe (total).......................... 1.48 %
S ..................................... 0.14 %
Al2O3 ............................... 5.60 %
CaO ................................ 0.74 %
CO2 ................................. 0.28 %

IAEA-RGTh-1

H2O+ ............................... 1.98 %


K2O................................. 0.99 %
MgO................................ 0.50 %
MnO.............................. 0.022 %
P2O5................................ 0.16 %
Na2O............................... 0.23 %

SiO2............................... 10.34 %
TiO2 ................................. 0.55 %
Ash................................ 20.78 %
Volatile matter................. 2.72 %

Thorium ore (with silica) - Constituents

500 g

Reference values
Th.............................. 800 mg/kg

U.................................6.3 mg/kg

Indicative value for K

IAEA-RGU-1

Uranium ore (with silica) - Constituents

500 g

Reference value
U ............................... 400 mg/kg
Indicative values for K, Th

NIST-120c

Phosphate rock, Florida - Constitutents

90 g

Certified values
Al2O3 ............................... 1.30 %
Fe2O3 .............................. 1.08 %
K2O ............................... 0.147 %

MnO.............................. 0.027 %
Na2O............................... 0.52 %
TiO2 .............................. 0.103 %

U3O8 ............................ 0.0135 %


V2O3 .............................. 0.016 %

Values for the AFPC-method-Dependent concentrations also available

NIST-694

Phosphate rock, western - Constituents

90 g

Certified values
Al2O3 ................................. 1.8 %
CaO ................................ 43.6 %
CdO .............................. 0.015 %
F........................................ 3.2 %
Fe2O3 .............................. 0.79 %

K2O................................. 0.51 %
MgO................................ 0.33 %
MnO............................ 0.0116 %
Na2O............................. 0.086 %
P2O5................................ 30.2 %

SiO2................................. 11.2 %
U ............................... 0.01414 %
V2O5 .............................. 0.031 %

Indicative values for, Cr2O3 , ZnO, TiO2

90

Edition 2003/2004

www.lgcpromochem.com

Refractories and carbides

Refractories and carbides


Code

NIST-76a

Product

Unit

Burnt refractory (Al2O3-40%) - Constituents

75 g

Certified values
Al2O3 ............................... 38.7 %
CaO ................................ 0.22 %
Fe2O3 .............................. 1.60 %
K2O ................................. 1.33 %

Li2O .............................. 0.042 %


MgO................................ 0.52 %
Na2O........................... 0.07 % %
P2O5.............................. 0.120 %

SiO2................................. 54.9 %
SrO ................................... 0.037
TiO2 ..................................... 2.03

Indicative value for LOI*

NIST-77a

Burnt refractory (Al2O3 - 60%) - Constituents

75 g

Certified values
Al2O3 ............................... 60.2 %
CaO ................................ 0.05 %
Fe2O3 .............................. 1.00 %
K2O ............................... 0.090 %

Li2O .............................. 0.025 %


MgO................................ 0.38 %
Na2O............................. 0.037 %
P2O5.............................. 0.092 %

SiO2................................. 35.0 %
SrO ................................... 0.009
TiO2 ................................. 2.66 %

Indicative value for LOI*

NIST-78a

Burnt refractory (Al2O3- 70%) - Constituents

75 g

Certified values
Al2O3 ................................. 1.7 %
CaO ................................ 0.11 %
Fe2O3 ................................ 1.2 %
K2O ................................. 1.22 %

Li2O ................................ 0.12 %


MgO................................ 0.70 %
Na2O............................. 0.078 %
P2O5.................................. 1.3 %

SiO2................................. 19.4 %
SrO ................................. 0.25 %
TiO2 ................................. 3.22 %

Indicative value for LOI*

NIST-198

Silica brick - Constituents

45 g

Certified values
Al2O3 ............................... 0.16 %
CaO ................................ 2.71 %
Fe2O3 .............................. 0.66 %
K2O ............................... 0.017 %

NIST-199

Li2O .............................. 0.001 %


MgO................................ 0.07 %
MnO.............................. 0.008 %
Na2O............................. 0.012 %

P2O5 .............................. 0.022 %


TiO2 ................................. 0.02 %
LOI*................................. 0.21 %

Silica brick - Constituents

45 g

Certified values
Al2O3 ............................... 0.48 %
CaO ................................ 2.41 %
Fe2O3 .............................. 0.74 %
K2O ............................... 0.094 %

NIST-887

Li2O .............................. 0.002 %


Na2O............................. 0.015 %
MgO................................ 0.13 %
MnO.............................. 0.007 %

P2O5 .............................. 0.015 %


TiO2 ................................. 0.06 %
LOI*................................. 0.17 %

Cemented carbide (W83-Co25-Ti4) - Cobalt

100 g

Certified value
Co ................................. 10.35 %
Indicative value for C

NIST-888

Cemented carbide (W64-Co25-Ti4) - Cobalt and tantalum

100 g

Certified values
Co ................................... 24.7 %

Ta ................................... 4.77 %

Indicative value for C

NIST-889

CEM carbide (W75-Co9-Ta5-Ti4) - Cobalt, tantalum and titanium

100 g

Certified values
Co ....................................... 9.50

Ta ........................................4.60

Ti......................................... 4.03

Indicative value for C

NIST-112b

Silicon carbide

80 g

Certified value
Al..................................... 0.44 %
C (total) ......................... 29.43 %

NIST-276b

C (free) ........................... 0.26 %


Ca................................... 0.04 %

Tungsten carbide - Carbon

Fe.................................... 0.13 %
Silicon carbide .............. 97.37 %

75 g

Certified value
C ..................................... 6.10 %
Indicative values for C (free), O, N

www.lgcpromochem.com

Edition 2003/2004

91

Cement

Cement
Code

Product

Unit

NIST-1880a - NIST-1889a
These materials are intended for x-ray spectroscopic and chemical analysis of cements and related
materials.
NIST-1880a

Portland cement (formally black) - Constituents

4x5g

Certified values
Cl .................................. 0.007 %
Al2O3 ............................... 5.18 %
CaO .............................. 63.83 %
Cr2O3 ............................. 0.007 %
Fe2O3 .............................. 2.81 %
K2O ................................. 0.92 %

MgO................................ 1.72 %
Mn2O3 ........................... 0.127 %
Na2O............................... 0.28 %
P2O5................................ 0.22 %
SiO2 .............................. 20.31 %
SO3 ................................. 3.25 %

SrO ............................... 0.083 %


TiO2 ................................. 0.25 %
ZnO ............................... 0.005 %
LOI*..................................... 1.32

Indicative values for Insoluble residue, CaO (free), F,Total

NIST-1881a

Portland cement - Constituents

4x5g

Certified values
Al2O3 ............................. 7.060 %
CaO .............................. 57.58 %
Cr2O3 ........................... 0.0588 %
Fe2O3 .............................. 3.09 %
K2O ............................... 1.228 %

MgO.............................. 2.981 %
Mn2O3 ........................... 0.013 %
Na2O............................. 0.199 %
P2O5............................ 0.1459 %
SiO2 .............................. 22.26 %

SO3 ............................... 3.366 %


SrO ............................... 0.036 %
TiO2 ............................. 0.3663 %
ZnO ................................. 0.0489

Indicative values for Cl, F, LOI, Insoluble residue

NIST-1882a

Calcium aluminate cement (formally orange) - Constituents

4x5g

Certified values
Al2O3 ............................. 39.14 %
CaO .............................. 39.29 %
Cr2O3 ............................. 0.113 %
Fe2O3 ............................ 14.67 %
K2O ............................... 0.051 %

MgO................................ 0.51 %
Mn2O3 ........................... 0.060 %
Na2O............................. 0.021 %
P2O5.............................. 0.070 %
SiO2 ................................ 4.01 %

SrO ............................... 0.024 %


TiO2 ............................... 1.786 %
ZnO ............................... 0.004 %
LOI*................................. 0.20 %

Indicative value for Total

NIST-1883a

Calcium aluminate cement (formally silver) - Constituents

4x5g

Certified values
Al2O3 ............................. 70.04 %
CaO .............................. 29.52 %
Fe2O3 ............................ 0.078 %

K2O............................... 0.014 %
MgO................................ 0.19 %
Na2O............................... 0.30 %

SiO2.............................0.24 % %

Indicative values for Cr2O3, P2O5, SrO, TiO2, LOI*, Total

NIST-1884a

Portland cement - Constituents

4x5g

Certified values
Al2O3 ............................. 4.264 %
CaO .............................. 62.26 %
Cr2O3 ........................... 0.0166 %
Fe2O3 ............................ 2.695 %
K2O ............................... 0.997 %

MgO.............................. 4.475 %
Mn2O3 ......................... 0.0853 %
Na2O........................... 0.2161 %
P2O5............................ 0.1278 %
SiO2 .............................. 20.57 %

SO3 ............................... 2.921 %


SrO ............................. 0.2984 %
TiO2 ............................... 0.186 %

Indicative values for ZnO, F, LOI, Total, Insoluble residues, free CaO

NIST-1885a

Portland cement - Constituents

4x5g

Certified values
Al2O3 ............................. 4.026 %
CaO .............................. 62.39 %
Cr2O3 ........................... 0.0195 %
Fe2O3 ............................ 1.929 %
K2O ............................... 0.206 %

MgO.............................. 4.033 %
Mn2O3 ......................... 0.0478 %
Na2O............................. 1.068 %
P2O5............................ 0.1220 %
SiO2 ............................ 20.909 %

SO3 ............................... 2.830 %


SrO ............................... 0.638 %
TiO2 ............................... 0.195 %

Indicative values for ZnO, F, LOI, Total, Insoluble residues, free CaO

NIST-1886a

Portland cement (cranberry) - Constituents

3x5g

Certified values
Al2O3 ............................... 3.99 %
CaO .............................. 67.43 %
Fe2O3 .............................. 0.31 %
K2O ................................. 0.16 %
MgO ................................ 1.60 %

Mn2O3 ........................... 0.013 %


Na2O............................... 0.02 %
P2O5.............................. 0.025 %
SiO2 .............................. 22.53 %
SO3 ................................. 2.04 %

SrO ................................. 0.11 %


TiO2 ................................. 0.19 %
LOI*................................. 1.73 %

Indicative values for Cl, Cr2O3, F, ZnO, Total

92

Edition 2003/2004

www.lgcpromochem.com

Cement
Code

NIST-1887a

Product

Unit

Portland cement - Constituents

4x5g

Certified values
Al2O3 ............................. 6.202 %
CaO .............................. 60.90 %
Fe2O3 ............................ 2.861 %
K2O ............................... 1.100 %
MgO .............................. 2.835 %

Mn2O3 ......................... 0.1186 %


Na2O........................... 0.4778 %
P2O5.............................. 0.306 %
SiO2 ............................ 18.637 %
SO3 ............................... 4.622 %

SrO ............................... 0.322 %


TiO2 ............................. 0.2658 %
ZnO ............................. 0.0667 %

Indicative values for Cl, F, LOI, Total, Insoluble residues, free CaO

NIST-1888a

Portland cements - Constiutents

4x5g

Certified values
Al2O3 ............................. 4.265 %
CaO .............................. 63.23 %
Fe2O3 ............................ 3.076 %
K2O ............................... 0.526 %

MgO.............................. 2.982 %
Mn2O3 ......................... 0.1256 %
Na2O........................... 0.1066 %
SiO2 .............................. 21.22 %

SO3 ............................... 2.131 %


SrO ............................... 0.082 %
TiO2 ............................... 0.263 %
ZnO ............................... 0.107 %

Indicative values for P2O3, Cr2O3, F, LOI, Total, Insoluble residues, free CaO

NIST-1889a

Portland cement - Constituents

4x5g

Certified values
Al2O3 ............................... 3.89 %
CaO .............................. 65.34 %
Fe2O3 ............................ 1.937 %
K2O ............................... 0.605 %
MgO .............................. 0.814 %

Mn2O3 ......................... 0.2588 %


Na2O............................. 0.195 %
P2O5.............................. 0.110 %
SiO2 .............................. 20.66 %
SO3 ................................. 2.69 %

SrO ............................... 0.042 %


TiO2 ............................... 0.227 %
ZnO ............................. 0.0048 %

Indicative values for Cl, F, LOI, Total, Insoluble residues, free CaO

NRMGBW03201a Portland cement - Constituents

25 g

Certified values
Al2O3 ............................... 5.02 %
CaO .............................. 62.34 %
Fe2O3 .............................. 3.16 %
K2O ................................. 1.15 %

NIST-2686

MgO................................ 1.40 %
Na2O............................... 0.18 %
SiO2 .............................. 20.56 %
SO3 ................................. 2.29 %

L.O.I. ............................... 3.39 %


Insolubile residue............ 0.98 %

Portland cement clinker - Major phases

3 x 10 g

Major phases in cement clinker


Certified values
Alite................................. 58.6 %
Belite............................... 23.3 %

Ferrite ............................. 14.1 %


Aluminate ......................... 2.3 %

Periclase ............................ 33 %

Informational values for elemental constituents expressed as the chemical forms.

NIST-2688

Portland cement clinker - Major phases

3 x 10 g

Major phases in cement clinker


Certified values
Alite................................. 66.1 %
Belite............................... 17.9 %

Ferrite ............................. 11.1 %


Aluminate ......................... 5.0 %

Arcanite............................. 1.0 %

Informational values for elemental constituents expressed as the chemical forms.

NIST-2687

Portland cement clinker - Major phases

3 x 10 g

Major phases in cement clinker


Certified values
Alite................................. 73.6 %
Belite................................. 9.1 %

Ferrite ............................... 2.2 %


Aluminate ....................... 12.1 %

Arcanite............................. 1.0 %

Informational values for elemental constituents expressed as the chemical forms.

www.lgcpromochem.com

Edition 2003/2004

93

Glass and ceramics

Glass and ceramics


Code

BCR-126A

Product

Unit

Lead crystal glass - Constituents

300 g

Specially selected glass with a composition that displays many typical analytical problems.
Size: 100 x 100 x 10 mm
Certified values
Al2O3 .........................................................0.128 cg/g
BaO...........................................................1.036 cg/g
CaO ..........................................................1.033 cg/g
Fe2O3 ......................................................0.0055 cg/g
K2O ...........................................................10.00 cg/g
Li2O ...........................................................0.495 cg/g
MgO ..........................................................0.512 cg/g

BCR-664

Na2O .......................................................... 3.58 cg/g


PbO .......................................................... 23.98 cg/g
Sb2O3 ....................................................... 0.290 cg/g
SiO2 .......................................................... 57.80 cg/g
ZnO .......................................................... 1.020 cg/g
3
Density(20C)....................................... 2.9905 g/cm
Refractive index (20C) at 589.3nm............. 1.55967

Glass - Trace elements

plate

Size: 50 x 50 x 7 mm
Certified values
As............................... 5.9 mg/kg
Ba ............................ 29.1 mg/kg
Cd .............................. 5.7 mg/kg

BCR-300 (RM)

Cl ..............................68.4 mg/kg
Co.............................2.77 mg/kg
Cr..............................2.65 mg/kg

Pb ............................ 53.1 mg/kg


Sb ............................ 24.3 mg/kg
Se .............................. 8.6 mg/kg

Corundum (alpha-aluminia) - Lattice spacing

50 g

High crystallinty. Content of -alumina of about 6 mg/g. No other phase detected.


Impurities: CaO, Fe2O3, K2O, MgO, Na2O, SiO2, TiO2
Values for lattice spacing and relative intensity at five different reflections.
Available in granular form to be ground by the user.

BCR-301 (RM)

Mullite

50 g

High crystallinty. Vitreous phase 0.03 g/g. No other phase detected.


Impurities: CaO, Fe2O3, K2O, MgO, Na2O, TiO2
Values for lattice spacing and relative intensity at five different reflections.
Available in granular form to be ground by the user.

NIST-1412

Multicomponent glass - Constituents

set (8)

Set of 8 platelets (32 x 32 x 3 mm)


Certified values
Al2O3 ............................... 7.52 %
B2O3 ................................ 4.53 %
BaO................................. 4.67 %
CaO ................................ 4.53 %

CdO ................................ 4.38 %


K2O................................. 4.14 %
Na2O............................... 4.69 %
PbO ................................ 4.40 %

SiO2............................... 42.38 %
SrO ................................. 4.55 %
ZnO ................................. 4.48 %

Indicative values for Fe2O3, Li2O, MgO

NIST-89

Lead-barium glass - Constituents

45 g

Certified values
Cl .................................... 0.05 %
Al2O3 ............................... 0.18 %
As2O3 .............................. 0.03 %
As2O5 .............................. 0.36 %
BaO................................. 1.40 %
CaO ................................ 0.21 %

NIST-92

Fe2O3 ............................ 0.049 %


K2O................................. 8.40 %
MgO................................ 0.03 %
MnO.............................. 0.088 %
Na2O............................... 5.70 %
P2O5................................ 0.23 %

PbO............................... 17.50 %
SiO2............................... 63.35 %
SO3 ................................. 0.03 %
TiO2 ................................. 0.01 %
ZrO2 .............................. 0.005 %
LOI*................................. 0.32 %

Low boron soda-lime powder - Boron

45 g

Certified value
B2O3 ................................ 0.70 %
Indicative values for CaO, K2O, MgO, Na2O, SiO2, ZnO, LOI*

NIST-93a

Borosilicate glass - Constituents

wafer

32 x 6 mm wafer
Certified values
Cl .................................. 0.060 %
Al2O3 ............................... 2.28 %
B2O3 .............................. 12.56 %
CaO ................................ 0.01 %

NIST-1411

Fe2O3 ............................ 0.028 %


FeO .............................. 0.016 %
K2O............................... 0.014 %
MgO.............................. 0.005 %

Na2O ............................... 3.98 %


SiO2................................. 80.8 %
TiO2 ............................... 0.014 %
ZrO2 .............................. 0.042 %

Soft borosilicate glass - Constituents

set (10)

Set of 10 platelets (32 x 32 x 3 mm)


Certified values
Al2O3 ............................... 5.68 %
B2O3 .............................. 10.94 %
BaO................................. 5.00 %
CaO ................................ 2.18 %

94

Fe2O3 ............................ 0.050 %


K2O................................. 2.97 %
MgO................................ 0.33 %
Na2O............................. 10.14 %

Edition 2003/2004

SiO2............................... 58.04 %
SrO ................................. 0.09 %
TiO2 ................................. 0.02 %
ZnO ................................. 3.85 %

www.lgcpromochem.com

Glass and ceramics


Code

Product

Unit

NRMGBW03132

Borosilicate glass - Constituents

50 g

Certified values
F...................................... 0.54 %
Al2O3 ............................. 14.50 %
B2O3 ................................ 8.87 %
CaO .............................. 16.54 %

NIST-81a

Fe2O3 .............................. 0.34 %


K2O................................. 0.59 %
MgO................................ 4.40 %
Na2O............................. 0.096 %

SiO2............................... 53.98 %
TiO2 ................................. 0.19 %
LOI*................................. 0.26 %

Glass sand - Constituents

75 g

Certified values
Al2O3 ............................... 0.66 %
Cr2O3 ........................... 46 mg/kg

NIST-165a

Fe2O3 ............................ 0.082 %


TiO2 ................................ 0.12 %

ZrO2 .............................. 0.034 %

Glass sand (low iron) - Constituents

75 g

Certified values
Al2O3 ............................. 0.059 %
Fe2O3 ............................ 0.012 %

NIST-1413

TiO2 .............................. 0.011 %


ZrO2 .............................. 0.006 %

Glass sand (high alumina) - Constituents

75 g

Certified values
Al2O3 ............................... 9.90 %
BaO................................. 0.12 %
CaO ................................ 0.74 %

Sand No.1

Fe2O3 .............................. 0.24 %


K2O................................. 3.94 %
MgO................................ 0.06 %

Na2O ............................... 1.75 %


SiO2............................... 82.77 %
TiO2 ................................. 0.11 %

Sand - Constituents

200 g

Certified values
Al2O3 ............................. 0.061 %
CaO .............................< 0.02 %
Fe2O3 (total Fe) ............. 0.014 %
K2O ..............................< 0.02 %

MgO.............................. <0.02 %
Na2O............................. <0.02 %
SiO2 .............................. 99.74 %
TiO2 .............................. 0.026 %

Cr3O3 ........................... 0.0003 %


LOI*................................. 0.12 %

*Loss on ignition

Sand No.6

Sand - Constituents

200 g

Certified values
Al2O3 ............................... 0.60 %
CaO .............................< 0.02 %
Fe2O3 (total Fe) ............. 0.032 %

K2O................................. 0.40 %
MgO.............................. <0.02 %
Na2O............................. <0.02 %

SiO2............................... 98.66 %
TiO2 ............................... 0.024 %
LOI*................................. 0.14 %

*Loss on ignition

Sand No.8

Sand - Constituents

200 g

Certified values
Al2O3 ............................... 2.07 %
CaO ................................ 0.06 %
Fe2O3 (total Fe) ............... 0.26 %

K2O.............................. < 1.06 %


MgO................................ 0.12 %
Na2O............................... 0.20 %

SiO2............................... 95.63 %
TiO2 ............................... 0.073 %
LOI*................................. 0.48 %

*Loss on ignition

Sand No.9

Sand - Constituents

200 g

Certified values
Al2O3 ............................... 1.35 %
CaO ................................ 0.02 %
Fe2O3 (total Fe) ............. 0.103 %

K2O................................. 0.82 %
MgO................................ 0.06 %
Na2O............................... 0.10 %

SiO2............................... 97.24 %
TiO2 ............................... 0.044 %
LOI*................................. 0.24 %

*Loss on ignition

NIST-620

Soda-lime flat glass - Constituents

set (3)

Set of 3 platelets (35 x 35 x 3 mm)


Certified values
Al2O3 ............................... 1.80 %
As2O3 ............................ 0.056 %
CaO ................................ 7.11 %
Fe2O3 ............................ 0.043 %

NIST-621

K2O................................. 0.41 %
MgO................................ 3.69 %
Na2O............................. 14.39 %
SiO2 .............................. 72.08 %

SO3 ................................. 0.28 %


TiO2 ............................... 0.018 %

Soda-lime container glass - Constituents

set (3)

Set of 3 disks (38 x 5 mm)


Certified values
Al2O3 ............................... 2.76 %
As2O3 ............................ 0.030 %
BaO................................. 0.12 %
CaO .............................. 10.71 %

www.lgcpromochem.com

Fe2O3 ............................ 0.040 %


K2O................................. 2.01 %
Na2O............................. 12.74 %
MgO................................ 0.27 %

Edition 2003/2004

SO3 ................................. 0.13 %


SiO2............................... 71.13 %
TiO2 ............................... 0.014 %
ZrO2 .............................. 0.007 %

95

Glass and ceramics


Code

NIST-1830

Product

Unit

Soda-lime float glass - Constituents

3 platelets

Set of 3 platelets (38 x 38 x 6 mm)


Certified values
Al2O3 ............................... 0.12 %
CaO ................................ 8.56 %
FeO ............................... 0.032 %
Fe2O3 ............................ 0.121 %

NIST-1831

K2O................................. 0.04 %
MgO................................ 3.90 %
Na2O............................. 13.75 %
SiO2 .............................. 73.07 %

SO3 ................................. 0.26 %


TiO2 ............................... 0.011 %

Soda lime sheet glass - Constituents

3 platelets

Set of 3 platelets (37 x 37 x 3 mm)


Certified values
Al2O3 ............................... 1.21 %
CaO ................................ 8.20 %
FeO ............................... 0.025 %
Fe2O3 ............................ 0.087 %

EC 1.1

K2O................................. 0.33 %
MgO................................ 3.51 %
Na2O............................. 13.32 %
SiO2 .............................. 73.08 %

SO3 ................................. 0.25 %


TiO2 ............................... 0.019 %

Soda lime-magnesia-silica glass - Constituents

75x75x6 mm

Certified values
Al2O3 ............................... 1.08 %
CaO ................................ 8.63 %
Fe2O3(total Fe).............. 0.121 %

NIST-1834

K2O................................. 0.59 %
MgO................................ 3.78 %
Na2O............................. 13.41 %

SiO2............................... 71.97 %
SO3 (total S) .................... 0.23 %
TiO2 ............................... 0.040 %

Fused ore glass - Constiutents

disk

30 x 3 mm disc
Certified values
Al................................... 20.71 %
Ba ................................. 0.062 %
Ca ................................... 0.0955
Fe.................................... 0.32 %

K ..................................... 0.42 %
Mg ................................ 0.088 %
P ................................... 0.152 %
Si .................................. 20.19 %

Sr .................................. 0.153 %
Ti..................................... 1.11 %

Indicative values for B, Cr, Li, Na, Zr

Glass No.4

Fluoride opal glass - Constituents

25 g

Reference: Glass Technol., 1962, 3 (1), 9-16, the chemical analysis of a fluoride glass described as Standard
Glass No. 4.
Certified values
F...................................... 4.96 %
Al2O3 ............................... 3.02 %
B2O3 ................................ 0.19 %
CaO ................................ 4.24 %
Fe2O3 (total Fe) ............. 0.099 %

K2O................................. 0.57 %
MgO.............................. <0.05 %
Na2O............................. 15.45 %
SO3 (total S) ................. <0.05 %
SiO2 .............................. 69.49 %

TiO2 ............................... 0.041 %


ZnO ................................. 3.28 %
LOI* (550C) ................... 0.22 %

*Loss on ignition

Glass No.5

Soda lime-magnesia-silica glass - Constituents

25 g

Reference glass Technol.,1973, 14 (1), 5-13, The chemical analysis of a colourless soda-lime-silica glass.
Certified values
Al2O3 ............................... 1.12 %
CaO ................................ 6.55 %
Fe2O3 (total Fe) ............. 0.043 %

Glass No.6

K2O................................. 0.42 %
MgO................................ 2.75 %
Na2O............................. 15.65 %

SO3 (total S).................... 0.21 %


SiO2............................... 72.74 %
TiO2 ............................... 0.034 %

Soda lime-silica glass - Constituents

25 g

Certified values
Al2O3 ............................... 1.70 %
CaO ................................ 9.97 %
Fe2O3 (total Fe) ............. 0.034 %

Glass No.7

K2O................................. <0.1 %
MgO................................ <0.1 %
Na2O............................. 14.65 %

SO3 (total S).................... 0.21 %


SiO2............................... 73.06 %
TiO2 ................................. 0.02 %

Soda lime-silica glass - Constituents

25 g

Certified values
Al2O3 ............................... 1.50 %
CaO .............................. 11.03 %
Fe2O3 (total Fe) ............. 0.044 %
K2O ................................. 0.43 %

Na2O............................. 13.90 %
MgO................................ 0.14 %
SO3 (total S) ................... 0.19 %
SiO2 .............................. 73.06 %

TiO2 ............................... 0.042 %


LOI* (550C) ................... 0.07 %

*Loss on ignition

Glass No.8

Lead oxide-potassium oxide-silica glass - Constituents

25 g

Certified values
Al2O3 ............................... 0.05 %
As2O3 (total As)............... 0.32 %
B2O3 ................................ 0.36 %
CaO ..............................<0.02 %

Fe2O3 (total Fe)............. 0.010 %


K2O............................... 11.85 %
MgO.............................. <0.02 %
Na2O............................... 0.23 %

PbO............................... 30.59 %
SiO2............................... 56.34 %
TiO2 ................................. 0.02 %
LOI* (550C) ................... 0.21 %

*Loss on ignition

96

Edition 2003/2004

www.lgcpromochem.com

Glass and ceramics


Code

SGT 10

Product

Unit

Soda-lime-silica container glass - Constituents

disc

40 mm diameter disc
Certified values
Al2O3 ............................... 1.62 %
BaO................................. 0.02 %
CaO ................................ 10.7 %
Fe2O3 ............................ 0.325 %

SGT 10-P

K2O................................. 0.35 %
MgO................................ 1.81 %
Na2O............................... 12.2 %
SiO2 ................................ 72.7 %

SO3 ................................. 0.05 %


TiO2 ............................... 0.097 %
Cr3O3 ............................. 0.020 %

Soda-lime-silica container glass - Constituents

pieces

Glass pieces

SGT 11

disc

Soda-lime-silica container glass - Constituents


40 mm diameter disc
Certified values
Al2O3 ............................... 1.83 %
BaO................................. 0.03 %
CaO ................................ 10.3 %
Fe2O3 ............................ 0.342 %

SGT 11-P

K2O................................. 0.69 %
MgO................................ 2.14 %
Na2O............................... 13.6 %
SiO2 ................................ 70.7 %

SO3 ................................. 0.06 %


TiO2 ............................... 0.068 %
Cr3O3 ............................. 0.205 %

Soda-lime-silica container glass - Constituents

pieces

Glass pieces

NIST-607

5g

Potassium feldspar - Trace elements


Certified values
Rb ........................ 523.90 mg/kg

Sr..........................65.485 mg/kg

NIST-610 and NIST-611


NIST-610 and NIST-611 are the same material and therefore have the same certified values. NIST-610 consists
of glass 3 mm thick and NIST-611 is 1 mm thick.

NIST-610

Glass - Trace elements

6 wafers

Certified values
Fe.............................. 458 mg/kg
Mn ............................. 485 mg/kg
Ni ........................... 458.7 mg/kg

Pb ..............................426 mg/kg
Rb...........................425.7 mg/kg
Sr............................515.5 mg/kg

Th........................... 457.2 mg/kg


U ............................ 461.5 mg/kg

Indicative values for Ag, Au, Co, Cu, K, Ti, Tl, Zn

NIST-611

Glass - Trace elements

6 wafers

NIST-612 and NIST-613


NIST-612 and NIST-613 are the same material and therefore have the same certified values. NIST-612 consists
of glass 3 mm thick and NIST-613 is 1 mm thick.

NIST-612

Glass - Trace elements

6 wafers

Certified value
Ag ............................ 22.0 mg/kg
Fe................................ 51 mg/kg
Ni ............................. 38.8 mg/kg

Pb ...........................38.57 mg/kg
Rb.............................31.4 mg/kg
Sr..............................78.4 mg/kg

Th............................. 37.9 mg/kg


U ............................ 37.38 mg/kg

Indicative values for Au, B, Ba, Ce, Co, Cu, Dy, Er, Eu, Gd, K, La, Mn, Nd, Sm, Ti, Tl, Zn

NIST-613

Glass - Trace elements

6 wafers

NIST-614 and NIST-615


NIST-614 and NIST-615 are the same material and therefore have the same certified values. NIST-614 consists
of wafers of glass 3 mm thick and NIST-615 is 1 mm thick.

NIST-614

Glass - Trace elements

6 wafers

Certified values
Ag ............................ 0.42 mg/kg
Cu ............................ 1.37 mg/kg
K ................................. 30 mg/kg

Pb .............................2.32 mg/kg
Rb...........................0.855 mg/kg
Sr..............................78.4 mg/kg

Th........................... 0.748 mg/kg


U ............................ 0.823 mg/kg

Indicative values for Au, B, Cd, Co, Eu, Fe, Ga, La, Ni, Sb, Sc, Ti, Tl

NIST-615

www.lgcpromochem.com

Glass - Trace elements

6 wafers

Edition 2003/2004

97

Glass and ceramics


Code

Product

Unit

NIST-616 and NIST-617


NIST-616 and NIST-617 are the same material and therefore have the same certified values. NIST-616 consists
of wafers of glass 3 mm thick and NIST-617 is 1 mm thick.

NIST-616

Glass - Trace elements

6 wafers

Certified values
K ................................. 29 mg/kg
Pb ............................ 1.85 mg/kg

Sr............................41.72 mg/kg
Th .........................0.0252 mg/kg

U .......................... 0.0721 mg/kg

Indicative values for Au, B, Cu, Fe, Ga, La, Rb, Sb, Sc, Ti, Tl

NIST-617

Glass - Trace elements

6 wafers

NIST-1872

Synthetic glass - Lead and germanium

set (3)

NIST-1872 consists of three different lead-germanate glasses in rod form approximately 2 x 2 x 20 mm.
K-453
Certified values
Ge ................................. 28.43 %

Pb ................................. 54.21 %

Indicative value for O


K-491
Certified values
Ge ................................. 26.10 %

Pb ................................. 54.69 %

Indicative values for Al, Ce, Fe, O, Si, Ta, Ti, Zr


K-968
Certified values
Ge ................................. 25.93 %

Pb ................................. 54.74 %

Indicative values for Ba, Cr, Eu, Mg, Ni, O, P, Si, Th, Ti, U, Zr

NIST-1873

Synthetic glass - Barium, silicon and zinc

set (3)

NIST-1873 consists of three different barium-zinc-silicate glasses in rod form approximately 2 x 2 x 20


mm.
K-458
Certified values
Ba ................................. 41.79 %

Si .................................. 23.05 %

Zn.................................... 3.01 %

Indicative value for O


K-489
Certified values
Ba ................................. 39.53 %

Zn ................................... 2.93 %

Indicative values for Al, Ce, Fe, O, Pb, Si, Ta, Ti, Zr
K-963
Certified values
Ba ................................. 39.21 %

Zn ................................... 2.95 %

Indicative values for Cr, Eu, Ge, Mg, O, Si

NIST-2063a

Mineral glass (for transmission electron microscope)

glass film

NIST-2063a consists of a mineral glass film that has been deposited onto a 20 nm thick carbon support film on a
3 mm diameter, copper transmission electron microscope grid.
Certified values
Ca ................................. 11.82 %
Fe.................................. 11.06 %

Mg .................................. 7.97 %
O..................................... 43.2 %

Si................................... 25.34 %

Indicative value for Ar

98

Edition 2003/2004

www.lgcpromochem.com

Plastics

Plastics
Code

Product

Unit

The Packaging-Directive - EC-Directive 94/62/EEC - regulates the amount of metals such as Cd, Cr,
Hg and Pb in plastics. The materials VDA 001-4 as well as BCR-680 and -681 were produced to
facilitate the implementation of this directive and to allow the effective introduction of QA-systems for
elemental analysis of plastic materials.
VDA 001-4

Plastic - Cadmium

4 bottles

Four polyethylene reference materials have been certified by IRMM on behalf of Verband der Automobilindustrie
e.V. (VDA).
Certified values
Sicolen Yellow 09/16493
Cd ................... 40.9 1.2 mg/kg
Sicolen Orange 28/16494
Cd ................... 75.9 2.1 mg/kg
Sicolen Red 39/16495
Cd ................. 197.9 4.8 mg/kg
Sicolen Bordeaux 49/16496
Cd ..................... 407 12 mg/kg

BCR-680

Polyethylene - Trace elements (high level)

100 g

Certified values
As............................. 30.9 mg/kg
Br .............................. 808 mg/kg
Cd .......................... 140.8 mg/kg

BCR-681

Cl ...............................810 mg/kg
Cr............................114.6 mg/kg
Hg.............................25.3 mg/kg

Pb .......................... 107.6 mg/kg


S ....................... 0.67x103 mg/kg

Polyethylene - Trace elements (low level)

100 g

Certified values
As............................. 3.93 mg/kg
Br ................................ 98 mg/kg
Cd ............................ 21.7 mg/kg

Cl ..............................92.9 mg/kg
Cr..............................17.7 mg/kg
Hg.............................4.50 mg/kg

Pb ............................ 13.8 mg/kg


S ................................. 78 mg/kg

Metals
Code

BCR-025A

Product

Unit

Aluminium (primary ingot) - Oxygen, carbon and boron

12 g

26 mm diameter x 9 mm disc
Certified values
O .............................. <0.1 mg/kg

BCR-025B

C...............................0.26 mg/kg

Aluminium (primary ingot) - Oxygen, carbon and boron

B .............................. 1.22 mg/kg

6g

8 mm diameter x 50 mm cylinder

BCR-329

Aluminium-Magnesium alloy (3 % Mg) - Boron

50 g

Chips
Certified value
B .................................... 30 g/g

BCR-330

Aluminium-Magnesium alloy (3 % Mg) - Boron

190 g

55 mm diameter x 30 mm disc
Certified value
B ................................. 30 mg/kg

BCR-017A

Copper - Sulphur and phosphorous

370 g

42 mm diameter x 30 mm disc
Certified values
P ................................ 6.9 mg/kg

BCR-017B

S ...............................10.4 mg/kg

Copper - Sulphur and phosphorous

50 g

Chips (bottle with 50 g)

www.lgcpromochem.com

Edition 2003/2004

99

Metals
Code

BCR-022A

Product

Unit

Copper (electrolytic tough pitch) - Oxygen

42 g

26 mm diameter x 9 mm disc
Certified value
Oxygen...................... 139 mg/kg

BCR-022B

Copper (electrolytic tough pitch) - Oxygen

28 g

9 m diameter x 50 mm rods

BCR-054R

42 g

Copper - Oxygen
7 m diameter x 50 mm rods
Certified value
O .............................. 0.47 mg/kg

BCR-058

Copper (continuous cast) - Oxygen

17 g

7 mm diameter x 50 mm rods
Certified value
Oxygen...................... 390 mg/kg

BCR-055

Lead (refined) - Oxygen

71 g

7 mm diameter x 9 mm discs
Certified value
Oxygen....................... 1.0 mg/kg

BCR-023A

Molybdenum - Oxygen, nitrogen and carbon

49 g

26 mm diameter x 9 mm discs
Certified values
Oxygen..................... 14.7 mg/kg

BCR-023B

Nitrogen....................<0.3 mg/kg

Carbon ..................... <0.2 mg/kg

Molybdenum - Oxygen, nitrogen and carbon

25 g

25 cubes of 1 g

BCR-099

50 g

Nickel - Oxygen and nitrogen


25 cubes of 2 g
Certified values
Oxygen....................... 8.4 mg/kg

BCR-024B

Nitrogen......................1.1 mg/kg

Titanium - Oxygen and nitrogen

10 g

25 cubes of 0.4 g
Certified values
Nitrogen .................... 117 mg/kg

BCR-024C

Oxygen ......................608 mg/kg

Titanium - Oxygen, nitrogen

5g

25 cubes of 0.2 g

BCR-059A

21 g

Titanium alloy Ti6Al4V - Oxygen and nitrogen


26 mm diameter x 9 mm discs
Certified values
Oxygen.................... 1750 mg/kg

BCR-059B

Nitrogen.....................172 mg/kg

Titanium alloy Ti6Al4V - Oxygen and nitrogen

5g

25 cubes of 0.2 g

BCR-318

20 g

Titanium - Hydrogen
7 mm diameter x 1 mm discs (approx. 100 discs)
Certified value
Hydrogen ................. 12.2 mg/kg

BCR-275

Zirconium alloy Zircaloy-4 - Oxygen, nitrogen and carbon

9g

10 discs each 13 mm diameter x 1 mm


Certified values
O ............................. 1673 mg/kg

BCR-276

N...............................39.0 mg/kg

C ............................ 113.3 mg/kg

Zirconium alloy Zircaloy-4 - Oxygen, nitrogen and carbon

20 g

4.5 mm diameter x 2 mm (approx. 100 cylinders)


Certified values
O ............................. 1541 mg/kg

100

N...............................41.1 mg/kg

Edition 2003/2004

C ............................ 107.6 mg/kg

www.lgcpromochem.com

Metals
Code

BCR-102

Product

Unit

Tungsten carbide powder - Oxygen

2-3 g

Powder sealed under argon


Certified value
O ............................... 185 mg/kg

BCR-074A

Electrolytic copper - Trace elements

disc

Cylinder of 40 mm diameter and 30 mm height


Certified values
Ag ............................ 12.8 mg/kg
As............................. 0.78 mg/kg
Cd .......................... <0.02 mg/kg
Co .......................... <0.05 mg/kg
Cr ............................. <0.1 mg/kg

Fe .............................1.14 mg/kg
Mn ............................1.27 mg/kg
Ni ..............................1.04 mg/kg
Pb .............................0.97 mg/kg
Sb .............................0.58 mg/kg

Se ............................ 0.37 mg/kg


Sn .......................... <0.07 mg/kg
Zn............................. 0.46 mg/kg

Indicative values for Bi, Te

BCR-074B

Electrolytic copper - Trace elements

2 rods

Pair of rods of 8 mm diameter and 100 mm lenght

BCR-074C

Electrolytic copper - Trace elements

50 g

Small pieces in a bottle containing about 50 g

BCR-075A

disc

Copper with added impurities - Trace elements


Cylinder of 40 mm diameter and 30 mm height
Certified values
Ag ............................ 12.2 mg/kg
As............................. 3.74 mg/kg
Bi.............................. 1.44 mg/kg
Cd ............................ 2.57 mg/kg
Co ............................ 2.50 mg/kg

BCR-075B

Cr..............................0.89 mg/kg
Fe ...............................9.0 mg/kg
Mn ............................3.23 mg/kg
Ni ..............................1.45 mg/kg
Pb .............................3.27 mg/kg

Sb ............................ 2.56 mg/kg


Se ............................ 1.26 mg/kg
Sn ............................ 1.09 mg/kg
Te............................. 1.52 mg/kg
Zn............................. 3.47 mg/kg

Copper with added impurities - Trace elements

2 rods

Pair of rods of 8 mm diameter and 100 mm length

BCR-075C

Copper with added impurities - Trace elements

50 g

Small pieces in a bottle containing about 50 g

BCR-691

Set (5)

Copper alloys - Alloying elements


Set of five discs (one of each composition) of 35 diameter and 2 mm thickness
Certified values
Substance

Quaternary bronze

Brass

Arsenic-Copper

Lead-bronze

Tin-bronze

As....................................1.94 g/kg.............. 0.99 g/kg ..............46.0 g/kg ..........2.85 g/kg.............. 1.94 g/kg
Pb .....................................79 g/kg................ 3.9 g/kg ..............1.75 g/kg .............92 g/kg.............. 2.04 g/kg
Sn ...................................71.6 g/kg.............. 20.6 g/kg ..............2.02 g/kg ...........101 g/kg................. 70 g/kg
Zn....................................60.2 g/kg............... 148 g/kg ..............0.55 g/kg ..........1.48 g/kg.............. 1.57 g/kg

BCR-286A

Lead (electrolytically refined) - Trace elements

600 g

Blocks of 60 mm x 60 mm x 12 mm
Certified values
Ag .......................... 0.015 mg/kg
As......................... <0.002 mg/kg
Bi.............................. 21.5 mg/kg
Cd .......................... 0.125 mg/kg

BCR-286B

Cu.............................1.49 mg/kg
Ni ............................0.041 mg/kg
Sb .............................0.10 mg/kg
Se ...........................<0.05 mg/kg

Sn .......................... <0.05 mg/kg


Te............................. <0.1 mg/kg
Ti................................ 2.5 mg/kg
Zn............................. <0.1 mg/kg

Lead (electrolytically refined) - Trace elements

160 g

Chips in bottles containing about 160 g

BCR-287A

600 g

Lead (thermally refined) -Trace elements


Blocks of 60 mm x 60 mm x 12 mm
Certified values
Ag ............................ 15.2 mg/kg
As......................... <0.003 mg/kg
Bi.............................. 67.3 mg/kg
Cd ............................ 0.36 mg/kg

BCR-287B

Cu.............................0.89 mg/kg
Ni ............................0.024 mg/kg
Sb ...........................0.040 mg/kg
Se ...........................<0.05 mg/kg

Lead (thermally refined) -Trace elements

Sn .......................... <0.05 mg/kg


Te............................. <0.2 mg/kg
Ti.............................. 0.73 mg/kg
Zn............................. <0.1 mg/kg

160 g

Chips in bottles containing about 160 g

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Edition 2003/2004

101

Metals
Code

BCR-288A

Product

Unit

Lead with added impurities - Trace elements

600 g

Blocks of 60 mm x 60 mm x 12 mm
Certified values
Ag ............................ 30.5 mg/kg
As............................. 55.7 mg/kg
Bi............................ 215.8 mg/kg
Cd ............................ 33.3 mg/kg

BCR-288B

Cu.............................19.3 mg/kg
Ni ..............................4.57 mg/kg
Sb .............................32.5 mg/kg
Se .............................<0.2 mg/kg

Sn ............................ 30.6 mg/kg


Te............................. 32.8 mg/kg
Ti................................ 2.3 mg/kg
Zn............................... 8.2 mg/kg

Lead with added impurities - Trace elements

160 g

Chips in bottles containing about 160 g

BCR-321

0.7 kg

Unalloyed zinc - Trace elements


Discs of 80 mm diameter and 20 mm thickness
Certified values
Al.............................. <0.7 mg/kg
In .............................. <0.2 mg/kg

Pb .............................4.85 mg/kg
Sn .............................<0.5 mg/kg

Tl.............................. 0.78 mg/kg

Indicative values for Cd, Cu, Fe

BCR-322R

Unalloyed zinc - Impurities

0.7 kg

Discs of 60 mm diameter and 30 mm thickness


Certified values
Cd .......................... 15.08 mg/kg
Cu ............................ 5.89 mg/kg

BCR-323R

Fe .............................19.1 mg/kg
Pb .............................15.0 mg/kg

Sn .............................. 5.6 mg/kg


Tl.............................. 5.28 mg/kg

Unalloyed zinc - Impurities

0.7 kg

Discs of 60 mm diameter and 30 mm thickness


Certified values
Cd ............................ 6.51 mg/kg
Cu ............................ 18.9 mg/kg

BCR-324R

Fe .............................11.3 mg/kg
Pb .............................48.6 mg/kg

Sn ............................ 18.7 mg/kg


Tl.............................. 10.8 mg/kg

Unalloyed zinc - Impurities

0.7 kg

Discs of 60 mm diameter and 30 mm thickness


Certified values
Cd ............................ 48.6 mg/kg
Cu ............................ 9.87 mg/kg

BCR-325R

Fe .............................58.5 mg/kg
Pb .............................26.1 mg/kg

Sn .............................. 9.8 mg/kg


Tl.............................. 19.9 mg/kg

Unalloyed zinc - Impurities

0.7 kg

Discs of 60 mm diameter and 30 mm thickness


Certified values
Cd ............................ 94.7 mg/kg
Cu ............................ 47.5 mg/kg

BCR-326

Fe .............................56.1 mg/kg
Pb ..............................142 mg/kg

Sn ............................ 46.1 mg/kg


Tl.............................. 36.8 mg/kg

Unalloyed zinc - Impurities

0.7 kg

Discs of 80 mm diameter and 2 mm thickness


Certified values
Cd .......................... 203.0 mg/kg
Cu .......................... 104.8 mg/kg

Fe ...........................264.8 mg/kg
Pb ...........................307.0 mg/kg

Indicative value for Al

BCR-327

Unalloyed zinc - Impurities

0.7 kg

Discs of 80 mm diameter and 2 mm thickness


Certified values
Cd .......................... 301.4 mg/kg

Fe ...........................144.0 mg/kg

Pb .......................... 409.4 mg/kg

Indicative value for Cu

BCR-351

Zinc alloy ZnAl4 - Trace elements

0.7 kg

Discs of 80 mm diameter and 20 mm thickness


Certified values
Al................... 43.55 x 103 mg/kg
Cu .......................... 12.13 mg/kg
In .............................. <0.2 mg/kg

Mg ..........................131.0 mg/kg
Pb .............................4.50 mg/kg
Sn ................................<1 mg/kg

Tl.............................. 0.74 mg/kg

Indicative values for Cd, In, Ni

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Metals
Code

BCR-352

Product

Unit

Zinc alloy ZnAl4 - Trace elements

0.7 kg

Discs of 80 mm diameter and 20 mm thickness


Certified values
Al................... 41.50 x 103 mg/kg
Cd ............................ 2.88 mg/kg
Cu .......................... 31.26 mg/kg

In ..............................3.02 mg/kg
Mg ..........................283.0 mg/kg
Ni ..............................6.74 mg/kg

Sn .............................. 3.0 mg/kg


Tl................................ 3.2 mg/kg

Indicative value for Pb

BCR-353

Zinc alloy ZnAl4 - Trace elements

0.7 kg

Discs of 80 mm diameter and 20 mm thickness


Certified values
Al..................... 39.5 x 103 mg/kg
Cd .......................... 10.44 mg/kg
Cu .......................... 100.0 mg/kg

BCR-354

In ..............................2.55 mg/kg
Mg ..........................452.5 mg/kg
Pb .............................24.4 mg/kg

Sn .............................. 5.6 mg/kg


Tl.............................. 3.95 mg/kg

Zinc alloy ZnAl4 - Trace elements

0.7 kg

Discs of 80 mm diameter and 20 mm thickness


Certified values
Al................... 37.27 x 103 mg/kg
Cd ............................ 29.7 mg/kg
Cu .......................... 312.3 mg/kg

BCR-355

In ................................9.8 mg/kg
Mg .............................602 mg/kg
Ni ..............................83.1 mg/kg

Pb ............................ 30.8 mg/kg


Sn ............................ 14.1 mg/kg
Tl............................ 11.01 mg/kg

Zinc alloy ZnAl4 - Trace elements

0.7 kg

Discs of 80 mm diameter and 20 mm thickness


Certified values
Al................... 34.43 x 103 mg/kg
Cd ............................ 58.1 mg/kg
Cu ........................... 1035 mg/kg

BCR-356

In ..............................24.6 mg/kg
Mg .............................786 mg/kg
Ni ...............................268 mg/kg

Pb ............................ 56.9 mg/kg


Sn ............................ 29.1 mg/kg
Tl............................ 23.25 mg/kg

Zinc alloy ZnAl4Cu1 - Trace elements

0.7 kg

Discs of 80 mm diameter and 20 mm thickness


Certified values
Al................... 44.34 x 103 mg/kg
Cd ............................ 0.73 mg/kg
Cu ................. 3.944 x 103 mg/kg

Fe .............................31.5 mg/kg
In ..............................<0.2 mg/kg
Mg ..........................132.3 mg/kg

Ni ............................. 3.43 mg/kg


Pb ............................ 9.87 mg/kg
Tl.............................. 0.79 mg/kg

Indicative value for Sn

BCR-357

Zinc alloy ZnAl4Cu1 - Trace elements

0.7 kg

Discs of 80 mm diameter and 20 mm thickness


Certified values
Al................. 42.270 x 103 mg/kg
Cd ............................ 2.83 mg/kg
Cu ................ 5.849 x 103 mg/kg
Fe............................. 25.7 mg/kg

BCR-358

In ..............................3.30 mg/kg
Mg .............................273 mg/kg
Ni ..............................9.82 mg/kg
Pb .............................13.8 mg/kg

Sn ............................ 3.51 mg/kg


Tl.............................. 2.76 mg/kg

Zinc alloy ZnAl4Cu1 - Trace elements

0.7 kg

Discs of 80 mm diameter and 20 mm thickness


Certified values
Al................... 39.46 x 103 mg/kg
Cd .......................... 10.22 mg/kg
Cu .................. 7.93 x 103 mg/kg
Fe............................. 40.5 mg/kg

BCR-359

In ..............................7.04 mg/kg
Mg .............................403 mg/kg
Ni ............................26.98 mg/kg
Pb .............................22.5 mg/kg

Sn ............................ 7.87 mg/kg


Tl.............................. 6.09 mg/kg

Zinc alloy ZnAl4Cu1 - Trace elements

0.7 kg

Discs of 80 mm diameter and 20 mm thickness


Certified values
Al................... 37.11 x 103 mg/kg
Cd ............................ 29.8 mg/kg
Cu .................. 9.89 x 103 mg/kg
Fe........................... 119.7 mg/kg

BCR-360

In ..............................15.5 mg/kg
Mg .............................557 mg/kg
Ni ..............................92.6 mg/kg
Pb .............................36.2 mg/kg

Sn .......................... 16.93 mg/kg


Tl............................ 13.34 mg/kg

Zinc alloy ZnAl4Cu1 - Trace elements

0.7 kg

Discs of 80 mm diameter and 20 mm thickness


Certified values
3
Al................... 34.27 x 10 mg/kg
Cd ............................ 59.5 mg/kg
Cu ................ 12.34 x 103 mg/kg

www.lgcpromochem.com

In ..............................29.8 mg/kg
Mg .............................705 mg/kg
Ni ...............................267 mg/kg

Edition 2003/2004

Pb ............................ 73.9 mg/kg


Sn ............................ 33.0 mg/kg
Tl.............................. 25.9 mg/kg

103

Metals
Code

BCR-361

Product

Unit

Zinc alloy ZnAl4Cu1 - Trace elements

0.7 kg

Discs of 80 mm diameter and 20 mm thickness


Certified values
Al................... 40.68 x 103 mg/kg
Cu .................. 7.98 x 103 mg/kg

Fe ...........................10.34 mg/kg
Pb .............................5.31 mg/kg

Sn ............................ 46.3 mg/kg


Tl.............................. 37.4 mg/kg

Indicativ values for cd, In

BCR-089

Titnanium alloy Ti 6Al 4V - Impurities

disc

Cylinder of 40 mm diameter and 20 mm height


Certified values
Al................................. 59.7 g/kg

BCR-090A

V ............................... 39.76 g/kg

Titanium - Impurities

disc

Cylinder of 40 mm diameter and 20 mm height


Certified values
B ....................... 28.2 x 10-3 g/kg
Co ............................ 0.501 g/kg
Cr .............................. 0.533 g/kg

Cu..............................0.513 g/kg
Fe ............................. 0.563 g/kg
Mn ............................ 0.314 g/kg

Mo ............................ 0.488 g/kg


Ni ............................. 0.667 g/kg

Indivativ values for Al, Nb, Sn, V, W, Zr

BCR-090B

Titanium - Impurities

25 g

Cubes of about 0.2 g

BCR-098

10 g

Zircaloy-4 - Impurities
Chips
Certified values
Cr ............................. 906 mg/kg
Fe............................ 2143 mg/kg

Hf..............................77.6 mg/kg
Sn ..........................14600 mg/kg

LGC Promochem supplies a comprehensive range of ferrous and non-ferrous metal certified

reference materials produced by BCR , European Commission and National Institute of Standards
and Technology (NIST), USA. Please contact the responsible office in your country.

104

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Miscellaneous

Miscellaneous
Code

Product

Unit

LGC9000

Wool worsted/polyester woven fabric

10 x 1 g

Wool/polyester fabric with the wool as combed fibres and the polyester as discontinuous fibres.
Certified values
Polyester ......................... 56.3 %

LGC9001

Wool ............................... 43.7 %

Cotton/polyester woven fabric

10 x 1 g

Cotton/polyester fabric with the cotton as normal unmercerized fibres and the polyester as discontinuous fibres.
Certified values
Polyester ......................... 51.5 %

LGC3004

Cotton............................. 48.5 %

Petroleum wax - Oil

5x1g

Certified value
Oil content....................... 0.54 %

NIST-2567

Catalyst package for lubricant oxidation - ASTM sequence IIIE engine test

set (5)

This Standard Reference Material is specified for the use in the NIST modification to ASTM D 4742, Standard
Test Method for the Oxidation Stability of Gasoline Automobile Engine Oils by Thin-Film Oxygen Uptake (TFOUT).
NIST-2567 consist of one ampoule each of the following:
- oxidised/nitrated fuel fraction
- nitro-paraffin model compound
- nitro-aromatic model compound
- metal naphthenate mixture
- distilled water

NIST-2556

Used auto catalyst - recycled pellet

70 g

Certified values
Pb ........................... 6228 mg/kg
Pd .......................... 326.0 mg/kg

NIST-2557

Pt ............................697.4 mg/kg
Rh.............................51.2 mg/kg

Used auto catalyst - recycled monolith

70 g

Certified values
Pb ........................... 1131 mg/kg
Pd .......................... 233.2 mg/kg

NIST-RM 8495

Pt .............................1131 mg/kg
Rh...........................135.1 mg/kg

Northern softwood bleached kraft pulp - Properties (RM)

10 sheets

Properties of fibres and paper sheets

NIST-RM 8496

Eucalyptus hardwood bleached kraft pulp - Properties (RM)

10 sheets

Properties of fibres and paper sheets

NIST-154c

Titanium dioxide - Purity

90 g

This Standard Reference Material (SRM ) is intended primarily for use in the evaluation of techniques employed
in the assay of titanium dioxide in the paint and ceramic industries.
Certified value
Titanium dioxide.......... 99.951 %
Informational values for impurities

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Edition 2003/2004

105

Filter media

Filter media
Code

BCR-545

Product

Unit

Glass fibre filter - Chromium

filter

Welding dust loaded on a filter.


Certified values
Cr (VI) .........................................................40.2 g/kg

total leachable Cr ....................................... 39.5 g/kg

NAMI A-2 and NAMI B-2


Intended for use in conjunction with measurements of elements in air filters collected from work-room
air. The levels correspond to current threshold limit values of contaminants in workroom atmospheres.
NAMI A-2

Cellulose ester membrane filter - Metals

filter

37 mm filters
Certified values
Al..................................... 255 g
As................................... 8.68 g
Be .................................. 1.68 g
Cd .................................. 16.9 g
Co .................................. 42.3 g
Cr ................................... 54.3 g
Cu .................................. 85.2 g

Fe ....................................593 g
Mg ..................................84.6 g
Mn ...................................170 g
Mo ..................................42.7 g
Ni ....................................68.4 g
Pb ...................................42.0 g
Sb ...................................42.6 g

Sn .................................. 42.8 g
Ti.................................... 42.0 g
Tl.................................... 2.96 g
V .................................... 17.6 g
W ................................... 43.4 g
Zn.................................... 256 g

Indicative values for B, Ba, Zr

NAMI(5)/A-2
NAMI B-2

Cellulose ester membrane filter - Metals

5 filter

Cellulose ester membrane filter - Metals

filter

37 mm filters
Certified values
Al..................................... 125 g
As................................... 4.25 g
Be .................................. 0.82 g
Cd .................................. 8.29 g
Co .................................. 20.7 g
Cr ................................... 26.6 g
Cu .................................. 41.7 g

Fe ....................................290 g
Mg ..................................41.4 g
Mn ..................................83.1 g
Mo ..................................20.9 g
Ni ....................................33.5 g
Pb ...................................20.5 g
Sb ...................................20.8 g

Sn .................................. 21.0 g
Ti.................................... 20.5 g
Tl.................................... 1.45 g
V .................................... 8.60 g
W ................................... 21.2 g
Zn.................................... 125 g

Indicative values for B, Ba, Zr

NAMI(5)/B-2

Cellulose ester membrane filter - Metals

5 filter

NIST-2679a

Filter media - Quartz

set (4)

Intended to be used to determine the levels of potentially hazardous materials in industrial atmospheres.
I
Certified value
Quartz ................................. 2 g
Indicative value for clay
II
Certified value
Quartz ............................ 30.8 g
Indicative value for clay
III
Certified value
Quartz ............................ 80.2 g
Indicative value for clay
IV
Certified value
Quartz .......................... 202.7 g
Indicative value for clay

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Filter media
Code

NIST-2783

Product

Unit

Air particulate on filter media - Trace elements

4 filter

This Standard Reference Material is an air particulate sample reduced in particle size to simulate PM25 air
particulate matter (particles with an aerodynamic equivalent diameter of 2.5 m) and deposited on a
polycarbonate filter membrane. NIST-2783 included two loaded filters and two blank filters.
Certified values
Al...................................... 23210
As........................................ 11.8
Ba ........................................ 335
Ca .................................... 13200
Co ......................................... 7.7
Cr ......................................... 135

Cu.........................................404
Fe .....................................26500
K .........................................5280
Mg ......................................8620
Mn ........................................320
Na.......................................2860

Ni ........................................... 68
Pb ........................................ 317
Sb ....................................... 71.8
Ti........................................ 1490
V ......................................... 48.5
Zn....................................... 1790

Indicative values for Ce, Rb, S, Sc, Si, SM, Th, U, W

NIST-2678

Blank cellulose acetate membrane filter

set (10)

Set of 10 blank filters


Intended for use in evaluating the performance of air sampling filter methods.
Certified values or limits of detection for each of 30 constituent elements as well as 6 leachable anions and
cations.

NIST-2681

Blank ashless filter - Trace elements

set(10)

Intended for use in evaluating the performance of air sampling filter methods.
Certified values or limits of detection for each of 30 constituent elements as well as 6 leachable anions and
cations.

RTC-CRM002

Activated charcoal filter - Trace elements

100 g

Certified values
Ag ............................... 18 mg/kg

Cr...........................36339 mg/kg

Cu ......................... 96935 mg/kg

Indicative values for 22 further elements

RTC-CRM004

Diatomaceous earth filter - Trace elements

100 g

Certified values
Ba ........................... 1595 mg/kg
Cd ................................. 2 mg/kg

Cr.................................21 mg/kg
Pb ..........................11871 mg/kg

Indicative values for 20 further elements

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Edition 2003/2004

107

Paint and industrial sludges

Paint and industrial sludges


Code

Product

Unit

BCR-620, BCR-621 and BCR-623


These paint reference materials are to be used in support of the EU Toy Safety Directive
(88/378/EEC). The certified and indicative values are method specific and relate only to the European
Standard EN71-3: 1994.
BCR-620

Mild steel coated with alkyd resin paint - Trace elements

panel

The material consists of a mild steel panel, size 150 x 100 mm, sprayed on one side with alkyd resin paint.
Certified values
As............................. 23.0 mg/kg
Ba ............................. 430 mg/kg
Cd ............................. 117 mg/kg

BCR-621 (RM)

Cr.................................64 mg/kg
Pb ..............................140 mg/kg
Sb ................................83 mg/kg

Se ............................. 240 mg/kg

Beechwood coated nitrocellulose paint - Trace elements

panel

The material consists of a beechwood panel, size 150 x 100 mm, sprayed on one side with nitrocellulose paint.
Indicative values for As, Ba, Cd, Se

BCR-623

Comminuted paint from alkyd resin paint - Trace elements

2g

Certified values
As................................ 23 mg/kg
Ba ............................. 105 mg/kg
Cd ............................ 26.0 mg/kg

NIST-2579a

Cr................................9.4 mg/kg
Pb ................................19 mg/kg
Sb ................................14 mg/kg

Se ............................... 40 mg/kg

Set of six lead paint films (NIST-2570 - NIST-2575) - Lead

set (6)

A unit of NIST-2579a consists of a set of six coated polyester sheets, approximately 7.6 cm wide and 10.2 cm
long. Five of the six sheets, NIST-2571 to NIST-2575, are coated with a single, uniform paint layer. The units are
color coded and each color indicates a different level of lead content. The paint layer and white polyester sheet
are approximately 0.04 mm and 0.2 mm thick, respectively. The sixth sheet, NIST-2570, is coated with a leadfree, lacquer layer of the same thickness as the lead paint samples and is included as a blank. All sheets are
over-coated with a clear, thin, plastic laminate to protect the surface from abrasion.

NIST-2570 - NIST-2576
These items consist of one Mylar sheet per unit. Each sheet, 7.6 cm x 10.2 cm, is coated with a
single uniform paint layer for use with portable x-ray fluorescence analysers.
NIST-2570

Lead paint film (white/blank) - Lead

2 sheets

Certified value
Pb ........................<0.01 mg/cm

NIST-2571

Lead paint film (yellow) - Lead

2 sheets

A unit of NIST-2571 consists of a white polyester sheet, approximately 7.6 cm wide, 10.2 cm long, and 0.2 mm
thick, coated with a single, yellow-colored paint layer, approximately 0.04 mm thick. A blank, SRM 2570, is also
provided.
Certified value
Pb .......................... 3.58 mg/cm2

NIST-2572

Lead paint film (orange) - Lead

2 sheets

A unit of NIST-2572 consists of a white polyester sheet, approximately 7.6 cm wide, 10.2 cm long, and 0.2 mm
thick, coated with a single, orange-colored paint layer, approximately 0.04 mm thick. A blank, NIST-2570, is also
provided.
Certified value
Pb ........................ 1.527 mg/cm2

NIST-2573

Lead paint film (red) - Lead

2 sheets

A unit of NIST-2573 consists of a white polyester sheet, approximately 7.6 cm wide, 10.2 cm long, and 0.2 mm
thick, coated with a single, red-colored paint layer, approximately 0.04 mm thick. A blank, NIST-2570, is also
provided.
Certified value
Pb ........................ 1.040 mg/cm

NIST-2574

Lead paint film (gold) - Lead

2 sheets

A unit of NIST-2574 consists of a white polyester sheet, approximately 7.6 cm wide, 10.2 cm long, and 0.2 mm
thick, coated with a single, gold-colored paint layer, approximately 0.04 mm thick. A blank, NIST-2570, is also
provided.
Certified value
Pb ........................ 0.714 mg/cm2

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Paint and industrial sludges


Code

NIST-2575

Product

Unit

Lead paint film (green) - Lead

2 sheets

A unit of NIST-2575 consists of a white polyester sheet, approximately 7.6 cm wide, 10.2 cm long, and 0.2 mm
thick, coated with a single, green-colored paint layer, approximately 0.04 mm thick. A blank, NIST-2570, is also
provided.
Certified value
Pb ........................ 0.307 mg/cm

NIST-2576

Lead paint film (blue) - Lead

2 sheets

A unit of NIST-2576 consists of a white polyester sheet, approximately 7.6 cm wide, 10.2 cm long, and 0.2 mm
thick, coated with a single, blue-colored paint layer, approximately 0.04 mm thick. A blank, NIST-2570, is also
provided.
Certified value
Pb .......................... 5.59 mg/cm2

NIST-2589

Powdered paint - Lead

35 g

Certified value
Pb ................................... 9.99 %

NIST-2580

Powdered paint - Lead

30 g

Certified value
Pb ................................... 4.34 %

NIST-2581

Powdered paint - Lead

35 g

Certified value
Pb ................................. 0.449 %

NIST-2582

Powdered paint - Lead

20 g

Certified value
Pb ............................. 209 mg/kg

NIST-RM 8680

Paint on fiberboard - Lead

1 sheet

10.2 x 15.2 x 1.3 cm sheet


Indicative value for Pb

RTC-CRM017

Powdered paint - Lead

20 g

Certified value
Pb ..................................... 7.4 %

RTC-CRM013

Paint chips/waste - Trace elements

50 g

Certified values
Cd ............................... 38 mg/kg

Cr...............................618 mg/kg

Pb ............................. 643 mg/kg

Indicative values for a further 21 elements

RTC-CRM006

Paint sludge - Trace elements

50 g

Certified values
Al................................. 73 mg/kg
Ba ........................... 9970 mg/kg
Ca ............................. 111 mg/kg
Cd ............................... 32 mg/kg

Cr.................................11 mg/kg
Fe ................................64 mg/kg
K ..............................8710 mg/kg
Mg ...............................47 mg/kg

Na ............................... 91 mg/kg
Pb ............................. 753 mg/kg
Zn........................ 737431 mg/kg

Indicative values for B, Cu, Mn, Ni, Se, Sn, Sr, Ti, Tl

NIST-2586

Soil containing lead from paint - Trace elements

55 g

Soil collected from urban areas where the principal source of lead is believed to be from old house lead-based
paint.
Certified values
As............................... 8.7 mg/kg
Cd ............................ 2.71 mg/kg

Cr...............................301 mg/kg
Pb ..............................432 mg/kg

Indicative values for a wide range of additional elements

NIST-2587

Soil containing lead from paint - Trace elements

55 g

Soil collected from a suburban garden known to have been contaminated by lead-based house paint.
Certified values
As............................. 13.7 mg/kg
Cd ............................ 1.92 mg/kg

Cr.................................92 mg/kg
Pb ............................3242 mg/kg

Indicative values for a wide range of additional elements

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Edition 2003/2004

109

Asbestos
Code

Product

Unit

RTC-CRM009

Plating sludge no. 1 - Trace elements

100 g

Certified values
Ag ................................. 9 mg/kg
Cr ................................ 50 mg/kg

Cu........................121415 mg/kg
Ni ...............................343 mg/kg

Indicative values for a further 22 elements

RTC-CRM010

Plating sludge no. 2 - Trace elements

100 g

Certified values
Ag ............................... 56 mg/kg
Al............................... 692 mg/kg
Ba ............................. 175 mg/kg
Ca ............................. 563 mg/kg

Cr.................................79 mg/kg
Cu..........................63169 mg/kg
Fe ...........................2,699 mg/kg
Pb ........................119344 mg/kg

Mn ............................... 17 mg/kg
Ni .............................. 194 mg/kg
Zn.............................. 183 mg/kg

Indicative values for Hg, Mg, Mo, Na

RTC-CRM011

Plating sludge no. 3 - Trace elements

100 g

Certified values
Cr .......................... 59225 mg/kg
Cu ............................. 108 mg/kg

Ni ...........................41975 mg/kg
Pb ..............................269 mg/kg

Indicative values for a further 21 elements

RTC-CRM101

API separator sludge - PAHs

100 g

Certified values
Fluorene...................... 55 mg/kg
Methylnapthalene...... 185 mg/kg

Napthalene ..................97 mg/kg


Phenanthrene............173 mg/kg

Pyrene......................... 17 mg/kg

Asbestos
Code

NIST-1866a

Product

Unit

Common commercial asbestos

set (4)

Standard Reference Material (SRM) 1866a is a set of three common bulk mine-grade asbestos materials and
one synthetic glass fiber material. The three asbestos types are chrysotile, grunerite (Amosite), and riebeckite
(crocidolite). The optical properties of each of these materials have been characterized by polarized light
microscopy.

NIST-1876b

Chrysotile asbestos for TEM

set

This Standard Reference Material (SRM ) is intended primarily for use in evalutating the techniques used to
count and identify chrysotile asbestos fibers in filter samples by transmission electron microscopy (TEM). NIST1876b consists of ten 3 mm x 3 mm sections of 0.45 m mixed-cellulose-ester (MCE) filters containing chrysotile
fibers deposted by an aerosol generator.

NIST-RM 8411

Mixed asbestos research filter

1 cm2

Research Material (RM) 8411 consists of a section approximately one centimeter square of collapsed mixed
cellulose ester filter with a high concentration of chrysotile asbestos and a medium concentration of grunerite
(Amosite asbestos). This RM is intended for use in deviating and refining sample preparatation and analytical
procedures for the determination of the asbestos concentration in ambient air samples by phase contrast light
microscopy, scanning electron microscopy, and transmission electron microscopy.
Asbestos concentration in fibers per 0.01 mm2
Section

chrysotile

grunerite

1................................ 97,24........................... 55.19


2................................ 86.73........................... 42.05
3.............................. 173.46........................... 57.82
4.............................. 115.64........................... 44.68
5.............................. 159.26........................... 50.73
6.............................. 183.97........................... 52.56
7.............................. 157.69........................... 49.93
8.............................. 162.94........................... 18.40
9.............................. 141.92........................... 21.02
10.............................. 78.84........................... 44.68
11............................ 128.78........................... 18.40
12............................ 134.03........................... 36.79
13............................ 139.29........................... 44.68
14.............................. 99.87........................... 44.68
15............................ 177.40........................... 63.07
16............................ 141.92........................... 39.42
17............................ 171.62........................... 49.93

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Ash and particulate

Ash and particulate


Code

LGC6180 (RM)

Product

Unit

Pulverised fuel ash - Extractable and total metals

5 x 50 g

Collected from a disposal site near Camarthan Bay in South Wales. Pulverised fuel ash is a waste product of
coal-fired power stations.
The extractable metal content refers to metals soluble in Aqua Regia using methods based on ISO11466 (1995).
Extractable metal content
Assessed values
Al........................... 25700 mg/kg
As............................. 91.7 mg/kg
Ba ............................. 676 mg/kg
Ca ........................... 6415 mg/kg
Co ............................ 18.5 mg/kg

Cr..............................43.8 mg/kg
Cu.............................67.9 mg/kg
K ..............................6170 mg/kg
Mg ...........................3660 mg/kg
Mn .............................259 mg/kg

Na ........................... 1230 mg/kg


Ni ............................. 48.4 mg/kg
Pb ............................ 48.6 mg/kg
V ............................... 105 mg/kg
Zn.............................. 115 mg/kg

Indicative values for B, Be, Fe, Hg, Li, Sb, Se, Ti


Total metal content
Indicative values for Al, As, Ba, Be, Ca, Co, Cr, Cu, Fe, K, Li, Mg, Mn, Mo, Na, Ni, Pb, Sb, Se, Sn, Ti, V, Zn

BCR-038

Fly ash from pulverised coal - Trace elements

5g

Certified values
As............................. 48.0 mg/kg
Cd .............................. 4.6 mg/kg
Cl .............................. 323 mg/kg
Co ............................ 53.8 mg/kg
Cr .............................. 192 mg/kg

Cu..............................176 mg/kg
F ................................538 mg/kg
Fe ..........................33800 mg/kg
Hg.............................2.10 mg/kg
Mn .............................479 mg/kg

Na ........................... 3740 mg/kg


Pb ............................. 262 mg/kg
Zn.............................. 581 mg/kg

Indicative values for Ni, Th, V

BCR-128

Fly ash on artificial filters - Trace elements


(1 charged filter + 1 blank)

set

Intended for the verification of the calibration in XRF- and PIXE-analysis of (air borne) dust. A filter will normally
last for at least ten measurements in a vacuum or twenty-five in air. The filter consists of a methyl cellulose filter
mounted on polythene backed paper in a petrislide. Each foil contains a certified amount of BCR-038 (see above)

BCR-490

Fly ash - PCDDs and PCDFs


Compound

30 g

Certified value
g/kg

Uncertainty
g/kg

2,3,7,8-TCDD................................................... 0.169........................ 0.012


1,2,3,7,8-PeCDD ............................................... 0.67.......................... 0.04
1,2,3,4,7,8-HxCDD ............................................ 0.95.......................... 0.11
1,2,3,6,7,8-HxCDD .............................................. 4.8............................ 0.4
1,2,3,7,8,9-HxCDD ............................................ 2.84.......................... 0.17
2,3,7,8-TCDF ..................................................... 0.90.......................... 0.05
1,2,3,7,8-PeCDF................................................ 1.71.......................... 0.12
2,3,4,7,8-PeCDF.................................................. 1.8.......................... 0.11
1,2,3,4,7,8-HxCDF............................................. 2.37.......................... 0.12
1,2,3,6,7,8-HxCDF............................................. 2.64.......................... 0.14
1,2,3,7,8,9-HxCDF............................................. 0.34.......................... 0.05
2,3,4,6,7,8-HxCDF............................................. 2.47.......................... 0.17

BCR-615

Fly ash - PCDDs, PCDFs

50 g

Certified values
2,3,7,8-T4CDD (D48) .................................... 27 pg/g
1,2,3,7,8-P5CDD (D54) ................................. 92 pg/g
1,2,3,4,7,8-H6CDD (D66).............................. 74 pg/g
1,2,3,6,7,8-H6CDD (D67)............................ 103 pg/g
1,2,3,7,8,9-H6CDD (D70)............................ 108 pg/g
1,2,3,4,6,7,8-H7CDD (D73)................0.87 x 103 pg/g
O8CDD (D75).....................................1.75 x 103 pg/g
2,3,7,8-T4CDF (F83) ..................................... 86 pg/g
1,2,3,7,8-P5CDF (F94) ................................ 176 pg/g

NIST-1633b

2,3,4,7,8-P5CDF (F114) .............................. 125 pg/g


1,2,3,4,7,8-H6CDF (F118) ........................... 203 pg/g
1,2,3,6,7,8-H6CDF (F121) ........................... 204 pg/g
1,2,3,7,8,9-H6CDF (F124) .......................... 13.3 pg/g
2,3,4,6,7,8-H6CDF (F130) ........................... 130 pg/g
1,2,3,4,6,7,8-H7CDF (F131) .............. 0.75 x 103 pg/g
1,2,3,4,7,8,9-H7CDF (F134) .......................... 61 pg/g
O8CDF (F135) .................................. 0.29 x 103 pg/g

Coal fly ash - Trace and constituent elements

75 g

Certified values
Al..................................... 15.5 %
As........................... 136.2 mg/kg
Ba ............................. 709 mg/kg
Ca ................................... 1.51 %
Cd .......................... 0.784 mg/kg
Cr ........................... 198.2 mg/kg
Cu .......................... 112.8 mg/kg
Fe.................................... 7.78 %

Hg...........................0.141 mg/kg
K ..................................... 1.95 %
Mg ................................ 0.482 %
Mn ..........................131.8 mg/kg
Na................................. 0.201 %
Nd...........................120.6 mg/kg
Ni ............................102.6 mg/kg
Pb .............................68.2 mg/kg

S ................................. 0.2075 %
Se .......................... 10.26 mg/kg
Si................................... 23.02 %
Sr ............................ 1041 mg/kg
Th............................. 25.7 mg/kg
Ti..................................... 0.75 %
U .............................. 8.79 mg/kg
V ............................ 295.7 mg/kg

Indicative values for Br, Ce, Co, Cs, Eu, Gd, Hf, Ho, La, Lu, Mo, P, Rb, Sb, Sc, Sm, Ta, Tb, Tl, Tm, W, Yb, Zn

www.lgcpromochem.com

Edition 2003/2004

111

Ash and particulate


Code

NIST-2689

Product

Unit

Coal fly ash - Constituent elements

set (3)

Set of 3 x 10 g
Certified values
Al................................... 12.94 %
Ca ................................... 2.18 %
Fe(total)........................... 9.32 %

K ..................................... 2.20 %
Mg .................................. 0.61 %
Na................................... 0.25 %

P ..................................... 0.10 %
Si................................... 24.06 %
Ti..................................... 0.75 %

Indicative values for As, Ba, Be, Cd, Co, Cr, Cs, Eu, Hf, Hg, Mn, Ni, Pb, Sb, Sc, Se, Sr, Th, Zn

NIST-2690

Coal fly ash - Constituent elements

set (3)

Set of 3 x 10 g
Certified values
Al................................... 12.35 %
Ca ................................... 5.71 %
Fe(total)........................... 3.57 %
K ..................................... 1.04 %

Mg .................................. 1.53 %
Na................................... 0.24 %
P ..................................... 0.52 %
S ..................................... 0.15 %

Si................................... 25.85 %
Ti..................................... 0.52 %

Indicative values for As, Ba, Be, Cd, Co, Cr, Cs, Eu, Hf, Hg, Mn, Ni, Pb, Sb, Sc, Se, Sr, Th, Zn

NIST-2691

Coal fly ash - Constituent elements

set (3)

Set of 3 x 10 g
Certified values
Al..................................... 9.81 %
Ca ................................. 18.45 %
Fe(total)........................... 4.42 %
K ..................................... 0.34 %

Mg .................................. 3.12 %
Na................................... 1.09 %
P ..................................... 0.51 %
S ..................................... 0.83 %

Si................................... 16.83 %
Ti..................................... 0.90 %

Indicative values for As, Ba, Be, Cd, Co, Cr, Cs, Eu, Hf, Hg, Mn, Ni, Pb, Sb, Sc, Se, Sr, Th, Zn

IC-CTA-FFA-1

Fine fly ash - Constituent elements

50 g

Collected from the 3rd zone electrofilters at Kozienice power station in Poland.
Certified values for elements
Al............................. 14.87 wt. %
As............................. 53.6 mg/kg
Ba ............................. 835 mg/kg
Ce ............................. 120 mg/kg
Cr .............................. 156 mg/kg
Cu ............................. 158 mg/kg
Dy............................. 9.09 mg/kg
Er ............................. 4.52 mg/kg
Eu ............................ 2.39 mg/kg
F................................ 198 mg/kg
Fe.............................. 4.89 wt. %
Gd ............................ 10.0 mg/kg

Hf..............................6.09 mg/kg
La .............................60.7 mg/kg
Li................................128 mg/kg
Lu ...........................0.658 mg/kg
Mn ...........................1066 mg/kg
Na.............................2.19 mg/kg
Nd.............................56.8 mg/kg
Ni ..............................99.0 mg/kg
P ................................725 mg/kg
Pb ..............................369 mg/kg
Rb..............................185 mg/kg
Sb .............................17.6 mg/kg

Si.............................. 22.48 wt %
Sm ........................... 10.9 mg/kg
Sc............................. 24.2 mg/kg
Sr .............................. 250 mg/kg
Ta............................. 2.11 mg/kg
Tb............................. 1.38 mg/kg
Th............................. 29.4 mg/kg
Tm.......................... 0.705 mg/kg
W ............................. 10.5 mg/kg
Y............................... 45.0 mg/kg
Yb............................. 4.24 mg/kg
Zn.............................. 569 mg/kg

Informational values for Be, Ca, Cd, Ga, In, K, Mg, Mo, Se

NRMGBW08401

Coal fly ash - Metals

30 g

Certified values
As................................ 11.4 g/g
Be ............................... 10.7 g/g
Cd ............................... 0.16 g/g
Co ............................... 33.2 g/g

Cr....................................60 g/g
Cu...................................53 g/g
Fe ................................... 7.65 %
Mn ..............................1178 g/g

Pb ............................... 33.8 g/g


Se ............................... 1.13 g/g
V .................................... 95 g/g
Zn................................... 61 g/g

Indicative values for Ba, Hg

NRMGBW08403

Coal fly ash - PAHs

10 g

Certified values
Anthracene .................................................. 2.0 g/g
Benzo(a)pyrene ........................................... 1.3 g/g
Fluoranthene................................................ 7.4 g/g

Phenanthrene............................................... 7.1 g/g


Pyrene............................................................. 7 g/g

Indicative values for Benzo(a)anthracene, Benzo(b)fluoranthene, Benzo(ghi)perylene, Benzo(k)fluoranthene,


Chrysene + Triphenylene, Dibenzo(a,h)anthracene

NIST-1975

Diesel particulate extract - PAHs

4 x 1.2 mL

This Standard Reference Material (SRM ) is intended for use in evaluating analytical methods for the
determination of selected polycyclic aromatic hydrocarbons (PAHs) in diesel particulate extracts and similar
matrices. In addition to certified and reference values for selected polycyclic aromatic hydrocarbons, reference
values are provided for the concentrations of selected nitro-substituted PAHs, extract residue mass, and
mutagenic activity.
Certified Concentrations for Selected PAHs
Mass Fraction
mg/kg

Mass Fraction
mg/kg

Phenanthrene ......................................... 8.00 0.20


Fluoranthene............................................. 13.5 0.6
Benzo(a)anthracene ........................... 0.092 0.015
Chrysene................................................. 1.95 0.07

Triphenylen ............................................. 2.38 0.10


Benzo(b)fluoranthene.............................. 3.20 0.10
Benzo(k)fluoranthene.......................... 0.174 0.050
Benzo(e)pyrene................................... 0.268 0.023

Reference Concentrations for PAHs, Nitro-substituted PAHs, Extract Residue Mass, Mutagenicity (revertants/ g
of organic extract).

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Ash and particulate


Code

NIST-2975

Product

Unit

Diesel particulate matter - PAHs

1g

This Standard Reference Material (SRM) is intended for use in evaluating analytical methods for the
determination of selected polycyclic aromatic hydrocarbons (PAHs) in diesel particulate extracts and similar
matrices. In addition to certified and reference values for selected polycyclic aromatic hydrocarbons, reference
values or informational values are provided for total extractable mass, particle-size distribution, specific surface
area, and the concentration of 1-nitropyrene.
Certified Concentrations for Selected PAHs
Mass Fraction
mg/kg

Mass Fraction
mg/kg

Phenanthrene ........................................... 17.0 2.8


Fluoranthene............................................. 26.6 5.1
Pyrene..................................................... 0.90 0.24
Benzo(a)anthracene ........................... 0.317 0.066
Chrysene................................................. 4.56 0.16
Triphenylen ............................................. 5.22 0.20

Benzo(j)fluoranthene............................... 0.82 0.11


Benzo(k)fluoranthene.......................... 0.678 0.076
Benzo(e)pyrene....................................... 1.11 0.10
Benzo(a)pyrene................................. 0.0522 0.043
Benzo(ghi)perylene ............................. 0.498 0.044

Reference Concentrations for PAHs, Total Extractable Mass and Particle-Size Characteristics.

NIST-1648

Urban particulate matter- Constituent elements

2g

Certified values
Al..................................... 3.42 %
As.............................. 115 mg/kg
Cd ............................... 75 mg/kg
Cr .............................. 403 mg/kg
Cu ............................. 609 mg/kg

Fe(total) .......................... 3.91 %


K ..................................... 1.05 %
Na................................. 0.425 %
Ni .................................82 mg/kg
Pb ................................. 0.655 %

Se ............................... 27 mg/kg
U ................................ 5.5 mg/kg
V ............................... 140 mg/kg
Zn.................................. 0.476 %

Indicative values for Ba, Br, Ce, Cl, Co, Cs, Hf, I, In, La, Mn, Th, Sb

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113

Dust and Fumes

Dust and Fumes


Code

BCR-605

Product

Unit

Urban dust - Trimethyllead

15 g

Certified value
Trimethyllead .............. 7.9 g/kg

NIST-1649a

Urban dust - Organic contaminants

2.5 g

Standard Reference Material (SRM) 1649a is an atmospheric particulate matter collected in an urban area and
is intended for use in evaluating analytical methods for the determination of selected polycyclic aromatic
hydrocarbons (PAHs), polychlorinated biphenyls (PCB) congeners, and chlorinated pesticides in atmospheric
particulate material and similar matrices.
Certified concentrations for selected PAHs
Mass fraction ( mg/kg)

Mass fraction ( mg/kg)

Phenanthrene ......................................... 4.14 0.37


Anthracene ......................................... 0.432 0.082
Fluoranthene........................................... 6.45 0.18
Pyrene..................................................... 5.29 0.25
Benzo(a)anthracene ............................. 2.21 0.073
Chrysene............................................. 3.049 0.060
Triphenylene ....................................... 1.357 0.054
Benzo(b)fluoranthene ............................. 6.45 0.64
Benzo(k)fluoranthene ......................... 1.913 0.031
Benzo(a)fluoranthene ......................... 0.409 0.035
Benzo(e)pyrene ...................................... 3.09 0.19

Benzo(a)pyrene................................... 2.509 0.087


Perylene .............................................. 0.646 0.075
Anthanthrene....................................... 0.450 0.067
Benzo(ghi)perylene ................................. 4.01 0.91
Indeno(1,2,3-cd)pyrene ........................... 3.18 0.72
Dibenz(a,j)anthracene......................... 0.310 0.034
Dibenzo(a,c)anthracene...................... 0.200 0.025
Dibenzo(a,h)anthracene...................... 0.288 0.023
Pentaphene......................................... 0.151 0.035
Benzo(b)chrysene ............................... 0.315 0.013
Picene ................................................. 0.426 0.022

Certified concentrations for selected PCB congeners


Mass fraction ( g/kg)
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB

PCB
PCB
PCB
PCB
PCB
PCB
PCB
PCB

PCB
PCB
PCB
PCB

8................2,4-Dichlorobiphenyl................................................. 12.28 0.29


18..............2,2',5-Trichlorobiphenyl ............................................. 20.44 0.84
28..............2,4,4'-Trichlorobiphenyl ................................................. 18.5 1.2
31..............2,4,5-Trichlorobiphenyl ................................................. 17.3 1.4
44..............2,2',3,5'-Tetrachlorobiphenyl ......................................... 15.4 1.6
49..............2,2,4,5-Tetrachlorobiphenyl ......................................... 12.2 1.5
52..............2,2',5,5'-Tetrachlorobiphenyl ..................................... 24.65 0.97
66..............2,3',4,4'-Tetrachlorobiphenyl +
95..............2,2,3,5,6-Pentachlorobiphenyl ......................................... 65 12
87..............2,2,3,4,5`-Pentachlorobiphenyl................................. 10.65 0.62
95..............2,2,3,5,6-Pentachlorobiphenyl ..................................... 51.6 4.2
99..............2,2,4,4,5-Pentachlorobiphenyl ................................... 9.58 0.69
101............2,2',4,5,5'-Pentachlorobiphenyl ..................................... 52.9 1.0
105............2,3,3',4,4'-Pentachlorobiphenyl ................................... 8.63 0.80
110............2,3,3,4,6-Pentachlororbiphyl........................................ 26.6 1.6
118............2,3',4,4',5-Pentachlorobiphenyl ..................................... 25.7 1.5
128............2,2',3,3',4,4'-Hexachlorobiphenyl................................. 6.35 0.69
138............2,2',3,4,4',5'-Hexachlorobiphenyl +
163............2,3,3',4',5,6-Hexachlorobiphenyl +
164............2,3,3',4',5',6-Hexachlorobiphenyl.................................. 69.7 .7.5
149............2,2',3,4',5',6-Hexachlorobiphenyl................................... 75.7 1.3
151............2,2',3,5,5',6-Hexachlorobiphenyl ................................... 34.3 3.9
153............2,2',4,4',5,5'-Hexachlorobiphenyl................................... 82.5 8.0
156............2,3,3',4,4',5-Hexachlorobiphenyl ............................... 16.25 0.77
170............2,2',3,3',4,4',5-Heptachlorobiphenyl +
190............(2,3,3,4,4,5,5-Heptachlorobiphenyl............................. 30.8 2.2
180............2,2',3,4,4',5,5'-Heptachlorobiphenyl .............................. 78.7 8.2
183............2,2',3,4,4',5',6-Heptachlorobiphenyl .......................... 20.34 0.95
187............2,2',3,4',5,5',6-Heptachlorobiphenyl +
159............2,3,3',4,5,5'-Hexachlorobiphenyl +
182............2,2,3,,4,4,5,6-Heptachlorobiphenyl ............................ 40.1 2.5
194............2,2,3,3,4,4,5,5-Octachlorobiphenyl ............................ 28.9 3.6
195............2,2,3,3,4,4,5,6-Octachlorobiphenyl ........................... 9.63 0.37
206............2,2,3,3,4,4,5,5,6-Nonachlorobiphenyl ........................ 20.6 4.6
209............Decachlorobiphenyl..................................................... 8.04 0.77

Certified concentrations for selected chlorinated pesticides


Chlorinated pesticides

Mass fraction in g/kg

Hexachlorobenzene .................................. 16.3 1.8


trans-Chlordane (gamma-Chlordane)....... 40.3 2.8
cis-Chlordane (alpha-Chlordane).......... 34.88 0.42
trans-Nonachlor ........................................ 27.6 1.6

Chlorinated pesticides

Mass fraction in g/kg

2,4-DDE ................................................. 5.79 0.85


4,4-DDE ................................................... 40.4 1.7
4,4-DDD ............................................... 34.01 0.48
4,4-DDT...................................................... 212 15

Reference values for PAHs, chlorinated pesticides, mutagenic anions activity, particle-size characteristics, total
organic carbon and percent extractable mass, carbon composition.

BCR-723

Road dust - Palladium, platinum and rhodium

25 g

Certified values
Pd ............................... 6.0 g/kg

114

Pt ...............................81.3 g/kg

Edition 2003/2004

Rh ............................. 12.8 g/kg

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Dust and Fumes


Code

Product

Unit

BCR-553-4

Formaldehyde-2,4-dinitrophenylhydrazone on filter

set

Set of 2 x BCR 553 & 1 x BCR 554 (blank)


BCR-553 (spiked filter)
Certified value (per filter)
Formaldehyde-2,4-dinitrophenylhydrazone....................... 4.96 g
BCR-554 (blank filter)
Certified value (per filter)
Formaldehyde-2,4-dinitrophenylhydrazone....................... < 0.1g

Council directive 80/1107/EEC and national legislation prescribes that the exposure of each individual
worker to certain potentially harmful vapours has to be monitored periodically. This requires personal
monitoring where a tube, containing a suitable sorbing agent, is attached to the workers clothes.
After a set sampling period any harmful vapours absorbed onto the material in the tube are desorbed,
either by heating or solvent extraction, and determined using gas chromatography.
BCR-112

Tenax charged tube - Aromatic hydrocarbons

tube

Certified values (per tube)


Benzene....................... 1.053 g

BCR-562

Toluene ........................1.125 g

m-Xylene...................... 1.043 g

Charcoal charged tube - Aromatic hydrocarbons

set

Set of 20 tubes (6 charged, 14 blanks)


Certified values (per tube)
Benzene......................... 15.0 g
Toluene........................ 147.3 g

BCR-555

m-Xylene ........................96.4 g
o-Xylene .........................93.0 g

Tenax charged tube - Chlorinated hydrocarbons

tube

Stainless steel tube of 9.0 cm length and 0.25 inches outer diameter containing a single section of 250 mg
TENAX GR, charged with 4 chlorinated hydrocarbons and toluene at the levels shown above.
Certified values
Dichloromethane............. 320 ng
1,1,1-Trichloroethane...... 370 ng

RTC-CRM014

Trichloroethylene.............390 ng
Perchloroethylene ...........327 ng

Toluene............................. 57 ng

Baghouse dust - Trace metals

50 g

Certified values
Cd ............................. 510 mg/kg

Cr............................2,228 mg/kg

Pb .......................... 1,914 mg/kg

Indicative values for a further 24 elements

NIST-1878a

Alpha quartz

5g

One form of respirable silica


Certified value
Crystalline quartz ................................... 100.00 %

NIST-1879a

Cristabalite

5g

One form of respirable silica


Certified value
Crystalline cristabolite.................................... 95.6 %

NIST-2583

Indoor dust - Trace elements

8g

Certified values
As............................... 7.0 mg/kg
Cd .............................. 7.3 mg/kg

NIST-2584

Cr.................................80 mg/kg
Hg.............................1.56 mg/kg

Pb ............................ 85.9 mg/kg

Indoor dust - Trace elements

8g

Collected from vacuum cleaner bags used in the cleaning of interior dwelling places
Certified values
As............................. 17.4 mg/kg
Cd ............................ 10.0 mg/kg

Cr............................135.0 mg/kg
Hg.............................5.20 mg/kg

Pb ........................... 9761 mg/kg

Indicative values for a wide range of additional elements

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115

Aldehydes/Ketones-DNPH standards

Aldehydes/Ketones-DNPH standards
Code

Product

CERERA-012

Acetaldehyde-DNPH

10 mg

Acetaldehyde-2,4-dinitrophenylhydrazone

10 mg

BCR-547

Unit

Certified purity................. 98.3 %

CERERA-024S

Acetaldehyde-DNPH 500 g/mL* in Acetonitrile

1.2 mL

CERERA-011

Acetone-DNPH

10 mg

Acetone-2,4-dinitrophenylhydrazone

10 mg

BCR-549

Certified purity..............> 99.6 %

CERERA-025S

Acetone-DNPH 500 g/mL* in Acetonitrile

1.2 mL

CERERA-021

Acetophenone-DNPH

10 mg

CERERA-026S

Acetophenone-DNPH 100 g/mL* in Acetonitrile

1.2 mL

CERERA-014

Acrolein-DNPH

10 mg

Acrolein-2,4-dinitrophenylhydrazone

10 mg

BCR-548

Certified purity..............> 97.9 %

CERERA-027S

Acrolein-DNPH 500 g/mL* in Acetonitrile

1.2 mL

CERERB-017

Benzaldehyde-DNPH

10 mg

CERERB-026S

Benzaldehyde-DNPH 100 g/mL* in Acetonitrile

1.2 mL

CERERB-023

1,4-Benzoquinone-DNPH (mono)

10 mg

CERERB-016

2-Butanone (MEK)-DNPH

10 mg

CERERB-028S

2-Butanone (MEK)-DNPH 100 g/mL* in Methanol

1.2 mL

CERERB-018

n-Butyraldehyde-DNPH

10 mg

CERERB-029S

n-Butyraldehyde-DNPH 500 g/mL* in Acetonitrile

1.2 mL

CERERC-006

Crotonaldehyde-DNPH

10 mg

CERERC-011S

Crotonaldehyde-DNPH 100 g/mL* in Acetontrile

1.2 mL

CERERC-016

Cyclohexanone-DNPH

10 mg

CERERC-015S

Cyclohexanone-DNPH 500 g/mL* in Acetonitrile

1.2 mL

CERERD-030

2,5-Dimethylbenzaldehyde-DNPH

10 mg

CERERD-035S

2,5-Dimethylbenzaldehyde-DNPH 500 g/mL* in Acetonitrile

1.2 mL

CERERF-003

Formaldehyde-DNPH

10 mg

Formaldehyde-2,4-dinitrophenylhydrazone

10 mg

BCR-546

Certified purity................ > 0.993

CERERF-004S

Formaldehyde-DNPH 100 g/mL* in Acetonitrile

1.2 mL

CERERF-005S

Formaldehyde-DNPH 500 g/mL* in Acetonitrile

1.2 mL

CERERG-002

Glutaraldehyde-DNPH

10 mg

Glutaraldehyde-2,4-dinitrophenylhydrazone

10 mg

BCR-550

Certified purity..............> 98.1 %

CERERH-011

Heptaldehyde-DNPH

10 mg

CERERH-012S

Heptaldehyde-DNPH 500 g/mL* in Acetonitrile

1.2 mL

CERERH-003

Hexaldehyde-DNPH

10 mg

CERERH-005S

Hexaldehyde-DNPH 500 g/mL* in Acetonitrile

1.2 mL

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Aldehydes/Ketones-DNPH standards
Code

Product

Unit

CERERI-003

Isobutyraldehyde-DNPH

10 mg

CERERI-005

Isophorone-DNPH

10 mg

CERERI-004

Isovaleraldehyde-DNPH

10 mg

CERERI-009S

Isovaleraldehyde-DNPH 500 g/mL* in Acetonitrile

1.2 mL

CERERM-002

Methacrolein-DNPH

10 mg

CERERM-022S

Methacrolein-DNPH 100 g/mL* in Acetonitrile

1.2 mL

CERERM-020

Methyl isobutyl ketone-DNPH

10 mg

CERERM-023S

Methyl isobutyl ketone-DNPH 500 g/mL* in Acetonitrile

1.2 mL

CERERM-024

Methyl isopropyl ketone-DNPH

10 mg

CERERP-005

Propionaldehyde-DNPH

10 mg

CERERP-030S

Propionaldehyde-DNPH 500 g/mL* in Acetonitrile

1.2 mL

CERERT-007

m-Tolualdehyde-DNPH

10 mg

CERERT-027S

m-Tolualdehyde-DNPH 100 g/mL* in Acetonitrile

1.2 mL

CERERT-012

o-Tolualdehyde-DNPH

10 mg

CERERT-011

p-Tolualdehyde-DNPH

10 mg

CERERV-001

Valeraldehyde-DNPH

10 mg

CERERV-002S

Valeraldehyde-DNPH 500 g/mL in Acetonitrile

1.2 mL

*as aldehyde or ketone


BCR-551-2

2,4-Dinitrophenylhydrazones in Acetonitrile

set

Each set consists of 4 samples of BCR-551 and 1 sample of BCR-552


BCR 551

2,4-Dinitrophenylhydrazones in Acetonitrile

Compound

Certified value
(g/mL)

Uncertainty
(g/mL)

Formaldehyde-DNPH ........................................ 2.94.......................... 0.05


Acetaldehyde-DNPH.......................................... 4.89.......................... 0.07
Acrolein-DNPH ................................................ 0.483........................ 0.011
Acetone-DNPH .................................................. 4.69.......................... 0.07
BCR-552

2,4-Dinitrophenylhydrazones in a solution of 2,4-Dinitrophenylhydrazine (blank)

Compound

Certified value
(g/mL)

Formaldehyde-DNPH ...................................... <0.08


Acetaldehyde-DNPH........................................ <0.05
Acrolein-DNPH ................................................ <0.04
Acetone-DNPH ................................................ <0.05

CERERA-020

Aldehyde/Ketone-DNPH Standard Solution

1.2 mL

(15 compounds)
15 g/mL (as Aldehyde/Ketone) of each analyte in Acetonitrile
Acetaldehyde-DNPH
Acetone-DNPH
Acrolein-DNPH
Benzaldehyde-DNPH
n-Butyraldehyde-DNPH
Crotonaldehyde-DNPH
2,5-Dimethylbenzaldehyde-DNPH
Formaldehyde-DNPH

CERERA-028

Hexaldehyde-DNPH
Isovaleraldehyde-DNPH
Propionaldehyde-DNPH
o- Tolualdehyde-DNPH
p-Tolualdehyde-DNPH
m-Tolualdehyde-DNPH
Valeraldehyde-DNPH

Aldehyde/Ketone-DNPH Standard Solution

1.2 mL

(13 compounds)
15 g/mL (as Aldehyde/Ketone) of each analyte in Acetonitrile
Acetaldehyde-DNPH
Acetone-DNPH
Acrolein-DNPH
Benzaldehyde-DNPH
2-Butanone-DNPH
n-Butyraldehyde-DNPH
Crotonaldehyde-DNPH

www.lgcpromochem.com

Formaldehyde-DNPH
Hexaldehyde-DNPH
Methacrolein-DNPH
Propionaldehyde-DNPH
m-Tolualdehyde-DNPH
Valeraldehyde-DNPH

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117

Aldehydes/Ketones-DNPH standards
Code

CERERA-013K

Product

Unit

Aldehyde/Ketone-DNPH Working Standard Solution

5 x 1.2 mL

(13 compounds)
3 g/mL (as Aldehyde/Ketone) of each analyte in Acetonitrile
Acetaldehyde-DNPH
Acetone-DNPH
Acrolein-DNPH
Benzaldehyde-DNPH
2-Butanone-DNPH
n-Butyraldehyde-DNPH
Crotonaldehyde-DNPH

CERERA-037

Formaldehyde-DNPH
Hexaldehyde-DNPH
Methacrolein-DNPH
Propionaldehyde-DNPH
m-Tolualdehyde-DNPH
Valeraldehyde-DNPH

Aldehyde/Ketone-DNPH Check
Standard Solution

5 x 1.2 mL

(13 compounds)
1 g/mL (as Aldehyde/Ketone) of each analyte in Acetonitrile
Acetaldehyde-DNPH
Acetone-DNPH
Acrolein-DNPH
Benzaldehyde-DNPH
2-Butanone-DNPH
n-Butyraldehyde-DNPH
Crotonaldehyde-DNPH

CERERA-030

Formaldehyde-DNPH
Hexaldehyde-DNPH
Methacrolein-DNPH
Propionaldehyde-DNPH
m-Tolualdehyde-DNPH
Valeraldehyde-DNPH

Aldehyde/Ketone-DNPH Calibration KIT-15

kit

Each kit contains one 3,0 mL ampoule of C1, C2, C3, C4 and C5.
Solvent: Acetonitrile
Concentrations (g/mL) as Aldehyde or Ketone
Analytes

C1

C2

C3

C4

C5

Acetaldehyde-DNPH................................. 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50


Acetone-DNPH ......................................... 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
Acrolein-DNPH ......................................... 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
Benzaldehyde-DNPH................................ 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
n-Butyraldehyde-DNPH ............................ 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
Crotonaldehyde-DNPH ............................. 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
2,5-Dimethylbenzaldehyde-DNPH ............ 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
Formaldehyde-DNPH ............................... 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
Hexaldehyde-DNPH.................................. 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
Isovaleraldehyde-DNPH ........................... 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
Propionaldehyde-DNPH ........................... 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
m-Tolualdehyde-DNPH............................. 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
o-Tolualdehyde-DNPH.............................. 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
p-Tolualdehyde-DNPH.............................. 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
Valeraldehyde-DNPH ............................... 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50

CERERA-029

Aldehyde/Ketone-DNPH Calibration KIT-4

kit

Each kit contains one 3.0 mL ampoule of C1, C2, C3, C4 and C5
Solvent: Acetonitrile
Concentrations (g/mL) as Aldehyde or Ketone
Analytes

C1

C2

C3

C4

C5

Acetaldehyde-DNPH................................. 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50


Acetone-DNPH ......................................... 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
Acrolein-DNPH ......................................... 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50
Formaldehyde-DNPH ............................... 0.01 .............. 0.02.............. 0.05.............. 0.10...............0.50

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Elemental analysis

Elemental analysis
Code

Product

Unit

LGC4000 - LGC4009
Produced in collaboration with the Micro and Chemical Methods Group of the Analytical Division of the
Royal Society of Chemistry.
LGC4000

Dibutyl sulphide

50 mL

Certified value
S ..................................... 21. 5%

LGC4001

Dibenzothiophene

500 mg

Certified value
S .................................... 17.6 %

LGC4002

Acetanilide

1g

Certified values
C ................................... 71.14 %

NIST-141D

H..................................... 6.73 %

N ................................... 10.33 %

Acetanilide - Carbon, hydrogen, nitrogen and oxygen

unit

Certified values
C ................................. 71.089 %
H ................................... 6.711 %

LGC4003

N................................. 10.363 %
O................................. 11.837 %

Benzoic acid - Oxygen

1g

Certified value
O ................................... 26.24 %

LGC4004

4-Chlorobenzoic acid - Chlorine

1g

Certified value
Cl .................................. 22.72 %

LGC4005

Cyclohexanone-2,4-dinitrophenylhydrazone - Nitrogen

1g

Certified value
N ................................... 20.11 %

LGC4006

Triphenylphosphine - Phosphorous

1g

Certified value
P ................................... 11.73 %

LGC4007

Arachidic acid - Carbon and hydrogen

1g

Certified values
C ................................... 76.81 %

LGC4008

H................................... 12.96 %

4-Bromobenzoic acid - Bromine

1g

Certified value
Br .................................. 39.74 %

LGC4009

2-Iodobenzoic acid - Iodine

1g

Certified value
I ..................................... 51.14 %

NIST-142

Anisic acid - Methoxyl

2g

Certified value
CH3O- ............................ 20.40 %

NIST-143D

Cystine - Carbon, hydrogen, nitrogen, oxygen and sulphur

2g

Certified values
C ................................... 29.99 %
H ..................................... 5.03 %

NIST-148

N................................... 11.66 %
O................................... 26.63 %

S ................................... 26.69 %

Nicotinic acid - Carbon, hydrogen and nitrogen

2g

Certified values
C ................................... 58.54 %

NIST-2141

H..................................... 4.09 %

Urea - Nitrogen

N ................................... 11.38 %

2g

Certified value
N ................................. 46.635 %

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119

Elemental analysis
Code

NIST-2143

Product

Unit

p-Fluorobenzoic acid - Fluorine

2g

Certified value
F.................................... 13.54 %

NIST-2144

m-Chlorobenzoic acid - Chlorine

2g

Certified value
Cl .................................. 22.62 %

NIST-1216

Carbon modified silicon - Carbon

Set

Certified values
Level I
C ....................................... 0.7 %
Level II
C ..................................... 9.06 %
Level III
C ................................... 17.04 %

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Stochiometry

Stochiometry
Code

NIST-17e

Product

Unit

Sucrose - Optical rotation

60 g

Intended for use as a saccharimetry standard in calibrating polarimetric systems.


Certified purity............. 99.950 %
Reference values are given for optical rotation at 3 wavelengths

NIST-40H

Sodium oxalate - Reductometric value

60 g

Certified purity............. 99.972 %

NIST-83D

Arsenic trioxide - Reductometric value

60 g

Certified purity........... 99.9926 %

NIST-84K

Potassium hydrogen phthalate - Acidmetric value

60 g

Certified purity........... 99.9911 %

NIST-350A

Benzoic acid - Acidmetric value

30 g

Certified purity........... 99.9958 %

NIST-723D

Benzoic acid - Acidmetric value

50 g

Certified purity........... 99.9958 %

NIST-351

Sodium carbonate - Oxidimetric value

50 g

Certified purity........... 99.9796 %

NIST-951

Boric acid assay - Acidmetric and boron isotopic value


Purity........................... 100.00 %

100 g

Certified value

Abundance ratio
10B/11B .......................... 0.2473

NIST-987

10B ............................. 19.827 %

11B ............................. 80.173 %

Strontium carbonate - Assay and isotopic values

1g

Certified values
Purity............................. 99.98 %
88
Sr............................ 82.5845 %

NIST-999A

87

Sr ............................. 7.0015 %
Sr ............................. 9.8566 %

86

84

Sr.............................. 0.5574 %

Potassium chloride - Assay values

60 g

Certified purity
KCl ............................ 99.9817 %

K ............................... 52.4354 %

Cl .............................. 47.5463 %

NRMGBW06101a Sodium carbonate

50 g

Certified purity............. 99.995 %

NRMGBW06102

EDTA disodium salt

25 g

Certified purity............. 99.979 %

NRMGBW06103a Sodium chloride

50 g

Certified purity............. 99.995 %

NRMGBW06104

Benzene

5 mL

Certified purity............... 99.95 %

NRMGBW06105b Potassium dichromate

50 g

Certified purity............. 99.984 %

NRMGBW06106a Potassium hydrogen phthalate

50 g

Certified purity............. 99.984 %

NRMGBW06107a Sodium oxalate

50 g

Certified purity............... 99.99 %

NRMGBW06108

Zinc oxide - Complexometric standard


Complexometric value .......................12.280 mmol/g

NRMGBW06109

Potassium chloride
Cl ................................ 100.00 %

NRMGBW06110

50 g
Certified value

50 g
K ................................... 99.97 %

Potassium iodate - Oxidimetry

Certified purities

50 g

Certified purity............... 99.91 %

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121

Organo-metallic compounds

Organo-metallic compounds
Code

NIST-1051B

Product

Barium cyclohexanebutyrate - Barium


Ba ................................... 28.7 %

NIST-1052B

Unit

5g

Certified value

Bis(1-phenyl-1,3-butanediono) oxovanadium (IV) - Vanadium

5g

Certified value
V ................................... 13.01 %

NIST-1053A

Cadmium cyclohexanebutyrate - Cadmium


Cd ................................... 24.8 %

NIST-1057B

5g

Certified value

5g

Certified value

5g

Certified value

Tris (1-phenyl-1,3-butanediono) iron (III) - Iron


Fe.................................. 10.45 %

NIST-1080A

5g

Certified value

Tris (1-phenyl-1,3-butanediono) chromium (III) - Chromium


Cr ...................................... 9.6 %

NIST-1079B

5g

Certified value

Silver 2-ethylhexanoate - Silver


Ag ................................. 42.60 %

NIST-1078B

5g

Certified value

Aluminium 2-ethylhexanoate - Aluminium


Al..................................... 8.07 %

NIST-1077A

Certified value

Zinc cyclohexanebutyrate - Zinc


Zn.................................. 16.66 %

NIST-1075A

5g

Triphenyl phosphate - Phosphorous


P ..................................... 9.48 %

NIST-1073B

5g

Certified value

Strontium cyclohexanebutyrate - Strontium


Sr .................................... 20.7 %

NIST-1071B

5g

Certified value

Sodium cyclohexanebutyrate - Sodium


Na ................................... 12.0 %

NIST-1070A

5g

Certified value

Octaphenylcyclotetrasiloxane - Silicon
Si................................... 14.14 %

NIST-1069B

5g

Certified value

Nickel cyclohexanebutyrate - Nickel


Ni .................................. 13.89 %

NIST-1066

Certified value

Lithium cyclohexanebutyrate - Lithium


Li ....................................... 4.1 %

NIST-1065B

5g

Lead cyclohexanebutyrate - Lead


Pb ................................... 37.5 %

NIST-1060A

5g

Certified value

Dibutyltin bis (2-ethylhexanoate) - Tin


Sn ................................. 22.95 %

NIST-1059C

Certified value

5g

Certified value

Bis (1-phenyl-1,3-butanediono) copper (II) - Copper


Cu ................................. 16.37 %

5g

Certified value

Speciation
Code

Product

Unit

BCR-544

Lyophilised chromium solution - Chromium

2 mg

Certified values
Cr(III)........................... 26.8 g/L

BCR-626

Cr(VI)...........................22.8 g/L

Total Cr ....................... 49.4 g/L

Arsenobetaine standard solution - Arsenobetaine

10 mL

Certified value
Arsenobetaine [as (CH3) As+CH2COO ] ................................................. 1031 mg/kg

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Isotopes

Isotopes
Code

NIST-951

Product

Unit

Boric acid assay - Acidmetric and boron isotopic value

100 g

Certified values
Purity........................... 100.00 %
Abundance ratio
10B/11B .......................... 0.2473

NIST-952

10B ............................. 19.827 %

11B ............................. 80.173 %

Boric acid (enriched 10B)

250 mg

Certified values
Purity............................. 99.97 %
Abundance ratio
10

B/11B............................... 18.80

NIST-975a

10

B .............................. 94.949 %

11

B................................. 5.051 %

Sodium chloride - Isotopic composition

250 mg

Certified values
Absolute abundance ratio
35

Cl/37Cl............. 3.1279 0.0047

Isotopic composition
35

Cl ......... 75.774 0.028 atom%

37

Cl......... 24.226 0.028 atom%

Atomic weight ........................... 35.45265 0.00055

NIST-977

Sodium bromide - Isotopic composition

250 mg

Certified values
Abundance ratio
79

Br/81Br ........................ 1.02784

NIST-978A

79

Br ............................. 50.686 %

81

Br.............................. 49.314 %

Silver nitrate - Assay/isotopic composition

250 mg

Certified values
Purity............................. 99.99 %
Abundance ratio
107

109

Ag/

NIST-979

Ag .................... 1.07638

107

Ag ......................... 51.8392 %

109

Ag.......................... 48.1608 %

Chromium nitrate - Isotopic composition

250 mg

Certified values
50

53

52

54

Cr ............................... 4.345 %
Cr ............................. 83.789 %

NIST-981

Cr ............................... 9.501 %
Cr ............................... 2.365 %

Lead metal, natural - Isotopic composition

1g

Certified values
204

207

206

208

Pb............................ 1.4255 %
Pb.......................... 24.1442 %

NIST-986

Pb ......................... 22.0833 %
Pb ......................... 52.3470 %

Nickel - Isotopic composition

500 mg

Certified values
58

61

60

62

Ni........................ 68.076886 %
Ni........................ 26.223146 %

NIST-987

Ni ......................... 1.139894 %
Ni ......................... 3.634528 %

64

Ni.......................... 0.925546 %

Strontium carbonate - Assay and isotopic values

1g

Certified values
Purity............................. 99.98 %
88
Sr............................ 82.5845 %

NIST-991

87

Sr ............................. 7.0015 %
Sr ............................. 9.8566 %

86

84

Sr.............................. 0.5574 %

Lead-206 spike - Assay/isotopic composition

15 g

Certified values
Pb ..................... 0.32261 mol/g
204
Pb................................ <3ppm

NIST-994

206

Pb ........................... 99.979 %
Pb ............................. 0.008 %

207

Gallium metal - Isotopic composition

208

Pb.............................. 0.013 %

250 mg

Certified values
Abundance ratio
69

71

Ga/ Ga ...................... 1.50676

69

Ga .......................... 60.1079 %

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71

Ga .......................... 39.8921 %

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Isotopes
Code

NIST-997

Product

Unit

Thallium metal - Isotopic composition

250 mg

Certified values
Abundance ratio
205

Tl/203Tl ....................... 2.38714

203

Tl ........................... 29.5235 %

IAEA-305

205

Tl .......................... 70.4765 %

Ammonium sulfate - Nitrogen-15

unit

Assessed values
Solution A
15

N..................... 39.8 activity/mL

Solution B
15

N................... 375.3 activity/mL

IAEA-311

Ammonium sulfate - Nitrogen-15

100 mg

Assessed value
15

N..................... 2.05 activity/mL

IAEA-303

Sodium bicarbonate - Carbon-13

2 x 3 mL

Assessed values
Solution A
13C .................... 93.3 activity/ml
Solution B
13C ..................... 466 activity/ml

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Standards for spectroscopy

Standards for spectroscopy


Introduction
This comprehensive range of elemental standards has been compiled by selecting complementary
materials from two sources, NIST and ULTRA Scientific Inc. Their combined range covers virtually all
calibration needs for elemental emission spectroscopy instruments.
It is important to understand that there are fundamental differences between standards prepared for
atomic absorption spectroscopy (AAS) and ICP and ICP-MS techniques. This is because of the
intrinsic difference in the way measurement is carried out. In AAS the sample is energized by
combustion, a specific light source is passed through the flame and elements present in the sample
absorb at a specific wavelength. With ICP and ICP-MS the sample is energized to the point where the
elements in the sample emit energy at a specific wavelength. Because measurement is dependent on
specific emission there is a considerable potential for impurities to interfere with the analyte of
interest. The distinction between AAS and ICP standards is the purity of starting materials. Typically
material of 99.9 or 99.99% purity is suitable for AAS, but for critical ICP work the standards need to be
produced from a starting material that is 99.999% or better. Remember that ICP/ICP-MS standards
are perfectly suitable for AAS, but not the reverse.

NIST Standard Reference Materials (SRMs)

NIST Standard Reference Materials are certified by procedures that conform with the requirements
of ISO Guides 30 to 35, and are therefore accepted as primary standards for use in atomic absorption
spectroscopy (AAS), optical emission spectroscopy (OES), inductively coupled plasma (ICP), mass
[plasma] spectroscopy (MS), ion chromatography or any other analytical technique that requires
aqueous solutions of elements for calibration. These SRM Standards are the most precise and
accurate solutions available and are best used as single element solutions.
TM

ULTRA Scientific

certified ICP/AA standards

The ULTRA Scientific range of single and multi-element solutions in this catalogue are of the highest
quality. ULTRA Scientific are one of the leading manufacturers in the US and have an ISO 9001
registered quality system verified by their ISO 17025 accredited laboratory. The ICP standards are
prepared from starting materials having a purity of 99.999 % (where possible), high purity acids and

ASTM Type I water (18 megohm). Standards are traceable to NIST Standard Reference Materials

(SRM ) whenever possible. Solution density data are available for single element standards.
Code

Product

Unit

Aluminum - Al
NIST-3101A

Al in 10% HNO3, 10 mg/g

50 mL

U-ICP-013

Al(NO3)3 x 9H2O in dilute HNO3, 1000 g/mL

100 mL

U-ICP-013-5

Al(NO3)3 x 9H2O in dilute HNO3, 1000 g/mL

500 mL

Antimony - Sb
NIST-3102A

Sb in 10% HNO3 + 2% HF, 10 mg/g

50 mL

U-ICP-051

Sb-metal in dilute HNO3/C4H6O6, 1000 g/mL

100 mL

U-ICP-051-5

Sb-metal in dilute HNO3/C4H6O6, 1000 g/mL

500 mL

Arsenic - As
NIST-3103A

As in 15% HNO3, 10 mg/g

50 mL

U-ICP-033

As2O3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-033-5

As2O3 in dilute HNO3, 1000 g/mL

500 mL

Barium - Ba
NIST-3104A

Ba in 1% HNO3, 10 mg/g

U-ICP-056

Ba(NO3)2 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-056-5

Ba(NO3)2 in dilute HNO3, 1000 g/mL

500 mL

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Code

Product

Unit

Beryllium Be
NIST-3105A

Be in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-004

Be acetate in dilute HNO3, 1000 g/mL

100 mL

U-ICP-004-5

Be acetate in dilute HNO3, 1000 g/mL

500 mL

U-ICP-083

Bi-metal in dilute HNO3, 1000 g/mL

100 mL

U-ICP-083-5

Bi-metal in dilute HNO3, 1000 g/mL

500 mL

Bismuth Bi

Boron B
NIST-3107

B in water, 5 mg/g

50 mL

U-ICP-005

H3BO3 in H2O tr. NH4OH, 1000 g/mL

100 mL

U-ICP-005-5

H3BO3 in H2O tr. NH4OH, 1000 g/mL

500 mL

Cadmium Cd
NIST-3108

Cd in 10% HNO3, 10 mg/g

50 mL

U-ICP-048

Cd(NO3)2 x H2O in dilute HNO3, 1000 g/mL

100 mL

U-ICP-048-5

Cd(NO3)2 x H2O in dilute HNO3, 1000 g/mL

500 mL

Calcium Ca
NIST-3109

Ca in 10% HNO3, 10 mg/g

50 mL

U-ICP-020

CaCO3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-020-5

CaCO3 in dilute HNO3, 1000 g/mL

500 mL

Cerium Ce
NIST-3110A

Ce in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-058

Ce(NO3)3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-058

Ce(NO3)3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-055

CsNO3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-055-5

CsNO3 in dilute HNO3, 1000 g/mL

500 mL

Cesium Cs

Chromium Cr
NIST-3112A

Cr in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-024

Ammonium dichromate in dilute HNO3, 1000 g/mL

100 mL

U-ICP-024-5

Ammonium dichromate in dilute HNO3, 1000 g/mL

500 mL

Cobalt Co
NIST-3113

Co in 10% HNO3, 10 mg/g

U-ICP-027

Co(NO3)2 x 6H2O in dilute HNO3, 1000 g/mL

100 mL

U-ICP-027-5

Co(NO3)2 x 6H2O in dilute HNO3, 1000 g/mL

500 mL

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Standards for spectroscopy


Code

Product

Unit

Copper Cu
NIST-3114

Cu in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-029

Cu(NO3)2 x 3H2O in dilute HNO3, 1000 g/mL

100 mL

U-ICP-029-5

Cu(NO3)2 x 3H2O in dilute HNO3, 1000 g/mL

500 mL

Dysprosium Dy
NIST-3115A

Dy in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-066

Dy2O3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-066-5

Dy2O3 in dilute HNO3, 1000 g/mL

500 mL

U-ICP-068

Er2O3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-068-5

Er2O3 in dilute HNO3, 1000 g/mL

500 mL

Erbium Er

Europium Eu
NIST-3117A

Eu in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-063

Eu2O3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-063-5

Eu2O3 in dilute HNO3, 1000 g/mL

500 mL

Gadolinium Gd
NIST-3118

Gd in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-064

Gd2O3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-064-5

Gd2O3 in dilute HNO3, 1000 g/mL

500 mL

Gallium Ga
NIST-3119

Ga in 10% HNO3, 10 mg/g

50 mL

U-ICP-031

Ga-metal in dilute HNO3, 1000 g/mL

100 mL

U-ICP-031-5

Ga-metal in dilute HNO3, 1000 g/mL

500 mL

Germanium- Ge
NIST-3120

Ge in 10% Oxalic acid, 10 mg/g

50 mL

U-ICP-032

GeO2 in H2O trace HF, 1000 g/mL

100 mL

U-ICP-032-5

GeO2 in H2O trace HF, 1000 g/mL

500 mL

Gold Au
NIST-3121

Au in 5% HNO3 + 2% HF, 10 mg/g

5 x 10 mL

U-ICP-079

Au-metal in dilute HCl, 1000 g/mL

100 mL

U-ICP-079-5

Au-metal in dilute HCl, 1000 g/mL

500 mL

NIST-3122

Hf in 10% HNO3 + 2% HF, 10 mg/g

50 mL

U-ICP-072

HfOCl2 x 8H2O in dilute HCl, 1000 g/mL

100 mL

U-ICP-072-5

HfOCl2 x 8H2O in dilute HCl, 1000 g/mL

500 mL

Hafnium Hf

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Standards for spectroscopy


Code

Product

Unit

Holmium Ho
U-ICP-067

Ho2O3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-067-5

Ho2O3 in dilute HNO3, 1000 g/mL

500 mL

Indium In
NIST-3124A

In in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-049

In-metal in dilute HNO3 , 1000 g/mL

100 mL

U-ICP-049-5

In-metal in dilute HNO3 , 1000 g/mL

500 mL

U-ICP-077

IrCl3 in dilute HCl, 1000 g/mL

100 mL

U-ICP-077-5

IrCl3 in dilute HCl, 1000 g/mL

500 mL

Iridium Ir

Iron Fe
NIST-3126A

Fe in 10% HNO3, 10 mg/g

50 mL

U-ICP-026

Fe(NO3)2 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-026-5

Fe(NO3)2 in dilute HNO3, 1000 g/mL

500 mL

Lanthanum La
NIST-3127

La in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-057

La2O3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-057-5

La2O3 in dilute HNO3, 1000 g/mL

500 mL

Lead Pb
NIST-3128

Pb in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-082

Pb(NO3)2 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-082-5

Pb(NO3)2 in dilute HNO3, 1000 g/mL

500 mL

Lithium Li
NIST-3129

Li in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-003

Li2CO3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-003-5

Li2CO3 in dilute HNO3, 1000 g/mL

500 mL

Lutetium Lu
NIST-3130A

Lu in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-071

Lu2O3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-071-5

Lu2O3 in dilute HNO3, 1000 g/mL

500 mL

Magnesium Mg
NIST-3131A

Mg in 10% HNO3, 10 mg/g

U-ICP-012

Mg(NO3)2 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-012-5

Mg(NO3)2 in dilute HNO3, 1000 g/mL

500 mL

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Standards for spectroscopy


Code

Product

Unit

Manganese Mn
NIST-3132

Mn in 10% HNO3

5 x 10 mL

U-ICP-025

Mn(NO3)2 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-025-5

Mn(NO3)2 in dilute HNO3, 1000 g/mL

500 mL

Mercury Hg
NIST-3133

Hg in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-080

HgNO3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-080-5

HgNO3 in dilute HNO3, 1000 g/mL

500 mL

Molybdenum - Mo
NIST-3134

Mo in 10% HCl, 10 mg/g

5 x 10 mL

U-ICP-042

MoO2 in H2O trace NH4OH, 1000 g/mL

100 mL

U-ICP-042-5

MoO2 in H2O trace NH4OH, 1000 g/mL

500 mL

Neodymium - Nd
NIST-3135A

Nd in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-060

Nd2O3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-060-5

Nd2O3 in dilute HNO3, 1000 g/mL

500 mL

Nickel - Ni
NIST-3136

Ni in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-028

Ni(NO3)2 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-028-5

Ni(NO3)2 in dilute HNO3, 1000 g/mL

500 mL

Niobium - Nb
NIST-3137

Nb in 5% HNO3 + 2% HF, 10 mg/g

50 mL

U-ICP-041

Nb3O5 in H2O trace HF, 1000 g/mL

100 mL

U-ICP-041-5

Nb3O5 in H2O trace HF, 1000 g/mL

500 mL

Palladium - Pd
NIST-3138

Pd in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-046

Pd-metal in dilute HNO3, 1000 g/mL

100 mL

U-ICP-046-5

Pd-metal in dilute HNO3, 1000 g/mL

500 mL

Phosphorus - P
NIST-3139A

P in 0.8% HNO3, 10 mg/g

5 x 10 mL

U-ICP-015

NH4H2PO4 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-015-5

NH4H2PO4 in dilute HNO3, 1000 g/mL

500 mL

Platinum - Pt
NIST-3140

Pt in 10% HCl, 10 mg/g

U-ICP-078

Pt-metal in dilute HCl, 1000 g/mL

100 mL

U-ICP-078-5

Pt-metal in dilute HCl, 1000 g/mL

500 mL

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Code

Product

Unit

Potassium - K
NIST-3141A

K in 1% HNO3, 10 mg/g

50 mL

U-ICP-019

KNO3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-019-5

KNO3 in dilute HNO3, 1000 g/mL

500 mL

Praseodymium - Pr
NIST-3142A

Pr in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-059

Pr6O11 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-059-5

Pr6O11 in dilute HNO3, 1000 g/mL

500 mL

Rhenium Re
NIST-3143

Re in 10% HNO3, 10 mg/g

50 mL

U-ICP-075

Re-metal in H2O, 1000 g/mL

100 mL

U-ICP-075-5

Re-metal in H2O, 1000 g/mL

500 mL

Rhodium Rh
NIST-3144

Rh in 10% HCl, 10 mg/g

5 x 10 mL

U-ICP-045

RhCl3 in dilute HCl, 1000 g/mL

100 mL

U-ICP-045

RhCl3 in dilute HCl, 1000 g/mL

100 mL

Rubidium Rb
NIST-3145A

Rb in 1% HNO3, 10 mg/g

5 x 10 mL

U-ICP-037

RbNO3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-037-5

RbNO3 in dilute HNO3, 1000 g/mL

500 mL

Ruthenium Ru
U-ICP-044

RuCl3 in dilute HCl, 1000 g/mL

100 mL

U-ICP-044-5

RuCl3 in dilute HCl, 1000 g/mL

500 mL

Samarium Sm
NIST-3147A

Sm in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-062

Sm2O3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-062-5

Sm2O3 in dilute HNO3, 1000 g/mL

500 mL

Scandium Sc
NIST-3148

Sc in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-021

Sc2O3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-021-5

Sc2O3 in dilute HNO3, 1000 g/mL

500 mL

Selenium Se
NIST-3149

Se in 10% HNO3, 10 mg/g

U-ICP-034

SeO2 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-034-5

SeO2 in dilute HNO3, 1000 g/mL

500 mL

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Standards for spectroscopy


Code

Product

Unit

Silicon Si
NIST-3150

Si in water, 10 mg/g

50 mL

U-ICP-014

(NH4)2SiF6 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-014-5

(NH4)2SiF6 in dilute HNO3, 1000 g/mL

500 mL

U-ICP-014

SiO2 in dilute NaOH, 1000 g/mL

100 mL

U-ICP-014-5

SiO2 in dilute NaOH, 1000 g/mL

500 mL

Silver Ag
NIST-3151

Ag in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-047

AgNO3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-047-5

AgNO3 in dilute HNO3, 1000 g/mL

500 mL

Sodium - Na
NIST-3152A

Na in 1% HNO3, 10 mg/g

50 mL

U-ICP-011

NaNO3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-011-5

NaNO3 in dilute HNO3, 1000 g/mL

500 mL

Strontium - Sr
NIST-3153A

Sr in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-038

SrNO3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-038-5

SrNO3 in dilute HNO3, 1000 g/mL

500 mL

Sulphur - S
NIST-3154

S in 0.1% H2SO4, 10 mg/g

5 x 10 mL

U-ICP-016

(NH4)2SO4 in H2O, 1000 g/mL

100 mL

U-ICP-016-5

(NH4)2SO4 in H2O, 1000 g/mL

500 mL

Tantalum - Ta
NIST-3155

Ta in 5% HNO3 + 2% HF, 10 mg/g

50 mL

U-ICP-073

Ta-metal in H2O trace HF, 1000 g/mL

100 mL

U-ICP-073-5

Ta-metal in H2O trace HF, 1000 g/mL

500 mL

Tellurium - Te
NIST-3156

Te in 20% HCl, 10 mg/g

5 x 10 mL

U-ICP-052

Te-metal in dilute HCl, 1000 g/mL

100 mL

U-ICP-052-5

Te-metal in dilute HCl, 1000 g/mL

500 mL

Terbium - Tb
NIST-3157A

Tb in 16% HNO3, 10 mg/g

U-ICP-065

Tb4O7 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-065-5

Tb4O7 in dilute HNO3, 1000 g/mL

500 mL

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Standards for spectroscopy


Code

Product

Unit

Thallium - Tl
NIST-3158A

Tl in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-081

TlNO3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-081-5

TlNO3 in dilute HNO3, 1000 g/mL

500 mL

Thorium - Th
NIST-3159

Th in 10% HNO3, 10 mg/g

50 mL

U-ICP-090

Th(NO3)4 x 4H2O in dilute HNO3, 1000 g/mL

100 mL

U-ICP-090-5

Th(NO3)4 x 4H2O in dilute HNO3, 1000 g/mL

500 mL

Thulium - Tm
NIST-3160A

Tm in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-069

Tm in dilute HNO3, 1000 g/mL

100 mL

U-ICP-069-5

Tm in dilute HNO3, 1000 g/mL

500 mL

Tin - Sn
NIST-3161A

Sn in 5% HNO3 + 2% HF, 10 mg/g

50 mL

U-ICP-050

(NH4)2SnF6 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-050-5

(NH4)2SnF6 in dilute HNO3, 1000 g/mL

500 mL

Titanium - Ti
NIST-3162A

Ti in 10% HNO3 + 2% HF, 10 mg/g

50 mL

U-ICP-022

(NH4)2TiF6 dilute HNO3, 1000 g/mL

100 mL

U-ICP-022-5

(NH4)2TiF6 dilute HNO3, 1000 g/mL

500 mL

Tungsten - W
NIST-3163

W in 7% HNO3 + 4% HF, 10 mg/g

50 mL

U-ICP-074

(NH4)2WO4 in H2O trace NH4OH, 1000 g/mL

100 mL

U-ICP-074-5

(NH4)2WO4 in H2O trace NH4OH, 1000 g/mL

500 mL

Uranium - U
NIST-3164

U in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-092

U3O8 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-092-5

U3O8 in dilute HNO3, 1000 g/mL

500 mL

Vanadium - V
NIST-3165

V in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-023

NH4VO3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-023-5

NH4VO3 in dilute HNO3, 1000 g/mL

500 mL

Ytterbium - Yb
NIST-3166A

Yb in 16% HNO3, 10 mg/g

U-ICP-070

Yb2O3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-070-5

Yb2O3 in dilute HNO3, 1000 g/mL

500 mL

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Standards for spectroscopy


Code

Product

Unit

Yttrium - Y
NIST-3167A

Y in 10% HNO3, 10 mg/g

5 x 10 mL

U-ICP-039

Y2O3 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-039-5

Y2O3 in dilute HNO3, 1000 g/mL

500 mL

Zinc - Zn
NIST-3168A

Zn in 10% HCl, 10 mg/g

50 mL

U-ICP-030

Zn(NO3)2 x H2O in dilute HNO3, 1000 g/mL

100 mL

U-ICP-030-5

Zn(NO3)2 x H2O in dilute HNO3, 1000 g/mL

500 mL

Zirconium - Zr
NIST-3169

Zr in 10% HNO3 + 2% HF, 10 mg/g

50 mL

U-ICP-040

Zr(NO3)4 in dilute HNO3, 1000 g/mL

100 mL

U-ICP-040-5

Zr(NO3)4 in dilute HNO3, 1000 g/mL

500 mL

TM

The ULTRA Scientific range of single element solutions for ICP are also
available at a concentration of 10000 g/mL in 100 mL and 500 mL units.

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133

Standards for spectroscopy


Code

Product

Unit
TM

ULTRA Scientific's EnviroConcentrate

kits for ICP

Kit
- 20 mL of analyte solution at 10000 g/mL
- yields 2 x 100 mL 1000 g/mL standards
- 500 ml of ASTM Type I water
- 100 mL pre-cleaned LDPE bottle for storage
- starting material 99.999 % pure, where available
- NIST traceable

Aluminum - Al
U-ECK-013

Al in dilute HNO3, 10000 g/mL

kit

Sb in dilute HNO3, 10000 g/mL

kit

As in dilute HNO3, 10000 g/mL

kit

Ba in dilute HNO3, 10000 g/mL

kit

Be in dilute HNO3, 10000 g/mL

kit

B in water with trace NH4OH, 10000 g/mL

kit

Cd in dilute HNO3, 10000 g/mL

kit

Ca in dilute HNO3, 10000 g/mL

kit

Cr in dilute HNO3, 10000 g/mL

kit

Co in dilute HNO3, 10000 g/mL

kit

Cu in dilute HNO3, 10000 g/mL

kit

Fe in dilute HNO3, 10000 g/mL

kit

Pb in dilute HNO3, 10000 g/mL

kit

Li in dilute HNO3, 10000 g/mL

kit

Antimony - Sb
U-ECK-051

Arsenic - As
U-ECK-033

Barium - Ba
U-ECK-056

Beryllium - Be
U-ECK-004

Boron - B
U-ECK-005

Cadmium - Cd
U-ECK-048

Calcium - Ca
U-ECK-020

Chromium - Cr
U-ECK-024

Cobalt - Co
U-ECK-027

Copper - Cu
U-ECK-029

Iron - Fe
U-ECK-026

Lead - Pb
U-ECK-082

Lithium - Li
U-ECK-003

Magnesium - Mg
U-ECK-012

134

Mg in dilute HNO3, 10000 g/mL

kit

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Standards for spectroscopy


Code

Product

Unit

Manganese - Mn
U-ECK-025

Mn in dilute HNO3, 10000 g/mL

kit

Hg in dilute HNO3, 10000 g/mL

kit

Mercury - Hg
U-ECK-080

Molybdenum - Mo
U-ECK-042

Mo in water with tr. NH4OH, 10000 g/mL

kit

Ni in dilute HNO3, 10000 g/mL

kit

Nickel - Ni
U-ECK-028

Phosphorus - P
U-ECK-015

P in dilute HNO3, 10000 g/mL

kit

K in dilute HNO3, 10000 g/mL

kit

Se in dilute HNO3, 10000 g/mL

kit

Si in water, 10000 g/mL

kit

Ag in dilute HNO3, 10000 g/mL

kit

Na in dilute HNO3, 10000 g/mL

kit

Sr in dilute HNO3, 10000 g/mL

kit

Tl in dilute HNO3, 10000 g/mL

kit

Sn in water, 10000 g/mL

kit

Ti in water with trace HF, 10000 g/mL

kit

V in dilute HNO3, 10000 g/mL

kit

Zn in dilute HNO3, 10000 g/mL

kit

Potassium - K
U-ECK-019

Selenium - Se
U-ECK-034

Silicon - Si
U-ECK-014

Silver - Ag
U-ECK-047

Sodium - Na
U-ECK-011

Strontium - Sr
U-ECK-038

Thallium - Tl
U-ECK-081

Tin - Sn
U-ECK-050

Titanium - Ti
U-ECK-022

Vanadium - V
U-ECK-023

Zinc - Zn
U-ECK-030

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135

Standards for spectroscopy


Code

Product

Unit

ULTRA Scientifics certified standards for atomic absorption spectroscopy


Aluminum - Al
U-IAA-213

Al in dilute HNO3, 1000 g/mL

100 mL

Sb in dilute HNO3, 1000 g/mL

100 mL

As in dilute HNO3, 1000 g/mL

100 mL

Ba in dilute HNO3, 1000 g/mL

100 mL

Be in dilute HNO3, 1000 g/mL

100 mL

Bi in dilute HNO3, 1000 g/mL

100 mL

B in water with trace NH4OH, 1000 g/ml

100 mL

Cd in dilute HNO3, 1000 g/mL

100 mL

Ca in dilute HNO3, 1000 g/mL

100 mL

Ce in dilute HNO3, 1000 g/mL

100 mL

Cs in dilute HNO3, 1000 g/mL

100 mL

Cr in dilute HNO3, 10000 g/mL

100 mL

Co in dilute HNO3, 1000 g/mL

100 mL

Cu in dilute HNO3, 1000 g/mL

100 mL

Antimony - Sb
U-IAA-251

Arsenic - As
U-IAA-233

Barium - Ba
U-IAA-256

Beryllium - Be
U-IAA-204

Bismuth - Bi
U-IAA-283

Boron - B
U-IAA-205

Cadmium - Cd
U-IAA-248

Calcium - Ca
U-IAA-220

Cerium - Ce
U-IAA-258

Cesium - Cs
U-IAA-255

Chromium - Cr
U-IAA-224

Cobalt - Co
U-IAA-227

Copper - Cu
U-IAA-229

Dysprosium - Dy
U-IAA-266

Dy in dilute HNO3, 1000 g/mL

100 mL

Er in dilute HNO3, 1000 g/mL

100 mL

Eu in dilute HNO3, 1000 g/mL

100 mL

Erbium - Er
U-IAA-268

Europium - Eu
U-IAA-263

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Standards for spectroscopy


Code

Product

Unit

Gadolinium - Gd
U-IAA-264

Gd in dilute HNO3, 1000 g/mL

100 mL

Ga in dilute HNO3, 1000 g/mL

100 mL

Gallium - Ga
U-IAA-231

Germanium - Ge
U-IAA-232

Ge in water with trace HF, 1000 g/mL

100 mL

Au-metal in dilute HCl, 1000 g/mL

100 mL

Hf in dilute HCl, 1000 g/mL

100 mL

Ho in dilute HNO3, 1000 g/mL

100 mL

In in dilute HNO3, 1000 g/mL

100 mL

Ir in dilute HCl, 1000 g/mL

100 mL

Fe in dilute HNO3, 1000 g/mL

100 mL

Gold - Au
U-IAA-279

Hafnium - Hf
U-IAA-272

Holmium - Ho
U-IAA-267

Indium - In
U-IAA-249

Iridium - Ir
U-IAA-277

Iron - Fe
U-IAA-226

Lanthanum - La
U-IAA-257

La in dilute HNO3, 1000 g/mL

100 mL

Pb in dilute HNO3, 1000 g/mL

100 mL

Li in dilute HNO3, 1000 g/mL

100 mL

Lu in dilute HNO3, 1000 g/mL

100 mL

Lead - Pb
U-IAA-282

Lithium - Li
U-IAA-203

Lutetium - Lu
U-IAA-271

Magnesium - Mg
U-IAA-212

Mg in dilute HNO3, 1000 g/mL

100 mL

Manganese - Mn
U-IAA-225

Mn in dilute HNO3, 1000 g/mL

100 mL

Hg in dilute HNO3, 1000 g/mL

100 mL

Mercury - Hg
U-IAA-280

Molybdenum - Mo
U-IAA-242

Mo in water with trace NH4OH, 1000 g/mL

100 mL

Neodymium - Nd
U-IAA-260
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Nd in dilute HNO3, 1000 g/mL

100 mL
Edition 2003/2004

137

Standards for spectroscopy


Code

Product

Unit

Nickel - Ni
U-IAA-228

Ni in dilute HNO3, 1000 g/mL

100 mL

Nb in water with trace. HF, 1000 g/mL

100 mL

Pd-metal in dilute HNO3, 1000 g/mL

100 mL

Niobium - Nb
U-IAA-241

Palladium - Pd
U-IAA-246

Phosphorus - P
U-IAA-215

P in dilute HNO3, 1000 g/mL

100 mL

Pt-metal in dilute HCl, 1000 g/mL

100 mL

K in dilute HNO3, 1000 g/mL

100 mL

Platinum - Pt
U-IAA-278

Potassium - K
U-IAA-219

Praseodymium - Pr
U-IAA-259

Pr in dilute HNO3, 1000 g/mL

100 mL

Re-metal in H2O, 1000 g/mL

100 mL

Rh in dilute HCl, 1000 g/mL

100 mL

Rb in dilute HNO3, 1000 g/mL

100 mL

Rhenium - Re
U-IAA-275

Rhodium - Rh
U-IAA-245

Rubidium - Rb
U-IAA-237

Ruthenium - Ru
U-IAA-244

Ru in dilute HCl

100 mL

Samarium - Sm
U-IAA-262

Sm in dilute HNO3, 1000 g/mL

100 mL

Sc in dilute HNO3, 1000 g/mL

100 mL

Se in dilute HNO3, 1000 g/mL

100 mL

Si in water, 1000 g/mL

100 mL

Ag in dilute HNO3, 1000 g/mL

100 mL

Na in dilute HNO3, 1000 g/mL

100 mL

Sr in dilute HNO3, 1000 g/mL

100 mL

Scandium - Sc
U-IAA-221

Selenium - Se
U-IAA-234

Silicon - Si
U-IAA-214

Silver - Ag
U-IAA-247

Sodium - Na
U-IAA-211

Strontium - Sr
U-IAA-238
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Standards for spectroscopy


Code

Product

Unit

Sulphur - S
U-IAA-216

S in water, 1000 g/mL

100 mL

Ta in trace HF, 1000 g/mL

100 mL

Te in dilute HCl 1000 g/mL

100 mL

Tb in dilute HNO3, 1000 g/mL

100 mL

Tl in dilute HNO3, 1000 g/mL

100 mL

Th in dilute HNO3, 1000 g/mL

100 mL

Tm in dilute HNO3, 1000 g/mL

100 mL

Sn in water, 1000 g/mL

100 mL

Ti in water with trace HF, 1000 g/mL

100 mL

W in dilute HNO3 with trace NH4OH, 1000 g/mL

100 mL

U in dilute HNO3, 1000 g/mL

100 mL

V in dilute HNO3, 1000 g/mL

100 mL

Yb in dilute HNO3, 1000 g/mL

100 mL

Y in dilute HNO3, 1000 g/mL

100 mL

Zn in dilute HNO3, 1000 g/mL

100 mL

Zr in dilute HNO3, 1000 g/mL

100 mL

Tantalum - Ta
U-IAA-273

Tellurium - Te
U-IAA-252

Terbium - Tb
U-IAA-265

Thallium - Tl
U-IAA-281

Thorium - Th
U-IAA-290

Thulium - Tm
U-IAA-269

Tin - Sn
U-IAA-250

Titanium - Ti
U-IAA-222

Tungsten - W
U-IAA-274

Uranium - U
U-IAA-292

Vanadium - V
U-IAA-223

Ytterbium - Yb
U-IAA-270

Yttrium - Y
U-IAA-239

Zinc -Zn
U-IAA-230

Zirconium - Zr
U-IAA-240

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139

Standards for spectroscopy


Code

Product

Unit
TM

ULTRA Scientific's EnviroConcentrates

for atomic absorption spectroscopy


TM

ULTRA Scientifics AA EnviroConcentrates consist of a 10 mL bottle of the selected element at a


concentration of 10000 g/mL. Simply pipette the required amount of EnviroConcentrate and dilute to

volume. Standards are traceable to NIST Standard Reference Materials whenever possible.

Aluminum - Al
U-IAA-013

Al in dilute HNO3, 10000 g/mL

10 mL

Sb in dilute HNO3, 10000 g/mL

10 mL

As in dilute HNO3, 10000 g/mL

10 mL

Ba in dilute HNO3, 10000 g/mL

10 mL

Be in dilute HNO3, 10000 g/mL

10 mL

Bi in dilute HNO3, 10000 g/mL

10 mL

B in water with trace NH4OH, 10000 g/mL

10 mL

Cd in dilute HNO3, 10000 g/mL

10 mL

Ca in dilute HNO3, 10000 g/mL

10 mL

Ce in dilute HNO3, 10000 g/mL

10 mL

Cs in dilute HNO3, 10000 g/mL

10 mL

Cr in dilute HNO3, 10000 g/mL

10 mL

Co in dilute HNO3, 10000 g/mL

10 mL

Cu in dilute HNO3, 10000 g/mL

10 mL

Antimony - Sb
U-IAA-051

Arsenic - As
U-IAA-033

Barium - Ba
U-IAA-056

Beryllium - Be
U-IAA-004

Bismuth - Bi
U-IAA-083

Boron - B
U-IAA-005

Cadmium - Cd
U-IAA-048

Calcium - Ca
U-IAA-020

Cerium - Ce
U-IAA-058

Cesium - Cs
U-IAA-055

Chromium - Cr
U-IAA-024

Cobalt - Co
U-IAA-027

Copper - Cu
U-IAA-029

Dysprosium - Dy
U-IAA-066

Dy in dilute HNO3, 10000 g/mL

10 mL

Er in dilute HNO3, 10000 g/mL

10 mL

Erbium - Er
U-IAA-068

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Standards for spectroscopy


Code

Product

Unit

Europium - Eu
U-IAA-063

Eu in dilute HNO3, 10000 g/mL

10 mL

Gadolinium - Gd
U-IAA-064

Gd in dilute HNO3, 10000 g/mL

10 mL

Ga in dilute HNO3, 10000 g/mL

10 mL

Gallium - Ga
U-IAA-031

Germanium - Ge
U-IAA-032

Ge in water with trace HF, 10000 g/mL

10 mL

Ho in dilute HNO3, 10000 g/mL

10 mL

In in dilute HNO3, 10000 g/mL

10 mL

Fe in dilute HNO3, 10000 g/mL

10 mL

Holmium - Ho
U-IAA-067

Indium - In
U-IAA-049

Iron - Fe
U-IAA-026

Lanthanum - La
U-IAA-057

La in dilute HNO3, 10000 g/mL

10 mL

Pb in dilute HNO3, 10000 g/mL

10 mL

Li in dilute HNO3, 10000 g/mL

10 mL

Lead - Pb
U-IAA-082

Lithium -Li
U-IAA-003

Magnesium - Mg
U-IAA-012

Mg in dilute HNO3, 10000 g/mL

10 mL

Manganese - Mn
U-IAA-025

Mn in dilute HNO3, 10000 g/mL

10 mL

Hg in dilute HNO3, 10000 g/mL

10 mL

Mercury - Hg
U-IAA-080

Molybdenum - Mo
U-IAA-042

Mo in water with trace NH4OH, 10000 g/mL

10 mL

Neodymium - Nd
U-IAA-060

Nd in dilute HNO3, 10000 g/mL

10 mL

Ni in dilute HNO3, 10000 g/mL

10 mL

Nb in water with trace HF, 10000 g/mL

10 mL

Nickel - Ni
U-IAA-028

Niobium - Nb
U-IAA-041

Phosphorus - P
U-IAA-015
www.lgcpromochem.com

P in dilute HNO3, 10000 g/mL

10 mL
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141

Standards for spectroscopy


Code

Product

Unit

Potassium - K
U-IAA-019

K in dilute HNO3, 10000 g/mL

10 mL

Praseodymium - Pr
U-IAA-059

Pr in dilute HNO3, 10000 g/mL

10 mL

Samarium - Sm
U-IAA-062

Sm in dilute HNO3, 10000 g/mL

10 mL

Se in dilute HNO3, 10000 g/mL

10 mL

Si in water, 10000 g/mL

10 mL

Ag in dilute HNO3, 10000 g/mL

10 mL

Na in dilute HNO3, 10000 g/mL

10 mL

Sr in dilute HNO3, 10000 g/mL

10 mL

S in water, 10000 g/mL

10 mL

Ta in water with trace HF, 10000 g/mL

10 mL

Te in dilute HCl, 10000 g/mL

10 mL

Tb in dilute HNO3, 10000 g/mL

10 mL

Tl in dilute HNO3, 10000 g/mL

10 mL

Th in dilute HNO3, 10000 g/mL

10 mL

Sn in water, 10000 g/mL

10 mL

Ti in water with trace HF, 10000 g/mL

10 mL

W in dilute HNO3 with trace NH4OH, 10000 g/mL

10 mL

U in dilute HNO3, 10000 g/mL

10 mL

Selenium - Se
U-IAA-034

Silicon - Si
U-IAA-014

Silver - Ag
U-IAA-047

Sodium - Na
U-IAA-011

Strontium - Sr
U-IAA-038

Sulphur - S
U-IAA-016

Tantalum - Ta
U-IAA-073

Tellurium - Te
U-IAA-052

Terbium - Tb
U-IAA-065

Thallium - Tl
U-IAA-081

Thorium - Th
U-IAA-090

Tin - Sn
U-IAA-050

Titanium - Ti
U-IAA-022

Tungsten - W
U-IAA-074

Uranium - U
U-IAA-092
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Standards for spectroscopy


Code

Product

Unit

Vanadium - V
U-IAA-023

V in dilute HNO3, 10000 g/mL

10 mL

Yb in dilute HNO3, 10000 g/mL

10 mL

Y in dilute HNO3, 10000 g/mL

10 mL

Zn in dilute HNO3, 10000 g/mL

10 mL

Zr in dilute HNO3,10000 g/mL

10 mL

Ytterbium - Yb
U-IAA-070

Yttrium - Y
U-IAA-039

Zinc - Zn
U-IAA-030

Zirconium - Zr
U-IAA-040

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Edition 2003/2004

143

Multielement standards

Multielement standards
Code

Product

Unit

U-IQC-007

Inorganic Quality Control Standard 1

100 mL

7 analytes in 5% HNO3
Aluminum.................. 100 g/mL
Barium ...................... 100 g/mL
Boron ........................ 100 g/mL

U-IQC-019

Potassium ...............1000 g/mL


Silicon..........................50 g/mL
Silver .........................100 g/mL

Sodium...................... 100 g/mL

Inorganic Quality Control Standard 2

100 mL

19 analytes each at 100 g/mL in dilute HNO3


Antimony
Arsenic
Beryllium
Cadmium
Calcium

U-IQC-026

Chromium
Cobalt
Copper
Iron
Lead

Magnesium
Manganese
Molybdenum
Nickel
Selenium

Thallium
Titanium
Vanadium
Zinc

Combined Quality Control Standard

100 mL

26 analytes in dilute HNO3


Aluminum.................. 100 g/mL
Barium ...................... 100 g/mL
Boron ........................ 100 g/mL
Potassium ............... 1000 g/mL
Silicon ......................... 50 g/mL
Silver......................... 100 g/mL
Sodium...................... 100 g/mL
Antimony................... 100 g/mL
Arsenic...................... 100 g/mL

Beryllium....................100 g/mL
Cadmium...................100 g/mL
Calcium .....................100 g/mL
Chromium..................100 g/mL
Cobalt ........................100 g/mL
Copper.......................100 g/mL
Iron ............................100 g/mL
Lead ..........................100 g/mL
Magnesium................100 g/mL

Manganese ............... 100 g/mL


Molybdenum ............. 100 g/mL
Nickel ........................ 100 g/mL
Selenium................... 100 g/mL
Thallium .................... 100 g/mL
Titanium .................... 100 g/mL
Vanadium.................. 100 g/mL
Zinc ........................... 100 g/mL

EPA Method 200.7


U-ICM-231

EPA Method 200.7 Mixed Calibration Standard I

100 mL

10 Analytes in 2% HNO3
Antimony..................... 50 g/mL
Arsenic...................... 100 g/mL
Barium ........................ 10 g/mL
Boron .......................... 20 g/mL

U-ICM-232

Cadmium.....................20 g/mL
Calcium .....................100 g/mL
Copper.........................20 g/mL
Manganese..................20 g/mL

Selenium..................... 50 g/mL
Silver............................. 5 g/mL

EPA Method 200.7 Mixed Calibration Standard II

100 mL

5 Analytes in 2% HNO3
Lithium ........................ 50 g/mL
Molybdenum ............. 100 g/mL

U-ICM-233

Potassium .................200 g/mL


Sodium ......................100 g/mL

Strontium .................... 10 g/mL

EPA Method 200.7 Mixed Calibration Standard III

100 mL

3 Analytes in 2% HNO3
Cobalt ......................... 20 g/mL

U-ICM-234

Phosphorus ...............100 g/mL

Vanadium.................... 20 g/mL

EPA Method 200.7 Mixed Calibration Standard IV

100 mL

5 Analytes in 2% HNO3
Aluminum.................. 100 g/mL
Chromium ................... 50 g/mL

U-ICM-235

Silicon........................100 g/mL
Tin ...............................40 g/mL

Zinc ............................. 50 g/mL

EPA Method 200.7 Mixed Calibration Standard V

100 mL

6 Analytes in 2% HNO3
Beryllium ..................... 10 g/mL
Iron............................ 100 g/mL

U-ICM-642

Lead ..........................100 g/mL


Magnesium................100 g/mL

TCLP Mercury Standard

Nickel .......................... 20 g/mL


Thallium ...................... 50 g/mL

100 mL

Mercury .................................. 20 g/mL in 2% HNO3

U-ICK-230A

EPA Method 200.7 Calibration Kit

Kit

Each kit contains 100 mL of each of the following standards


ICM-231
ICM-232

144

ICM-233
ICM-234

ICM-235
ICM-642

Edition 2003/2004

www.lgcpromochem.com

Multielement standards
Code

Product

Unit

U-ICM-240

EPA Method 200.7 LPC Solution

100 mL

30 Analytes in 2% HNO3
Aluminum.................... 20 g/mL
Antimony..................... 20 g/mL
Arsenic........................ 20 g/mL
Barium ........................ 20 g/mL
Beryllium ..................... 20 g/mL
Boron .......................... 20 g/mL
Cadmium .................... 20 g/mL
Calcium....................... 20 g/mL
Chromium ................... 20 g/mL
Cobalt ......................... 20 g/mL

U-ICM-245

Copper.........................20 g/mL
Iron ..............................20 g/mL
Lead ............................20 g/mL
Lithium.........................20 g/mL
Magnesium..................20 g/mL
Manganese..................20 g/mL
Mercury........................20 g/mL
Molybdenum ................20 g/mL
Nickel ..........................20 g/mL
Phosphorus ...............100 g/mL

Potassium ................. 100 g/mL


Selenium..................... 20 g/mL
Silicon ....................... 100 g/mL
Silver............................. 5 g/mL
Sodium........................ 20 g/mL
Strontium .................... 20 g/mL
Thallium ...................... 20 g/mL
Tin............................... 20 g/mL
Vanadium.................... 20 g/mL
Zinc ............................. 20 g/mL

EPA Method 200.7 Lab Fortifying Stock Solution

100 mL

26 Analytes in 2% HNO3
Aluminum.................... 25 g/mL
Antimony..................... 25 g/mL
Arsenic........................ 25 g/mL
Barium ........................ 25 g/mL
Beryllium ....................... 5 g/mL
Boron .......................... 25 g/mL
Cadmium .................... 10 g/mL
Chromium ................... 25 g/mL
Cobalt ......................... 10 g/mL

U-ICM-241

Copper.........................25 g/mL
Iron ..............................25 g/mL
Lead ............................25 g/mL
Lithium.........................25 g/mL
Manganese..................25 g/mL
Mercury..........................5 g/mL
Molybdenum ................10 g/mL
Nickel ..........................25 g/mL
Phosphorus .................50 g/mL

Selenium..................... 25 g/mL
Silicon ......................... 25 g/mL
Silver.......................... 2.5 g/mL
Strontium .................... 25 g/mL
Thallium ...................... 25 g/mL
Tin............................... 10 g/mL
Vanadium.................... 10 g/mL
Zinc ............................. 25 g/mL

EPA Method 200.7 SIC Solution I

100 mL

Molybdenum .......................... 50 g/mL in 2% HNO3

U-ICM-242

EPA Method 200.7 SIC Solution II

100 mL

5 Analytes in 2% HNO3
Chromium ................... 20 g/mL
Cobalt ......................... 10 g/mL

U-ICM-243

Copper.........................40 g/mL
Manganese..................20 g/mL

Vanadium.................... 20 g/mL

EPA Method 200.7 SIC Solution III

100 mL

3 Analytes in 2% HNO3
Aluminum.................... 30 g/mL

U-ICM-237

Iron ............................150 g/mL

Nickel .......................... 20 g/mL

EPA Method 200.7 Plasma Solution

100 mL

4 Analytes in 2% HNO3
Arsenic........................ 10 g/mL
Lead............................ 10 g/mL

U-ICM-238

Selenium .....................10 g/mL


Thallium.......................10 g/mL

EPA Method 200.7 Tuning Solution

100 mL

2 Analytes in 2% HNO3
Copper ........................ 10 g/mL

Lead ............................10 g/mL

U-ICP-051

Sb-metal in dilute HNO3/C4H6O6, 1000 g/mL

100 mL

U-ICM-202

EPA Method 200.7 Calibration Standard #1B

100 mL

5 Analytes in 5% HNO3
Arsenic.................... 1000 g/mL
Cadmium .................. 500 g/mL

U-ICM-203

Lead ........................1000 g/mL


Selenium ...................500 g/mL

Thallium .................. 1000 g/mL

EPA Method 200.7 Calibration Standard #2

100 mL

7 Analytes in 2% HNO3
Barium ...................... 100 g/mL
Beryllium ................... 100 g/mL
Cobalt ....................... 200 g/mL

U-ICM-204

Copper.......................100 g/mL
Iron ..........................1000 g/mL
Manganese................100 g/mL

Vanadium.................. 100 g/mL

EPA Method 200.7 Calibration Standard #3

100 mL

3 Analytes in water with trace hydrofluoric acid


Boron ........................ 100 g/mL

U-ICM-205

Molybdenum ............1000 g/mL

Silicon ..................... 1000 g/mL

EPA Method 200.7 Calibration Standard #4

100 mL

9 Analytes in 5% HNO3
Aluminum................ 1000 g/mL
Calcium................... 1000 g/mL
Chromium ................. 500 g/mL

Magnesium..............1000 g/mL
Nickel ........................500 g/mL
Potassium ...............1000 g/mL

Silver......................... 500 g/mL


Sodium.................... 1000 g/mL
Zinc ........................... 500 g/mL

U-ICP-022

(NH4)2TiF6 dilute HNO3, 1000 g/mL

100 mL

U-ICP-028

Ni(NO3)2 in dilute HNO3, 1000 g/mL

100 mL

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145

Multielement standards
Code

Product

Unit

U-ICM-221

EPA Method 200.7 Interference Check Std #1

50 mL

4 Analytes in water with trace hydrofluoric acid


Boron ........................ 500 g/mL
Molybdenum ............. 300 g/mL

U-ICM-223

Silicon........................230 g/mL
Titanium ..................1000 g/mL

Interference Check Std #3

50 mL

16 Analytes in 5% HNO3
Arsenic.................... 1000 g/mL
Barium ...................... 300 g/mL
Beryllium ................... 100 g/mL
Cadmium .................. 300 g/mL
Chromium (III) ........... 300 g/mL
Cobalt ....................... 300 g/mL

U-ICM-224

Copper.......................300 g/mL
Lead ........................1000 g/mL
Manganese................200 g/mL
Nickel ........................300 g/mL
Potassium .............20000 g/mL
Selenium ...................500 g/mL

Silver......................... 300 g/mL


Thallium .................. 1000 g/mL
Vanadium.................. 300 g/mL
Zinc ........................... 300 g/mL
~ob~

Interference Check Std #4

100 mL

5 Analytes in 2% HNO3
Aluminum................ 3000 g/mL
Calcium................. 15000 g/mL

Iron ........................12500 g/mL


Magnesium..............7500 g/mL

U-ICP-051

Sb-metal in dilute HNO3/C4H6O6, 1000 g/mL

U-ICM-211

EPA Method 200.7 Spiking Standard #1

Sodium.................... 2500 g/mL

100 mL
50 mL

3 Analytes in water with trace hydrofluoric acid


Boron ........................ 500 g/mL

U-ICM-212

Molybdenum ..............500 g/mL

Silicon ..................... 2000 g/mL

EPA Method 200.7 Spiking Standard #2

50 mL

4 Analytes in 5% HNO3
Calcium................... 1000 g/mL
Magnesium ............. 2000 g/mL

U-ICM-213

Potassium .............10000 g/mL


Sodium ....................3000 g/mL

EPA Method 200.7 Spiking Standard #3

50 mL

12 Analytes in 5% HNO3
Aluminum................ 2000 g/mL
Barium .................... 2000 g/mL
Beryllium ..................... 50 g/mL
Chromium ................. 200 g/mL

U-ICM-215

Cobalt ........................500 g/mL


Copper.......................250 g/mL
Iron ..........................1000 g/mL
Manganese................500 g/mL

Nickel ........................ 500 g/mL


Silver........................... 50 g/mL
Vanadium.................. 500 g/mL
Zinc ........................... 500 g/mL

EPA Method 200.7 Spiking Standard #5

50 mL

5 Analytes in 5% HNO3
Arsenic...................... 800 g/mL
Cadmium .................. 100 g/mL

Lead ........................1000 g/mL


Selenium .................1000 g/mL

Thallium .................. 1000 g/mL

EPA Method 6010A


U-ICM-601

EPA Method 6010A Mixed Standard Solution I

100 mL

6 Analytes in 2% HNO3
Beryllium ..................... 50 g/mL
Cadmium .................. 150 g/mL

U-ICM-602

Lead ..........................500 g/mL


Manganese................100 g/mL

Selenium................... 200 g/mL


Zinc ........................... 150 g/mL

EPA Method 6010A Mixed Standard Solution II

100 mL

5 Analytes in 2% HNO3
Barium ...................... 100 g/mL
Cobalt ....................... 100 g/mL

U-ICM-603

Copper.......................100 g/mL
Iron ........................10000 g/mL

Vanadium.................. 100 g/mL

EPA Method 6010A Mixed Standard Solution III

100 mL

2 Analytes in 2% HNO3
Arsenic...................... 500 g/mL

U-ICM-604

Molybdenum ..............100 g/mL

EPA Method 6010A Mixed Standard Solution IV

100 mL

8 Analytes in 2% HNO3
Aluminum.................. 200 g/mL
Calcium................... 1000 g/mL
Chromium ................... 20 g/mL

U-ICM-605

Lithium.......................100 g/mL
Nickel ..........................20 g/mL
Potassium .................400 g/mL

EPA Method 6010A Mixed Standard Solution V

Sodium...................... 200 g/mL


Strontium .................... 10 g/mL

100 mL

4 Analytes in 2% HNO3
Antimony................... 200 g/mL
Magnesium ............. 1000 g/mL

146

Silver ...........................50 g/mL


Thallium.....................200 g/mL

Edition 2003/2004

www.lgcpromochem.com

Multielement standards
Code

Product

Unit

U-ICM-607

EPA Method 6010A Mixed Standard Solution IIa

500 mL

5 Analytes in 2% HNO3
Barium ...................... 100 g/mL
Cobalt ....................... 100 g/mL

Copper.......................100 g/mL
Iron ..........................1000 g/mL

Vanadium.................. 100 g/mL

U-ICP-015

NH4H2PO4 in dilute HNO3, 1000 g/mL

100 mL

U-ICM-611

EPA Method 6010A Interference Check Std I

100 mL

5 Analytes in 2% HNO3 with trace hydrofluoric acid


Lithium ...................... 300 g/mL
Molybdenum ............. 300 g/mL

Phosphorus .............1000 g/mL


Strontium ...................200 g/mL

U-ICP-051

Sb-metal in dilute HNO3/C4H6O6, 1000 g/mL

U-ICM-223

Interference Check Std #3

Titanium .................. 1000 g/mL

100 mL
50 mL

16 Analytes in 5% HNO3
Arsenic.................... 1000 g/mL
Barium ...................... 300 g/mL
Beryllium ................... 100 g/mL
Cadmium .................. 300 g/mL
Chromium (III) ........... 300 g/mL
Cobalt ....................... 300 g/mL

U-ICM-224

Copper.......................300 g/mL
Lead ........................1000 g/mL
Manganese................200 g/mL
Nickel ........................300 g/mL
Potassium .............20000 g/mL
Selenium ...................500 g/mL

Silver......................... 300 g/mL


Thallium .................. 1000 g/mL
Vanadium.................. 300 g/mL
Zinc ........................... 300 g/mL
~ob~

Interference Check Std #4

100 mL

5 Analytes in 2% HNO3
Aluminum................ 3000 g/mL
Calcium................. 15000 g/mL

Iron ........................12500 g/mL


Magnesium..............7500 g/mL

Sodium.................... 2500 g/mL

Standards for ICP/MS


U-IMS-102

ICP/MS Calibration Standard #2

100 mL

29 Analytes , 10 g/mL of each analyte in 5% HNO3


Aluminum
Arsenic
Barium
Beryllium
Bismuth
Cadmium
Calcium,
Cesium

U-IMS-103

Chromium
Cobalt
Copper
Gallium
Indium
Iron
Lead
Lithium

Magnesium
Manganese
Nickel
Potassium
Rubidium
Selenium
Silver
Sodium

Strontium
Thallium
uranium
Vanadium
Zinc

ICP/MS Calibration Standard #3

100 mL

10 Analytes, 10 g/mL of each analyte 10% HCl


Antimony
Gold
Hafnium

U-IMS-104

Iridium
Palladium
Platinum

Rhodium
Ruthenium
Tellurium

Tin

ICP/MS Calibration Standard #4

100 mL

12 Analytes, 10 g/mL of each analyte in water


Boron
Germanium
Molybdenum

U-IMS-105

Niobium
Phosphorus
Rhenium

Silicon
Sulfur
Tantalum

ICP/MS Calibration Standard #5

Titanium
Tungsten
Zirconium

100 mL

Mercury .................................. 10 g/mL in 5% HNO3

U-IMS-110

ICP/MS Tuning Solution

100 mL

5 Analytes, 10 g/mL of each analyte 2% HNO3


Beryllium
Cobalt

U-IMS-111

Indium
Lead

Magnesium

ICP/MS Internal Standard

100 mL

Bismuth................................ 100 g/mL in 2% HNO3

U-IMS-112

ICP/MS Internal Standard

100 mL

Indium .................................. 100 g/mL in 2% HNO3

U-IMS-113

ICP/MS Internal Standard

100 mL

Scandium............................. 100 g/mL in 2% HNO3

U-IMS-114

ICP/MS Internal Standard

100 mL

Terbium................................ 100 g/mL in 2% HNO3

www.lgcpromochem.com

Edition 2003/2004

147

Ion chromatography standards


Code

U-IMS-115

Product

Unit

ICP/MS Internal Standard

100 mL

Yttrium ................................. 100 g/mL in 2% HNO3

U-IMS-100

ICP/MS Verification Standard

100 mL

9 Analytes, 10 g/mL in 2% HNO3


Beryllium
Bismuth
Cerium

Cobalt
Indium
Lead

Magnesium
Nickel
Uranium

Ion chromatography standards


Anions
Code

Product

Unit

ULTRA Scientific standards and NIST SRMs are solutions prepared gravimetrically for use in ion
chromatography or other techniques that require aqueous standard solutions for calibration.

The standards from ULTRA Scientific are traceable to NIST Standard Reference Materials (SRM )
wherever possible.
-

U-ICC-001

Bromide (Br ), 1000 g/mL

NIST-3182

Chloride (Cl ), 1000 mg/kg

100 mL

50 mL

100 mL

U-ICC-002

Chloride (Cl ), 1000 g/mL

NIST-3183

Fluoride (F ), 1000 mg/kg

50 mL

100 mL

U-ICC-003

Fluoride (F ), 1000 g/mL

NIST-3185

Nitrate (NO3 ), 1000 mg/kg

5 x 10 mL

100 mL

U-ICC-007

Nitrite (NO2 ), 1000 g/ml

100 mL

NIST-3186

Phoshate (PO4 ), 1000 mg/kg

U-ICC-004

Nitrate (NO3 ), 1000 g/mL


-

3-

5 x 10 mL

3-

100 mL

U-ICC-005

Phoshate (PO4 ), 1000 g/mL

NIST-3181

Sulfate (SO4 ), 1000 mg/kg

U-ICC-006

2-

5 x 10 mL

2-

Sulfate (SO4 ), 1000 g/mL

100 mL

100 mL

100 mL

U-ICC-010

Bromate (BrO3 ) 1000 g/mL in water

U-ICC-011

Chlorate (ClO3 ) 1000 g/mL in water


-

U-ICC-012

Chlorite (ClO2 ) 1000 g/mL in water

100 mL

U-ICC-013

Perchlorate (ClO4 ) 1000 g/mL in water

100 mL

Anion mixtures for ion chromatography


U-ICC-200

IC Anions Mixture 1

100 mL

Solvent : Water
Chloride (Cl-)............... 30 g/mL
Fluoride (F-)................. 20 g/mL

U-ICC-210

2-

Nitrate (NO3 )............100 g/mL


3Phosphate (PO4 ) .....150 g/mL

2-

Sulfate (SO4 )........... 150 g/mL

IC Anions Mixture 2

100 mL

Solvent : Water
Bromide .................... 400 g/mL
Chloride (Cl-)............. 200 g/mL

148

Fluoride (F-) ...............100 g/mL


Nitrate (NO32-)............400 g/mL

Edition 2003/2004

Phosphate (PO43-)..... 600 g/mL


Sulfate (SO42-)........... 400 g/mL

www.lgcpromochem.com

Ion chromatography standards


Code

Product

Unit

Cations
+

U-ICC-101

Ammonium (NH4 ), 1000 g/mL

U-ICC-102

Barium (Ba ), 1000 g/mL

100 mL

U-ICC-103

2+

100 mL

2+

Calcium (Ca ), 1000 g/mL


+

U-ICC-104

Lithium (Li ), 1000 g/mL

U-ICC-105

Magnesium (Mg ), 1000 g/mL

100 mL

2+

100 mL

U-ICC-106

Potassium (K ), 1000 g/mL

U-ICC-107

Sodium (Na ), 1000 g/mL

U-ICC-108

100 mL

100 mL

100 mL

2+

Strontium (Sr ), 1000 g/mL

100 mL

Cation mixtures for ion chromatography


U-ICC-300

IC Cations Mixture 1

100 mL

Solvent: 2% HNO3
Ammonium (NH4+) .... 400 g/mL
Calcium (Ca2+) ........ 1000 g/mL

U-ICC-310

Lithium (Li ) .................50 g/mL


2+
Magnesium (Mg ).....200 g/mL

IC Cations Mixture 2

Potassium (K ).......... 200 g/mL


+
Sodium (Na ) ............ 200 g/mL

100 mL

Solvent: 0.5% HNO3


+

Ammonium (NH4 ) .... 100 g/mL


Lithium (Li+)................. 10 g/mL

U-ICC-320

Potassium (K+) ............50 g/mL


Sodium (Na+).............100 g/mL

IC Cations Mixture 3

100 mL

Solvent: 2% HNO3
2+

Barium (Ba ).......... 1600 g/mL


Calcium (Ca2+) ........ 1000 g/mL

www.lgcpromochem.com

2+

Magnesium (Mg ).....200 g/mL


2+
Strontium (Sr ) .........600 g/mL

Edition 2003/2004

149

CERTAN - The ampoule in the bottle

CERTAN - The ampoule in the bottle

The CERTAN capillary bottle is sample container with a capillary-opening. It has been specifically

developed for use with and storage of reference solutions. Using the CERTAN bottle the problems
of storing volatile solutions become a thing of the past. Unopened glass ampoules provide an efficient
way of storing volatile standards, but once opened are impossible to reseal and are unsuitable for
further storage. The use of screw cap bottles for volatile standards invariably leads to losses by virtue
of their construction. There is also a higher risk of contamination from the cap itself and from the
insert within the cap.

CERTAN is the solution for solutions!

CERTAN Advantages
- No change in concentration of standard solutions even when open
- Totally secure storage, free of losses
- Minimised risk of contamination
- The filling and removal of aliquots can be easily achieved using a standard GC syringe
- Proven usability from -30C to +50C
- Serial filling is easy with an auto diluter
- Almost impossible to spill.

CERTAN Application Examples


- Supply and storage of LGC Promochem standard solutions
- Storage of standard solutions removed from conventional glass ampoules
- Storage of working stock and standard solutions
- Storage of difficult samples, such as volatile halogen compounds or BTEX aromatics
- Archiving of production samples and extracts
- Transport and storage of ringtest samples.

150

Edition 2003/2004

www.lgcpromochem.com

CERTAN Principle

The properties of the patented CERTAN capillary bottle depend on the unique way in which the glass
bottle, capillary and screw cap closures have been engineered. The 1.2 mm diameter and 28 mm long
capillary works as a re-condensation zone for any of solvent vaporous. Reducing the surface area
inside the cap ensures a more efficient sealing of the bottle. It also minimizes the chance of
contamination by the cap insert.

The CERTAN capillary bottles combines the advantages of a sealed ampoule with the flexibility of a
screw cap bottle or a septum vial.

Storage tests on CERTAN bottles at room temperature showed that after 15 months the loss by

evaporation from the CERTAN bottle was much lower then the loss by evaporation on opening a
flame sealed ampoule. Both cap and insert have been manufactured in materials which have been
tested to ensure they retain their sealing properties, even with such critical solvents such as
Diethylether.

CERTAN Cleaning Protocol


The CERTAN bottle can be easily cleaned using the following method:

A 0.53 mm quartz capillary is inserted into the CERTAN bottle which is then inverted over a solvent
container similar to a wash bottle. (Refer to illustration below). Dry nitrogen from a standard gas
cylinder pressurizes the container forcing the cleaning solvent up the capillary tube spraying the inside
of the bottle and hence thorough cleaning of the bottle should be achieved. The capillary of the

CERTAN bottle itself is simply cleaned by the action of the cleaning solvent draining through. Tests
using different cleaning solvents showed that Toluene was the most effective solvent in cleaning the

CERTAN bottles.

Once the cleaning process is complete and the cleaning solvents, is all used up, the CERTAN bottle
should be dried by flushing with nitrogen and finally placed in a suitable flame proof oven at 400 C for
at least two hours.

Please note that the CERTAN capillary bottles are gamma-irradiated to obtain the brown colour.
However, at a temperature above 270 C the brown colour will disappear without leaving any
residues.

CERTAN bottle
quartz capillary

container for used solvents

dry Nitrogen

wash bottle with solvent

www.lgcpromochem.com

Edition 2003/2004

151

Advice

The manufacturing process of the CERTAN bottle, ensures that as far as possible the bottles are
free of any chemical contamination. However it would be good practice to rinse the bottles out with the
same solvent in which your standards are dissolved in. The bottle should also be checked for any
minute glass particles which may occasionally be found, these can be easily flushed out using dry
nitrogen which has been passed through an activated charcoal filter. In the same way the bottle can
be dried after rinsing with the appropriate solvent.

Care should be taken when removing aliquots from the CERTAN bottle, ensure that there are no
droplets adhering to the end of the needle.

Prior to opening a full CERTAN bottle, check to see if a small column of the solution has migrated
into the capillary, if so this can be returned to the bottle easily by a quick flick of the wrist, as you
would mercury in clinical thermometer.

When replacing the cap onto the CERTAN bottle, it should be firmly tightened so that the top of the
capillary leaves a clear indentation on the insert of the cap.

We also recommend that with new CERTAN bottles the cap be re-tightened after 30 minutes to take
up any slack caused by the initial indentation on the insert.

The CERTAN bottle is manufactured out of high quality Duran glass, and robust in its construction.
However, care should be taken when handling to avoid dropping onto hard surfaces.

CERTAN-The ampoule in the bottle


Code

Product

Unit

DE-CE 01

CERTAN capillary bottle (10 x 1.5 mL)

set

DE-CE 05

CERTAN capillary bottle (5 x 4.5 mL)

set

DE-CE 10

CERTAN capillary bottle (5 x 10 mL)

set

Racks for CERTAN


DE-MIG 13

10 place rack for DE-CE 01

unit

DE-MIG 17

10 place rack for DE-CE 05

unit

DE-MIG 19

10 place rack for DE-CE 10

unit

DE-ENG 416

Plastic shipping container for single DE-CE 01 / DE-CE 05 bottle

unit

DE-ENG 484

Plastic shipping container for single DE-CE 10 bottle

unit

CERTAN wash-bottle
DE-WB 1000

CERTAN wash bottle incl. capillary

each

Trademarks

CERTAN - LGC Promochem GmbH

BCR - IRMM (Institute for Reference Materials and Measurement)


TM

EnviroConcentrates - ULTRA Scientific, Inc.

Standard Reference Materials , SRMs - NIST National Institute of Standards and Technology

CONOSTAN - Conoco Inc.


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Edition 2003/2004

www.lgcpromochem.com

Code number index

Code
number
index
ARC/CL1 ....................14
ARC/CL2 ....................50
ARC/CL4 ....................36
BCR-010.....................86
BCR-017A ..................99
BCR-017B ..................99
BCR-022A ................100
BCR-022B ................100
BCR-023A ................100
BCR-023B ................100
BCR-024B ................100
BCR-024C ................100
BCR-025A ..................99
BCR-025B ..................99
BCR-026.....................86
BCR-027.....................86
BCR-028.....................86
BCR-029.....................86
BCR-030.....................86
BCR-031.....................86
BCR-032.....................56
BCR-033.....................56
BCR-038...................111
BCR-054R ................100
BCR-055...................100
BCR-058...................100
BCR-059A ................100
BCR-059B ................100
BCR-060.....................61
BCR-062.....................58
BCR-063R ..................13
BCR-065.....................64
BCR-074A ................101
BCR-074B ................101
BCR-074C ................101
BCR-075A ................101
BCR-075B ................101
BCR-075C ................101
BCR-089...................104
BCR-090A ................104
BCR-090B ................104
BCR-098...................104
BCR-099...................100
BCR-100.....................58
BCR-101.....................58
BCR-102...................101
BCR-104R ..................68
BCR-105.....................68
BCR-106.....................68
BCR-107.....................68
BCR-108.....................86
BCR-109.....................86
BCR-110.....................86
BCR-112...................115
BCR-113.....................56
BCR-114.....................56
BCR-115.....................55
BCR-121.....................32
BCR-122.....................16
BCR-123A ..................42
BCR-123B ..................42
BCR-126A ..................94
BCR-128...................111
BCR-129.....................60
BCR-150.....................13
BCR-151.....................13
BCR-163.....................20
BCR-178.....................56
BCR-179.....................56
BCR-180.....................64
BCR-181.....................64
BCR-182.....................64
BCR-184.....................19
BCR-185R ..................19
BCR-186.....................19
BCR-187.....................14
www.lgcpromochem.com

BCR-188 .....................14
BCR-189 .....................32
BCR-190R ..................34
BCR-191 .....................49
BCR-262 .....................37
BCR-264 .....................37
BCR-273 .....................63
BCR-274 .....................63
BCR-275 ...................100
BCR-276 ...................100
BCR-278R ..................22
BCR-279 .....................61
BCR-282 .....................14
BCR-283 .....................14
BCR-286A.................101
BCR-286B.................101
BCR-287A.................101
BCR-287B.................101
BCR-288A.................102
BCR-288B.................102
BCR-300 (RM) ............94
BCR-301 (RM) ............94
BCR-302 .....................63
BCR-318 ...................100
BCR-321 ...................102
BCR-322R ................102
BCR-323R ................102
BCR-324R ................102
BCR-325R ................102
BCR-326 ...................102
BCR-327 ...................102
BCR-329 .....................99
BCR-330 .....................99
BCR-331 .....................64
BCR-332 .....................64
BCR-333 .....................64
BCR-334 .....................64
BCR-335 .....................64
BCR-336 .....................64
BCR-349 .....................28
BCR-350 .....................28
BCR-351 ...................102
BCR-352 ...................103
BCR-353 ...................103
BCR-354 ...................103
BCR-355 ...................103
BCR-356 ...................103
BCR-357 ...................103
BCR-358 ...................103
BCR-359 ...................103
BCR-360 ...................103
BCR-361 ...................104
BCR-366R ..................34
BCR-367R ..................34
BCR-375 .....................55
BCR-376 .....................55
BCR-377 .....................33
BCR-378 .....................33
BCR-381 .....................33
BCR-382 .....................32
BCR-383 .....................36
BCR-384 .....................19
BCR-395 .....................68
BCR-396 .....................33
BCR-400 .....................38
BCR-401 .....................37
BCR-402 .....................61
BCR-411 .....................19
BCR-412 .....................19
BCR-420 .....................68
BCR-421 .....................13
BCR-422 .....................28
BCR-423 (RM) ............39
BCR-430 .....................20
BCR-431 .....................36
BCR-444 .....................21
BCR-445 .....................21
BCR-446 .....................34
BCR-447 .....................34
BCR-448 .....................34
BCR-449 .....................69
BCR-450 .....................14
BCR-458 .....................38
BCR-459 .....................38

BCR-460 .................... 64
BCR-463 .................... 28
BCR-464 .................... 28
BCR-465 .................... 33
BCR-466 .................... 33
BCR-467 .................... 34
BCR-471 .................... 33
BCR-472 .................... 33
BCR-474/475 ............. 19
BCR-477 .................... 22
BCR-482 .................... 63
BCR-485 .................... 36
BCR-487 .................... 19
BCR-490 .................. 111
BCR-492-3 ................. 16
BCR-514 .................... 36
BCR-515 .................... 36
BCR-516 .................... 37
BCR-517 .................... 36
BCR-518 .................... 49
BCR-519 .................... 15
BCR-532 (RM) ........... 14
BCR-533 (RM) ........... 15
BCR-534 (RM) ........... 15
BCR-537 .................... 38
BCR-538 .................... 38
BCR-539 .................... 38
BCR-542 .................... 24
BCR-543 .................... 24
BCR-544 .................. 122
BCR-545 .................. 106
BCR-546 .................. 116
BCR-547 .................. 116
BCR-548 .................. 116
BCR-549 .................. 116
BCR-550 .................. 116
BCR-551-2 ............... 117
BCR-553-4 ............... 115
BCR-555 .................. 115
BCR-562 .................. 115
BCR-563 .................... 32
BCR-593 .................... 38
BCR-596 .................... 61
BCR-598 .................... 28
BCR-599 .................... 16
BCR-605 .................. 114
BCR-607 .................... 15
BCR-615 .................. 111
BCR-620 .................. 108
BCR-621 (RM) ......... 108
BCR-623 .................. 108
BCR-626 .................. 122
BCR-627 .................... 29
BCR-648-9 ................. 19
BCR-651 .................... 54
BCR-652 .................... 54
BCR-653 .................... 54
BCR-660 .................... 42
BCR-664 .................... 94
BCR-668 .................... 22
BCR-670 .................... 61
BCR-671 .................... 68
BCR-672 .................... 68
BCR-679 .................... 37
BCR-680 .................... 99
BCR-681 .................... 99
BCR-682 .................... 22
BCR-683 .................... 60
BCR-691 .................. 101
BCR-718 .................... 29
BCR-719 .................... 28
BCR-723 .................. 114
B-MYC0200 ............... 39
B-MYC0220 ............... 39
B-MYC0240 ............... 39
B-MYC0260 ............... 39
B-MYC0280 ............... 39
B-MYC0300 ............... 40
B-MYC0320 ............... 39
B-MYC0320-C............ 39
B-MYC0340 ............... 39
B-MYC0340-C............ 39
B-MYC0360 ............... 39
B-MYC0360-C............ 39

Edition 2003/2004

B-MYC0400................ 39
B-MYC0400-C............ 39
B-MYC0420................ 39
B-MYC0440................ 40
B-MYC0480................ 39
B-MYC0480-C............ 39
B-MYC0490................ 39
B-MYC0490-C............ 39
B-MYC0500................ 39
B-MYC0600................ 40
B-MYC0600-C............ 40
B-MYC0700................ 40
CERERA-011........... 116
CERERA-012........... 116
CERERA-013K ........ 118
CERERA-014........... 116
CERERA-020........... 117
CERERA-021........... 116
CERERA-024S ........ 116
CERERA-025S ........ 116
CERERA-026S ........ 116
CERERA-027S ........ 116
CERERA-028........... 117
CERERA-029........... 118
CERERA-030........... 118
CERERA-037........... 118
CERERB-016........... 116
CERERB-017........... 116
CERERB-018........... 116
CERERB-023........... 116
CERERB-026S ........ 116
CERERB-028S ........ 116
CERERB-029S ........ 116
CERERC-006........... 116
CERERC-011S ........ 116
CERERC-015S ........ 116
CERERC-016........... 116
CERERD-030........... 116
CERERD-035S ........ 116
CERERF-003 ........... 116
CERERF-004S......... 116
CERERF-005S......... 116
CERERG-002 .......... 116
CERERH-003........... 116
CERERH-005S ........ 116
CERERH-011........... 116
CERERH-012S ........ 116
CERERI-003 ............ 117
CERERI-004 ............ 117
CERERI-005 ............ 117
CERERI-009S.......... 117
CERERM-002 .......... 117
CERERM-020 .......... 117
CERERM-022S........ 117
CERERM-023S........ 117
CERERM-024 .......... 117
CERERP-005........... 117
CERERP-030S ........ 117
CERERT-007 ........... 117
CERERT-011 ........... 117
CERERT-012 ........... 117
CERERT-027S......... 117
CERERV-001........... 117
CERERV-002S ........ 117
CON-Ag1000 ............. 77
CON-Ag5000 ............. 77
CON-Al1000............... 75
CON-Al5000............... 75
CON-AM41000........... 79
CON-AM4900............. 79
CON-AM81000........... 79
CON-AM8900............. 79
CON-As100................ 75
CON-B1000 ............... 76
CON-B5000 ............... 76
CON-Ba1000 ............. 75
CON-Ba5000 ............. 75
CON-Be1000 ............. 75
CON-Be5000 ............. 75
CON-Bi1000............... 75
CON-Bi5000............... 75
CON-Ca1000 ............. 76
CON-Ca5000 ............. 76
CON-Cd1000 ............. 76

CON-Cd5000 ............. 76
CON-Cl10................... 80
CON-Cl100................. 80
CON-Cl1000............... 80
CON-Cl10000............. 80
CON-Cl500................. 80
CON-Cl5000............... 80
CON-Cl50000............. 80
CON-Cl-blank............. 80
CON-Co1000 ............. 76
CON-Co5000 ............. 76
CON-Cr1000 .............. 76
CON-Cr5000 .............. 76
CON-Cu1000 ............. 76
CON-Cu5000 ............. 76
CON-D12810 ............. 83
CON-D128100 ........... 83
CON-D12830 ............. 83
CON-D128300 ........... 83
CON-D1285 ............... 83
CON-D12850 ............. 83
CON-D19 Set ............. 84
CON-D19-0 ................ 83
CON-D19410 ............. 83
CON-D194100 ........... 84
CON-D19430 ............. 84
CON-D194300 ........... 84
CON-D1945 ............... 83
CON-D19450 ............. 84
CON-D194500 ........... 84
CON-D194700 ........... 84
CON-D194900 ........... 84
CON-D38100 ............. 83
CON-EBO2016 .......... 81
CON-EBO204 ............ 81
CON-EBO7516 .......... 81
CON-EBO754 ............ 81
CON-Fe1000.............. 76
CON-Fe5000.............. 76
CON-FTIR-OTSBR .... 82
CON-FTIR-OTSPE .... 82
CON-Hg100 ............... 76
CON-In1000 ............... 76
CON-In5000 ............... 76
CON-K1000................ 76
CON-K5000................ 76
CON-La1000 .............. 76
CON-La5000 .............. 76
CON-Li1000 ............... 76
CON-Li5000 ............... 76
CON-Mg1000 ............. 76
CON-Mg5000 ............. 76
CON-Mn1000 ............. 76
CON-Mn5000 ............. 76
CON-Mo1000 ............. 76
CON-Mo5000 ............. 76
CON-Na1000 ............. 77
CON-Na5000 ............. 77
CON-Ni1000............... 76
CON-Ni5000............... 76
CON-P1000................ 76
CON-P5000................ 76
CON-Pb1000.............. 76
CON-Pb5000.............. 76
CON-PS2806 ............. 81
CON-PSCK ................ 81
CON-PSOLV19.......... 81
CON-PSOLV4............ 81
CON-PSSCF.............. 81
CON-PSUFTD ........... 81
CON-PTSM-Set ......... 82
CON-PTSQ-Set ......... 82
CON-S100.................. 80
CON-S1000................ 80
CON-S10000.............. 80
CON-S12410.............. 78
CON-S124100............ 79
CON-S12430.............. 78
CON-S124300............ 79
CON-S12450.............. 78
CON-S124500............ 79
CON-S124900............ 79
CON-S12810.............. 78
CON-S128100............ 79

153

Code number index


CON-S12830 ..............78
CON-S128300 ............79
CON-S12850 ..............78
CON-S128500 ............79
CON-S128900 ............79
CON-S15000 ..............80
CON-S20000 ..............80
CON-S21410 ..............77
CON-S214100 ............78
CON-S21430 ..............77
CON-S214300 ............78
CON-S21450 ..............78
CON-S214500 ............78
CON-S214900 ............78
CON-S21810 ..............77
CON-S218100 ............78
CON-S21830 ..............77
CON-S218300 ............78
CON-S21850 ..............78
CON-S218500 ............78
CON-S218900 ............78
CON-S250 ..................80
CON-S2500 ................80
CON-S25000 ..............80
CON-S30000 ..............80
CON-S40000 ..............80
CON-S50 ....................80
CON-S500 ..................80
CON-S5000 ................80
CON-S50000 ..............80
CON-S750 ..................80
CON-S7500 ................80
CON-Sb1000 ..............75
CON-Sb5000 ..............75
CON-Sblank ...............80
CON-Sc2000 ..............76
CON-Se100 ................76
CON-Si1000 ...............76
CON-Si5000 ...............77
CON-Sn1000 ..............77
CON-Sn5000 ..............77
CON-Sr1000...............77
CON-Sr5000...............77
CON-Ti1000 ...............77
CON-Ti5000 ...............77
CON-V1000 ................77
CON-V5000 ................77
CON-W1000...............77
CON-W5000...............77
CON-Y1000 ................77
CON-Y5000 ................77
CON-Zn1000 ..............77
CON-Zn5000 ..............77
CSIR-MYC 005 ...........39
CSIR-MYC 006 ...........39
CSIR-MYC 007 ...........39
CSIR-MYC 008 ...........39
CSIR-MYC 009 ...........39
CSIR-MYC 013 ...........39
CSIR-MYC 015 ...........39
CSIR-MYC 017 ...........40
CSIR-MYC 019 ...........40
CSIR-MYC 020 ...........40
CSIR-MYC 021 ...........40
CSIR-MYC 024 ...........39
CSIR-MYC 025 ...........39
CSIR-MYC 026 ...........39
CSIR-MYC 027 ...........39
CSIR-MYC 028 ...........39
CSIR-MYC 029 ...........39
CSIR-MYC 030 ...........39
DE-CE 01 .................152
DE-CE 05 .................152
DE-CE 10 .................152
DE-ENG 416.............152
DE-ENG 484.............152
DE-MIG 13................152
DE-MIG 17................152
DE-MIG 19................152
DE-WB 1000 ............152
EC 1.1.........................96
Glass No.4..................96
Glass No.5..................96
Glass No.6..................96

154

Glass No.7 ..................96


Glass No.8 ..................96
IAEA-140OC ...............62
IAEA-140TM ...............62
IAEA-152 ....................15
IAEA-153 ....................14
IAEA-154 ....................15
IAEA-155 ....................14
IAEA-156 ....................61
IAEA-303 ..................124
IAEA-305 ..................124
IAEA-311 ..................124
IAEA-321 ....................15
IAEA-336 ....................63
IAEA-352 ....................31
IAEA-359 ....................37
IAEA-373 ....................61
IAEA-MA-B3/R............31
IAEA-RGTh-1..............90
IAEA-RGU-1 ...............90
IAEA-V-10...................60
IAEA-V-8.....................33
IAEA-V-9.....................61
IBPO002 .....................53
IBPO003 .....................53
IBPO004 .....................53
IBPO005 .....................53
IBPO007 .....................53
IBPO008 .....................53
IBPO009 .....................53
IBPO010 .....................53
IBPO011 .....................53
IBPO012 .....................53
IBPO013 .....................53
IBPO014 .....................53
IBPO015 .....................53
IBPO016 .....................53
IBPO017 .....................53
IC-CTA-FFA-1...........112
IC-CTA-OTL1..............59
IC-CTA-VTL2 ..............60
IC-INCT-MPH-2 ..........63
IC-INCT-TL-1 ........37, 60
IPO F 010....................52
IPO F 170....................52
IRMM-410S0...............35
IRMM-410S1...............35
IRMM-410S2...............35
IRMM-410S3...............35
IRMM-410S4...............35
IRMM-410S5...............35
IRMM-413-0 ................35
IRMM-413-1 ................35
IRMM-413-2 ................35
IRMM-413-3 ................35
IRMM-413-4 ................35
IRMM-413-5 ................35
IRMM-441 ...................71
IRMM-442 ...................71
IRMM-444 ...................21
IRMM-445 ...................21
IRMM-446 ...................21
LGC3000 ....................68
LGC3001 ....................68
LGC3002 ....................68
LGC3003 ....................68
LGC3004 ..................105
LGC4000 ..................119
LGC4001 ..................119
LGC4002 ..................119
LGC4003 ..................119
LGC4004 ..................119
LGC4005 ..................119
LGC4006 ..................119
LGC4007 ..................119
LGC4008 ..................119
LGC4009 ..................119
LGC5000 ....................54
LGC5001 ....................54
LGC5002 ....................54
LGC5003 ....................54
LGC5004 ....................54
LGC5005 ....................54
LGC5100 ....................54

LGC5404.................... 54
LGC5405.................... 54
LGC5406.................... 54
LGC5407.................... 54
LGC5408.................... 54
LGC6147.................... 68
LGC6180 (RM)......... 111
LGC7000.................... 17
LGC7001.................... 17
LGC7003.................... 32
LGC7011.................... 51
LGC7012.................... 51
LGC7013.................... 51
LGC7014.................... 51
LGC7015.................... 51
LGC7016.................... 49
LGC7101.................... 28
LGC7103.................... 49
LGC7104 (RM)........... 13
LGC7105 (RM)........... 49
LGC7106 (RM)........... 13
LGC7107 (RM)........... 49
LGC7111.................... 36
LGC7112.................... 17
LGC7120 (RM)........... 38
LGC7122-23 .............. 38
LGC7130.................... 51
LGC7131.................... 51
LGC7140 (RM)........... 51
LGC7150 (RM)........... 17
LGC7151 (RM)........... 17
LGC7152 (RM)........... 17
LGC7160.................... 22
LGC7162.............. 36, 62
LGC7172 (RM)........... 55
LGC7173 (RM)........... 55
LGC7176.................... 55
LGC7200 (RM)........... 17
LGC7201 (RM)........... 17
LGC7202 (RM)........... 17
LGC7203 (RM)........... 18
LGC7204 (RM)........... 18
LGC7205 (RM)........... 18
LGC7206 (RM)........... 18
LGC7207 (RM)........... 18
LGC7208 (RM)........... 18
LGC7209 (RM)........... 18
LGC7300.................... 52
LGC7301.................... 52
LGC7302.................... 52
LGC7305.................... 52
LGC9000.................. 105
LGC9001.................. 105
LGCQC1001 .............. 41
LGCQC1002 .............. 41
LGCQC1003 .............. 41
LGCQC1004 .............. 41
LGCQC1005 .............. 41
LGCQC1050 .............. 41
MURST-ISS-A2.......... 29
NAMI A-2 ................. 106
NAMI B-2 ................. 106
NAMI(5)/A-2 ............. 106
NAMI(5)/B-2 ............. 106
NIES03....................... 62
NIST-1051B ............. 122
NIST-1052B ............. 122
NIST-1053A ............. 122
NIST-1057B ............. 122
NIST-1059C ............. 122
NIST-1060A ............. 122
NIST-1065B ............. 122
NIST-1066................ 122
NIST-1069B ............. 122
NIST-1070A ............. 122
NIST-1071B ............. 122
NIST-1073B ............. 122
NIST-1075A ............. 122
NIST-1077A ............. 122
NIST-1078B ............. 122
NIST-1079B ............. 122
NIST-1080A ............. 122
NIST-1083.................. 72
NIST-1084a................ 72

Edition 2003/2004

NIST-1085b................ 72
NIST-112b.................. 91
NIST-120c ............ 56, 90
NIST-1216................ 120
NIST-1411.................. 94
NIST-1412.................. 94
NIST-1413.................. 95
NIST-141D ............... 119
NIST-142.................. 119
NIST-143D ............... 119
NIST-148.................. 119
NIST-1515.................. 58
NIST-1544.................. 50
NIST-1546.................. 20
NIST-1547.................. 58
NIST-1548a................ 50
NIST-1549.................. 13
NIST-154c ................ 105
NIST-1563.................. 38
NIST-1566b................ 25
NIST-1567a................ 32
NIST-1568a................ 34
NIST-1570a................ 63
NIST-1573a................ 63
NIST-1575A ............... 58
NIST-1577b................ 19
NIST-1580.................. 70
NIST-1582.................. 70
NIST-1588a................ 29
NIST-1616a................ 70
NIST-1617a................ 70
NIST-1619b................ 70
NIST-1620c ................ 70
NIST-1621e................ 70
NIST-1622e................ 70
NIST-1623c ................ 70
NIST-1630A ............... 64
NIST-1632c ................ 65
NIST-1633b.............. 111
NIST-1634c ................ 69
NIST-1635.................. 65
NIST-1648................ 113
NIST-1649a.............. 114
NIST-165a.................. 95
NIST-17e.................. 121
NIST-180.................... 86
NIST-181.................... 86
NIST-1815a................ 71
NIST-1816a................ 71
NIST-1818a................ 69
NIST-1819a................ 69
NIST-182.................... 86
NIST-1829.................. 72
NIST-183.................... 87
NIST-1830.................. 96
NIST-1831.................. 96
NIST-1834.................. 96
NIST-1835.................. 90
NIST-1836.................. 69
NIST-1837.................. 72
NIST-1838.................. 72
NIST-1839.................. 72
NIST-1845.................. 49
NIST-1846.................. 13
NIST-1848.................. 69
NIST-1866a.............. 110
NIST-1872.................. 98
NIST-1873.................. 98
NIST-1876b.............. 110
NIST-1878a.............. 115
NIST-1879a.............. 115
NIST-1880a................ 92
NIST-1881a................ 92
NIST-1882a................ 92
NIST-1883a................ 92
NIST-1884a................ 92
NIST-1885a................ 92
NIST-1886a................ 92
NIST-1887a................ 93
NIST-1888a................ 93
NIST-1889a................ 93
NIST-193.................... 56
NIST-194.................... 56
NIST-1946.................. 30

NIST-1975................ 112
NIST-198.................... 91
NIST-199.................... 91
NIST-200a.................. 56
NIST-2063a................ 98
NIST-2141................ 119
NIST-2143................ 120
NIST-2144................ 120
NIST-2286.................. 72
NIST-2287.................. 72
NIST-2288.................. 73
NIST-2289.................. 73
NIST-2290.................. 73
NIST-2291.................. 73
NIST-2292.................. 73
NIST-2293.................. 73
NIST-2294.................. 73
NIST-2295.................. 73
NIST-2296.................. 73
NIST-2297.................. 73
NIST-2298.................. 70
NIST-2299.................. 70
NIST-2383.................. 49
NIST-2387.................. 16
NIST-2430.................. 87
NIST-2556................ 105
NIST-2557................ 105
NIST-2567................ 105
NIST-2570................ 108
NIST-2571................ 108
NIST-2572................ 108
NIST-2573................ 108
NIST-2574................ 108
NIST-2575................ 109
NIST-2576................ 109
NIST-2579a.............. 108
NIST-2580................ 109
NIST-2581................ 109
NIST-2582................ 109
NIST-2583................ 115
NIST-2584................ 115
NIST-2586................ 109
NIST-2587................ 109
NIST-2589................ 109
NIST-25d.................... 87
NIST-2678................ 107
NIST-2679a.............. 106
NIST-2681................ 107
NIST-2682b................ 65
NIST-2683b................ 65
NIST-2684b................ 65
NIST-2685.................. 65
NIST-2686.................. 93
NIST-2687.................. 93
NIST-2688.................. 93
NIST-2689................ 112
NIST-2690................ 112
NIST-2691................ 112
NIST-2692b................ 65
NIST-2695.................. 61
NIST-2713.................. 71
NIST-2714.................. 71
NIST-2717a................ 70
NIST-2718.................. 67
NIST-2719.................. 67
NIST-2721.................. 70
NIST-2722.................. 70
NIST-2724b................ 71
NIST-276b.................. 91
NIST-277.................... 87
NIST-2775.................. 66
NIST-2776.................. 66
NIST-2783................ 107
NIST-2890.................. 71
NIST-2975................ 113
NIST-2976.................. 22
NIST-2977.................. 23
NIST-2978.................. 24
NIST-3101A ............. 125
NIST-3102A ............. 125
NIST-3103A ............. 125
NIST-3104A ............. 125
NIST-3105A ............. 126
NIST-3107................ 126

www.lgcpromochem.com

Code number index


NIST-3108 ................126
NIST-3109 ...............126
NIST-3110A ..............126
NIST-3112A ..............126
NIST-3113 ................126
NIST-3114 ................127
NIST-3115A ..............127
NIST-3117A ..............127
NIST-3118 ...............127
NIST-3119 ...............127
NIST-3120 ...............127
NIST-3121 ................127
NIST-3122 ................127
NIST-3124A ..............128
NIST-3126A ..............128
NIST-3127 ...............128
NIST-3128 ................128
NIST-3129 ...............128
NIST-3130A ..............128
NIST-3131A ..............128
NIST-3132 ................129
NIST-3133 ................129
NIST-3134 ................129
NIST-3135A ..............129
NIST-3136 ................129
NIST-3137 ................129
NIST-3138 ................129
NIST-3139A ..............129
NIST-3140 ................129
NIST-3141A ..............130
NIST-3142A ..............130
NIST-3143 ................130
NIST-3144 ................130
NIST-3145A ..............130
NIST-3147A ..............130
NIST-3148 ...............130
NIST-3149 ................130
NIST-3150 ................131
NIST-3151 ................131
NIST-3152A ..............131
NIST-3153A ..............131
NIST-3154 ................131
NIST-3155 ................131
NIST-3156 ................131
NIST-3157A ..............131
NIST-3158A ..............132
NIST-3159 ................132
NIST-3160A ..............132
NIST-3161A ..............132
NIST-3162A ..............132
NIST-3163 ................132
NIST-3164 ................132
NIST-3165 ................132
NIST-3166A ..............132
NIST-3167A ..............133
NIST-3168A ..............133
NIST-3169 ................133
NIST-3181 ................148
NIST-3182 ................148
NIST-3183 ................148
NIST-3185 ................148
NIST-3186 ................148
NIST-330 ....................87
NIST-350A ................121
NIST-351 ..................121
NIST-40H..................121
NIST-600 ....................89
NIST-607 ....................97
NIST-610 ....................97
NIST-611 ....................97
NIST-612 ....................97
NIST-613 ....................97
NIST-614 ....................97
NIST-615 ....................97
NIST-616 ....................98
NIST-617 ....................98
NIST-620 ....................95
NIST-621 ....................95
NIST-670 ....................89
NIST-690 ....................88
NIST-691 ....................88
NIST-692 ....................88
NIST-693 ....................88
NIST-694 ..............56, 90

www.lgcpromochem.com

NIST-696 ....................89
NIST-697 ....................89
NIST-698 ....................89
NIST-699 ....................89
NIST-69b ....................89
NIST-723D................121
NIST-76a ....................91
NIST-77a ....................91
NIST-78a ....................91
NIST-79a ....................86
NIST-81a ....................95
NIST-83D..................121
NIST-84K ..................121
NIST-886 ....................90
NIST-887 ....................91
NIST-888 ....................91
NIST-889 ....................91
NIST-89 ......................94
NIST-92 ......................94
NIST-93a ....................94
NIST-951 ..........121, 123
NIST-952 ..................123
NIST-975a ................123
NIST-977 ..................123
NIST-978A ................123
NIST-979 ..................123
NIST-981 ..................123
NIST-986 ..................123
NIST-987 ..........121, 123
NIST-991 ..................123
NIST-994 ..................123
NIST-997 ..................124
NIST-999A ................121
NIST-RM 8411..........110
NIST-RM 8412......33, 61
NIST-RM 8413......33, 61
NIST-RM 8414............20
NIST-RM 8415............49
NIST-RM 8418............32
NIST-RM 8432............33
NIST-RM 8433............33
NIST-RM 8435............13
NIST-RM 8436............32
NIST-RM 8437............32
NIST-RM 8438............32
NIST-RM 8441............33
NIST-RM 8455............87
NIST-RM 8495..........105
NIST-RM 8496..........105
NIST-RM 8505............71
NIST-RM 8506a..........71
NIST-RM 8507............72
NIST-RM 8509............72
NIST-RM 8510............72
NIST-RM 8680..........109
NJV 94-1.....................67
NJV 94-2.....................67
NJV 94-3.....................67
NJV 94-4.....................67
NJV 94-5.....................67
NRCCARP-2...............31
NRCCRM-DA-d ..........27
NRCCRM-dcSTX........26
NRCCRM-GTX14b .....26
NRCCRM-GTX23b .....26
NRCCRM-GTX5b .......26
NRCCRM-MUS-b .......25
NRCCRM-NEO-b........26
NRCCRM-OA-b ..........26
NRCCRM-STX-d ........26
NRCCRM-STXdiAc.....26
NRCDOLT-3 ...............31
NRCDORM-2..............31
NRCLUTS-1................25
NRCTORT-2...............25
NRMGBW03118.........90
NRMGBW03119.........90
NRMGBW03120.........90
NRMGBW03132.........95
NRMGBW03201a.......93
NRMGBW06101a.....121
NRMGBW06102.......121
NRMGBW06103a.....121
NRMGBW06104.......121

NRMGBW06105b .... 121


NRMGBW06106a .... 121
NRMGBW06107a .... 121
NRMGBW06108 ...... 121
NRMGBW06109 ...... 121
NRMGBW06110 ...... 121
NRMGBW06501 ........ 57
NRMGBW06502 ........ 57
NRMGBW06503 ........ 57
NRMGBW07213 ........ 88
NRMGBW07218a ...... 88
NRMGBW07235 ........ 89
NRMGBW07236 ........ 89
NRMGBW07237 ........ 86
NRMGBW07238 ........ 90
NRMGBW07239 ........ 90
NRMGBW07240 ........ 87
NRMGBW07241 ........ 87
NRMGBW07261 ........ 87
NRMGBW07262 ........ 87
NRMGBW07263 ........ 87
NRMGBW07264 ........ 88
NRMGBW07265 ........ 88
NRMGBW07266 ........ 88
NRMGBW07602 ........ 59
NRMGBW07603 ........ 59
NRMGBW07604 ........ 59
NRMGBW07605 .. 37, 60
NRMGBW08401 ...... 112
NRMGBW08403 ...... 112
NRMGBW08501 ........ 58
NRMGBW08503 ........ 32
NRMGBW08508 ........ 34
NRMGBW08510 ........ 34
NRMGBW08511 ........ 34
NRMGBW08512 ........ 34
NRMGBW08551 ........ 20
NRMGBW08552 ........ 20
NRMGBW08571 ........ 22
NRMGBW08572 ........ 25
NRMGBW10001 ........ 52
NRMGBW10002 ........ 52
NRMGBW10003 ........ 52
NRMGBW10004 ........ 52
NRMGBW10005 ........ 52
NRMGBW11101c ...... 65
NRMGBW11102c ...... 65
NRMGBW11103b ...... 65
NRMGBW11104b ...... 66
NRMGBW11105a ...... 66
NRMGBW11106a ...... 67
NRMGBW11107b ...... 66
NRMGBW11108b ...... 66
NRMGBW11109b ...... 66
NRMGBW11110b ...... 66
NRMGBW11111a ...... 66
NRMGBW11112a ...... 66
NRMGBW11113a ...... 66
NRMGBW11201 ........ 73
NRMGBW11202 ........ 73
RH36976.................... 39
RTC-CRM002 .......... 107
RTC-CRM004 .......... 107
RTC-CRM006 .......... 109
RTC-CRM009 .......... 110
RTC-CRM010 .......... 110
RTC-CRM011 .......... 110
RTC-CRM013 .......... 109
RTC-CRM014 .......... 115
RTC-CRM017 .......... 109
RTC-CRM101 .......... 110
RTC-CRM920 ............ 69
Sand No.1 .................. 95
Sand No.6 .................. 95
Sand No.8 .................. 95
Sand No.9 .................. 95
SGT 10....................... 97
SGT 10-P ................... 97
SGT 11....................... 97
SGT 11-P ................... 97
SLV DIET A ............... 50
SLV DIET B ............... 50
SLV DIET C ............... 50
SLV DIET D ............... 50

Edition 2003/2004

SLV DIET E................ 51


SLV DIET F................ 51
SLV FUNGUS ............ 37
SMRD 2000................ 20
SS99850-0 ................. 74
SS99851-0 ................. 74
SS99852-0 ................. 74
SS99853-0 ................. 74
SS99854-0 ................. 74
SS99856-0 ................. 74
SS99857-0 ................. 70
SS99858-0 ................. 70
SS99859-0 ................. 68
SS99860-0 ................. 69
SS99861-0 ................. 69
SS99862-0 ................. 69
SS99863-0 ................. 69
SS99864-0 ................. 74
SS99865-0 ................. 74
STA 003 ..................... 54
U-ECK-003............... 134
U-ECK-004............... 134
U-ECK-005............... 134
U-ECK-011............... 135
U-ECK-012............... 134
U-ECK-013............... 134
U-ECK-014............... 135
U-ECK-015............... 135
U-ECK-019............... 135
U-ECK-020............... 134
U-ECK-022............... 135
U-ECK-023............... 135
U-ECK-024............... 134
U-ECK-025............... 135
U-ECK-026............... 134
U-ECK-027............... 134
U-ECK-028............... 135
U-ECK-029............... 134
U-ECK-030............... 135
U-ECK-033............... 134
U-ECK-034............... 135
U-ECK-038............... 135
U-ECK-042............... 135
U-ECK-047............... 135
U-ECK-048............... 134
U-ECK-050............... 135
U-ECK-051............... 134
U-ECK-056............... 134
U-ECK-080............... 135
U-ECK-081............... 135
U-ECK-082............... 134
U-FLBA-001 ............... 45
U-FLBA-002 ............... 45
U-FLBA-003 ............... 45
U-FLBA-004 ............... 45
U-FLBA-006 ............... 45
U-FLBA-007 ............... 45
U-FLBA-008 ............... 45
U-FLBA-011 ............... 45
U-FLBA-012 ............... 45
U-FLBA-013 ............... 45
U-FLBA-014 ............... 45
U-FLBA-015 ............... 45
U-FLBA-016 ............... 45
U-FLBA-017 ............... 45
U-FLBA-018 ............... 45
U-FLBA-021 ............... 44
U-FLBA-022 ............... 45
U-FLBA-026 ............... 45
U-FLBA-027 ............... 45
U-FLBA-028 ............... 45
U-FLBA-030 ............... 44
U-FLBA-031 ............... 45
U-FLBA-032 ............... 45
U-FLBA-034 ............... 44
U-FLBA-035 ............... 45
U-FLBA-036 ............... 45
U-FLBA-037 ............... 45
U-FLBA-038 ............... 45
U-FLBA-042 ............... 46
U-FLBA-043 ............... 46
U-FLMS-010............... 47
U-FLMS-012............... 44
U-FLMS-013............... 44

U-FLMS-014............... 46
U-FLMS-015............... 45
U-FLMS-016............... 43
U-FLMS-017............... 44
U-FLMS-018............... 43
U-FLMS-019............... 47
U-FLMS-020............... 47
U-FLMS-021............... 46
U-FLMS-022............... 44
U-FLMS-023............... 44
U-FLMS-024............... 46
U-FLMS-026............... 47
U-FLMS-035............... 46
U-FLPK-001 ............... 47
U-FLPK-002 ............... 52
U-FLPK-003 ............... 47
U-FLPK-004 ............... 47
U-FLPK-005 ............... 48
U-FLPK-007 ............... 52
U-FLSA-001 ............... 43
U-FLSA-002 ............... 43
U-FLSA-003 ............... 44
U-FLSA-004 ............... 46
U-FLSA-005 ............... 43
U-FLSA-006 ............... 43
U-FLSA-007 ............... 47
U-FLSA-008 ............... 44
U-FLSA-009 ............... 46
U-FLSA-010 ............... 43
U-FLSA-011 ............... 43
U-FLSA-012 ............... 47
U-FLSA-013 ............... 44
U-FLSA-014 ............... 45
U-FLSA-015 ............... 47
U-FLSA-016 ............... 43
U-FLSA-017 ............... 43
U-FLSA-018 ............... 44
U-FLSA-019 ............... 46
U-FLSA-020 ............... 43
U-FLSA-021 ............... 43
U-FLSA-022 ............... 47
U-FLSA-023 ............... 44
U-FLSA-024 ............... 46
U-FLSA-025 ............... 43
U-FLSA-026 ............... 43
U-FLSA-027 ............... 47
U-FLSA-028 ............... 44
U-FLSA-029 ............... 45
U-FLSA-030 ............... 47
U-FLSA-031 ............... 44
U-FLSA-032 ............... 46
U-FLSA-033 ............... 46
U-FLSA-034 ............... 44
U-FLSA-035 ............... 45
U-FLSA-036 ............... 43
U-FLSA-037 ............... 47
U-FLSA-038 ............... 46
U-FLSA-039 ............... 44
U-FLSA-040 ............... 45
U-FLSA-041 ............... 44
U-FLSA-046 ............... 44
U-FLSA-047 ............... 46
U-FLSA-048 ............... 46
U-FLSA-049 ............... 44
U-FLSA-050 ............... 45
U-FLSA-051 ............... 44
U-FLSA-052 ............... 47
U-FLSA-053 ............... 46
U-FLSA-054 ............... 44
U-FLSA-055 ............... 45
U-FLSA-056 ............... 44
U-FLSA-057 ............... 47
U-FLSA-058 ............... 46
U-FLSA-059 ............... 44
U-FLSA-062 ............... 45
U-FLSA-063 ............... 46
U-FLSA-064 ............... 46
U-FLSA-065 ............... 46
U-FLSA-066 ............... 43
U-FLSA-067 ............... 46
U-FLSA-068 ............... 46
U-FLSA-069 ............... 46
U-FLSA-070 ............... 46
U-FLSA-071 ............... 46

155

Code number index


U-FLSA-072................43
U-FLSA-073................43
U-FLSA-074................45
U-FLSA-076................45
U-FLSA-077................46
U-FLSA-078................46
U-FLSA-079................46
U-FLSA-080................43
U-FLSA-081................46
U-FLSA-082................46
U-FLSA-083................47
U-FLSA-084................46
U-FLSA-085................46
U-FLSA-086................43
U-FLSA-087................43
U-FLSA-088................45
U-FLSA-089................44
U-FLSA-090................44
U-FLSA-091................43
U-FLSA-092................44
U-FLSA-093................44
U-FLSA-094................43
U-FLSA-095................44
U-FLSA-096................44
U-FLSA-097................43
U-FLSA-098................43
U-FLSA-100................43
U-FLSA-101................43
U-FLSA-104................44
U-FLSA-105................44
U-FLSA-106................43
U-FLSA-107................43
U-FLSA-109................43
U-FLSA-110................43
U-FLSA-113................43
U-FLSA-114................46
U-FLSA-115................43
U-FLSA-117................44
U-FLSA-118................44
U-FLSA-119................46
U-FLSA-120................45
U-FLSA-121................43
U-FLSA-125................47
U-FLSA-127................46
U-FLSA-130................43
U-FLSA-131................46
U-FLSA-132................43
U-FLSA-134................44
U-FLSA-135................44
U-FLSA-136................46
U-FLSA-137................45
U-FLSA-138................43
U-FLSA-142................47
U-FLSA-144................46
U-FLSA-147................44
U-FLSA-148................44
U-IAA-003 .................141
U-IAA-004 .................140
U-IAA-005 .................140
U-IAA-011 .................142
U-IAA-012 .................141
U-IAA-013 .................140
U-IAA-014 .................142
U-IAA-015 .................141
U-IAA-016 .................142
U-IAA-019 .................142
U-IAA-020 .................140
U-IAA-022 .................142
U-IAA-023 .................143
U-IAA-024 .................140
U-IAA-025 .................141
U-IAA-026 .................141
U-IAA-027 .................140
U-IAA-028 .................141
U-IAA-029 .................140
U-IAA-030 .................143
U-IAA-031 .................141
U-IAA-032 .................141
U-IAA-033 .................140

156

U-IAA-034 .................142
U-IAA-038 .................142
U-IAA-039 .................143
U-IAA-040 .................143
U-IAA-041 .................141
U-IAA-042 .................141
U-IAA-047 .................142
U-IAA-048 .................140
U-IAA-049 .................141
U-IAA-050 .................142
U-IAA-051 .................140
U-IAA-052 .................142
U-IAA-055 .................140
U-IAA-056 .................140
U-IAA-057 .................141
U-IAA-058 .................140
U-IAA-059 .................142
U-IAA-060 .................141
U-IAA-062 .................142
U-IAA-063 .................141
U-IAA-064 .................141
U-IAA-065 .................142
U-IAA-066 .................140
U-IAA-067 .................141
U-IAA-068 .................140
U-IAA-070 .................143
U-IAA-073 .................142
U-IAA-074 .................142
U-IAA-080 .................141
U-IAA-081 .................142
U-IAA-082 .................141
U-IAA-083 .................140
U-IAA-090 .................142
U-IAA-092 .................142
U-IAA-203 .................137
U-IAA-204 .................136
U-IAA-205 .................136
U-IAA-211 .................138
U-IAA-212 .................137
U-IAA-213 .................136
U-IAA-214 .................138
U-IAA-215 .................138
U-IAA-216 .................139
U-IAA-219 .................138
U-IAA-220 .................136
U-IAA-221 .................138
U-IAA-222 .................139
U-IAA-223 .................139
U-IAA-224 .................136
U-IAA-225 .................137
U-IAA-226 .................137
U-IAA-227 .................136
U-IAA-228 .................138
U-IAA-229 .................136
U-IAA-230 .................139
U-IAA-231 .................137
U-IAA-232 .................137
U-IAA-233 .................136
U-IAA-234 .................138
U-IAA-237 .................138
U-IAA-238 .................138
U-IAA-239 .................139
U-IAA-240 .................139
U-IAA-241 .................138
U-IAA-242 .................137
U-IAA-244 .................138
U-IAA-245 .................138
U-IAA-246 .................138
U-IAA-247 .................138
U-IAA-248 .................136
U-IAA-249 .................137
U-IAA-250 .................139
U-IAA-251 .................136
U-IAA-252 .................139
U-IAA-255 .................136
U-IAA-256 .................136
U-IAA-257 .................137
U-IAA-258 .................136
U-IAA-259 .................138

U-IAA-260 ................ 137


U-IAA-262 ................ 138
U-IAA-263 ................ 136
U-IAA-264 ................ 137
U-IAA-265 ................ 139
U-IAA-266 ................ 136
U-IAA-267 ................ 137
U-IAA-268 ................ 136
U-IAA-269 ................ 139
U-IAA-270 ................ 139
U-IAA-271 ................ 137
U-IAA-272 ................ 137
U-IAA-273 ................ 139
U-IAA-274 ................ 139
U-IAA-275 ................ 138
U-IAA-277 ................ 137
U-IAA-278 ................ 138
U-IAA-279 ................ 137
U-IAA-280 ................ 137
U-IAA-281 ................ 139
U-IAA-282 ................ 137
U-IAA-283 ................ 136
U-IAA-290 ................ 139
U-IAA-292 ................ 139
U-ICC-001................ 148
U-ICC-002................ 148
U-ICC-003................ 148
U-ICC-004................ 148
U-ICC-005................ 148
U-ICC-006................ 148
U-ICC-007................ 148
U-ICC-010................ 148
U-ICC-011................ 148
U-ICC-012................ 148
U-ICC-013................ 148
U-ICC-101................ 149
U-ICC-102................ 149
U-ICC-103................ 149
U-ICC-104................ 149
U-ICC-105................ 149
U-ICC-106................ 149
U-ICC-107................ 149
U-ICC-108................ 149
U-ICC-200................ 148
U-ICC-210................ 148
U-ICC-300................ 149
U-ICC-310................ 149
U-ICC-320................ 149
U-ICK-230A.............. 144
U-ICM-202................ 145
U-ICM-203................ 145
U-ICM-204................ 145
U-ICM-205................ 145
U-ICM-211................ 146
U-ICM-212................ 146
U-ICM-213................ 146
U-ICM-215................ 146
U-ICM-221................ 146
U-ICM-223........ 146, 147
U-ICM-224........ 146, 147
U-ICM-231................ 144
U-ICM-232................ 144
U-ICM-233................ 144
U-ICM-234................ 144
U-ICM-235................ 144
U-ICM-237................ 145
U-ICM-238................ 145
U-ICM-240................ 145
U-ICM-241................ 145
U-ICM-242................ 145
U-ICM-243................ 145
U-ICM-245................ 145
U-ICM-601................ 146
U-ICM-602................ 146
U-ICM-603................ 146
U-ICM-604................ 146
U-ICM-605................ 146
U-ICM-607................ 147
U-ICM-611................ 147

Edition 2003/2004

U-ICM-642................ 144
U-ICP-003 ................ 128
U-ICP-003-5 ............. 128
U-ICP-004 ................ 126
U-ICP-004-5 ............. 126
U-ICP-005 ................ 126
U-ICP-005-5 ............. 126
U-ICP-011 ................ 131
U-ICP-011-5 ............. 131
U-ICP-012 ................ 128
U-ICP-012-5 ............. 128
U-ICP-013 ................ 125
U-ICP-013-5 ............. 125
U-ICP-014 ................ 131
U-ICP-014............... 131
U-ICP-014-5............ 131
U-ICP-014-5 ............. 131
U-ICP-015 ........ 129, 147
U-ICP-015-5 ............. 129
U-ICP-016 ................ 131
U-ICP-016-5 ............. 131
U-ICP-019 ................ 130
U-ICP-019-5 ............. 130
U-ICP-020 ................ 126
U-ICP-020-5 ............. 126
U-ICP-021 ................ 130
U-ICP-021-5 ............. 130
U-ICP-022 ........ 132, 145
U-ICP-022-5 ............. 132
U-ICP-023 ................ 132
U-ICP-023-5 ............. 132
U-ICP-024 ................ 126
U-ICP-024-5 ............. 126
U-ICP-025 ................ 129
U-ICP-025-5 ............. 129
U-ICP-026 ................ 128
U-ICP-026-5 ............. 128
U-ICP-027 ................ 126
U-ICP-027-5 ............. 126
U-ICP-028 ........ 129, 145
U-ICP-028-5 ............. 129
U-ICP-029 ................ 127
U-ICP-029-5 ............. 127
U-ICP-030 ................ 133
U-ICP-030-5 ............. 133
U-ICP-031 ................ 127
U-ICP-031-5 ............. 127
U-ICP-032 ................ 127
U-ICP-032-5 ............. 127
U-ICP-033 ................ 125
U-ICP-033-5 ............. 125
U-ICP-034 ................ 130
U-ICP-034-5 ............. 130
U-ICP-037 ................ 130
U-ICP-037-5 ............. 130
U-ICP-038 ................ 131
U-ICP-038-5 ............. 131
U-ICP-039 ................ 133
U-ICP-039-5 ............. 133
U-ICP-040 ................ 133
U-ICP-040-5 ............. 133
U-ICP-041 ................ 129
U-ICP-041-5 ............. 129
U-ICP-042 ................ 129
U-ICP-042-5 ............. 129
U-ICP-044 ................ 130
U-ICP-044-5 ............. 130
U-ICP-045 ................ 130
U-ICP-046 ................ 129
U-ICP-046-5 ............. 129
U-ICP-047 ................ 131
U-ICP-047-5 ............. 131
U-ICP-048 ................ 126
U-ICP-048-5 ............. 126
U-ICP-049 ................ 128
U-ICP-049-5 ............. 128
U-ICP-050 ................ 132
U-ICP-050-5 ............. 132

U-ICP-051 125, 145, 146,


147
U-ICP-051-5 ............. 125
U-ICP-052 ................ 131
U-ICP-052-5 ............. 131
U-ICP-055 ................ 126
U-ICP-055-5 ............. 126
U-ICP-056 ................ 125
U-ICP-056-5 ............. 125
U-ICP-057 ................ 128
U-ICP-057-5 ............. 128
U-ICP-058 ................ 126
U-ICP-059 ................ 130
U-ICP-059-5 ............. 130
U-ICP-060 ................ 129
U-ICP-060-5 ............. 129
U-ICP-062 ................ 130
U-ICP-062-5 ............. 130
U-ICP-063 ................ 127
U-ICP-063-5 ............. 127
U-ICP-064 ................ 127
U-ICP-064-5 ............. 127
U-ICP-065 ................ 131
U-ICP-065-5 ............. 131
U-ICP-066 ................ 127
U-ICP-066-5 ............. 127
U-ICP-067 ................ 128
U-ICP-067-5 ............. 128
U-ICP-068 ................ 127
U-ICP-068-5 ............. 127
U-ICP-069 ................ 132
U-ICP-069-5 ............. 132
U-ICP-070 ................ 132
U-ICP-070-5 ............. 132
U-ICP-071 ................ 128
U-ICP-071-5 ............. 128
U-ICP-072 ................ 127
U-ICP-072-5 ............. 127
U-ICP-073 ................ 131
U-ICP-073-5 ............. 131
U-ICP-074 ................ 132
U-ICP-074-5 ............. 132
U-ICP-075 ................ 130
U-ICP-075-5 ............. 130
U-ICP-077 ................ 128
U-ICP-077-5 ............. 128
U-ICP-078 ................ 129
U-ICP-078-5 ............. 129
U-ICP-079 ................ 127
U-ICP-079-5 ............. 127
U-ICP-080 ................ 129
U-ICP-080-5 ............. 129
U-ICP-081 ................ 132
U-ICP-081-5 ............. 132
U-ICP-082 ................ 128
U-ICP-082-5 ............. 128
U-ICP-083 ................ 126
U-ICP-083-5 ............. 126
U-ICP-090 ................ 132
U-ICP-090-5 ............. 132
U-ICP-092 ................ 132
U-ICP-092-5 ............. 132
U-IMS-100 ................ 148
U-IMS-102 ................ 147
U-IMS-103 ................ 147
U-IMS-104 ................ 147
U-IMS-105 ................ 147
U-IMS-110 ................ 147
U-IMS-111 ................ 147
U-IMS-112 ................ 147
U-IMS-113 ................ 147
U-IMS-114 ................ 147
U-IMS-115 ................ 148
U-IQC-007................ 144
U-IQC-019................ 144
U-IQC-026................ 144
VDA 001-4.................. 99

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