Heat and Thermal Energy

When scientists originally studied thermodynamics, they were really studying heat andthermal energy. Heat can do anything: move from one area to another, get atoms excited, and even increase energy. Did we say energy? That's what heat is. When you increase the heat in a system, you are really increasing the amount of energy in the system. Now that you understand that fact, you can see that the study of thermodynamics is the study of the amount of energy moving in and out of systems.

Heat of Atoms
Now all of this energy is moving around the world. You need to remember that it all happens on a really small scale. Energy that is transferred is at an atomic level. Atoms and molecules are transmitting these tiny amounts of energy. When heat moves from one area to another, it's because millions of atoms and molecules are working together. Those millions of pieces become the energy flow throughout the entire planet.

Heat Movement
Heat moves from one system to another because of differences in the temperaturesof the systems. If you have two identical systems with equal temperatures, there will be no flow of energy. When you have two systems with different temperatures, the energy will start to flow. Air mass of high pressure forces large numbers of molecules into areas of low pressure. Areas of high temperature give off energy to areas with lower temperature. There is a constant flow of energy throughout the universe. Heat is only one type of that energy.

Increasing Energy and Entropy

Another big idea in thermodynamics is the concept of energy that changes the freedom of molecules. For example, when you change the state of a system (solid, liquid, gas), the atoms and/or molecules have different arrangements and degrees of freedom to move. That increase in freedom is called entropy.

Atoms are able to move around more and there is more activity. That increase in freedom (also called randomness) is an increase in entropy.
Thermodynamics is a branch of physics which deals with the energy and work of a system. It was born in the 19th century as scientists were first discovering how to build and operate steam engines. Thermodynamics deals only with the large scale response of a system which we can observe and measure in experiments. Small scale gas interactions are described by the kinetic theory of gases. The methods complement each other; some principles are more easily understood in terms of thermodynamics and some principles are more easily explained by kinetic theory. There are three principal laws of thermodynamics which are described on separate slides. Each law leads to the definition of thermodynamic properties which help us to understand and predict the operation of a physical system. We will present some simple examples of these laws and properties for a variety of physical systems, although we are most interested in thermodynamics in the study of propulsion systems and high speed flows. Fortunately, many of the classical examples of thermodynamics involve gas dynamics. Unfortunately, the numbering system for the three laws of thermodynamics is a bit confusing. We begin with the zeroth law. The zeroth law of thermodynamics involves some simple definitions of thermodynamic equilibrium. Thermodynamic equilibrium leads to the large scale definition of temperature, as opposed to the small scale definition related to the kinetic energy of the molecules. The first law of thermodynamics relates the various forms of kinetic and potential energy in a system to the work which a system can perform and to the transfer of heat. This law is sometimes taken as the definition of internal energy, and introduces an additional state variable, enthalpy. The first law of thermodynamics allows for many possible states of a system to exist. But experience indicates that only certain states occur. This leads to the second law of thermodynamics and the definition of another state variable called entropy. The second law stipulates that the total entropy of a system plus its environment cannot decrease; it can remain constant for a reversible process but must always increase for an irreversible process.