Daily Practice Problems

Target IIT ENTRANCE 2014

PH YSICAL CH EM ISTRY

CLASS : XII(N1, N2 & N) MARKS : 24 TIME : 30 MIN DPP. NO.-6 Single correct : Q Q.1 The rate of the simple reaction 2NO + O2 2NO2, when the volume of the reaction vessel is doubled. [2] (A) Will grow eight times of its initial rate (C) Will grow four times of its initial rate Q.2 (B*) Reduce to one-eight of its initial rate (D) Reduce to one-fourth of its initial rate

The initial rate of zero order reaction of the gaseous reaction A(g) 2B(g) is 102 M min1. If the initial concentration of A is 0.1 M, what would be the concnetration of B after 60 sec.? [2] (A) 0.09 M (B) 0.01 M (C*) 0.02 M (D) None of these Consider the following reaction 2A(g) 3B(g) + C(g). Starting with pure A having pressure 2atm initially, the total pressure is exactly doubled in 2hrs. The possible order of reaction is [2] (A*) zero (B) first (C) second (D) third For the gaseous phase reaction : A(g) between [CA is : dt dt dt Concentration of reactant A, nA dn
A

Q.3

Q.4

products, occurring at constant volume the correct relation [2] Moles of reactant A, PA dC (B)
A A

dCA

dnA

and

dPA

Partial pressure of reactant A] dP RT 1 dn

A

dC A (A) dt dC (C*) Q.5

dP

dt
A

dt
A

1 dP

1 dn

dt dC (D)

dt 1 dn

V dt 1 dP
A

RT dt V dt dt V dt V dt The rate constant for the dissociation of N2O5 2N2O5 4NO2+O2 is 3.0 105 sec1. if the rate is 2.4 105 mol litre1 sec1, then the concentration of N2O5 (in mol litre1 ) is (A) 1.4 (B) 1.2 (C) 0.004 (D*) 0.8

dt

[2]

Q.6

The theoretically computed equilibrium constant for the polymerisation of formaldehyde to glucose in aqueous solution 6 HCHO C6H12O6 24 is 1.0 10 . If 1 M - solution of glucose was taken, what should be the equilibrium concentration of formaldehyde? [2]
1/ 6

(A) 6.0 10 M

(B*) 1.0 10 M

(C) 1.0 10 M

(D)

1 6

104 M

More than one correct : Q.7 In a chemical reaction A(g) is converted to B(g), following observation is made. Identify the correct statement(s). [3] PB 8 6 4 2 10 20 PA 30 time (min.)

1 (A*) Chemical reaction should be 2 A(g) B(g). (B) t1/2 of the reaction is independent of initial partial pressure of A. (C*) Reaction must be complex reaction. (D*) Time of completion for the reaction is 40 minutes. Q.8 For the two reactions Reaction I : A B following curves are plotted
1M [A] [C]

[3] Reaction II : C D

0.5M

60 [A]

30

[C] time (min.)

which of the following is/are true (A*) (t100%)reaction I = 2 3 (t100%)reaction II (B*) [A] = [C] at t = 3 4 minutes

(C*) When [B] = [A] at that time [C] = 2[D] (D*) If both [A]0 & [C]0 are 1M then (t50%)I = 1 (t ) 3 50% II

Subjective : [2] Q.9 For a zero order chemical reaction, 2NH3 (g) N2 (g) + 3H2 (g) rate of reaction = 0.1 atm / sec. Initially only NH3 is present & its pressure = 3 atm. Calculate total pressure at t = 10 sec. [Ans. 5]

Q.10

It is found that in 11.2L at 0C and 1 atm, of any gaseous compound of 'X', there is never less than 15.5 gm of 'X'. It is also found that 11.2 L of vapours of 'X' at 0C and 1 atm, weighs 62 gm. The atomicity of 'X' is : [Ans. 0004] [4]

FROM TEACHERS CORNER :

THE DIFFERENCE BETWEEN ALMOST RIGHT AND RIGHT IS VERY LARGE. IF YOU CAN FIX THAT YOU ARE SURE TO GET SUCCEED.

DPP ANALYSIS TOOL (TA) IIT-JEE preparation involves a continuous & rigorous analysis of your attempts of the questions. Evaluate your DPP performance using the below tool to identify your weak areas. Make it a habit to increase your chances of getting selected in IIT JEE. Analysis Key Topics: Sub-Topics: CK - Chemical Kinetics CE - Chemical Equilibrium MC -Mole Concept

(i) First Order Reaction (FOR) (iii) Calculation of Order of Reaction (ROC) (v) Zero Order Reaction (ZOR) (vii) Instantaneous Rate of Reaction (IROR) E - Easy, (i) (ii) (iii) (iv) (v) (vi) M-Medium,

(ii) Rate Law (RL) (iv) Calculation of Equilibrium constant (CEC) (vi) Atomic Weight (AW)

Level : Category:

D-Difficult

(DFB): Direct formula based (FI):Factual Info Based Tricky/Googly (T) : Mistake prone question Mixed concepts (MCB) : Based on more than one concept Advanced Learning (AL) : Above JEE level, useful for understanding Theory Based (TB)
1 CK RL E DFB 2 CK ZOR E DFB 3 CK ROC E DFB 4 CK IROR E DFB 5 CK FOR E DFB 6 CE CEC E DFB 7 CK ROC M MCB 8 CK ROC M DFB 9 CK ZOR E DFB 10 MC AW D DFB

Q.NO. TOPIC SUB TOPIC LEVEL CATEGORY EVALUATION