Product Stewardship Summary

MURIATIC ACID (AQUEOUS HYDROCHLORIC ACID)

BURNER GRADE

Product Overview
PPG produces burner grade muriatic acid, or aqueous hydrochloric acid at several plants across North America. This acid is produced on dedicated lines to create a quality product that is ideal for applications in which a reliable, tightly specified, high purity acid is essential to the final product.

Chemical Identity
Names: CAS Number: Chemical Formula: Molecular Weight: Description: Hydrochloric Acid, Aqueous Hydrochloric Acid, Muriatic Acid, HCl 7647-01-0 HCl, aqueous 36.46 Muriatic acid is a clear, colorless to slightly yellow liquid and has a pungent irritating odor. It is a strong, highly corrosive acid. It is available from PPG as an aqueous solution of hydrogen chloride in several concentrations.

Production
PPG produces aqueous hydrochloric acid, or muriatic acid, directly on dedicated burner units. This burner acid is produced from chlorine and hydrogen from the chlor-alkali process to provide a reliable supply of high quality, pure acid. In this process, hydrogen and chlorine are passed through a burner nozzle and ignited in a graphite combustion chamber to produce clean, high quality gaseous hydrochloric acid. H2 + Cl2 2HCl

The gas is then cooled, absorbed in demineralized water, and diluted to specified concentrations, or degrees Baum. The relationship between these is shown in the following table.
Approximate HCl Concentration 26.5 % - 29.5% 29.0 % - 31.0% 31.5 % - 32.9% 35.2 % - 36.2% 37.1% - 38.0% Degrees Baum 18 19 20 22 23

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Product Stewardship Summary

Muriatic Acid (Aqueous Hydrochloric Acid) Edition 4.0

Uses
As one of the common mineral acids, muriatic acid has a variety of merchant uses. It is commonly used as a strong non-oxidizing acid in industrial segments. The largest of these are in food processing, oil well acidizing, chemical production, and steel pickling. PPGs burner-grade muriatic acid makes it ideal for consumption where quality and purity is a key issue in the final product. With all downstream applications, appropriate registrations and/or approvals may be required. The role of muriatic acid in these end uses is described below: Steel and Metals ProducersThe steel and metal industry use muriatic acid for pickling steel to remove mill scale (or surface oxides). Most steel is also cleaned, or fluxed, in acid before galvanizing, tinning, and other coating applications. Petroleum and Natural GasThe oil and gas industry use muriatic acid to acidize oil wells. The acid increases and stimulates oil production by dissolving calcium and magnesium carbonate bedrock to produce fissures, or pores, in the oil bearing rock formation. These pores make them more permeable to oil and gas flow into the well casing. PlasticsHydrochloric acid is integral to the PVC value chain. It is used to make ethylene dichloride (EDC), which is a major feedstock of vinyl chloride monomer (VCM). VCM is then polymerized to make PVC, which is used in residential and commercial construction. EDC is also used to manufacture other chlorinated solvents, ethylene amines, and plastics. PharmaceuticalsThe pharmaceutical industry consumes HCl as a catalyst, for pH control, water treatment, and as a reducing agent in production. Organic Chemical SynthesisChemical manufacturers react muriatic acid to form chlorides and hydrochloride or as a pH regulator for process and effluent streams. Water and Wastewater TreatmentHydrochloric acid is used to control pool water and industrial waste water pH and to clean commercial pool plasters and masonry. Brine TreatmentMuriatic acid is used to purify and adjust the pH of brine prior to chlorine/sodium hydroxide production. Food Additives and ProcessingThe food industry uses hydrochloric acid in a variety of products, the majority of which is the production of high fructose corn syrup. It is also used to produce a vitamin supplement in animal feed, saccharin and aspartame, and in the processing of gelatin, vegetable and fruit juices, and canned goods. Ore and Mineral ProcessingMining operations use muriatic acid for ore treatment, extraction and separation, purification and water treatment. Mineral processesing requires muriatic acid for the recovery of gold and molybdenum, as well as in the production of tungsten metals and chemicals. Muriatic acid is also used in potash ore, zirconium, and uranium production.

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Health Effects
Muriatic acid can cause severe burns to eyes and skin and is severely corrosive to the respiratory tract. It is harmful or fatal if ingested, and even small amounts in the eye can cause blindness. Please refer to the Material Safety Data Sheet and Product Warning Label for more information on the health effects of this product.

Environmental Effects
Muriatic acid is toxic to fish and should be kept out of lakes, streams, ponds, or other water sources. Please refer to the Material Safety Data Sheet and Product Warning Label for more information on the environmental effects of this product.

Exposure Potential
Muriatic acid is corrosive so precautions should be taken to minimize potential harm to people, animals and the environment. When handling muriatic acid, refer to the Material Safety Data Sheet and Product Warning Label and follow all instructions and warnings. Based on the expected uses for muriatic acid, exposure could be through: Workplace exposureExposure can occur in facilities that either manufacture or use muriatic acid. Consumer exposureMuriatic acid is not sold directly to consumers, however it is an ingredient in some consumer products. Keep all chemical products out of the reach of children. Consumers should refer to product labels for correct use and precautionary information. Environmental releasesEnvironmental exposure to muriatic acid could occur if the product is spilled. Refer to the Material Safety Data Sheet for instructions to contain and clean up a spill to minimize exposure.

Physical & Chemical Properties

Muriatic acid is a clear, fuming liquid with an irritating odor. It is a highly corrosive strong acid. It is completely miscible with water. When mixing with water, extreme heat of reaction will occur. Always add small amounts of acid to large amounts of water, with constant agitation to allow heat to dissipate. Vapor from the acid is highly irritating to the respiratory tract.

Baume Concentration Range (% HCl) Boiling Point pH Vapor Pressure mm Hg Specific Gravity Bulk Density 15.6 oC, lbs/gal
oC

18 26.5 % - 29.5% 100 -58 -1.0 14 1.142 9.5

20 31.5 % - 32.9% 84 -44.5 -1.0 24 1.160 9.7

22 35.2 % - 36.2% 61 -32 -1.1 100 1.179 9.8

23 37.1% - 38.0% 48 -27 -1.1 150 1.189 9.9

Freezing Point oC

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Regulatory Information
PPG Material Safety Data Sheets contain considerable regulatory information on our products, including Global Chemical Inventory Status information, California Proposition 65 status (if a warning is required on the product), TSCA Section 12(b) information, Transportation Classifications, SARA Title III information, CERCLA Part 302 information, WHMIS Classifications, and HMIS/NFPA ratings. The following is additional regulatory information not contained on the Material Safety Data Sheet.

North American Regulatory Information

FDA StatusMuriatic acid is Generally Recognized as Safe (GRAS) when used as a buffer and neutralizing agent and when used in accordance with good manufacturing practices (21 CFR 182.1057). CONEG Regulation/Model Toxics in Packaging LegislationNot determined. RCRA Hazardous Waste ChemicalMuriatic acid if discarded or spilled, as well as other wastes generated during use of muriatic acid or containing muriatic acid may exhibit one or more hazardous waste characteristics under 40 CFR 261.24: D002 corrosive. (Note: PPG provides information on U.S. hazardous waste criteria for the product as manufactured. It remains the obligation of the user to evaluate their specific waste and to manage, treat, and dispose of unused material, residues, and containers in accordance with applicable federal, state, and local requirements.) VOC InformationMuriatic acid does not contain constituents that qualify as a volatile organic compound (VOC) based on the definition in 40 CFR 51.100. HAP Information Muriatic acid is listed as a hazardous air pollutant (HAPs) in the Clean Air Act Amendments of 1990, 42 USC 7412 (b). Ozone-Depleting ChemicalsMuriatic acid is not/does not contain ozone depleting chemical (40 CFR 82, Subpart A, Appendix F) Canadian Food Inspection Agency (CFIA)/Agence Canadienne dInspection des Aliments (ACIA) Muriatic acid manufactured at Beauharnois, Quebec, Canada is acceptable for use with food in Registered Establishments per CFIA provided that the label instructions are followed. FDA Bioterrorism Act of 2002 Section 305 (Registration of Food Facilities) The following PPG facilities have been registered with the FDA: Beauharnois, Quebec, Canada (Registration Number 10613313230), Lake Charles, Louisiana, USA (Registration Number 10481961256), Longview, Washington, USA (Registration Number 14013723824) and New Martinsville, WV, USA (Registration Number 17799959488). TSCA Information Muriatic acid is not currently subject to any rule or order under TSCA Sections 4,5,7,8(a), or 8(d).

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Other Regulatory Information

RoHS/WEEEMuriatic Acid has been reviewed with regard to the EU Directive 2002/95/EC Restriction on the Use of Certain Hazardous Substances (RoHS). Based on our knowledge of this product and information on the raw material suppliers Material Safety Data Sheets, this product does not contain cadmium, hexavalent chromium, lead, mercury, polybrominated biphenyls (PBBs) or polybrominated diphenyl ethers (PBDEs) at levels greater than the tolerated maximum concentration values established by the EU Commission Decision 2005/618/EC.

Product Certifications & Listings

Food Chemicals CodexMuriatic acid meets the Food Chemicals Codex specifications (Edition 7, 2nd Supplement). NSF Standard 60 Drinking Water Treatment ChemicalsMuriatic acid has the Health Effects listing, and is certified for maximum use levels as noted on the NSF website, which can be viewed at www.nsf.org/certified/PwsChemicals. Kosher CertificationMuriatic acid, including the equipment used in its manufacture, does not come into contact with or contain any animal by-products, animal fats, or animal products, nor does it contain chemical additives that are organic in nature. According to the current policies of the Orthodox Union (OU) muriatic acid is acceptable for use in Kosher-related activities without Kosher certification. Halal CertificationPPG Muriatic acid is not Halal certified. However, muriatic acid does not contain alcohol, natural L-cysteine extracted from hair or feathers, animal fats and/or extracts, blood of any origin, blood plasma, or pork/or other meat byproducts. Alcohol is not used as processing aid. As such, this product may be acceptable for Halal consideration.

Additional Product Information

SourceMuriatic acid is derived from mineral and petroleum sources and has not been derived from plant, animal, synthetic, or fermentation sources Allergenic MaterialsMuriatic acid is not manufactured using any of the following allergenic materials: carmine/cochineal extracts, celery, colors/color additives, dyes/food dyes, eggs/egg products, seafood/fish/shellfish/crustaceans, flavors, glutens, legumes, milk, mollusks, monosodium glutamate (MSG), mustards, plant nuts/seeds/oils (sesame, sunflower, safflower, canola, etc.), peanuts/peanut products, protein hydrolysates, soy/soybeans/soybean products, spices, sulfites, sulfates, tree nuts/tree nut oils, and wheat. Bovine Spongiform EncephalopathyMuriatic acid is not of animal origin, and, to PPGs knowledge, does not contribute to Transmissible Spongiform Encephalopathy (TSE)/Bovine Spongiform Encephalopathy (BSE). Genetically Modified Organisms (GMOs)Muriatic acid is not manufactured with and does not contain genetically modified organisms. Natural Latex RubberMuriatic acid is not manufactured with and does not contain natural latex rubber as defined in 21 CFR 801.437(b)(1). Nutritional ValueMuriatic acid does not have nutritional value.

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Product Stewardship
As a member of the American Chemistry Council (ACC) and the Chemistry Industry Association of Canada (CIAC), PPG is committed to the Responsible Care initiative, an industry commitment to improve environmental, health, safety and security performance. Please consult the ACC, CIAC and PPGs Corporate Environment, Health and Safety (EHS) for information regarding the following: measuring and publically reporting performance implementing the ACCs Responsible Care Codes applying an EHS management system to achieve and verify results and obtaining independent certification that the management system is in place and functioning appropriately

Please see the information at the following web link for a description of the steps PPG takes to work with our Direct Customers and Distributors regarding the safe storage, handling, use and disposal of our products (www.ppgchloralkali.com). Our intent in taking these actions is to minimize adverse effects of our products on human health and well-being, and on the environment.

Additional Information
Samples are available for existing and potential industrial customers on request in various sizes to meet customer requirements. For more information regarding PPGs muriatic acid, contact our customer service department by calling 800-CHEM-PPG (800-243-6774). In Canada, contact PPG Canada Inc., 31 Industry Road, Beauharnois, Quebec J6N 3C3 Canada, 450-429-4641. In the US west coast, contact PPG Longview, WA 3541 Industrial Way Longview, WA 98632, 1-800-225-6422 or 360-577-5580.

Customer Service
PPG Chlor-Alkali Customer Service, a two-time recipient of the International Customer Service Association Award for Excellence, welcomes the opportunity to serve you. You can use our toll-free number (1-800-243-6774) 24 hours a day. Dedicated service is available during our normal working hours of 8 AM to 5 PM EST. Extended service hours exist to facilitate your unexpected product or service needs.

References
PPG Chlor-Alkali Web page: www.ppgchloralkali.com CEH Marketing Research Report: Hydrochloric Acid CEH Chemical Economics Handbook, SRI Consulting, c. 2009 Pioneer Material Safety Data Sheet: Hydrochloric Acid c. 2003

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440 College Park Drive Monroeville, PA 15146 PPG Canada Inc 31 Industry Road Beauharnois, Qubec Canada J6N 3C3 www.ppgchloralkali.com
Statements and methods presented are based upon the best available information and practices known to PPG Industries at present, but are not representations or warranties of performance, result or comprehensiveness, nor do they imply any recommendations to infringe any patent or an offer of license under any patent. The products mentioned herein can be hazardous if not used properly. Any health hazard and safety information contained herein should be passed on to your customers or employees, as the case may be. PPG Industries also recommends that, before use, anyone using or handling this product thoroughly read and understand the information and precautions on the label, as well as in other product safety publications such as the Material Safety Data Sheet. Like all potentially hazardous materials, this product must be kept out of the reach of children. 2011 PPG Industries, Inc. All Rights Reserved.

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