1

Small-Amplitude Oscillatory Shear Material Functions

0
0
0
cos ) (

= t t
Kinematics:
123
2
0
0
) (
|
|
|
.
|

\
|

x t
v

Material Functions:
t G t G
t

cos sin
) , (
0
0 21
+ =

Storage modulus

cos ) (
0
0
G

sin ) (
0
0
G
Loss modulus
( is the phase
difference
between stress
and strain)
Faith A. Morrison, Michigan Tech U.
Predictions of the Generalized Maxwell Model (GMM)
and Generalized Linear-Viscoelastic Model (GLVE)
Faith A. Morrison, Michigan Tech U.
Small-amplitude
oscillatory shear
GMM
}


=


(

=
t
k
t t
k
k
t d t e
k
) (
3
1
/ ) (

t d t t t G
t
=
}

) ( ) (

=
=
+
=
+
=
N
k k
k
N
k k
k k
G
G
1
2
1
2
2
) ( 1
) (
) ( 1
) (

GLVE
}
}

=
=
0
0
sin ) ( ) (
cos ) ( ) (
ds s s G G
ds s s G G


2
0.00001
0.0001
0.001
0.01
0.1
1
10
0.001 0.01 0.1 1 10 100 1000

1
|
|
|
.
|

\
|
1
1
'

G
|
|
|
.
|

\
|
1
1
"

G
10
-5
10
-4
Faith A. Morrison, Michigan Tech U.
Predictions of (single-mode) Maxwell Model in SAOS
2
1
1
2
1
1 1
2
1
2
1 1
2
1
2 2
1 1
) ( 1 ) ( 1
) (
) ( 1 ) ( 1
) (

+
=
+
=
+
=
+
=
g
G
g
G
Faith A. Morrison, Michigan Tech U.
Predictions of (multi-mode) Maxwell Model in SAOS
Figure 8.8, p. 284
data from
Vinogradov, PS melt
1.E+01
1.E+02
1.E+03
1.E+04
1.E+05
1.E+06
1.E+07
1.E+00 1.E+01 1.E+02 1.E+03 1.E+04 1.E+05 1.E+06 1.E+07
a
T
, rad/s
G' (Pa)
G'' (Pa)
k
k
(s)
g
k
(kPa)
1 2.3E-3 16
2 3.0E-4 140
3 3.0E-5 90
4 3.0E-6 400
5 3.0E-7 4000

=
=
+
=
+
=
N
k k
k
N
k k
k k
G
G
1
2
1
2
2
) ( 1
) (
) ( 1
) (

3
Faith A. Morrison, Michigan Tech U.
Predictions of (multi-mode) Maxwell Model in SAOS
Figure 8.10, p. 286
data from Laun, PE
melt
1.E-01
1.E+00
1.E+01
1.E+02
1.E+03
1.E+04
1.E+05
1.E+06
1.E-04 1.E-02 1.E+00 1.E+02 1.E+04 1.E+06
a
T
rad/s
m
o
d
u
l
i
G' (Pa)
G" Pa
k gk
50 4.42E+02
5 3.62E+03
1 4.47E+03
0.5 3.28E+03
0.2 9.36E+03
0.1 1.03E+04
0.05 1.71E+03
0.02 1.18E+02
0.02 2.55E+04
0.01 3.33E+04
0.0007 1.83E+05

=
=
+
=
+
=
N
k k
k
N
k k
k k
G
G
1
2
1
2
2
) ( 1
) (
) ( 1
) (

Faith A. Morrison, Michigan Tech U.

Limitations of the GLVE Models
Predicts constant shear viscosity
Only valid in regime where strain is additive (small-strain,
low rates)
All stresses are proportional to the deformation-rate tensor;
thus shear normal stresses cannot be predicted
Cannot describe flows with a superposed rigid rotation (as we
will now discuss; see Morrison p296)
4
0.1
1
10
100
1000
0.01 0.1 1 10 100
s
t
e
a
d
y

s
h
e
a
r

m
a
t
e
r
i
a
l

f
u
n
c
t
i
o
n
s

1
(Pa s
2
)
(Pa)

2
(Pa s
2
)
PS/TCP squares
PS/DOP circles
1
,

s
Steady shear viscosity and first and
second normal stress coefficient
Figure 6.6, p. 174 Magda et
al.; PS solns
Faith A. Morrison, Michigan Tech U.
BOGER FLUIDS