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| X,
M / M
E
+
=0.44 V and
X / X
E =0.33 V. From this
data we can deduce that:
(a) M +X M
+
+X
Fe
2+
; E =+0.77 V , Zn
2+
+2e
Zn ; E = 0.76 V.
Predict which out of the following statement is correct?
(a) Zinc can reduce ferric (Fe
3+
) to ferrous (Fe
2+
).
(b) Zinc can oxidise ferrous (Fe
2+
) to ferric (Fe
3+
).
(c) Nothing happens.
(d) (a) and (b) both.
9. Calculate the standard potential for the reaction
O
2
+2H
+
+2e
H
2
O
If E for the reaction O
2
+H
2
O +2e
2OH
is +0.4 V
(a) 1.23 V (b) 1.23 V (c) 0.828 V (d) 8.28 V
10. Which of the following statements is correct?
(a) Oxidation occurs at anode in both galvanic and electrolytic cells
(b) Reduction occurs at anode in both galvanic and electrolytic cells
(c) Reduction occurs at anode in electrolytic cell whereas oxidation occurs at cathode in a galvanic
cell
(d) Oxidation occurs at anode in electrolytic cell whereas reduction occurs at anode in a galvanic
cell.
11. If in a standard hydrogen electrode half cell 2H
+
(aq) +2e H
2
(g) ; 1 atm ; on addition of base
hydrogen ion concentration is reduced to 10
1
(M) then the emf will be
(a) +0.0591 V (b) 0.1182 V (c) 0.0591 V (d) 0.1182 V
12. When 2L of 0.5 M NaCl is electrolysed with 112.10 F of charged, the pH of resulting solution is
close to (assume the concentration of Cl
cell
E of the reaction
4
MnO +Fe
2+
+H
+
Mn
2+
+Fe
3+
+H
2
O is 0.59 V at 25C.
The equilibrium constant for the reaction is
(a) 50 (b) 10 (c) 10
50
(d) 10
5
15. A current of 2.0 A when passed for 5 hours through a molten metal salt, it deposits 22.2 g of metal
of atomic weight 177. The oxidation state of metal in metal salt is
(a) +1 (b) +2 (c) +3 (d) +4
16. Calculate the standard potential for the reaction,,
O
2
+2H
+
+2e
H
2
O
If E for the reaction, O
2
+H
2
O +2e
2OH
is +0.4 V
(a) 1.23 V (b) 1.23 V (c) 0.828 V (d) 8.28 V
17. The fraction of a mole of iron metal produced by the passage of 4 A of current through 1 litre of
0.1 M Fe
3+
solution for 1 hour would be approximately (assume that only iron is reduced)
(a) 0.05 mole (b) 0.025 mole (c) 0.035 mole (d) 0.07 mole
18. During charging of a lead storage battery, the reaction, taking place at the anode is
(a) Pb
2+
+
2
4
SO PbSO
4
(s)
(b) Pb
2+
+2e
Pb
(c) Pb Pb
2+
+2e
(d) 2PbSO
4
(s) +2H
2
O Pb(s) +PbO
2
(s) +2H
2
SO
4
19. The standard reduction potentials, E, for the half reactions are
Zn
2+
+2e
=Zn E = 0.76 V
Fe
2+
+2e
=Fe E = 0.41 V
The standard emf of the cell involving the reaction Fe
2+
+Zn Zn
2+
+Fe is
(a) 0.35 V (b) 1.17 V (c) +0.35 V (d) 1.17 V
20. In acidic medium
4
MnO is an oxidizing agent.
4
MnO +8H
+
+5e
Mn
2+
+4H
2
O
If H
+
ion concentration is doubled, electrode potential of the half cell
4
MnO , Mn
2+
/Pt will
(a) increase by 28.46 mV (b) decrease by 28.46 mV
(c) increase by 14.23 mV (d) decrease by 142.30 mV
21. The standard reduction potentials of Cr
3+
| Cr
2+
and Cr
3+
| Cr are 0.41 V and 0.74 V respectively.
The standard electrode potentials of Cr
2+
| Cr halfcell is
(a) +1.81 V (b) 1.81 V (c) +0.905 V (d) 0.905 V
22. Zn | Zn
2+
(c
1
M) || Zn
2+
(c
2
M) | Zn
For this cell, AG would be negative, if
(a) c
1
=c
2
(b) c
1
>c
2
(c) c
2
>c
1
(d) None of these
23. For a reaction M
+n
(aq) +ne
(C
1
M) | AgCl | Ag is given by
(a) E
cell
=
1
sp
C
K
log
1
059 . 0
(b) E
cell
=
sp
1
K
C
log
1
059 . 0
(c) E
cell
=
1
sp
C
K
log
1
059 . 0
(d) E
cell
=
sp
1
K
C
log
1
059 . 0
(where K
sp
is the solubility product of AgCl)
25. The
cell
E of the reaction
4
MnO +Fe
2+
+H
+
Mn
2+
+Fe
3+
+H
2
O is 0.59 V at 25C.
The equilibrium constant for the reaction is
(a) 50 (b) 10 (c) 10
50
(d) 10
5
ANDHERI/BORIVALI/DADAR/CHEMBUR/THANE/CHURCHGATE/NERUL/POWAI/MULUND
Time : 1 hr TW Test Max. Marks : 75
Batch: APJC 3 Topic: Electrochemistry
1. (c)
Cell
E =
eq
K log
2
059 . 0
0.295 =
eq
K log
2
059 . 0
log K
eq
=
059 . 0
2 295 . 0
=10
K
eq
=10
10
.
2. (c) At anode: H
2
(g) H
+
(aq.) +e
At cathode: AgCl(s) +e
Ag(s) +Cl
(aq.)
H
2
(g) + AgCl(s) H
+
(aq) +Cl
(aq) +Ag(s).
3. (b)
4. (c)
5. (b)
6. (a) E
cell
=
2
1
P
P
log
2
059 . 0
E
cell
is positive when P
1
>P
2
.
7. (b) The given galvanic cell is represented as
Pt | H
2
(1 atm) | acid(0.1M) || H
+
(1M) | H
2
(1 atm) | Pt
At anode: H
2
+
+ e H
A
At cathode:
+
+ e H
C
H
2
Net cell reaction:
+
C
H
+
A
H
This is an electrolyte concentration cell whose
cell
E will be zero.
E
cell
=0.059 log
] [
] [
+
+
A
C
H
H
The ] H [
C
+
is fixed at 1 M, so to get the maximum emf of the cell ] H [
A
+
should be least. So
the acid must be weakest among all. Order of acidity of the given acids is
H
2
C
2
O
4
>HCO
2
H >C
6
H
5
CO
2
H >CH
3
CO
2
H
8. (a) As
Zn | Zn
2
E
+
is lower than , E
2 3
Fe | Fe
+ +
zinc will reduce Fe
3+
to Fe
2+
and itself gets oxidised.
Zn +2Fe
3+
Zn
2+
+2Fe
2+
=
cell
E
+ + 2 3
Fe | Fe
E
Zn | Zn
2
E
+
=0.77 (0.76) =+1.53 V
A positive value of
cell
E indicates that the cell reaction is feasible.
9. (b) 2H
+
+2OH
2H
2
O
1
G A =RT ln
2
14
10
1
|
.
|
\
|
2
O
2
1
+H
2
O +2e
2OH
2
G A =2F 0.4
2H
+
+
2
1
O
2
+2e
H
2
O
3
G A =2FE
E =+1.23 V.
10. (a)
11. (c) E =
2
] H [
1
ln
F 2
RT
+
0.0591 log
2
] H [
1
+
=0.0591 log 10 = 0.0591 vol.
12. (d) 1 F charge oxidise one mole Cl
produced =1 mol.
remaining 111.10 F charge will break H
2
O
= ) 2 n (
H
2
+ O
2
moles of H
2
O electrolysed =
2
10 . 111
=55.55 weight of H
2
O electrolysed =999.99 gm n 1 L
H
2
O molarity after electrolysis =1 M NaOH ; pH =14.
13. (b)
14. (c) For the given halfcell reaction
n F
cell
E =RT ln K
eq
5 96500 0.59 =2.303 8.314 298 log K
eq
K
eq
=7.8 10
49
~ 10
50
.
15. (c) Number of Faraday =number of equivalents
96500
60 60 5 2
=
177
2 . 22
n
n =3.
16. (b) 2H
+
+2OH
2H
2
O
1
G A =RT ln
2
14
10
1
|
.
|
\
|
2
O
2
1
+H
2
O +2e
2OH
2
G A =2F 0.4
2H
+
+
2
1
O
2
+2e
H
2
O
3
G A =2FE
E =+1.23 V.
17. (b) The reduction of Fe
3+
(in general, any ion) takes place in steps.
Fe
3+
+ e
Fe
2+
Initial moles 0.1
96500
3600 4
=0.15 0
After the reaction 0 0.15 0.1 0.1
=0.05
Fe
2+
+ 2e
Fe
Initial moles 0.1 0.05 0
After the reaction 0.1
2
05 . 0
0
2
05 . 0
=0.025
=0.075
Thus, mole of Fe produced are 0.025.
18. (d)
19. (c)
0
Zn / Zn
0
Fe / Fe
0
cell 2 2
E E E
+ +
=
=(0.41 +0.76)V
=0.35 V
20. (a)
4
MnO +8H
+
+5e
Mn
2+
+4H
2
O
8
4
2
0
Pt / Mn , MnO Pt / Mn , MnO
] H [ ] MnO [
] Mn [
log
5
059 . 0
E E
2
4
2
4
+
+
=
+ +
(i)
8 8
4
2
0
Pt / Mn , MnO Pt / Mn , MnO
2 ] H [ ] MnO [
] Mn [
log
5
059 . 0
E E
2
4
2
4
= '
+
+
+ +
(ii)
(i) (ii) gives change in electrode potential =
(
8
2
1
log
5
059 . 0
= 0.02 841 V
=28.41 mV
21. (d)
+ + 2 3
Cr | Cr
E =0.41 V and
Cr | Cr
3
E
+
=0.74 V
Cr
3+
+e Cr
2+
(i)
1
G A =F(0.41) J
Cr
3+
+3e Cr (ii)
2
G A =3F(0.74) J
(ii) (i) Cr
2+
2e Cr
3
G A =
2
G A
1
G A
2F
Cr | Cr
2
E
+
=(3 0.74 0.41) F
Cr | Cr
2
E
+
= 0.905 V.
22. (c) AG is negative, if E
cell
is positive as AG =nF E
cell
.
For the given concentration cell
E
cell
=
|
|
.
|
\
|
2
1
C
C
log
2
0591 . 0
If C
2
>C
1
, E
cell
is positive and AG is negative.
23. (a) E =E
] M [
1
ln .
nF
RT
n +
=E + ]. Mn ln[
nF
RT
+
As [M
n+
] increases ln[Mn
+
] increases
24. (c) The given cell can be reduced to
Ag | AgCl (saturated solution) || Ag
+
|
|
.
|
\
|
] Cl [
K
sp
| Ag
The reaction occurring at the two electrodes are
At anode: Ag
+
A
Ag + e
At cathode:
+
c
Ag +e
Ag
Net cell reaction:
+
c
Ag
+
A
Ag
E
cell
=
cell
E 0.059 log
] Ag [
] Ag [
C
A
+
+
=0.059 log
] Ag [
] Ag [
A
C
+
+
[Since, it is a concentration cell for which
cell
E =0]
E
cell
=0.059 log
sp
sp
K ] Cl [
K
=0.059 log
] Cl [
K
sp
=0.059 log
1
sp
C
K
.
25. (c) For the given halfcell reaction
n F
cell
E =RT ln K
eq
5 96500 0.59 =2.303 8.314 298 log K
eq
K
eq
=7.8 10
49
~ 10
50
.