Std 12 Sem 3 Marks 29

chapter: 1 ,2,3 Time 60min

1. In a solid lattice, the cation has left a lattice site and is located at interstitial position, the lattice defect is
(a) Interstitial defect (b) Vacancy defect (c) Frenkel defect (d) Schottky defect
2. Which of the following metal oxides is antiferromagnetic in nature ?
(a) MnO
2
(b)TiO
2
(c)NO
2
(d)CrO
2
3. The intermetallic compound crysta-llizes in cubic lattice in which both lithium and silver have co-
ordination number of eight. The crystal class is.
4. (a) Simple cube (b) Body centred cube (c) Face centred cube (d) None
Which among the following will show anisotropy ?
(a) Glass (b) Barium Chlorid (c) Wood (d) Paper
5. In a crystal, all the lattice sites are found to be occupied by covalent molecules. To which kind of solid
does it belong?
(a) ionic (b) molecular (c) covalent (d) None of these
6. Which one of the following is correct?
(a) Schottky defect lowers the density
(b) Frenkel defect increases the dielectric constant of the crystals
(c) Stoichiometric defects make the crystals good electrical conductors (d) All of these
7. The electrical conductivity of semiconductors
(a) Increases with temperature (b) Decreases with temperature
(c) Remains constants on heating (d) None of the above
8. The unit cell with crystallographic dimen-sions a=bc; = = = 90
0
is
(a) cubic (b) tetragonal (c) monoclinic (d) hexagonal
9. In a crystal of an ionic compound the ions form the close packed lattice and the ions A occupy all the
tetrahedral voids. The formula of the compound is.
(a)
2
AB (b)
2
A B (c) AB (d)
3
AB
10. An aqueous solution freezes at 0.186
0
C ; (Kf = 1.86
0
; Kb = 0.512
0
) what is the elevation in boiling
point ?
(a) 0.186 (b) 0.512 (c) 0.86 (d) 0.0512
11. The average osmotic pressure of human blood is 7:8 bar at 37
0
C . What is the concentration of an
aqueous NaCl solution that could be used in the blood stream ?
(a) 0.15 mol/L (b) 0.30 mol/L (c) 0.60 mol/L (d) 0.45 mol/L
12. A 5.25 % solution of a substance is isotonic with a 1.5 % solution of urea (molar mass = 60 g ) in the
same solvent. If the densities of both the solutions are assumed to be equal to 1.0 g , molar mass of
substance will be..................
(a) 210.0 g (b) 90.0 (c) 115.0 g (d) 105.0 g
13. For the structure give below the site marked as S is a.
(a) Tetrahedral void
(b) Cubic void
(c) Octahedral void
(d) None of these
14. A 6% solution of urea is isotonic with...........
(a) 0.05 M solution of glucose (b) 6% solution of glucose
(c) 25% solution of glucose (d) 1 M solution of glucose
15. A student has 100 mL of 0.1 M KCl solution. To make it 0.2 M he has to.
(a) evaporate 50 mL of the solution (b) add 0.01 mole of KCl
(c) both (a) and (b) can be used (d) neither (a) nor (b) can be used
16. When electricity is passed through molten Al
2
O
3
+Na
3
AlF
6
13.5g of Al are deposited. The number of
faradays passedare
(a) 1.5 (b) 3 (c) 15 (d) 0.15.
17. The electrode potential of an electrode is
(a) the potential applied to the electrode
(b) the ionisation potential ofthe material of the electrode
(c) the tendency of the electrode to lose or gain electrons when it is in contact with its ions.
(d) the potential energy of the electrons in an electrode.
18. During charging of a lead storage battery, the reaction taking place at anode.
S
(a) Pb
2+
+ SO
( )
PbSO
4
(b) Pb
2+
+ 2e

-Pb
(c) Pb Pb
2+
+ 2e

(d) PbSO
( )
+ 2H2O
( )
PbO
( )
+ SO
( )
+4H
( )
+2e

19. In a galvanic all, a salt bridge is used to

(a) complete the circuit (b) reduce electric resistance in cell
(c) attain equilibrium (d) carry salts for electrons occurring in cell
20. The time in hours required for a current of 3 ampere to decompose electrolytically 18gm of H
2
O is
(A) 9 (B) 18(C) 36 (D) 54
21. The relative lowering of vapour pressure of an aqueous solution containing non-volatile solute is 0.0125.
The molality of the solution is................
(a) 0.70 (b) 0.50 (c) 0.60 (d) 0.80 (e) 0.40
22. One molal solution of a complex of cobalt chloride with in water showed an elevation in boiling point
equal to . Assuming that the complex is completely ionized in the solution, the complex is ( for water =
0.52 k kg )
(a)
, )
3 3
6
CO NH Cl
(

(b)
, )
3 2
5
CO NH Cl Cl
(

(c)
, )
3 2
4
CO NH Cl Cl
(

(d) none of these
Question no 25 to 32 are two mark questions
23. At , the vapour pressure of pure liquid A is 520 mm Hg and that of pure liquid B is 1000 mm Hg. If a
mixture solution of A and B boils at and 1 atm pressure then amount of A in the mixture is (1 atm =
760 mm Hg) (2 mark)
(a) 48 mol percent (b) 50 mol percent (c) 52 mol percent (d) 34 mol percent
24. Calculate the standard free energy change for the reaction given that for
is 0.80V (2mark)
a) +154.4kJ b) +308.8kJ c) 154.4kJ d) 308.8Kj
25. A solid has a structure in which W atoms are located at the cube corners of the unit cell, O atoms are
located at the face centres and the atoms at the cube centre. The formula of the compounds is.(2mark)
(a)
3
NaWO (b)
2 3
Na WO (c)
2 3
NaW O (d)
2
NaWO
26. The volumes of 4 NHCl and 10 N HCl required to make 1 litre of 6 NHCl are. .................(2mark)
(a) 0.75 litre of 4 NHCl and 0.25 litre of 10 N HCl (b) 0.25 litre of 4 N HCl and 0.75 litre of 10 N HCl
(c) 0.67 litre of 4 N HCl and 0.33 litre of 10 N HCl
(d) 0.80 litre of 4 NHCl and 0.20 litre of 10 N HCl (e) 0.50 litre of 4 N HCl and 0.50 litre of 10 N HCl
27. By how much will the potential of a copper electrode change if the solution CuSO
4
in which it is
immersed is diluted to 10 times at 298K?(2 mark)
a. increases by 30mV b. Decreases by 30mV
c. Increases by 60mV d. Decreases by 60mV
28. The edge length of face centred unit cubic cells is 508 pm. If the radius of the cation is 110 pm, the
radius of anion is.................(2mark)
(a) 110 pm (b) 144 pm (c) 618 pm (d) 398 pm
29. Equivalent conductances of NaCl, HCl and at infinite dilution are 126.45, 326.16 and 90
ohm
1
cm
2
respectively. The equivalent conductance of CH
3
COOHat infinite dilution will be : (2 mark)
a)
-1 2
101.38ohm cm
b)
-1 2
253.62ohm cm
c)
-1 2
289.71ohm cm
d)
-1 2
678.90ohm cm
30. Two liquids X and Y form an ideal solution. At 300 k, vapour pressure of the solution containing 1 mol of
X and 3 mol of Y is 550 mm Hg. At the same temperature if 1 of Y is further added to this solution,
vapour pressure of the solution increases by 10 mm Hg. Vapour pressure (in mm Hg) of X and Y in their
pure states will be respectively. (2mark)
(a) 200 and 300 (b) 300 and 400 (c) 400 and 600 (d) 500 and 600
31. For the columns below Which of the following is correct? (4 mark)
List - I List - II
1) Solid in gas A) Brass
2) Solid in solid B) Amalgam
3) liquid in solid C) Comphor in air
4) Gas in liquid D) Alcohol in water
2
2 2 2 Ag H H Ag
+ +
+ +
0
E
Ag e Ag
+
+
1 2 3 4 1 2 3 4
a)C A B D b) A C D B
c) C B A D d) D A B C
32. A solution of sucrose (molar mass=342) has been prepared by dissolving 68.4 g of sucrose in one kg of
water. Kf for water is 1.86 K kg and vapour pressure of water at 298 K is 0.024 atm.............. (4marks)
(i) The vapour pressure of the solution at 298 K will be................
(a) 0.230 atm (b) 0.233 atm (c) 0.236 atm (d) 0.0239 atm
(ii) The osmotic pressure of the solution at 298 K will be..............
(a) 4.29 atm (b) 4.49 atm (c) 4.69 atm (d) 4.89 atm
(iii) The freezing point of the solution will be .................
(a) 0.684
0
C (b) 0.342
0
C (c)0.372
0
C (d) 0.186
0
C
(iv) The mass of sodium chloride that should be dissolved in the same amount of water to get the same
freezing point will be
(a) 136.8 g (b) 32.2 g (c) 5.85 g (d) 11.60 g
(v) If on dissolving the above amount of NaCl in 1 k of water the freezing point is found to be , the
percentage dissociation of NaCl in the solution is..................
(a) 75% (b) 80%(c) 85% (d) 90%
(a) (i) b (ii) b (iii) a (iv) a (v) a
(b) (i) c (ii) c (iii) b (iv) a (v) d
(c) (i) d (ii) d (iii) c (iv) c (v) c
(d) (i) a (ii) b (iii) d (iv) c (v) d
33. An acidic solution of
2
Cu
+
salt containing 0.4 g of
2
Cu
+
is electrolysed until all the copper is deposited.
The electrolysis is continued for seven more minute with the volume of solution kept at 100 ml and the
current at 1.2 amp. Calculate the volume of gases evolved at STP during the entire electrolysis (4mark)
a)
2 2
O =99.79 ml, H =48.45ml b)
2 2
O =87.91ml, H =58.48ml
c)
2 2
O =99.79 ml, H =58.48ml d)
2 2
O =100 ml, H =50 ml