Escolar Documentos
Profissional Documentos
Cultura Documentos
Class
Full Name
Index Number
PRELIMINARY EXAMINATION
2012
5116/03
I believe, therefore I am
SCIENCE (CHEMISTRY)
Secondary 4 Express / 5 Normal Academic
30 Aug 2012
1h 15 minutes
INSTRUCTIONS TO CANDIDATES
Write your full name, class and index number on all the work you hand in.
Do not use staples, paper clips, highlighters, glue or correction fluid.
SECTION A
Answer all questions in the spaces provided.
SECTION B
Answer any two questions.
Write your answers on the writing paper provided.
The number of marks is given in brackets [ ] at the end of each question or part of a
question.
A copy of a Data Sheet and the Periodic Table is provided.
All essential workings must be shown.
The use of a calculator is allowed in this paper.
DO NOT OPEN THIS PAPER UNTIL YOU ARE TOLD TO DO SO
65
This document consists of 18 printed pages, including a copy of the Periodic Table.
Setter: Ms Chua S. H.
5116/Prelim/2012
[Turn over
2
Section A [45marks]
Answer all questions in the spaces provided
For
Examiners
Use
Boiling Point / oC
Melting Point / oC
Water vapour
100
Carbon dioxide
-78 (sublimes)
-78 (sublimes)
Xenon
-108
Krypton
-153
Oxygen
-182
Argon
-186
Nitrogen
-196
Figure 1.1 boiling and/or melting point of the main gases in air
Before liquefying the air from room temperature to -200oC, dust particles
are removed. Air is first cooled to a temperature of about -80oC. This is to
facilitate the removal of carbon dioxide and water vapour because at low
temperature of -200oC they would block the pipes.
(a)
[1]
(b)
Particles of air behave differently before and after it was liquefied. Give
[2]
Differences in movement:
5116/Prelim/2012
[Turn over
3
1
(c)
What is the name for the type of separation process taking place in the
For
[1]
Examiners
(d)
Use
(ii)
Liquefied
air in at
-200OC
Separating
column
Oxygen
(iii)
(iv)
Heater
(e)
[1]
Two isotopes of an element, A-13 and A-14 exist naturally with atomic
mass of 13 and 14 respectively. Each of the isotopes neutral atoms has
six electrons. The proportion of these isotopes in ivory elephant tusks
can be used to determine where in the world the tusks come from.
Complete Figure 2 below:
Isotope
No of proton
per atom
No of electrons
per atom
A-13
A-14
No of neutrons
per atom
[2]
5116/Prelim/2012
[Turn over
4
3
For
Examiners
Use
Figure 3
Which element will form three covalent bonds when it forms a [1]
compound?
(b)
(i)
Which two elements will form a compound with the formula of the type [1]
YZ2 of melting point of 1130oC?
(ii)
[2]
(c)
(i)
Draw a dot and cross diagram to show the bonding in the compound [2]
formed between A and B. You only need to show outer shell electrons.
(ii)
Suggest a reason why the compound formed between A and B in (ci) [2]
cannot be YZ2 of melting point of 1130oC?
5116/Prelim/2012
[Turn over
5
4
For
Examiners
Use
(a)
[1]
(b)
5116/Prelim/2012
[Turn over
6
5
For
Examiners
Use
[1]
(b)
[2]
(c)
Identify the reducing agent in the above extraction of germanium (IV) [1]
oxide.
(d)
[1]
(e)
(i)
525g of germanium (IV) oxide and 192 dm3 of hydrogen gas was [3]
supplied. Determine the limiting reactant in this reaction. Explain your
answer.
(ii)
[2]
Mass: ____________g
5116/Prelim/2012
[Turn over
7
6
For
Examiners
Use
(a)
[1]
(b)
Draw the graph to show the change in temperature during the reaction.
[1]
Figure 6
5116/Prelim/2012
Time / mins
[Turn over
8
7
For
Imagine that three metals are transported to Earth by rocket ship from a
Examiners
far distant planet. On the planet the three metals are called beium,
Use
Reaction with
water
Beium
Gas
sulfuric acid
extinguishes
extinguishes
magnesium sulfate
Magnesium
was
displaced
Ceium
pop sound
a pop sound
No reaction
Gas produced
extinguishes
displaced
No reaction
No reaction
Figure 7
(a)
Name the gas which extinguishes lighted splint with a pop sound.
[1]
(b)
(c)
(d)
Deium could be the same metal as one of the metals found in the Earths [1]
crust. Name one of Earths metals that might have similar properties as
deium.
5116/Prelim/2012
[Turn over
9
8
(a)
For
Examiners
Use
their source. Complete the table by giving the issues caused by each
chemical.
Chemical
Source
Oxides of nitrogen
Internal
engines
[2]
Problem caused
combustion
Incomplete
Breathing difficulties
death
due
obstruction
to
in
uptake of oxygen
Figure 8
(b)
(i)
Element X: ____________________
[1]
(ii)
Element Y: ____________________
[1]
5116/Prelim/2012
[Turn over
10
9
For
Examiners
Use
Glucose
Process I: Yeast, 37oC
Process IV:
Sufficient Oxygen
Forms white
precipitate in
Calcium hydroxide
solution
(a)
[1]
(b)
[2]
(c)
[1]
(d)
Identify R.
[1]
5116/Prelim/2012
[Turn over
11
Section B [20marks]
Answer any two questions from this section on the lined pages provided and, if necessary,
continue on separate answer paper.
10
(a)
For
Examiners
add dilute
sulfuric
acid
add water
and stir
colourless
solution
B
add copper(II)
sulfate
blue
precipitate
E
add
white solid
C
Use
colourless
solution
A
water
sodium
chloride
solution
water
colourless
gas D
blue
solution
(i)
[5]
(ii)
[1]
5116/Prelim/2012
[Turn over
12
10
(b)
copper(II)
nitrate,
Cu(NO3)2.3H2O,
from
copper(II)
(i)
Describe what you would see in step (1) when the above reaction is
[1]
carried out.
(ii)
[1]
(iii)
[1]
5116/Prelim/2012
[1]
[Turn over
13
11
(a)
For
Examiners
Use
(i)
[1]
(ii)
Based on your understanding of the homologous series, draw the full [1]
structural formula of propanol.
(b)
[2]
How would you test for presence of butene and differentiate it from [2]
propane? Give your observations.
(d)
(i)
(ii)
(iii)
(iv)
5116/Prelim/2012
[Turn over
14
12
For
Examiners
Use
(a)
Experiment
Volume
Concentration
Temperature
Reaction
number
of acid
of acid in
of acid
time
/cm3
mol/dm3
/ 0C
/ seconds
50
1.0
25
132
50
2.0
25
65
100
2.0
25
65
50
2.0
35
33
Which two experiments show that the volume of acid used does not [1]
affect the rate of reaction?
(b)
Describe and explain the effect of increasing temperature on the rate [2]
of reaction, in terms of collisions between reacting particles.
(c)
(i)
Write down the equation for the reaction between calcium carbonate [1]
and hydrochloric acid.
(ii)
(iii)
Calculate the mass of calcium carbonate that will react with this [2]
number of moles of hydrochloric acid.
(d)
(i)
Why does the rate of reaction between antacid tablets and [2]
hydrochloric acid gradually decreases as the reaction proceed?
(ii)
5116/Prelim/2012
[1]
[Turn over
15
Answers for Section B
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
5116/Prelim/2012
[Turn over
16
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
________________________________________________________________________________
---END OF PAPER---
5116/Prelim/2012
[Turn over
17
DATA SHEET
White
Light blue
Green
Red-brown
Lead(II) hydroxide
White
Zinc hydroxide
White
5116/Prelim/2012
[Turn over
18
5116/Prelim/2012
[Turn over