Name:___________________________

Reviseu SB 7171S LaBiake & vanuen Bout 2u1S

!"# %&'( ) *+,'- .(/01(0/+2 3.456 78+9/:2 3; <:=/'>'?@('9&2 "A 78+9/:
Fill in the chait below.
Nolecule N2 02 BF SeCl4


Lewis
Stiuctuie









vSEPR:
Electionic
geometiy of
cential
atom(s).

Lineai

Tiigonal Planai
B: Lineai
F: Tetiaheuial

Tiigonal
Bipyiamiual
vSEPR:
Noleculai
geometiy of
cential
atom(s).

Lineai

Lineai

Lineai

See-Saw
Is the
molecule
polai.
No No Yes Yes
What is the
pieuominate
INF.
Bispeision
Foices
Bispeision
Foices
B-
Bonuing
Bipole-Bipole
Foices
vB: What
types of bonus
aie in the
molecule.
What atomic
anuoi hybiiu
oibitals make
up each bonu.
1
!
" bonu:
N(sp) anu N(sp)
2 bonus:
N(2p) anu N(2p)
1
!
" bonu:
0(sp
2
) anu 0(sp
2
)
1 bonu:
0(2p) anu 0(2p)

1
!
" bonu:
B(1s) anu
F(sp
S
)

4
!
" bonus:
Se(sp
S
u) anu
Cl(sp
S
)

Name:___________________________


Reviseu SB 7171S LaBiake & vanuen Bout 2u1S




N0: Finu the
N0 uiagiam
foi the
molecule in a
book oi on the
website anu
fill it in.



The N0 uiagiam
foi this molecule
is moie
complicateu anu
goes beyonu the
scope of the
class. See this
website foi moie
info.
http://www.ch.ic.ac.uk/
vchemlib /course/
mo_theory/main.html


The N0 uiagiam
foi this molecule
is moie
complicateu anu
goes beyonu the
scope of the class.
See this website
foi moie info.
http://www.ch.ic.ac.uk/
vchemlib /course/
mo_theory/main.html
What is the
bonu oiuei.
Boes it
coiiesponu to
what you
founu in the
Lewis
stiuctuie anu
vB analysis.
B0=V(8-2)=S
YES, a B0 of S pieuicts
the tiiple bonu fiom
vSEPR anu vB.
B0=V(8-4)=2
YES, a B0 of 2 pieuicts
the uouble bonu fiom
vSEPR anu vB.

Biamagnetic
oi
Paiamagnetic.
Biamagnetic Paiamagnetic
Fill in the chait below.
Nolecule methane ethene ethyne 4-
aminobenzoic
aciu


Lewis
Stiuctuie




(Look it up!)

vSEPR:
Electionic
geometiy of
cential
atom(s).

Tetiaheuial

Tiigonal
Planai

Lineai

Tiigonal
Bipyiamiual
vSEPR:
Noleculai
geometiy of
cential
atom(s).

Tetiaheuial

Tiigonal
Planai

Lineai

See-Saw
Name:___________________________


Reviseu SB 7171S LaBiake & vanuen Bout 2u1S

Is the
molecule
polai.
No No No Yes
What is the
pieuominate
INF.
Bispeision
Foices
Bispeision
Foices
Bispeision
Foices
B-
Bonuing
vB: What
types of bonus
aie in the
molecule.
What atomic
anuoi hybiiu
oibitals make
up each bonu.

4
!
" bonus:
C(sp
S
) anu B(1s)

4
!
" bonus:
C(sp
2
) anu
B(1s)
1
!
" bonu:
C(sp
2
) anu
C(sp
2
)
1 bonu:
C(2p) anu
C(2p)
2
!
" bonus:
C(sp) anu
B(1s)
1
!
" bonu:
C(sp) anu
C(sp)
2 bonus:
C(2p) anu
C(2p)
1
!
" bonu:
0(sp
S
) &
C(sp
2
)
1
!
" bonu:
C(sp
2
) &
C(sp
2
)
1
!
" bonu:
0(sp
S
) &
C(sp
2
)
1
!
" bonu:
Cl(sp
2
) &
C(sp
2
)
1
!
" bonu:
N(sp
S
) &
C(sp
2
)
1
!
" bonu:
N(sp
S
) &
B(1s)
1 bonu:
0(sp) & C(2p)


N0: Finu the
N0 uiagiam
foi the
molecule in a
book oi on the
website anu
fill it in.

The N0 uiagiam
foi this molecule
is moie
complicateu anu
goes beyonu the
scope of the
class. See this
website foi moie
info.
http://www.ch.ic.ac.uk/
vchemlib /course/
mo_theory/main.html
The N0 uiagiam
foi this molecule
is moie
complicateu anu
goes beyonu the
scope of the class.
See this website
foi moie info.
http://www.ch.ic.ac.uk/
vchemlib /course/
mo_theory/main.html
The N0 uiagiam
foi this molecule
is moie
complicateu anu
goes beyonu the
scope of the
class. See this
website foi moie
info.
http://www.ch.ic.ac.uk/
vchemlib /course/
mo_theory/main.html
What is the
bonu oiuei.
Boes it
coiiesponu to
what you
founu in the
Lewis
stiuctuie anu
B0=V(8-u)=4
YES, a B0 of 4 pieuicts the 4
bonu fiom vSEPR anu vB.

Name:___________________________


Reviseu SB 7171S LaBiake & vanuen Bout 2u1S

vB analysis.
Biamagnetic
oi
Paiamagnetic.
Biamagnetic
The HOMO-LUMO gap of a molecule is equal to !E = 2 eV. What wavelength of
electromagnetic radiation do you expect it to absorb?

Work:
!
"E = 2eV(
1.60x10
#19
Js
1eV
) = 3.20x10
#19
Js
E =
hc
$
$ =
hc
E
$ =
(6.626x10
#34
Js)(3x10
8
m
s
)
3.2x10
#19
J
= 6.20x10
#7
m = 620nm


A molecule absorbs light of " = 490 nm. What do you predict is the HOMO-LUMO gap of that
molecule?
Work:
!
"E
H#L
= E
photon
E
photon
=
hc
$
E
photon
=
(6.626x10
#34
Js)(3x10
8
m
s
)
4.9x10
#7
J
= 4.06x10
#19
J
"E
H#L
= E
photon
= 4.06x10
#19
J(
1eV
1.60x10
#19
J
) = 2.53eV