Você está na página 1de 3

The enthalpy of fusion of ice is 6.020 kJ/mol. The heat capacity of liquid water is 75.4 J/molC. What is the?

The enthalpy of fusion of ice is 6.020 kJ/mol. The heat capacity of liquid water is 75.4 J/molC. What is the smallest number of ice cubes at 0C, each containing one mole of water, necessary to cool 500 g of liquid water initially at 20C to 0C? The only unknown is the conversion from 500g of H2O to moles of H2O At wt of H = 1 at wt of O =16 so H2O = 18g/mole 500g/18g/mole = 27.8moles to cool 27.8 moles 20deg = 27.8mole x 75.4 J/mole.deg x 20 deg 41,922J are needed to cool the water 41.922kJ/6.02kJ = 7 therefore 7 moles of ice cubes (7 cubes) will be needed 30mL of pure water at 280. K is mixed with 50.0 mL of pure water at 330. K. What is the final temperature of t The first answer you got is for sure wrong, since to make his equation satisfied, both sides of his equation must be both positive or negative, that means either T > 330K or T < 280K. But we know for sure that the correct answer should have temperature between 280K and 330K. The right equation is: 30*(T-280) = 50.0*(330-T) or: 80*T = 50.0*330+30*280 or: T = (50.0*330+30*280)/80 = 311.25 311 (K) 127. When a reactions occurs between two substances and thetemperature of the reaction mixture decreases, it means that thereaction is absorbing the heat of the surroundings as itprogresses. This means it is an endothermic reaction. So the correct answer is C What is the heat capacity of mercury if it requires 167 J to change the temperature of 15.0 g mercury from 25.? Additional Details What is the heat capacity of mercury if it requires 167 J to change the temperature of 15.0 g mercury from 25.0 degrees C to 33.0 degrees C? delta T = 8.0 deg C (33.0-25.0 = 8.0) 167 J = 15.0 g x 8.0 deg x heat capacity Hg heat capacity = 1.39 J/gC The heat of formation of Fe2O3(s) is -826 KJ/mol. Calculate the heat of the reaction? 4Fe(s)+3O2(g) --> 2Fe2O3(s) when a 55.8 g sample of iron is reacted Molar mass Fe = 55.8g/mol You have 1 mol Fe From the balanced equation: 4mol Fe will produce 2molFe2O3 1mol Fe will produce 0.5mol Fe2O3 Heat of reaction: 826/2 = 413kJ of energy produced. When 0.157 mol of NH3 is reacted with excess HCl, 6.91 kJ o f energy is released as heat. What is H? When 0.157 mol of NH3 is reacted with excess HCl, 6.91 kJ of energy is released as heat. What is H for this reaction per mol e of NH3 consumed? Since 6.91 KJ is released as heat, meaning that H=E. So we have that H= -6.91. Negative because it is released. Then you have to fine per mole, so you divide H/moles, -6.91kJ/.157 mols= -44kJ Calorimetry question...? A 4.0 g sample of Colorado oil shale is burned in a bomb calorimeter, which causes the temperature of the calorimeter to increase by 5.0 degrees Celsius. The calorimeter contains 1.00 kg of water (C_water=4.184 J/g degrees Celsius) and the heat capacity of the empty calorimeter is .1 kJ/degree Celsius. How much heat is released per gram of oil shale when it is burned? Hello again, ok this was fun... q(rxn) = - [ q(water) + q(bomb) ] {the energy of the reaction is equal to the energy of the water plus the bomb.} We know the change of temperature (delta T) from the problem, so the rest is just plug-n-chug. q(rxn) = - { [ (1000g)(4.184)(5.0) ] + [ (5.0)(0.10) ] } q(rxn) = - ( 20920 + 0.5 ) Now we divide by 4.0 since that was the grams present and our equation needs to result in how much energy per gram. q(rxn) = - ( 20920.5) / ( 4.0 grams) q(rxn) = - 5230.125

And our final answer, changing it to Kilo joules to keep units is... -q(rxn) = 5.23 KJ/gram If a student performs an endothermic reaction in a calorimeter.... (please help!)?

how does the calculated value of H differ from the actual of the heat exc hanged with the calorimeter is not taken into account? a) H would be more negative because the calorimeter always absorbs heat from the reaction b)H would be less negative because the calorimeter would absorb heat from the reaction c)H would be more positive because the reaction absorbs heat from the calorimeter d)H would be less positive because the reaction absorbs heat from the calorimeter e)H would be equal to the actual value because the calorimeter does not absorb the heat an endothermic reaction is one in which energy goes endo the system .... the delta H should show that energy went into it. delta H should show an increase, which is a positive delta H delta H experiments are usually run in water, in which case in an endothermic reaction both the water and the calorimeter give energy to the reaction system under study. in an endothermic reaction, if you only measure the energy lost from the water to the system... it won't be enough... because: c)H should be more positive because the reaction also absorbed heat from the calorimeter A bomb calorimeter has a heat capacity of 2.47 kJ/K. When a 0.106-gsample of ethylene (C2H4) was burned in thiscalorimeter, the temperature increased by 2.14 K. Calculate theenergy of combustion for 1 mol of ethylene. I would use the equations q=ct and q=mst to solvethis problem. 1.find the amount of energy given off usingq=ct c is heatcapacity ( 2.47 KJ/K)(2.14K)=q=5.2858 KJ 2. use q to find the specific heat of ethelene usingq=mst rearrange to gets=q/(m*t) 5.2858 KJ/[(.106 g)(2.14K)]=s=23.3019KJ/g*K 3. find the molecular mass of one mol of ethelene 2*12.01+1.008*4=28.052 gin one mol 4. substitute new information into q=mst m=28.052 g s=23.3019 KJ/g*K t=2.14K q=(28.052g)(23.3019KJ/g*K)(2.14K)=1398.84 KJare given off -1.40*10^3kJ/mol is the correct answer, q=c?t (2.47kJ/K)(2.14K) q=-5.2858kJ/.003777619*10^-3mol=-1.40*10^3kJ/mol Which of the following does not have a standard enthalpy of formation equal to zero at 25C and 1.0 atm..? Which of the following does not have a standard enthalpy of formation equal to zero at 25C and 1.0 atm? A) F2(g) B) Al(s) C) H2O(l) D) H2(g) E) They all have a standard enthalpy equal to zero. H2O will not have a standard enthalpy of zero as only things in their elemental form at standard conditions have a enthalpy of zero.

How much heat is required to raisethe temperature of a 6.21-g sample of iron (specific heat = 0.450J/(g C) from 25.0C to 79.8C? Formula: Heat required = specific heat *Amount of sample * T Given specific heat = 0.450 J/g C Amount of sample = 6.21-g T = 79.8C - 25.0C = 54.8 C Heatrequired = 0.450 J/g C * 54.8 C * 6.21-g = 153.13 J So "E" is the answer. Thermochemistry, calorimetry? A 25.0 g piece of aluminum (which has a molar heat capacity of 24.03J/Cmol) is heated to 82.4C and dropped into a calorimeter containing water (specific heat capacity of water is 4.18J/gC) initially at 22.3C. The final temperature of the water is 24.9C. Calculate the mass of water in the calorimeter. the answer is 118 g. can you show me how to get to the answer? remember: q = m*c*dT First I converted 24.03J/Cmol to grams (24.03J/Cmol) * (1 mol Al/27g Al)= 0.89J/Cg The final temp of water will be the same as the final temp of aluminum q(aluminum) = 25g * 0.89J/Cg * (24.9C - 82.4C) = -1279.375 J

q(water) = +1279.375 J = m * 4.18J/gC * (24.9C - 22.3C) 1279.375 = 10.868m m = 117.72 grams of water which is almost 118g. Chemistry help - specific heat capatity? I need to know how to do these two types of problems: 1) A 44.8 g piece of Aluminum (which has a molar heat capacity of 24.03 J/C*mol) is heated to 82.4 C and dropped into a calorimeter containing water ( 4.18 J/g*C) initially at 22.3 C. The final temperature of the water is 24.9C. Calculate the mass of water in the calorimeter. 2) A 40.2 g sample of a metal is heated to 99.3 C and then placed in a calorimeter containing 120.0 g of water ( 4.18 J/g*C) at 21.8 C. The final temperature of the water is 24.5 C. What is the specific heat capacity of the metal? Thank You 1) heat loss by aluminium=44.8g(1mole/26.98g)(24.03J/C*m 2294.34J heat gain by water=2294.34J=m(4.18J/g*C)(2.6C) m=211.11g of Water 2)120g(4.18J/g*C)(2.7C)=1354.32J c=q/(m*deltaT) c=1354.32J/((40.2g)[(99.3C-24.5C)])= .450395J/g*C

Você também pode gostar