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WEBA Technology
1213 N Sherman Ave #351 Madison, WI 53704 USA Tel: 608-819-8806 Fax: 608-237-2054 www.webacorp.com
Copyright 2003 WEBA Technology All rights reserved. No part of this manual may be reproduced in any form by any means, mechanical or electronic, including: recording, photocopying or any storage and retrieval, without per mission in writing from WEBA Technology.
WEBA Technology 1213 N Sherman Ave #351 Madison, WI 53704 USA Tel: 608-819-8806 Fax: 608-237-2054 www.webacorp.com
Table of Contents
TECHNICAL MANUAL Glycol-Based Heat Transfer Fluid Technical Manual Introduction Why Choose WEBA Technology's Heat Transfer Fluids? Applications Heavy Duty Industrial Service Applications - HVAC Applications - Food Grade Burst Protection HVAC Coolants Choose Between Ethylene Glycol-Based & Propylene Glycol-Based Coolants Available as Concentrate or Dilution Analytical Services General System Design and Equipment Considerations Operating Temperature Preparation of Existing Systems for Heat Transfer Fluids Preparation of New Systems for Heat Transfer Fluids Water Quality Considerations Safety, Handling, Storage, and Disposal of Heat Transfer Fluids 6 6 7 7 8 9 10 10 11 12 13 13 13 14 15
APPENDICES SECTION 1: Physical Properties and Engineering Data for WEBA Technology Ethylene Glycol-Based Heat Transfer Fluids 17 Figure 1: Freezing points of aqueous solutions of ethylene glycol-based heat transfer uid products. Figure 2: Boiling points of aqueous solutions of ethylene glycol-based heat transfer uid products. Figure 3: Typical concentrations of ethylene glycol heat transfer uids required to provide freeze and burst protection at various temperatures. Figure 4: Ethylene glycol concentration versus freezing points and boiling points. Figure 5: Graph - Thermal conductivity of aqueous solutions of ethylene glycol-based heat transfer uids. Figure 6: Chart - Thermal conductivity of aqueous solutions of ethylene glycol-based heat transfer uids. Figure 7: Graph - Specic heat of aqueous solutions of ethylene glycol-based heat transfer uids. Figure 8: Chart - Specic heat of aqueous solutions of ethylene glycol-based heat transfer uids.
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Figure 9: Film coefcients for ethylene glycol-based heat transfer uids at 30 percent (volume). Figure 10: Film coefcients for WEBA Technology ethylene glycol-based heat transfer uids at 40 percent (volume). Figure 11: Film coefcients for WEBA Technology ethylene glycol-based heat transfer uids at 50 percent (volume).
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SECTION 2: Physical Properties and Engineering Data for WEBA Technology Propylene Glycol-Based Heat Transfer Fluids Figure 1: Freezing points of aqueous solutions of propylene glycol-based heat transfer uid products. Figure 2: Boiling points of aqueous solutions of propylene glycol-based heat transfer uid products. Figure 3: Typical concentrations of propylene glycol heat transfer uids required to provide freeze and burst protection at various temperatures. Figure 4: Propylene glycol concentration versus freezing points and boiling points. Figure 5: Graph - Thermal conductivity of aqueous solutions of concentrated propylene glycol-based heat transfer uids. Figure 6: Graph - Thermal conductivity of aqueous solutions of 70% heavy duty propylene glycol-based heat transfer uids. Figure 7: Chart - Thermal conductivity of aqueous solutions of propylene glycol-based heat transfer uids. Figure 8: Graph - Specic heat of aqueous solutions of concentrated propylene glycol-based heat transfer uids. Figure 9: Graph - Specic heat of aqueous solutions of 70% heavy duty propylene glycol-based heat transfer uids. Figure 10: Chart - Specic heat of aqueous solutions of propylene glycol-based heat transfer uids.
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Figure 11: Film coefcients for propylene glycol-based heat transfer uids at 30 percent (volume). Figure 12: Film coefcients for propylene glycol-based heat transfer uids at 40 percent (volume). Figure 13: Film coefcients for propylene glycol-based heat transfer uids at 50 percent (volume).
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HVAC system freeze/burst/corrosion protection Cold room dehumidifying systems Refrigeration coil defrosting Process cooling Conveyor roller defrosting Ice skating rink refrigeration systems Process heating Air preheating Waste heat recovery Sidewalk snow melting systems Solar heating Refrigeration warehouse oor heating
At a treat rate of 6% METALGUARD H50 additive package in ethylene glycol is ideal for a wide variety of applications. Most common heavy-duty applications are as corrosion-inhibiting coolants for large stationary engines which drive the compressors used in the transmission of natural gas and other products through pipeline distribution systems. Nitrite can be added to your nished product to meet additional chemical requirements of some systems. Uses at the higher treat rate include:
Small eld compression units Utility combustion air preheaters Utilities using LPG bath heaters Line heaters to prevent formation of hydrates in natural gas or other hydrocarbons Electricity-producing engine generator sets in nuclear or conventional power plants, hospitals, shopping centers, or installations that require standby power Industrial diesel engines that use non-aluminum cooling systems
Generally, WEBA Technology's heat transfer uids can be used whenever needed to provide freeze protection, minimize vaporization at high temperatures, and protect systems from boiling and corrosion.
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color appearance irregularities glycol concentration and type glycol degradation by-products freeze point pH reserve alkalinity inhibitor types and concentrations water quality ion contamination
We will describe what specic actions should be taken if any deciencies are indicated. These actions may include:
adding glycol to maintain freeze protection increasing the pH adding inhibitor concentrate to restore specic inhibitor levels and/or the reserve alkalinity
We will also assist you in establishing the capability for conducting uid monitoring tests at your facility.
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Operating Temperature
WEBA Technology heat transfer uids have an effective operating bulk temperature range of -50F to 350F. At temperatures below -50F, larger pumps may be needed to overcome the increased viscosity of the uids, Film temperatures should not exceed the average bulk temperature by more than 50F. Brief temperature excursions of up to 100F above the 350F recommended upper limit are tolerable, but extended exposure exceeding 50F above the limit will accelerate degradation of the glycol and inhibitor system. The pressure at all points in the system should be at least 5psi greater than the vapor pressure exerted by the coolant to avoid localized boiling and resulting precipitation. At temperatures above 150F, the system must be closed to avoid rapid evaporation of water, oxidation of the glycol, inhibitor depletion, and subsequent increased corrosion.
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Drum Storage - WEBA Technology heat transfer uids can be stored in the drums in which they are shipped. Because glycols are hygroscopic (water attracting), water should be prevented from contaminating the drums. If temperatures are anticipated to fall below 50F, drums should be stored in a heated building to prevent freezing or pumping problems. Environmental Considerations Ethylene glycol and propylene glycol have been found to be biodegradable and should not concentrate in common water systems. However, ethylene glycol has been classied as a hazardous material by the US EPA and DOT. Shipments of 5,000 pounds of more in one container must be placarded, and spills of 5,000 pounds or more must be immediately reported to the appropriate regulatory agency in your area. The biochemical oxygen demand approaches the theoretical oxygen demand value in the standard 20-day test period for both glycol types. However, since rapid oxygen depletion may be harmful to aquatic organisms, the possibility of spills in lakes or rivers should be avoided. Extensive testing has shown ethylene glycol and propylene glycol to be virtually nontoxic to aquatic organisms.
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Spill, Leak, and Disposal Procedures - With appropriate safety equipment, common absorbent material should be used to soak up small spills. Large spills should be pumped into suitable containers located in diked areas and residual material cleaned up with water. Concentrate can be handled according to local, state, and federal regulations. Salvage - If spent uids are not otherwise contaminated, local regulations usually permit their disposal in local sewage treatment facilities, provided these facilities are notied and prepared in advance. Aerobic bacteria easily oxidize the uids to carbon dioxide and water within the usual 20-day test period. Check with local, state, and federal authorities to determine the regulations in your area. When disposing of the additive packages themselves, be sure to reference the safety data sheet for each product and dispose of accordingly.
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SECTION 1 Physical Properties and Engineering Data for WEBA Technology's Ethylene Glycol-Based Heat Transfer Fluids
Figure 1: Freezing points of aqueous solutions of ethylene glycol-based heat transfer uid products. Figure 2: Boiling points of aqueous solutions of ethylene glycol-based heat transfer uid products. Figure 3: Typical concentrations of ethylene glycol heat transfer uids required to provide freeze and burst protection at various temperatures. Figure 4: Ethylene glycol concentration versus freezing points and boiling points. Figure 5: Graph - Thermal conductivity of aqueous solutions of WEBA Corp ethylene glycol-based heat transfer uids. Figure 6: Chart - Thermal conductivity of aqueous solutions of WEBA Corp ethylene glycol-based heat transfer uids. Figure 7: Graph - Specic heat of aqueous solutions of ethylene glycol-based heat transfer uids. Figure 8: Chart - Specic heat of aqueous solutions of ethylene glycol-based heat transfer uids. Figure 9: Film coefcients for ethylene glycol-based heat transfer uids at 30 percent (volume). Figure 10: Film coefcients for ethylene glycol-based heat transfer uids at 40 percent (volume). Figure 11: Film coefcients for WEBA Technology ethylene glycol-based heat transfer uids at 50 percent (volume).
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Figure 1
Freezing points of aqueous solutions of WEBA Technology's ethylene and propylene glycol-based heat transfer uid products.
+40
+4.4
+30
-1.1
+20
-6.7
+10
-12.2
-17.8
-23.3
-20
Temperature, F
-28.9
-34.5
-40.0
-50
-45.6
-60
-51.1
-70
-56.7
10
20
30
40
50
Volume, Percent
60
70
80
90
Freezing Point The freezing points for glycols are the temperatures at which ice crystals rst form. Below these temperatures, a slushy solution of glycol ice crystals and liquid will still permit ow and provide coolant protection. However, as the temperature decreases, the slush becomes more and more viscous until solid freezing takes place.
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Figure 2
Boiling points of aqueous solutions of WEBA Technology's ethylene and propylene glycol-based heat transfer uid products.
350 340
330 320
310 300
290 280
270
230 Heat Transfer Fluid Propylene Glycol 220 210 200 0 10 20 30 40 50 60 70 80 90 100
Vapor Pressure and Boiling Point As liquids vaporize, pressure is exerted which increases as temperature increases. Aqueous solutions of WEBA Technology heat transfer uid products have vapor pressures lower than water and boiling points above water. However, aqueous solutions of WEBA Technology heat transfer uid products have vapor pressures close to that of water because of the water in the solution. Actually, the vapor pressure of the glycol by itself is much less. As a result, these solutions will tend to lose water by evaporation as temperature rises above the dew point. Because glycols are hygroscopic (attract water molecules), the uids pick up water molecules from the air and dilute the solution (lowering the boiling point) as the temperature drops below the dew point. Closed systems of course, reduce this potential problem.
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Figure 3
Typical concentrations of WEBA Technology's ethylene glycol heat transfer uids required to provide freeze and burst protection at various temperatures.
Percent (Volume) Glycol Concentration Required For Freeze Protection Temperature F 20 10 0 -10 -20 -30 -40 -50 -60 For Burst Protection
Heat Transfer Fluid Heat Transfer Fluid Ethlyene Glycol Ethlyene Glycol 16% 25 33 39 44 48 52 56 60 11% 17 22 26 30 30 30 30 30
Note It is usually prudent to select your required uid concentration by picking a temperature at least 5F below the lowest expected operating temperature. Note that if you select a solution containing less than 30% glycol, more inhibitor should be added to inhibit the additional water. Consult WEBA Technology for details.
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Figure 4
Ethylene Glycol Concentration versus Freezing Points and Boiling Points
Wt. % Ethylene Glycol 0.0 5.0 10.0 15.0 20.0 21.0 22.0 23.0 24.0 25.0 26.0 27.0 28.0 29.0 30.0 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 39.0 40.0 41.0 42.0 43.0 44.0 45.0 46.0 47.0 48.0 49.0 50.0 51.0 52.0 53.0 54.0 55.0 56.0 57.0 58.0 59.0 60.0 65.0 70.0 75.0 80.0 85.0 90.0 95.0 Vol. % Ethylene Glycol 0.0 4.4 8.9 13.6 18.1 19.2 20.1 21.0 22.0 22.9 23.9 24.8 25.8 26.7 27.7 28.7 29.6 30.6 31.6 32.6 33.5 34.5 35.5 36.5 37.5 38.5 39.5 40.5 41.5 42.5 43.5 44.5 45.5 46.6 47.6 48.6 49.6 50.6 51.6 52.7 53.7 54.7 55.7 56.8 57.8 62.8 68.3 73.6 78.9 84.3 89.7 95.0 Wt. % HTF-EG 0.0 5.2 10.5 15.7 20.9 22.0 23.0 24.1 25.1 26.2 27.2 28.3 29.3 30.4 31.4 32.5 33.5 34.6 35.6 36.6 37.7 38.7 39.8 40.8 41.9 42.9 44.0 45.0 46.1 47.1 48.2 49.2 50.2 51.3 52.4 53.4 54.5 55.5 56.4 57.6 58.6 59.7 60.7 61.8 62.8 68.0 73.3 78.5 83.8 89.0 94.2 99.5 Vol. % HTF-EG 0.0 4.6 9.3 14.2 19.0 20.1 21.0 22.0 23.0 24.0 25.0 26.0 27.0 28.0 29.0 30.2 31.0 32.0 33.1 34.1 35.1 36.1 37.2 38.2 39.3 40.3 41.4 42.4 43.5 44.5 45.5 46.6 47.6 48.8 49.8 50.9 51.9 53.0 54.0 55.2 56.2 57.3 58.3 59.5 60.5 65.8 71.5 77.1 82.6 88.3 93.9 99.5 Freezing Point F 32.0 29.4 26.2 22.2 17.9 16.8 15.9 14.9 13.7 12.7 11.4 10.4 9.2 8.0 6.7 5.4 4.2 2.9 1.4 -0.2 -1.5 -3.0 -4.5 -6.4 -8.1 -9.8 -11.7 -13.5 -15.5 -17.5 -19.8 -21.6 -23.9 -26.7 -28.9 -31.2 -33.6 -36.2 -38.8 -42.0 -44.7 -47.5 -50.0 -52.7 -54.9 * * * -52.2 -34.5 -21.6 -3.0 Boiling Point F @ 760 mm Hg 212 213 214 215 216 216 216 217 217 218 218 218 219 219 220 220 220 220 220 221 221 221 221 221 222 222 222 223 223 224 224 224 224 224 225 225 225 226 226 227 227 228 228 229 230 235 242 248 255 273 285 317 Refractive Index 72F 1.3328 1.3378 1.3428 1.3478 1.3530 1.3540 1.3551 1.3561 1.3572 1.3582 1.3593 1.3603 1.3614 1.3624 1.3635 1.3646 1.3656 1.3667 1.3678 1.3688 1.3699 1.3709 1.3720 1.3730 1.3741 1.3752 1.3763 1.3774 1.3785 1.3796 1.3807 1.3817 1.3828 1.3838 1.3849 1.3859 1.3869 1.3879 1.3890 1.3900 1.3910 1.3921 1.3931 1.3942 1.3952 1.4003 1.4055 1.4107 1.4159 1.4208 1.4255 1.4300
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Figure 5
Thermal conductivity (Btu/(hrft2)(F/ft)) of aqueous solutions of WEBA Technology's ethylene glycol-based heat transfer uids. (volume percent ethylene glycol)
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Figure 6
Thermal conductivity (Btu/(hrft2)(F/ft)) of aqueous solutions of ethylene glycol-based heat transfer fluids (volume percent ethylene glycol).
Volume Percent Ethylene Glycol Temp. F -30 -20 -10 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 250 0% 10% 20% 30% 40% 50% 0.193 0.197 0.200 0.204 0.207 0.210 0.212 0.215 0.218 0.220 0.223 0.225 0.227 0.229 0.230 0.232 0.233 0.235 0.236 0.237 0.238 0.239 0.240 0.240 0.240 0.241 0.241 0.241 60% 0.178 0.181 0.184 0.186 0.176 0.191 0.194 0.196 0.198 0.200 0.202 0.204 0.206 0.208 0.209 0.210 0.212 0.213 0.214 0.215 0.216 0.217 0.218 0.218 0.219 0.219 0.219 0.219 0.220 70% 0.167 0.170 0.172 0.174 0.176 0.178 0.180 0.182 0.183 0.185 0.186 0.188 0.189 0.190 0.192 0.193 0.194 0.195 0.196 0.197 0.197 0.198 0.199 0.199 0.200 0.200 0.200 0.200 0.201 80% 0.158 0.160 0.161 0.163 0.164 0.166 0.167 0.169 0.170 0.171 0.172 0.173 0.174 0.175 0.176 0.177 0.178 0.179 0.180 0.180 0.181 0.181 0.182 0.182 0.183 0.183 0.183 0.184 0.184 90% 0.151 0.152 0.153 0.154 0.155 0.156 0.157 0.158 0.159 0.160 0.161 0.161 0.162 0.163 0.163 0.164 0.165 0.165 0.166 0.166 0.167 0.167 0.168 0.168 0.168 0.169 0.169 0.169
0.328 0.335 0.341 0.347 0.352 0.358 0.362 0.367 0.371 0.374 0.378 0.381 0.384 0.386 0.388 0.389 0.391 0.391 0.392 0.392 0.392 0.392
0.294 0.300 0.305 0.311 0.316 0.329 0.325 0.329 0.333 0.336 0.339 0.342 0.345 0.347 0.349 0.351 0.352 0.353 0.354 0.355 0.355 0.355 0.354
0.264 0.269 0.274 0.279 0.284 0.288 0.292 0.296 0.299 0.302 0.305 0.308 0.311 0.313 0.315 0.316 0.318 0.319 0.320 0.321 0.321 0.322 0.322 0.321
0.238 0.243 0.247 0.251 0.255 0.259 0.263 0.266 0.269 0.272 0.275 0.277 0.280 0.282 0.284 0.285 0.287 0.288 0.289 0.290 0.291 0.291 0.291 0.291 0.291
0.216 0.220 0.224 0.227 0.231 0.234 0.237 0.240 0.243 0.246 0.248 0.251 0.253 0.255 0.256 0.258 0.259 0.261 0.262 0.263 0.263 0.264 0.265 0.265 0.265 0.265
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Figure 7
Specic heat (Btu/(lbF)) of aqueous solutions of WEBA Technology's ethylene glycol-based heat transfer uids. (volume percent ethylene glycol)
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Figure 8
Specific Heat (Btu/(lb F)) of aqueous solutions of ethylene glycol-based heat transfer fluids.
Volume Percent Ethylene Glycol Temp. F -30 -20 -10 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 250 0% 10% 20% 30% 40% 50% 0.739 0.744 0.749 0.754 0.759 0.765 0.770 0.775 0.780 0.785 0.790 0.795 0.800 0.806 0.811 0.816 0.821 0.826 0.831 0.836 0.842 0.847 0.852 0.857 0.862 0.867 0.872 0.877 60% 0.680 0.686 0.692 0.698 0.703 0.709 0.715 0.721 0.727 0.732 0.738 0.744 0.750 0.756 0.761 0.767 0.773 0.779 0.785 0.790 0.796 0.802 0.808 0.813 0.819 0.825 0.831 0.837 0.842 70% 0.625 0.631 0.638 0.644 0.651 0.657 0.664 0.670 0.676 0.683 0.689 0.696 0.702 0.709 0.715 0.721 0.728 0.734 0.741 0.747 0.754 0.760 0.766 0.773 0.779 0.786 0.792 0.799 0.805 80% 0.567 0.574 0.581 0.588 0.595 0.603 0.610 0.617 0.624 0.631 0.638 0.645 0.652 0.659 0.666 0.673 0.680 0.687 0.694 0.702 0.709 0.716 0.723 0.730 0.737 0.744 0.751 0.758 0.765 90% 0.515 0.523 0.530 0.538 0.546 0.553 0.561 0.569 0.576 0.584 0.592 0.600 0.607 0.615 0.623 0.630 0.638 0.646 0.654 0.661 0.669 0.677 0.684 0.692 0.700 0.708 0.715 0.723
1.004 1.001 1.000 0.999 0.998 0.998 0.998 0.998 0.998 0.999 0.999 1.000 1.001 1.002 1.003 1.004 1.005 1.007 1.008 1.010 1.012 1.014
0.940 0.943 0.945 0.947 0.950 0.950 0.954 0.957 0.959 0.961 0.964 0.966 0.968 0.971 0.973 0.975 0.978 0.980 0.982 0.985 0.987 0.989 0.992
0.897 0.900 0.903 0.906 0.909 0.912 0.915 0.918 0.922 0.925 0.928 0.931 0.934 0.937 0.940 0.943 0.946 0.949 0.952 0.955 0.958 0.961 0.964 0.967
0.849 0.853 0.857 0.861 0.864 0.868 0.872 0.876 0.880 0.883 0.887 0.891 0.895 0.898 0.902 0.906 0.910 0.913 0.917 0.921 0.925 0.929 0.932 0.936 0.940
0.799 0.803 0.808 0.812 0.816 0.821 0.825 0.830 0.834 0.839 0.843 0.848 0.852 0.857 0.861 0.865 0.870 0.874 0.879 0.883 0.888 0.892 0.897 0.901 0.905 0.910
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Figure 9
Film coefcients for WEBA Technology's heat transfer uids at 30% (volume) ethylene glycol.
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Figure 10
Film coefcients for WEBA Technology heat transfer uids at 40% (volume) ethylene glycol.
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Figure 11
Film coefcients for WEBA Technology's heat transfer uids at 50% (volume) ethylene glycol.
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SECTION 2 Physical Properties and Engineering Data for WEBA Technology's Propylene Glycol-Based Heat Transfer Fluids
Figure 1: Freezing points of aqueous solutions of propylene glycol-based heat transfer uid products. Figure 2: Boiling points of aqueous solutions of propylene glycol-based heat transfer uid products. Figure 3: Typical concentrations of propylene glycol heat transfer uids required to provide freeze and burst protection at various temperatures. Figure 4: Propylene glycol concentration versus freezing points and boiling points. Figure 5: Graph - Thermal conductivity of aqueous solutions of WEBA Corp concentrated propylene glycol-based heat transfer uids. Figure 6: Graph - Thermal conductivity of aqueous solutions of WEBA Corp 70% heavy duty propylene glycol-based heat transfer uids. Figure 7: Chart - Thermal conductivity of aqueous solutions of WEBA Corp propylene glycol-based heat transfer uids. Figure 8: Graph - Specic heat of aqueous solutions of concentrated propylene glycol-based heat transfer uids. Figure 9: Graph - Specic heat of aqueous solutions of 70% heavy duty propylene glycol-based heat transfer uids. Figure 10: Chart - Specic heat of aqueous solutions of propylene glycol-based heat transfer uids. Figure 11: Film coefcients for propylene glycol-based heat transfer uids at 30 percent (volume). Figure 12: Film coefcients for propylene glycol-based heat transfer uids at 40 percent (volume). Figure 13: Film coefcients for propylene glycol-based heat transfer uids at 50 percent (volume).
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Figure 1
Freezing points of aqueous solutions of WEBA Technology's ethylene and propylene glycol-based heat transfer uid products.
+40
+30
+20
+10
-20
Temperature, F
-50
-60
-70
10
20
30
40
50
Volume, Percent
60
70
80
90
Freezing Point The freezing points for glycols are the temperatures at which ice crystals rst form. Below these temperatures, a slushy solution of glycol ice crystals and liquid will still permit ow and provide coolant protection. However, as the temperature decreases, the slush becomes more and more viscous until solid freezing takes place.
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Figure 2
Boiling points of aqueous solutions of WEBA Technology's ethylene and propylene glycol-based heat transfer uid products.
350 340
330 320
310 300
290 280
270
230 Heat Transfer Fluid Propylene Glycol 220 210 200 0 10 20 30 40 50 60 70 80 90 100
Vapor Pressure and Boiling Point As liquids vaporize, pressure is exerted which increases as temperature increases. Aqueous solutions of WEBA Technology heat transfer uid products have vapor pressures lower than water and boiling points above water. However, aqueous solutions of WEBA Technology heat transfer uid products have vapor pressures close to that of water because of the water in the solution. Actually, the vapor pressure of the glycol by itself is much less. As a result, these solutions will tend to lose water by evaporation as temperature rises above the dew point. Because glycols are hygroscopic (attract water molecules), the uids pick up water molecules from the air and dilute the solution (lowering the boiling point) as the temperature drops below the dew point. Closed systems of course, reduce this potential problem.
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Figure 3
Typical concentrations of WEBA Technology's propylene glycol heat transfer uids required to provide freeze and burst protection at various temperatures.
Percent (Volume) Glycol Concentration Required For Freeze Protection Temperature F 20 10 0 -10 -20 -30 -40 -50 -60 42 46 50 54 57 60 For Burst Protection
Heat Transfer Fluid Heat Transfer Fluid Propylene Glycol Propylene Glycol 18% 29 36 28 30 33 35 35 35 12% 20 24
Note It is usually prudent to select your required uid concentration by picking a temperature at least 5F below the lowest expected operating temperature. Note that if you select a solution containing less than 30% glycol, more inhibitor should be added to inhibit the additional water. Consult WEBA Technology for details.
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Figure 4
Propylene Glycol Concentration versus Freezing Points and Boiling Points
Wt. % Propylene Glycol 0.0 5.0 10.2 15.0 20.0 21.0 22.0 23.0 24.0 25.0 26.0 27.0 28.0 29.0 30.0 31.0 32.0 33.0 34.0 35.0 36.0 37.0 38.0 39.0 40.0 41.0 42.0 43.0 44.0 45.0 46.0 47.0 48.0 49.0 50.0 51.0 52.0 53.0 54.0 55.0 56.0 57.0 58.0 59.0 60.0 65.0 70.0 75.0 80.0 85.0 90.0 95.0 Vol. % Propylene Glycol 0.0 4.8 9.6 14.5 19.4 20.4 21.4 22.4 23.4 24.4 25.3 26.4 27.4 28.4 29.4 30.4 31.4 32.4 33.5 34.4 35.5 36.5 37.5 38.5 39.6 40.6 41.6 42.6 43.7 44.7 45.7 46.8 47.8 48.9 49.9 50.9 51.9 53.0 54.0 55.0 56.0 57.0 58.0 59.0 60.0 65.0 70.0 75.0 80.0 85.0 90.0 95.0 Wt. % HTF-PG 0.0 5.2 10.5 15.7 20.9 22.0 23.0 24.0 25.1 26.1 27.2 28.2 29.3 30.3 31.4 32.4 33.5 34.5 35.5 36.6 37.6 38.7 39.7 40.8 41.8 42.9 43.9 45.0 46.0 47.0 48.1 49.1 50.2 51.2 52.3 53.3 54.4 55.4 56.5 57.5 58.5 59.6 60.6 61.7 62.7 68.0 73.2 78.4 83.6 88.9 94.1 99.3 Vol. % HTF-PG 0.0 5.0 10.0 15.1 20.3 21.3 22.4 23.4 24.5 25.5 26.5 27.6 28.6 29.7 30.7 31.8 32.8 33.9 35.0 36.0 37.1 38.2 39.2 40.3 41.4 42.4 43.5 44.5 45.7 46.7 47.8 48.9 50.0 51.1 52.2 53.2 54.3 55.4 56.5 57.5 58.5 59.6 60.6 61.7 62.7 68.0 73.2 78.4 83.6 88.9 94.1 99.3 Freezing Point F 32.0 29.1 26.1 22.9 19.2 18.3 17.6 16.6 15.6 14.7 13.7 12.6 11.5 10.4 9.2 7.9 6.6 5.3 3.9 2.4 0.8 -0.8 -2.4 -4.2 -6.0 -7.8 -9.8 -11.8 -13.9 -16.1 -18.3 -20.7 -23.1 -25.7 -28.3 -31.0 -33.8 -36.7 -39.7 -42.8 -46.0 -49.3 -52.7 -56.2 -59.9 <-60.0 <-60.0 <-60.0 <-60.0 <-60.0 <-60.0 <-60.0 Boiling Point F @ 760 mm Hg 212 212 212 212 213 213 213 213 213 214 214 214 215 215 216 216 216 216 216 217 217 217 218 218 219 219 219 219 219 220 220 220 221 221 222 222 222 223 223 223 223 224 224 224 225 227 230 237 245 257 270 310 Refractive Index 72F 1.3328 1.3383 1.3438 1.3495 1.3555 1.3567 1.3579 1.3591 1.3603 1.3615 1.3627 1.3639 1.3651 1.3663 1.3675 1.3687 1.3698 1.3710 1.3721 1.3733 1.3744 1.3756 1.3767 1.3779 1.3790 1.3802 1.3813 1.3825 1.3836 1.3847 1.3858 1.3870 1.3881 1.3892 1.3903 1.3914 1.3924 1.3935 1.3945 1.3956 1.3966 1.3977 1.3987 1.3998 1.4008 1.4058 1.4104 1.4150 1.4193 1.4235 1.4275 1.4315
Typical properties are not to be confused with specifications. For additional protection, select a temperature in the above table that is at least 5F lower than the expected lowest ambient temperature. When using solutions of less than 30% glycol, adjust inhibitor levels. For additional information and specific case assistance contact WEBA Corp laboratory services
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Figure 5
Thermal conductivity (Btu/(hrft2)(F/ft)) of aqueous solutions of WEBA Technology's propylene glycol-based heat transfer uid concentrate. (volume percent propylene glycol)
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Figure 6
Thermal conductivity (Btu/(hrft2)(F/ft)) of aqueous solutions of WEBA Technology's propylene glycol-based 70% heavy duty heat transfer uid. (volume percent propylene glycol)
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Figure 7
Thermal conductivity (Btu/(hrft2)(F/ft)) of aqueous solutions of propylene glycol-based heat transfer fluids.
Volume Percent Propylene Glycol Temp. F -30 -20 -10 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 250 260 270 280 290 300 310 320 325 0% 10% 20% 30% 40% 50% 0.188 0.191 0.194 0.196 0.199 0.201 0.204 0.206 0.208 0.210 0.211 0.213 0.214 0.215 0.217 0.218 0.218 0.219 0.220 0.220 0.221 0.221 0.221 0.221 0.220 0.220 0.220 0.219 0.218 0.217 0.216 0.215 0.214 0.212 0.211 0.210 60% 0.171 0.174 0.176 0.178 0.179 0.181 0.183 0.184 0.186 0.187 0.188 0.189 0.190 0.191 0.192 0.193 0.193 0.194 0.194 0.194 0.195 0.195 0.195 0.194 0.194 0.194 0.193 0.193 0.192 0.191 0.191 0.190 0.188 0.187 0.186 0.185 0.184 70% 0.159 0.160 0.161 0.162 0.163 0.164 0.165 0.166 0.167 0.168 0.168 0.169 0.169 0.170 0.170 0.170 0.170 0.171 0.171 0.171 0.171 0.170 0.170 0.170 0.169 0.169 0.168 0.168 0.167 0.166 0.166 0.165 0.164 0.163 0.162 0.160 0.160 80% 0.147 0.148 0.148 0.149 0.149 0.150 0.150 0.150 0.150 0.150 0.151 0.151 0.151 0.151 0.151 0.150 0.150 0.150 0.150 0.150 0.149 0.149 0.148 0.148 0.147 0.147 0.146 0.146 0.145 90% 0.137 0.137 0.136 0.136 0.136 0.136 0.135 0.135 0.135 0.134 0.134 0.134 0.133 0.133 0.132 0.132 0.131 0.131 0.130 0.130 0.129 0.129 0.128 0.127 0.127 0.126 0.125 0.125 0.124
0.328 0.335 0.341 0.347 0.352 0.358 0.362 0.367 0.371 0.374 0.378 0.381 0.384 0.386 0.388 0.389 0.391 0.391 0.392 0.392 0.392 0.392 0.391 0.389 0.388 0.386 0.384 0.381 0.378 0.376
0.293 0.299 0.304 0.310 0.315 0.319 0.323 0.327 0.331 0.334 0.338 0.340 0.343 0.345 0.347 0.348 0.350 0.351 0.351 0.352 0.352 0.351 0.351 0.359 0.349 0.347 0.346 0.344 0.341 0.339 0.337
0.262 0.267 0.272 0.277 0.281 0.285 0.289 0.292 0.295 0.298 0.301 0.304 0.306 0.308 0.309 0.311 0.312 0.313 0.314 0.314 0.314 0.314 0.314 0.314 0.313 0.312 0.310 0.309 0.307 0.305 0.302 0.301
0.235 0.239 0.243 0.247 0.251 0.254 0.258 0.261 0.263 0.266 0.268 0.270 0.272 0.274 0.276 0.277 0.278 0.279 0.280 0.280 0.280 0.280 0.280 0.280 0.279 0.278 0.277 0.276 0.275 0.273 0.271 0.269 0.268
0.211 0.215 0.218 0.222 0.225 0.227 0.230 0.233 0.235 0.237 0.239 0.241 0.243 0.244 0.245 0.246 0.247 0.248 0.249 0.249 0.249 0.249 0.249 0.249 0.249 0.248 0.247 0.246 0.245 0.244 0.242 0.241 0.239 0.238
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Figure 8
Thermal conductivity (Btu/(hrft2)(F/ft)) of aqueous solutions of WEBA Technology's propylene glycol-based concentrate and 70% heavy duty heat transfer uid.
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Figure 9
Specic Heat (Btu/(lbF/ft))of aqueous solutions of WEBA Technology's propylene glycol-based concentrate and 70% heavy duty heat transfer uid. (volume percent propylene glycol)
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Figure 10
Specific Heat (Btu/(lb F)) of aqueous solutions of propylene glycol-based heat transfer fluids.
Volume Percent Propylene Glycol Temp. F -30 -20 -10 0 10 20 30 40 50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 210 220 230 240 250 260 270 280 290 300 310 320 325 0% 10% 20% 30% 40% 50% 0.758 0.764 0.770 0.776 0.782 0.788 0.794 0.800 0.806 0.812 0.818 0.824 0.830 0.836 0.842 0.848 0.854 0.860 0.866 0.872 0.878 0.884 0.890 0.896 0.902 0.908 0.914 0.920 0.926 0.932 0.938 0.944 0.950 0.956 0.962 0.965 60% 0.684 0.691 0.698 0.705 0.712 0.719 0.727 0.734 0.741 0.748 0.755 0.762 0.769 0.776 0.783 0.791 0.798 0.805 0.812 0.819 0.826 0.833 0.840 0.847 0.855 0.862 0.869 0.876 0.883 0.890 0.897 0.904 0.912 0.912 0.926 0.933 0.936 70% 0.608 0.616 0.625 0.633 0.641 0.649 0.658 0.666 0.674 0.682 0.691 0.699 0.707 0.715 0.724 0.732 0.740 0.748 0.756 0.765 0.773 0.781 0.789 0.798 0.806 0.814 0.822 0.831 0.839 0.847 0.855 0.864 0.872 0.880 0.888 0.897 0.901 80% 0.615 0.623 0.630 0.637 0.645 0.652 0.660 0.667 0.674 0.682 0.689 0.696 0.704 0.711 0.718 0.726 0.733 0.740 0.748 0.755 0.762 0.770 0.777 0.784 0.792 0.799 0.806 0.814 0.821 90% 0.542 0.550 0.558 0.566 0.574 0.583 0.591 0.599 0.607 0.615 0.623 0.631 0.639 0.647 0.656 0.664 0.672 0.680 0.688 0.696 0.704 0.712 0.720 0.729 0.737 0.745 0.753 0.761 0.769
1.004 1.001 1.000 0.999 0.998 0.998 0.998 0.998 0.998 0.999 0.999 0.100 1.001 1.002 1.003 1.004 1.005 1.007 1.008 1.010 1.012 1.014 1.017 1.019 1.022 1.025 1.029 1.032 1.036 1.038
0.969 0.970 0.972 0.973 0.975 0.976 0.978 0.979 0.981 0.982 0.984 0.985 0.987 0.988 0.990 0.991 0.993 0.994 0.996 0.997 0.999 0.100 0.002 1.005 1.008 1.011 1.013 1.016 1.019 1.022 1.025
0.929 0.932 0.935 0.937 0.940 0.943 0.945 0.948 0.951 0.953 0.956 0.959 0.961 0.964 0.967 0.969 0.972 0.975 0.977 0.980 0.983 0.985 0.988 0.991 0.993 0.996 0.999 1.001 1.004 1.007 1.009 1.011
0.882 0.886 0.890 0.894 0.897 0.901 0.905 0.909 0.913 0.916 0.920 0.924 0.928 0.932 0.935 0.939 0.943 0.947 0.951 0.954 0.958 0.962 0.966 0.970 0.973 0.977 0.981 0.985 0.989 0.992 0.996 1.000 1.002
0.827 0.832 0.837 0.842 0.847 0.852 0.857 0.862 0.867 0.871 0.876 0.881 0.886 0.891 0.896 0.901 0.906 0.911 0.916 0.920 0.925 0.930 0.935 0.940 0.945 0.950 0.955 0.960 0.965 0.969 0.974 0.979 0.984 0.987
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Figure 11
Film coefcients for WEBA Technology's heat transfer uids at 30% (volume) propylene glycol.
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Figure 12
Film coefcients for WEBA Technology's heat transfer uids at 40% (volume) propylene glycol.
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Figure 13
Film coefcients for WEBA Technology's heat transfer uids at 50% (volume) propylene glycol.
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