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Background Annealing Quench Annealing Stabilising Anneal Cleaning Process Annealing Controlled Atmospheres Hardening Cooling and Quenching Stress Relieving Low Temperature Stress Relieving Annealing A ter !elding Sur ace Hardening "itriding Ph#sical $apour %eposition &P$%'
Background
Stainless steels are o ten heat treated( the nature o this treatment depends on the t#pe o stainless steel and the reason or the treatment) These treatments* which include annealing* hardening and stress relieving* restore desirable properties such as corrosion resistance and ductilit# to metal altered b# prior abrication operations or produce hard structures able to withstand high stresses or abrasion in service) Heat treatment is o ten per ormed in controlled atmospheres to prevent sur ace scaling* or less commonl# carburisation or decarburisation)
Annealing
The austenitic stainless steels cannot be hardened b# thermal treatments &but the# do harden rapidl# b# cold work') Annealing &o ten re erred to as solution treatment' not onl# recr#stallises the work hardened grains but also takes chromium carbides &precipitated at grain boundaries in sensitised steels' back into solution in the austenite) The treatment also homogenises dendritic weld metal structures* and relieves all remnant stresses rom cold working) Annealing temperatures usuall# are above +,-,.C* although some t#pes ma# be annealed at closel# controlled temperatures as low as +,+,.C when ine grain si/e is important) Time at temperature is o ten kept short to hold sur ace scaling to a minimum or to control grain growth* which can lead to 0orange peel0 in orming)
Quench Annealing
Annealing o austenitic stainless steel is occasionall# called 1uench annealing because the metal must be cooled rapidl#* usuall# b# water 1uenching* to prevent sensitisation &e2cept or stabilised and e2tra3low carbon grades')
Stabilising Anneal
A stabilising anneal is sometimes per ormed a ter conventional annealing or grades 45+ and 4-6) 7ost o the carbon content is combined with titanium in grade 45+ or with niobium in grade 4-6 when these are annealed in the usual manner) A urther anneal at 86, to 9,,.C or 5 to - hours ollowed b# rapid cooling precipitates all possible carbon as a titanium or niobium carbide and prevents subse1uent precipitation o chromium carbide) This special protective treatment is sometimes use ul when service conditions are rigorousl# corrosive* especiall# when service also involves temperatures rom about -,, to 86,.C* and some speci ications enable this treatment to be speci ied or the product)
Cleaning
Be ore annealing or other heat treating operations are per ormed on austenitic stainless steels* the sur ace must be cleaned to remove oil* grease and other carbonaceous residues) Such residues lead to carburisation during heat treating* which degrades corrosion resistance)
Process Annealing
All martensitic and most erritic stainless steels can be subcritical annealed &process annealed' b# heating into the upper part o the errite temperature range* or ull annealed b# heating above the critical temperature into the austenite range* ollowed b# slow cooling) :sual temperatures are 6;, to 84,.C or sub3critical annealing) !hen material has been previousl# heated above the critical temperature* such as in hot working* at least some martensite is present even in erritic stainless steels such as grade -4,) Relativel# slow cooling at about 5<.C=hour rom ull annealing temperature* or holding or one hour or more at subcritical annealing temperature* is re1uired to produce the desired so t structure o errite and spheroidised carbides) However* parts that have undergone onl# cold working a ter ull annealing can be sub3criticall# annealed satis actoril# in less than 4, minutes) The erritic t#pes that retain predominantl# single3phase structures throughout the working temperature range &grades -,9*
--5* --; and 5;Cr3+7o' re1uire onl# short recr#stallisation annealing in the range 6;, to 9<<.C)
Controlled Atmospheres
Stainless steels are usuall# annealed in controlled atmospheres to prevent or at least reduce scaling) Treatment can be in salt bath* but the best option is 0bright annealing0 in a highl# reducing atmosphere) Products such as lat rolled coil* tube and wire are regularl# bright annealed b# their producers* usuall# in an atmosphere o nitrogen and h#drogen) The result is a sur ace re1uiring no subse1uent scale removal( the product is as bright a ter as be ore annealing) These products are o ten re erred to as 0BA0)
Hardening
7artensitic stainless steels are hardened b# austenitising* 1uenching and tempering much like low allo# steels) Austenitising temperatures normall# are 98, to +,+,.C* well above the critical temperature) As31uenched hardness increases with austenitising temperature to about 98,.C and then decreases due to retention o austenite) >or some grades the optimum austenitising temperature ma# depend on the subse1uent tempering temperature) Preheating be ore austenitising is recommended to prevent cracking in high3carbon t#pes and in intricate sections o low3carbon t#pes) Preheating at 69,.C* and then heating to the austenitising temperature is the most common practice)
Stress Relieving
Stress relieving at temperatures below -,,.C is an acceptable practice but results in onl# modest stress relie ) Stress relieving at -5< to 95<.C signi icantl# reduces residual stresses that otherwise might lead to stress corrosion cracking or dimensional instabilit# in service) ?ne hour at 86,.C t#picall# relieves about 8<A o the residual stresses) However* stress relieving in this temperature range can also precipitate grain boundar# carbides* resulting in sensitisation that severel# impairs corrosion resistance in man# media) To avoid these e ects* it is strongl# recommended that a stabilised stainless steel &grade 45+ or 4-6' or an e2tra3low3carbon t#pe &4,-L or 4+;L' be used* particularl# when length# stress relieving is re1uired) >ull solution treatment &annealing'* generall# b# heating to about +,8,.C ollowed b# rapid cooling* removes all residual stresses* but is not a practical treatment or most large or comple2 abrications)
Lo
!hen austenitic stainless steels have been cold worked to develop high strength* low temperature stress relieving will increase the proportional limit and #ield strength &particularl# compressive #ield strength') This is a common practice or austenitic stainless steel spring wire) A two hour treatment at 4-< to -,,.C is normall# used( temperatures up to -5<.C ma# be used i resistance to intergranular corrosion is not re1uired or the application) Higher temperatures will reduce strength and sensitise the metal* and generall# are not used or stress relieving cold worked products)
Sur!ace Hardening
?nl# limited sur ace hardening treatments are applicable to the stainless steels) Bn most instances hardening o carbon and low allo# steels is due to the martensitic trans ormation* in which the achievable hardness is related to the carbon content 3 as most martensitic stainless steels have carbon contents ranging rom airl# low to e2tremel# low* this hardening mechanism is o little use)
#itriding
Bt is possible to sur ace harden austenitic stainless steels b# nitriding) As in nitriding o other steels the hard la#er is ver# hard and ver# thin( this makes the process o limited use as the underl#ing stainless steel core is relativel# so t and unsupportive in heavil# loaded applications) A urther drawback is that the nitrided case has a signi icantl# lower corrosion resistance than the original stainless steel) A number o alternative* proprietar# sur ace hardening processes or austenitic stainless steels have been developed but these have not as #et become commerciall# available in Australia)
>or more in ormation on this source please visit Atlas Steels Australia