Car Dip UK MSDS

1. Identification
1.1. Name of Substance or Preparation: 1.2. Use of Product: 1.3. Supplier:

Car Dip UK - Liquid Spray Wrap - All Types:

Gloss, Satin, Matt, Clear, Black, White, Grey, Red, Yellow, Green, Blue, Orange, Fluorescents, Metallics, Pearlescents.
Spray on rubber coating for car panels. Car Dip UK Unit 1, Crown Farm Crown Lane, Wychbold Worcestershire WR99BX. United Kingdom technical@cardipuk.com

1.4. Telephone:

+44 (0) 7763 648721

2. Hazards Identification
2.1. Classification: 2.2. Label Elements:
Risk Phrases:

Highly Flammable, Harmful, Dangerous for the environment Symbol(s)

R11 R20/21 R36/38 R51/53 R65 R66 R67 Highly Flammable Harmful by inhalation and in contact with skin Irritating to eyes and skin Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Harmful: may cause lung damage if swallowed Repeated exposure may cause skin dryness and cracking Vapours may cause drowsiness and dizziness Avoid contact with skin Wear suitable gloves This material and its container must be disposed of as hazardous waste. Avoid release to the environment. Refer to special instructions/safety data sheet.

Safety Phrases:

Other Phrases: Other Information:

S24 S37 S60 S61 -

Contains: Xylene, Acetone

3. Composition/Information on Ingredients
3.1. Substance
Substance Name: CAS Number:
N/A N/A

EC Index Number:

N/A

3.2. Mixture
Components
Xylene

% by Wt.
>20%

EC No.
215-535-7

CAS No.
1330-20-7

Hazard
Flammable, Harmful

Risk phrases
R10 - Flammable R20/21 - Harmful by inhalation and in contact with skin R38 - Irritating to skin R11 - Highly flammable R36 - Irritating to eyes R66 - Repeated exposure may cause skin dryness and cracking R67 - Vapours may cause drowsiness and dizziness

Acetone

5 - 20%

200-662-2

67-64-1

Highly Flammable, Irritant

Safety Data Sheet for: Car-Dip Liquid Spray-On Wrap Status: Revision 1 Date of Issue: 5/4/13

Page 1 of 6

Car Dip UK MSDS

4. First Aid Measures
Immediate medical attention required? Professional assistance from physician required? Inhalation: Skin Contact: Eye Contact: Ingestion:
No Yes

Move to fresh air. Keep at rest. If breathing is difficult give oxygen or artificial respiration & seek medical advice. In case of severe exposure or if any discomfort continues get medical attention. Remove contaminated clothing and shoes. Wash affected area with soap and water. Launder clothes before re-use. If irritation or discomfort occurs after washing seek medical advice. Rinse thoroughly with plenty of water for at least 15 minutes separating eyelids gently with fingers. Seek medical advice. If swallowed, seek medical advice immediately and show this container or label . Rinse mouth with water.

5. Fire Fighting Measures

Extinguishing Media Suitable: Not to be used: Other Comments: Special Exposure Hazards:
Foam, dry chemical, CO2, water mist. Water as jet. Where large quantities are involved breathing apparatus should be used. Vapours are heavier than air and may spread near ground to sources of ignition. Severe explosion hazard when vapours are exposed to flames. Sealed containers of the product or other flammable liquids in the near vicinity of the fire can explode due to pressure build up. Prevent run-off from entering drains and watercourses. Be aware of dangers from other hazardous substances in the immediate area. Containers close to the fire area should be cooled with water if safe to do so. Be aware that any flammable substance containers are liable to explode when heated. Where large quantities are involved breathing apparatus should be used. Oxides of carbon.

Special Fire Fighting Procedures:

Protective Equipment Required: Hazardous Combustion Products:

6. Accidental Release Measures

Personal Precautions
Ventilate area. Wear gloves, goggles, and overalls. Isolate all sources of ignition. Provide adequate ventilation. Avoid ingestion, inhalation of vapours and contact with skin and eyes. Restrict access to the area until the spillage is treated, if large amounts of vapours are produced that will be hazardous to others, evacuate the area. Use suitable respiratory equipment if spillages occur in enclosed spaces and vapours are produced. Have emergency procedures in place for treating spillages, evacuating the area and informing the emergency services if necessary. When any other effects of spillages will affect the safety of others the area should be evacuated. Avoid unauthorised discharge to the environment. Do not discharge into drains, water courses or onto the ground. Clean up any spillages immediately, prevent material from spreading and entering drains or sewage systems. If spillages to land cannot be treated safely or if contamination will occur the Environment Agency must be alerted immediately. Large spillages or uncontrolled discharge to water systems must be alerted to the Environmental Agency or other regulatory body. If the substance has entered a foul drain or sewage system in significant quantity to cause a hazard the local Water Treatment Company must be informed. Isolate all ignition sources. Avoid heat, flames, sparks and static discharge. NO SMOKING. Small Spillages: Absorb with inert, non-combustible material. Large Spillages: Dam and absorb spillages with sand, earth or other inert, non-combustible material. Fit drain covers where they are available if the spillage is likely to enter the drainage system. Ventilate well. Any extraction systems used to ventilate the area must be flameproof. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. Containers with collected spillage must be properly labelled with correct contents and hazard symbol. Ensure there are no ignition or heat sources in the waste storage area. Wash spillage site well with water and detergent, be aware of the potential for surfaces to become slippery. Wash thoroughly after dealing with a spillage. After spillages in enclosed areas test atmosphere before using any potential ignition sources. Ventilate area and allow to dry before allowing access.

Environmental Precautions

Clean-Up Procedures

Safety Data Sheet for: Car-Dip Liquid Spray-On Wrap Status: Revision 1 Date of Issue: 5/4/13

Page 2 of 6

Car Dip UK MSDS

7. Handling and Storage
Handling
Static electricity and formation of sparks must be prevented. Eliminate all sources of ignition. Avoid spilling, skin and eye contact. Avoid inhalation of vapours and spray mists. Do not mix with incompatible substances or mixtures. Do not eat, drink or smoke when handling. Do not dispose of the substance to the environment through unauthorized means. Do not discharge to land or water including the drainage system. Do not use in areas close to drainage systems unless measures are in place to prevent access of product. Do not use in confined spaces without adequate ventilation and/or respirator. Use flame proof fume extraction systems to remove vapours away from the work area. Wash at the end of each work shift and before using the toilet. Remove contaminated clothing/footwear/equipment before entering eating areas or other places that would expose others to the substance. Ensure emergency procedures are in place to treat spillages and cope with other situations such as evacuation. Flammable/combustible - Keep away from oxidisers, heat and flames. Avoid all ignition sources. Store in area with adequate ventilation and sufficient air movement to prevent any build up of vapours. Store in closed original container at temperatures between 15C and 25C. Store away from heat, direct sunlight and moisture. Store away from oxidising agents. Store away from incompatible materials. Keep above the chemical's freezing point. Store in a stable situation to avoid spillages. It is advisable to store in a bunded area or use other protective measures such as a sump pallet or storage tray. If the substance is transferred to other containers ensure the packaging material is compatible. Consult with the packaging manufacturer or supplier. Do not leave storage containers exposed to the atmosphere as this will result in evaporation of contents.

Storage

8. Exposure Controls
8.1. Control parameters
Name Xylene STD WEL TWA - 8 Hrs 50 ppm (220 mg/m )(Sk)
3

STEL - 15 Min 100 ppm (441 mg/m )(Sk)

3

Biological Limit Values - No information available. DNEL Industry Industry Industry Inhalation. Inhalation. Dermal Short Term Long Term Long Term 289 (Systemic & local) 77 289 (Systemic) 0.327 0.327 6.58 12.46 12.46 2.31 TWA - 8 Hrs 500 ppm (1210 mg/m )
3

mg/m 3 mg/m 3 mg/m

PNEC Fresh water Marine water STP Sediment (fresh water) Sediment (marine water) Soil Name Acetone STD WEL

mg/L mg/L mg/L mg/kg mg/kg mg/kg STEL - 15 Min 1500 ppm (3620 mg/m )
3

Biological Limit Values - No information available. DNEL Industry Industry Inhalation. Inhalation. 30.2 30.2 Short Term Short Term mg/L mg/L 1210 (Systemic) 1210 (local) mg/kg/day 3 mg/m

PNEC Fresh water Marine water

WEL = Workplace Exposure Limit. Safety Data Sheet for: Car-Dip Liquid Spray-On Wrap Status: Revision 1 Date of Issue: 5/4/13 Page 3 of 6

Car Dip UK MSDS

8.2. Exposure controls
Engineering measures
Provide adequate ventilation, including appropriate local extraction, to ensure that the defined workplace exposure limit (WEL) is not exceeded. Where there is lack of sufficient ventilation and extraction which would lead to exposure of operators then the substance should be handled in a closed system. Ensure sufficient earthing is in place on equipment that can build up a static charge. When mists or sprays are produced work under fume extraction. Ventilation systems and extraction facilities should be flame-proof.

Respiratory equipment
Wear respiratory protection if workplace exposure limits are exceeded due to inadequate ventilation or extraction. Chemical respirator with organic vapour cartridge. Type AX. Respiratory protection should conform to the following standards. BS EN 140: Half-face masks. BS EN 136: Full face masks. CAUTION: Air purifying respirators do not protect the user in oxygen deficient atmospheres, use air supplied system. Powered air respirators should meet requirements of EN146 and EN12941. Airline fed respirators should meet the requirements of EN 270 and EN1835. Consult with the supplier as to the compatibility of the equipment with the chemical of concern. Respiratory protection should be maintained in a proper condition and inspected at the frequency specified by current legislation.

Hand protection
When removing used gloves apply proper technique by avoiding skin contact with the outer surface. Use full length gloves. Butyl rubber. When packages of the product are being handled during storage or transport it is advisable to wear protective gloves to prevent damage to the skin. Consult with the supplier as to the compatibility of the glove material and intended use. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. Gloves showing signs of degradation should be changed to avoid skin contamination. Gloves should conform to EN 374 (Chemical and Micro-organisms hazards). For gloves involving total immersion 1.0mm thickness (if available) are recommended, at least 0.5mm and breakthrough time of >480 minutes. For splash resistance use minimum 0.5mm thickness and breakthrough time > 240 minutes.

Eye protection
Wear approved chemical safety goggles conforming to EN 166.

Other Protection
Wear suitable protective clothing as protection against splashing or contamination. Wear protective boots in the case of treating a spillage. Wear anti-static footwear. Wear suitable protective clothing during transport, handling and storage operations connected with the product. Have facilities in place to wash eyes in case of contact. If handling large amounts it is recommended to have a safety shower. If there is a risk of splashing then wear a face shield. Safety footwear should conform to standards EN 344 - 347. Protective clothing should conform to the general requirements of EN 340:2003. Also consider EN 13034:2005; EN 14605:2005; EN 943:2002 dependent upon the situation resulting in exposure. Wear rubber apron and full length gauntlets if handling large amounts.

Hygiene measures
Wash hands at the end of each work shift and before eating, smoking and using the toilet. Wash skin with soap and water after contact with the substance. Do not eat, drink or smoke in the work area. Remove clothing when contamination will result in exposure to the substance, segregate and wash before re-use. Environmental Exposure Controls

9. Physical and Chemical Properties

Appearance: Colour: pH: Initial Boiling Point: Melting Point: Key:
Viscous liquid Colourless N/A ~ 56C (Acetone) N/A N/A - Not Applicable

Flashpoint: Autoignition Temperature: Flammability Limit - Lower: Flammability Limit - Upper: Relative Density:

-17C (CC) (Acetone) 465C 1% (Xylene) 13% (Acetone) ~ 0.95

Safety Data Sheet for: Car-Dip Liquid Spray-On Wrap Status: Revision 1 Date of Issue: 5/4/13

Page 4 of 6

Car Dip UK MSDS

10. Stability and Reactivity
10.1. Reactivity
Formation of explosive mixtures with: Nitric-sulphuric acid. Hydrogen peroxide. Chromium trioxide. Sulphuric acid - potassium dichromate. Chloroform in presence of a base. Nitrosyl chloride in presence of Pt catalyst. These listed reactions are known to be explosive or have a potential to cause explosion or fire. There is the possibility of other hazardous reactions as acetone is known to react in the presence of bases. Can form explosive peroxides on contact with oxidising agents.

10.2. Chemical stability

Stable when stored in sealed container at normal temperatures and in a suitable location. Forms explosive mixtures with air. Vapours are heavier than air and can travel some distance to a source of ignition. Evaporation will occur if the containers are not sealed correctly. Agitation of the substance in storage containers may produce a build up of electrostatic charge.

10.3. Possibility of hazardous reactions

Hazardous reactions as specified in section 10.1. There will be immense pressure build up under explosive conditions causing sealed containers to rupture. Do not mix with materials known to cause hazardous reactions. May also react explosively with bromoform, chromic anhydride, chromyl chloride, nitric / acetic acid mixture, nitrosyl perchlorate, nitryl perchlorate. Can ignite on contact with chloride.

10.4. Conditions to avoid

Avoid heat, flames and other sources of ignition. Situations that would produce vibration or agitation of the substance in storage containers as there is the potential to build up static charge, particularly in metal or compatible plastic containers. Avoid direct sunlight and moisture. Avoid storage in freezing conditions. Ensure sufficient earthing is in place when there is a potential to create electrostatic build up. Do not allow the storage container to be left exposed to the atmosphere. Avoid storage with incompatible materials. Avoid storage near to unprotected drainage systems. It is advisable to store the product within some form of containment to prevent spillages reaching drainage systems. Avoid storage in an unstable manner or in a situation that would result in exposure to the product.

10.5. Incompatible materials

Materials To Avoid Alkalis Nitric-sulphuric acid mixtures. Oxidising agents. Amines. Many plastics, rubber and some coatings.

11. Toxicological Information

Acetone
Acute Toxicity: LD50 Oral: LD50 Dermal: LC50 Inhalation: 5800 mg/kg (rat) >15688 mg/kg (rabbit) 76 mg/L (vapours) (rat - 4 hours)

Irritation
Sensitization Mutagenic Effects Chronic Toxicity Carcinogenic effects Other Toxicological Information

Eye contact: Irritant (rabbit) (OECD 401) Not sensitising No information available No information available No evidence of carcinogenic effects in animal experiments. No information available

12. Ecological Information

No information available.

13. Disposal Considerations

Waste disposal methods This material and its container must be disposed of as hazardous waste. Dispose in a safe manner in accordance with local/national regulations.

Safety Data Sheet for: Car-Dip Liquid Spray-On Wrap Status: Revision 1 Date of Issue: 5/4/13

Page 5 of 6

Car Dip UK MSDS

14. Transport Information
Class Packing Group UN-No Proper Shipping Name 3 II 1139 Coating solution.

15. Regulatory Information

No further information.

16. Other Information

Recommended uses and restrictions:
Sprayable rubber coating. No other use recommended.

Information sources:
Raw-material Safety Datasheets

Training advice:
Please read all datasheets carefully. If any point remains unclear or if further training is required please contact Car-Dip UK.

Revision Information:
New datasheet. NOTE: This SDS has been prepared from information we believe to be reliable, however it is provided without warranty, expressed or implied, as to its correctness. Since the conditions of handling, storage, use and disposal of this material are beyond our control we accept no responsibility whatsoever for any loss, damage or expense which results from the handling, storage, use or disposal of this material.

Safety Data Sheet for: Car-Dip Liquid Spray-On Wrap Status: Revision 1 Date of Issue: 5/4/13

Page 6 of 6