Glass Bubbles

Propriedades e Aplicaes

Glass Bubbles

3M EAMD Plataformas Tecnolgicas

Mercados
Energia (Petrleo & Gs, Solar)
Tintas & Revestimentos
Processamento Qumico
Transportes
Fios & Cabos
Equipamentos

Glass Bubbles

3M AdMD Portflio de Produtos

Specialty Additives

3M Scochlite Glass Bubbles

3M Ceramic Microspheres
3M Cosmetic Microspheres

Ceramic Fibers

3M Nextel Ceramic Fibers

3M Nextel Woven Tapes and Fabrics
3M Nextel Flame Stopping Dot Paper
3M Nextel Non-Woven Mats

Glass Bubbles

Specialty Chemicals

3M Easy Clean Coatings

3M Novec Fluorosurfactants
3M Stain Resistance Additives

Fluoropolymers

3M Dyneon Fluoroplastics
3M Dyneon Fluoroelastomers
3M Dyneon Specialty Additives

3M Glass Bubbles - Propriedades

Glass Bubbles

Caracteristica

Valor

Aspecto

Esferas ocas unicelulares

Composio

Borosilicato de sdio e clcio

(similar ao Pyrex)
Branco

Cor

Densidade Real
Resistencia
compresso
Dureza

0.12 - 0.60 g/cc

Softening Temp
Tamanho de
partcula

600 C

250 28,000 psi

Mohs scale 5

15 - 135 microns

ASTM D 3102-78 Standard Practice for the Determination of

Isostatic Collapse Strength of Hollow Glass Microspheres
(withdrawn in May 1984)

Helium Gas Pycnometer

Glass Bubbles

3M Glass Bubbles Comparao entre Aditivos

Classificao pela forma fsica
Ndulos: Carbonato de Clcio / Slica

Placas: Mica / Talco / Argila

Fibras: Asbestos / Fibra de vidro / Wollastoniae

Esferas: Slidas / Ocas

Glass Bubbles

3M Glass Bubbles Comparao entre Aditivos

Sulfato de Brio

4,3

Talco

2,7

Carbonato de Clcio

2,7

Slica

2,7

Esferas Slidas de Vidro

2,5

Resina Termofxa

1,05 1,30

Resina Termoplstica

0,90 1,35

Esferas Ocas de Vidro

0,125 0,60

Glass Bubbles

3M Glass Bubbles Comparao entre Aditivos

Viscosidade / Carregamento
81600

480
1440
11920
214000

100000

400
880
4640
Talco
125600

320
540
1240
CaCO3
5330

Zeeospheres G-200

Viscosidade (cps)

10000

K1 Glass Bubbles

1000

100
0%

10%

20%

30%

Volume de carga em resina polister

Glass Bubbles

40%

50%

3M Glass Bubbles
Unidades produtivas:

Glass Bubbles

Aplicaes
Industria automotiva,tintas e revestimentos
e outros.
New Products
- IM30k (30KPSI, 0.6 g/cc)
- K42HS (8KPSI, 0.42 g/cc)
- Im16k (16KPSI, 0.45 g/cc)
- Coated Bubbles

Untreated Bubble

Petroqumica
New Products
- S38XHS
- XLD3000, XLD6000
- S42XHS
- HGS8000X

Treated Bubble

Glass Bubbles

PRODUCTS

DENSITY

Strength

g/cc

psi

PARTICLE SIZE (microns)

10 % <

Standard Series
Floated Series

3M Products
K1
K15
S15
K20
S22
K25
S32
S35
XLD 3000
XLD 6000
K37
S38
S38HS
S38XHS
K46
S42XHS
S60
iM16K
S60HS

0.125
0.15
0.15
0.20
0.22
0.25
0.32
0.35
0.23
0.30
0.37
0.38
0.38
0.38
0.46
0.42
0.60
0.46
0.60

250
300
300
500
400
750
2000
3000
3000
6000
3000
4000
5500
5500
6000
8000
10000
16500
18000

30
30
25
30
20
25
20
17

iM30K

0.60

A16
A20
H20
D32
H50

Glass Bubbles

50 % <

90 % <

TOP

AVG. WALL

VOL. %

VOL %

THICKNESS

GLASS

GAS

5%
6%
6%
8%
9%
10%
13%
14%
9%
12%
15%
15%
15%
15%
18%
16%
24%
18%
24%

95%
94%
94%
92%
91%
90%
87%
86%
91%
88%
85%
85%
85%
85%
82%
84%
76%
82%
76%

110
105
90
110
60
95
75
48

120
115
95
120
75
105
80
58

20
15
17
17
15
11
15
13
11

65
60
55
65
35
55
40
37
30
18
40
48
45
42
40
22
34
22
30

80
75
66
60
70
37
55
31
50

85
85
83
80
80
42
65
37
60

microns
0.55
0.61
0.56
0.89
0.53
0.95
0.89
0.90
0.47
0.38
1.04
1.28
1.20
1.12
1.31
0.65
1.49
0.72
1.09

30000

16

25

29

0.70

24%

76%

0.16
0.20
0.20
0.32

500
1000
1000
4500

35
30
25
20

70
60
55
40

115
100
90
70

135
100
110
85

0.76
0.82
0.75
0.89

6%
8%
8%
13%

94%
92%
92%
87%

0.50

6000

20

40

50

60

1.43

20%

80%

h: wall thickness of the sphere

R0: outer radius of the sphere
v: poissons ratio for material
E: Modulus of sphere

Ri: Inner radius of the sphere

Ro: outer radius of the sphere (Particle size at 50%)
d: True density of hollow spheres
Solid density of glass: 2.54 g/cc

3M Glass Bubbles Portflio de Produtos

iM16K

Glass Bubbles

3M Glass Bubbles Manuseio

Glass Bubbles

3M Glass Bubbles Conceito Bsico

Qualquer incorporao, reposio ou

troca de componente na
formulao, deve ser realizada por
volume, nunca por peso.

Glass Bubbles

3M Glass Bubbles Formulao

Frmula
Tpica

Custo /
kg $

Densidade
g/cm3

Peso
kg

Peso
%

Volume
litros

Volume
%

Custo
Total $

Resina

2.00

1.05

8.00

40.00

7.62

64.00

16.00

Talco

0.18

2.80

12.00

60.00

4.29

36.00

2.16

Totais

.91

1.680

20.00

100.00

11.91

100.00

18.16

Custo / litro
Nova
Frmula

1.525
Custo /
kg $

Densidade
g/cm3

Peso
kg

Peso
%

Volume
litros

Volume
%

Custo
Total $

Resina

2.00

1.05

8.00

40.00

7.62

7.35

16.00

Glass
Bubbles

5.42

0.13

12.00

60.00

96.00

92.65

65.04

Totais

4.05

0.19

20.00

100.00

103.62

100.00

81.04

Custo / litro
% Variao

Glass Bubbles

0.78
-88.51%

-48.73%

3M Glass Bubbles Formulao

Frmula
Tpica

Custo /
kg $

Densidade
g/cm3

Peso
kg

Peso
%

Volume
litros

Volume
%

Custo
Total $

Resina

2.00

1.05

8.00

40.00

7.62

64.00

16.00

Talco

0.18

2.80

12.00

60.00

4.29

36.00

2.16

Totais

.91

1.680

20.00

100.00

11.91

100.00

18.16

Custo / litro
Nova
Frmula

1.525
Custo /
kg $

Densidade
g/cm3

Peso
kg

Peso
%

Volume
litros

Volume
%

Custo
Total $

Resina

2.00

1.05

8.00

93.72

7.62

63.98

16.00

Glass
Bubbles

5.42

0.13

0.54

6.28

4.29

36.02

2.91

Totais

2.21

0.72

8.54

100.00

11.91

100.00

18.91

Custo / litro
% Variao na Densidade

Glass Bubbles

1.59
-57.33

% Variao Custo / litro

4.07

3M Glass Bubbles Formulao

Frmula
Tpica

Custo /
kg $

Densidade
g/cm3

Peso
kg

Peso
%

Volume
litros

Volume
%

Custo
Total $

Resina

2.00

1.05

8.00

40.00

7.62

64.00

16.00

Talco

0.18

2.80

12.00

60.00

4.29

36.00

2.16

Totais

.91

1.680

20.00

100.00

11.91

100.00

18.16

Custo / litro
Nova
Frmula

1.525
Custo /
kg $

Densidade
g/cm3

Peso
kg

Peso
%

Volume
litros

Volume
%

Custo
Total $

Resina

2.00

1.05

7.28

44.33

6.93

58.24

14.56

Glass
Bubbles

5.42

0.13

0.22

1.36

1.79

15.00

1.21

Talco

0.18

2.80

8.92

54.31

3.19

26.76

1.61

Totais

1.06

1.38

16.42

100.00

11.91

100.00

17.38

Custo / litro
% Variao na Densidade

Glass Bubbles

1.46
-17.09

% Variao Custo / litro

-4.03

3M Glass Bubbles
Aplicao em massa leve de reparao.

Glass Bubbles

Massa de reparao leve

Padro

Leve

Resina PVA :

7% volume

Resina PVA:

19% volume

gua:

36% volume

gua:

13% volume

Cargas:

55% volume

K1

66% volume

Glass Bubbles

Massa de reparao leve

Vantagens :

Sem contrao

Rpida secagem

Glass Bubbles

Massa de reparao leve

Parede
danificada

Glass Bubbles

Massa corrida

Massa leve de
reparao

3M Glass Bubbles
Massa Poliester reparao automotiva

Glass Bubbles

Massa Poliester reparao automotiva

Glass Bubbles

Massa Poliester reparao automotiva

Tradicional

Leve

Resina

60 65 %
Volume

Resina

56 57 %
Volume

Talco

35 40 %
Volume

Talco

17 19 %
Volume

K1

25 26 %
Volume

Glass Bubbles

24

Massa Poliester reparao automotiva

Vantagen
Facilita lixamento

Otimiza tempo de trabalho

Reduz empastamento

Glass Bubbles

25

3M Glass Bubbles
Application in Paint Solar Reflectance

Glass Bubbles

Solar Irradiance
1.6
UV
5%

Visible
46%

N-IR
49%

Solar Irradiance (W/m.nm)

1.4

1.2

0.8

0.6

0.4

0.2

0
300

400

500

600

700

800

900

1000 1100 1200 1300 1400 1500 1600 1700 1800 1900 2000 2100 2200 2300 2400 2500

Wavelength (nm)

Glass Bubbles

Solar paint STD formulation

(with CaCO3)

raw material
Water
Wetting agent
TiO2
CaCO3
Acrylic dispersion
Thickener
Anti-foam
Totals

Density(g/cc)
1.00
1.16
4.10
2.70
1.06
1.06
1.00
1.58

Weight
69.57
0.80
61.50
121.50
94.68
2.47
0.29
350.81

Solids by weight %
Solids by volume %
Density wet
Density dry

Glass Bubbles

W%
19.83
0.23
17.53
34.63
26.99
0.70
0.08
100.00

65.17%
45.00%
1.58
2.29

Volume
69.57
0.69
15.00
45.00
89.32
2.33
0.29
222.20

Filler Vol =
Binder Vol=
PVC =
CPVC =
CPVC/PVC =

V%
31.31
0.31
6.75
20.25
40.20
1.05
0.13
100.00

60.00
40.00
60.00
62.23
1.04

Vol Dry
0
0.21
15.00
45.00
39.14
0.60
0.05
100.00

% Vol Dry
0
0.21
15.00
45.00
39.14
0.60
0.05
100.00

Solar paint S22 formulation

raw material
Density(g/cc)
Water
1.00
Wetting agent
1.16
TiO2
4.10
CaCO3
2.70
Acrylic dispersion
1.06
3M Glass Bubbles S22
0.22
Thickener
1.06
Anti-foam
1.00
Totals
1.08

Weight
69.57
0.80
61.50
0.00
94.68
9.90
2.47
0.29
239.21

Solids by weight %
Solids by volume %
Density wet
Density dry

Glass Bubbles

W%
29.08
0.33
25.71
0.00
39.58
4.14
1.03
0.12
100.00

48.92%
45.00%
1.08
1.17

Volume
69.57
0.69
15.00
0.00
89.32
45.00
2.33
0.29
222.20

Filler Vol =
Binder Vol=
PVC =
CPVC =
CPVC/PVC =

V%
31.31
0.31
6.75
0.00
40.20
20.25
1.05
0.13
100.00

60.00
40.00
60.00
67.52
1.13

Vol Dry % Vol Dry

0.00
0.00
0.21
0.21
15.00
15.00
0.00
0.00
39.14
39.14
45.00
45.00
0.60
0.60
0.05
0.05
100.00
100.00

Testing Equipment: Spectrophotometer Cary 500 UV Visible - N-IR

+ Integrated Sphere

Labsphere Integrated Sphere

Measurement: Hemispherical Reflectance properties

Glass Bubbles

Solar reflectance, white paint

100
90
80

% Reflectance

70
60
50
40

Sample
White STD
White S22

TSR
81.76
86.18

UV
12.36
13.24

Vis
89.48
92.31

IR
81.13
87.39

30
20
10
0
250

750

1250

1750

Wavelength (nm)
White STD

Glass Bubbles

White S22

2250

Osram Ultra-Vitalux lamp

Painted aluminum panel

Thermocouple

Data logger

Glass Bubbles

Back side temperature versus Time

100

90

45% CaCO3
45% S22

Temperature (C)

80

Average temperature
reduction = 3.25C

70

60

50

40

30
0

10

20

30
Time (minutes)

Glass Bubbles

40

50

60

3M Glass Bubbles - Obrigado

Glass Bubbles