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physics for teachers

a modern review
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Physics for Teachers:

A Modern Review

Physics for Teachers:

A Modern Review
Robert L. Weber
Associate Professor of Physics

The Pennsylvania State University

vV'

McGraw-Hill Book Company

New

York

Son Francisco

Toronto

London

to Marion, Robert, Karen,

Meredith, and Ruth

who were

patient

WIQAN

UBRARfES

WITHDRAWN FOR

PHYSICS FOR

EW

Copyright 1964 by McGraw-Hill, Inc. All Rights Reserved. Printed in the United States of America, This book, or parts thereof, may not be reproduced in any form without permission of the publishers.
Library of Congress Catalog Card

Number 63-19320

68806

Preface

The

reader of this boob

is

assumed to be interested

in space

physics and atomic physics and to have had a full-year course in


general physics at the college level.
in

Capitalizing on his interest

rockets and satellites. Part

presents enough of the principles

mechanics and electricity to serve as a good basis for understanding nineteenth-century classical physics. In Part 2, with the atom as the central theme, the theories of relativity and
of

quantum physics which have characterized twentieth-century


such as wave properties and
calculus notation
is

modern physics are developed. In both parts important topics relativity, which are likely to be
used,-

less familiar to the reader, are

developed in greater but where feasible (e.g.,

detail.

Some

in Sec. 4.4),

noncalculus explanations are used, and several derivations involving integration are subordinated in an Appendix. An aim of

book is to encourage the reader, whether a student or a mature teacher, to appreciate the relatedness of the various fields of science and to be willing to venture into new areas with the ability he has gained from intensive study of a few selected
this

areas.

In the planning of this book I am indebted to the interest of students and colleagues in several science institutes sponsored by the National Science Foundation. For six years I served as
vii

Preface

and teacher of the physics part of programs at The Pennsylvania State University; Colorado State University, and Yale University. The present text evolved from
associate director, director,

the study guide used in the last-mentioned program. I express indebtedness to that scholarly textbook "Physics for Students of Science and Engineering," by David Halliday and Robert Resniek, for the manner of presentation used in the first part of

Chap.

13.

Contents
Robert L. Weber

Preface

vll

Part 1

Looking Out: Rockets,


3
of

Satellites,

Space Travel

What's Up?
Environment

Space 20
40

Rocket Propulsion Escape from Earth


Satellites

50
in

Motion of Bodies
Travel to

Space
Planets

60
68

Moon and

Part 2
8.

Looking In: Atomic and Nuclear Physics


Idea
91

75

The Atomic
Electric

77
116

9.

Wave Motion
The Electron
Ions

10.

and Magnetic Forces


136

11.
12.

and Isotopes
Classical

149

13.

Electromagnetic Radiation
I

Theory
Effects

156 167

II

Quantum

14.
15. 16. 17.

Wonderland 184 Hydrogen Atom Bohr Model Quantum Dynamics 216


Relativity

203

Radioactivity

238
252 260 272

18.
19.

Nuclear Reactions

Absorption of Radiation

20.

Unconventional Energy Sources

Appendices
A.
B.

289 Burnout Velocity and Range


Reaction Thrust

291

C.

Schrodinger
1.

Wave
for a

Equation

293

D.

Books

Physics Teacher's Reference Shelf

2. 3.

Some

Periodicals for a School Science Library

295 296

PART

Professional Organizations of Interest


to the Physics

Teacher

296

4. 5. 6.
7.

Some

Suppliers of Physics Apparatus for Teaching

297

Greek Alphabet 297 Symbols 298 Instruction on the Use

Looking Out: Rockets, Satellites,

of a Slide Rule

298

7A. Slide Rule Bibliography


8. 9.

300
301

Trigonometric Functions

Space Travel
304 305

Logarithms

to the

Base e

302

10. 11.

Values of Physical Constants

Conversion of Electrical Units

Index

307

What's Up?

In his millennia of looking at the stars,

man has never found


denly thrust upon

so exciting a

challenge as the year 1957 has sud-

him.

Fred

L.

Whipple

1.1

ASTRONAUTICS TODAY

Fictional accounts of space travel had been written before the lime of Jules Verne. In the second century a.i>., Lucian of Santos wrote of a visit to the moon. But the foundation for converting fantasy into an engineering possibility was the invention of lite
rocket.

Most current

progress

in

the science and technology of


efforts since

space

flight is

an outgrowth of the

World War

II

to

develop long-range military missiles. Popular concern aboul space technology was aroused when
the
first artificial

earth satellite was launched by the Soviet Union

in 1!J">7. In the

next 3 years, some 36 satellites carrying instruments were launched, 30 of them by the United States. Also dur-

moon shots and space probes sought information farther from the earth. Next came the spectacular manned orbital flights made l>y astronauts of the Soviet Union and the United States.
ing this period several
3

What's Up?
4
Looking Out: Rockets,
Satellites,

Space Travel
Table
1,1

In the "World Almanac" one may find a listing of the major space vehicles launched since 19">7. Table 1.1 gives the longer
perapective of the history of man's use of rockets.
Table
c.

Milestones

in

missilery (continued)

1954 1957
1.31.58

United States starts

ICBM program; USAF awards

contracts to

Convair, North American Aviation, and General Electric. Sputniks and II launched First artificial earth satellites

by

rocket (October
1.1

4 and November
"permanent"

3).

Milestones

in missilery

Explorer
States.

I,

first
I,

United States

satellite,

launched.

300
1200 1780 1792 1800 1812

Hero of Alexandria uses the reacting force of escaping steam propel an experimental device.
Chinese use gunpowder
lent to to

to

3.17.58
10,11.58

Vanguard
Pioneer
I,

first

satellite

launched by the United


States.

c.

propel "arrows of flying


in India.

fire,"

equiva-

first

lunar probe, launched

by the United

present-day skyrockets.
British
in

12.18.58
1.2.59

Project Score (Atlas) launched, broadcasting a

human
sun.

voice from

c.

Advanced type of rocket developed


second Mysore War. Sir William Congreve of Great
to
British

outer space for the

first

time.
satellite to orbit

Troops of Tipu, Sultan of Mysore, use rockets against


Britain

Russia launches Lunik,

first first

around

3.3.59

Pioneer IV launched,
Russia launches Russia launches
first

United States satellite to orbit sun.


to

c.

improves rocket propellant

9.12.59
10.4.59

provide considerable increase in range. use rockets in attack on Fort McHenry (Baltimore), commemorated in the line "... and the rockets' red glare" in our
National Anthem.

8.11.60
4.12.61

land on moon. moon. United Slates recovers first space vehicle from orbit. Manned orbital flight achieved in Soviet Vostok satellite,

space vehicle

first satellite

to orbit

2.20.62
stability of rockets

Pfoject

Mercury succeeds

in

manned
in

orbital flight,

1830 1846

William Hale, an American, increases


nozzle vanes.

by adding

7.10.62
8.13.62 8.27.62

Telstar satellite relays

first

transatlantic television, programs.

Two

Russian astronauts put


II

reloted orbits.

Mexican War sees first use of rocket weapons by United States in o war. Lifesaving rockets developed by English and German
inventors.

12,14.62

Mariner Mariner

II

launched to encounter Venus. passed within 22,000 mi of Venus, reporting data on

1913 1915

Ramjet proposed and patented in France. World War sees advent of guided missile to supplant aimed
I

temperature, cloud cover, magnetic field, particles and radiation dosage encountered throughout voyage.

rockets.

1.2

ASTRONAUTICS
feat

TOMORROW

1926

Dr.

Robert H. Goddard, professor of physics at Clark University,

fires first successful liquid- fuel rocket.

What
used to power the Nazi V-1

c 1930
1931

Germans experiment with the pulse "bun bomb" of World War II. Germany uses liquid rocket fuel.

jet,

expected, perhaps in the next 2 or 3 years, from adaptations of the intercontinental ballistic missiles already
available?

may be

The

staff of the

RAND

Corporation has estimated

1932
1936
1941

Captain Walter Dornberger undertakes development of liquidfuel rocket weapons for the German Army. German Peenemunde Project is organized, to develop war rockets. United States starts work on controllable rocket weapons.

that
1.

we

shall

be able to do the following:


lb to 300 mi altitude payloads of 2,500 lb at 22,000 mi

Orhit satellite payloads of 10,000

2.
3.

Orbit

satellite

1942 1944
c.

1945

American Razon missile, controllable in both azimuth and range, is developed. United States government awards first contract for research and development of guided missile to General Electric Company. Germany uses V-1 buzz bomb, V-2, and other rocket missiles in

4.

Impact 3,000 lb on the moon Land, intact, more than 1,000


Venus, or Mars

lb of

instruments on the moon,

.").

World War
bombers.

II.

United States uses

"Weary

Willie"

unmanned

fi.

Probe the atmosphere of Jupiter with 1,000 lb of instruments Place a man, or men, in a satellite orbit around the earth for
recovery after a few days of flight

1946 1949
c

Work
missile

is

started

in

the United States on an intercontinental ballistic

program, the MX-774,


of a missile

First flight

beyond

earth's

atmosphere

is

made

at

1.3

WHO SHOULD

CARE?

White Sands, N. Mex.


.

By

1952

United States long-range missile program is stimulated by Atomic Energy Commission warhead developments.

pushed chiefly as a gunless

the military, the costly development of the rocket has been artillery device and for bombardment

Looking Out: Rockets, Satellites, Space Travel

What's Up?

over intercontinental distances with nuclear warheads. Rocketlaunched viewing satellites may make possible the inspection of foreign territory and thus discourage preparation for war. The difficulties that statesmen now have in reaching agreement on inspection and on disarmament will, however, probably increase
as military space technology expands. In addition to the military reasons, there are

The philosopher and the theologian are already adapting their thinking to the eventuality that man may encounter life elsewhere in the universe. It seems probable that just as the telescope profoundly altered seventeenth-century thought, the space vehicle will extend twentieth-century man's understanding of the
universe

and

his role in

it.

many

scientific

incentives for

making

satellites.

Some important problems

await1.4

CAREERS

IN

ASTRONAUTICS

ing investigation are:


1.

2.

Determination of density, pressure, and temperature in the upper layers of the atmosphere Exact measurement of the dimensions of the earth, the continental distances, and other geodetic measurements A detailed study of radiation from the sun

Astronautics touches almost


nology.
1

may

into the field

all fields of current science and techbe expected to lead to entirely new fields. Entrance of astronautics can be made by one who has acquired

:i.

4.

Observation of the intensity of cosmic rays and other radiation in the earth's

atmosphere

in one or more of these fields: mechanical, aeronautand electrical engineering; mathematics; physics; biophysics; and chemistry. Mathematics and physics are basic. With nuclear power a necessity for distant space travel, the field of
ical,
is of special importance. Information about careers in astronautics can be obtained from the corporations active in this field, and also from the agency

knowledge

f).

Correlation of the currents of nuclei, neutrons, and other particles flying toward the earth with sunspot activity

nuclear physics

(i.

7.

Kstimation of the distribution of mass in the earth's crust from the orbital planes of the artificial earth satellite Study of the propagation of radio waxes in the upper atmosphere and provision of radio communication, navigation beacons,

which coordinates the government's activities, NASA. The .National Aeronautics and Space Administration was created by an act of Congress signed by President Eisenhower on July 2H, I9">8.

8.
it.

10.

and television with the aid of satellites Improvement in weather forecasting Making feasible astro no mica investigations without atmospheric and other disturbances Study of biological specimens in environments different from
I

The

act declared that "it

activities in

is the policy of the United States that space should be devoted to peaceful purposes for the

benefit of

mankind."

FILMS ON ASTRONAUTICS
For a listing of some 9(1 films on rockets, missiles, and space science see It. Weber: Films for Students of Physics, Supplement I, American Jcwntd of I'h units, SO: 321 327 (192).

that on earth

Although we have these incentives for space exploration, it is likely that such exploration will enlighten us in fields even beyond our present speculations. Space flight obviously demands development of devices of great reliability 1o operate for long periods under extreme conditions of environment. Engineering advances depend on fundamental scientific knowledge, and in the past these advances have contributed tools for the obtaining of new knowledge. This interaction or feedback
is

SUGGESTIONS FOR FURTHER READING IN ASTRONAUTICS


Hooks:

Adams, Carsbie

occurring

in

astronautics.

When

spaceships

can carry instruments, or man solar system, new information will surely become available for the physicist, biologist, and astronomer.
himself, into other parts of the

C: "Space Flight, " McGraw-Hill Book Company, Inc., York, I95S, 373 pp. Hcnson, t). 0., and H. Strugliold: "Physics and Medicine of the Atmosphere ami Space," .John Wiley A Sons, Inc., New Yolk. IWiO,
New
4f)

pp.

"uchheim.

It. W and Staff of HAND Corp.: "Space Handbook," House Document 80, U.S. Government Priming Office, Washing-

Looking Out: Rockets, Satellites, Space Travel


ton 25,
edition),

D.C,

1959. Also

Random House,

hit-.

(Modern Library

New

York.

The National Aeronautic* and Space Administration: "Space: The New Frontier," U.S. Government Printing Office, Washington 25,
D.C., 1962,48 pp. Ordway, Frederick I.: "Annotated Bibliography of Spaee Science and Technology," Arfbf Publications, P.O. Box 6285, Washing! on 15, D.C.,
Scifert,
1011-2.

Howard

New

S. (ed.): "Sparc Technology," .John Wiley & Sons, Int.. York, 1959. Text based on graduate-level lectures presented
in

by University Extension, University of California,


with Hamo-Wooldridgc Corp.
Periodicals:

cooperation

Environment of Space

Astronautics.
Inc.,

Published monthly by

The American Pocket

Society,

500 Fifth Ave,

New York W. NY.


The
most
incomprehensible
is

Aviation HVefc (Including Space Technology). McGraw-Hill Publishing

Company, Inc., 330 West 42 St., New York 36, N.Y. and Rockets. Published weekly by American Aviation Publications, 1001 Vermont Ave., NW, Washington 5, D.C. Sky and Telescope. Published monthly by Sky Publishing Co., 60 Garden St., Cambridge 38, Mass.
Missiles

thing

about the universe


hensible.

that

it

is

compre-

Albert Einstein

Space Aeronautics. Published monthly by Conover-Mast Publications. foe., 20.") East 42 St., New York 1 7, N.Y. Space Age. Published quarterly bv Quinn Publishing Co., Kingston, N.Y. Spaceflight. Published bimonthly hy British Interplanetary Society, 12 Bessborough Gardens, London, SW 1. England. Space Journal. Published quarterly by Space Enterprises, Inc., P. O. Box 94, Nashville, Tenn.
Publications of Sperial Interest
to

2.1

INTRODUCTION
sun, the 9 major planets, 31

Students:

Adams. Carsbie C, Wernher von Braun, and Frederick I. Ordway: "Careers in Astronautics ami Rocketry," McGraw-Hill Book ComYork. 1902, 248 pp. by 35 in.. General Electric Missile and Space Vehicle Department, Valley Forge Space Technology Center (Mail: P.O. Box 8555, Philadelphia 1. Pa.). Map of Outer Spaee, chart, 28 by 25 in., General Electric Missile and Space Vehicle Department. "Short Glossary of Space Terms," National Aeronautics and Spaee Administration, U.S. Government Printing Office, Washington 25, pany,
Inc.,

New

Map

of the

Moon,

chart, 45

known moons, and thousands around the sun constitute the solar -v-ii'iii. The planets move around the sun in the same direction in elliptical orbits which are nearly circular (big. 2.1). All the orbits lie in nearly the ecliptic plane of the sun's apparent path
Our
of lesser bodies all revolving

among

the stars.

The
is

orbit

of Pluto deviates most, about

17.

from the

ecliptic plane.

the ecliptic plane


mi, a distance

The zone about 17 wide on each known as the zodiac.


is

side of

The average distance


which

"Space

1962, 57 pp. Primer: An Introduction to Astronautics," Convair-Asfronautics. Dcpl. 120, P.O. Box 112s, San Diego 12, Calif., 72 pp.

D.C,

The

of the earth from the sun is 92,900,000 defined as one astronomical unit (a.u.). diameter of the orbit of Pluto, the outermost member of the
is

solar system,

about 79

a.u.

The
are
9

four inner planets, Mercury, Venus, Earth,


terrestrial planets,

and Mars,

sometimes called the

They

are relatively

10

Looking Out: Rockets, Satellites, Space Travel

Environment

of

Space

11

small, dense bodies.

The next four outer planets, Jupiter, Saturn, Uranus, and Neptune, are called the major planets or the giant planets. They are relatively large bodies with ice and rock cores
% >.

among

stars in size, in temperature,


Its

type C-2).

and in brightness (spectral nearness to the earth makes the sun appear to us

Meteors
Jupiter

very large and bright. The surface temperature of the sun has Keen measured as about ti000C, or I0,000r', The energy output of the sun as light and heat is remarkably constant. Solar energy
arrives at the surface of the earth at

an average rate of 1.35

kilo-

watts/ m-. This solar energy, resulting from a series of thermonuclear reactions, makes life possible on the earth.
Sunlight takes a
little

more than 8 min

to reach the earth.

Fig.

2.1

Solar

system;

orbits

of

Mercury, Venus, Eorth, Mars, and

is found to consist but with the colors crossed by many dark lines. The absorption lines are produced by gaseous materials in the atmosphere of the sun. From their lines, some 70 of the chemical elements occurring on earth have been identified as

When analyzed with a

spectrograph, sunlight

of a continuous spectrum,

Jupiter.

present in the sun.


visible

below their

atmospheres. Physical data on objects of principal interest in the solar system are given in Table 2.1.
2.1

Table
Body

Physical

data on some bodies

in

the solar system


Intensity

The radiating surface of the sun is called the photosphere. Above it is the chromosphere, visible to the unaided eye al times of total eclipses as a turbulent pinkish-violet layer. The pearly light of corona extends millions of miles beyond the chromosphere. Corona are related to the appearance of sunspots dark,

Mean
distance

Man,
times
earth's

Diameter,
mi

Gravitational force

Length
of

Length of year

irregular regions

which

of
sunlight,
rel. to

day

miles across

and

whicii

may extend several hundred thousand may last for a few weeks to several months.

from
tun,
a.u.

at solid
surface.
9'

mass

earth

waves ("static"), and charged particles (cosmic rays) from the sun is highly
of ultraviolet radiation, radio
variable.

The output

Sun

329,000

864,000
3,100

Mercury Venus
Earth

0.39 0.72
1

0.05 0.82
1

0.3
0.91
1

6.7
1.9
1

68 d
?

7,500 7,920

24 hr

Mars
Jupiter

1.52

0.11

Saturn

Uranus Neptune
Pluto

Moon
*
f

5.2 9.5 19.2 30 79 1.0

317 95
15 17

4,150 87,000

0.38
t t
t

0.43 0.037
0.01
1

24.6 hr
10 hr

88 d 225 d 365 d 1.9


12 yr

2.3
yr

THE PLANETS

71,500 32,000
31,000
?

10 hr
11 hr

0.0027
0.0011

29 yr 84 yr
165
yr

because of its nearness to the sun, Mercury is difficult to observe ami knowledge of its physical characteristics is not very accurate. Mercury has a mass about one-twentieth the mass of the earth. It
no moon. .Mercury has a rockysurl'ace. probably similarlof hat our moon. Mercury always keeps the same side turned toward the sun. This side probably has surface temperatures as high as
lias

t
|

16 hr
?

0.8 0.012

0.0006
1

248

yr

2,160

0.17

27 d

Hoi no

solid surface. location of solid surfoce not known (far below dense atmospheric gases).

b)()C, while

gases, with

the side in darkness is cold enough to retain frozen temperatures approaching absolute zero.
slightly smaller

Venus
2.2

is

THE SUN
sun,

than the earth, shrouded

in

a dense

The

whose gravitational attraction


is

chiefly controls the

mo-

tion of planets in the solar system,

classified as

about average

opaque to light of all wavelengths, Neither free oxyRen nor water vapor has been detected on Venus. Carbon dioxide s abundant in its atmosphere, with nitrogen and argon also
;

ilinospherc

12

Looking Out: Rockets, Satellites, Space Travel


is

Environment

of

Space

13

thought that die surface of Venus is hot {about 425C), dry, and dark beneath a continuous dust storm.
present. It

distance from the earth of 239,000 mi.

ciable atmosphere. Its surface, comprising

diameter ahoul half that of the earth, its rate of revolution is about the same as that of earth, and its axis, too, is inclined about 2;"> from the plane of its orbit. Mars takes <87 of our days to make one circuit of the sun. Although the orbit is nearly circular, it is not centered on the sun; Mars is more than

Mars

mountains,
on
its

is

lias u

probably dry,

The moon has no appremany craters and high dust-covered rack. The moon rotates

axis in a period of time equal to the period of its revolution about the earth, 27.3 days. The moon's elliptic orbit and its variation in altitude from season to season permit us to examine

about 00 per cent of

its surface,

over a period of time.

30 million mi farther from the sun at some parts of its year than at others. More than half of the surface of Mars is a desert of
rusty rock, sand, and
color changes
soil.

2.5

ASTEROIDS, COMETS,

AND METEORITES

The

rest of the sin-face

shows seasonal
planets, are of irregular shape.

which have been interpreted as due to vegetation. While noon summer temperature on Mars probably reaches 30C, night temperatures probably fall to 70C. The atmosphere {mostly nitrogen) on Mars has a pressure about 10 per cent of the earth's atmosphere. Oxygen has not been detected. The white polar caps are probably frost layers, which on melting furnish moisture for the summer growth of vegetation. Mars has two
small satellites about 5 and 10 mi in diameter. Each of the four giant planets, Jupiter, Saturn, Uranus, and Neptune, seems to have a dense rocky core surrounded by a thick

Asteroids are pieces of planetlike material which, unlike the They may be the shattered frag-

Fig.

2.2

Radiation

pressure

which

forces the tail of

a comet away from

the sun might propel a spaceship.

*
meats of one or more planets. Most measure
the largest, Ceres,
asieroids
lie

V
few miles across;

and covered by thousands of miles of compressed hydrogen and helium with smaller quantities of methane and ammonia. These planets receive relatively feeble radiation from the sun, so that the temperatures of their upper atmospheres range from -100 to -200C. These planets rotate rapidly and
layer of ice

orbits of most between the orbits of Mars am! Jupiter {Fig. 2.1). The time for one revolution varies greatly among the asteroids.
is

nearly f>00 mi across.

The

the same direction. Some of the satellites of these planets are larger than the earth's moon and may have physical characteristics less formidable for space-flight visits than the major planets
in

Comets are large, loose collections of material that penetrate the inner regions of the solar system from outer space. The most
famous one, named after Halley, has been sighted every 7(i.02 years since 240 h.c, but not all return periodically. Comets have a head and tail. The head is made up of heavy particles and is
attracted by the sun. The tail is made up of dust and gas forced away from the sun by radiation pressure as the

themselves. Jupiter has 12

satellites.

Four are bright enough to

be easily visible with binoculars, and their rapid motion causes interesting changes in position from night to night. Saturn is the farthest of the planets visible to the unaided eye. It has nine satellites. Saturn is surrounded by remarkable flat
rings in the plane of the equator. It has been suggested that the
rings are

and is comet

made up

of tiny particles of a shattered tenth satellite.

sweeps past the sun. The brightness of the comets is probably due to reflected sunlight. The earth has passed through the tails of many comets without effect.

Some

2,000 tons of material from outer space reaches the

Ruth's atmosphere each day


2.4

THE MOON

a mass about BV that of the earth, a diameter of about 2,l(iO mi, and an elliptic orbit which gives it an average

The moon has

in the form of meteorite particles, atmosphere with speeds of 10 to 50 mi/sec and are heated to incandescence, producing the light streaks called incteors. Reflection of radio waves from the ionized paths

1'hose enter the earth's

14

Looking Out: Rockets,


of sky

Satellites,

Space Travel

and observations

counting of meteors indicate

gk)W at twilight as well as direct visual tliat a large amount of material inadequate. How much meteoiare data but is received daily, vehicle might encounter is an important itie material a space

unknown.
|,

dust,

of zodiacal light can In the night sky a faint tapered band is evidence of cosmic It ..en and traced photoelectrically. plane of the solar mierometeorites, concentrated toward the

system.
2.6

RADIATION
x rays, ultravinl.t

Beyond the shelter of the earth's atmosphere, intensities which may have to be rays, and cosmic rays exist at vehicles. The WA considered in planning exploration by space
belt of high-energy radMr Explorer satellite detected an encircling of a few hundred miles, most tion extending upward from a height The earth's magnetic intense in the equatorial region (Fig. 2.3). electrons and protons, constituting field traps the particles, chiefly flares, the sun delivers as much solar During the radiation belt. as 1,000 times its normal radiation. is described in The nature of the radiation found in space astronaut* to radiation Table 2.2. In order to avoid subjecting
space
Charge Mass

Fig. 2.3

Space

radiation: cross section of the radiation pattern in longitude

75 west, from

Explorer

satellites.

(Adapted from

the

New

York Times,

October 27, 1958.)

Table 2.2

Radiation

in

Name

Nature of
radiation

Where found

Photon

Electronic gnetic
Electronic gnetic

Quantum

Radiation belts, solar radiation (produced by nuclear


reactions
electrons)

Xray

Electromagnetic

and by stopping

Gamma
Electron

ray

Electromagnetic
Particle
Particle

Proton

lm, 1,840m,
or
1

Radiation belt

Cosmic rays, inner rodiotion


belts, solar

omu

cosmic rays

Neutron

Porticle

1,841m,

Vicinity of

planets and sun

(produced in nuclear inter* decoys into proactions

ton

and

electron)

Alpha porticle

Particle

+ 2.
&+3e
E
'

4 6

amu amu

Cosmic

Heovy primaries

Porticle

roys (nucleus of helium atom) Cosmic rays (nuclei of heavier

otomsl

Pioneer V, o 95-1 b highly instrumented space planetoid, supply the first comprehensive data collected ,ary space.
'9-

2,4

was launched
in

March

11, 1960, to

interplane-

From

H.

E.

Newell and

J.

Naugle, Science, 132i 1*65 (1960).

15

Environment

of

Space

17

5
in

excess of tolerable dosages (Table 2.3),

it

may

be necessary

-n.

Dl

to plan flights from the earth along trajectories which avoid the regions of concentrated radiation (Fig, 2,">).
Table 2.3

* t
I

Maximum
exposure

permissible radiation dosages and


levels {in roentgens)

some

typical

o
t

1)

<

Item

Amount

Permissib/e exposures

Maximum
Maximum

permissible dosages

0.3*

r/'quarter

permissible

emergency exposure
Typical exposures

5.0 r/yr 25 r

3 o
i
a
y,

'

'" '. v /.: '

-. >.
'-,.

Normal radiation

level (sea level)

*-*/

Undisturbed interplanetary space (cosmic rays) Heart of inner belt (protons)

0.001 r day 5-12 r/yr 24 r/hr

c 5

Heart of outer belt


i
.

(soft x rays)

J!

~200
2-400
Under
this limit

r/hr

So!ar proton event (protons)


Total exposure
* Limit prescribed for radiation workers.

10-10" r/hr
r

S-5!

z o
I

i &
the yearly

u
u% in
1/1

maximum would be
From H.
E.

1.2

r. J. E.

Newell and

Naugle, Science, 132: 1465 (1960).

z
I

2.7

MORE DISTANT SPACE

The sun's nearest star neighbor is Alpha Centauri, which is more than 4 light-years away. (In contrast, the outermost planet of the solar system, Pluto, is only 0.000 light-year from the sun.) The
relative brightness of several stars and their distances from the sun are shown in Table 2.4.

Insofar as man knows, the universe is infinite. Scattered throughout this void is an apparently endless number of galaxies, each of which contains millions of stars. Some galaxies are themselves

grouped
of

in clusters.

The
I

constellation

made up

some 400

galaxies. In the observable region

Ei
16

us there are an estimated billion galaxies, tance between galaxies of about 2 million liglil -years. Galaxies usually have the shape of disks thousands of lightyears in diameter. The larger galaxies have spiral arms suggesting a pattern of rotation. Our own galaxy, the Milky Way, appears tn have this form. Our solar system is believed to be situated in

Corona Borealis is around with an average dis-

18

Space Travel Looking Out: Rockets, Satellites,

Environment

of

Space

19

Table 2.4
Star

Some

star distances

to

Park, Pa., 1982, 54 pp. A manual for adult discussion study groups which a Guide for the Discussion Leader is keyed,

Brightness, relative to sun

Distance from sun,


light-yeors

Duncan, John
Inc..

C: Astronomy,"
York, 1055.

5th ed., Harper

it'

Row, Publishers,
Library of

Now

Hoyie, Fred: "Frontiers of Astronomy." New American Win-id Literature, Inc., New York. 1955.

Alpha Centauri
Barnard's Star

Wolf 539
Sirius

A,B

60,000 23

Proeyon
Altair

6 8
5,200 6,600
13,000

Argo Deneb
Betelgeuse

4.3 6.0 7.7 8.7 11.3 16.5 180 640

James. .1. N.: The Voyage of Mariner 70-84 (1983).


Krogdfthl,

II,

Scientific

American, 209:

Wasley S.: "The Astronoinical [.'inverse," The Macmillan Company, New York, 1952. McLaughlin, Dean II.: "Introduction to Astronomy," Houghton Mifflin Company, Boston, 1981.
Newell,
II.
!",..

and

J.
I

K,

Xaugle: Uadiulion Environment

in

Space.

Sririr. 1:12:1

if 15

172 (Mil ill).

650

one

of the spiral arm*,

The
it

manned

one circuit of the, galaxy. takes 200 million vears to complete may lead to techniques Ylthough presently envisioned not suffice for will they system, exploration in the solar

solar

system

is

about 30,000 light-years from the center. see, but moving at a speed of about 1-.0 mi

Shaw, John II.: The Radiation Environment of Interplanetarv Space, Applied Optics, I 87-95 (1902). Zim. Herbert, and Robert 1L linker: "Stars." Colder, Press. Xew York
-.

1950.

QUESTIONS FOR DISCUSSION


1. Would you expect Mercury to have an atmosphere, that is, a permanent gaseous envelope? 2. Estimate the fraction of the total mass of the solar system which

exploring (he vast distances beyond. stars less than 12 per cent of all If as has been estimated, our stars m billion some 200 have planetary systems, then nut of is led One systems. planetary galaxy, there are some billion with number there are probably some to speculate that out of this support life. Communisystems with earthlike planets that may galaxy is a matter ,t speculacation with distant planets of the other galaxies at least out only. And bevond our galaxy arc
tion
telescopes: to the limits accessible to present directions. all years in

i"

lie

sun.

Am.

(iO.fi

per cent

Does a physical environment of the sort needed to support plant and animal life such as we know exist elsewhere in the universe? Where? Can you conceive of a form of life not based on water chemistry? Might ammonia or fluorine compounds serve? Where in the universe would you expect lids differenl form of life to exist? If it docs exist in intelligent. r,, rmi ,[,, vnu tM n k Wl ou ( tHnmu i t at p ,vilh it? I. A point on the earth's equnlor is carried ahoul 1,090 uii.hr by
3.
, . j ( j |

,.

some

'2

billion light-

the rotation or the earth. Jupiter has an equatorial diameter II times thai of the earth and a day of 10 hr. Calculate (he speed of a point on the equator of Jupiter. _>2.i mi hr

.W

5.

Express the diameter of Pluto's orbil


In

in

mi.

A FILM INTRODUCTION TO SPACE

Ut*mB.28wto

(I960), National Contemporary Films. Inc., 287

Fiim^r,Ur Ca^la.

For vent from


I,

West 25 St, New York

N.Y.

Teachers' guide available,

Ami. 7,309 million mi what ways is it true that all our sources of energyplant life, "oal. oil, and water -arc derived from the radiant energy we receive uom the sun? T. Furnish some evidence for or against the statements: The climate "ii Mars is similar to that which one would encounter on a iO-mi-high -'i on earth. Granted transportation, a self-sustaining colon v might
6.
' '

SUGGESTIONS FOR FURTHER READING


e<L, I). Van Nostrum! Baker, Robert H.: "Astronomy," 7th 1989. ., Inc., Princeton, NJ. t Known to the Unknown, n Bauer Carl \ "The Universe bom fee Umvcrsitj Kdueation, Pennsylvania Stale University. Continuing
:

'"'

Company,

established on Mars. 8. The four outermost


i
1

npitei-

of Jupiter's 12 satellites revolve about rrom east to west, contrary to Ihe motion of most satellites in solar system and to the direction of revolution of Ihe planets around m. Can yon suggest a possible reason for this retrograde motion?

Rocket Propulsion
ally, for practical reasons,

21

confined to two dimensions. So the


is

theory of motion in one plane


cation,

adequate. In further simplififlight

we may begin by considering the

path to be a

straight line (one-dimensional theory).

We shall
weight ratio

consider in this chapter the basic principles of rocket


1
1

propulsion; the effects of mass ratio, specific impulse, and

mist/

on the

flight of

a single-stage rocket; and then the

performance of multistage rockets.

Rocket
Propulsion
3,1

MECHANICAL PRINCIPLES: NEWTON'S LAWS


in

Three laws formulated by Sir Isaac Newton century are fundamental to rocketry:
Necessity
tion;
its
is

the seventeenth

not the mother of inven-

1.

A body at
to

rest

remains at rest and a body


in

in

motion continues

knowledge and experiment are

move

at constant speed

a straight line unless acted upon

parents.

W.

R.

Whitney
2.

by an
in

externa}, unbalanced force.

An unbalanced

force acting on a body produces an acceleration the direction of the net force, an acceleration that is directly

proportional to the force and inversely proportional to the mass of the body.
3.

All vehicles move !>y reaction with some other thing. Cars require traction on the road. Snip* and planes push or pull themselves through water or air. Only rockets carry their own "something

For every force that acts on one body, there is a force equal magnitude but opposite in direction that reacts upon a second hody.
in

Table

3.1

Consistent systems of units for Newton's second law

else" to push against. In the

words of J. X. Savage, "a rocket is any machine that propels itself by ejecting material brought
along for the purpose." A rocket is an internal-combustion engine that carries its own supply of oxygen (in any of several forms of "oxidizer")- Therefore, it

Name

of system

Unit of

mass

Unit of force

Unit of

acceleration

does not require air but can operate in a vacuum, as


description of a rocket in flight
is

in

Mks (absolute) Cgs absolute Cgs gravitational


British British

kilogram

gram No name assigned

newton* dyne*

meter, second -

centimeter second

gram
poundal* pound

centimeter, second 3

space.

m = W,
a particular application
It is
absolute
gravitational

The

pound
slug*

foot/second 2
foot /second 1 as that

dynamics of rigid bodies. venient to consider separately the motion of the center of mass and the motion of the body around its center of mass. The former
of the general theory of the
is

con-

Any system

W, g

Same

unit

Same

unit

as that

used for
In

used for g

the theory of flight performance, the

bility

and

control.

The

the theory of stapowered flight of a ballistic rocket is usulatter,

each

set the starred unit

is

the one usually defined from the second

law

so as to

make

in F

kma.

20

22

Looking Out

Rockets, Satellites, Space Travel


If this in

Rocket Propulsion

23

3.2

UNIFORMLY ACCELERATED MOTION


is

convenient to list and remember the equations which apply acceleration in a straight to a body which moves with constant met. The average speed often but one case, special line. This is a required, 5 = s/t, or time by the divided traveled v is the distance
It
,

mixture were ignited, there would result a high pressure the chamber exerting force equally in all directions. The pt sphere would remain at rest because there would be no net force acting on it. Consider a section to be removed from one side of the sphere

=U

M>

The sphere would now experience a net force. Since there would be no balancing force across area A\ (Fig. 3.1b), the force on area A-> would cause the sphere to
so that the gases could escape.

direction, the accelSince we have assumed motion in a constant a - (i Vi)/t, the time, by divided speed in eration is the change

to the left. The magnitude of this force or thrust F would be equal to the product of the pressure p c in the chamber and the area A t of the throat:

move

or
v,

- =

at

03)
f is

F = pAt A greater force


3.(>)

cm

speed Since the speed changes at n uniform rate, the average speeds: final and initial the of sum equal to half the
S

+
2

"

(3.3)

can be obtained under certain conditions (Sec. nozzle at the exit (Fig. 3.1c). The contribution of the nozzle is represented by a thrust coefficient Cp used as a multiplier in the previous thrust equation, so

by adding an expansion

By

combining these, two other useful equations can be obtained. Eliminating u s and v, we get
s

F =

PrAtCp
laws,
if

(3.7)

From Xewton's
A(mi>)

is

M + Jo*
6

<

3 4>
-

a system, the rate of change of

momentum

the net external force applied to of the system is

By

eliminating

and

from Eq.

(3,1) to (8.3),

we

get

_
(3.8)
is

When
3.3

a rocket
is

in free space,

the net external force acting upon


their rate of

REACTION PRINCIPLE

the rocket

zero. If

mass

particles are ejected


iv,

Xewton's third rocket engine develops thrust by employing sphere (Fig. stationary a Imagine manner. law in the following

with a constant exhaust velocity

from the rocket change of momen-

tum
'

gives the rocket

an accelerating

force

vapor 3.1) containing a combustible mixture of gasoline

and

air.

- "

A,

* F and
c,

(3.9)

The negative
directions.

sign expresses the fact that

are in opposite

a Ah-

P,

The exit pressure p of the gas from a rocket often may be either greater or lower than pressure of the racket's environment,
ambient pressure
p. Also, while p r remains constant, p will decrease as the missile gains altitude. If the difference between the

(a)
Fig. 3.1

(6) Reaction, the principle of


jet

M
propulsion.

two pressures

is multiplied by the exit area .4,.. we have the magnitude of the unbalanced force (p c pa )A e acting on the rocket.

24

Looking Out: Rockets, Satellites, Space Travel


is

Rocket Propulsion

25

This force

called the "pressure thrust," in contrast with the

3.4

EFFECTIVE EXHAUST VELOCITY

thrust" expressed in Eq. (8.9). The total thrust of a rocket engine can be expressed as the sum of the momentum thrust and the pressure thrust:

"momentum

velocity
V,n

In order to simplify the thrust equation, an effective exhaust >\. fi is defined as

F = -

-^T- V*

(}Je

F
V-) A
-

(3.10)

Am

A!
is

(3.11)

"Usually, the only

term on the right-hand


is p,

side of this equation

Then Eq.
_

(3.10)

written

in

simplified

form as
(3.11a)

that

will

vary with respect to time

the ambient pressure.

Am
v

66

64

/-"
f

Of course

is

variable with altitude, whereas

, is

o X
1

62

a particular rocket system.


sion of the gas,
if

Cnder optimum conditions

constant for for expane,. f r

when p, = p, the effective exhaust velocity equal to the theoretical exhaust velocity r,.
SPECIFIC IMPULSE
of a rocket engine
is

=e

60

/
58
-

X
3.5

/
i

The performance
its specific

impulse. This

is conveniently described by the thrust produced divided by the

56 54

il
40,000
Altitude,
ft

weight of propellant consumed per second


_! 80,000

20,000

60,000

100,000

Aw/At
Since

(3.12)

F and w

are expressible in the

same unit
If

Fig. 3.2

Decrease of

thrust with altitude,

V-2

missile.

unit for specific

impulse

is

the second.

(e.g., pounds), the other factors are held

Positive thrust

Negative

thrust

constant, the speed that a missile can attain is directly proportional to the specific impulse of its propellants.

The specific impulse varies with altitude, since thrust is variable with altitude. By combining Kqs. (3.11) and (3.12), the following useful relationship is obtained:
j

/' _ Vv it / At Air/ At " i) Am II

Am

r,.
'

fi

-t
Fig. 3.3

~f

(3.13)

To

Pressure thrust

in

a rocket motor.

avoid the difficulty of having /, become infinitely large as the gravitational acceleration g approaches zero at high altitudes, it is generally agreed that the value g u = 32.2 ft/sec- si mil be used
in K<). (3.13):

The resulting decrease in thrust as a missile gains altitude is shown in Fig. 3.2. If, as often at sea level, p e < P-, the pressure
thrust term will be negative (Fig. 3.3).

(3-14)

Rocket Propulsion

27

26

Looking Out: Rockets, Satellites, Space Travel

intended to summarize the facts that certain quantities, such as theoretical exhaust velocity u propcllant flow rate Am /At, gas pressure in chamber p and exit pressure p, are constant for the rocket system. Other quanti-

The

simplified

graph

(Kig. 8,4)

is

As the measure of over-all engine performance, specific impulse and expansion performance. From thermodynamics il may be shown that
related to both combustion performance

ties,

such as thrust F, effective exhaust velocity vMt and specific

<-
M

(3.15)

F> "'

where T is the combustion temperature and is the molecular mass of the exhaust gas. Thus a hot, lightweight gas gives a high specific impulse. Roth a large value for the heat of propellant combustion and low specific heat of the gas are desirable to produce the high temperature.

-*.ve ,Pe ,Pc

The requirement of low-molecular mass suggests that the products of combustion should be rich in hydrogen compounds.

3.6

FUEL COMBUSTION AND EXPANSION


basic principles
in

The
Sea level
Altitude
Fig.

150,000

ft

ments
p and
increase

design can be illustrated

engine using a liquid


(,

we have been discussing and some refineby considering a typical rocket fuel and oxidizer (Kig. 3.5). The engine conCombustion

3.4

Simplified representation of the fact that dm, dt, v

p t are independent of a rocket altitude, while F, v,ti, and with altitude since they depend on ambient pressure pa
.

De

Laval

chamber

nozzle

impulse

/,

vary with altitude since they depend upon the ambient


.

pressure p a
Table 3.2

Performance of typical
for expansion from

liquid propellant
lb
in.
1

combinations (calculated

300

to

otm)

Propellant combination

Mixture
ratio

Exhaust
velocity,

Specific

impulse,
sec
Fig, 3.5

(oxidizer/fuel)

ft/sec

Simplified liquid racket motor.

Liquid

oxygen and 75% ethyl alcohol, H 5 (V-2 propellant) Liquid oxygen and liquid H-,. Liquid oxygen and kerosene Fluorine and hydrazine H-.0;:(S7%) and H,.0 (13%) Red fuming nitric acid and aniline

25%

1.3 5.33 2,2 1.9

7700
10,800

7,970 9,610

239 335 248 299


126
221

verts the thermochemical potential energy of the propellants into the kinetic energy of the gas in the exhaust jet. The steps involved

3.0

Ni from ethane

4,060 7,090 7,010


&.

218
Sons,
Inc.,

From G,

P. Sutton,

"Rocket Propulsion Elements," John Wiley

and expanfrom their tanks into the injector by means of compressed gas or a turbopump. The injector distributes the fuel and oxidizer in a flow pattern that causes thorough mixing. Ignition is started by a device at the surface of the injector; thereafter heat from the combustion gases mainsion. Tin: liquid propellants arc forced

;nc propellant feed, injection, ignition, combustion,

New

York, 1949.

28

Looking Out: Rockets,

Satellites,

Space Travel

Rocket Propulsion

29

tains continuous ignition.

Combustion takes place throughout the combustion chamber with some residual burning in the exhaust
gas
jet.

wall before reaching the nozzle exit.

The

thrust coedieient

is

slightly higher during separation than for a full-flowing nozzle.

During combustion, the propellants change from liquid to new chemical gas, and by electron sharing they combine to make into thermal converted is energy compounds. Chemical potential The change temperature. high very energy, raising the gas to a of the temperature high plus the from the liquid to the gas state
forced gas results in a high chamber pressure. Gas particles are
to the rear.
It is

Optimum
expansion
Jet separation Jet separation
.

Underexpansion expansion
'

Pe

> Pa

Pe <Pa
6

the purpose of the nozzle to allow the gases to leave the


Expansion area ratio,
Fig.
t

rear rocket in smooth flow and also to accelerate these gases. The A area throat converges to a first of the combustion chamber the about have which may area A then expands to an exit

3.6

Jet separation.

and same diameter

m as the combustion chamber. The change from potential energy (nondireeted thermal motion of gas atoms) to steps. the kinetic energy of a high-velocity gas jet occurs in two nozzle, the of portion As the gas passes through the converging up. the decreasing cross-sectional area causes the flow to speed
speed corresponding to sonic speed (Mach 1)* at the nozzle throat provided the chamber surpressure exceeds a critical value, approximately twice the nozzle diverging rounding atmospheric pressure. The addition of a

3.7

BURNOUT VELOCITY AND RANGE


line inclined

Consider the case of a rocket moving in a straight

at

an angle

with respect to the direction of gravity, with thrust

paraDel to the path.

The equation

of

motion

will

be
(3.17)

The

gas flow reaches a

maximum

m
where

to
At

D +

mg

cos

is

the aerodynamic drag and g

is

the acceleration of
usually depends on

provides for even more acceleration of the gases. A typical throat speed may be 4,000 ft/sec and exit speed 7,000 ft/sec. The expansion area rat in

gravity at the location of the rocket. Since

A,

Cilo)

A
is

chosen for a particular engine to give the highest average thrust over the powered portion of the trajectory, For a given c a bell nozzle may be some 30 per cent shorter than a conical nozzle, and hence its use conserves rocket weight. An interesting phenomenon called jet separation may add additional thrust. When the exit pressure is very low in compari-

son with the ambient pressure, gas flow breaks away from the
Fig. 3,7

Forces on a rocket,

* Mach number M is defined as the ratio of Free stream speed v to = v/a\ it is the ratio of directed molecular the local speed of sound a, motion to random molecular motion.

the shape and speed of the rocket and the density of the snrroundng air, let us assume for this illustration that the rocket is at such

30

Looking Out: Rockets,

Satellites,

Space Travel
(3.17)

Rocket Propulsion

31

high altitude that

D=

0. If

we divide Eq.

by

m and

use
3.9

Eq. (3.13) to set


1

F = gJ.Am/At, we have
(3.18)

MULTIPLE-STAGE ROCKETS
empty mass
must be used to even after most of

Am
the rocket starts from rest,
v

In a single-stage rocket the propulsion energy


accelerate the entire
of the rocket

t'^'irsIf

that

we assume

tliat

0.

We

set

empty mass is no longer useful. This severely limits the velocity attainable. Tn fact, with present fuels, a single-stage
rocket cannot achieve velocities of the order of 25,000 ft/sec and higher required to place a satellite in orbit or to escape the earth's

tVi/ff

mass,

and let R he the ratio of initial R = m /m b Then E(|. (3.18) can be


u
.

mass

to final

burnout

solved (Appendix )

to find the velocity


vt

at burnout
(3.19)

gravitational

field.
is

= hu

In

gh cos

multiple-stage rocket

made up

of a

number

ent sections each equipped with a propulsion

of independsystem and a portion

where k is the duration of burning. The two averages iv and g are necessary since the values of both effective exhaust velocity and gravitational acceleration are dependent on altitude. Greater range and less time for interception of a rocket will
result

of the total propellant load. After the first (booster) stage has
its burnout velocity, its dropped from the rocket. A second (sustainer) stage carrying the payload is then fired and continues to accel-

lifted

the entire rocket and has reached


is

empty mass
erate the
(

from increasing the burnout velocity of the missile. This improvement, can he obtained, according to Eq. (3.19), by increasing the effective exhaust velocity and the mass ratio.

now

lightened missile to the appropriate

final velocity.

3.8

MASS RATIO
ratio
is

two stages can be used, but design and operational difficulties become more numerous as stages are added. If each of a series of stages has the same values of specific impulse, dead-weight fraction, payload fraction, and thrust/ weight fraction, each will contribute the same increase in velocity to the
)f

course more than

The mass
mass

defined as the quotient of the initial or total

final

payload. This design results in the lightest over-all rocket


simplified expression for the burnout velocity of a two-stage
is

of a rocket

and

its

burnout mass

h 4 :

to perform a given mission.

A
(3.20)
III:,

rocket
Vt

This

is

one

or several dimension less ratios useful in


lie

comparing

=
t

fvrln

(/r,/rs)

(3.22)

rocket designs. Others, whose- definitions should

apparent, arc

the thrust, full-weight ratio, the dead-weight fraction, and the payload fraction. The burnout mass is related to the initial mass

Here R is the initial mass of entire rocket divided by the burnout mass of the first stage plus the initial mass of the second stage, R = (wioi vus)/("'m + t 02) and R.< m hi,,., ,jj,,,. if the second

simply by

stage

Am
where

(3.21)

the propellant flow rate, From Eqs. (3.18) and (3.19) it is evident that to achieve the desirable high burnout velocity, a fuel with high specific impulse is needed. Further, for a given value of / larger mass ratios provide higher values of iv The mass ratio of the World War II
is

Am /At

small in relation to the first stage, the value of the logarithmic term in Eq. (3.22) will he greater than that in Eq. (3.19), predicting a greater final burnout velocity for the twostage rocket than that given by Eq. (3.19) for a single-stage
is

made

rocket in vertical flight, namely,

1%

i\.rr

In R.

3-10

NUCLEAR PROPULSION

Some advanced concepts


s1

German

V-2 rockets was about 3.2. For present rockets


.">.

R U

for rocket-propulsion systems have to do with development of recoverable boosters, restartable engines,
"nit>k'

as high as

propcilants.

and nozzles which allow

reduction in

32

Looking Out: Rockets.


size.

Satellites,

Space Travel

Rocket Propulsion

33

engine

But

efforts are also being

made

to find

new sources

of

should

rocket power, other than chemical reactions;. Figuratively, we like to be able to pack the power output of Hoover Dam 6 kilowatts) into a sports car. The development of (1.3 X 10 nuclear power sources promises to provide specific impulses significantly greater than the values,
fuels.

around 400

sec, for

chemical

Research on the use of a nuclear reactor as a rocket energy source has been carried out since 1955 in Project Rover, directed by the Atomic Energy Commission and the National Aeronautics

Pressure shell

Nozzle

Fig. 3.9

KiwI-A nuclear engine at Project Rover test

site in

Nevada.

Reactor core

space.

So one would expect

to be able to

nuclear energy into thrust.


Fig. 3.8

The

limiting factor

put almost all the is the energy denit

Scheme

for a nuclear-powered rocket engine.

sity one can

put into the propellant to eject

at sufficiently

high speed.

and Space Administration. The


Kiwi's, after a flightless bird.

test engines

have been named


in solid-fuel

Heat

is

generated

elements by nuclear fission (('hap. 20). Hydrogen gas flows through channels in the core. The heated gas is exhausted at high
speed through a nozzle (Fig- 3.8). The thermodynamic (Caniot) efficiency of any heat engine
is

\ssumc thai one has an ideal nozzle to recover directed energy from the thermal motion of the propellant molecules and that the propellant acts as a perfect gas. Then
kinetic

RT

(3.24)

given by
Efficiency

7',

T->

(3.23)

Ti

and the exhaust velocity v c is proportional to \/T/p or to \/T/M, where p is the density of the propellant, is its molecular mass, and Ft is the universal gas constant. For high velocities one wants

where 7'i is the temperature (absolute) of the source of energy and Ta is the temperature at which the working fluid is discharged.

maximum temperature and minimum

The

lieat -exchanger

nuclear engine exhausts into a


especially

relatively low temperature environment,

when

in

,J

molecular mass. Thus hydrogen heated to the highest feasible temperature gives the largest specific impulse of any material. Estimates range from 00 to 1,500 sec for the specific impulse of a heat -ex changer

34

Looking Out: Rockets, Satellites, Space Travel

Rocket Propulsion

35

nuclear rocket engine. Recalling the relation n, = 7 p ln (mo/m,), with nuclear proit is apparent that the larger l. p attainable or escape velocity orbital desired pulsion allows one to reach a
velocity with a

rocket

is

very large.

The weight

of the electric

using nuclear fission or solar radiation devices,


to

is

power plant, even a major obstacle

an

efficient ion rocket.

much

lower

initial fully

fueled weight (smaller

mass ratio )<>/') Under Project Sherwood, studies are being conducted to find ways of controlling and using the energy liberated in the fusing of
the lightest nuclei into heavier nuclei.
in

s
Electrons
Distributor plots and

El eel Electric generator

V-a f

Electrons

The phenomena involved

housing ot 40,000 volts

>.

thermonuclear (fusion) rockets, plasma rockets, and ion rockstudy ets fall under the general term magn^ohydrodynamica: the and magelectric by upon acted of the behavior of ionized gases
netic fields.

Propel ont
I

Heated to a very maintain a high-speed would high temperature, the deuterium rated in impulses specific of plasma (hot, ionized gas) capable confining a in problem difficult millions of seconds. There is a million around :i">0 he to plasma at the temperatures estimated degrees. Perhaps the plasma could be kept from coming into contact with material walls in chamber and nozzle by suitably shaped

Deuterium

is

a likely fuel for a fusion rocket.

Heater coils ^Ionization gr

20,000 volts-''
10,000 volts-

5,000
Fig. 3.10

volts

Scheme

for

an

ion rocket engine.

Propellent injection

magnetic

fields.

3.11

ION PROPULSION
of one or

The removal
laut,

more

electrons from molecules of a propelgrids, proHigh- current


circuit

by passing the propelknt through heated metal

vides ions which can then be accelerated to high velocities through a nozzle by an electric field. Volt age takes the place of tempera-

Arc discharge

ture in producing acceleration. One such technique uses metallic rubidium or cesium prope.l-

Each time an atom of cesium comes in contact with the heated tungsten grids, an electron leaves the cesium atom and goes to the tungsten metal. The resulting cesium ions travel past decreasing potential levels and arc accelerated
lant

and tungsten

grids.

to their final exhaust velocity.

The
will

It ion rocket will always have relatively small thrust. in rockets) nuclear or chemical require assistance (from

Fig. 3.11

Scheme

for

plasma rocket engine.

ground takeolTs where strong gravitational force must be overcome. But the performance of an ion engine at high altitudes will be very good. Estimates of its specific impulse are as large as 20,000 sec. The amount of electric power required for an ion

3.12

PLASMA PROPULSION

Hie propcllant
electric arc in

may

be heated directly

by maintaining a powerful
But
this device,

it.

In this

way

high temperatures can be obtained,

leading to a specific impulse of perhaps 2,000 sec.

36

Looking Out

Rockets, Satellites, Space Travel

Rocket Propulsion

37

power, too, will require 8 great amount of electric thrust. watts for each pound of

about

(50

kilo-

solar rays
lie

would he used

to

heat hydrogen gas which would then


ion or a fusion system.

expelled through a nozzle. Kstimated values of the thrust are low

applied conIn plasma and ton propulsion the thrust can be these techby Hence time. period of tinuously over an extended on earth whose weight rockets space niques one can propel in propulsion. ion thrust of greatly exceeds the

hut are several

hundred times those of an

3.14

MODEL ROCKETRY
a youth has
felt

Many

the urge to become a backyard rocketeer.

3.13

SOLAR PROPULSION

pressure of solar In one scheme of solar propulsion, the radiation sphere, reflecting lightweight a perhaps rays (ailing on a "sail," scheme, the another In if. propel would attached to the spaceship
Sun's rays heat water

of Rocketry, founded in 15)57, seeks to advance model rocketry as a scientific hobby and as ati educational program. The NAR has developed rules and procedures for a safe, supervised, citizen-operated model-rocketry program

The National Association

for enthusiasts of all ages.

Model rocketry
rockets

is

concerned with small,


balsa,
plastic,

light,

inexpensive
noninetallic

made

of paper,

and other

circulating
at Focus of mirror,

producing steam
Steam-driven
turbogenerator
to

powered by commercially available rocket motors. Emphasis is placed upon design, performance, flight characteristics, instrumentation, and reliability. Competitions are sponmaterials,

sored

hy

local societies.

I'iiblicat ions

ami informal

ion

about the

XAR

can

lie

obtained

develop

from G. Harry Stine, President, National Association of Hockel rv, Stamford Museum it Nature ( "enter, Stamford. Connecticut.
Physics teachers

may

he interested

in

model rocketry as a

device for stimulating student interest in mathematics, mechanics,

aerodynamics,

meteorology, electronics, optics, and pho-

tography. Ideas based on the experience of the most active sections of the NAIl may be requested from Dr. Stine at the address

above.

MANUFACTURERS OF MODEL ROCKETS


American Telasco Limited, 135 New York Ave., IhUesitc, X.V. Centuri Knpncering Co.. 340 \V. Wilshirc Drive, Phoenix 3, Ariz.
Ci>aler Corporation, P.O.

Solar sail

Box 2S0, Hiiless. Tex. Bates Industries, Inc.. P.O. Box 227. Penrose, Colo. Model .Missiles, Inc., 2ti!<) Bast Cedar Ave., Denver 22, Colo. Propulsion Dynamics. Inc., P.O. Pox 2XXA. Ut. 1, Officii, Utah

Rocket Development Corp., Box 522, Rich mood, bid. Cnited Scientific Co., Inc.. P.O. Box S9, Waupaca, Wis.

FILM
Schemes for solar propulsion, (o) Steam generated by solar energy drives electric generator. {b\ Recoiling photons
Fig. 3.12

The

Itislor,/

impart momentum to

ami Development of the fiwkri. 10 min (1962). MeUruw-llill Text-Film Division, 330 West 42 St., New York 36, N.Y. Available in color or black and white.

sail.

38

Looking Out: Rockets, Satellites, Space Travel

Rocket Propulsion

39

SUGGESTIONS FOR FURTHER READING


Hobbs. Marvin: "Fundamentals of Rockets, Missiles, and Spacecraft," John F. Rider, Publisher, Inc. New York, L962, 27ft pp. "An Introduction to Rocket Missile Propulsion," Rocketdync, Canoga
Park, Calif.. 1958,
12ft

7. Show that if one increases the exhaust temperature of a hc-alcNclianger nuclear rocket, the specific impulse and power requirements ! and the mass ratio will decrease as exp T. What will increase as J'
limits this favorable picture?
8. The Atlas 1CBM is called a '-stage rocket because of its unique application of the step principle. The Atlas has three main engines: two booster engines and one suslainer. Each engine receives propellant from a single very lightweight tank. The three engines are mounted parallel to one another. All three engines are ignited at takeofT. I/titer. at staging, the boosters ami housing slide backward on rails and drop to earth, leaving the suslainer engine to propel (he vehicle. Can you suggest some advantages of this type of staging over the convent iona! tandem staging? 9. How can rocket action be demonstrated with a toy balloon? 10. What is the fallacy in the following argument? "A horse pulls on u cart. By Xewton's third law, the cart pulls back on the horse with a force etjiuil to that exerted by the horse on the earl. Hence the sum of the forces is zero, from which it follows that it is not possible for the
I

pp,

"Model Kits," Revcll, Inc., 4223 Cileneoe, Venice, Calif. "The Next Ten Years in Space, 1959-1989," House Document 115, U.S. Government Printing Office, Washington 2ft, DC., 1959,
221 pp.
,

"1959

Missiles

and Rockets Encyclopedia," Re veil,

Inc.,

Venice,

Calif., 32 pp. "Physical Data, Constants and Conversion Factors," General Electric Missile and Space Vehicle Department (Mail: P.O. Box Sftfto, Philadelphia 1, Pa.), 1959, 24 pp. Rocket Experiment Safety: Safety Suggestions for the Rocket Hobbyist/'

Atlantic Research Corp., Alexandria, Va., 1958, 19 pp.

Seiferl,

Howard

S..

Mark M.

Mills,

and Martin Summerlield: The

horse to accelerate the cart."


11. Comment on the remark, "Space stations will be obsolete when they are feasible." 12. A rocket whose thrust is 27,000 lb weighs initially 22,000 lb, of which SO per cent is fuel. Assuming constant thrust, find the initial acceleration and the acceleration just before burnout. Xeglect air

121-140, Physics of Rockets, American Journal of Physics, 15:1-21,

255-272 (1947). and "Space Facts: A Handbook of Basic and Advanced Space Might ElecGeneral Engineers," and Scientists for Data Environmental Forge Space tric Mis>ile and Space Vehicle Department, Valley Philadelphia Box 1, Pa.), 8555, P.O. Technology Center (Mail:
I9f>0. fil

resistance
13.

and variation
(3.19)

of g.

Arts. 39.2 ft/sec 2 , 190 ft/sec 2


for a rocket

pp.

launched horizontally and continuing in a path parallel to the earth, the burnout velocity is given by Vt = err In R. II. What is the minimum value of mass ratio R for which the
exceed the effective exhaust ve2.718 4 ns. R 15. Do you agree with Professor Fink's comment that Hie methods of achieving lift listed in order of increasing sophistication of the underlying physical principle are (1) satellite vehicles, (2) displacement of lighter-than-air craft, (3) hover craft or ground-cushion vehicles, (4) vertical flight rockets, (5) vertical takeoff and landing machines, (<>) conventional airplanes? If so, how do you account for the historical fact that the "simplest" methods were not the first to be suecessfullv Used?
n,

From Eq.

show that

QUESTIONS AND PROBLEMS


Verify the statement: "Near the surface of the earth, gravity each second, robs a vertically rising rocket of about 20 mi/hr in speed or about 2,400 mi/hr for each 2 iniu of acceleration." ^ angle ot 87 2. A projectile is Srcd with a speed of 300 ft/sec at an height of with the horizontal. Compute the speed when it first reaches a j4s. 83.5 ft, sec .jqq- fj._
1.

burnout velocity
locity iv?

of a rocket

will

>

dynes acts on a 20-gm mass for 8.0 sec. (a) What Bow Tar docs the mass move from rest in the acceleration is caused? 8.0 sec? () How fast is it going at the end of S.O see? Am. 24ft em/see, 8,140 cm, 1,900 era/see
3.

force of 4,900

(I>)

that the mass ratio tin/m,, for a multistage rocket is the product of the mass ratios of its individual stages. cesium, a prospec5. Would you consider an alkali metal, such as
4.

Show

tive propellant for an ion rocket?


6.
If
it

Why?

becomes possible to convert nuclear-fusion energy of a plasma

generdirectiv into electric energy, without the conventional rotating feasible? ator, would this make ion propulsion of rockets more

Escape from Earth


tioual field, a vehicle in space
of gravitational fields,

41

would encounter an endless mixture one superposed on another. The terms escape and capture refer to the transfer of the vehicle from one
field

to another.

4.1

GRAVITY

Escape from Earth

Newton formulated the law of universal gravitation: Every particle in the universe attracts every other particle with a force that is directly proportional to the product of the masses of the two particles and inIn addition to the three laws of motion,
versely proportional to the square of the distance between their centers of

mass
(4.1)

No

thing
:

is

too high for the daring of

F =G
where
[

mortals
folly.

We storm heaven itself in our


Horace
in

F =

force of attraction

Every great advance


issued from a
nation.

science has
of imagi-

new audacity

m and mi = s = G =
In

masses of the two particles distance between them


gravitational

constant, whose value depends on

John Dewey

the system of units used

mks

units
(5.07

G=

10 " newton-mVkg s

traveling in space, a vehicle

Gravity acts as a brake on a vehicle leaving the earth. While is always subject to some gravity.
vehicle attracts

The

and

is

attracted by

all celestial

bodies.

But

Through the ages men have dreamed of the power of flight. In Creek mythology Daedalus and Icarus made a daring ascent into the air on wings made of birds' feathers and wax. In the notebooks of Leonardo da Vinci are found detailed drawings of a flying machine. With the success of the Wright brothers, man began to realize his long ambition of flight through the air. But now he turns his dreams to flight beyond the enveloping and
protective atmosphere into space. In designing a vehicle to escape the earth, one has to solve the problem of piercing the earth's atmosphere. A second, more

because gravitational force follows an inverse square law (/' <* 1 -), the mutual attractions of only the nearest bodies are usually

When a vehicle returns to earth, an increasing gravitational force.


significant.
4.2

it is

accelerated by

FREELY FALLING BODIES


starting from rest near the surface of the
first

An unsupported body
earth drops 10
iH'Xt
r, f

ft

during the

second, 04

ft

at the end of the

second, 144 at the end of the third, etc. It has an acceleration

troublesome, problem of escape is that of overcoming the force of gravity. Since each body in the universe has its own gravita40

"V2 ft per sec per sec, or 32 ft/sec-. The symbol g is used to represent the acceleration due to gravity. At sea level and 4:">

latitude, g

has a value of 32.17 ft/sec 2 or 9.806 m/sec 2 The value of g varies slightly over the earth owing to local
.

42

Looking Out: Rockets, Satellites, Space Travel

Escape from Earth

43

variations in

mass

distributions

and to the

fact that the earth

bulges slightly ai the equator. Surface gravity values vwy from planet to planet owing to differences in mass, radius, and rotational speed.

The small mass m is used only as a means of detecting and measuring the gravitation field, Whether m is large or small, the. force per unit mass placed at .4 has a definite value, J.

When

air resistance

for uniformly accelerated


t,

can be neglected, the equations in Sec. 3.2 motion apply to falling bodies.

By substituting Eq. (1.1) for F in Kq. (4.2), we get the expression for the gravitational field intensity / at a distance r from niitss .1/ in terms of the universal gravitational constant Gas

sec

v,

ft/sec

s, ft

m
When

r2

(4.3)

O O

32

16

one knows the field intensity, one can mass m as the product of m and /, any on
Fig,

find the force acting

64

64
4.1

Position

and speed of a body


rest after successive

falling freely

from

equal

96

144

time intervals.

Fig, 4.2

Gravitational forces of attraction.

\
4.3

128

256

GRAVITATIONAL FIELDS

force which one body exerts on another at a distance is conveniently described by the "force field" set up by one of the bodies, the source. Various kinds of forces can be treated in this way. Electric charges exert forces upon other electric charges.

The

tional force

Magnets exert forces on other magnets. Matter exerts gravitaupon other matter. The force exerted on a unit test particle (unit charge, unit mass, etc.) has a definite magnitude and direction for each possible location of the test particle.

Fig. 4.3
field.

Parabolic poth of a projectile

in

a uniform gravitational

The whole assemblage

of these

for08 vectors, or the mathematical function


position,
is

relating force to

For a freely falling body, Newton's second law of motion becomes F = mg. At the earth's surface, therefore, the gravitational field intensity
is

called a field of force.

Any path
is

that would be fol-

equal to

g,

the acceleration due to gravity


(4.4)

lowed by a free incrtialess test particle

called a line of force.

The

gravitational field intensity / at

any point

in the

'

= - =

space near a mass ,1/ is defined as the force per unit mass acting on any mass m placed at A
:

newton
kilogram

meter
second 2

(4.2)

111

mka

units, g

9.80 m/sec 2

44

Looking Out: Rockets, Satellites, Space Travel

Escape from Earth

45

field is pracIn a region of free space where the gravitational taken by a path the tically constant in direction and magnitude,

and

in

the third

projected mass

is

a parabola (Kig. 4.3).


If

Wt = GMjn (- - -)
we add these three expressions, the intermediate values r, and n cancel out. The work done in the first three intervals can be expressed in terms of the values of r at the ends: It and r 3 Thus
.

4.4

GRAVITATIONAL POTENTIAL ENERGY


find the

To

work needed to get off the earth, let us calculate the earth, work done in moving a mass m from the surface of the Imagine earth. the radius R, to a distance r from the center of

W
is

GM m (it ~
-

'

(4.5)

the general expression for the work required to

Distance

against the earth's gravitational field out to a distance


definition this
is

move a mass in r. By

r*
_

measured
from

the gravitational potential energy of mass

in

the field of the earth.

4.5
Fig.
tial

AA

Calculation of gravitational poten-

VELOCITY OF ESCAPE, FROM CONSIDERATION OF ENERGY


estimate the

energy.

To

maximum

height attained
its

straight up,

we may equate
its

kinetic
it

by a rocket fired energy at burnout to the


height, t
x

gravitational potential energy

acquires thereafter in rising,

with decreasing speed, to

maximum

^mv 2 = mgR*
\lt
''i..:.

(4.0)

</
:it

Example.

roirkci

has an upward speed uf 5.0 mi/see


it

burnout. Find

small equal intervals so the distance from 5 tor to be divided into force F a will lie practically conthat over each the gravitational done in each interval work thr stant. Then we can easily calculate 1 surface, Fa = QMjm A' At the and add to get the total. At the Since these values are top of the first interval Fa is OMjm r,. force in the first average the nearly the same, we can use for
'.

the

maximum height From Eq. (4.6)

attains.

mf-n
V

mi

ft

(*ixm
..

3960- mi' \
r.n<

880/ 25 / miV

"* \ / 32 \

%\&) =Uoj
r n , ax

i(irin

o)

{ iniV

) ( 82 \ /39(i0= mi

tcj

-U/U.*W
in this

interval

(!M<w
Fair,

ltr u

The work done

in

the

first

interval

is

then

8,S(W mi
Bohition?)

Wt =

8)

Vg

fir.

*> =
is

W* (l "

(What amplifying assumptions have been made


,')
4 -6

VELOCITY OF ESCAPE, FROM CONSIDERATION OF FORCE


gun on a
cliff.

Likewise the work

in

the second interval

If

cliff

overlooking the ocean

fires

a bullet horizontally,
of

,.

9 h --.., (i-I)

the bullet will strike the water at

some distance from the base


is

he

If

the

initial

speed of the bullet

increased, the range

46

Looking Out

Rockets, Satellites, Space Travel

Escape from Earth


acts on the

47

is increased. For a particular speed, which depends on the distance of the gun from the center of the earth, the hullet would make a complete circuit of the earth, at a constant altitude, A (Fig. 4,">), If it- did not encounter resistance, it would continue

its path. But the condition of experienced because there is nothing to resist the body's motion in response to gravity. Human beings have experienced weightlessness for the first

body and determines


is

weightlessness

to

move in orbit about the earth. Prom Newton's second law, F = ma, and Eq.

(4.2),

the

few seconds after leaving a high diving board, or for somewhat longer periods in aircraft on "zero g" trajectories, and more
recently in

force needed to hold the bullet in a circular path at altitude

is

manned

rocket flights.

4.8

POTENTIAL-WELL MODEL

Using Eq.
energy
tances r

Kp

(4."), we may plot a graph showing the potential which a body of mass ni would have at various disfrom the center of the earth (Kig. 4.6). When the mass m

50,000

25.000

,,, 25,000
1

50, 000 mi
1

ennnn

S GrOVltOtlOnol ,
free spoc
:

Fig. 4.5

Range increase*
reached.

with horizontal firing

speed

until

circular (orbital

speed

is

inv-fQi

R). This force

is

provided by the gravitational attrac-

tion of the earth, so


/'

(/,'

CM ,i +

i-ni

/,)'

(4.7)

Example. At what speed would a projectile have to leave a platform, horizontally, 300 mi above the earth in order to enter a state of "continuous fall" around the earth?

From Kq.
ys

(4.7),

Fig.

4.6

Gravitational potential energy of mass m, showing "well" analogy for

= = =

-C.U e

6.67

IP"" newton-m* 5.983


kg'
(3,950

10" kg

mi

earth's field,

R+
58.1

+ 300)

mi 1,609

m
from earth, li p = 0. As mass m is brought closer work is done on m by the earth's field and the potential energy of m acquires a larger and larger negative value. Thus on the surface of the earth we live in a gravitational well thousands of miles deep. To reach the moon or another planet we must climb out of this well onto the plane marked
is

ICm'/sec*
sec

infinitely far

7,2() in

1,700 mi/hr

and

closer to the earth,

4.7

WEIGHTLESSNESS

A body

in orbit around the earth or following an unrestricted, un powered course in a gravitational field anywhere in space is

"gravitational free space" in Fig,

4.(i.

said to be in "free fall," also called a state of "zero gravity."

A
orbits

potcntial-energy-well

Actually, gravity

is

not absent.

The

force of gravity continually

may

model for demonstrating satellite be made from a suitably shaped wine glass to reprc-

48

Looking Out: Rockets, Satellites, Space Travel


(r

Escape from Earth

49
is

sent the surface (Fig. 4.7) obtained by rotating the graph of Fig. 4.6 ahout its vertical axis. A marble representing the satellite

150

10 e

km) with a speed

of

about 30

km

see.

What

the

may

be caused to travel a variety of orbits by varying

its initial

velocity.

acceleration of the earth toward the sun? 9. Show that to escape from the atmosphere of a planet, a molecule of gas must have a speed r such that ! > 2C.i//r, where .1/ is the mass of the planet and r is the distance of the molecule from the center of the
t

Fig.
(c)

4,7

Potential -well
elliptic
(e)

model

for demonstrating circular


J.

What hearing does this have on the composition of (lie atmosphere surrounding the earth and other planets? 10. A balloon which is ascending at the rate 12 m/sec is 80 m above the ground when a -lour is dropped from it. How long a time will be required for the stone to reach the ground? Ans. 5.4 sec 11. An elevator is ascending with an acceleration of 4.0 It sec 2 At the instant its upward speed is K.O Ft/see, a holt drops from the top of the cage 9.0 ft from its floor. Find the time until the holt strikes the floor and the distance it has fallen. Ans. 0.71 sec, 2.3 ft 12. A body hangs from a spring balance supported from the roof of an elevator, (a) If the elevator has an upward acceleration of 4.0 ft/ sir- and the balance reads 45 |b, what is the true weight of the body? (ft) In what circumstances will the balance read 35 lb? {<} What will the balance read if the elevator cable breaks? Ans. 40 lb, a = 4.0 ft/sec s downward, zero 13. If the mass of the moon is the mass of the earth and its diameter is -J- that of the earth, what is the acceleration due to gravity on the moon? How far will a 2.0 gm mass fall in 1.0 .-cc on the moon?
planet.
.

and

orbits.

({See

S.

Schooley, Satellite

Orbit Simulator, American Journal of Physks, 30: 531-532


(1962).]

QUESTIONS AND PROBLEMS


1.

What

is

the largest gravitational force of attraction between

metal spheres cadi of 50.0 kg mass and 10.0 em radius? How does lllis force compare with the force of attraction of the earth on each sphere? Ans. 4.17 X 10" newton, weight is 120 million times larger 2. What would be the value of <j. the acceleration clue to gravity, if the earth had half its present diameter?

two

solid

Ans. I g, 3.2 ft standing on a diving hoard throws a ball with a horizontal velocity of 50 ft/sec to a man in the water. In doing so, she loses her balance, falls off the hoard, and strikes the water in 2.0 sec, (a) How far is the man from the base of the diving board? (b) How high is the diving hoard above the water? (e) What is the velocity of the ball at the end of its path? .bis. 100 ft, 64 ft, SI ft/scc, at 52 with the horizontal
14.

girl

3. If the mass of the moon were doubled hut the orbit remained the same, what would he the period of the moon? t. A 100-lb man starts sliding down a rope with a downward

acceleration of p/S. (a) What is his apparent weight? (b) What is the tension in the rope above the man? 5. Using the experimentally determined value of (7 and the distance

93

mi from carlh to sun. calculate the mas* of the sun. At what point in its trajectory does a projectile have its minimum speed? 7. If a rocket at tains a speed of (500 mi hr hy the time it reaches
10
6.

1,000

ft,

how many times g


earth

8.

The

is its acceleration? revolves about the sun in a nearlv circular orbit

Satellites

51

5.1

ELEMENTS OF AN ORBIT
define the position of an earth satellite in the solar system and its path, one needs to know the period of the satellite

To

to describe

Satellites

and the elements of its orbit, that is, the constants which fix its position and shape in space: The period is the time for a satellite to make one revolution around the earth.

The

perigee

is

of the earth.

Apogee

the position of closest approach to the center is the position of the satellite farthest from

the earth (Fig. 5.1a),

The
It is

eccentricity describes the flatness of the orbit as the ratio

no paradox to say that

in

our most

of e to a (Fig. 5.1/j).

Here

e is

the distance from the center of the

theoretical
to

moods we may be nearest


practical

our

most

applications,

Apogee

A. N.

Whitehead

Perigee

The launching
Sputniks
I

of the first artificial earth satellites, the


II, in

Russian

Fig. 5.1

Elliptical orbit.

and

1957, aroused worldwide interest in the


rockets.

power and control attainable with


investigations

The

special scientific

orbit to the focus at the center of the earth, while a

is

the semi-

made during

the International Geophysical Year

major

axis.

were significantly aided by data from instruments carried in satellites. From the orbit of a satellite one may better estimate the shape and dimensions of the earth. A permanent satellite can be useful as an aid in the navigation of ships, aircraft, and missiles. For a satellite which eventually returns to earth, measurements of the orbit may yield a more precise value of g. Atmospheric drag and the effectiveness of radio emission at various altitudes can be studied. Equipped with suitable instruments, a satellite can also measure solar and cosmic radiation, temperature and pressure variations, and the distribution of the earth's magnetic field. In short, satellites can tell us much that we want to know about our earth and much that we need know about space hazards before we venture into space ourselves.
50

The angle of inclination i of the orbit is the angle between the plane of the orbit and the plane through the equator (Fig. 5.2). The plane of the satellite orbit intersects the equator plane in a straight line called the line of nodes. This line intersects the
satellite orbit at

two points, called nodes. At one of these, the ascending node, the satellite crosses northward from "below" the equator plane to "above" the equator plane. At the other, the descending node, the satellite crosses southward from "above"
th f equator plane to

"below" the equator plane. The orbit


the longitude
V,

ele-

ment we now
"<>'

define

is

of the node, or the angle of

f
J

tiding node. This angle, P. in Fig. ,5.2, is measured in the plane the equator from the direction of the vernal equinox to the unction of the ascending node. (To describe the motion of a

Satellites

53

planet about the sun, one substitutes "ecliptic" for "equator" in the definitions above.)

The argument of perigee us is the angle measured in the orbit plane between the direction of the ascending node and the direction of the perigee.

To summarize, the elements of an orbit are period, perigee apogee, eccentricity, angle of inclination, angle of ascending node,
ami argument of perigee.

5.2

CIRCULAR ORBIT
of any body acted on only by an inverse square force a l/r ! ) due to a neighboring fixed body will ho an ellipse,

The path
(/-'

(i). To simplify our analysis, remainder of this chapter we shall examine an earth satellite in a circular orbit and consider only the interaction between the earth and the satellite. Although small perturbations may be produced by the atmosphere, the moon, other planets, and satellites, for the present these effects will be neglected.

circle,

parabola, or hyperliola (Chap.

for the

For a satellite in circular orbit, the gravitational force exerted on it by the earth has no component in the direction of motion which could either increase or decrease the speed of the satellite.
It

orbits at constant speed.

The

force

on the

satellite

is

given

by Xewton's law of

gravitation

F = G
-Q

Mm
(5.1)

where the mass of the earth and the mass of the satellite m are concentrated at the center of each, a distance r apart. The constant of gravitation G can In* determined in the laboraicffiirded as

Because the mass of the earth is so very large, the center of mass of the two bodies is practically at the center of mass of the earth. The motion may be described as a circular motion of the satellite about a fixed center of force.

tory.

The direction of the velocity of the satellite in circular orbit continually changing (Fig. 5.3). Gravitational force continually produces a "centripetal" acceleration a toward the center.

54

Looking Out: Rockets, Satellites, Space Travel


is

Satellites

55

For this uniform circular motion the acceleration


centripetal force
is

v-/r

and the

and since

mv*/r.

y-\A
v
canst.
\13\- const.

we obtain an
7'2

equation.

GM

(5.4)

which says that the square of the period of the satellite is proporcube of its distance from the center of the earth. This is Kepler's third law of motion, for the special case of a
tional to the circular orbit.

\a\ const.

5.4

ENERGY

Fig, 5.3

satellite in circular orbit is continually

accelerated toward center of

orbit.

The total energy remains constant in satellite motion. This can be shown very easily for our special case of a circular orbit.
Substitution for the speed of the satellite (Eq. 5.3) into the equation for kinetic energy E k gives

5.3

PERIOD
equate the gravitational force and the centripetal force

We may
-z

vk = \mv* i * = h

GMm
-

2r
Ey
of the satellite

(5.5)

,Mm f G
From

mv'1

Since the gravitational potential energy


(5.2)

is

~rr

B,
this equality

= -

GMm
(5.6)
is

we

find the speed that a satellite has to obtain


1
1

ie

total

to maintain a particular altitude

energy

= x

GM
-

Ek +
(5.3)

GMm
2r
(5.7)

The mass m of the satellite does not appear in the equation for speed. The closer the satellite is to the earth, the greater must be
the speed, because the gravitational attraction Since the angular speed tn is 2w/"period,
is

The total energy is negative for both circular and elliptical orbits. This means that the satellite is bound to the center of force and cannot escape unless sufficient positive energy is provided (see
*'ig. 4.7).

greater.

5.5

ANGULAR MOMENTUM

2x

JOM

Iho total angular momentum L of a satellite moving at constant speed in a circular orbit is the product of its linear momentum mv

56

Looking Out; Rockets, Satellites, Space Travel

Satellites

57

and the radius r. Vcctorially, the angular momentum is represented by a vector L drawn to scale to represent the scalar magnitude mvr and drawn along a line perpendicular to the plane of r and v in the direction indicated by tlie thumb of the right hand when the fingers are allowed to curt from the direction of r into the direction of v. Thus L results from a vector "cross product,"
the notation for winch
is

These observations are interpreted as proof that the earth bulges slightly around the equator, owing to the earth's rotation. The gravitational force tends to pull the satellite toward the
equator. Consider the gyroscopic property of the satellite.

The

gravitational force due to the bulge tends to tip the axis of the

L =
It
is

rX

(hit)
satellite in
is

obvious that for a

the total angular

momentum

constant. This

uniform circular motion is also true when a

Fig. 5.4

Angular momentum of mass


I.

is

re-

presented by vector

*S^
an elliptical orbit. The radius and speed vary, momentum remains constant. This is angular but the total law, that a line joining the focus second Kepler's equivalent to areas in equal periods of time equal out sweeps and the satellite
satellite

moves

in

(Fig. 5.5).

Fig. 5.5

The

satellite

sweeps out equal

areas

in

inequal periods of time.

Earth's rotation

Fig.

5.6

It

is

not feasible or even particularly desirable to launch a

different

Rotation of the earth and precession of the satellite orbit expose areas of the earth to the satellite, os shown in Fig. 5,7.

satellite into

a perfectly circular orbit. If such an orbit were attained, slight perturbations would soon make it elliptical. Observation of a satellite in orbit gives us information about irregularities in the shape of the earth. As the satellite orbits, the
plane of
its

orbit.

orbit rotates or regresses orbit turns in its

toward the west. At the


flattened.

The reaction causes the plane of the orbit to prccesK around the earth in a westerly direct ion, while the earth is rotating from "est to east. This precession may be an advantage in the case of
which thus
5.7).

same time the

own

plane, swinging the perigee

Certain types of observational satellites

may

"see"

around. Also, both ends of the orbit become somewhat

most of the earth's surface

(Kigs. 5.6

and

Satellites

59

QUESTIONS
I.

Why

is tin*

upper (dotted) path

in i)k>

accompanying sketch

not.

a possible satellite orbit about the earth?

Fig. 5.8

2.
it

will

Show ilial if frictional forms cause move into an orbit closer to (he

;i satellite to lose total energy, earth with an actual increase

speed. 3. After a certain satellite was put in orbit, it was stated thai the satellite would not return to earth but would burn up on its descent. low is this possible, since it did not burn up on ascent?
in
I

Motion

of

Bodies

in

Space

61

Law
Law

II.

The

line joining the

sun and a planet sweeps out equal

areas in equal periods of time.


III.

to the

The square of the period of a planet is proportional cube of its mean distance from the sun.

An

ellipse

may

of string to guide

a pencil

be constructed by using two pins and a loop (Kig, 0. 1). This method of construction

Motion of Bodies in Space


Fig. 6.1

Construction of an

ellipse.
If

have seen farther than ethers,

it

is

hy

standing on the shoulders of giants.


old saying quoted by

An

Newton

makes use
li.

of

the distances from


is

a geometrical property of the ellipse: The sum of any point on an ellipse to the two foci, A and

constant.

An

ellipse

with

its

center at the origin of coordiis

space vehicle when not under power is governed by the same laws which determine the motions of stars, planets, and comets. These laws are Newton's law of universal gravitation and Kepler's

nates
<>!'

and with the form


a2

foci

on the x axis

represented

by an equation

taws of planetary motion. Karly

in

the seventeenth century,

= + T b*

Kepler by inductive reasoning formulated his three laws to fit the astronomical observations and calculations made available

From

Kepler's second law,

if

the shaded areas in Kig.

(>,2

arc

him by his patron Tycho Brahc. Xewton in his "Principia Mathematica" (Ih'87) showed that the kind of planetary motion described by Kepler's laws can be deduced from the universal
1

1!

S3
x,
Fig, 6.2

f~~^

Law of areas.

law of gravitation.

6.1

KEPLER'S LAWS

Kepler's description of planetary motion

may

a " equal, a planet takes equal time intervals to travel the distances St, $ and s a
2l
.

be stated as follows;

Law

I.

The

planets

move

in ellipses

having a

common

focus

situated at the sun.


60

Kepler's third law, called the harmonic law, expresses the Proportionality of period squared, 7", and the cube of the scmiBoajor axis a of the ellipse.

62

Looking Out: Rockets, Satellites, Space Travel

Motion

of

Bodies

in

Space

63

Example. Calculate the height of a satellite in a 24-hr orbit about the if it has been observed that a satellite at a mean distance of 4,100 mi from the center of the earth has a period of 5,000 sec. From Kepler's third law
earth

The
circles,

orbits of all the planets (except Pluto) are very nearly with the sun at the common center. Kepler's third law

can be derived by equating the centripetal force to the gravitational force (Sec. u.3) to obtain

3Y
7V
we
a.*

T*

i* =

wish to find o 2 when T~

day

8.6

10

4 !

con8tant

see

a-i

= (I/V

[tf)l 4,100

mi =

27,000 mi

Kepler's second law, the law of equal areas, follows whenever the interaction between two particles is in the direction of the line joining them. The force need not follow an inverse square.

Kepler's lawn apply to the ideal ease of only two bodies moving under their mutual gravitational attraction. But in space travel, effects of other bodies have to he considered. consider the feasibility of certain proposals or devices, one starts by examining qualitative orbits. Such trajectories are predicted with the aid of simplifying assumptions: that the moon

To

around the earth, that the earth may be considered symmetrical, that any disturbing masses are in the orbit plane of the space vehicle, etc. The precision trajectories needed for actual space travel do not allow these approximations. Hence

moves

in

circle

Fig. 6.3

Derivation of Kepler's second law.

the calculations become enormously more complicated.*

Let Pi, P->, and P% be points along a planet's orbit marking the position of the planet at time intervals of 1 sec. Then the distance

6.2

NEWTON'S DERIVATION OF KEPLER'S LAWS

PiPz

As a test of his theory of universal gravitation, Newton desired to show that Kepler's laws could be derived from the law of gravitation and he desired to investigate the more general problem:

is numerically equal to the planet's velocity 1% and /VJ 3 is numerically the velocity r., in the next second. When the only

force acting

on the planet

is

in the direction of the sun, this force

has a

component zero perpendicular

to line / J 2 ,S'.

Hence the com-,.S'

What

necessary according to that law? In its basic statement, the law of universal gravitation applies only to particles ("point" masses). Newton needed first to show that the

kind of motion

is

ponent of the planet's velocity perpendicular to / J unchanged, according to Newton's first law of motion:

must be

r tL

u 2l .

attraction for an exterior particle exerted


(either

by a

spherical

homogeneous or somewhat like the earth, concentric homogeneous shells) was directly proportional to the total mass of the sphere and inversely proportional to the square of the distance of the particle from the sphere's center. Newton's
difficulty in establishing this principle to his satisfaction

mass made up of

second by the line joining the planet and the sun is &P1P1. The area swept in the next second is SP t P These triangles have the same base PS and equal alti3 tudes v hence they have equal areas.
first
. ;

The area swept during the

may have

been the cause of his delaying some twenty years in publishing


his conclusions.
* Precision

The derivation of Kepler's first law is more lengthy, and it involves differential equations.* The question is: Given an inverse-square law of attraction, what shape must a planet's (or comet's) orbit have? The answer turns out to be: The orbit will
be one of the conic sections with the attracting body (sun) one focus,
* A derivation without calculus is presented mental Physics," pp. 70-73, .John Wiley & Sons,
in

in

namies,"

I).

Van Xostrand Company,

rocket orbits are discussed in S. Herrick, "AstrodyInc., Princeton, N'..l., 1959.

Inc.,

Jay Orear, "FundaNew York, 19GI.

64

Looking Out: Rockets. Satellites, Space Travel

Motion of Bodies

in

Space

65

Conic sections are curves? obtained by taking plane slicas of a cone (Fig. G.4). The cone sliced parallel to its base (I) gives a circle. If the cut is slanted, the section is an ellipse (2). With greater slant, the section is a parabola (3). With still greater
solid circular
slant, the section is

The

significance of the various conic-section trajectories

may

be clarified by an example based on Newton's own suggestion for an earth satellite. About 1660 he predicted in a drawing (Fig, (5.o) that if a cannon ball could be fired with a muzzle velocity of
"i

a hyperbola

(4).

mi/sec,

it

would

circle the earth

as shown.

The Sputnik and

Explorer satellites did achieve this velocity, For a low-flying


earth satellite in a nearly circular orbit, equating the centripetal
acceleration r/r to g gives
v

\/gr

9.8

r
(>.' >

10 6 m/sec

8 km/sec or 5 mi /sec

Now alter Newton's drawing (Fig. (U>) by considering the mass of the earth to be concentrated at point E (Fig. (i.(i). Con-

Hyperbola
1. Circle

2. Ellipse 3. Parabola (parallel to lineaO)

4. Hyperbola
Fig. 6.4

Basic orbits related to conic sections.

Fig. 6,6

Conic orbits cotangent at

satellite

launching point p.

is to be launched at point p with a velocity Perpendicular to the line K v J-et the, circle represent the orbit of the satellite described in the preceding paragraph. The effect of the
.

^ider that a satellite

Newton's proposal for an earth satellite, [(a) From Sir Isaac Newton, ," edited by F. Co/oW, University of California Press, Berkeley, Calif., 1934. (b) From E. M. Rogers, "Physics for the inquiring Mind," Princeton University Press, Princeton, N./., 1960.1
Fig. 6.5

earth's attraction

is

to cause the satellite to fall r

"Mafnemoficai Principles

Igl

4.9

toward the earth


tangent.

in

the

same second

it

travels 8

km

along the

The two displacements

bring the satellite back to the

66

Looking Out: Rockets, Satellites, Space Travel

Motion of Bodies

in

Space

67

same distance
falls

it had before. So, during each second, the satellite toward the earth but never gets any closer. Now suppose that the satellite's velocity is made less than S km/sec. The earth's effect of 4.0 m each second is unchanged. So the satellite will fall closer to the earth along the smaller

ellipse of Pig. 6.0. Since the earth

is

not a "point" as implied in the earth after traveling a

Fig. 0.0, the satellite actually will not he able to complete the
elliptical orbit

but rather
is
si

will strike

trajectory which

portion of an ellipse (Fig. 6.5). (The smaller

by equating the centripetal force required to keep a planet in its (circular) orbit to the gravitational force due to the sun's attraction. 5. What is the mass of a planet, .1/,., if it is observed to have a moon revolving about it at a distance /?, center to center, in period T? 6. If the earth, considered to be spherical, were to shrink to 0.9 of its present radius, what changes would occur (a) in the length of the solar day, (/>) in the value of g at the North Pole, (<) in the value of g at the equator? 7. The earth satellite Kxplorer III had a highly eccentric orbit witli perigee at a height of 109 mi. At this point the velocity was 27,600 ft/sec
in

ellipse of Fig. 0.0 could represent

the path of a comet or planet

Show

about the sun at

A'.)

If the satellite at

than 8 km/sec, the 4.9

p were given a velocity somewhat greater m by which it would fall to the earth each

a direction perpendicular to the radius to the center of the earth. that this speed is too great for a circular orbit at the radius (R, + h) of 4,109 mi. Hence the satellite described an elliptical orbit. Its apogee was at the height 1,630 mi. Show that the speed at apogee was too small for a circular orbit at radius 5,630 mi.

second would be insufficient to hold the distance constant. The satellite would climb away from the earth on the larger of the two
ellipses

(Fig.

0.0).

With decreasing speed the

satellite

would
It is

arrive at a point a opposite the start. There the centrifugal

overcome gravitational attraction, though the latter would also have decreased. Accordingly, the satellite would begin to fall back toward the earth, regaining speed along the elliptic path until it reached point j> with the same
reaction would be insufficient to
velocity as at the start.
at p still more would semi along the parabola shown in Fig. 6.6. Still greater velocities would carry the satellite away from the earth along a hyperbolic

the supreme art of the teacher to

awaken

joy in creative expression and

knowledge.
A. Einstein, motto for the

Astronomy Building, Pasadena Junior College

Increasing the satellite's velocity

Putting on the spectacles of science in expectation of finding the answer


to

it off

everything looked at signifies inner blindness.

J,

Frank Dobie

path. In either case the attraction of the earth would be insufficient to decrease the radial velocity of the satellite

enough to

Science
facts
is

is

built

up with facts, as a house

is

with stones. But a collection of


is

cause

it

to return.

no more a science than a heap of stones

a house.

H. Poincare

QUESTIONS AND PROBLEMS


and Jupiter
(1

Science

is

organized knowledge.

Herbert Spencer

periods of revolution of the planets Mercury, Venus, Mars, are, respectively. 0.241, 0.017, 1.88, and 11.9 years. Find Iheir mean distances from the sins, expressed in astronomical units
1.

The

Science

is

nothing but perception.

Plato

a.u.
2.

distance from sun 1o earth).

km. A satellite completes an orbit, about Jupiter every J 6.7 days. The radius of the orbil of the satellite is 27 times the radius of the planet. Compute the mass of Jupiter. 3. What docs Kepler's second law say about the duration of winter in the Southern Hemisphere (which occurs in .inly when the earth is farthest from the sun) compared with winter in the Northern Hemisphere? 4. Show the correctness of Kepler's third law of planetary motion
.Jupiter lias a radius of 74,000

Travel

to

Moon and

Planets

69

and other bodies in the solar system is almost a perfect vacuum. This is an ideal environment for a space vehicle to move at speeds
which make it practical to travel interplanetary distances. Since he earth is one of the smaller planets, it requires a comparatively low escape velocity. Its relatively thin atmosphere offers less resistance to rapidly ascending and descending objects. The fa el
I

Travel to Moon and Planets

that the planets


sense

lie

in nearly

the same plane and


in

move

in

the

same

makes

it

possible for an interplanetary traveler to apply the

orbital speed of

one planet

launching himself to another. The

fact that the elliptical orbits of the planets are nearly circular

means that the energy requirements to transfer a spaceship from one orbit to another do not vary greatly for different points of

We

first

throw a

little

something into
more, then a
then our-

the skies, then a shipload


selves.

little

same direction

departure along the orbit. Finally, most planets rotate in the in which they revolve about the sun. So a space-

of
.

instruments

ship launched at the surface of one of these planets can get an

Fritz

Zwicky

added push by taking


7.2

oil"

in

the direction of rotation.

LAUNCHING
it is

Before

launched, the space vehicle


is

is

at the earth's distance

from the sun, and it sun (about 100,000


solar system, consisting of 9 planets moving in elliptical paths around the sun, 31 known moons, and many other bodies all in motion, does not invite simple straight-line travel from the

moving with the


If

earth's speed

around the

The

launched at greater than the earth's escape velocity, the vehicle will take up an independent orbit around the sun, at a speed somewhat different from that of
ft/sec).

the earth.

To conserve both power and time, departure dates and trajectories must be chosen which utilize favorable positions and relative velocities. Conditions favorable for return passage may not occur until some time later.
earth to a selected destination.

Owing to the ever-changing distribution of bodies in the solar system, no two courses between even the same two bodies are
likely to

be the same.

The

calculations of desired trajectories


in flight are

and corrections of the course while for computing machines.

complex tasks

7.1

INVITATION TO INTERPLANETARY FLIGHT


difficulties of travel in

Despite obvious

the solar system, there are


Fig. 7.1

some

interesting favorable factors.

The space between the earth


Launching! to inner and to outer planets.

68

70

Looking Out: Rockets, Satellites, Space Travel

Travel to

Moon and

Planets

71

If it is launched in the same direction as the earth's orbital motion, the vehicle will have a speed greater than that of the earth (l'"ig. 7,1.1), and could reach the outer planets, Mai's,

S
>
'G

i.o
Scientific sotellire (100 mi)
1

Jupiter, etc.,

if

properly directed.

The minimum
transit times to

starting speeds
_o

required to reach these planets arc given in Table 7.1.


Table
7.1

>

Minimum launching speeds, with


reach the planets

o
1=

a,

I
S.

0.1

Plonet

Minimum launching
speed,

|
Transit time
.8

Impact on moon (+100


o.oi

ftsee
E

Around moon
return to

Mercury Venus

Mars
Jupiter

Saturn

Uranus

Neptune
Pluto

44,000 38,000 38,000 46,000 49,000 51,000 52,000 53,000


R.

10

150 260 2.7 6 16


31

days days days


years

o>

braking eclipse
0.001 0.001
0.01
0.1 error, per cent

Speed
Fig.

years

yea rs
years years

7.2

Maximum

permissible errors for alignment of velocity vector and for

speed at power

cutoff.

(Genera'

Electric,

"Space

Facts.")

46

From
If

W.

Buchheim, "Space Handbook," 1958.

the vehicle
it

is

velocity,

will

move

in

launched "backward," against the earth's an orbit like H in Fig. 7.1, so it could reach
it

VettUS or Mercury. However,


to propel a vehicle in to

requires almost, as
to propel
it

much energy

Mercury as

out to Jupiter.

7.3

ROCKET GUIDANCE

In the flight of an unmanned probe, satellite, or missile, one or more boosters provide the initial impulse, but after burnout the

remainder of the flight is unpowered. The vehicle coasts in the complex gravitational field of interplanetary space. The accuracy of guidance is generally determined by the position and velocity at the instant free flight begins. Figure 7.2 gives an idea of the maximum allowable errors of angular alignment, and vehicle velocity at power cutoff for several kinds of moon-directed
mis-ions. Inertiul Isiyro) or radio-guidance techniques are adequate for such relatively simple missions. Interplanetary expeditious present complex problems of guidance. First, a launching site might be chosen at not more than
2:}

Initio!

ascent

-^ ^~v'/- Earth

^^
7.3

'

Fig.

Possible flight paths to Mars,

north or south latitude. This

is

the angle of inclination of the

ecliptic

plane to the earth's equator.

The

vehicle would
in

be

launched into a satellite orbit around the earth,

the ecliptic

|>'ig. 7.H. With the vehicle in orbit, an ion-propulsion system might be started to cause the vehicle to spiral out into a legion where the sun's gravitational field is stronger than the

plane,

72

Looking Out: Rackets, Satellites, Space Travel

Travel to

Moon and

Planets

73

earth's.

The

fer orbit

vehicle would then be guided into an elliptical transaround the sun, planned to intercept the orbit of the,
planet.

vehicle are used to obtain a very gradual penetration of the

destination

Where these

orbits intersect,

the vehicle

would be directed into an orbit around the destination planet. Radio or inertial guidance techniques could serve in the early stages of such an interplanetary flight, but would probably be inadequate for interplanetary missions of a year or more in duration, A three-dimensional form of present-day two-dimensional celestial navigation may be necessary. A useful instrument for establishing a reference direction is the horizon seeker which
senses the infrared radiation of the earth or

atmosphere. The path angle is generally small, a few tenths of a degree, and is adjusted to the forces acting on the vehicle. Deceleration increases gradually and can be limited to a relatively
small value.

The more gradual the descent, the longer is the time required and the longer is the range. Starting at a given altitude and velocity, a direct descent may traverse a distance of a few hundred miles and require about A min. An orbit, decay might cover a range of several thousand miles and require 5 to 10 min. A
Direct from space
Ballistic rocket

some other warm

body. Optical trackers and magnetometers

may

also

provide

data to establish the vehicle's position. To orient and stabilize a space vehicle, torque is produced, either by the ejection of mass (rocket exhaust) or by the rotation of a mass within the vehicle. The internal type of torque control serves to rotate the vehicle about its center of mass it does not
;

influence the flight path.

7.4

RETURN THROUGH THE ATMOSPHERE

To

return safely to earth, a space vehicle must overcome the problems of penetrating the earth's atmosphere. There are three general types of reentry path, each with its characteristic deceleration pattern: direct descent, orbit decay,

Fig.
tric,

7.4

Different types of atmospheric entry. (Generaf Elec-

and
is

lifting descent.

"Space Fads")

These are
phere, the

illustrated in Kig. 7.4. In direct descent into the

maximum

deceleration experienced

atmosindependent of

lifting

descent from the

same point might range over o,000


hi*.

to

the drag characteristics of the vehicle, but depends on the path


angle, initial velocity,

10,000 mi and require 2

The

altitude at which

maximum

and characteristics of the atmosphere. deceleration occurs does depend

When a vehicle penetrates the atmosphere, the reduction of the vehicle's energy is accompanied by an increase in the thermal
energy of the surrounding
air,

on the drag characteristics of the vehicle. For entry of the atmosphere in orbit decay, the vehicle executes many revolutions about the earth in a very gradual spiral that becomes more and more nearly circular. The rate of energy loss through aerodynamic drag is sufficiently small so that the vehicle's kinetic and potential energies adjust to a momentary "equilibrium" orbit, with potential energy decreasing and kinetic energy increasing. Thus the velocity of the vehicle actually increases in the start of orbit decay. The final phase of descent is similar to that of direct descent at a shallow angle. In a lifting descent, the aerodynamic characteristics of the

some

of

which

is

communicated to

the surface of the vehicle. At very high altitude, about one-half the energy loss appears as heat in the body. At lower altitudes, the heating is produced not directly at the vehicle's surface but
in

the air between the shock

wave and the

vehicle.

ferred
tion,

from the hot gases of

this region to the vehicle

Heat is transby conduc-

convection,

and

radiation.

7 -5

THE NEXT DECADE OF SPACE RESEARCH

Historically, man's attempts to predict the future of science and technology have shown a tendency to be overly optimistic about

74

Looking Out: Rockets,


will

Satellites,

Space Travel

what

bo accomplished in the immediate future and too con-

servative about the long-range future.


of outer space

been predicted that man's curiosity about the unknowns can be only partly satisfied by the placing of in meters outer space; eventually he will want to go there to see for himself. But it is probable that the extent and pace of space
It has

PART

research in the foreseeable future will be determined by


are regarded as our military requirements.

what
in

The

military advantage to be gained from putting

man

space is at least debatable, From the standpoint of psychological warfare, there may be better ways of demonstrating our scientific prowess. For man's future happiness, more important purescience experiments might be performed in other fields, such, as
medicine. Yet many dedicated scientists feel that man-in-space experiments are important to our chances of survival This viewpoint is stated by Dr. Simon Ramo in the following
terms. Suppose
for

Looking In: Atomic and Nuclear Physics

two

rival nations base their security

wisdom

in the use of limited technical


first

Suppose, however, that the

on a race and physical resources. nation makes one decision in

man will never be needed in space. These two nations start to develop their weapons systems of the future. One group has maximum flexibility; the other has some prohibitions. "To achieve this maximum of flexibility, it is very clear to me that the United States must prepare for putting man in space," says Dr. Ramo. On the assumption, then, that we shall have militarysponsored programs in space technology, one can make some
contrast to that of the second: It decides that
predictions for the near future.

Many

projects involving

munications, weather prediction,

manned

satellite stations,

comand

exploration within the solar system will probably be

fulfilled.

Exploration beyond the solar system


chiefly

now seems

unattainable

from considerations of time and power. Man's life is short the time required to reach the nearest star, even in a vehicle traveling with a speed approaching that of light. The other problem, "Where is the energy In he obtained for long voyages or to lift large masses into space?" may find an answer in the achievement of a nuclear-fusion reactor. It is the thermonuclear bomb which threatens to make the earth a very unpleasant place. Ironically, the energy of a controlled thermonuclear reaction may provide us with the power resources for a migration

when compared with

into space.

8
The Atomic Idea

Science does not


nation,

R.

know its debt W. Emerson

to imagi-

Although Democritus had introduced the word "atom," it was the English school teacher John Dal ton (1803) who made fertile the assumption that matter is not divisible indefinitely but rather is composed of ultimate particles called atoms. Physics dealing with phenomena on a scale large enough to be visible to the unaided eye was well understood by the year 1890. Then a remarkable mutation occurred in science, caused by the series of discoveries made in the decade 1895-1905:
1895

18%
1897

Discovery of x rays by Roentgen Discovery of radioactivity by lleequerel


Identification of the electron

by Thomson

H'OO
Pi05

Statement of the basic postulate of quantum theory by Planck Formulation of the theory of relativity by Einstein

It became clear that the structure of matter was complicated than had previously been thought.

much more

scopic (atomic
77

The term "modern physics" is often used to designate microand nuclear) physics, investigated from the view-

78

Looking In: Atomic and Nuclear Physics


tions of temperature

The Atomic

Idea

79 of

quantum theory and relativity, as distinct from the macroscopic or "classical" physics which was known before 1890.
point of
8.1

and pressure contain the same number

molecules. This hypothesis guided Bcrzelius and others in determining the ratio of combining weights (e.g., is water HO or H s O?).

DEVELOPMENT OF THE ATOMIC CONCEPT OF MATTER

The

existence of atoms has been inferred from many experiments, the earliest of which were studies of simple chemical professes.

A molecule is the smallest particle of any substance (element compound) as it normally exists. or atom is the smallest portion of an element found in a moleAn compounds. An atom is the smallest portion of any of its cule of
an element that can enter into chemical combination. By measuring combining weights, it is possible to determine the relative masses of atoms of various elements. We may arrange

By

1800,

of chemical

some 30 elements had been identified and the formation compounds had been studied. Lavoisier showed that
in

mass appeared to be conserved


Proust, Dalton,
Berzelius,

chemical reactions.

and Richter discovered "laws"

them

which
1.

may

be summarized in the statements:

particular compound always contains the same elements chemically united in the same proportions by weight. (Law of
definite proportions.)

order of increasing mass, assigning a number to each to indicate its relative mass. Since only the ratios of the numbers are important, we may assign one number arbitrarily to a particular
in

2.

When two

elements A and B combine as constituents of more than one compound, the weights of B which unite with a fixed weight of A (and vice versa) aj-e related to each other as the ratios of whole numbers, which are usually small. (Law of
multiple proportions.)

atom and adjust the others accordingly. Conventionally, the number Hi (exactly) was assigned to an oxygen atom. Then by Avogadro's hypothesis, for any gaseous substance
.Molecular mass of substance

density of substance

density of oxygen (Os)


Since
of the
19(51,

32.000

(8.1)

Dalton showed that these chemical laws could be explained most directly in terms of an atomic theory of matter. Its assumptions arer
1.

clature in Physics has defined the atomic

the Commission on Symbols, Unite and Nomenmass unit as one-twelfth


1

matter is made up of elementary particles (atoms) retain their identity in chemical reactions.
All

which

2.

The atoms of any pure substance (element) are alike (on the average, at least) in mass and other physical properties,
Atoms combine, pounds.
in

:>.

simple numerical proportions, to form com-

first

Dalton's clear formulation of the atomic concept of matter is the important landmark in the development of modern atomic

physics.

8.2

AVOGADRO'S NUMBER

mass of an atom of the carbon- "2 nuclide. The number representing the mass of any atom on this scale is called its atomic mass. (The term "atomic weight" is also used.) On this scale, which differs only very slightly from the former one, the mass of the hydrogen atom is nearly 1 amu and the heaviest known atom has a mass of about 250 amu. We shall use the symbol .1* to represent, as needed, either atomic mass or molecular mass. A quantity of any substance whose mass, in grams, is numerically equal to its molecular mass is called a mole. In the mks system we define the "kilogram mole" as: kmole of a substance is that quantity whose mass in kilograms is numerically equal to its atomic (or molecular) mass. The mass of 1 kmole of any subI

stance

is

thus

.1 *

kg.

Joseph Gay-Lussac (1808) showed that, at a constant temperature and pressure, gases combine in simple ratios by volume. Amadeo Avogadro was led (181 1) to make the important assumption that equal volumes of different gases under the same coudi-

The volume occupied by a mole


molecular volume. It
is

of

22.4 liters for a gas at

any gas is called a gram 0C and 76 cm of


is

mercury pressure.

The numerical value

of

Avogadro's number

not easy to

80

Looking In: Atomic and Nuclear Physics

The Atomic Idea

81

measure, and it was not known for some time after Avogadro's hypothesis was accepted. This constant can be determined independently from experiments in electrolysis, Brownian motion,
radioactivity, and x-ray diffraction in crystals. accepted value of Avogadro's number is

reduced sufficiently. For then the molecules occupy an insignificant fraction of the volume of the container and the widely separated molecules exert no attracting forces on each other.
It is

The

currently

from these considerations that Eq.

(8.3)

has importance as

the "ideal-gas" equation of state.


(8.2)
8.4

NA

(6.02486 -f-O.OOOHi)

10 2S

molcculcs/kmolc

Example. Compote the number of atoms in a 1.5-mg sample of lead, atomic mass 207. The mass of 207 atomic muss units (amu) may be thought of as 207 kg/mote. Then

KINETIC

THEORY OF GASES

Kinetic theory treats atomic and molecular processes and reaction

N=

I0~ 6

ksr

207ki7kmole

6 25

^" ^m./kmole
=
4.36

by applying elementary methods of mechanics and statisshall examine what the kinetic theory has to say about the observed properties of a gas: its pressure, volume, and
rates
tics.

We

I0 1S

atoms

temperature.
y\

8.3

THE IDEAL GAS LAW


state of matter
is

/\
i

The gaseous
forces

simplest to analyze, chiefly because the molecules of a gas arc far apart and do not exert appreciable

Fig. 8.1

Model

for kinetic theory of

West

i
i

on each other. The behavior of a gas is expressed by an equation of state, which relates pressure, temperature, and volume when the gas is in equilibrium. Numerous empirical equations have been suggested to describe the behavior of gases.

gas pressure.

We make

East

The

simplest

is

A
We
shall consider a gas confined at a fixed

/
temperature in a
the
fol-

pV - nRT
where p

(8.3)

= pressure of gas V = volume T = absolute temperature n = number of moles (or kilomoles)

cubical container with each side of length L.

lowing assumptions:
of gas present
is
I.

units the proportionality constant stant per kilomole, and from experiment,

In

mks

R
it

called the gas con-

has the value


(8.4)
(8.3),

R =

8.317

10 s joules/(kmole){K)

When other units are used for the variables in Eq. constant will be expressed differently; for example,

the gas

The molecules have negligible volume; they are "points." The molecules move in random directions, but every molecule has the same speed v (obviously an oversimplification, which we shall reconsider soon). The molecules exert forces only in collisions. The collisions with the walls are clastic. The number of molecules is very large, justifying use of
statistics.

R =
Xo

1.987 cat/ (mole) (K)

0.082();>

liter-atm/(mole)(K)

8.317

10' ergs/ (mole) (K)

The

pressure of the gas

may

be calculated as the force per

unit area at a wall. Let .V he the total

number
will

of molecules in a

actual gas obeys Eq. (8.3) precisely at any nonzero pressure. Hut this equation holds for all gases when the pressure is

cubical container (Tig. 8.1). Then the east wall and the west wall.

N/8

be bouncing lietween
in

Each molecule

this

group

82

Looking In: Atomic and Nuclear Physics

The Atomic Idea

83 of

v/2L times per second. In each clastic impact the velocity of the molecule changes sign and the change in its momentum is mv ( me) = 2mv, where m is the mass of the
strikes the east wall

number of molecules moving at random, the average values iv, tv, and rr are all equal. Equation (8.6) then becomes

molecule.
is

From Newton's second

law, the force on the cast wall

pV =
ami the
velocity,

llVmi*
v of

the total

momentum change

per second at that wall

i>

,.

Nmu

locity," the

our earlier discussion is replaced by the "rms vesquare root of the mean value of the square of the

VP.

The
P

pressure

is

given by
8,5

DISTRIBUTION OF MOLECULAR SPEEDS


and
pressure,

J_ l-

Nmjfi

_ 1 Nmv* "a v

(8.5)

In a gas at a given temperature

we expect that some

V = I* is the volume of the container. To compare this prediction with the ideal-gas may rewrite Eq. (8.5) as
where

equation

we

have speeds in excess of the root-mean-square value, and others will have smaller speeds. Clerk Maxwell applied the laws of probability to find the distribution of speeds in a large number of molecules in a kinetic- theory gas. He obtained the
molecules
will

result

pV = i(AW) = \8%m* - %NBt


where

(8.6)

Ek

is

the translational kinetic energy of one molecule.

X
where

\Ztt

Combining

Imjs. (8.3)

and

(8.0),

we have

(&f
number
v

-mT =/s*r

f}

(8.10)

nRT =

N =

total

of molecules

fJVA't

(87)

dv/N -

fraction of all molecules

whose speeds are between

suggesting that the absolute temperature of a gas is proportional to the kinetic energy of its molecules. Further, since N/n is the

and
fe

dv

number of molecules per kilomole, #,1, we have for the kinetic energy
h\

Avogadro's number of a molecule


that
is,

T = absolute temperature = Boltzmann constant m = mass of a molecule


in

R = T =
3
k,

'I:T

(8.8)

The constant
per molecule

called Boltzmann's constant, is the gas constant

For a gas at any given temperature, the number of molecules a speed interval A increases up to a maximum at the most probable speed v p of Fig. 8.2a and then decreases toward zero at high speeds. The distribution is not symmetrical about , for the lowest speed is zero, but the theory predicts no upper
limit for the speed a molecule can attain.

=
A',

8-317
1.38

6.025

X 10 oules/(kmole )(K') X M molecules/ kmole X 10" M joule/ (molecule) (IC)


a
j
1

average value v of all speeds root-mean-square value v rim is

is

somewhat
larger.
is

For this reason, the larger than . The

still

(8.9)

kinetic theory
all

be made in our simples) statement of the by removing the second assumption above, that molecules have the same speed. Instead we can say that for particular molecule v-

An improvement can

increased, the most probable speed of the molecules increases in accord with the meaning of temperature (Eq. 8.7). The range of speeds is greater (Fig. 8.2b);

As the temperature

of a gas

any

vt *

+ vf +

v?. If

we have a

large

* L. U. Loeb, "Kinetic Theory of Gases," McGraw-Hill Book Company, Inc., New York, 1934; Leigh Page, "Introduction to Theoretical Physics," chap. 9, D. Van Nostrand Co., Inc., Princeton, K.J., 1935.

84

Looking In: Atomic and Nuclear Physics


rules in going a distance L. Its

The Atomic

Idea

85

No.

*-/Fs

/=m

~kT
/itr

mean

free

path X

is

the average

distance per collision:

=
r(2R)*Ln

4*Rhi

(8.11)

This equation is based on the picture of the single moving molecule hitting other molecules which are stationary. Actually the molecule hits moving targets. The collision frequency is
(a)

200

400

600

800

m/sec

m
Fig. 8.2
(b)

2R

Fig. 8.3

Path of a molecule.

(o) Maxwell distribution of molecular speeds at 0C. Maxwell speed distributions at three different temper-

increased as a result.
nieaii free

More complete

analysis shows that the

atures, T 3

>

T-i

>

T|.

path

is

reduced to

X
there
is

=
4tt

(8.12)

an increase

iti

(lie

number

of molecules

which have speeds

y/2

tr-n

greater than a given speed.


Example. I" helium gas at 0C and atm pressure, the mean free path one molecule (or atom, He) is 1.86 X 10 -7 m. Estimate the radius of 8 helium atom. The number of molecules per cubic meter under standard condiI

of

8.6

MEAN FREE PATH


mean
free patli
is

tions

m
.V,,

TIxe

defined as the average distance a molecule

travels between collisions with other molecules.

Assume that each


lilt-

n =
22.4

molecule

is

a sphere of radius R. Consider the motion of a par-

(m 3 bnole)
.

2.(59

10" molceulcs/m'

ticular molecule

among all

the other molecules of a gas. It will


lies

any molecule whose center

R =
{Aw

=
j

1.05

within a cylinder of radius 2J9

X I0-"m

y/2 Xh)

around its path (Fig. &.',t). In going a distance L, the molecule sweeps out a volume ir(2R)'1 L. If there are >i molecules per unit volume in the gas, the moving molecule will bitx(2R) iLn molc-

which agrees in order of magnitude with other methods of measurement. Note that the mean free path X is about 1.86 X 10 7 m/2

86
(1.05

Looking

In:

Atomic and Nuclear Physics


moleeuliir

The Atomic Idea

87

X
=

10

speed of the
u

u m) = 900 He atoms is =

diameters.

From Bq.

(S.8)

the

= 2

1,310 m/sec

So the frequency
v

of collision

is

In Lammert's method, two disks each with ")0 notches were mounted fi cm apart on a rotating axis (Fig. 8.46), in an arrangement similar to that used by I'izeau to measure the speed of light. For a particular constant speed of rotation of the disks, only those Hg atoms of a certain speed will be able to pass through

1,310 m/sec
1.86

10-'

m/(2

1.05

10

10

m)

lO'sec

-'

both notched wheels and reach the collector plate P. !3y varying the speed of rotation and by determining the number of atoms
received at

as a function of their speed, one obtains results in

or 7 billion collisions per Becond.

u.o
8.7

MEASUREMENT OF MOLECULAR SPEEDS


verification of the. distribution of molecular
l>y

N(v)
0,?0
'

-\ -

-1

An experimental

speeds predicted by kinetic theory was reported

Stern

in
0.15

1
(a)

m
(a)

0.10

^"1
0.05

G&rtn
(4)

^~=="
Fig. 8.5

90

140

190 240 290 Speed, m/sec

340

390

Speed

distribution of mercury

vapor molecules at 100C.


(1929).]

(6.

tammert,

Zeitschrift

her

Physik, 56(3-4):

244-253

Fig.

8.4

Apparatus for measuring molecular speeds,


(b)

Stem's rotating drum,

Lammert's slotted disks.

i926.

Atoms
(Fiji.

(Ilg)

through a
its wiill

slit <S

from an oven at known temperature pass and enter a cylinder C through a narrow slit, in

good agreement with Maxwell's predicted distribution (Fig. S..V). (The slight discrepancies with the predicted values, shown dotted, were attributed to difficulties of alignment.)

8.4a).

With

the cylinder stationary, the molecular


slit.

8.8

SPECIFIC HEATS

beam
If

reaches

diametrically opposite the entrance

Hut

if

is rotated rapidly, the molecular beam is interrupted. a point on (he cylinder wall rotates clockwise from O to () in the time it takes an Tig atom to cross the diameter d, then the trace left on the wall by IIg atoms will be displaced counter-

the cylinder

specific heat

Consider a gas confined at constant volume which is heated. The C? of the gas is defined as the heat required to raise the temperature of a unit quantity of the gas one degree. This heat is stored in the form of increased kinetic energy of the gas
molecules.
1

clockwise a distance 00% (= 0\0) from the reference point. speed of the atoms can be calculated from

The

From Bq,

(8.8) the increase in the internal


in

energy of

mole divided by the increase

temperature

is

given by

Speed of atoms Speed of drum surface

diameter d
displacement

OaO

(8.13)

88

Looking In: Atomic and Nuclear Physics

The Atomic
experimentally
(1) that, (2)

Idea

89

Thus our
that
all

basic kinetic theory makes the challenging prediction gases have the same value of specific heat

contrary to kinetic theory,

varies with

C\

[1.987 calV(moIe)(C)|

2.98 cal/(mole)(C)

The value

monatomic gases, but not of two or more atoms.


Toble
8.1

predicted checks well with experimental data for for gases whose molecules are made up

we need to devise empirical models that differ from gas to gas. We have come to the limit of validity of classical mechanics when we seek to
that for polyatomic molecules
describe the behavior of very small particles of matter (molecules

temperature, and

and atoms). Quantum theory is the extension of classical theory which we need for this {Chaps, I o and Hi). We shall reach another
Degrees of freedom

Specific heats (at 15C)

Type of gas

Gas

C,.

(experimental),

cal/{moleHC)

(a)

3:

trans!.

Monatomic
Diatomic

He

A
Hi

o,
N,
Polyatomic

CO C0 2
NH
C^Hg

2.98 3.00 4.80 4.96 4.94 4.95 6.74 6.78 9.50

3 tronsl,

(b)

2 rota

Degrees of freedom: independent modes of energy absorption.


Fig.

8.6

3 trans)
(c)

OmKD

2 rota
1

vibra.

To explain may result in


frnvf.

the data of Table 8.1,

we may ask whether heating


in

energy being stored

tional kinetic energy of molecules, expressible in

forms other than translaterms such as

(d)

a dumbbell-model diatomic molecule (Fig. 8.6b), there may be kinetic energy of rotation, expressible in terms such as ^/ur. If the two atoms can vibrate and have a force
In

constant

k,

there will be vibrational energy expressible as


of absorbing energy
is

\l.\r-.

Each independent mode


freedom,/.

called a degree of

limitation in

well, says that for

theorem of cquipartition of energy, stated by Maxa large number of particles which obey Newis

Newtonian mechanics when we deal with particles which are moving very fast ( * c). Relativity (Chap. 1-1) modifies Newtonian mechanics in this case.

tonian mechanics, the available energy


the degrees of freedom,
.]/.V for

equally divided

among
PROBLEMS
Copper which has a specific gravity S.9 has an atomic mass amu. What is the average volume per atom of copper? Ans. 1.2 X 10" cm 3 2. Compute the rms speed at 0C of the molecules of () CO,
1.

each.

Thus

modified, our kinetic theory eau be


for diatomic gases

made

to agree fairly

well with experimental data for

monatomic gases
(/

(/

8,

R3.8

35/2) and
*

5,

5B/2). One finds


(b)

The calorie originally defined as the amount of heat necessary to raise the temperature of one gram of water one centigrade degree In caloric = 4.1840 joules. The large calorie 1948 it was redefined as {kcal or Cal) used in nutritional measurements is 1,000 times as large.
was
1

H
3.

2,

(c)
If

Xo.

Aits.

H02

in

sec, 1X4

'.-ee.

!()2

'sec

the average distance between collisions of CO* molecules under I atm pressure and at QC is ft. 29 X 10 6 in, what, is the time between collisions? Ans. 1.6 X 10"" sec

90

Looking

In:

Atomic and Nuclear Physics

i. In a certain electron microscope, electrons travel 1.0 from electron gun to screen. To avoid scattering of electrons by residual molecules of nitrogen in lie vacuum chamber, below what pressure
I

would you recommend operating (lie microscope? The radius of a nitrogen atom is about 2 X 10 10 m. Ana. p < 8 X 10~ s atm 5. What pressure will 10 gin of helium exert if contained in a 50-cm* cylinder at 2lC-? Would a cylinder rated at 100 atm maximum safe pressure be safe to hold this helium? 4ns. p 1,000 atm

Wave Motion
Equipped with
calls the his five senses,

man

explores the universe around him and

adventure Science.

E. P.

Hubble To the mathematician the problems of wave motion offer a field for his

series of judgments, revised without ceasing, goes to

make up

the incon-

highest
physicist

power
they
all

of

analysis;

to

the

testable progress of science.

DuClaux

suggest
the

experiments
disposal

demanding
to

skill at his

the engineer and to those


to

who go

down The main


ages
is

the sea

in

ships these problife

difference of

modern

scientific research

from that of the middle

lems are matters of

and death,

lies in its collective

character, in the fact that every fruitful experiment

while to the poet and the artist they


are

published, every
is

new

discovery of relationship explained

Scientific

"the

sea dancing

to

its

research

a triumph over natural instinct, over that


to

mean

own

instinct

which

music "

Henry Crew

makes a man keep knowledge


tage

himself and use

it

slyly to his

own advan-

... To

science this

is

a crime.

H. G. Wells

In the study of

wave motion wc

arc concerned with the propaga-

tion of disturbances in physical systems.

A wave

is

a description

of a disturbance wliicli propagates

from one point in a medium to other points, without causing atiy permanent displacement in the medium as a whole. Tints sound is a type of wave motion; wind is not.

Wave motion
kinetic
91

occurs

in

medium

in

which energy can be


elastic material,
in

stored in both kinetic

energy results

and potential form. In an from inertia and is stored

the motion of

92

Looking In: Atomic and Nuclear Physics

Wave Motion

93

the molecules, whereas potential energy results from the displacement of molecules against an elastic restoring force. In an electromagnetic wave, we may regard kinetic energy as stored in the

Elastic waves, of which acoustic or sound waves are a particular kind, require a
inertia. Elasticity of the

medium having two properties, elasticity and medium is needed to provide a force to
particle fo
its

and potential energy in the electric field. In a traveling wave, one part of the medium disturbs an adjacent part so that kinetic energy at one point is transferred into potential energy at an adjacent one, and that potential energy becomes kinetic energy at still another point, and so on.
magnetic
field

restore a displaced

original

position.

Inertia

is

needed to enable the displaced particle to transfer momentum to a neighboring particle. In an elastic medium one may have,
in addition to a longitudinal or a transverse wave, a shear wave. This is a rotational wave which causes an element of the medium to change its shape without a change of volume. Light waves, radio waves, and other electromagnetic waves

9.1

TYPES OF WAVES
is

are not elastic

waves and therefore can


In a

travel in free space as


all

a disturbance that moves through a medium in such a manner that at any point the displacement is a function of time, while at any instant the displacement at a point is a function of the position of the point. The medium as a whole does not pro-

A wave

well as in transparent media.

vacuum

electromagnetic
:j

waves travel with constant speed, approximately

10* m/sec.

gress in the direction of motion of the wave.

Waves

are usually

described mathematically

terms of their amplitude (maximum displacement from equilibrium) and how the displacement varies with both space and time. This requires solution of the wave
in

-km
Tvv
In material

equation consistent with the boundary conditions for the particular case being studied. In cases most often considered, the wave

equation

is

a second-order,

linear, partial differential

equation.

The

general solutions of the

wave equation

for a one-dimensional

space coordinate x are of the form

(a)
Fig. 9.1

(6)

* = F(x The
tions,

vt)

+ G(x +
(!

Wave

fronts; (a)

plane;
is less,

vt)

(0.1)

(b) spherical.

Arrows represent rays.

functions

P and

and the speed v term represents a wave traveling in the positive x direction; the second term represents a wave traveling in the negative x direction. These are usually sine or cosine waves, for the one-dimensional case.

boundary condiby the properties of the medium. The first


are determined by the

media the speed

and

its

value depends on the

medium.

Waves may be classified further in terms of time: the periodicity or lack of periodicity of the disturbance. If a long coil
spring ("Slinky")
is

stretched out on a table, a single sidewise

movement
spring.

A wave moving on a string is an example of a one-dimensional wave. Hippies on water are two-dimensional waves. Acoustic and
light

wave along the Kaeh particle remains at rest until the puke reaches it, then moves for a short time, and returns to rest, However, a

at one end will send a pulse or single

waves are three-dimensional.

Waves may be classified in accordance with the motion of individual particles. Transverse waves and longitudinal waves
are the most
as a

continuing to-and-fro motion applied to the end of the spring will produce a train of waves. If the motion is periodic, we shall have

common
is

types, but there are others. For example,

wave moves on

the surface of water, the path followed by


either a circle or an ellipse.

an

individual particle

a periodic train of waves. An important special case of periodic wave is a simple harmonic wave in which each particle is given an acceleration proportional to its displacement and directed toward the equilibrium position.

94

Looking In: Atomic and Nuclear Physics

Wave Motion

95
(e.g.,

An
front

aid in visualizing waves


is

is

the idea of a

wave

front.

A wave

is

the

maximum

value attained by the variable of the wave


in space.
all

a surface drawn through points undergoing a similar disturbance at a given instant. The location of a disturbance (pulse) at successive e(|iial time intervals may be indicated by drawing successive wave fronts. A line perpendicular to a wave

the displacement) at a given point

The frequency

of a

wave remains constant under

circum-

stances except for a relative motion between the source of the wave and the observer (see Sec. 9.15, Doppler Effect). The speed
of propagation, however,
is

showing the direction of motion of the wave, is called a ray. fronts spreading from a point source in a homogeneous medium are spherical. Hut at large distance from the source a
front,

dependent on the properties of the

Wave

medium

(and, sometimes, also on the frequency).


will

Hence the
(9.2),

wavelength
as suggested

vary with speed in accordance with Eq.

section of the

wave

front

may

be treated as practically plane.

in Fig, 9.2.

9.2

FUNDAMENTAL RELATIONS
is

9.3

WAVE FORM
is

A wave
\ or
its

commonly

identified

in

terms of either

its

wavelength

frequency J". In any kind of wave motion these two quantiby the simple ses are related to the velocity of propagation
>

A wave form
a wave
is

a pictorial representation of a wave obtained by

plotting the displacement with respect to lime or distance.

When

equation

traveling along a string in the


I

the string at some instant


v
is

shape of can be expressed by an equation


direction, the
(9,3)
is some function wave is moving to the the wave at some later time
:/

/A

(9.2)

/(#)

when

The

period

the reciprocal of the frequency.


Medium
t

The amplitude A
which states that the transverse displacement
>u,)
f(x) of the distance x along the string. If the
right with a speed
I

"-Pi -A*

Medium 2
(f 2

v,

the equation of

is

f{x

Bt)

(9.4)

This gives the same wave shape about the point x as we observed about point x = at time t = 0.

vl

at time

The
(a)

relative positioti (displacement) of

two points

in

a wave

is

-A

called the phase.

Two

points which have displacements of the


t=*t

=
a

\e

d(
<vt

Fig, 9.3

traveling

wave.

Wavelength
(6)
Fig. 9.2

m-

Wavelength \j

When

wave passes from one medium


frequency
is

to another, in which the

wave

same magnitude and sign (a and h in Fig. 9.3) arc said to have the same phase, or to be "in phase." Points c andrf do not have the same phase, for although both have zero displacement, the displacement
is

speed

is

different, (a) the

constant,

(fa)

the wavelength changes.

decreasing at

c,

increasing at d.

To

follow a particu-

96
lar

Looking

In:

Atomic and Nuclear Physics


t

Wave Motion

97

phase in an ongoing wave, wc ask how x changes with when vt has some particular constant phase value P. Differentiation of x vt = P gives dx/dl = v. So v is the phase velocity of the wave. A wave form of considerable importance is one defined by a
x

There are many wave forms of interest in physics. To specify a particular wave Form, one chooses the appropriate function /(.!) It is possible to represent any periodic wave form mathematically as a

Fourier scries of sine and cosine terms at har1,

monics (multiples) of the frequency


Fig. 9.4.

T.

Examples are shown

in

sine function

f/o

sin -r-

(*"

i>0

ij

si"

(x

t)

(9.5)
9.4

WAVES

IN

A LIQUID
often see arc those which occur on Ihe

The maximum displacement // is called the amplitude of the wave. The wavelength A represents the distance between two the displacement points which have the same phase, ['or a given is the same at x, at x + X, at x + 2X, etc. The period T is the time required for the wave to travel a distance of one wavelength X, so X = vT, From the second form of LCq. (9,5) it is apparent
(, //

The waves which we most


Their propagation
is

surface of a body of liquid.

Waves

also occur within

made

use of in marine

a liquid. equipment such as

the fathometer and Sofar.

that y has the same value at the times a given position x.

t,

T,

2T,

etc.,

at

T
2

Fig. 9.5

Liquid in a channel, showing

two positions of o

liquid

element being

considered.

Sine

wave
sin

Square wave

y=y

jr
=
1,3,5-

litt

A quantitative description of a wave motion often can be obtained by applying fundamental laws of physics to a particular situation. As an example, consider a channel of unit width and vertical walls which contains a layer of liquid whose initial depth
is

outlined by the solid line in Fig. 9.5.

Examine how

this

can
line.
is

move

to successive positions, as suggested by the dotted

We
of
Saw-tooth wave
J'0

shall

apply two physical laws:


2

(1)

No

liquid disappears or
<.n

created during the process.

The

rate of increase

momentum

applied to that element.


tint

J'

r->

it

= 1,2,3-

Fig. 9.4

Some wove
t

forms, defined in terms of sine functions of the


multiples, n/T.

clement must be equal to the net external force The force applied to a fluid element at a cross section such as .1.1 equals the area times the average pressure. Since we have assumed unit width for the channel, area = X It. The element considered will be the liquid which initially lies under the solid line of Fig. 9.5, between .4.1 and ('('. After time I,
liquid
I

any

frequency,

T,

and

its

this

same

liquid will be

under the dotted

line

between

.I'.l'

and

98
C'C.

Looking In: Atomic and Nuclear Physics

Wave Motion
where
h,
is

99

The distance from

.1.1

to A' A'

is u^l,

the speed of

the liquid lying to

tfie left

of B.

To
(At

satisfy the first requirement

mentioned above
(9.6)

is

hi)x

kiUtt

where x

the distance the liquid originally at rest lias been accelJ.

erated during time interval

from a faucet into a basin. The flow can be adjusted so that in the basin there can be seen an inner zone consisting of a thin layer of water moving rapidly outward. Surrounding this is an outer zone which is a thicker, more slowly moving layer. The manner in which a continuing oscillatory wave is propagated may be examined from considerations similar to those just < ,' a suggested for a .-urge wave. In shallow water (say, h
,\
.

To

satisfy the second requirement

2(,
Fig.

(A, 2

A.')

= "*f -'

9.6

large-amplitude
(Fig. 9.5).

wove

(9.7)

steepens to form a bore

where ipgki is the average pressure (above atmospheric) in the liquid of depth Ai, \pgh-i is the average pressure at CC where the depth is As, and p is the mass per unit volume of liquid. The lefthand side of Eq. (9.7) is the net horizontal force on the element of liquid considered. The mass of liquid phx is accelerated from rest to speed a 5 in time t, so (phx/t)ui is the rate of change of

wave of small amplitude will be propagated without change of shape at a speed y/gh, which is consistent with Eq. (9.9), If, however, the wave height is an appreciable fraction of the liquid depth, the wave speed is significantly greater at positions
of greater depth.

momentum. The two requirements expressed by


give for the speed
,

The wave

front

becomes successively steeper

Eqs. (9.6) and (9.7)

now

(Fig.

9.(i),

and a bore

starts to form.

m,

of the particles of liquid

(Ai

deep-water waves, individual fluid particles move in approximately circular orbits (Fig. 9.7). At the surface, the radius
In
(9.8)
StiM-woter leve

A;) 2 (Ai

h*)g

2hih a

But the wave speed


advances
is

x/t at which the front of the deeper layer


*

given by
(At

"^

Shallow water

v=

+ A )flig
2

2A 3
v is greater

(9.9)
Bottom

The wave speed


particles.

than the speed u of the material

(b)
Fig. 9.7

In this simplified treatment,

we have

Orbital motion of fluid particles for surface waves

(a) in

deep water,

disregarded energy )o->i>.

and

(b) in

shallow water.

variation of speed with depth, and a detailed specification of the

shape of the wave

front.

Vet we have obtained a valid description

of the orbit of a particle


of almost zero particle of the

of the tidal bores which occur in certain rivers.

Such a surge

is equal to the amplitude of the wave. Hut the radius decreases exponentially with depth, and a region

wave

is sometimes employed as a means of dissipating flow energy at the bottom of a dam spillway. If the channel is so designed that = ~r then the velocity of the surge relative to
i/
t

motion

is

soon reached hence the behavior


;

wave

is

unaffected by the total depth of the liquid.

lu shallow

water there can

tie

im vortical motion of particles

This form of surge is known us a hydraulic jump. it can often lie viewed on a small scale by allowing water to flowearth
is

zero.

at the bottom.
vertical axis

The

orbits of the particles are ellipses in


(Fig. 9.76).

which the

becomes zero at the bottom

100

Looking in: Atomic and Nuclear Physics

Wave Motion

101

A wave

lias

equal amounts of potential energy, owing to

Since in a steady flow there can be no accumulation of the

above or below the still-water level, and kinetic energy, owing to the motion of the particles in their orbits. The speed at which energy is transmitted in the direction of wave travel is called the group velocity n. us distinct from the phase velocity v = x/l. In deep-water waves the group velocity is onehalf the phase velocity. In shallow-water waves u = e.
particle displacement

mass at the wave


Pi*'i

front,

= wis
the density of gas at the right of the

(9.10)

where

p is

wave

front

and

gas relative to the observer moving with the wave front. Also, an increase in gas momentum across the
h 2 is the velocity of this

wave front requires a drop


9.5

in

pressure from pi to p 2

SOUND WAVES
in

IN

A GAS
is

P2>1?

Pll

Pl

P'J

(9.11)

In sound waves usually encountered, the intensity

so small are a

that the changes

temperature and pressure

in

the

wave

very small fraction of the ambient temperature and pressure.


Plane wave Front

Tiiis expression is obviously related to Bernoulli's theorem for the steady flow of on incompressible fluid (p = const). If we consider (he fluid flowing past two different cross sections of a pipe at different elevations A] and h~ and apply the principle of conservation of energy, we get

{As
2 Pi
Fig. 9.8

Ai)

+ \ (* -

,*)

p,

pj

(9.12)

1 Pi

Plane

wave

front

in

a gas.

theorem thus says (hal at any two points along a streamline an ideal fluid in steady flow, the sum of the pressure, he potential energy per unit volume, and the kinetic energy per unit volume have
Bernoulli's
in
I

the

same

value.

These waves

ravel at a speed which

depends only on the ambient

For a small disturbance where the fractional changes in gas and pressure are much smaller than unity, these changes across the wave front can be written as it* = u\ + du, Pz = p\ + dp, and p : = pi + dp. When we substitute these in Kqs. (9.10) and (t).ll) and neglect product terms of differential quantities, we have
velocity, density,
Pl

state of the fluid.

sound wave in three dimensions can be derived from fundamental physical principles starting in this way. Imagine, a small prism or a packet of gas enclosed by a weightless dcformable membrane. The mass within this packet remains constant. The elasticity is expressed by the ideal-gas law. The inertia appears in Newton's second law, from which the
of a

The propagation

du

tt

2p,u, du

+ urdp = -dp
r

dp

(9.10a)
(9.1 In)

By

eliminating du from these two equations,

we obtain an expres-

sion for the


u

wave speed
(9.13)

p F

equation for the wave propagation can be derived. A simpler procedure may be followed in describing the special case of a plane wave front moving from right to left at constant speed it, in a gas initially at rest and having density pi. To an
observer moving with this wave front there will appear to be a steady flow of gas from left to rigbl across the wave Ironi (Kg,
9.8),

Laplace assumed the compressions and expansions associated with sound waves should obey the adiabatic gas law, pp> = constant where y is the ratio of the specific heats, Cp /C r If this
.

Relationship for

p and

p is

assumed, the speed of sound becomes


(<ut)

tti

VyRT = J?l

102

Looking In: Atomic and Nuclear Physics


result,

Wave Motion

103

This

for gases at

based on the adiabatic law, does not hold for liquids, extreme pressures and temperatures, or for acoustic
the pressure fluctua-

9.7

WAVES

IN

SOLIDS

waves

of very high frequencies.

tions in
justifies

However, sound waves range from about 10 9 to 10~ 3 atm, which the asumption of small disturbance in deriving

Different types of acoustic waves may occur in solids, depending on the way in which potential energy is stored in the solid. Transverse waves on flexible stretched strings are described

Bq. (9.14).

by an equation of the form


IN

9.6

SHOCK WAVES
wave

A GAS

3P"

6\r

(9. If))

In a
in

of

wave speed is higher than wi regions of condensation (p > pi) and lower than i in regions rarefaction. This causes the wave to distort as it propagates.
of large amplitude, the

where

;/

is

the displacement of the string at a point


is

of propagation v

,r. The speed equal to the square root of the ratio of the

Regions of higher condensation overtake those of lower condensation (Fig. 9.9).

tension to the mass per unit length of the string:

The

thin "characteristic lines"

are shown

for cor*

4In
in

(9.10)

Fig. 9.9

When wave speed


amplitude, the
distorted
1, I,,

Acoustic waves occur


increases

bars
is

when
due

the bar

i>

brm and

re-

with

wave

wave form

leased.

Here the restoring

force

to the

moment

of the forces

becomes
intervals,

at successive time

2f

i.

fD

responding points in the wave. The slope di/dx of these lines is inversely proportional to the speed. The net effect is to steepen compression regions and to flatten expansion regions. Before the
situation represented at

about the neutral plane in the bar and depends on the crosssectional dimensions and on Young's modulus. Seismic waves which travel through the ground originate from natural readjustment of the faults in the earth's crust or from explosions. Both body and surface waves result. The body waves, which travel through the interior of the earth, may be classified into dilationai (longitudinal) waves, which are similar to acoustic waves in compressible fluids, and shear (transverse) waves, which occur on account of the large shear modulus of most elastic
solids.

2d

is

reached, friction and heat-transfer

effects counteract the steepening tendency.

The compression
is

part

From known

relationships between propagation speeds

and

of the

wave propagates without

further distortion. It

then a

the mechanical properties of various substances, seismologists

shock wave.

obtain from seismograms valuable information about the strnci

Bomb

blasts start as shock waves, large-amplitude compres-

lire

of the earth.

Such information can be applied

to prospecting

sion waves. Planes traveling at speeds greater than the speed of

Tor

mines and

wells.

sound (Much niiniher = speed of body/ local speed of sound > 1) generate shock waves which are responsible for the sonic boom sometimes heard and felt on the ground. When an astronaut reenters the earth's atmosphere, the early motion of his vehicle is determined by its shock wave and can be estimated from the size and velocty of the vehicle and the known temperature, pressure, and density relations for the wave.

9.8

ELECTROMAGNETIC WAVES

lames C. Maxwell recognized about 180-1 that the basic equations for electric and magnetic lields could be combined to give an equation which resembled the wave equation for mechanical waves in a fluid {see Sec. Fi.fi).

104

Looking In; Atomic and Nuclear Physics


particle in the

Wave Motion

105

9.9

SUPERPOSITION OF WAVES

medium transmitting a complex wave the form of equation of an


y

is

given by

For many kinds of waves, two or more waves ean pass through the same space independently of one another. One can distinguish the notes of a particular instrument while listening to a full orchestra. The displacement of a particle in the medium at any instant is just the sum of the displacements it would be given by each wave independently. The principle of superposition states that the net displacement of a particle is the vector sum of the displacements the individual waves alone would give it. This principle holds for an elastic medium whenever the restoring
force
is

= A
B

sin

co(
i

Ai
oil

sin 2ut

At

sin Swi
B,i

+
:io>t

+ if

cos

Bi cos

2U

cos

(9.17)

In Fig. 9.10, the

wave

(dotted) which has an approximately

square wave form is shown to be equivalent to three component waves with frequencies in the ratio :3:o and amplitudes in the ratio 1 :| g. The Fourier series representing the square wave is
1 :

= A

sin id

A
tt sin

JW

+ = sm out +
.

(9.18)

proportional to the deformation. Superposition holds for


9.10

INTENSITY OF A
is

WAVE
transmitted through the
travels.

In any wave, energy

direction in which the

wave

medium in the The amplitude of the wave,


Each
particle has energy

which
Fig. 9.10

is

the amplitude of vibration of the particles in the medium,

Analysis of a complex

is

related to the transmission of energy.

wave

form.

of vibration

which it passes on to the succeeding particles. In simple harmonic motion, where there is no damping, the energy of a vibrating particle changes from kinetic to potential and back, the total energy remaining constant. We may find this constant energy from an expression for the maximum kinetic energy

electromagnetic waves because of the linear relations between


electric

E k

lm(u ui:ix y

and magnetic

fields,

( r

')'

"

\m@rfv<>y

2ir

mf y^
2

The superposition principle does not hold in every ease. It fails when the equations describing the wave motions are not linear. An acoustic shock wave has a quadratic wave equation;
superposition does not hold. Hippies which can cross gentle ocean
swells cannot preserve their identity in breakers. Intermodulation

(9.19)

where

y<>

amplitude of vibration
period

T / =

frequency

mass

of the particle

when the system fails combine two tones linearly. An important consequence of the superposition principle is that it provides a means of analyzing a complicated wave motion as a combination of simple waves. Joseph Fourier showed that any smooth periodic function may be represented as the sum of a number of sine and cosine functions having frequencies which
distortion occurs in an electronic amplifier
to

The energy per unit volume in the medium is the energy per particle times the number n of particles per unit volume

~ - a2* 8*/W s

-iTr-pp-ih?

(9.20)

where

= mn

is

the density.

are multiples of a single basic frequency.

The displacement

of a

/ of a wave is defined as the energy transferred per unit time per unit area normal to the direction of motion of

The

intensity

106

Looking In: Atomic and Nuclear Physics

Wave Motion
ence
is

107

the wave. The energy tluil travels through such an area per unit time is that contained in a volume which has unit cross section and a length equal numerically to the speed 8 of the wave. From Eq. (9.20)
/

constructive.

of the individual waves.

The amplitude is the sum of the amplitudes Where waves arrive 180 or X/2 out of
1

phase, the interference


of alternate maxim;!

is

destructive.

When two wave trains of different


and minima
is

2Teh>ppij,r
is

(9.21)

the vibration

(l-'ig.

i).ll).

frequency interfere, a series produced in the amplitude of The frequency of these "beats" is the

The

intensity

directly proportional to the square of the ampli-

difference of the
in

tude and to (he square of the frequency of the wave.

When u wave originates at a point source and travels outward through a uniform medium, at some instant the energy is passing through the surface of a sphere. A moment later the same energy is passing through a larger spherical surface. Since the total energy per unit time is the same at the two surfaces, the intensity
is

A familiar example occurs two tones of slightly different frequency are sounded together, one perceives that the loudness pulsates at the beat
two wave frequencies.
sound.
If

inversely proportional to the area 4?rr 2 of the surface:


/

wwvwm wwwvwm
Two waves
wave

=
lirr*

/.":

(9.22)

If

instead
is

energy

we have a line source (e.g., a fluorescent lamp), the spread over successively larger cylindrical surfaces.
is

The

intensity

inversely proportional to the area

27rr/

of the

Fig. 9.11

of different frequency combine to couse beats.


trains of frequencies

Two

cylindrical surface:
f

coincidences per unit time are shown for

10 and 12.

=
2jrrt

hi
r

(9.23)

Frequency.

Thus

if

the tones are middle

(2(i!/sec)

and

O sharp

(280.5/scc), there will be 16.5 beats sec.


is inversely proportional to the distance r. For a plane source (e.g., a skylight), which is large compared to the distance from the source, the energy passes through suc-

Here the intensity

9.12

DIFFRACTION
of a

cessive planes of equal area.

There is no divergence of the rays. independent of distance. As a wave passes through any medium, some energy is absorbed by the medium. Hence the energy |>;i-<iim through sucIn this case the intensity
is

The bending
Diffraction
is

wave around an

obstacle

is

called diffraction.

readily observed as ripples on water

bend around a

stick placed in their path.

The
the
grating.

principles of diffraction
of

cessive surfaces decreases faster than expected from the change


in area alone. The decrease in intensity due to absorption of energy is called damping, A wave whose amplitude decreases for

measurement

and interference are applied in light with an optical diffraction A transmission grating is a glass plate upon which is
wavelength of
lines,

ruled

many

equally spaced

usually several thousands per

this reason is called a

damped wave.

9.11

INTERFERENCE OF WAVES
physical effect of superposing

The

two or more wave motions

is

called interference.

Where waves

arrive in phase, the interfer-

monochromatic light falling waves in all forward directions from each slit. Along certain definite directions waves from adjacent slits are in phase and reinforce each other. Consider parallel rays making an angle with OB, the normal to the grating, which are brought to focus at a point P by an
centimeter.
parallel

beam

of

normal to

this grating

(l-'ig.

9.12) sends

108

Looking In: Atomic and Nuclear Physics

Wave Motion

109

achromatic Ions, If ray AP travels a distance X farther than ray CP, then waves from .1 and C will interfere constructively at /' for they differ in phase by a whole number of wavelength*. The wave front CD makes an angle 8 with the grating. From the smallest right triangle, the path difference X is seen to be CA sin 0. The distance ('A between corresponding points in the ruling is called the grating space />. The condition for reinforcement in
the direction 8
b sin
is

formed by a grating that has 5.000 lines/in., compute the separation of these two lines in the third-order spectrum
o

ttIsL o.OOO

cm =
5.791

5.08

X
r'

10"

cm
4^68 A =
=

5,791
sinfl

A = =

^=
b

10"

am
10-'

4.358
e

10

am

3(5^?1_X 10
5.08

<n.O

...

_
'

"

X
X

cm

2();r

(first

order)

(9.24)

sin

8i,

3(4,358

IP" 6 cm)
10- 4

5.08

X
~

cm

0.258

ft,

15.0

There are other directions on each side of OH for which waves from adjacent slits differ by 2X, 3X, -IX, etc., and for which the

Separation

'*

ft

5,3

9.13
Tf

STANDING WAVES
wave on reaching the boundary of a medium is totally the reflected wave proceeds in the opposite direction

reflected.,

Fig. 9.12

Diffraction grating.

fW
(a)
Fig.

(b)

9.13

directions; R

Standing waves from superposition of waves traveling in opposite is the resultant of A and S. The envelope of a standing wave is

corresponding bright images P>, /\,


order, third-order, etc.,

etc.,

are called the second-

shown

in

(M.

images.

The

grating equation in more

general form
b sin 6

is

= AT X

(9.2.-))

and with equal amplitude (big. 9.13.!. The incident and reflected waves add according to the principle of superposition. Two such waves, proceeding to the right and left, may be represented by
the equations

where

is

When
persion
is

the order of the spectrum and b is the grating space. white light fulls on the grating, it is dispersed into its
colors.

i/ x

yo sin

component
appear
in

Spectra are produced at Pi, r\ etc. The disgreater in the higher-order spectra. In each, the colors
the sequence violet (small X) to red (large X) with in-

MM)
:

y-i

!/ B

sin

creasing deviation. Example. A yellow line and a blue tine of the mercury-arc spectrum h;ivc wavelengths of 5,791 A and 4,358 A, respectively. In the spectrum

The

resultant

may
t/s

be written
tf

,'/t

si n

(9.26)

110

Looking In: Atomic and Nuclear Physics

Wave Motion

til

We may
of
sin

use the trigonometric relation for the

sum
B)

of the sines

two angles A

sin

II

=
in

2 sin l(A

B) cos %{A

If a system which can oscillate is acted upon by periodic impulses having a frequency equal or nearly equal to the natural frequencies of the system, oscillations will occur with relatively

large amplitude. This vigorous response of a

system

to pulses
is

to

put Eq. (9.26)


y

the form
I
=-,

nearly synchronous with one of


resonance.
(9.27)

its

natural frequencies

called

=
is

2wx 2y sin -y- cos 2w

This

the equation for a standing (no n progressing) wave.

Let us determine the natural frequencies of a stretched string. standing waves are established in the string, the end points will be nodes. There may be other nodes in between. So the

When
harmonic motion. All particles vihrate with the same frequency. But the amplitude is not the same for all particles; the amplitude varies with the location x. The points x = X/2 (where n is an integer), at which sin (2tx, X) = 0, show no displacement and arc called nodes. The 2 + X amplitude has a maximum value 2i/ n at points .< = and
particle at a particular point % executes simple
I

wavelength of the standing waves can have


Since the distance between adjacent nodes

many
is

distinct values.

X/2, in a string of

2'

Vib rotor

such points are called autinodos, or loops (Fig. 9.136). In general, when a wave reaches a boundary, there
reflection

is

partial
Fig.

and

partial transmission.

Consider a stretched string


a

9.14

Standing waves

in

string driven at

attached to a second string.

When

wave

in

the

first

string

frequency nearly equal to a natural frequency,

reaches the boundary joining the strings,

the. reflected

smaller amplitude than that of the incident

second siring carries incident energy. If the second string has a smaller linear density than the first, reflection occurs without change of phase. If the second string has a greater linear density than the first, there is a
in the

transmitted

wave

wave has wave because the away some of the,

length

there must
2,

be exactly an integral

number n

of half

wavelengths, X
X

so

*
7i

n
Kqs. (9.1)

1,2,3,
(9.2ti),

phase shift of 180 on reflection.


relation X

From Eq.

(9.2fi), it is

evident
the

From
are

and

the natural frequencies of vibration

that the wave travels more slowly in the denser string.

From

in the denser string the wavea study of light waves we frequently observe this phenomenon of change of speed and wavelength as light passes from one; medium to another. v/f,

we conclude that

length

is

shorter. In

21 yitn/t

n=

1,2,3,

(9.28)

9.14

RESONANCE

Free or natural oscillation refers to the oscillation of a body or a system which has been given a displacement from equilibrium and then is not acted on by any external or driving force. The body or system will generally have several distinct frequencies of natural
oscillation.

These relations may be demonstrated in a string one end of which receives energy from a vibrator, such as an electrically driven tuning fork. The string passes over a pulley, I' in Fig. i>. 14, and is attached to a weight which maintains the string under tension I<\ The frequency / of the wave is that of the vibrator. The wavelength is
9
1
i

F_
in
I

/ V

112

Looking In: Atomic and Nuclear Physics

Wave Motion

113

The wavelength may be varied by changing the tension F, which changes the wave speed v. Whenever the wavelength becomes
nearly equal to 2l/n, standing waves of large amplitude may be observed. The string is then vibrating in one of its natural modes

fi

Then the general equation relating the observed frequency and the source frequency fs is

h
u

f*

vL

9u

vs

(9.29)
I'M

and

is

in

resonance with the vibrator.


the optical Doppler effects.

Example, What forte must be exerted on the string, using the apparatus of Kg. 9.14, to produce resonance with the string vibrating in one loop? The vibration has a frequency 20/sec, the string has a length 18 ft and weighs o.O ok. From Eq. (9.28), with n = I,

There an; important differences between the acoustical and ( The optical frequency change does
I

F =

Ifm =

400 6.0 slug


4(18
ft)

sec 2 10

3-1

11)

32

9.15

DOPPLER EFFECT

is a change in the observed frequency of sound, light, or other waves caused by motion of the source or of the observer, \ ami liar example is the increase in pitch of a train whistle as the

There

train approaches

and a decrease

in pitch as the train passes.


is

In the radar system used for traffic control, the speed of a car

estimated from the Doppler frequency shift in the radar


reflected

beam
mo-

from the

car.

In acoustics the Doppler effect deals with cases of relative


tion

and source, plus the effect of any motion of the medium. If the source moves toward a stationary observer with speed vn, waves emitted with a frequency fs appear to have their wavelength shortened in the ratio (u Vn)/u, because of the crowding of the waves in the direction of motion of the source
between
listener
(big. 9.15), Theses

Fig, 9.15

Doppler effect due


1

to

motion of the source S toward observer O.


front 2

Wave

waves, however, arrive at the listener with the

was emitted when the source was at position 1; wave emitted when the source was at position 2, etc. The drawing shows Wave fronts when the source is at S.
front

Was

positions of

speed u characteristic of the medium. If, instead, the listener moves with speed u L toward a stationary source, the waves appear to him to arrive with speed m v,l- The wavelength in this case is the same as that measured

not depend on whether

it is

the source or the observer that

is

when both

listener

and source are at

rest in the

medium.

Xow
The

consider motion of the medium. Let Vm be the component

of its velocity taken positive in direction

from listener to source. components v f and vs are taken to be positive in the direction from listener to source.
velocity
,

moving with respect to the other. (2) An optical frequency change is observed when the source (or observer) moves at right angles to the line connecting source and observer. No acoustical frequency shift is observed in the corresponding case. (3) Motion of the medium through which light waves are propagated docs not
affect the

observed frequency.

Analysis of the Doppler effect for electromagnetic waves

114

Looking

In:

Atomic and Nuclear Physics

Wave Motion
6.

115

(light) requires use of

Lorcntz transformations and the relativity


c is

postulate that the


observers.

wave speed

the

same

as measured
is

by

all

density
lb/in.*. 7.

find the speed of a compressional wave in a steel rail whoso 3 6 is 490 lb/ ft and for which Young's modulus has a value 29 X 10

The

result for the observed frequency fa

Am.
the speed of sound waves in air at 0C.
is

5,200 ft/scc

Compute

The average

molecular weight of air

29,

j0
.

Js
1

Vl - WJ&)
. I ,

y =

1. 40.

and

R =

8.3

10 a joules/

(0.30)

(kmole)CK).
a person inhales hydrogen and then speaks, how will the changed? How would the situation be changed if carbon dioxide were used? 9. A student places a small sodium vapor lamp just in front of a blackboard. Standing 20.0 ft away, he views the light at right angle-; to (be blackboard while holding in front of his eye a transmission grating ruled with 14,500 lines, in. He has his assistant mark on the hoard the positions of the first -order diffracted images on each side of the lamp. The distance between these marks is found to he 14 ft, 2 in. Compute the wavelength of the light.
8.
If

(u/c) cos 6

COS do

cos B s

{V/C) COS Or

(v/c) + -;

characteristics of his voice be

(9.31)

where

0<, is

the angle measured in the observer frame and 9s


if it

is

the angle that would be measured in the source frame

were

moving with velocity v relative to the observer frame. The term transverse Dtrppler effect refers to the relativistic,
direction-independent
Is
of

\/l

(u'/c

)-

above, fo m This shows that the observed frequency will be


factor
in

the

equations

less

than the source frequency regardless of the apparent direction


effect is the direction-dependent factor
effect,
is

motion of the source. The radial Doppler

and, like the acoustical Doppler

understandable on the An ocean


traveler has

basis of classical physics, fo /s/[l if>/c) cos 0|. In MK-18 II. ]' Ives and (1. It. Stilwcll measured frequencies in

even more vividly the impression that the ocean


it is

is

made

of

waves than

that

made

of water.

A. S. Eddington

the spectrum emitted by moving hydrogen atoms and compared the frequency shifts with those predicted by the equations above
for the transverse

Doppler
14.!)).

effect.

This became an experimental

False facts are highly injurious

to the

progress of science, for they often

verification of the special theory of relativity

and of the "dilata-

endure long; but


for

false views,

if

supported by
in

some

evidence, do

little

harm,

tion of time" (Sec.

every one takes a salutary pleasure

proving their falseness.


C. R.

Darwin

QUESTIONS AND PROBLEMS


Knergv can lie transferred by particles as well as by waves. How can you distinguish experimentally between these methods of energy
!.

What

art

was

to the ancient world, science is to the

modern.

Benjamin

Disraeli

transfer?
2. 3.

When waves

interfere, is there a loss of

energy? Kxplain.

Science and art belong to the whole world, and the barriers of nationality
vanish before them.

wo observe interference effects between the light beams omitted from two flashlights, or between the sound waves from violins in an orchestra?
don't
4. A line source (fluorescent lamp) emits a cylindrical expanding wave. Assuming the medium absorbs no energy, find how the amplitude and intensity of the wave depend on the distance from the source. 5. A cord 75 cm long has a mass of 0.252 gm. It is stretched by a load of 2.0 kg. What is the speed of a transverse wave in this cord? Am. 242 m/scc

Why

Goethe

-*
Electric

and Magnetic Forces

117

magnetism were initially developed as separate sciences has led to some inconveniences in concepts and units which the viewpoint
of the inks units (which

we

shall use) seeks to minimize.

10
Electric

10.1

CHARGE AND MATTER

anticipate experimental evidence described in later chapters summarize, some modern basic knowledge. Experiments on the electrification or charging of bodies show that there are two
to
Nucleons:

We

and Magnetic Forces

Nuclei

Atoms

Neutrons
Protons

O O *

:h()i
Electrons

cannot help thinking while

dwell upon them that


is

this

discovery of magnet-electricity (induction)

thB

greatest experimental result ever obtained by an investigator, J. Tyndall

Mo

ecu

'"(0)
Visible matter

Compounds

}p

Electric charges
in

and

electric

and magnetic

forces are important

**

le
Fig. 10.1

many

experiments? designed to reveal the structure and beComposition of matter.

havior of atoms. All visual information cornea to us in electromagnetic waves, and study of the ultimate structure of atomic nuclei depends on electromagnetic processes and detectors. We
shall outline here only the

main ideas

in electricity

and magne-

tism needed for our study of atomic and nuclear physics. The study of electricity dates from the observation ((500 ux.) that bits of straw and other materials arc attracted to rubbed amber. The study of magnetism dates back at least as far, to the observation that magnetite stones attract iron (but not other These two sciences were developed sepasubstances, lieneralh rately until 1820, when Hans Christian Oersted observed a relation between them: An electric current in a wire can affect a
,

A glass rod may be rubbed with silk, placed in a and suspended horizontally on a silk thread. If a second ulass rod is also rubbed with silk and then brought near the rubbed end of the first rod, the two rods will repel each other. Hut a hard-rubber rod electrified by rubbing with fur will attract the glass ra cJ. Two rubber rods rubbed with fur will repel each other. The charges on the glass and hard rubber must be different. We add the following details to the atomic picture of Chap. 8. An atom has most of its mass concentrated in a very tiny (10 -13 cm) nucleus. The simplest atom, hydrogen, has a nucleus which
kinds of charge.
stirrup,

magnetic compass needle. However, the fact that electricity and


116

comprises a single proton. All other nuclei contain, in addition to protons, one or more neutrons. Each atom has circulating

118

Looking In: Atomic and Nuclear Physics


its

Electric

and Magnetic Forces

119

nucleus a number of electrons equal to the number of within the nucleus. The mass of the electron is about protons of a proton or neutron (Table 10.1). An arbimass the 1/1,840

around

object on another
x ,

is

proportional to the product of the charges,

the square of the distance q and q 2 and inversely proportional to are regarded as "point" objects them (where the between r

trary convention adopted

in

Franklin's time for the sign of the

masses)

two kinds of electric charge leads us to call the electron charge negative, the proton charge positive. A neutron lias zero charge.
Toble 10.1
Particle

F =
The

<?><7s

(10.1)

Properties of

some baste

particles

Symbol

Charge

Mass, kg

Electron

-e
P
n

(= -5.60

10-"coul]

Proton

Neutron

9.108 1.672 1.675

10- 31

X X

10""
10

proportionality constant k is a positive number whose value depends on the system of units. Tn the electrostatic system of units (esu), the unit of charge is defined conveniently to make k = 1 in Eq. (10.1): One statcoulomb is that quantity of charge which repels a like charge with a force of one dyne when the charges are spaced one centi-

An

element

may

be designated by symbols zEl- 1 such as Be*


,

for berillium.

The

atomic:

tons (or electrons) in the atom. Its


the

number Z represents the number of promass number A represents

number of nucleons (neutrons and protons) in the nucleus. The number of neutrons is .1 Z, The chemical properties of an atom are determined by its atomic number. Two atoms which have the same atomic number, but whose nuclei contain different numbers of neutrons, are said
to be isotopes of the given element.

meter apart in a vacuum (or practically, in air). However, the meter-kilogram-second (mks) system of units defines a unit for current (ampere) as a fundamental unit; the unit for charge (coulomb) becomes a derived unit. The ampere is defined in terms of an electromagnetic experiment. The ampere is the strength of that constant current which, maintained in two

Objects can be electrified, or charged, either positively or negatively by the removal or addition of electrons.

Charges of like sign repel unlike charges attract. In the atomic model proposed by Niels Bohr in 1913, electrons arc pictured as whirling about the nucleus in circular or elliptical orbits. The centripetal force needed To hold an elect nm in its orbit is provided by the force of attraction exerted by the positive nucleus on the negative electron. In addition to the electrostatic (coulomb) forces between charges, there are forces which depend on the relative motion of the charges. These forces determine the magnetic behavior of
;

and very long conductors of negligible cross vacuum at a distance of one meter from each "' other, produces between these conductors a force of 2 X 10 newtou per meter of their length. The coulomb is that charge transferred by an unvarying current of one ampere in one second. In principle, we have only to measure the force, in newtous, between two 1-coul charges separated by 1 m in vacuum to hud
parallel, straight,

section placed in a

k in

mks

units.

The experimental value


10

is

8.987

10* newton-m-'/coul 2

(10.2)

In the so-called rationalized

mks system

of units, a different
is

constant

called the permittivity of free space,

introduced in

the equation for Coulomb's law


/'

4ttc

(10.3)
r2

matter.
so that
10.2

COULOMB'S LAW
eo

=
4irfc

Coulomb's law (1785) expresses the experimental observation that the force of attraction (or repulsion) exerted by one charged

4tt(8.987

X
=

JO

11

newton-mVcoul 2

8.85

10

'-

coul7newton-m

(10.4)

120

Looking In: Atomic and Nuclear Physics

Electric

and Magnetic Forces

121

The

Coulomb's fundamental law makes certain derived formulas more convenient. No it's then appear in formulas referring to plane surfaces, a factor 2tt appears in "cylindrical" formulas, and 4jt appears in formulas relating to spherical symmetry. For example, Table 10.2 gives expressions
arbitrary inclusion of the Factor
4ir in

diminishes the force between charges r/i and q*. Coulomb's law is then written F <7ifj a /4jrer s where is replaced by the larger
,

number

e,

the permittivity of the material in question.

10.3
If

ELECTRIC FIELD INTENSITY

for the

capacitance

(charge held per unit potential difference)


in

for capacitors of different

ized units

and

in

symmetry as expressed rationalized mks units.

unratioual-

there are several charges

Qu

Q->,

3,

in fixed positions,

The vehemence
argued

with which questions of units have long been

may

be inferred from Oliver Ileaviside's statement (1893)

and we bring up another charge 7, it will experience a force. We say that the fixed charges set up an electrostatic field about them and the charge q experiences a force when in this field. We define
the electric field intensity as the net force per unit

charge

Table 10.2

Comparison of expressions for capacitonce


Unrationalized
units

R
Rationalized
units

force

charge

+q

(10.3)

</
L

^
i

Plane capacitor

C=

Awd

C = iAJd

i|

Coaxial cylinders
2
In

ji (I

b;a

C=
2
In

is a vector quantity. Its mks units are newtons per coulomb (or volts per meter, from Sec. 10.4). We can often calculate the value of K at each point of a region of space; these values determine the force on (and hence the motion of) a charged particle in that region.

Electric field intensity

b/a

F = gE
Concentric spheres

(10.(>)

C=

Ah b -a

(4r)ab
b

The

electric field

near an isolated point charge


is

Q
r

is

easily
it

-a

calculated. If a test charge q

brought to a distance

from Q,

experiences a coulomb force

that "the unnatural suppression of Aw in the funrationalizedj

formula for central


out
all

force,

where

it

has the right to he, drives

it

F = ~

q (4x eo )r 2 of the field

(10.7)

into the blood, there to multiply

itself, and afterward to break over the body of electromagnetic theory." The mks units were adopted by international agreement for scientific and engineering use beginning in 1940, but actual acceptance of the mks system has progressed slowly. We shall use the rationalized mks system of units.

The magnitude

is

then

K - P +q

Q
(4areo)r*

(10.8)

The statement that Coulomb's law applies to "point" charges means, practically, that charges qy and q-> must be associated with bodies whose dimensions are negligibly small compared to r. The
evaluation of the constant k above holds only for the case where the two charged particles are in vacuum. If they are immersed in

This electric field intensity is represented by a vector which, at each point in space, points directly away from Q if Q is positive
or directly toward

if

is

negative.
10
-9

Example.
t'tiLil,

some medium,

say,

oil,

the polarization of

its

molecules greatly

are 8.0

Two charges, q, = 75 X cm apart in uir. Find

coul

and q t
field

+ 75 X
E

10

-9

he electric

intensity

at a

122

Looking In: Atomic and Nuclear Physics


is 5.0 era from each charge (Fig. 10.2). The field intensity represented by the vector PA and is given by

Electric

and Magnetic Forces

123

point P, which

due to
2?,

171

Considering a field due solely to a fixed charge Q, we shah compute the work done by an external agent in bringing another
charge q from a great distance (infinity)
in to

_-L
4weor i

at a distance

=
=
The
but
field
its

75

X
X

10-'(9 .0
(0.05)*

10')

newton
i-oul

As q is moved an arbitrary path (Fig. 10. .'5), it


Q.

H from

infinitesimal distance ds along


will

an

be acted on by a practically

27

10*

newton/coul
q*
is

Ei due to charge
is

also 27

10*

newton/coul

in

magnitude,

direction
8

that represented by vector PC.


?,=>

The

resultant field
D

9 l =-75xT0"

+75xicr

Fig.
Fig.

10.3

Calculation of potential at a point

P.

10.2

represented by vector PR. Since triangles TKiP and one may write the following proportion:
is

PRC
cm cm

constant force
are similar,

F =

qQ/4irt D r s

The work done on the system

of

charges by the agent exerting force

is

PB = DG PC PG E = 43 X
10.4

or

_B
27

8.0
5.0

10*

newton/coul

dW = F cos
and q
it

6 ds

-7-^, dr

(10.10)

10* newton/coul, parallel to the tine joining t q

where the negative sign comes from the fact that


cos
fl

F and

ds

(=

dr)

are vector quantities in opposite directions.


in

The

ELECTRIC POTENTIAL

total

work done

bringing q from

=o

to

is

then
(10.11)

In electrical phenomena the concept that is important in cases of energy transfer is that of potential difference. If we move a charge through an electric field, we exert a force through a distance, and so do work. The force exerted at each point is proportional to the

IK

lQ

R<

t=
s

flQ

4iro

J"

hrtjt

amount
b

of charge

moved, and thus the

total

in this charge.

The

electric potential difference

work is proportional between positions


in

Dividing by q in Eq. (10.1 1), we have the work per unit charge, which is the potential, given by

and a

is

the work done per unit

charge

carrying charge

v R - r =
Strictly,

from a to

Q 4aW

(10.12}

AV=
Potential

V
is

- Va =

^
in volts:
1

we have defined only


is

difference of potential. Jf arbi-

(10.9)

trarily the potential

measured

volt

joule/caul

the charges (l'

0),

taken to be zero at infinite separation of then the potential (sometimes called the

124

Looking En: Atomic and Nuclear Physics


r

Electric

and Magnetic Forces

125

"absolute" potential^ at a distance

from an isolated point charge


10.5

Qis

ELECTROSTATIC DEFLECTION
deflection of charged particles
in

V Tf q

Q
4xe r

(10.13)

The
and

by

electric

and magnetic

fields

has been important


positive (or both negative) charges, then
</

the identification of elementary particles

and Q are both

in the

the external agent bringing


tion of the

system.
tial

II"

toward Q exerts a force in the direcmotion and does a positive amount, of work on the k(ijQ '"). This work is stored in the system as poten-

oscilloscope

development of such useful devices as the cathode-ray and the mass spectrograph.
case,

As

special

consider a

parallel-plate?

capacitor (Fig.

10.4) with

charge

on the upper plate and

+Q
+

on the lower

energy
Fig.

10.4

AV,

for o uniform

P = qQ = qV
4vt
r

(10.14)
If

electric field.

I
between the plates
field
is is

z
Q

Tin's potential

energy can be recovered.

the charge q at a point

plate. If the distance s

small compared with

distant r from

is

released,

it

will fly off; its potential

energy

is

converted into kinetic energy.

and Q have different signs, then in the trip from ; to It, the agent will have to hold q back (to prevent acceleration).
If

uniform in the region from the upper between the plates. If we lake a small charge plate across to the lower, the work done is the product of the conthe other dimensions, the electric
</

stant force liq and the distance


difference, the

s.

From

the definition of potential

The IF
in

of Eq. (10.1

1)

will

be negative. Because energy

is

trans-

work

is

also the product" of the charge q


A'r/s

moved and

ferred from the electric field to the agent, the charges are placed

AV. By equating

these,

AV, we have
(10.15)

a configuration of lower potential. Energy would have to be put back into the system to separate the charges again to infinity. These ideas will be used in calculating the energy stored in an atom of hydrogen, where a positive nucleus attracts the negative
electron (('hap. lo).
lisniiifih-. Kleetrons which leave a healed filament with negligible energy arc accelerated to pass through an aperture in a metal plate maintained at. a potential of !)00 volts above thai of the filament. What is the final s))eod. of the electrons?

AV E A

for uniform field

sists of

device for studying the charge and mass of particles conan evacuated tube in which a narrow beam of particles,
slits c,

defined by

plate capacitor
it

and <. passes between the plates of a and then impinges on a fluorescent screen

parallel-

S'

where

Each electron has a charge


9.00

10" 11 kg.
it in

The

10"" coul and a mass of of 1 .130 electron gains kinetic energy equal to the work

produces a visible spot (Fig. 10.;">), The x component, of the velocity of a particle suffers no change as the particle passes

through the capacitor and goes to the screen. In the

electric field

dime on

falling

through potential difference V.

(l)w*

= Ve

Hence

">/?-(
The
1

1.6

lO"

'

coul 901)

9.11

10-" kg

*)'= M X
in falling

I0*m/sec

AV
+

TT
S'

kinetic energy attained


1

by an electron
given the

through a

potential difference of

volt

is

name

electron volt (ev).

ev

- (-e)(-AV) = 1.602 X = 1.002 X 10- ' joule

10-

,u

1
Fig.

k-L-4
10.5
Electrostatic deflection of a

coul (1.00 joule/conl)

beam of charged

particles.

126

Looking In: Atomic and Nuclear Physics

Electric

and Magnetic Forces

127

of the capacitor,
tf

a positive
tlie force

particle will experience

acceleration n from

exerted by the

field

E on the

an upward charge
(I

Fv _ qE

proportional to the kinetic energy of the particle. Such deflection experiments are important in identifying, sorting, and utilizing charged particles.
Toble 10.3

m
The
particle

O.K.)

Charge-moss

ratios for

several particles

velocity
vx

emerges at the right components

side of the capacitor with


Particle

q/m, coul kg

v
Electron
I

1.75V

m
where
(

(10.17)

Proton

particle

9.579 4.822

X X X

I0 11

10 7 10 7

l/v,

the time required for the particle to pass through

the capacitor.

emerges from the capacitor at an angle original path, where


particle

The

with

its

10.6

ELECTRIC CURRENT
motion constitute an
electric

Electric charges in
(10.18)

current.

In
is,

ten b

"JL

' ?

vx

T.'

metallic conductors there are electrons not

many

"free" electrons, that

A C observed on the screen is the sum of the deflecwhich the particle incurs while in the capacitor and deflection BC brought about by the v velocity component while the particle travels distance D.
The
tion

deflection

AB

ir

(10.19)

bound strongly to particular atoms of the metal. Each electron moves in an irregular path, continually colliding with atoms of the metal. If a wire is connected across a battery, an electric field is set up within the metal. The electrons tend to drift from regions of low potential to regions of high potential. This electron "wind" is the current. The continual collisions are responsible for the resistance of the metal. The kinetic energy gained by the electrons from the field and given up in collisions is he power loss i-R which produces heating in any currentl

BC = Dt&n0 = ^E-,D
Thus the measured
deflected through
deflection

(10.20)

carrying conductor.
In electrolytic solutions, in

some types

of

vacuum

tubes,

and

an angle
q

AC is as if the beam were abruptly midway through the capacitor:


(>E
{

in certain solid-state devices, electric current

may

result

from the

Positive plate

+. Negative plate
|t

AC = AB + BC =
If

\ mv* 2

,+ moI,

- (d
\
find

-A tan 2/
6.

(10.21) v '

we measure AC, D, and


.

we can

tan

Measurement
Electron flow

,/) Ammeter

of

through Eq. (10.18), gives a value speed v of the particles, we can iind a value for q/m, or vice versa. The experiment does not determine q and m separately. The experiment is usually done in such a way that = (exis a very small angle, so that tan pressed in radians). Then, for a given instrument, is inversely
for

AV and $ determines E and,


q/mv 1
If

we know the

initial

High potential
Conventlal current
Fig.

Low

potential

10.6

Direction of electron flow

and of con-

ventional current.

128

Looking In: Atomic and Nuclear Physics

Electric

and Magnetic Forces

129

motion of both positive and negative charges. Any currenl direction is a convention; the choice of sign is arbitrary. In this honk

perpendicular to both v and


of the right point in

B and directed so that, if the fingers hand are directed from the direction of v (around
than 180) to that of B, the right thumb the direction of F. The magnitude of F is given by
less

we

shall regard the direction of conventional current as that of

through an angle of
will

the flow of positive electricity.

The conventional

high potential to low potential ("from


circuit.

to

"}

current
in

is

from

the external

F^qvIixmB

(10.23)

If two parallel wires carrying current in the same direction are brought near each other, they attract each other. This effect is the basis for the definition of the ampere, the inks unit of current (Sec. 10.2). This attraction is not an electrostatic (coulomb) force between unbalanced charges. It is a magnetic force arising from the motion of charges. It is convenient to discuss these magnetic forces in terms of a field.

where 8 is the angle included between the positive directions of v and B, Xote that a vector cross product v x B is zero if v is parallel or antiparallcl to B, Notice also that A x B = B x A; that is, A X B is equal in magnitude but opposite in direction
to

B X
The

A.

unit for B, from Eq. (10.22)

is

second). This inks unit for

is

given the

newton/(coulomb meter/ name weber/meter 1

we her
10.7

MAGNETIC INDUCTION
basic vector for describing a magnetic field
is

m
called the

eoul

newton m/sec
still

newton
1

amp-m
is

The

mag-

An

earlier cgs unit for H,

often used,

the gauss.

netic induction, B. (Magnetic field strength

would be an appro1

priate

name

for B,

but historically this

name has been


fields.)

assigned
identi-

weber nv

10*

gauss
r/s is

to another vector
fied

connected with magnetic

We

and measured an

electrostatic field in terms of the force

The summation of B over a surface J'B flux *. The weber is the unit of flux.

called the

magnetic

exerted on a unit positive charge. Kxperimetitally

we

identify the
field

presence of a magnetic
is

field

from the fact that

if

a magnetic

present, a

moving

electric charge will experience a

sideways

a charged particle moves through a region in which both electric and magnetic fields are present, the resultant force on the particle is given by

When

magnetic force. The magnetic induction


fies

is

defined as the vector which satis-

F =

ryE

f/(v

B)

(10.24)

the relation

F =

q(v

It)

(10.22)

Only in the special case where E, v, and B are suitably oriented can we replace Eq. (10.24) by a scalar equation which suggests
straight, addition:

where force F, charge q, and velocity v are the measured quantities. This notation of a "vector cross product" means that F is

F = qE

qv

B sin

(10.25)

is the angle included between the positive directions of where v and B.

Fig.

t0.7

F =

q(v

B)

10.8

MAGNETIC FORCE ON A CURRENT


electric current

An

be visualized as moving charges. Assume that in a conductor of length I there are n conduction electrons

may

per unit volume, each with charge q and each having an average drift speed i\ (The negative electrons drift in a direction opposite

130

Looking In: Atomic and Nuclear Physics

Electric

and Magnetic Forces


in circular

131

to that of the current, Fig. 10.8.)

The

distance an electron

moves
JV con-

tripetal force

needed to keep the particle

motion

is

per second
tion

is v.

The volume
is

of charge passing a certain cross sec-

of the wire

Av. In this

volume there are nAv


is

supplied by the magnetic side thrust. Since the velocity of the in particle is always perpendicular to the induction, sin 8 =
1

duction electrons.
/

If this

conductor

in

a uniform magnetic
Representation of an

Eq. (10.25). Newton's law

F = ma

then can be expressed as

Fig.

10.8

U
induction B, the force q(v

electric current.

5
on each moving charge in the / which is

The momentum

of the particle

mv can be found

if

we know B

xB)

conductor produces a force on the conductor of length

F = Nq(v X
But the
velocity

B)
is 1//,

and Nq/t

is

the current

i,

so the equation

for the force hecomes

and q and measure r. If measurements of electrostatic deflection and magnetic deflection are carried out on the same beam of charged particles, one can determine both q/m and v for the particles. In this way Thomson measured the charge/ mass ratio for electrons in 1897 (Chap. 11). Similar deflection methods arc used today in some types of mass spectrometers to obtain accurate values of q/m for ions and isotopes.

F = Nq
or

(j

N X b) = (

f\

(1

B)

(|

B)

(10.26)
10.10

MAGNETIC INDUCTION OF A CURRENT

F=
10.9

Bil sin d

We

MAGNETIC DEFLECTION OF CHARGED PARTICLES


force

have just considered problems relating to the forces exerted by a magnetic induction on a moving charge or on a currentcarrying conductor. A second class of problems involving magnetic lields concerns the production of a magnetic induction by a
current-carrying conductor or by moving charges.

on a charged particle moving in a magnetic induction is at right angles to B and to v. The particle is accelerated, nit always perpendicular to its velocity. The magnetic force changes the velocity (vector) but not the speed (scalar). No work is done on the particle by the magnetic force, for cos 9 = in the expresI

The

The
is

relationship between current

and magnetic induction


a point

given by Ampere's law.

The magnetic induction at

B P

sion

W = /F cos da. When a charged particle

from a current i in a wire is the vector sum of contributions from every element of the wire. The induction at P due to the current in element d\ of the wire is
arising
d\\

enters a uniform held with


to

its

ve-

locity perpendicular to B, the particle experiences

an acceleration
velocity.

-_ til I\ Air r'

(10.27)

of constant magnitude

qvB/m perpendicular

its

The

particle describes a circular

path with constant speed. The cen-

have again used the notation of the vector cross product. The magnitude of rfB is given by

We

dB Fig. 10.9

u.,

idl
r2 sin 8

(10.28)

4w

Path of charged particle


1i.

in

plane

normal to

The constant u,. is called mks system its value is


/in

the permeability of free space.

In the

4jr

10 -7 joule/amp*-m

132

Looking

In

Atomic and Nuclear Physics


is

Electric

and Magnetic Forces

133

The
dl

direction of r/B
r,

and such that if the (through an angle less than


will

and

perpendicular to the plane of the vectors fingers of the right hand arc turned
180)

from
dli.

dl to

r,

then the right

perpendicular to the plane of the current elements i dl and r, in the sense given by the cross product d\ x r, or out of the page. Since a radius to any point on the loop is perpendicular to the

thumb

point

in

the direction of

tangent to the circle at that point, sin = in Bq. (10.28). Writing r d<p for dl, the magnitude of B at the center of the loop is
1

B = toL-* r*"=
To

>,

0&>
it is

calculate the magnetic induction at a distance

infinitely long straight wire (Fig. 10.12),

R from an convenient to take

Fig.

10.10

Induction
i

dU

contributed by cur-

rent element

dl.

Fig.

10.12

Induction

near a Mroight conductor.

Ampere's law as expressed

in

the last two equations cannot


the z axis along (he wire in the direction of / and with the origin at the point of the wire closest to l\ The upper and lower halves

we cannot isolate an element i dl of an electric circuit. Actually Ampere's law was not deduced from any single experiment. Rather it summarizes many experiments dealing with magnetic effects of circuits of different geometry and witli magnetic forces exerted by currents on each
be subject to direct experimental check, for
other.

of the wire

make equal
sin
i

contributions so we

may compute B by

integration of the expression

To

illustrate the tise of

Ampere's law we

shall calculate the

B =

2 f-

magnetic induction (I) at the center of a circular loop, and (2) at a point near a long straight conductor. At the center of the loop (Fig. 10.11) the direction of the magnetic induction H is

4x

/-*. } -

'/:

(10.30)

For the section of wire below the origin

(z

<

0)

we have

-R
dz

tan 8

and

R
2

sin 6

Fig.

10.11

Induction

(out

of

page) at

de d(.^\=4 \tm 0} sin


in

center of a circular loop.

Equation (10.30) may be written

terms of one variable


noi

0:

R _

tint

[*ft

sin

d0

r*te

134

Looking

In:

Atomic and Nuclear Physics

Electric

and Magnetic Forces

135

giving

B =

li.nl

(10.32']
2-xii

(h) When a current-carrying wire is in a magnetic field, the magnetic force on the wire is directed from the region of stronger induction toward the region of weaker induction. Consider a wire perpendicular to the page carrying a current into the page (Fig. 10.14a). The local magnetic induction encir-

10,11

DIRECTION RULE
relative directions of the vector quantities in Eqs. (10.22)

cles the current in the clockwise sense. If

now
field

this current-carry-

The
and

ing conductor

is

placed in an external

B,

(Fig.
field

10.

4b),

(10.27) implicit in the vector cross products can be remembered conveniently from the following rules: (a) If, in imagination, the right hand grasps a current-

B and

B\ reinforce each other above the wire (strong

region)

and partly cancel each other below the wire (weak field region). The force F on the wire is down. A representation of the net field due to B and Bj is shown in Fig. 10.14c,

=^z^
(a)
Fig. 10.13

10.12

INDUCED CURRENTS
and
electric

further important relation between magnetic fields


is

current

the principle of induced emfs on which the design of

generators, transformers, and motors

(M B
i

current: {a} Side view,


j

Magnetic induction toward

right; (b)

near an electric end view,

out. It counterclockwise.

is based. Michael Faraday and Joseph Henry, at about the same time (1831), showed that an emf is induced in a conductor when there is any change of magnetic flux linked by the conductor. It is convenient to consider this single principle from two viewpoints, (i) An emf e is induced whenever a conductor moves across a magnetic field

Current "in"

Current "out"

=
I

IvB sin d

(10.33)

B,

(a)
Fig.

where

= =

length of wire
its

velocity

angle between and

B
is

When mks
in joules
(b)
(c)

units are used on the right of Eq. (10.33), e

given

per coulomb or in volts.


is

(2)
field region

An emf

induced whenever the flux ($

= BA) changes

through a circuit:
10,14
Force on a current-carrying conductor
field region.
is

from strong

toward weak

= d*
dt
is in

(10.34)

carrying conductor with the

thumb

pointing

in

the direction of
If

the conventional (+) current, the fingers encircle the wire in the same sense as the magnetic induction B. Thus in rig. 10.13a, B

the rate of change of flux

webers per second, the emf

e is

in volts.

out of the page above the wire (indicated bj dots) the page below the wire (indicated by crosses).
is

is

into

Lena's law states that whenever an

emf

is

induced, the induced


its

current

is in

such a direction as to oppose (by

magnetic

effects)

136

Looking

In:

Atomic and Nuclear Physics


is

Electric

and Magnetic Forces

137

the change inducing the current. Lena's law


of the conservation of energy principle.

really

an example

QUESTIONS AND PROBLEMS


State some similarities and some differences between the pheof electric fields and gravitational fields. 2. A positively charged rod is brought near a ball suspended by a silk thread. The hall is attracted by the rod. Does this indicate that the ball has a negative charge? Justify your answer. Would an observed force of repulsion be a more conclusive proof of the nature of the charge on the ball? Why?
1.

As applied

to Fig. 10.

r
l. >,

Lea*

's

current induced in the

moving wire must he Mich as motion. This requires the magnetic force on the wire
a

law says that the direction of to oppose its


to

nomena

be toward

Fig. t0,!5 Emf induced in wire ob moving across a uniform magnetic


field.
II

3.

tions

AC

The circuit in the diagram consists of two concentric circular secand l)E and two radial sections CI) and HA. There is a cur-

the

left.

right)

From Sec. 10.1 b, the net induction ahead of the wire (at must be greater than that behind the wire (at left). To
1

Fig.

10.17

reinforce the external

li,

directed out, ahead of the wire, the


b,

induced current must be down, from a to


rule (Sec. 10.1 In).

from

tint

right-hand
rent i in the direction shown. Starting from Kq, (I0.2S). derive an expression for the flux density at O, the common center of the arcs. Show the limits of integration arid any special values of factors in die equation. Show clearly the contribution of each part of the circuit.

What

is

the direction of the (lux density at

0?

Ans. ?

ol(fii

~_^ij

4. A 5.0-m straight wire ab (Fig. 10.18} is allowed to fall through a uniform magnetic induction of 2.0 XII) webcr/m* directed pcrpen5

Emf induced in a coil moving from a to b in nonuniform magnetic field.


Fig. 10,16 Fig. 10.18

dicular to the wire, (n) What is the emf induced in the wire at the instant its speed is 3.6 m/see? (6) What is lire direction of this emf in the wire? (c) Which end of the wire is at the higher potential?

Note that
potential)

in this

"generator" b

is

at a higher potential than

a.

Positive charge

is forced to flow from a (low potential) to b (high by the work an external agent does in moving the wire

ab against the magnetic force. In the external circuit bca, the

Am. 3.6 X I0-* volts; toward right: 1',. l' 100 ft in diameter. Ms axis of rotation i- on a north-south line, (a) If the horizontal component of the earth's field is 2.00 X 10 _i weber/m* and the wheel is rotating at 2.00 rev/rain, what i* the potential difference existing between the axle and the end of one
5.

>

Ferris wheel

is

apoke?
(}.

charge flows from high potential toward low potential ("from to "); it can do useful work, and it produces ,-/>' heating in the conductor.

(b) Which i^ at the higher potential? Ans. 488 pv Assume thai this mom has a uniform magnetic field directed vertically downward and of flux density B = 1.0 X 10-" weber/m*. (a) Determine the magnitude and direction of the force on an electron

138

Looking In: Atomic and Nuclear Physics

room moving due east and at an angle of 30 above the 10* m/sec. What, will be the speed of horizontal with a speed of 3.0 see after if enters the room? (b) An east-west this electron 1.0 X 10 wire is stretched horizontally across the room. What will be the direction and magnitude of the force on (i.O-m section oT the wire when there is a current, of 12 amp westward in the wire?
thai enters the

''

:i

Am.
sou til

2.4

10-" newton, south;

3.0

10*

m/sec; 7.2

10" 1 newton,

11
The Electron

The

electron has conquered Physics,


idol rather

and many worship the new


blindly,

H. Poincare

The most important


physics
is

thing a young

man can

learn

from his

first

course

in

an appreciation of the need for precise ideas.

W.

S. Franklin

A new

principle

is

an inexhaustible source of new views.

Marquis de Vauvenargues

To succeed

in

science

it is

necessary to receive the tradition of those

who

It is the purpose of this chapter to discuss the experimental evidence of the existence of the electron, some of the measurements which have been made on it, and the limitations of the classical free-electron theory of the conduction of electricity in metals.

have gone before dead and the

us. In science,

more perhaps than


Charles Singer

in

any other study, the


11.1

living are one.

IDENTIFICATION OF THE ELECTRON

In a paper

"On Cathode Rays"

(1897), J. J.

Thomson

first

estab-

lished the existence of free electrons.

Thomson's investigation was

prompted by ihe divergent opinions people had at that time about the nature of cathode rays. Experimenters had shown that at
low pressures (about 0.01 conductor of electricity and

mm

of

mercury)

air

becomes a good

that,

the discharge of electricity

through a gas produces light whose color depends on the gas and in a pattern which depends on voltage and gas pressure (Kig. 11.1).

Some
139

people considered the rays charged particles; others


in the "aether."

thought of the display as a phenomenon

Thomson

140

Looking In: Atomic and Nuclear Physics


2.

The
Deflection by an electric
in Fig.
It

Electron

Mi

working suggested that an explanation based on particles as hypothesis was more likely to he successful and could he more
:i

shown
3.

easily tested

hy known laws

(of

mechanics) than any explanation

oscilloscope.

field was investigated in the tube the precursor of our modern cathode-ray verified the negative charge of cathode rays.

11.3,

based on properties of the aether about which little was known. Mr therefore devised experiments "to test some of the conseCrooke's dork space

of the cathode rays was measured in a tube without deflection plates and provided with a screened electrode,

The energy

Cathode

Faraday dork spoce

Positive column

#-

! % -A
II

Anode

Cathode glow

Negative glow

Anode glow

To pump
Fig, 11.1

Discharge of electricity through a gas at reduced pressure.

Fig. 11,2

Discharge tube far demonthe

quences of the electrified particle theory." The objects of son's experiments were:
1.

Thom-

(negative! charge and magnetic deflection of cathode rays. The magnetic field is excited in space S by coils placed outside the tube.
strating

To

verify that cathode rays carry a charge, a charge which accompanies the rays when they are deflected by a magnetic
field

2.

To
in

:?.

investigate quantitatively the deflection of cathode rays an electric field, which deflection also indicates the presence oT charge To determine the energy of the cathode rays and, by using this value with data on the magnetic deflection, to deter-

as in

Fig.

11.2.

The
in

innermost, electrode contained a thermo-

couple. Its increase

temperature

in

mine the speed and the


"particles"
4.

ratio of charge to

mass

e/tn, for the

and simultaneous measurement was made


rays received at the thermocouple.

a given time was measured, of the charge from the

To determine
tric

speed and

<

hi

also

from a combination of

elec-

and magnetic

deflections
of these properties in

Thomson obtained information on each


the following ways:
1.

If, in the time considered, Ar particles strike the thermocouple each bearing a charge r, the total charge is Q = A>. From the ri.-e in temperature the total energy is known

Ek - S\mt:~

(i i.|)

In a tube such as shown in Fig. 11.2, cathode rays leave the cathode C, pass through an opening in the anode A, and reach a region B where they are deflected by a magnetic field, pass

through an opening
collecting conductor
in

in a
/'

grounded cylinder 6, and

finally reach

mounted

inside that cylinder.

An

increase

charge

when rays enter the opening


charge
it

is

by an electrometer connected to /' only in Q. The observations prove that a inseparably connected with the cathode rays and that
is

registered

is

a negative charge.

Fig. 11.3

Thomson's tube for electricol deflection of cathode rays.

142

Looking In: Atomic and Nuclear Physics

The Electron

143

where
radius

is

the mass and

the speed of one particle. Next the

From
e

Eqs. (11.0) and


v

(1 1.7)

r is

measured

for the path described

by the

particle in a

Ei
rBJi-,
air,

magnetic
thrust

field.

The

centripetal force

is

equated to the magnetic

m
With

,B,
this

(11.8)

method, and using

C0

and

2,

Thomson obtained

cvB
of the

(11.2)

similar values for e/m. Again, the nature of the gas did not influence e/m.

For each
netic

two

flat circular coils

used to produce the mag11.2

field,

is

given by Eq. (10.29)


(11.8)

THE CATHODE -RAY TUBE

o _ B -

Mo/
"27

We

where J is the current and mu is the permeability of free space, 4w 10" 7 weber/amp-m. It follows from the preceding equations
thai
v

digress to point out the relationship between Thomson's apparatus and the modern cathode-ray tube. If the potential to be observed is applied to plates !\ (Fig. 11.4) and a potential

me*
erli

Nmv 1
NerB

2Ek

QnJ

(11.4)

and

-o
p.
(a)

2Ek

tB

Qho2P
,

(11.5)

With different gases (air, II 2 and CO.) in the tube, Thomson showed that e/m had the same value 2.2 X 10" coul/kg. Thus
cathode-ray particles are independent of the nature of the gas. 4. Values of e/m can be obtained by a different method for comparison with the foregoing results. In the tube of Fig. 11.3,

a magnetic

two

coils

plates.

field is established, into the plane of the paper, by whose diameters are etjual to the length of the capacitor The crossed electric and magnetic fields are adjusted to

give the cathode-ray zero deflection.


electric force

The

cancellation of the
is

(upward) and the magnetic force (downward)

expressed by

isV

Bicv

(11.0)

Fig. 11.4

(o)

Cathode ray tube,

(b)

Test

and sweep

potentials.

where A'i is the electric field intensity. Next the particles are deflected by a magnetic field only, directed perpendicular to their velocity, and the radius r of the path is determined from observed deflection on the screen. Here

that increases linearly with time


deflecting plates
/*.,

is

applied to the horizontally

Btfo

(11.7)

a wave form. If frequency as the alternating potential on Pt , the trace oi\ the screen is repeated each cycle and appeal's to be stationary.

beam (cathode ray) traces out a saw-tooth wave form is repeated at the same
the electron

144

Looking In: Atomic and Nuclear Physics

The
11.4

Electron

145

11.3

ELECTROLYSIS AND THE ELECTRON

CHARGE OF AN ELECTRON, MtLLIKAN'S EXPERIMENT

It has l>een seen (Chap. 8) that the combining properties of the elements can l>o interpreted in terms of an atomic theory of matter. Faraday's study of the electrolysis of aqueous solutions of chemical compounds suggested thai electricity is also "atomic" in nature. Faraday's discoveries of fundamental importance may

be expressed thus:

1.

The mass The mass

of a substance separated in electrolysis

is

propor-

tional to the quantity


2.

Q of the

electricity that passes.

;!/ of a substance deposited is proportional to the chemical equivalent k of the ion, that is, to the atomic mass A of the ion divided by its valence t>,

M-kQ-^Q
where
/"'

(11.9)

Millikan, about 1909, devised a highly precise experiment based on the fact that electrically charged droplets of oil can be held stationary between the horizontal plates of a capacitor by adjusting the voltage between the plates so that the weight of the drop is balanced by the force due to the electric field. The "oil drop" experiment can be used (1) to show that electric charge occurs in multiples of a discrete amount and (2) to measure the value of the smallest charge, the electron. See Fig. 1.5, page 147. An oil drop will fall with accelerated motion until the drag due to air viscosity becomes great enough to balance the weight of the drop. For the small speeds which occur in this experiment, the frictioual drag is proportional to the speed of the drop. Setting the weight mg equal to the f fictional drag fct>) gives us an expression for the terminal speed vi reached by the drop falling
1

is

a constant of proportionality

known

mg =
as Faraday's
ij

h'i

(11.10)

constant.

Careful

electricity required to lilierate a

measurements have been made of the amount of mass of any substance numeri107.88 kg of silver,
is

cally equal to its chemical equivalent, say


1

.008 kg of hydrogen, or 05.38/2 kg of ainc. This value


is

9.052

X
in

take from hydrodynamics Stoke'slaw/.' = t'wnjr, where is the viscosity of air and r is the radius of the drop, assumed spherical. If the oil drop has a charge c/, due to an excess (or deficiency) of electrons, and if a uniform electric field is now established between the capacitor plates, the electric force on the drop is

To evaluate k, we

10 7 coul/kmole. It

called

faraday. It

is

represented by

Eq. (11.9).

F-ft-J,
When
the drop
it

(li.ll)

Faraday inferred from

his

experiments that the same definite


in

now

falls

amount
charge

under the influence of gravitational and

of electricity

is

associated

the process of electrolysis

electric fields,

with one atom of each of these substances.


is

He considered

attains a
O'o

new terminal

velocity v^:
(11.12)

that this

by the atom, or in some eases by a group of atoms, and he called the atom or group of atoms with its charge an ion. In 1874, Stoney stated the hypothesis that "nature presents us with a single definite quantity of electricity." He suggest ed the name electron for this quantity and calculated its value from the faraday and from Avogadro's number N*. In terms of
carried

F mg =
V
--,<}

ftj

up taken as positive)

Combining Kqs.

(11.11)
hit

and

(11.12) gives
(11.13)

mg =

Suppose now
change change
in

values
/.'

now

accepted,

the drop increases by an

owing to random ionization, the charge on amount q. There will be no significant mass, but a new terminal speed v 3 will result from the
that,

jy,e

ij,cjf)2

10'

coul/kmole

in electrical force:

9.052
e

0.0219

10' coul /kmole

_
,
'

molecules/kmoie

6021

X -
l

y
-j
(<1

C Ui

9)

mg =

Icv-s

(11.14)

146

Looking In: Atomic and Nuclear Physics

The Electron

147

From

Eqs. (11.13) and (11.14), we have a measure of the change in charge in terms of observed speeds:
Qn

the properties of the material as a conductor of electricity (and


heat).

Xo

other property of solids has such an enormous range of

= y &(-> -

*>j)

(11.15)

values as does electrical conductivity (Fig. 11.6).


best insulators by a factor of 10".

The

best con-

ductors have electrical conductivities greater than that of the

whole-number multiples of a certain quantity.


this

Millikan observed that experimental values for q were always Pie inferred that

quantity

is

the basic unit of charge, the electron.

^=feo

Example. By timing its full through a known distance, an experimenter determines "the successive -prods y and c +1 of a single oil drop having successive different random charges. He computes the change in charge data indicate (q) from Kq. (11.15) as tabulated below. What do these
charge of an electron? inspection, one notes that the values for </ are, within experi10"". By dividmental uncertainty, whole-number multiples of 1.6 ing this number into the charges q, we find the values n in the second column. The experimental value for the electronic charge is (hen the
for the

By

Telescope

average of the values of

in the last

column.
Fig.

11.5

Millikan's

apparatus for determining the charge of an electron.

q,

X10-"
4.76
3.21

coul

1.6

10~"

qn

X 10 n

"coul

4.96 8.07

2.98 2.00 3.10 5.05

1.59
1.61

2 3
5
e

1.65
1.61

= 1.61

11.5

ELECTRONS

IN

METALS
is

The conduction

of electricity through metals

fundamentally

Conduction electrons have been compared to a gas which is move within the metal, under the influence of an applied electric field. The metal is visualized as consisting of an assembly of stationary positive ions permeated by an electron gas which makes the metal as a whole neutral. This qualitatively attractive picture proves to be inadequate in several important respects. first, on this basis we should expect the specific heat of a metal to consist of two parts: that of the ionized atoms considered as vibrators (3/2) and that of the electron gas (}!), or a total specific heat of f ft. This finding is in marked disagreement with
free to

different from electrolytic conduction.

When

a copper wire has


_

Ohm-cm
10 10"
10

carried an electric current, even for a long time, no chemical

io

10
i i

10'
i

to"

io

,:

10"

10*
=f

change can be detected in the copper. .More than a century ago it was first assumed that electricity is an agent that can flow

n
Cu Ni Ho
Si

Se

CU2O

r
Mica
Glass

Celluloid

Amber
Porcelain

Paraffin

and its direction of How were unknown, but the flow was assumed to be from the arbifreely in a metal.

The

sign of this charge

Ge

ZnO

Quortz Ceraml

trarily defined positive (high-potential) terminal to the negative

(low-potential) terminal.

At present we have evidence that

elec-

trons flowing in the opposite direction are responsible for the conduction of electricity in metals. These electrons are called free
electrons because they are temporarily detached from atoms. The number and freedom of motion of these electrons determine

-*-

Conductors
11,6
lO. 2 "

-Semiconductors

Insulators

Fig,

Resistivities

(ohm-centimeters) vary over

the

enormous range of

aboyt

148

Physics Looking In: Atomic and Nuclear

measured

5S
and

conductivity with temperature emishigh temperature (thermion.c through a metal surface at ct on e c classical a on quantitatively sion) cannot be explained conductivity. m the great variation gas theory, neither can satisfactory way out of theory (Chap. 16) provides a

by Du hmg 3/f a relation discern! e tec tncal of variations Second, the Petit as early as 1810. electrons of escape and the
cal
(

heat, of specific P

dements
.

in

the solid state, namely,

mole degree)

12
Ions

Quantum

and Isotopes

these difficulties.

QUESTIONS AND PROBLEMS


electron which moves in a the kinetic enemy of at, magnetic mi uction of 9 .1 to a perpendicular oirce" of radius 5.2 em to potential difie^nce would be reqmred (6)
1

(a)

What

Ls

The most important trends


try

in

indus-

TlO^weWom*?

523

today spring from an increasing


of the properties of parts.

.top this electron after

l0 ' volts and charge B falls through a potential 2 Vn electron of mag1' right angles, a region of uniform at enters .hen and difference electron pa* the of radius 8. What is the

i,

^fctff'fi^ ,j X
X
10'
in

knowledge
and
their

atoms

component

mas

David Sarnoff

fiS*.
" L,t 3

m^mag-

by Thomson the apparatus f i,uha-tb plate capacitor The to them to return the beam to its mvoltage imiM be applied to the .ketch in a StioBl () J tnUuld fc.^ induction ft and the Uu maguel.c eleclrnu velocity r. the

Etetrom

traveling 2.00

m/see are subjected to a magnetic

K3> Snee/Ma)
wSt
1

0.0030 weber/m

^teJ
4.

SL

An

oil

droplet of mass 2.5


is

2 electron charges,

ft* *e JpSZnS what must


from
10
falling,

X 10"" gm. which em ate* 2 between two horizontal capacitor p by etectne foraefe droptef is entirely.snpported
holi be the potential ddTerenrc

^*~* <^"MH^d
of

'^J"J-

v^^Pjg
an

a circle of 12-cm radius

?i<WlutP

tho enemy of the electron (*) Calcdate *.,,,, { dthe in cm is 20 radius Hec.ron whose path J"""10-' 6 joule or 2.2 Mev, ^.U X iw /Ins. 3.6 with speed e along toe traveling electrons of 6 V narrow beam plates of a parallel-plate eapacrig pa s^s etwecn the horizontal x & the V. The separation of difference potential a lo ,3 Htamed F the beam capuclor the ( in distance a plan-s 111 Show that in traveling from J lie x axis, given by will experience a deflection the

rft *SKbbv
enemy

bjrfWo photograph, an ejeotron pato* O.OOsO weber/m^ a magnetic induction of

was foreshadowed by studies in radioThe possibility that two different radioelements might lie identical chemically was inferred by the failure to separate certain ones by any chemical means available. Also Thomson's study of positive rays (HJl.Tj in ion-deflection experiments yielded two lines for neon (atomic masses 20 and 22) yet no dilTereuees were observed in the optical spectrum of the Ne gas. Thomson recorded his suspicion that "the two gases, all hough of different atomic weights, may be indistinguishable in their chemical and .spectroscopic properties."
of isotopes

The discovery

activity (Chap. 17) about 1007.

12.1

MASS SPECTROMETERS

t V I = - T ~\

War I, Dempster, Aston, Bainhridge, and others devised instruments for determining both the masses of isotopes
Boon after World
149

150

Looking In: Atomic and Nuclear Physics

Ions

and Isotopes
is

151

and their relative abundance. Although there are many types of mass spectrometers,* a brief consideration of their common elements should clarify the operation of any type. A moving particle might be characterized by its velocity v,
its

This equation can be rearranged to show that the device energy selector

an

&nv*

= %REq

(12.3)

momentum

mv, or

its

kinetic energy \rns-.

We may

consider

arrangements of electric and magnetic lie Ids designed to sort charged particles according to these properties. Two types of energy selector are suggested in Fig. 12.1. In the first, ions from a source 8 are accelerated through a potential

In the selector of Fig. 1 2.2, the beam of positive ions passes through a region where a magnetic induction B is directed out-

Fig.

12.2
0).

Momentum

selector

(B

is

directed out;

/V'.lJ
,'

bid

<

-A. v R

i.ri J""\
{a)
Fig. 12.1

ward from the page. By equating the centripetal force to the magnetic side thrust, we get
mi(6)
selectors.

:
and

qvB
tie vice is

li

(12.4)

Energy

it is

apparent that this

momentum

selector
(12,5)

difference V.

They acquire
is

kinetic energy

^mu 2 equal to Vq. The

mv = RBq

speed of an emerging ion

then
(12.1)

field li

Consider next a twain of positive ions acted on by an electric and a magnetic induction B at right angles to each other. In the situation of Fig. 12.3, the ions experience an upward force
B,

have tacitly assumed that the ions are at rest at s. Actually they may have small (I ev) energies of thermal motion. This is usually negligible compared with the energy {say, >100cv) ob'ained from the electric field. But for some purposes, the slight spread in the velocity values for emerging particles might have, to lx> considered. In Fig. 12.16, the ion beam passes between the plates of a curved capacitor. The ions are acted upon by an elecin the direction of O. The ions move in a circular arc. tric field

We

Fig.

12.3

Velocity selector.

*
1
I

fr.
I

qE due to the electric field. With B directed out from the


magnetic side thrust on the ions ions for which
qii
will
is

page,

he-

qvB,

downward. Only those

/-'

The

centripetal force

is

provided by the electric

field:

= qvB

(I2.fi;

mv* -

r. = Eq

pass through without any deviation. This

filter selects

(12.2)

ions

of a particular velocity

* in a

mass spectrometer, a meter measures an ion current;


is

in

a mass

E
= B
(12.7)

Spectrograph, the record

obtained on a photographic plate.

152

Looking In: Atomic and Nuclear Physics

Ions

and Isotopes

153
inter-

I a Baiubridge mass .spectrograph (Fig. 12.4), positive ions from an ion source arc colli mated by slits s, and x* and then pass
into a region in which they experience an electric force to the left and a magnetic force to the right (supplied by Hi which is directed
into the page).
slit 3

the mass scale from


polation between

to

2">0.

Unknown masses are found by

known masses

(often using ions of molecules as

energy release

From

Etj. (12.7),

the only ions which pass through

are those of speed

atomic masses can be deduced from the (Chap. 18). A table of the "Ix-st" values of atomic masses obtained as averages of mass spectrometer and nuclear reaction data, adjusted
well as of atoms). Also,
in certain kinds of nuclear reactions

for self-consistency,
r

is

useful

in

many

calculations in

modern

= -

Bi

(12.8)

physics.

where /; has Iktu expressed as V only by a uniform induction B

".-,-.

Beyond

s the ion
;i

is

influenced

12.2

ISOTOPES

(into the page) which causes the

Fig. 12.4

Boinbridge moss speetro-

groph.

a circular arc of radius ft until it strikes the photowhere it makes a developable trace. By measuring the distance 2/1 from this trace to slit s a and using Eq. (12.4), we can find the charge mass ratio
ion to

move

in

graphic plate

/'

'/

''

BJl

B B#R
y

(12.9)

The charge on

the ion will he a multiple of the charge on the, or 2c), which the experimenter must find. electron (usually of the ion. lie may With q known, he can calculate the mass

then add the mass of the missing elect ron(s) to (hid the mass of
the atom.
7 For measurements of highest precision (a few parts in I0 }, a in region mass spectrometer is designed to cover only a limited

As the accuracy in measurement of atomic masses increased, it was established that not. all atoms of the same element have the same mass. Atoms of the same element (same Z) which have different masses are called isotopes. Many elements (Be, F, Xa, Al, P, Co, etc.) occur naturally with only one isotope. Many others (H, He, Li, B, etc.) have two, and tin, the most varied, has no less than 10 isotopes. It the mass of a carbon atom is taken to be exactly 12, then the masses of the other elements, determined by quantitative chemical analysis, come out to be nearly whole numbers. Historically this led to Front's hypothesis that all elements were built from hydrogen. This picture was spoiled by certain atomic masses determined chemically: 35.8 for CI, 63.54 for Cu, etc. But when measurement of isotope masses became possible, it was found that the mass of every isotope of every element was very close in an integer on the scale in which carbon is taken as 12 antra (or, originally, oxygen defined as 10 amu). Naturally occurring chlorine, for example, is a mixture of about 7o per cent of an isotope :S4.!)7!K) and 25 per cent of an isotope 38.9773. Its average mass, as found in chemical experiments, is then (35) + t($~) = 35.5. The whole-number rule may be retained in this form: The mass of every isotope of every element is well within per cent of a whole number when expressed in atomic mass units, defined by taking carbon as 12 amu, exactly. We thus retain the picture of all atoms built up of some unit of which there is in hydrogen, 4 in helium, Hi in oxygen, etc. We have yet to explain, however,
1
1

* Sec (.'. II, Blunt-hard, C. R. Burnett, H. G. Stoncr. and R. L Weber, "Introduction to Modern Physios," appendix fi, pp. 392 100, l'rciitireHall, liic, Engleivood Cliffs, X. J. 1958.
,

154

Looking In: Atomic and Nuclear Physics

Ions and Isotopes

155

why

the atomic masses arc not exactly integers instead of being

very nearly integers.

QUESTIONS AND PROBLEMS


1.

5. On the photographic plate of a ma>s spectrograph, a trace made by a singly charged ion is h.und jusf halfway between the line formed by 16 (+) and that formed by CH,(+). Find (he mass of this ion if the mass sped rennet er is (u) a Bainbridge type, when the mass of an ion is proportional In the radius m = kr, and (b) a Dempster type, where the
1

dispersion equation

is i

kr 1 .

The

values of

and

in

the velocity selector of a mass spec6.

Ans. 10.018148 amu; 1B.009074


In a

amu

trometer are MIDI) colts, n. and 0,050 weber/m*. (fl) Wluit will be the speed of ions passing through this selector? (b) By what radius will a singly riiarsnl ion of mass 50 amu be deflected by a magnetic field of
2.5

method devised by S. A. Goudsmit, masses of heavy ions are determined by timing (heir period of circulation in a known magnetic field. To get an idea of the timing requirements, calculate the
of a singly charged ion of iodine ail 127 (mass an induction of 0.045 weber/m 5 -4ns, about 1.8 X I0~* sec 7. Show why the mass spectograph gives data on the atomic masses of individual ions, while conventional chemical methods yield results only on average atomic, masses. 8. Silicon has an atomic number of II. Consider two isotopes of silicon having mass numbers 28 and 30, fill in ihe remaining spaces in

X
2.

10~ a

weber/m1

after leaving the velocity selector?


Arts. 1.6

period

of

revolution
in

10' m/aee;2.1

em

126.945

amu)

accelerated through a potential difference of 1,000 volts, li is then subjected to a magnetic field of 0.10 weber/m1 in which it is deflected into a circular path of radius
is

singly charged positive ion

18.2 cm. (a) of the ion?


3.

What

is

the mass of the ion? (h) Am. 2.05

What

is

the mass
kg. 15.9S

10

'

number amu: If.

dust particle has a mass of 3.0 X 10~ s kg and a charge of 10 10 coul. The particle is accelerated in an electric held until it has a speed of 4.0 m/sec. (a) Calculate its kinetic energy in joules, (b) What potential difference is required to give the particle this speed? (c) If the particle moves at right angles to a magnetic induction of 0.20 weber/m 2 what force will the particle experience? (</) What is the radius of the circular path in which the particle will move in this mag5.0

the table:

Mass number.

28
atom
in

30

netic field?

X 10"' joule; 480 volts; 4.0 X lO" 10 newtnn; 1.2 X 10 a m Dempster mass spectrometer, positive ions formed by heating a salt of an element are accelerated to a slit s, by a potential difference V (about 1,000 vol Is). A narrow bundle of ions then passes
Ans. 2.4
In
4.

Number of Number of Number of Number of

electrons in the
positive charges

the nucleus

protons

in in

the nucleus
the nucleus.

neutrons

Photo, plote or
electronic detector

Fig.

12.5

through the slit into a semicircular chamber where there is a magnetic induction II perpendicular to the ion velocity (Fig. 12.5). Ions having
i>

different values of e,'m will travel arcs or different radius.

Show

that the

charge/mass quotient of an ion can be computed from


e

2F
fi ! r 2

Electromagnetic Radiation

157

13
Electromagnetic Radiation

measuring the force between currents. This theory was experimentally verified by Hertz in 1888, and by 1901 Marconi succeeded in transmitting electromagnet ic signals across the Atlantic Ocean. The. electric generator, motor, betatron, television, and radar are based on principles included in Maxwell's equations. Home of the relations and experimental facts which Maxwell
synthesized carry the names of earlier investigators,*

13.T

GAUSS'

LAW FOR AN ELECTRIC FIELD

flux

Imagine a potatolike surface immersed in an electric field. The * of the electric field through this arbitrary surface is measured by the number of lines of electric force that cut through

Electricity,

carrier of

light

and power,
Fig.

devourer of time and space, bearer of

13.1

Electric

flux

through

human speech

over land and sea, greatest

surface.

servant of man.

Charles Eliot

the surface. Let the surface be divided into elementary squares An small enough so they may be considered to be plane. An clement of area can be represented by a vector As whose magnitude
I.

CLASSICAL THEORY
1

is

proportional to the area: the direction of

.is is

taken as the

outwarddrawn normal to the surface element.


of classi-

In
cal

8(14

James Clerk Maxwell completed the structure


and magnetic theory.

The
As; B
is

field

intensity

is

practically constant over


As.

an element-

electric

His summarizing equations

the angle between


scalar product A*

K and

The

stand with Newton's laws of motion and the- laws of thermodynamics as masterpieces of intellectual achievement. The four differential equations

up the

As cos

8 for all

found by adding elements into which the


flux is

the surface has been divided:

related to the charges


related to each other.
of physics

show how electric and magnetic fields are and currents present and how they are
-

*k

= 2E-As

(13.1)

They

correlated experiments in large areas

For a more precise definition we replace the sum by an integral:

and predicted important new results. Specifically, Maxwell showed that a changing current will radiate electromagnetic waves in which E and li are perpendicular to each other and
to the direction of the

* K - /E The
*

r/s

(13.2)
is

integration

to be taken over a closed surface.

wave motion.
all

electromagnetic waves of

theory predicted that frequencies should travel with tiie


Tlis
of

reader not familiar with calculus notation

speed of light

c,

whose numerical value can be determined by


156

Sees. 13.1 to 13.4

and resume

his

may wish (o skhn study immediately after the statement,

Maxwell's equations

in Sec. 13.5.

158

Looking In: Atomic and Nuclear Physics

Electromagnetic Radiation

159

Gauss' law states that the net (outward) electric flux through any closed surface is equal to l/* times the net charge q enclosed

hy the surface
eu

$K =

or

,,/ ds

(13.3)

where a uniform magnetic paper and is increasing with induction B is directed out of the charge, revolution, per is the product time. The work done on the of the emf S and the charge q. The work is also the product of the

moves around the

circle in Fig. 13.3,

Gauss' law provides a convenient way of calculating E if the charge distribution is symmetrical enough so we can easily evaluate the integral in F.q. (13.3).
Fig.

13.3

CKorged
6.

particle

q moving

in

Example

unit length. earrics charge per unit length

charge of +q/l per A long copper tube of radius a has which It is surrounded by a coaxial copper tube of radius
;i
!>

magnetic Induction

tanee cable

ri
at,

from the axis where t distance r : from the axis, Fig.

q/l. Find the electric field outside 6 > r > a and


(l>)

(a) at a

di*

this coaxial

13.2.

force

qE

that acts on the charge and the distance

2irr.

Equating

these two expressions gives

or,
Fig. 13.2

2iffli

(13.4)

more
8

generally,

= 6E

dl

(13.5)

If this last equation is combined with law of induction can be written

= d$ B/dl,

Faraday's

(13.G)
in) Draw a gaussian surface which is a cylinder of radius r u coaxial with ihe cable. Since the electric field is radial, there will be no flux through the cutis of the cylinder. For a length I of cable Eq. (13.3)

13.3

GAUSS'

LAW FOR MAGNETIC FIELDS

becomes
*u/E
giving

da

E(2irri)l

Gauss' law for a magnetic field expresses the fact that in magnetism there is no counterpart to the free charge q in electricity. Isolated magnetic poles do not exist. Hence the magnetic flux
'l>; (

through any closed surface must be zero:

(6)

When

the gaussian surface


is

is

charge within it outer conductor.

(+q/l

q/l)

a cylinder of radius r-i, the net outside the 0, and hence E =


13.4

*b =
<f>

da

(13.7)

AMPERE'S LAW

13.2

FARADAY'S LAW OF INDUCTION

Ampere's law (Sec. 10.10) giving the relationship between current i and magnetic induction li can be written in circuital form as

changing magnetic field produces an electric field, as described which in Faraday's law (Sec. 10.12). Consider a test charge

Ho

(/

<6

dl

(13.8)

160

Looking

In:

Atomic and Nuclear Physics

Electromagnetic Radiation

161

The

can be applied to any closed path near the current; symmetry usually suggests the most convenient path.
line integral
Si al

Example. Find the magnetic induction Straight wire currying current i.

a distance

from a long

two ways of setting up a magnetic field, by a changing electric field dK dt and (2) by a current i, we have assumed that there is uo current in the space considered in (1) and that no changing electric fields are present in (2). But,
In considering the
(I)

Fig,

13.4

Magnetic induction S near a

long, straight wire.

(a)

(b)
13.5

Consider a

circle of radios r centered af


It is

integration. Since

tangent

i<>

he path of the circle al each point .4, vectors It


I

lie

wire for

Fig,

The charging of a capacitor


field

ami
It

(the element of are) poinl in (lie same direction. From symmetry, has tiie same magnitude at each point on the wire. Equation (138)
<l\

changing

dE

dt,

which

(b)

(a) produces a produces a magnetic field 8.

becomes
in general,

- 6(27rr)
winch
is

ir

B =

**2irr

sidered.

the contributions of both dE/dl and i must be conMaxwell generalized Ampere's law, writing it in the form

the result obtained in Sec. 10.10.

.The term
current
current
t,\{d$y.'dl)
i is

dt

(13.11)

Experiments show that just as a changing magnetic held induces an electric field (Faraday's law, Sec. 10.12), a changing electric field induces a magnetic field. Faraday's law for an induced emf G may be written

has

he dimensions of current and

is

often

called the diaplawmvtit mrri-nt. Tims, although the conduction

no charge
%

is

not continuous across the gap of a capacitor (because transported across the gap), there is a displacement
i.

D in the gap equal to the external

E
dt

(13.9)
13.5

The analogous
by a whanging
/"'

expression for the magnetic induction produced


electric field
is

MAXWELL'S EQUATIONS AND ELECTROMAGNETIC WAVES


four basic equations

We assemble here the


(13.10)

we have

just discussed
(1

<p II

(II

eg
fjl

3.3)

*/

=
d

(13.7) (13.9)

where the constants n and a, are required in the mks system of units we are using. The situation expressed in Fq. (13.10) can be visualized by considering the region between the plates of a capacitor (Fig. 13.">a) which is being charged with a steady current i. The accompanying dl'I/dt produces a magnetic field: B is

0E-rfl= ~
m<>
I [

<

di

t^-%?
dt

(i3.li) '

shown

For four arbitrary points in Fig. 13.56.

We have written

.Maxwell's equations in the form they have

when

162

Looking In: Atomic and Nuclear Physics


is

Electromagnetic Radiation

163

no dielectric or magnetic material

present, since

we

are chiefly

magnetic flux * for the rectangle


this gives

is

B(tdx).

By

differentiation

interested in radiation in "free space."

Consider that the start of an electromagnetic wave occurs at the termination of a transmission line whicli is energized by an
oscillating electric circuit. Figure 13.fi suggests

d$n

how

the electric

W=

ldx

dB
-dl

field lines break away from an electric dipole as the charges +q and q first approach and then recede from each other in successive time intervals of one-eighth of a period 7. An observer at /' looking toward the antenna will "see" an instantaneous electromagnetic field pattern with E down and B toward his right

From Eq.

(13.9)

we have dE

= -Idx

(dB/dt), or

dE
dx

dB
dt

(13.14)

indicate that both

where we have changed to the d notation of partial derivatives to B and E are functions of x and ( but that in

N
E-r<fE

B+rfB

dx
t

r/a

r/4

3T/3

(c)

Fig.

13.6

Radiation from an oscillating electric dipole. [Adapted from


"Efecfric

S.

S.

A ft wood,
1949.)

and Magnetic

Fields,"

John Wiley

&

Sans, Inc.,

New

Fig. 13.7

to)

Section of a plane electromagnetic

wave

troveltng to the right


is

York,

E parallel to i axis, 6 parallel to y axis. The part


in

marked dx

viewed

in (b)

the xz plane,

and

in (c) in

the yx plane,

(into this page).

A moment
is

later, as

the wave advances, these

directions will reverse.


If

an observer

at a relatively large distance from the source,

t is assumed constant (Fig. 13.7// is an instantaneous "snapshot"). Also, x is assumed constant in evaluating dB/dl at the particular strip in Fig. 13.7c. From Eqs. (13.12)

evaluating dE/dx,

the waves that

For the

move waves shown


B
sin (kx
sin (kx

past

hi in will

be practically plane waves.

and

(13.13),

in Fig. 13.7,
wt) at)
I

kE
(13.12) (13.13)
I

cos (kx

oil)

o>Bn cos (kx

o>t)

B = E =

Eo

and we have the

relation

dx to be fixed in space. Its trace in the z.r plane is shown in Fig. 13.86. As the wave passes over it, the magnetic flux <t?n through the rectangle will change, inducing electric fields around the rectangle. The line integral of Eq. (13.9) is dE h there is no contribution from the top or bottom
Consider the rectangular prism
;

E _
~

CD

&

_ ~

(13.15)

where
angular frequency speed c
u>

2ir/

wave number k = 2*/X

of the rectangular

path where dl and

are perpendicular.

The

f\

a>/k

164

Looking In: Atomic and Nuclear Physics


ratio of the amplitudes of the electric
is

Electromagnetic Radiation

165

The

and magnetic com-

The magnetic part


netic induction B. For

of

an electromagnetic wave
//,

equal to the speed c of the electromagnetic wave. In considering the trace of our rectangular prism in the yx plane, Fig. 13.7r, we see that as the wave moves by, * changes with time and a magnetic field is induced at each point around

ponents

scribed by the magnetic field strength

is often derather than by the mag-

waves propagated

in free space,

the only

case

we

shall consider,

This induced H is the magnetic component of the electromagnetic wave; K and li each depend on the time rate of change of the other. Since there is no conduction current in the space
I

d.r.

H = -B
Since
ju

(13.19

4r

considered, the line integral of Bq. (13.10) hecomes iilli.


flux *s through the rectangular element Idx
is

The
dif-

(weber
space.

m'-'i

weber/amp-m. // has the dimensions = (amp-m/ weber), or amp/ in. The quantity

10 -7

EH

E{ld.t).

By

vVu/tu = 376.7 ohms

is

sometimes called the resistance of free

ferentiation this gives


et*a = M
tt, ,

ax

dE
-jt dt
13.6

ENERGY FLOW: INTENSITY OF A WAVE

From Eq.

(13.10)

expression of genera! validity for

an

dE
,0

aJ"**

"

(13.16)

Consideration of a parallel-plate capacitor can lead us to an the* energy stored in an electric field. To charge the capacitor to a potential difference A V requires

work
is

W equal to AC AV*,
is

where
a.s

is

the capacitance. This energy

where partial derivatives have been indicated for the same reasons as in Eq. (13.14). From Eqs. (13.12) and (13.13)
hllu COS {kx

stored in the capacitor

potential energy.

Between the plates

there
tion.

an

electric field
is

ut)

= enflqfi'o COS

(kx

The

capacitance

AV/s, where is the plate separagiven in terms of the area A of the plates

E=

<>)t)

and the permittivity


be expressed as

eu

as

C -

tA/s.

The

stored energy can then

and

since c

w/k,

we have
l

U
By
c

_L
e<ijuiiw

W=
(13.17)

C(AF) 2 = i*,is

EV

U E*As
field,

liu

tviinC

Since .4s
eliminating the fields between Eqs. (13,15) and (13.17),

the volume of the space between the plates of the


associate the energy with the
field

we get
(13.18)

capacitor,

we may

defining

the energy density of the electric

as the energy per unit

volume:
u,

(k) (u E*

(13.20)

Substitution of numerical values in this relation gives


Similarly, consideration of the
c

=
v/(8.!)

work required to establish a current in an inductive circuit suggests that the energy density for
field is

X
10"

10

l2

eoulViit-m ! )(4jrl0

'

weber,,'nt-m)

a magnetic
.

- 3.0

m/sec

;//*

- |B*

(13.21)
fields exist,

which is the speed of light in free space. Maxwell made this calculation before it was recognized that light was electromagnetic in nature and before Herts had detected
electromagnetic (radio) waves.

In a region where both electric and magnetic energy density is given by

the

= U

lt

E-

+ -^H*

(13.22)

166

Looking In: Atomic and Nuclear Physics

Electromagnetic Radiation

167

The

rale at which energy


is

is

transported by a wave across unit


.S'

The wavelength
10 sec. (13.12) the electric
2.0

is

area per unit time

called the intensity

of the

wave. Since the

-7

If

X = c/f = 60 m. The period T = 1// = 2jt/ coordinates are chosen as in Fig. 13.8, from Eq.

wave speed

field is

is c,

B, =

B. B

S - c(iP
By
written

innH*)

(13.23)

Ev = E
the use of Eqs. (13.17) to (13.19), the energy density can be

sin 2jr

(H)"
0.060 volt/m

060

sin (irl0 7f

0.105s)

The amplitude
s/tofie

// of

the magnetic

field is

w =

EH =

EH
wave
intensity

(I3.1M)
//

Vjo

p Bo =
//

37 G./
field is

ohm

1.59

10

<

amp/m

and the equation

for the

becomes
(13.25)

Since the magnet ie


//,

confined to the east-west direction,


//.-

S = c- EH =
c

EH
and the velocity
of the

=0
is

1.59

10-* sin (jtIO'J

0.105s)
its

The Poynting

vector

S = E X

is in

the x (north) direction, and

The

directions of E, H,
if

wave

are properly

magnitude

related

we

define the intensity

as the vector cross product


(13.26)

5 =

#o//u sin s

2v

(*-*)- 54 X 10-sin=
over a cycle
is
.V,

(xlO'

O.lOox)

S= ExH
This vector
is

The average value of this wave is


S

of sin- o

so the average intensity

called Poynting's vector. In

mks

units,

it

gives the

intensity in watts per square meter. Although


this expression for the special case of

we have derived
it is

= hEoIh =

4.74

10- \vatt/m

a plane wave,

a general
properties of light

relation which can be derived from Maxwell's equations.

Maxwell's electromagnetic theory explained the then-known the experimentally measured speed of light in
;

Example. Consider a plane monochromatic plane-polarized electromagnetic wave (raveling horizontally northward, polarized vertically (eleeirie field intensity directed alternately up and down). The frc-

free space,

polarization, interference,

and

diffraction,

and the

dispersion that occurs

when

light,

passes through a

medium where

y (up)

wave speed depends on wavelength. Extended to x rays, the theory identified them as also electromagnetic radiation, the diffraction of x rays by a crystal lattice being similar to the diffraction of light

x (north)
Fig.

by a ruled grating.

Many

tions were
13.8

shown

to be related regions of

seemingly diverse radiaan electromagnetic

spectrum of grand extent some 80 "octaves," of which the visible spectrum comprises a little less than one octave.

II.

QUANTUM EFFECTS

(east)

quency
electric

is

5.0 megacycles/see. intensity

field

pression for this wave, (6)

The amplitude (maximum value) of the 0/160 volt/m. (a) Give an analytical exFind the average intensity of this wave.
is

Beginning in 1900, developments took place which indicated that Maxwell's theory does not predict accurately all aspects of electromagnetic radiation and absorption of energy. These develop-

ments

led to the

quantum

theory.

We

shall trace the

quantum

168

Looking In: Atomic and Nuclear Physics

Electromagnetic Radiation
All materials exhibit characteristic differences in their

169

hypothesis from its origin in explaining blackbody radiation, its confirming success in explaining the photoelectric effect and Compton effect, and its striking hut limited success in the Bohr

absorp-

tion of radiation in different parts of the spectrum.

(The colors of

model of the atom (Chap. l;">) to its merging with other hypotheses in wave mechanics (Chap. 16).

things we view are due to such selective absorption.) Hence the emission spectrum for thermal radiation at a given

many

13.7

BLACKSODY RADIATION

Any object continually emits and absorbs radiation, exchanging energy with its surroundings. If the temperature of the object is high enough, the radiation may be seen- the material glows. There is a direct relation between absorption and emission. Kirchhoff's law stales that an object which absorbs radiation of a

temperature depends on the material of the emitter. We can imagine an ideal body which absorbs all radiation incident upon it. By KirehholV's law, this body would also be the most effective emitter of thermal radiation at all wavelengths. Such an ideal absorber-emitter is culled a blackbody.
Fortunately
it

is

possible

to

realize

blackbody conditions

experimentally to any degree of approximation requited. If we form our material to make a cavity with a small opening to the outside, the hole will behave as a blackbody. Radiation which
enters the hole will bounce around at the inner walls of the cavity,

Fig. 13,10 Fig. 13,9

Cavity radiation Is nearly

Good

absorbers are good

blackbody radiation.

radiators.

gradually being absorbed. Only a tiny fraction of the radiant energy will be reflected back through the hole. Viewed from the
outside, the hole
is

an excellent approximation to a blackbody.

is also a strong radiator at that platinum disk in a furnace (Kg. 13.9) at wavelength. Consider a that it receives one unit of energy thermal equilibrium. Suppose

particular wavelength strongly

the walls of a blackbody cavity are maintained at some temperature T, the interior is filled with radiation. A tiny fraction

When

leaks out of the hole.

ray leaving the hole has, in general,

per unit area per unit time and that the fraction p is reflected. Then p is the fraction absorbed, designated a. Hut if the temI

perature of the disk


as

is

to

remain constant, the disk must


it

lose
t

much energy

per second as

receives.

The

rate of emission

from the area considered must equal a. If a carbon disk is in thermal equilibrium in the same furnace, it receives the same energy per unit area per unit time as does the platinum, but it absorbs a larger fraction (1 - p') and hence must emit more, to keep T constant. Good absorbers of radiation are good emitters,
p, p',

undergone many reflections. At each, reflected energy is added to emitted energy until in the emerging (blackbody) radiation, the energy distribution depends only on the temperature of the cavity and not on the material of which its walls are made. The blackbody radiation can lie dispersed by a grating, and a bolometer or thermopile can be used to measure the energy radiated in each wavelength interval. A continuous spectrum is
found; that
Fig.
is,

radiation at

all

frequencies

is

observed.
is

The

disin
is

tribution of intensity per unit wavelength interval


13.11.

shown
is

as represented by the relative lengths of the arrows for


t,

When

the temperature

is

increased,

more energy

radiated at every frequency, and the relative increase

greater

and

'

in Fig.

13,9.

at the higher frequencies, shifting the

maximum

of the intensity

170

Looking In: Atomic and Nuclear Physics

Electromagnetic Radiation

171

distribution to lower wavelengths (Fig.

13.11a) or higher fre"


f

quencies (Fig,

13, lib).

fn fact, it leads to an "ultraviolet catastrophe" by predicting that as X becomes smaller, R\ increases without limit; the total
XT',

The area under

the blackbody distribution curve

S(f) df,

whirl] represents the total

power radiated,

is

found

i" increase as

the fourth power of the absolute temperature:

power radiated by any body is infinitely large! Wilhelm Wien assumed that cavity radiation came from molecular oscillators among which energy was distributed with respect to frequency according to a Maxwell distribution (similar
to the distribution law successfully used for molecular speeds in the kinetic theory of gases). The resulting distribution law agrees

P-eAT*
where

(13.27)

is

the radiant flux from a blackbody of surface area


is

with experimental data in the short-wavelength region of the


Intensity

at absolute temperature T. This

known

as the Stefau-Boltz-

mann law
Intensity

the constant a has the value 5.7

10" 8 watt/ (m*) (K*).

Intensity

3000 K

Planck's law

2.0

4.0

(o)
Fig. 13.11

Wavelength, microns

(6)

Frequency

Blackbody radiation

distribution: (a) intensity vs.

wavelength, with

visible region dotted, (b) intensity vs. frequency, with

Ti

<

T.

<

12
Fig.

It.

\Wgvelength, microns

13.12

Agreement of radiation formulas


(circles).

with

13.8

PLANCK'S LAW

Coblentz's experimental data

of physicists advanced theories based on classical physics to explain the distribution of energy in the continuous spectrum from a blackbody. Lord Raylcigh and Sir James Jeans
in a cavity has degrees of freedom which correspond to the frequencies of standing waves that are possible in the cavity and that the energy is divided equally among these different degrees of freedom. The resulting distribution law is

A number

spectrum, but predicts values of

I{\

which arc too low

in

the region

where
th

X7'

is

large:

assumed that radiation

= cV-V '"

(Wien)

(13.29)

Max

l'lanck also started with the

assumption that the

wallt-

of a cavity radiator are

made up

of tiny electromagnetic oscilla-

tors or resonators of molecular dimensions. He, too, used a

Maxoscil-

(Rayleigh-Jeans)

(1.3.28)

well distribution, taking e~ HlkT as the probability that


lator has energy
/.'.

an

where K is the radiancy (power per unit area) at a wavelength X and ci and c a are empirical constants. The Rayleigh-Jeans law fits the experimental data (Fig. 13.12) only for large values of

accepted the Rayleigh-Jeans calculation for the number of oscillators per unit volume in the frequency
lie

range from / to /

df.

But Planck was

led to

make two

radical

assumptions:

172
1.

Looking In: Atomic and Nuclear Physics

Electromagnetic Radiation

173

An

oscillator

can have only energies given by


(13.30)

the stopping potential V,


the collector.

is

found for which no electrons reach

E
where
c

nhv

The

chief features oT photoemissiou are


la<i

= frequency = Planck's constant (of "action") n = an integer (now called a quantum number)
k
asserts

able time

(>

10

'

sec'i

(1 ) There is no detectbetween irradiation of an emitter and


:

ejection of photoelectrons; (2) the

number

of electrons ejected

per second

is

proportions!

to the intensity of radiation, at a given

The equation
"quantized."
2.

that

the.

energy

frequency;
is

(3)

of

the

oscillator

the photoelectrons have energies ranging from

zero up to a definite

maximum, which
is

is

proportional to the freof its intensity; (4) for


vK

An

oscillator does nut radiate continuously (as expected

on

quency

of the radiation

and independent

.Maxwell's theory) but only in quanta of energy, emitted

when

each material there

a threshold frequency

below which no

an

states.

changes from one to a lower of its quantized energy (or photon) radiated has energy proportional to the frequency of the wave:
oscillator

photoelectrons are ejected.


*
Light source

The quantum
hv

K=
From

(13.31)

these assumptions, Planck derived the distribution law


2irAc
2

R*where
c

_CiX-
1
,,r,

X e*"*T
6

\r

(I'lanck)

(13.32)

= = =

speed of light
Boltzmaiui constant (Mi2" X 10" w joule/sec
Ci

Fig. 13.13

Apparatus for photoelectric

effect.

Planck's law has been written in the second form with empirical

These characteristics of photoemissiou cannot be explained

comparison with Eqs. (13.29) and (13.30). For a wide range of temperatures (300 to 2000 K) and a wide range of wavelengths (O.o to n2 ft), Planck's law represents the experimental data within per cent. It is interesting to note that
constants

and

c* for

by Maxwell's theory of electromagnetic radiation. Kinslein made the assumption that light of frequency
energy to the elections
Fit
If it is
v>
f

In
c

MM)">

can give

in he metal only in quanta of energy hv. her an electron absorbs one of these quanta, or it docs not.

despite

its initial

success the

quantum hypothesis was


in

resisted

by

Planck himself. Conservative


reconcile his

nature, he tried for years to

in

given energy hv, an electron may use an amount of energy escaping from the metal, where it has negative potential
it

"quantum

of action" (A) with classical theory.

energy, into the vacuum, where

has zero potential energy.


of the surface.

quantity

is

called the

work function

mum
13.9

kinetic energy which the electron


is

The The maxican have when it leaves

PHOTOELECTRICITY

the surface
/: *. NIEIJS

therefore

bight or other electromagnetic radiation falling on the surface of a metal (Fig. 13.13) can under certain circumstances liberate electrons from the metal. The number of electrons emitted pet

hv

w
E =
i:

(13.33)

This

is

called Ivinstein's photoelectric equation. It explains the

second can he determined hy measuring the photoelectric current. The energy distribution of the electrons can he determined by applying a retarding potential and increasing it gradually until

linear relationship

an

shown

in Fig. 13.1-1:

The

slope a

measured from the graph agrees with the value of Planck's constant A; the negative intercept b is identified with the work func-

174
lion

Looking
id

In:

Atomic and Nuclear Physics

Electromagnetic Radiation

175

of the metal.

The

intercept on the frequency axis

is

the

voltaic

cell.

Photovoltaic cells are used in photographic exposure


in solar batteries.

frequency of light that will liberate electrons from the particular metal. At this threshold frequency vt, the photon delivers just enough energy to enable the electron to get out of
the metal (with
hvo

minimum

meters and

Ek =

0):

= w
(13.33), #*.,*
is

(13.34)

From Eq.

independent of the intensity of illumi-

nation, in agreement with experiment.

There is also an internal photoelectric process, within an atom, called the Auger effect, or autoionization. An x-ray quantum may be absorbed within the same atom from which it originates, with the ejection of one of its electrons. The net effect is thai the atom adjusts from an excited level to a lower-energy level, with the emission of an electron. Finally, there is an inverse photoelectric effect in which an electron is absorbed by a solid and a photon emerges.

The term

photoelectricity includes several distinct

phenomena.

In the external photoelectric effect

(photoemission), electrons

The photoelectric effect gives strong support to Planck's hypothesis that light of frequency v can be emitted or absorbed only in packets of energy hv. The citation which accompanied the
award of the Xobel
Prize to Einstein stated that
it

*!,

was

for "his
dis-

M.

attainments in mathematical physics and especially for his covery of the law of the photoelectric effect."

13.10

THE CONTINUOUS

RAY SPECTRUM
a battery

rays are electromagnetic waves of very short wavelength,


(Fig. 13.1"))
li

about 10"" to I0~" m. In an x-ray tube

Fig.

13.14

Dependence of maximum energy of

photoelectrom on frequency.

are ejected from a solid (or liquid) surface into a surrounding vacuum. Photomultiplier tubes use this effect.

Electrons and ions


tion.

The

ionization

may he produced in a gas by ptiotoionistachambers used to detect x rays utilize this

effect.

inside a solid

Conduction electrons and positive "holes" which remain may be responsible for either photoconduction or
is

Fig,

13.15

An x-roy

tube.

a photovoltaic effect. Photoconduction

a decrease in resistivity
heats a tungsten filament

under the influence of radiation. It is used in television camera tubes and in control devices where an external battery furnishes
the electric power.
layers in the

so that

it

emits electrons.

A potential
and target
are quickly

difference of several thousand volts between cathode

('

The

photovoltaic

cell is

a device for converting

accelerates the electrons.

The fast-moving electrons

radiation into electrical power. Kadiation acting on


cell

voltage

is

two dissimilar emf in much the same way a produced when Cu and Zn plates are dipped in acid in a
gives rise to an

when they strike the metal target. Most of their converted into heat by collisions with atoms of the target. But as the electrons are decelerated, they are expected to
decelerated
is

energy

176

Looking In: Atomic and Nuclear Physics

Electromagnetic Radiation

177

according to Maxwell's electromagnetic theory. The Gorman term Itrrmxxtniltliniu is used for this "slowing-down radiation." The radiation is emitted in all directions. When one examines the beam of x rays emerging from the hole in a lead
radiate,
shield,

certain

one finds a continuous distribution of frequencies up to a maximum. This maximum frequency depends on the potential difference at which the tube is operated: v, x /AV = a
constant for a wide range of voltages. The high-frequency limit in the continuous x-ray spectrum photon is difficult to explain classically. It is easily clarified by the
hypothesis.

According to classical theory, scattered radiation should have same frequency as the incident radiation. Compton found such unmodified radiation, but in addition he found a scattered wavelength X' greater than that of the incident beam. The shift In wavelength X' - X was found to increase as the angle 8 at which the scattering was observed was increased (Fig. 13.17).
the

The

scattering of x rays with increase in wavelength

is

called the

An

electron

may

suffer

numerous decelerations as

it

encounters various atoms in the target. ICach time a photon is produced, whose energy hi> is equal to the decrease in kinetic energy A A'* of the electron. Clearly, the highest-frequency photon
that can be produced is that which results from the complete. conversion of the electron's kinetic energy into a single photon.

Since electrons arrive at the target with energy

Al".

hv mnx

AV

(13.35)

From this Duane and Hunt law, Eq. (13.35), r'h may be determined from the sharp cutoff of the x-ray intensity versus frequency curve at p k x There is good agreement with the ratio e/h
,

determined

in

other ways.
Fig.

13.17

Wavelength

shift

in

Compton
13.11

scattering of x rays.

THE COMPTON EFFECT


|<)23 in

Another even more direct confirmation of the photon hypothesis

came about
x rays to

A. H.

scattered x rays.
fall

Compton allowed a beam

Compton's explanation of properties of of monochromatic

The

on a hlock of scattering material such as carbon. in an x-ray spectrometer uses crystal and an ionization chamber instrument which (an to measure the wavelength of x rays incident on it J.
scattered radiation was examined
Spectrometer /-\

Fig.

13,16

Apparatus

for

observing

Compton

scattering of x roys.

Wavelength,

*"

178

Looking In: Atomic and Nuclear Physics


effect.

Electromagnetic Radiation

179

Campion,

The. plioton hypothesis provides a straightforward


of a

Example. What
in

is

the change
(6

in

wavelength
180)?
3t

<>r

x rays

Com|ii on-scattered

explanation.

the

backward direction

We describe the Compton scattering as an elastic collision


photon with a free electron which
(Fig.
is

at rest before the collision

X'

-X

=
9.1

6.625

10

joule sec

10

3l

kg (3.0

(1

cos 180)

IIP in

sci")

13.18). We ascribe to the photon the "equivalent mass" (Chap. 14), and to this mass we attribute linear momentum hvfe* The conservation of momentum may be stated in two hv/c.
13.12
Photon

0.048

IO" 1 *

m =

0.0484

WAVE-PARTICLE DUALITY: PROBABILITY

*
Fig. 13.18

Before

After
Electron

Compton

scattering of a photon.

have discussed two theories of electromagnetic radiation. classical theory says iliat radiant energy flows continuously as a wave. The wave theory gives a satisfying explanation of interference, diffract ion. and polnrixa! ion experiments. The quantum theory says that radiant energy is exchanged in quanta of amount Ac, whose value depends on the frequency c of the light. This photon theory gives a satisfactory interpretation of many experiments in atomic physics (blackbody radiation, photoelectric effect, the frequency limit in a continuous x-ray spectrum,

We

The

the
equations, since

Compton

effect,

and the

line

spectra

characteristic

of

momentum
kv

is

a vector quantity and the law of

elements).

conservation applies to each of the components:

In some ways these two theories are mutually contradictory.

X component: y component:

=
=
hv
c

cos 8
.

+
,

me

cos

(13.30)

The wave theory says that the photoelectric effect should show a time lag when the light source has a very low intensity. The photon theory when used to explain a single-slit diffraction pattern

hv'

sin $

mv sin

4>

(13.37)

would have to assert that these


its

particles arriving at certain

points on the screen would "cancel" each other. (How?) Although

each theory works well for

own

experiments, something has

where

v'

is

the frequency of the scattered photon and


of the recoil electron.

me

is

the

to "give"

when we

try to put the

momentum
hv

A
(13.38)

resolution of this tlillieulty

two theories together. was suggested by a novel idea

Conservation of energy requires that

proposed by Louis de Broglie,


particles

in his 1'h.D. thesis in 1924.

From
all

hv' 4-

A*
final kinetic

consideration of relativity theory (Chap. 14), he deduced that

must have a wave

nature, just as light has a

wave
(or

energy of the electron. Solution of these three equations provides an expression for the wavelength

where
shift
X'

is

the

nature.

The

intensity of the particle

wave

at

any given point

the square of the


to

wave amplitude)
for the

is

interpreted as proportional

the probability of finding the particle at that point.

The
is

= -mr

(1

de Broglie relationship
cos 9)
(13.39)

wavelength X of a matter wave

*
(13.40)

which agrees with experimental data. The unmodified radiation is interpreted as due to photons scattered by electrons strongly

V
where p
is

the

momentum

(mv) of the particle and h

is

Planck's

bound

in

atoms.

constant.

rr *
1

180

Looking In: Atomic and Nuclear Physics

Electromagnetic Radiation

181

exploration of wave-particle duality was continued in by Max Horn. as follows. Kuergy is not distributed continuM)28 ously throughout an electromagnetic wave: the energy is carried by the photons. The intensity of the wave (which the classical theory defines as energy flow) at a point in space is really a measure of the probability of finding a photon there. The classical wave has become a sort of guide for the individual quanta of energy. We have resolved the wave-particle dilemma, but at the cost of admitting that laws of chance govern the motion of micro-

The

by

classical

theory

is

shown by the dashed


is

line.

The

distribution

actually observed (solid line)


interference of the
tie

that

predicted by considering

Hroglie waves.

Now

consider one electron

shot at a time. According to this wave picture, each electron is represented by a single wave packet which divides equally be-

tween the two

slits.

Vet

if

whole particle or no particle. It is intriguing to try to devise an experiment that would reveal the slit used by individual electrons, without destroying the interference pattern. No one has succeeded. If a
half an electron:
find cither a

we never observe

we place a we

particle detector at

slii

.1,

detector

is

placed at A, the interference pattern smooths out; the

classical result is obtained.

13.13

THE UNCERTAINTY PRINCIPLE


of

consequence

quantum theory

is

that one cannot determine


velocity

simultaneously the exact position and

(or

momentum)

Fig. 13.21

Supermicroscope.

CDBEAEBDC
Fig. 13.19

o/vw
slit.

Diffraction at a single

Fig. 13.20

Double-slit diffraction.

scopic particles. If
(Fig.

we photograph a
.4,
/.'.

single-slit diffraction

pattern

13,19), the relative intensities tell us that

struck the plate in the region

a fair

many photons number in li, some in C


t

Very few hit near I) or experiment with one photon.


etc.

probability of hitting near


little

.1.

Suppose, now, we perforin the We can predict that it has a high a fair chance for li. less for ('. very

i) or K, Hut prediel to we 08JQ which point the photon will actually go. Consider an experiment in which a beam of electrons falls on two slits (Fig. 13.20). The electron distribution at I 1 predicted

chance

of hitting near

particle. As an example, assume that the exact momentum a particle is known. Then it has a definite wavelength X = h/p and is a continuous plane wave of uniform "intensity." It is equally probable to find the particle anywhere in space. At the other extreme, assume that we have located the particle within a very small region of space. Then its wave function is a short packet that does not have any unique X. Hence the momentum is fuzzy. The uncertainty principle predicts that in general we cannot make a measurement on a system without disturbing it. for example, suppose we try to "view" an electron with an (imaginary) supermicroscope .1/ (Fig. 13.21) to determine its position x and momentum p. We may borrow an expression from optics which says that the smallest displacement A.v the instrument can

of of

any

182

Looking In: Atomic and Nuclear Physics


Electromagnetic Radiation

183

defect depends on the wavelength of the light and the half-angle a subtended by the objective lens: Ax = X/(a sin a). We "view" the elect ion by light which (-liters the microscope anywhere within angle 'la. This radiation, scattered by the electron, makes a con-

tore of small particles, IT the


think, there
is

quantum theory

is

correct, as

we

no hope of understanding the elementary structure of matter (atomic and nuclear physics) from the viewpoint of
classical physics. In

tribution to the electron's

momentum which

is

unknown by

of

quantum
is

there

Apz

sin

the following chapters we shall use the ideas theory. It will be interesting to see, however, that a region between macroscopic and microscopic physics
classical

^ sin a

where the laws of

and quantum physics smoothly overlap

(correspondence principle).

we write Ax as the uncertainly in position of the electron and Ap* as the uncertainty in its momentum, combining the last two
If

equations gives
1

Ax Ap x =

/ X \ (k \sm a/ \\
I

-.

:-

sin

\
/
J

h a

(13.41]

The

secret of education lies in respecting the pupil.

R.

which shows that as we increase the precision of our measurement of 3% the value of p becomes subject to greater uncertainty. (The foregoing is offered merely to amplify the statement that wc cannot make a measurement on a system without disturbing it. The numerical value of a depends on the criterion used for resolving
power.)

W. Emerson

Werner Ileisenberg formulated the uncertainty principle in 1927 showing that from Sehrodinger's equation (Chap. Hi) /i/4ir is the lower limit of the product of simultaneously measured
value of a particle's position and

The most

essential characteristic of scientific technic

is

that

it

proceeds from

experiment, not from tradition.

Bertrand Russell

momentum:
(\:i.m

Ax Ap

>

-r-

Mere Ar and

A/; are defined as

vm- deviations. There

is

an uncerThe most brilliant discoveries in theoretical physics are not new laws, but of terms in which the law can be discovered.
discoveries of

tainty relation only between certain pairs of variables, those

which are "canonically conjugate variables."* There are uncertainty relations, for instance, between position and momentum (discussed above), angular momentum and angle, and energy

Michael Roberts and E. R,

Thomas

and

time.

We
from

have seen that quantum theory

is

significantly different

classical

theory in dealing with the interactions

and struccinq).
I>,

* See Condon and Odtshaw (wis.), "Handbook of Physics," McGraw-Hill Book Company, Inc., New York, 19oX.

Relativity

Wonderland

185

tivistic

gives into the binding energy of our cbier nuclei and the liberation of nuclear energy will he simulabout says relativity We shall look, also, at what

mechanics.

The

insight

it

interest.

14
Relativity

voyagers in taneity of events, time dilatation, and the aging of


spaceships.

14.1

NEWTONIAN RELATIVITY

Wonderland

transIn elementary experiments in mechanics we recognize that other relative to motion as lator? motion can be measured only

Measurematerial bodies, such as the workbench or the earth. time. and distance both ment of a speed involves measurement of
S'

The supreme task

of the physicist is

to arrive at those universal

elemenvt

tary laws from which the

cosmos can
is

be built up by pure deduction. There

no

logical

path to these laws; only


resting

intuition,

on

sympathetic

understanding
reach them.

of

experience,

can
Fig.
in

A. Einstein

Reference system S' moves with constant velocity v 1 4.1 x direction relative to reference system S.

Up

to

now we have perhaps

intuitively regarded time as a unique

variable, quite distinct from, say, space, energy, or the* behavior


of material things. \Ye might agree with
true,

Relativity and quantum mechanics are two great theories of twentieth-century physics which have modified in remarkable ways our ideas of the physical universe. For bodies traveling at speeds close to the speed of light, Newtonian mechanics is replaced

and mathematical time, of itself, Hows uniformly on, without regard to anything external." It these is helpful to formulate the kind of relativity implied by ideas for later comparison with the new relativity. Consider a material reference body and some sort of timing
device (the rotating earth, or a crystal oscillator) to constitute
a space-time system of reference for making measurements to locate particles or to describe events. Now suppose a second

Newton that "Absolute, and by its own nature.

by rclativistic mechanics. The relativity theory of the physical meaning of space and time makes some simple predictions of great importance. (I) The mass of a particle is shown to be variable, depending on the speed of the particle; (2) it is impossible for any particle to have a speed greater than the speed of lighl (3) mass and energy are interconvertible. In this chapter we shall consider the evidence which leads to the formulation of rela184

system of reference S'


i

be in uniform motion with respect to the first reference system >S\ along the common line of heir x axes. Let the velocity of S' relative to S be v. Let us agree ito reckon time from the instant at which the two origins of coord
(Fig. 14.1) to

186

Looking In: Atomic and Nuclear Physics


Relativity

Wonderland

187

momentarily coincide. At any later time, ordinates of 0' measured in system S will be x = vt, z = 0. An event which occurs at coordinates x,i/,z and in system A' will, according to Xcwlon, have coordinates in S' given by
nates
0'

and

the coy

0,
/

time

system

will arrive at E in phase and produce a bright field, by conby moving suuetive interference. As distance .1.1/ is increased X mirror .1/, the optical path for ray 1 is lengthened by X/2, and destructive interference of rays 1 and 2 at li gives a dark field.

and 2

X =
v*

(14.1)
t

3-w

14.2

THE AETHER

properties of light were, demonstrated by Young, and others during the first part of the nineteenth century and were explained in Maxwell's brilliant theory of electromagnetic radiation (Chap. 13), It was difficult for scientists of the nineteenth century, as for us, to conceive of a wave motion without a material medium to transmit its vibrations. So they
Fresnel,

The wave

c\ r
~G\
Source
Fig,

medium called the aether for the propagation of light. The aether was thought to pervade all space, as well as transparent material bodies. The assumed existence of the aether suginvented a
gested check,
(c

14,2

Michelson's nf erf ero meter.


i

two interesting consequences worthy of experimental (I) Light waves should travel with a definite speed

aether
rial

m see in "empty" space) with respect to the Then the apparent speed of light relative to a matebody moving through the aether should be different from c
3.0

10"

Mirrors

.1/

and
field

.1/'

are set nearly but not quite perpendicular to

itself.

produce a

crossed by alternate bright and dark interference

fringes (Fig. 14.8).

These are counted as they move past a

refer-

and should depend on the speed of the body. (2) An "absolute" velocity of the earth or any other body should be ascertainable from measurements on tight waves transmitted through the
aether.

ence mark R, For each fringe that passes the mark, the optical path has changed by one wavelength. This change might he pro-

duced by moving .1/ a half wavelength. However, the change might also he produced by a change in the speed of light in beam (on the substitution, for example, of a gas of different index of refraction for the air in that one beam).
I

14.3

MICHELSON'S INTERFEROMETER
to detect the motion of the earth relative would require very sensitive apparatus, for the orbiI

An experiment designed
to the aether
tal

speed of

he earth

is

only about
in

III

'

the speed of the light

signals that would be used

the measurement.

With

this probFig. 14.3

lem in mind, Miehelson devised an interferometer, an instrument in which interference patterns produced by two light beams are
used to reveal differences
in

Fringes and a reference mark.

the optical paths of the beams.

When

the optical paths (Fig. 14.2)

happen to he equal, beams

188

Looking In: Atomic and Nuclear Physics

Relativity

Wonderland

189

14.4

THE MICHELSON -MORLEY EXPERIMENT

Assume that the earth travels through stationary aether with a and that light has a speed c in the aether. Consider a speed Mieheison interferometer arranged so that one of its two equal
i>

Waves which are in phase when they reach A from the monochromatic source will differ in phase when they return to .4 after reflection, because of the time difference:
Ai

ft

h=

si-

(14. o

arms

is

parallel to the earth's velocity {Fig. 14.4).

required for the light

AM' A
.1/

will

Then the. times beams to travel the distances A and be unequal. The speed of a beam traveling from .1 to

AM

If

the interferometer

is

rotated 90, paths

and 2

will

have

is c

their roles interchanged

and the

! total retardation will be 2sp

t"

relative to the interferometer.

On

the return from

.1/

The number

of fringes passing the reference

mark should be
(14.6)

M'
i

N=

path difference wavelength

_cA/ =
X

c2st>*

2siP
c
2

Xc*

A
i

4W
Fig.

M
n

HI
u

To estimate the magnitude of fringe shift to be expected, we may assume that the earth's velocity through the aether is the same as its orbital velocity, about HO km sec. By using multiple
reflections, .Mieheison

and Morley attained an


light of

effective path s of

10

(Fig. 14.5).

For

wavelength 5,000

A we

should then

estimate a
14.4
Light

maximum
2

fringe shift of

poths

in

moving interferometer and velocity

vector diagram.

N_ ~
beam
round
relative to the interferometer
trip
is

10m(3

lOWsec)'

OTX

10m/)(5.0

10- T m)
is

U *

f " lge lr

4 U4
(

' J ?)

to A, the speed of the


c

v.

The time
c

for the

AM A

is

thus
(14.2)

fringe shift of this

amount

readily detectable with the

2w

apparatus. It should then be possible to measure the fringe shift and from it compute the velocity of the earth relative to the
aether, that
is,

the absolute velocity of the earth.

Since

is

small compared

with

c,

we may use the binomial

theorem to obtain the approximation

Mieheison and Morley found no fringe shift when the interferometer was rotated in a pool of mercury. Itappeared that optical experiments cannot detect motion of the
Surprisingly.

rye

(1-U)
c

c*

earth relative to the aether.

A wave front leaving A toward mirror .1/' will be returned, according to Huygen's principle, but only after A has moved to a new position .]'. The component of the velocity of light in the direction perpendicular to the motion of the interferometer is 1 v i The time for the round trip AM' A is

Mieheison and Morley reported their results in 1887. No subsequent experimental evidence contradicts them. Some lingering doubts were laid to rest in a review article published in the
Reviews of Modern Physics (pages 107- 178) in 1955. Several attempted explanations for the apparent impossibility of measuring the earth's absolute motion failed to gain acceptance when they either did violence to established theory, disagreed
with

VV

2s

!n /; 2/

2* /

vV

v*

Vi

+ 1+3^ 2
ri

Iff*

)
(14,1)

known astronomical

data, or introduced too

many

special

hypotheses.

Relativity

Wonderland

191

14.5

POSTULATES OF THE SPECIAL THEORY OF RELATIVITY

Consider several physicists in a completely enclosed elevator or railroad car, moving with constant velocity relative to earth. Could these people detect and measure the velocity of their enclosure from observations made inside, with pendulum, spring
balance, etc?

Proceeding from considerations such as these, Henri Poincard it is in the period 1 SiM) to 1904 developed the hypothesis that impossible to determine absolute motions of a body or of a reference system by any dynamical, electromagnetic, or optical means. Measurement of the velocity of bodies relative to a stationary
net Iter

seemed to

Iks

for determination of "absolute" motion.

the best device classical physics could offer The negative result of

the Michelson-Morley experiment was interpreted by Einstein as indicating that only relative velocities can be measured. Consequently, the general laws of physics must be independent of the velocity of the particular reference system of coordinates used to
state them, otherwise
lute
it

would be possible to ascribe some abso-

meaning

to different velocities.

was limited at a constant moving systems to consideration of reference based his Einstein {Fig. 14.1). other velocity with respect to each

The

special or restricted relativity theory of 1905

theory on two postulates:


1.

The laws

of physical

phenomena are the same when

stated in

m
2.
Fig. 14,5

terms of either of two reference systems moving at constant velocity relative to each other {and can involve no reference to motion through an aether).

The
and

is

velocity of light in free space is the same for all observers independent of the velocity of the light source relative

Michelson interferometer designed to detect "absolute motion" of

to the observer,

the earth, (o) Interferometer


to

was mounted on a
(b)

damp vibrations and to permit rotation, an effective path length of 10 m.

ond floated in mercury Multiple reflection of beams gave


stone,

{The "general" theory of relativity, 9 Hi, is Einstein's theory of gravitation and will not be considered here.) Suppose person A. at rest in a laboratory, assigns to every event which he observes a position (j-.i/a) relative to a particular origin fixed in his laboratory and a time as indicated by a clock at rest in his laboratory. Now let person B move through A's
1

190

laboratory with speed u

in

A's positive x direction. Let person

192

Looking In: Atomic and Nuclear Physics

Relativity

Wonderland

193

measure positions relative to an origin moving with him and

transport energy from one point to another with a speed exceeding


the speed of
li<iht.

times with a clock (just like A's clock) also moving with him. Then to each event B will assign a position (x',y',z') and a time I'. Assume that the clocks are synchronized to read I = (' = when the (x'y'z') axis momentarily coincides with the (xi/z) axis. The

Several relations of particular interest will now be discussed to illustrate the meaning of space and time variables.

which connect the distance and time intervals between two events as measured from the two inertial reference frames are
relations

14.6

VELOCITIES NEVER ADD TO

MORE THAN

x V
z

= =

x' +
y'
z'

lit'

==

X'

=
!J

ut

Suppose that our two observers in coordinate systems S and S' both observe an object which Hies past in the x direct ion. Observer

U'

Z' = _

B measures the speed of the object


If

relative to

him

as

v'

dx'/dt'.

we

express

v'

in terms of the coordinates of the laboratory

t_ (u/c*)x

observer A,
(14.8)
dt'

we

find

Vi -

1*

1/**

d[(x
d[[t

- mQ / V'1 - u */c*]
(*/c*)*]/Vl

dx
di

These transformation equations were developed by Voigt


(1887) and Lorentz (1904) in exploring the aether hypothesis. But Einstein showed that the transformations satisfied
tivity hypothesis that the speed of light will be the
his relain

Vc*l

-udl ~ (*/<&*
(l4!

-r^ws

same

each

coordinate system.
Example. Show that
systems.
at J = and moves in the positive x direction. It will arrive ill the point x = A' at the time X/e, time its speed through the laboratory is Person B will observe the light to arrive at the point
light starts
light

where in the last step numerator and denominator were divided hy dt and dx/dt = was written for the speed of the object in the laboratory. Thus we have
V

has speed

c in

both the
0,

8 and

S' coordinate

Suppose that the

from x

=
1

u
1

0, t

or

=
1

'

not, as

uv/c

+
v'

(14.10)

uv'/c*
is

The speed

relative to the laboratory

we might have

,-..

X - u(X/c) Vl - u7c*
X/e

expected, exactly equal to the speed u of B relative to the laboratory.

relative to

plus the speed

at the time
,

- (uM )X Vl - m*/c*
of light in the S' coordinate system
is

Example. While observer B is moving through the laboratory with speed u = 0.90c, a flying object passes him with a speed which he measures as v' = 0.90c. What is the speed of the flying object relative to the laboratory?

The speed V =
x' -7
I'

=
1

V'

+
w'/c*
1

0.90r

0.90c
! 1

I.SOc

thus

(0.90c) (0.90c)/c

0.994c

0.81

X/e

X - (u/c)X - (u/c*)X

In other words, if a car were traveling at speed 0.90c, you would have to drive at a speed of only 0.994c to pass it with a relative speed of 0.90r!

form under Lorentz transformations. The basic physical assumption of relativity is that no mechanical or electromagnetic influence can

In a mathematical sense, the principle of relativity equations of physical phenomena must be invariant in

is

that the

14.7

WHAT DOES "SIMULTANEOUS" MEAN?

Einstein pointed out by the following railroad story that man cannot assume that his sense of "now" applies to all parts of the

194

Looking In: Atomic and Nuclear Physics


Relativity

Wonderland

195

pictured a straight section of track with an observe? seated on an embankment beside it. During a thunderstorm, two lightning bolts strike the track simultaneously, at points Xi and
.):.

universe.

He

The

special theory of relativity predicts the

same contraction

Kiustein asks:

What do we mean by "simultaneously"?

but ascribes it to the relative motion of the body and the observer. Consider a material object in coordinate system S' whose surface may be defined by the relation 4>{x' ,tf ,z') = 0. Then, by the Lorentz transformation, the form of the. surface as viewed in
coordinate system

is

xi
Fig. 14.6

A
My
time
is

not necessarily your time.

Assume that the observer is seated midway between r, and Assume that he has arranged mirrors so he can see x and z the same time without moving his eyes. Then If the reflections
t

described
.<-._>,

In particular, suppose that a spherical surface of radius a is 1 2 {*')" ' a" = <> Tbfe in system S' by (Y) Cv')

at
of

appears in system S to be a moving ellipsoid

the lightning flashes are seen in the mirrors at precisely the same instant, the flashes may be regarded as simultaneous, by observer A.

r*J + K + 3-1
(a

assume that a train speeds along the track and that observer B on the train sits in an observation dome, with an arrangement of mirrors for viewing points xx and x->. It happens
that observer
to

Now

whose semiaxes are

\/\

u- c-,a.a).

The

surface undergoes

contraction in the direction of

motion

in the ratio

y/\

u s /c 2

1.

B
if

finds himself directly opposite

strikes the rails at

and

x-,.

A when lightning Will the flashes appear simultaneous


moving from
x-,

14.9

TIME DILATATION: THE CLOCK PARADOX

B? No,

for

his train

is

toward

.c,,

then the

.10 will be reflected in his mirrors a fraction of a second than the flash in .r,. (In the limiting case with a train traveling at speed e, B would never see light from x.) Whatever the speed of the train, the observer B on it will always say that the

flash at

later

Consider now ihreflVel of relative motion on a flock. Two events occur at a point in coordinate system .S": one at time t\, the other T <> an observer in S these events take place at at a later time

different points in space,

(.ri,//,s)

and

Oj.(/,z), as well as at differ-

lightning Hash ahead of

ent times, such that {x transformations

xi)

u(t t

h).

Prom the Lorentz

In generalizing,

him has struck the track first. we are forced to admit that two events which
tt

occur at different places may be simultaneous for one observer and not simultaneous for another. We cannot assume that a single time scale (( = (') can be used with any and all coordinate systems.

h =
the same, but &t

Thus

the sequence in time of the two events

is

appears longer for the observer in S than for the observer in .S". This is interpreted as meaning that a moving clock appears to

14.8

THE FITZGERALD-LORENTZ CONTRACTION

run at a slower rate than does an identical clock at


ratio

rest, in

the

To

Vl -

7c-:l.

explain the null result of the Michelson-Morley experiment, Fitzgerald in 1893 arbitrarily assumed a contraction of the arm of

The imminence

of space travel has revived interest in the

"clock paradox" or "twin paradox."

One

of

two

identical twins

the interferometer in the direction of motion of the apparatus.

leaves his brother on earth and voyages at high speed into distant space. On his return, he finds that his brother has grown

196

Looking In: Atomic and Nuclear Physics

Relativity

Wonderland

197

much
Also,
in

Superficially, this
it

older than he, because of time dilatation in the spaceship. is a paradox, for it challenges "common sense."

the

same

light signal travels the larger distance 2D'. If observer

describing physical events

seems to contradict the assertion of special relativity that all observers are equivalent; none

effect

has a preferred or absolute reference system. The aging or clock seems to provide a way of distinguishing among observers.
in

up a similar experiment in his coordinate system S', his light signals would complete their round trips in shorter times than noted by observer A. The discrepancies arise because the two observers do not agree on which of two distant events {completion of the nth round trip by either light signal) takes place
set
first.

But, relativity asserts the equivalence of observers

inertial

systems, and since one of the twins accelerated at the start of his space trip and again when he altered course to return, he did not

Now
is

let

observer

B suddenly

reverse his velocity (u[).

He

view

his brother

the trip. So there

from the same is no paradox.

inertial

system before and after


stay-at-home

The intriguing question remains: Did the brother grow older faster? Yes. In his 190") paper
trodynamics of Moving Bodies," Einstein wrote,
If

"On the

Elec-

(He accelerated.) His notions of simultaneity have changed. Observer A sees B coming toward him, with B's light signals arriving slower than his own. When they meet, A's signals have completed a larger number of LM L circuits than have B's signals. Observer A has aged more than B.
in

now

a different Lorentz frame.

at the points

A and B

there arc

ho stationary

clocks which,

viewed by a stationary observer, arc synchronous, and if the clock at A is moved with the velocity v along the line AB to B, then on its arrival at B the (.wo clocks no longer synchronize, but the clock moved from A to B lags behind the other which has remained at B by tv 3 /2c- (up to magnitudes of fourth and higher orders), ( being the time required for the journey from A to B. It is at once apparent that this result still holds if the clock moves from A to B in any polygonal line, and also when the points A and B
coincide.

Example. What, will he the difference in he rates of two identical one of which is on a spaceship moving at 300 mi sec relative u> the other?
I

clocks,

300 mi/sec

5.25

10

s
-

m/scc

3.0

10 a m/sec

Relative change

in rate

f.

u*

f,

S^iTx

10"

10"

=
Bergman n has suggested
effect,

0.002 per cent, approx.

the following elucidation of the clock

tig.

1.7.

9"-^=
Fig. 14,7

Experimental detection of time dilatation was achieved by Ives and Stilwell (1938) on viewing the spectral lines of hydrogen atoms which were given a high speed directed away from the spec-

I"

An arrangement was used to distinguish relativity from Doppler effects. Light from the atoms fell on the spectrograph slit directly, and also after reflection in a mirror set
troscope.
effects

Clock paradox.

at some distance and normal to the velocity of the atoms. Owing to the Doppler effect, each spectrum line was split into two frequencies.

Then

light

from hydrogen atoms at rest was viewed

arranges for periodic light signals to go from .1/ and back (a kind of optical clock). Light travels a distance 2/) for each L circuit. Observer B is moving

Observer

lamp L to mirror

with the same spectrograph. This gave lines slightly displaced, in frequency, from the middle, of the Doppler pairs, in amount predicted by relativity,

LM

with constant speed u at right angles to the

line

LM. For

him,

.Measurements of the lifetimes of mesons have been used to cheek relativity predictions. The mean life of fi mesons (about

Relativity

Wonderland

199

198
'2

Looking In: Atomic and Nuclear Physics

Table
I

14.1

Date on electrons
Energy, ev
ffl

10"* sec) has been found to depend on

heir speed roughly

fllfl

8R,

X10

weber/m

in (lie

way

predicted by relativity.
0.

14.10

MASS AND ENERGY


results of relativity theory
(1) tlie variation of the

Two
in

which are of especial importance mass of a particle with its speed and (2) the equivalence of mass and energy. Experiments have been performed, first by Bucherer in 1909, deflection by a magnetic field of electrons whose speeds the on

atomic physics are

are not small compared with the speed of light. The acceleration may be determined from the radius of curvature of the path

v*/R.

The

force producing this acceleration

side thrust on the electron /

Bev.

It is

is the magnetic found that for high-

0,0100 0.0200 0.0500 0.100 0.200 0.500 0.600 0.700 0.800 0.900 0.990

25.54 102.2 638.5


2,575 10,530

79,030 127,700

204,300 340,500 661,000 3,110,000

1.00000 1.00005 1.00020 1.00125 1 .00504 1 .02062 1.1547 1.25000 1.4002 1.6666 2.2941 7.0888

17.0

34.06 85.0
171.3

347.8 983.6
1,278 1,669

2,272 3,517
11,960

speed electrons Newton's law in the form/ = ma is not satisfied. But Newton's law written in the form / = d(mv)/dt is satisfied,
provided we assume
its

The kinetic energy of an object having speed energy required to accelerate it from rest to the

r is

equal to the

final

speed

v.

that the mass

of the particle depends on

Eh -

//-'(cos $)

ds

= jT dx
in

(14.13)

speed. It

has mass

mu

found necessary to assume that a particle which when at rest has a mass
is

But now we must use

place of/

ma

for

Xewtou's second law,

Fm=
y/\
m-o

d
dt

me
y/l

(14.11)
i.'Ve*

B */c

givmg
v.

when moving with speed


mass.

The quantity
is

wio is called

the rest

[* ft- J dt
This

g_
y/\

When

m
c,

dX
J3

= m

r*

f JO

vd(

VVl -

^=) W/
(14.14)
(14.ir>)

m-u.

accepted in relativity theory as requisite for the conservation of momentum, which remains a basic principle of mechanics. In order to have the total momentum of an isolated system remain constant, the momentum of a
Variation of mass with speed

may

be integrated by parts using the standard form

/ dv
to obtain

uv

$v

du

panicle

is

delined as
Met)

ft = ffloiM
(14.12)

7=
muc 2

p = mv =

ft =

ic 2

Vl 1

Ve*
for various ratios of v/c the kinetic
,

Table

4.

shows

energy of

an electron, the ratio vi/m

and the product BR, from which one

may get the radius R of the path in a magnetic induction B of given value. Looking at the table, one might say that in problem solving to slide-rule accuracy, one can neglect relativity variation he speed of light. of mass for bodies having speeds less than 0.
1

This expression replaces the classical formula hn^ for kinetic energy when v is comparable with c. The equation for kinetic energy, Kk = (m m.n}c' says that when we speed up a particle, the increase in energy is proportional to the increase in mass of the particle:
i
,

&S =

c-(Am)

(14.10)

200

Looking In: Atomic and Nuclear Physics

Relativity

Wonderland

201

We

can identify

c-

times the relativist ie mass of the particle with


of the particle:

the total energy

K =

E = mc * = A*
Total energy
Kinstc.in's

Woc 2

(14.17)

which of course include electrons. We justify this procedure the following facts: (1) If a nuclear reaction is written in terms by symbols for the corresponding atoms, the number of elecof the
Mx..\

kinetic energy
relation
IC

rest
%

energy
states that
tells

famous

= mc

mass and
us
tiie

energy are different aspects of the same thing. It at which one may he converted into the other.
Example. Find the energy equivalent of
substance).
1

rate

gm
= =

number of The minute changes in mass which may accompany the formation of an atom from its ion and electron(s) is negligible. (3) The mass data from mass spectrograph experiments are always tabulated in terms of neutral atoms (e.g., Na) even though deflection measurements must be made on
trons on one side of the equation generally cancels the
electrons on the other side. (2)

of coal (or

any other

ions

(e.g.,

Na ++ ).

It

is

to avoid the trouble of specifying each time

the degree of ionization that the experimenter adds to his experi2

E = me =
Only a liny
of
I

0.001 kg (3.0

10* m/sec,} 1

9 X 10 13 joules 25,000 niogawutt-lir

mental value for the mass of the ion the proper number of electron masses and reports as the isotope mass the* computed mass of the
neutral atom.

Km
1

than takes place, but

fraction of this amount of energy is released in the burning of coal: tin- combustion products have a mass only sJightly less Kin. In nuclear reactors, a somewhat larger percentage conversion
it is still

The binding energy


Binding energy _ Xucleon

per nucleoli

is

defined as the binding

a small fraction.

energy divided by the number of nuclear particles:

Am
.1

<-

(14.19)
is

14.11

NUCLEAR BINDING ENERGY


It
is

this value

which

significant in

comparing the

stability of

Mass spectrograph measurements show that the mass of any stable isotope is less than the sum of the masses of its constituent protons, neutrons, and electrons. Kinsfein's mass-energy relation
suggests thai the mass discrepancy might account for the energy

two

different isotopes.

14.12

RELATIVITY AND SPACE TRAVEL


for

needed to hold a nucleus together, against the dispersive forces exerted by the protons on each other owing to their positive
charges.

Rockets

space exploration require highly efficient sources of

thrust and large amounts of electric power. These requirements

suggest nuclear power sources. In this sense, the mass-energy


.elation of relativity
is

The mass of the constituent particles for nucleus zX. A is the sum of Z proton masses and (A-Z) neutron masses. The mass
defect Ant
is

important to space travel. But other pre-

dictions of relativity, such as time dilatation, are probably not


significant to space travel.

then calculated from

Am =
where

Zm.fi

(A

Z)m

z,A

(14.18)

If

the

initial

we could burn nuclear fuel so efficiently that one-tenth of mass of the spaceship were converted into kinetic

ma =
m
,

1.00814o amu, mass of the hydrogen atom


1.00898b'

energy, the

Mx
From
to
Oil
I

= =

amu, mass

of the neutron

A/i

mass of the neutral atom of atomic number Z and and atomic mass number .1 = (Awi)c 3 one can calculate that I amu is equivalent
(million electron volts).
is

final speed would be less than 0.5c. This would give a very small (0.14) time dilatation hardly enough to allow one generation of voyagers to reach destinations outside the solar system.

Mev

Binding energy
the equation above

primarily a property of the nucleus. Yet in


for neutral

PROBLEMS
1.

we have used data

atoms

>u

and

An atom moving

at a

speed of

1.0

10"

sec ejects an electron

in the forward direction with a relative speed of 2.0

10" m/scc. Find

202

Looking In: Atomic and Nuclear Physics

the electron's speed as seen by an observer at rest (a) using a Newtonian transformation and (6) using a I.orentz transformation.
Arts, (o) 3.0 X 10* m/sec, (6) 2.7 X 10 s m/sec Find the length of a meter stick when it is moving at a speed 0.90c relative to the observer. Consider the cases when the stick is oriented () parallel and (6) perpendicular to its direction of motion. Arts. () 18.5 em, (b) 10(1 cm 3. What speed will an electron have to acquire for its relativity Ans. 2.5 X 10 K m/sec mass to be twice its resi mass? 1. What is (he energy equivalent of the mass of an electron? Ans. 0,51 Mot 5. What is the radius of curvature of the path of an electron whose kinetic energy is 20 Mev when moving perpendicular to a magnetic Attn. 0.6S m induction of 0. 10 weber/rn-? h. Imagine that you are moving with a speed |c past a man who picks up a watch and then sets it down. If you observe thai be held the wmIcIi for (>,0 sec, how long does he think be held it? {Hint: You want Ans. 4.0 sec It U when you know t' t l\.) 7. From the mass-energy relation, calculate the energy released in the reaction ,H= ,H* tHe*. (Data: ,H = 2.014743 amu, Mr* = 4.003874 amu) Ans. 24 Mev 8. A meson has a lifetime / = 1.0 X 10~*see before it decays. Find Ans. 300 m how far a meson with = 0.09c can travel. 9. Find the energy liberated when an electron and a positron Ans. 1.02 Mev annihilate. 10. If one uses the nonrehitivistic formula E,. = },m,r~. does one overestimate nr underestimate the kinetic energy of a particle of rest mass io and speed vl

2,

15
Hydrogen Atom Bohr Model

...
ing

for the

value of his study of the struc-

ture of

atoms and of the radiation emanatNobel


Prize citation

from them.
1922

for Niels Bohr,

t>

By
the

1011,

two
J.

rival pictures of the structure of

an atom had
of

evolved. J.

Thomson suggested a "currant pudding" model

which the positive charge was spread throughout a spherical volume of radius about 10 -ll> m, with electrons vibrating about fixed points within this sphere. Ernest Rutherford suggested a nuclear model of the atom in which the positive charge and almost the whole mass were concentrated in a very tiny nucleus; the electrons roamed through the rest of the atom, out to a radius of about 10~ 10 m. In crucial experiments, II. Geiger and E. Marsden probed the atoms in thin metallic foils with fast (" sV c) a particles and showed that the observed deflections could be explained by the intense electric field near the center of a nuclear atom. Building on Rutherford's nuclear picture and using Planck's quantum hypothesis, X. Bohr fashioned a model of the hydrogen atom which explained its characteristic line
iu

atom

203

204

Looking

In:

Atomic and Nuclear Physics


of

Hydrogen Atom Bohr Model

205

spectrum and correlated this with electrical measurements excitation potentials and the ionization energy.

deflection cannot result

from several successive


if

collisions with

electrons.

But, Rutherford reasoned,


of the

all

the positive charge

15.1

NUCLEAR ATOM REVEALED BY ALPHA SCATTERING

a particles are helium ions (He ++ ) and are emitted spontaneously by some radioactive substances. In the Geiger and Marsden apparatus (Fig. 15.1), a particles are directed against a thin

mass of an atom are concentrated in a very small a particle can come very close to a large amount of charge all at once, and it will experience a large deflecting force. Further, since the mass of the deflecting nucleus is greater than that of the a particle, backscattering is possible. Rutherford derived an equation for a scattering based on the assumptions that the nucleus and a particle behave as point

and most

nucleus, then the

Fig.

15.2

Deflection

of

particles

by

nuclear-made!

W^
Incident

atoms.

Fig.

15.1

Apparatus for investigating


fi,

rt

particle

scattering, showing:

a
positive charges, that sion

particles

Target

radioactive substance

the source of

particles, thin foil

and microscope M. a I, strike foil F, and ore scattered to screen S. The conical bearing allows rotation of microscope and screen about vertical axis FF. [H. Geiger and E. Marsden, The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, 25. 604 (I913).l
material, zinc sulfide screen S,

F of scattering particles emerge from

a channel cut

in

the lead block

Coulomb's law applies to the mutual repuleven at small distances, and that ordinary Newtonian mechanical principles hold (conservation of energy and conservation of

momentum). The number


r

area of screen at distance

of a particles N reaching unit from the scattering foil was predicted

an evacuated chamber. The number of a parvarious angles with the original beam direction is found to decrease with increasing angle, but some a particles are scattered at angles greater than 90, up to 180. Rutherford
metallic
foil

in

to

depend on

ticles scattered at

r1

4VW
number
/

AV i

(15.1)

</2)

found this "almost as incredible as if you had fired a 15-inch shell at a piece of tissue paper and it came back and hit you." For the IIe ++ ion is roughly 7,:i00 times the mass of an electron, and
therefore the large deflections of a particles cannot occur by single collisions with electrons. Also, the foil used is so thin that a large

where

A' a
(

initial kinetic

energy of a particle

N =
2e

Z = =

on foil of thickhaving n target nuclei per unit volume nuclear charge a's charge
of a's incident per unit time

ness

Hydrogen
206
Looking In: Atomic and Nuclear Physics

Atom Bohr Model

207

We

shall consider the

much-studied spectrum of hydrogen,

In their precise and very readable report, Geigcr and Marsden neatly tabulated the results of counting thousands of a particles to show that .V was found to be proportional to (a) the thickness / of the scattering foil, (M the square of the nuclear charge

the simplest atom. Its spectrum comprises several well-defined groups of lines: the Lyman series in the ultraviolet, the Maimer series in the visible region, the I'aschen series in the infrared, and others
still

farther oul

in

the infrared, Fig. 15.3.

Ze (using foils of Au, Ag, Cu, etc.), (c) the reciprocal of sin (0/2), where B is the angle of deflection, and ((f) the reciprocal of the square of the initial energy K a of the a particles (using
different radioactive sources).

Balmer limit

Lymon
verified Rutherford's
.

limit

"
1

Visible
*-

pasc hen limit


j

The Geiger and Marsden experiments


meaning
nificant
of the

'

nuclear model of the structure of an atom.

They
it

clarified the

1
Some
units).

i
1

.1

-i_

j
20,000
in

4,000
Fig.

8,000

2,000

16,000

atomic number
in

Z and showed
limit of 10
IS

to be

more

sig15.3
series of lines in the spectrum of

than atomic mass

ordering elements in relation to

hydrogen (wavelengths

chemical properties.

An upper

was obtained
verified

Angstrom
for

the size of the nucleus, in terms of distance of closest approach of

particles.

The

validity of Coulomb's law

was

down

to

As a
spectra,

first

step in developing au acceptable theory of atomic


relation which allows one to calculate

about this distance of separation between charges. When Geigcr and Marsden used still more energetic a particles in their deflection experiments, some deviations from the scattering pattern predicted by Kq. (15.1) were observed. This was the
first

Rydberg found a
the

the wavelengths in

hydrogen spectrum from differences

between terms:

hint of the existence of a "nuclear force" of attraction in

= R
rtf

addition to gravitational force and the electrostatic (Coulomb)


force of repulsion.

w
=
I

}y
, is

Khvve

R =

Lm x 10

~3

A ~'

<

I5 2 >
'

When

and
1

the differences of the terms


15.2

DATA FROM SPECTROSCOPY

wave numbers
and
it;

,/X
.",

:>.

!,

given successive values, 2, 3, 4, 5, in the Rydberg equation give the for the lines of the Lyman series. When nf = 2 .... the Rydberg equation gives the wave
.

A
its

grating spectrograph (Sec. 9.12) disperses the light incident on

and focuses on a photographic plate a line image of the slit for each different wavelength present. As fine diffraction gratings became available, owing largely to the skill of H. A. Rowland (1848 1901), spectroscopists diligently accumulated a vast number of measurements on the radiation emitted by atoms when excited in electrical discharge tubes, in ares, and otherwise. In general they found that (I) each element has its own characteristic line spectrum of wavelengths A or frequency v, (2) spectrum lines are generally sharp; elements producing the lines in a sped rum may differ sharpest Hues are very stable; in relative intensity and in degree of polarization; (4) to the spectrum of every element can be ascribed a series of "term values" such that the frequency of every observed spectrum line can be obtained by differences of these term values.
entrance
slit
('.',)

Halmer series, etc. Although this formula was obtained empirically, it turns out to be closely related with the way the spectrum originates.
for lines of the

numbers

15.3

BOHR'S THEORY

There is a similarity of the hydrogen atom and our planetary system, in that in each case there is an attractive force inversely proportional to the square of the distance between the bodies. Bohr accepted Rutherford's concept of the nuclear atom and devised a model of the hydrogen atom in which orbital motion of
the election was used to predict wavelengths of radiation which agree very closely with the observed wavelengths of the spec-

trum

lines

(Table

15. 1),

208

Looking In: Atomic and Nuclear Physics

Hydrogen Atom
hydrogen
Joules
Elec. volts

Bohr Model

209

Table 15.1

Some term values end energy

levels for

of attraction exerted

by the nucleus on the

electron has the

Wovenos. (1/cm)

magnitude

*
3,047 4,387

-6.0x10" 20
-8.7
-13.6

-0.38

F =
The

-0.54
-0.85

(l-,,.w-

(15.4)

ty
HH
t> N
r*>

6,855
12,184

central acceleration a e
O
nT

~
cm

-24.2

-1.51

moving with uniform circular motion, experiences a = r 2 /r and a centripetal force mr- r, from Newton's second law. We equate the Coulomb force and the
electron,

fo PI
in

CN

CM

O
27,419
-54.3 -3.39

centripetal force
rHi
2
-

<0

!.'

Batmer series

u
00 CM 00

ti

u ^

(4xe u )r

(15.5)

i 4 CM o 8 & d 3 s
109,677

The
ally,

kinetic energy of the electron

we take K p
/*.'

A* = mr*. If, conventionwhen the electron is far from the nucleus, the
is is

-217.3

13.58

potential energy

of the electron in orbit

man

series
Sol tier series

Ep =
15, 233c 20,264c 23,032c

(15.6)
(4irt)r

6562A
4861 4341

so

its

total

energy

is

4102
3646
(Limit)

24,373c
27,419c

E=

A*

- Smv !

(Smb>

(15.7)

from which Eq.

(15.5) gives
e
(-lvtn)r
1

The following assumptions are made in the Bohr theory of the hydrogen atom: (1) The electron moves around a stationary nucleus (a good approximation, since m, iue = 1,830m,.). (2) The electron is held in a stable circular orbit by the Coulomb attraction between the negative electron and the positive nucleus. (3) Only certain (quantised) orbits are possible for the electron, namely, those for which its angular momentum is a whole-number multiple of h/2-ir, where h is Planck's constant. (4) Radiation is
emitted (or absorbed) by the hydrogen atom only when the electron undergoes an energy change in a transition from one orbit to another. The energy of the photon emitted (or absorbed) is given

/;

s"

(15.H)

2 (4jre)r

2 (4Te )r
is

Of course, the
total

kinetic energy of the electron

positive, but its

bound to the and work equal to |/i'| must be supplied to remove the electron from the atom (process of ionization), Fig. 15.4.
energy
in a

stable orbit

is

negative since

it is

nucleus,

Bohr's third assumption says that the permitted values of


electron angular

momentum
n

are
3,

mm-

n rr

'

4/W

(15.9)

by
hv

K,

The
/:,

radii of

permitted orbits are obtained by solving Kqs. (15.5)


:

(15.3)

and

2 (15.9) for the quantity (mr)

Newton's laws of motion are assumed to lie applicable to the hydrogen atom, just as to bodies of larger dimensions. The force

(mv)i

- jEsp

and

(m )s

Hydrogen
210

Atom Bohr Model

211

Looking

In

Atomic and Nuclear Physics


Mini

and equating the


4jr*me
!

results to got

"

2* im <A

(A
\n/

L\
n, s /

n'

-l^me

1, 2, 3,

(15.10)

(15.13)

(4rco)%^e

from which the value of the Rydberg constant


li

R can

be verified as

From
Sn

Eq. (15.8), the total energy can he written

2xW
(iirtn)''/r'r

1.097

X
1

10

A->

= -

2 (4we D )r

(4jreo)W
n

The

orbit for which

n =

is

referred to as the lowest state,

1, 2, 3,

(15.11)

the ground state, or the normal state for the hydrogen atom. If an
electron in the lowest energy state receives 12.07 ev of energy by
it can be Table 15.1). The time interval before the electron spontaneously drops back to a lower energy level is called the lifetime of the excited energy state, and -s sec. The electron we. are considering is ordinarily about 10 might drop Brat from state n = 3 to 2, then from . = 2 to n - 1. It would thus be responsible for the emission of two photons. One would have the frequency of the first (H) line in the Balnier series; the other would contribute to the first line in

These are the only energy levels possible for the hydrogen atom in arc indicated to the Bohr theory. The energy values for levels
I

collision

with an electron or by absorption of a photon,


level

"kicked up" into energy

n = 3

(see

Totcl energy

UnquanHzed

__

O
f

Radius r
Tj

""""-s^Binding energy
r3

l\'
^^.
,

/y
Ionization

the

Lyman
The

series.
is

ionization potential

defined as the energy needed to

MM srgy

P=

-*\

in the lowest energy energy needed to promote an electron from one state to another of greater energy is called an excitation potential. Obviously the hydrogen atom lias only one ionization potential,

remove, from an atom an electron initially

state.

The

lesser

but several excitation potentials.


lias

An atom

with

many

electrons

a corresponding number of ionization potentials. Because of the Pauli exclusion principle (Chap. 10), only in II and He do all in the ground state. In other atoms, the the electrons have it =
I

ground state

is

taken as the state of lowest energy.

15.4

EXTENSION TO HYDROGENLIKE IONS

Fig. 15,4

Bohr's

model of the hydrogen otom.

only one electron, that


the

Bohr's model and theory apply successfully to ions which have + Li ++ Be s+ etc. The equation for is, I!e
, , ,

Coulomb

force

is

modified to read

F =

e(Ze) / (iwuijr* where

Table 15.1. The frequencies of radiation which the atom can emit or absorb are predicted from Eqs. (15.3) and (15.1 1) as
in
A',-

Ze is the charge on the nucleus. This leads to inclusion of Eq. (15.13), and thus

in

E,

2tt'-W /

(15.12)

-JL\ I-W-L \nr my


X

(15.14)

212

Looking In: Atomic and Nuclear Physios

Hydrogen

Atom Bohr Model

213

This relation predicts that He + (Z


iiiies hi

2) should radiate a series of

between electron and nucleus.


velocity

the visible region for transitions to /


series for

Balmer

4 similar to the (Fig. 15.5). This Pickering series for Hc + was


He*

w -

/r, [Kq. (15.5)1, for

If we introduce the angular the centripetal force

mi-

(4rtu )r

becomes

= mr*> nr t-Mreojr\

(18.15)

*t

4- 3-

8:

6-

The equation quantizing angular momentum, Eq.


mr,*a>
Fig.

(15.9),

becomes
(15.16)

.l/r 2 u

7r-

15.5

levels for

Comparison H and for He

of
1

energy

2ir

where

.1/ is

the mass of the nucleus.

From

the definition of center

of mass,

M
m+
n=
\

and
,1/

m+M
we
find

(15.17)

n=

By combining
observed
first in

Eqs. (15.15) and (15.17),

star spectra

and was subsequently

identified witii

a laboratory

helium light source.

(4^jH
and

= m ">* rwi

(15.18)

15.5

CORRECTION FOR CENTER-OF-MASS ROTATION

The frequencies in the Pickering series for He + are not precisely the same as those in the Maimer series for H, as Bq. (15.14) predicts.

w m irw
!'*,.<

= "fts2.TT

5. fit)

Also, the

shifted in

heavy isotope II* has spectrum lines slightly frequency from those which Kq. (la. t:i) predicts should

where the symbol


Wr,.i

i r ..,i is

used for the "reduced mass,"

m\!
;

m
1

m+

.1/

tn/M

<

5.

JO.

Since Fqs. (15.18) and (15.19) differ from Eqs, (15.15) and (15.16) for no nuclear motion only in the replacement of electron mass m

M
Fig.

CM

by reduced mass w, we
motion of the nucleus
Eq. (15.11) by
is

see that the energy

/.'.

corrected for

related to the uncorrected energy A' of

15,6

Rotation about center of mass (CM).

B.
since
If

m "" m

/:

(-)*

(15.21)

be identical for both H and TI-. These discrepancies suggest thai instead of simply considering that llic electron moves around a fixed nucleus, we should consider that both electron and nucleus move about their common center of mass (Fig. 15.6). Let r f and
1

m/M

we use the corrected expression for energy in Eq. the Bohr equation (15.13) for wave numbers becomes
1
u

(15.11),

be the distances from the center of mass to the electron and to r is the distance. the nucleus, respectively. Then r = r e
r

_2irV_
(47r e }
a

mM
m+M

\_

\
(15.22)

A 3c

\rf

nf)

214

Looking in: Atomic and Nuclear Physics

Hydrogen Atom

Bohr

Model

215

This correction shifts each energy level by ahout 0.055 per cent For the isotope II 1 the shift is less. Hence a frequency for H difference can be observed when two isotopes of an element are
1
. ,

where An becomes
Vln.lir

tii

n/ and

n?ij %. Then

the Bohr frequency

present in a light source.


of II
1

The

first (II a ) line hi

the Balmer series


2

~
4

me* 2 s A a3

An
(15.24)

(15.24)

has wavelength (in(>2.80 A; that for II lias wavelength The reduced mass correction also explains why the energy difference, and hence the frequency of radiation, is slightly
6561.01 A.
greater for the helium ion
for

Comparison

of Eqs.

and

(15.23)

shows that for large

from n = 6 to n = 4) than the corresponding transitions (n = 3 to n = 2) for hydrogen.

He +

(say,

and radiates the frequency 1 , expected from classical electromagnetic theory. For An > 1, we get harmonics. This is an example of a transition region between
orbits (large n) for Are

the

atom

macroscopic and microscopic physics where the laws of classical


physics and
15.6

quantum physics

overlap.

THE CORRESPONDENCE PRINCIPLE


QUESTIONS AND PROBLEMS
1. Which of the experimental observations mentioned in Sec. 15.2 are satisfactorily explained by the Bohr theory of the atom? Are any

Bohr's correspondence principle is the guiding idea that, in the limit, the laws of quantum theory must join and agree with classical theory (which does not involve It). This asymptotic approach is to be expected when we go from microscopic systems
to those of larger dimensions, or for large values of the

quantum

number

n.

not explained? 2. How can the fact that the spectrum lines of hydrogen are sharp be used to support the statement that all electrons have identically the

Bohr's theory for the hydrogen

ment. With the aid of Kqs. (15.5)

atom does show such agreeand (15. 10), we may express the
in

frequency of rotation of an electron

a Bohr orbit as

f'orb

tj-~

2Hr

C4ire u )mr

]'

me*

WllW

(15.23)

same charge ef 3. At what temperature will the mean kinetic energy of hydrogen atoms be just sufficient to excite the H a line? Am. 93,40GK 4. Selig Hecht showed experimentally that a dark-adapted human eye experiences the sensation of light when the retina is irradiated by as little as 10 X 10~ 12 erg. What is the minimum number of quanta of
yellow light (5,893 A) which the eye can detect? Arts, about 3 5. Assume that a free electron having kinetic energy 24.2 X I0 -so joule unites with a H + ion, goes to the lowest (n = 1) level, and gives up its energy in a single photon. What is the frequency of the photon radiated? Ans. 36 X 10'Vsec 6. How much energy is there in a quantum of violet light, wavelength 4,358 A? In a quantum of yellow light, wavelength 5,893 A? Ans. 2.84 ev, 2.10 ev

On

(Maxwell) theory we should expect this electron to and possibly its harmonics. But the theory which includes Bohr's quantum assumptions for the 11 atom gives for the frequency radiated
classical

radiate energy of this frequency,

me*

(I

_1_\

Now
nr
ii/
2

-nf

(n, 4- n,)(nj

nf)

,'

,-%/

If

rii

and

n; are both large

compared

to

and

if

An

is

small,

we

can write this approximation

2n Am nf1
n, s

2An

n8

Quantum Dynamics
able theory of atomic physics.

217

We

arrive at

logical

branching

point

in

our path.

Armed with a

successfully tested theory of the

16
Quantum
Dynamics

atom, we can now (I) try to understand and predict properties of atoms in intimate aggregation (solid-state physics) or (2) we can
turn to investigation of the internal structure of atoms. A goal of such nuclear studies might be ultimately to manipulate nuclear
particles to our use, as a chemist manipulates

atoms to create

molecules with desired proper! tee.

16.1

PARTICLES AND WAVES

In this

paper

am

going to attempt to

find the foundation for a

mechanics

of
is

quantum
based

theory. This mechanics

exclusively

on

relations

be-

tween quantities which are observable


in

principle (e.g., frequencies

and

in-

tensities of line spectra,

and not elec-

Planck's derivation of the law for the energy distribution of blackbody radiation (1900) first brought to light the particle (quantum) aspect of electromagnetic radiation. Einstein strikingly established this viewpoint with his explanation of the photoelectric emission of electrons from solids (1905). Photons were endowed with momentum {hv/c) by the Conipton effect (1924). Also in 1924, Louis de Broglie, proceeding from relativity theory and the observation that nature is symmetrical in many ways, suggested that whenever there are particles witli momentum p, their motion is associated with (or "guided by") a wave of wavelength

tron orbits),

...

W, Heisenberg,

1925

(16.1)

The square

of the
is

amplitude of the de Broglie (matlcr) wave

in

given region

interpreted as being proportional to the probability of finding the particle of momentum p in that region. In

Beginning with Bohr's initial formulation of the quantum theory of atomic structure in 1914. physicists recognized that the mechanics of systems of atomic dimensions must obey laws different- from the larger systems successfully described by the classical mechanics of Newton. By 11)24, a new method of treating atomic phenomena began to be developed. It is known as quantum mechanics, quantum dynamics, or wave mechanics. The names of L. de Broglie, K. Sell nidi tiger. W. Heisenberg, P. A. M. Dime, ami EL U. Condon arc chiefly associated with this development. The concepts discussed in this chapter bring us to an acecpt216

de Broglie's hypothesis about wave-particle duality, an electromagnetic wave tS the de Broglie wave for a photon, and proceeds with speed c. The de Broglie waves for electrons, protons, neuThat electromagnetic waves, but "matter waves," which travel with the speed of the particle. We shall now discuss (I) a verification of these de Broglie waves and (2) something about how their value at various

trons, etc., are

points in space

may

lie

calculated.

Since the de Broglie equation predicted that 100-ev electrons should have wavelengths of about I A, it was suggested that the

wave nature wave nature

of

mailer might be tested

in the

same way

that the

of x rays

was

first

tested.

A beam

of electrons of

218

Looking In: Atomic and Nuclear Physics

Quantum Dynamics
electrons collide, with

219

appropriate energy could be directed onto a crystalline solid (Fig. Hi. In). The atoms of the crystal form a three-dimensional

and share

their kinetic

energy with some of

the electrons in the solid, with the result that

some

of these are

array of diffracting enters for the de Broglie wave guiding the electrons. There should be strong diffraction of electrons in certain directions just as for the Bragg diffraction of x rays.

emitted at random angles.) Experiments on electron diffraction confirms the hypothesis that their motion is directed by a wave of

some

kind,

and the wavelength agrees with that predicted by the

de Broglie relation, A

h/p.

16.2

DIFFRACTION OF PHOTONS AND NEUTRONS


Bro^lie's hypothesis suggests that particles of

De

any type may

O
(a)

exhibit diffraction effects.

The

diffraction of neutrons has been

useful in the investigation of the structure of solids.

Beams

of

neutrons whose wavelength is roughly equal to the spacing of atoms in a solid can be obtained from a nuclear reactor. These

beams are

diffracted

by layers
highest.

of atomic nuclei.
in

On

the other

hand, x rays are diffracted from planes


density of electrons
is

the solid where the

Thus

the two types of experiment

can give supplementary information about the structure of a solid. X-ray investigations reveal the location of the (bound)
electrons in a solid neutron diffraction reveals the arrangement of
;

the nuclei.

16.3

WAVE MECHANICS
expect that a de Broglie wave
will

We
(c)
Fig. 16.1
(o)

obey the same type of

second-order differentia] equation (Appendix C) used to represent other waves (Chaps. 9 and 12).
Davis son and Germer apparatus,

{fa)

Angular

distribution of secondary electrons, (c) Interpretation in terms of Bragg reflection of electrons (refraction of rays has been omitted).

This idea was tested by C. J. Davisson and L II. Germer using 54-ev electrons and a crystal of nickel (Kig. HUfe). The
emerge]
i (

Important applications of Schrodiugor's equation are to cases where the electron is subject to forces which hold it in a certain region, as in an atom or in the atomic lattice of a metal. The potential energy of the electron then varies from point to point. As the simplest case of this type, let us examine the wave function i>(x,i) for a particle of mass m which can move along a line between stops a distance L apart, like a bead on a stretched wire.

beam showed an

intensify

peak for

50.

The waveFig, 16.2

length calculated From the Bragg equation turns out to be just h/p for a 54-ev electron. (The fact that electrons are observed at

Particle confined to

linear motion within

range

L.

other angles

-o

is

attributed to secondary emission:

Some

incident

220

Looking In: Atomic and Nuclear Physics


particle will never be outside the interval

Quantum Dynamics

221

The
^
is

<

<

L; so
f

zero for x

<

mid x >

tion has solutions for only certain values of the energy.

The
(Fig.

L. Inside the region considered

here

higher the energy the more nodes there are in the


16.46).

wave

are no forces on the particle;

it is a free, particle. So the wave equation has sine and cosine, solutions, hut these must he zero at the. ends of the allowed interval. The allowed wavelengths of the

The

solutions are sinusoidal inside the well


tails outside.

exponential

Thus

(here

is

and have some probability for lind-

de Broglie wave arc A


h nh P = \ = 2L

2L/n, which leads to

(lfi.2)
'1

showing that the linear


energy of the particle
is

momentum

is

quantized.

The

kinetic

a
I

ii'

h-

2m~

2m

4JS

8mP
0,

(18.3)

Fig. 16,3

Wave

functions for a

bead on

string, for states

1,2,3,4.

and

since

we have taken K v =

the total energy must have one

of flic values

(16-4)

The

particle

is

located

by the matter wave


n

iff

^D sin

cos

ait

2, 3,

(16.5)

x
The amplitudes
of the

*-

'.

X-

\L

standing waves for states of motion cor,

responding to n = 1, 2, 3, ... vary as shown in fig. 1(5.3. (There is a close analogy with standing waves in a vibrating string.) We see that the act of localizing or hounding a particle
leads to the requirements that (1) the energy of the system can

take on only certain values and


the kinetic energy.

(2) zero

is

not a possible value of

'>i
of prediction

>

Another important type

from wave mechanics


Fig.

(a)
16.4
1,2,3.
(a)

deals with the "leakage" of particles across an energy barrier.

Suppose we have a particle bound in a shallow potential energy "hole" (1'ig. Hi. 4). There are now two kinds of solutions for the wave equation. There are solutions for any K > 0. Particles in these states have enough energy to escape; ^ extends over all space for them. Hut for particles whose lit is less than #n (Tig. 1G.4), the total energy is negative, and for K < the wave equa-

A "square"

potential hole,

and

(b)

the

wave

function of

its

states

ing particles in a region where, according to classical theory, they do not have enough energy to be. Around a nucleus we may think of a potential harrier whose craterlike shape is determined by the Coulomb electrostatic force and a shorter-range force of nuclear
1

222

Looking In: Atomic and Nucfear Physics

Quantum Dynamics
gular

223

The wave viewpoint predicts that, charged particles which do not have enough energy to go over the top of this barrier have a small but not zero probability of occasionally tunneling through the barrier.
attraction.

coordinates

to

spherical

polar

coordinates,

using

the

relations
r
8
4>

=
= =

distance of point a from origin

= y/x 2 +
{z/r)

y*

+z

angle from z axis to

cos~

angle around z axis measured from x axis


of the coordinates
r, Q,

tan -1

(</

as)

16.4
If

BOHR ORBITS OR DE BROGLIE WAVES?


With the introduction
$,

Kq.

(Ifi.O)

can be

matter waves and the probability interpretation of Sehrodinger's equation to the hydrogen atom, we find that he features which the Bohr theory correctly preof
I

we apply the concept

separated into three ordinary differential equations, a fact


represent by
f(r,e,<t>)

we

dicted (only with the aid of arbitrary assumptions: = nh/'lir, etc.) follow as a natural outcome of the mathematics involved.

mr

= rt(r)0(0)*W
li

(lfi.7)

The quantum dynamical treatment provides additional information as well. The electron in a hydrogen atom has potential
energy -('
r
\irtr.

The function

describes

nucleus in a definite direction.

how f varies as we go out from the The functions 8 and <$ describe
posi-

If

we
z1

write for the radial distance

how ^ behaves from point to point on a sphere of radius r. The equation for the function K(r) has a solution for any
tive value of E.

- V-t

y*

Sehrodinger's relation |Appendix C, Kq.

(4}|

becomes

These solutions correspond to states in which the electron has enough energy to escape from the atom; there are no quantum restrictions on the energy of a free electron. But there are only certain negative values of E for which Kq. (16.7) has any continuous solution. When the electron is bound in the atom, an acceptable wave function ^ exists only if E has one of
(16.fi)

the particular values

a function which has a definite value at each point in the neighborhood of the nucleus. To discuss this equation, it is convenient to change from reetanis

The

solution of this equation, ^(r,ij,z),

4 = -me

-I3.fi

ev
for the

1,

2, 3,

(10.8)

These are the same values

energy states that the Bohr

theory predicted. The quantum number n is here related to the part R(r) of the wave function which describes the probability
per unit volume of finding the electron in a given volume element
at various distances from the nucleus. This
is

independent of

can compute the average distance of the electron from the nucleus by averaging over the probability distribution. The

and
Fig.

*.

We

16.5

Rectangular

and

spherical

co-

ordinates.

result

is

The energy
or

roughly the same as the radius of the first Bohr orbit. (Kq. 10.8) is in exact agreement with the Bohr theory.
n,

For each value of

the equation for 8(8)

is

found to have one


I.

by a second quantum number This quantum number takes on only the values more
solutions, described
/

0,

1,2,3,

(16.9)

224

Looking

In:

Atomic and Nuclear Physics


arc related to solutions of the
is

Quantum Dynamics

225

Solutions of the

* equation

tion such that the electron

less

R equalikely to he found near the


when
in a low-/ state of the

nucleus when

in

a high-/ state than

same energy.
/, the equation for *(<) is found to have one designated hy a third quantum number jtcj. or more solutions, on the values This takes only

For each value of

which has a magnetic moment passes through a uniform magnetic field, it experiences a torque, but no deflecting force. If, however, the field is nonuniform, the atom experiences a net deflecting force as well. Consider a beam of II atoms. The electron in the normal state has zero orbital angular momentum for n = 1, / = 0, mi = 0. There is no magnetic moment due to orbital motion. Vet the beam of II atoms is observed to split into two
parts, each associated with a restricted orientation of the clec-

m = -/,_(/,

i),

-(I -2),

10 12 (I - I),

(16.10)

Xo

solutions of Schrodinger's equation for the hydrogen

atom

exist for

any other values

of ,

/,

and m

16.5

THE QUANTUM-NUMBERS GAME


be completely described by the use of just four
for

An atom can

quantum numbers
already introduced.

each electron. Three of these we have


energy,
. . . .

The
E<|.

principal

(10.8). It

may have

The

orbital

quantum number determines the the integral values n = 1, 2, angular- momentum quantum number

:i,

deter-

mines the angular


the nucleus. It

momentum of the motion of the electron about may take on any integral value from to n 1. The corresponding value of the electron angular momentum i1)

VKI+
a

h/2n.
of the orbital

The component
axis
is

angular

momentum

along the
-jI

given by

null, 2x,
.
. .

where
,

m may

lake on any of the 2/

values: 0, 1, 2,

the
of

The quantum number mt is called magnetic quantum number because physically the presence,
1.
field is

Fig.

16.6

Possible orientations of

angular-momentum

an external magnetic
(z

necessary to establish a reference


field,

vectors.

direction

axis)

in

space. In a magnetic
is

the electron's
its

angular

momentum
2tt

said to be "space-quantized" because


>i

tron's spin angular

momentum. The two

possible values of the


in

component along the


to the values mji

di recti

the magnetic

field

is

restricted

component
magnetic

of the spin angular

momentum

the direction of the

(Fig.

l(i.(i).

spin

introduce a fourth quantum number 8, the electronangular-momentum quantum number. This quantum number defines the internal angular momentum {and associated magnetic moment) which an electron is found to have, independent of its orbital motion. An experiment to show this property of the electron was performed by Stern and Clerlach. If a neutral atom

We now

conclude that, unlike the other quantum numbers, which are integers, n can have only the value be either , The component of the spin angular momentum may we can So held. magnetic parallel or antiparallel with the applied
field

are %k/2*.

We

define a spin magnetic

quantum number m - \ and

write the

component
applied

of the spin angular

momentum

in the direction of the

field

as mji/2w.

Quantum Dynamics

227

16.6
(>
J

THE PAULI EXCLUSION PRINCIPLE


W.

Traces on
receiving

Paul! suggested that a complete description of the include a unique description of each electron in the atom must in an atom may have identical values for electrons two atom. Xo

In 1925

set of four

To

see

quantum numbers. how this rule operates, consider


in

the

number

of elec-

trons permitted n = 1. Since n is

the

first

orbital

1, 1

and
in

m =
t

group (or shell) for which 0, But m, may be +1 or '..

So

in this first

group there

may

only by having their spins


tion of this assigning of

be two electrons, distinguished opposite directions. The continuato electrons in

quantum numbers
in

many-

electron
Table 16.1

atoms

is

shown

Table

16.1.

Numbers of

electrons in groups (or shells) as determined

by

Pauli's

exclusion principle

Orbital

No. elec.

in

group

subgroup

No. elec. in completed group

1 1
i

2s

Direction atoms

move 1

Magnetic field used in Stern-Gerloch experiWith no field there is a single beam, (b) With field, beam splits; some atoms are deflected toward N po!e, some toward S pole. Traces where beam strikes detecting plate are shown at top. (Adopted from R. 0. Rusk, "Afomk and Nuclear Physics," Applet on- Century -Crofts, Inc., New
Fig.

16.7
(a)

ment,

York, 1958.)
Iii the terminology of Table 16.1, we replace the term "orbit" by "group" or "shell" (determined by n). This emphasizes the

three-dimensional nature of the atom.

The

shells are often


=

the K, L,
226

M,

,Q

shells,

corresponding ton

1,2,3,

named ... 7.
,

228

Looking In: Atomic and Nuclear Physics


shell,

Quantum Dynamics
electrons in a complex
little.

229

Within a

electrons with a
s,

common
rl,

shell These arc designated

p,

or

value of / form a sub/ subshells according to

atom must disturb each

other's orbits very

whether

has the value

0,

1,2, or 3,

One
tioned.

sort of disturbance, called screening, should

An outer

electron
it

is

in

a weak electric

field

be menbecause inner

16.7

BUILDING THE PERIODIC TABLE OF ELEMENTS


the elements are arranged in order of increasing atomic a periodicity in their chemical properties becomes

When

number,

apparent, as shown by Mendeleev. The structure of the periodic table is in agreement with the ideas of filled shells and subshells as predicted by the 1'auli principle. We may "build up" an atom

from the positive charge of the nucleus. Hence some probability of being found very near the nucleus will have lower energy (greater binding) than those states in which the electron tends to stay outside the screening inner electrons. Of the solutions of the Schrodinger equation for a given n, those with lower values of J will tend to
electrons screen
states in which the electron has

by putting each electron

in the shell of lowest energy until the quota of permitted states is filled. Any additional elections mustbe put. in the next shell as shown in Table lfi.2. The final column

/
2.1

Table 16.2
>,/-*

Electron configured ion for

ght atoms

16

1,0

2,0
(2s)

2,1

3,0
(3*)

3,1
(3 P )

3,2
(3d,

4,0
(4s)

Configuration

Element

(U)

(2P )

12

H He
Li

If

2
3

2
2
I

w
2*
2s*
1

Be
B

4 5 6
/ 8 9
10
11

2 2 2 2 2
2

2
2

4 -

2p
2p= 2p*

2 2 2 2 2 2

_i

2 3

!!
14
(J

...

I I i

10
Fig. 16.8

IS
in ev)

22

26

30

O
F

Ne No

2 2

4 5 6
6
T

2p 4
2p

Variation of ionization energy

with atomic

number

Z, sug-

gesting greater stability of certain electron configurations.

2p
3s

r>

penetrate the cloud of screening electrons most. Hence, for atoms containing more than one electron, penetration causes the energy
of Table KS.2
for the
is

a description of the electrons in the outside shell

of

normal (ground) state of the atom. The electron configuration of an atom is described by the abbreviated not at inn ui" he last column. For example, %- means there are two electrons in the n - .i, I = subshell.
t
I

picture, energy
size.)

an orbit to depend on I. as well as on ti. (In terms of the liohr depends on the shape of the orbit as well as on its
Klectrical

The quantum numbers we are using were originated for the case of one electron. J I is remarkable thai by assi nin occupied g g states in terms of these numbers we get ati accurate description of many of the properties of complex atoms. Kvidently the various

measurements which correlate well with electron shown in I'ig. Ili.8. The ionization energy is the work needed to remove the least tightly bound electron from an atom. The variation of ionization energy with atomic number 7. suggests that certain electron configurations have relatively great stability. The first is for helium, where the it = shell has
configurations are
I

230
its

Looking In: Atomic and Nuclear Physics


ii""
<>f

Quantum Dynamics
to the

231

''

two
is

electrons.

The sharp drop

binding energy

for lithium
bi>

attributed to the fact that the third electron must ndded io l lie n - 2 shell and is therefore farther from the
is

the Bohr formula with allowance for screening by the inner electrons. From the relation

a trend toward increasing binding energy until another maximum is reached at neon, when the n = 2 shell is filled. Like He, Xe is an inert gas.
nucleus. Tor the elements after lithium, there

= Rc(z - ]y-(L- L\

(16.11)

This variation
gas, followed
size of

in

binding energy

is

repeated several times

in

the

periodic table, each time giving a

maximum

binding at an inert

Moseley was able to prove that early assignment of atomic numbers to cobalt and nickel was in error. The atomic mass of a natural mixture of the isotopes of Xi is 58.(i!) and for Co 58.94.

by a minimum
1

for the succeeding alkali metal.

The

They were

first

placed in the periodic table in the order of increas-

atoms

also oscillates from shell to shell, about a value

ing atomic mass. Hut the x-ray lines

showed that

this order

approximately

for the radius. In each shell, the alkali metal

should be reversed, for

ZCo =

27 and Zy,

28.

Moseley 's work

has the largest radius.

K
16.8

CHARACTERISTIC X-RAY SPECTRA


a target
is

K
(l>),

When

bombarded with electrons of high energy

x rays are produced which have a spectrum which is continuous up to the maximum frequency given by the relation fcjWx = I <
In addition, x-ray spectrum lines arc observed at frequencies which are characteristic of (determined by) the target material. Characteristic x-ray spectra can now be explained in terms of the shell structure of atoms. First, a vacancy must he created by the displacement of an inner electron from, say, the K or L shell. Since there are usually no near-lying vacant energy levels to which these electrons may be promoted, they must be removed altogether from the atom (ionization). This may he accomplished when atoms of the target are bombarded by electrons which have been accelerated through a potential difference of many thousand electron volts or by high-frequency photons. Transition of a nearlying electron then occurs to Jill the vacancy. If a vacancy in the K shell is filled by an electron from the h shell, an x-ray photon is radiated whose frequency depends on the difference in energy

0.2 0.4 0.6 0.8

1.0

E,

Wavelength,
(a)

La
EM
\

H
V
35

<Ma N

(b)
Fig.
(a)

16.9

Characteristic x-ray spectrum,

(a)

Molybdenum target

with

kv.

Simplified energy level diagram.

first accurate method for measuring atomic number, Z. The committee awarding the 1917 Xohel Prize to C. G. Barkla, for his work on characteristic x rays, stated that Moseley would have shared the award but for his death at

(1913) gave the

between the K and L shells. The vacancy left in the L shell is in turn tilled by an electron from a still higher energy state, with radiation of a photon of somewhat lower frequency, Fig. lfi.9.
Since the energy of the electron in the

Callipoli.

16.9

shell

is

chiefly

PHYSICS OF THE SOLID STATE


theory, based on the nuclear
tells

determined by the nuclear charge Z, Moseley found he could use the K a lines of the elements to identify the atoms in the target of the x-ray tube. lie found a linear relation between the square root of the frequency and (Z l), as would be expected from

Our

atom model and quantum

us that under ordinary circumstances of temperature and pressure the nuclei of atoms will never get very close
to one another.

mechanics,

The combination

of

atoms should therefore be

232

Looking In: Atomic and Nuclear Physics

Quantum Dynamics

233

explainable through the exchange or sharing of electrons. In terms of tfic measured masses and charges it should be possible
to describe the formation of molecules and chemical reactions. One might also hope to describe crystal lattices and the mechan-

speed squared, the average kinetic energy depends on the average of the squares of the speeds. The square root of this average is called the root-niean-square (rms) speed. The distribution curve

becomes

flatter

and the maximum

shifts
8).

toward higher speeds as

thermal, electric, and magnetic properties of solids. Practically, the difficulty is the complexity of the computations. We
ical,

the temperature increases (Chap.

shall

examine some

of the successes of

quantum mechanics

in

explaining important electric and magnetic properties of solids. This comprises hut one segment of solid-state physics in which there is very active research.

16.10

CLASSICAL THEORY OF CONDUCTION IN METALS

rough predictions of the electrical and thermal conductivities of metals, if is in accord with the experimental observation that the best conductors of electricity are also the best conductors of heat. Wiedemann and Franz 850} showed that the electrical conductivity thermal conductivity ratio is a constant, for metals. The classical theory, using known values for e and k, predicts that the thermal conductivity/
classical theory gives
( 1

The

electrical conductivity ratio

li.ll

10 _B 'T cal

ohm

sec (K).

theory proposed by Drude and Lorentz, soon after the discovery of the election, assumed, as have later theories, that some
of the electrons are free to travel throughout the

whole volume of
Fig. 16.10

a crystalline material. In a "good" metal, it was assumed thai there is about one free electron per atom and that the number of conduction electrons is independent of temperature. These electrons dart around in
agitation. Hut
if

Hall effeel

D D'

all

directions ui) h the high speeds of thermal


is

an electric held

applied, the "electron atmosdrift,

This checks well with values measured for platinum and other
I

phere" experiences a relatively slow random thermal motions. The electron

superposed on the
the electric current.

mre metals.
But the
classical

drift

is

The transfer of any increase in the energy of random motion in any direction constitutes thermal conduction. To make quantitative predictions, is necessary to make some assumptions about
it

predicts that

the

free

theory meets with significant failures. It electrons should contribute |/f to the

specific heat of a crystal.


is

This considerable electronic specific heatis

not observed experimentally. Also, the theory

unable to

the distribution of electron speeds. Theories have differed these assumptions.

in

explain the

enormous range

of electrical resistivity for different

materials. Further, the theory suggests that since the free elec-

The classical theory assumed that the electron speeds followed the same distribution law as .Maxwell and Bollzmanii had used
for

molecular speeds
8).

in

developing a successful kinetic theory of


the frac-

gases (Chap.
tional

Among a large number N of electrons, number N,'N having speed r is given by

AT

vV \2fc27
plot this expression against
r,

(16.12)

o, the area under the curve and v-> equals the fraction of all the electrons whose speeds are between r, and r*. Since kinetic energy depends on the

Tf

we

between

trons have magnetic moments, even a weak magnetic field should produce a large paramagnetic magnetization (magnetic moment per unit volume) in a conductor. It does not. Finally, the theory has difficulty in predicting the sign of the Hall coefficient. For a current-carrying conductor (Fig. Hi. 10) one would expect that a potentiometer connected between Cand J), in a plane perpendicular to the current would indicate zero potential difference. If now an external field H is applied, the conduction electrons experience a magnetic thrust perpendicular both to H and their velocity v. The equipotential line CD is tilted through some angle to position CD'. The classical theory predicts that tan 4> (the Hall coefficient) should have the same sign for all metals. It docs not.
.

<j>

234

Looking In: Atomic and Nuclear Physics

Quantum Dynamics
occupied up to a certain

235

maximum
to
still

(Fig.

16.12a).

At a higher
Btl1

16.11

FREE-ELECTRON QUANTUM THEORY OF CONDUCTION


free

Fermi introduced a radically different description of the


electrons

temperature some accept energy ami move

electrons in upper levels have been able to

higher [ovate (Kg. [6.126).


relatively

iii a metal. He incorporated the exclusion principle, assuming that the "free" electrons hi a metal are quantized and that no two can act exactly alike. Momenta are quantized; only two electrons (having opposite spins} can have a given momentum. As the temperature is lowered, electrons settle down hy quantised slops to lower momentum values. But as a consequence of the exclusion principle, some electrons wil! remain at momentum values considerably above zero: thai is, linn- will have appreciable energy, even at absolute zero temperature. When the

few electrons have owing to quantum Fermi rise. The theory predicts temperature participated in the contribute roughly per cent should conductor that electrons in a theory, in agreement Maxwell by the predicted of the amount
restrictions,
1

with experiments

in

calorimetry.
to

a certain maximum, are in a Thus traveling toward the left. all ion elect metal there is another relatively be the metal must due to the electrical conduction in few electrons near the top of the distribution (Fig. JO. 126) which

The fact that all energy levels, up filled means that for every electron

traveling to the right

J0K
i

300 K

Fig.

16.12
to

Fermi

distribution

of

energies, showing

(a) all

levels filled

up
\Very high temp.

electrons
levels at

K, (b) some a maximum of promoted to higher energy

a high temperature.
Rel, no
Rel
*

no

Fig.

16.11

Fermi

distribution

of

speeds

at

various

temperatures.

temperature
values.

rises,

only the electrons of highest

accept thermal energy and

move
is

to

still

momentum can higher momentum

can be excited easily to an unoccupied quantum level. One concludes that electricity must be conducted by only a small fraction of the free electrons (rather than by all, as assumed in classical theory). In turn, this implies that an electron must be able in
travel long distances without being
lattice.

The Fermi

distribution law

expressed by

The
is

free-electron

bumped by ions in the crystal quantum theory, like the classical

N
where

hl
E,
is

e m,"' i!_A

"-'*r

(16.13)

theory,

unable to account for the distinction between con-

ductors and insulators.


the

maximum

energy an electron can have at 0K. In

Fig. 16.11, the progressive rounding of the curve as temperature

increases represents the shift of

some

electrons to higher energies.

16.12

The Fermi

distribution curve should be

compared with the MaxIn the

BAND THEORY OF CONDUCTORS, SEMICONDUCTORS, AND INSULATORS

well distribution (Chap. 8).

The ['ermi theory successfully accounts for the slight participation of electrons in specific heats. In Fig. Hi. 12, the Fermi
distribution of energy
is

plotted.

At 0K

all

energy states are

theory of the electronic structure of solids, the effects of the lattice ions on the free electrons are considered to explain the occurrence of conductors, insulators, and semiconductors. The moving electrons are pictured in terms of

modem band

236

Looking In: Atomic and Nuclear Physics


is

Quantum Dynamics
appreciably separated from other bands
(a),

237
is

do Broglie waves of wavelength \ - h/mr. The influence of the lattice ions arises from the variation of potential from atom to

the materia!

an

insulator.

To produce

a current

in

such a material, electrons have

atom
waves
used

in the crystal (Fig.


is

The passage of he do Broglie treated mathematically by methods similar to those


Hi. 13).
I

in investigating

the passage of light waves through a similar

to be advanced across an energy gap large compared to thermal energy /,'/'. In a conductor, however, the highest band containing electrons is not full (/*). Kven a small external electric field can

lattice.

Allowed

Yinnrvv
It

(Empty)

Allowed

[Partly full

Fig. 16,13
tial

Variations of poten-

along

one-dimensional
Forbidden

crystal lattice.
/

Forbidden

momentum,
which
of
it

turns out that the graph of electron kinetic energy versus instead of having the parabolic shape (Fig. Hi. 14a)
;

(Allowed
(Full)

would have

in a

conductor where there was no variation


for

i)

potential,

jumps discontiuuously
(Fig. 16.14/*).

particular
all

values of

de Broglie wavelengths

(a)

Not

electron

momenta

(6)

Allowed (empty)
-Forbidden

E9 , p 2skT

Allowed

(full)

(C)
Fig.

16.15

Distribution of electrons in

bands

in

(a)

an

insulator, (b)

a conductor, and

(c)

a semiconductor.

(a)
Fig.

(b)
vs.

16.14

Energy

momentum:
(b)

potential

between atoms;

Assuming no variation of assuming a variation of potential


(a)

produce an unbalanced momentum distribution {a current) by promoting electrons to energy states of small excitation. Semiconductors arc an intermediate case in which the highest occupied hand is full (c), but. the energy jump to the next band is comparable to kT. Increase in temperature would be expected to lower the resistance of a semiconductor.

similar to that of Fig. 16.13.

are possible.
is

From

this point of view, the effect of the ion lattice

to preclude certain values of electron

leave forbidden energy gaps at these

momentum and hence momentum values.

to

The properties of conductors, insulators, and semiconductors ran now be interpreted in terms of the conduction bands (Pig, Hi. 15). If the highest energy band containing electrons is full and

Radioactivity

239

The decay

of these artificial radioactive nuclides

is

in

accord with

the laws found earlier in the study of natural radioactivity.

17
Radioactivity

17.1

TYPES OF RADIOACTIVITY
is

In the theory of the nucleus there


easily visualized mechanical of the

model employed

no counterpart of the simple, in the Bohr theory

atom. But the concept of energy levels, found so useful in studying the atom, is carried over to the description of the nucleus. Nuclear spectroscopy deals with the identification of these energy levels and is an important source of information

about the nucleus, since radioactive changes can be measured


with high precision.

The new
in

discoveries

made

in

physics

When

the electronic structure of an

atom acquires some extra

the last few years, and the ideas


potentialities

energy, the

and

suggested by them,

gets rid of this extra energy very the ground state in roughly 10 * sec. It does returning to quickly,

atom almost always

have had an
this
in

effect

upon the workers


to

in

subject
literature
J, J,

akin

that produced

by

the
in

Renaissance.

Thomson,

an address on

radioactivity, 1909

more photons or an electron if there is enough extra energy. Many nuclei, however, can exist for long periods of time in an unstable state, that is, in a state from which the nucleus can and eventually will decay to a stable state. A nucleus may go to a state of lower energy by emitting an a particle (a radioactivity), an electron or positron (fi radioactivity), or a photon {7 radioactivity). Most "natural radioactivity" is found among the very heavy elements (A > 210), which tend to be unstable to a decay. These nuclei decay so slowly thai there are still some of them left
so by emitting one or

from the time of formation of the elements. Radioactive isotopes not found in nature can lie prepared in nuclear reactions.
Radioactivity has provided us with

much

of the

knowledge we
ji

now have concerning

the nucleus. Emission of a and

particles
17.2

by certain atoms suggested the idea that atoms are built of smaller units. Measurements of the scattering of a particles by atoms confirmed Rutherford's idea of the nuclear atom. The discovery of isotopes can be traced to the analysis of the chemical
relationships

STATISTICAL

LAW OF RADIOACTIVE DECAY


is

The

activity of a radioactive sample

defined as the

number

of

among

the various radioactive elements.

The bom-

disintegrations per second. The activity decreases with time. Each radioactive isotope has its own characteristic rate of decrease, figure 17.1 is the plot of the decay of a radioisotope which

atoms with energetic a particles from radioactive su Instances was found to cause disintegration of some atomic nuclei; this led in turn to the discovery of the neutron and to the present theory of the make-up of the nucleus. The transmuted atoms resulting from such bombardment are often radioactive.
of

bardment

decreases in activity by 50 per cent every 4.0 hr. The form of Inexperimental decay curve suggests that the decay is a logat

rithmic process. This


activity versus time.

is

verified

by plotting the logarithm

of

straight line results.

We

can derive an exponential law of decay for a sample con-

238

240

Looking In: Atomic and Nuclear Physics


Radioactivity
241

tabling a large

number

of radioactive atoms.

We

assume that

each undeeayed nucleus has a definite probability X of undergoing decay in the next second and that this probability is independent of time and is independent of whatever other atoms are
present.
to the

Then Iho number of decays in a time interval dt is equal number of undeeayed atoms present times the probability

a is the number of undeeayed atoms in the sample when (Note the mathematical similarity with the equation for the exponential ahsorption of a beam of radiation.) The activity of a sample, the number of decays per second, is given by

where
t

0.

Activity
or

-.:-

= XAV-W

(17.4)

Activity
g <
*m

= XN

(17.5.

c 3
^

activity depends on the number of atoms present and on their decay constant, X.

The

%
fc
">

KT

t
<

\ \ t=^L. "
i

17.3

HALF-LIFE

0.693

The

half-life T of a radioactive substance is the time interval in which the activity (and hence the number of undeeayed atoms) decreases by 50 per cent. For the activity of Fig. 17.1 this is
t

.i
20

4.0 hr. Itoiii the definition that


t,

- T when

= IN^

Eq. (17.3)

4
Fig,

12

16

24

hr

becomes

17,1

Decrease

in activity

of a radioisotope

hN a = AV"W
which gives

(17.6)

with

4.0-hr half-life.

X
in

(ll

that each one of them will decay.

Thus the change

(decrease)

the
(IN

number

T=

log, 2

0.3
(17.7)

of

undeeayed atoms

is

= -\N(U
is

(17.1)

The average

life

'/',

or

life

expectancy, of a radioactive nucleus


of all the nuclei

may
,

be calculated by

The decay constant X


radioactive isotope

the relative number


considering,

dX/N

of

atoms

dividing by the total


?

Rimming the lives number of nuclei


I

and

which decay per second. The value of X depends only on which

we are

fi/ot

dN
No

Jo

-57-

= tt / No Jo

'Wr M
,

..

.,

dt

(17.8)

Uy separating

variables in Kq. {17.1),

we obtain a simple

differential equation

The decay constant


(17.2)

X is the reciprocal of the average life, in accord with the interpretation of X as the probability of decay of

tlX

N
N=

Xdt

an atom per second.

whose solution

is

17.4

UNITS OF RADIOACTIVITY was


historically defined as the

AV"*

A
(17.3)

unit of activity

(gas)

in equilibrium with

one gram

of radium.

amount of radon The National

242

Looking In: Atomic and Nuclear Physics


tion energies (/) are

Radioactivity

243

Research Council in 1948 extended this definition to define one curie as that quantity of any radioactive substance which gives
3.70

photons

may

known. Hence the energy of the y-ray be determined by measuring the energies of the

10 10 disintegrations per second. Since the curie

is

a rela-

photoelectrons.
Positron-electron pairs (Chap. 19) can be created

tively large unit, the millicurie (I mc = 0.001 curie) microcurie (I ^c = 10 -s curie) are widely used. A

and the
particles

by 7 rays

counter near a

with hv
hv

> 2m
2m,e*

c'.

The photon energy


.

is

transformed thus:
(17.12.

radioactive source detects a certain

fraction

of the

emitted; the counting rate


source.

is

proportional to the activity of the

+ Ek+ + Ek ~ + Ek

tceoil

The
which
1

From
specific activity of

conservation of

momentum,
of the

the recoil velocity of the

a radioactive source

is

the rate at

nearby nucleus should be small.


neglected.

gin emits charged particles.

Measurements

positron in a magnetic
17.5

field

energy can generally be of the electron and then give information from which the
Its

momenta

GAMMA DECAY

energy of the X ray can he found.

A nucleus in an excited statc(z*Xi) may go to a state of lower energy by emitting the difference in energy as a photon:
zX*

17.6

ALPHA DECAY
particle
is

hv

CMv)
in

(1 7.!

When an a

ejected from the nucleus, the original


Its

Now y decay

nucleus loses two protons and two neutrons.

mass number

does not cause a change

the atomic

number

or

the mass number of the nucleus. The half-lives for y decay are seldom very long. Study of y radiation gives important information about the initial and final states of the nucleus undergoing a y transition. Like the spectra of atoms, the y spectra of nuclei are found to consist of sharp lines, showing that the nucleus has discrete energy levels. The observed energies of emitted photons give
consistent results for the nuclear energy levels

atomic number Z decreases by two. decay thus causes transmutation of the parent chemical element into a different chemical element
decreases by four units while
its

Z X* - _,**-*

-.He'

+ Q

(energy)

-17.1:;.

Now

a decay occurs spontaneously, without any external

forces,

hv

Ei

- E}
of y radiation
is

and it provides kinetic energy (#*,) for the ejected n part ideas well as some kinetic energy {E k d ) for the recoil ''daughter" nucleus. Hence a decay cannot occur unless the total rest mass decreases.
,

(17.10)

The decrease

in rest

energy

is

equal to the kinetic energy released,

The electromagnetic-wave nature

demon-

called the disintegration energy Q:

strated experimentally by diffraction. This is feasible only for those 7 rays of relatively low energy because ruled gratings or
crystals with effective spaeings about equal to very short

Q = Ek
To

,,i

+E

k ,

(m

- m - w Q )c
lt

(17.14)

wavelengths are not available. The energies of high-energy 7 rays may be measured in several ways. When a 7 ray ejects a photoelectron from the inner shell of ati atom,

hv

= Ek

a decay, we may commass with the sum of the masses of the product nuclei. Actually we can use the masses of atoms instead of those of the nuclei. The same number of electrons are associated with the initial and final nuclei, so the electron masses cancel in the
predict whether a nucleus will undergo
its rest

pare

(17.11)

calculation of Q.

From Eq,

(17.13),

the kinetic energy of the ejected electron and / is the binding energy of the shell from which it is removed. The ionizak is

where

Q = (m* - mr

trine)*?

(17.16)

Radioactivity

245

244

Looking In: Atomic and Nuclear Physics


t t>N'l

Exampk, Find the Q value for the disintegration Prom tables of isotope mosses:
toX'!'*'

u * *

tlic* 4- S8 Ce I4l>.

n, t

He =
4

4.00387

Produeta

Ce l4 = 139.01977
143.95364

m
Q =
mc*

= =

[43.95550 143.95364

/
1

u" 8
Decay

V,
4.20

7.68 Mev

0.00192
1.79

Mev

Me>
1

Example. In a decay, what fraction of the disintegration energy appears as kinetic energy of (he a particle? Conservation of energy and conservation of momentum in a decay
require
Fig.

/
17.2

mava
From
(he

Q =

Et.4

+ E kia =
ive

lmj>S

= m&t momentum
have

fli a p a

energy
particle.

particle

Coulomb borrier: scattering of a highand tunneling of a low-energy

equation, v d

(ia/ij)e. Substituting this in the

energy equal ion.

or

Q "

^-'(S)
a
1

(17.16)

AY~ =
If .4 is the

m/m d
of the parent nucleus, then

(17.17)

mass number

m a /m a

=*

4/(A

4)

and
**

4-4
(17.1 7)

Thus

for large .4, the integration energy.

particle gets most, but not quite

all,

of the dis-

An interesting feature of a decay called the tunnel effect may be illustrated by data for a particular ease. One can perform an
experiment similar to the Kutlierford-Ceiger-Marsden scattering experiment (Chap. 15) using a thin foil of 94 U i!8 to scatter the 7.68- Mev a particles from mIV 4 (also called Ra C). One finds that the Rutherford scattering law is obeyed. Kvtdently the 4 a particles from do not have sufficient energy to get over

Fig. 17.3

Wave

mechanical description of tunnel effect.

energy curve of an a particle near a

Um

nucleus and a

IV

a a

particle being turned

away by

the potential barrier. Contrast


itself is
is

IV

the

Coulomb

barrier; they are scattered


is

away from

the

l"'

:,s

nucleus. This

suggested

in Fig. 17.2,

which shows the potential-

an a emitter, emitting We have a paradoxical situation The lower-energy U S39 a particle can cross a barrier which the higher-energy I'o 414 a particles appear unable
this with the following fact:

U 2,s

particles

whose kinetic energy


:

only 4.20 Mev.

246

Looking In: Atomic and Nuclear Physics

Radioactivity

247

to cross.

An explanation on

the basis of classical physics

is

impossible.

The wave nature of the a particle must be taken into account. use wave mechanics to describe an a particle in the nucleus, we find that a little of the wave function will "leak"

When we

decay occur: ff~ decay, in which an emitted from the nucleus, and (3 + decay, in which a positron is emitted. If the nucleus consists of neutrons and protons only and if electric charge is conserved, then upon emission
different types of
is

Two

electron

of

an electron, a neutron must be converted to a proton,

hZ =

-f- 1.

through the barrier so that there is a small probability that the particle may be found outside (Fig. 17.8). According to wave mechanics, if the a particle has enough energy to be outside,

Similarly, positron emission involves the conversion of a proton


to a neutron,

AZ = 1.
(17.18)

some probability that it will be found there. This probability is very small for U 2M and accounts, roughly, for the U 23 half-life of 4,f> billion years. The tunnel effect works in either direction, so some of the IV" a particles used in the scattering experiment must have penetrated the nucleus, but the fraction which succeeded was negligible. The probability of tunneling depends strongly on the height and width of the potential barrier.
then there
" 1

is

(17.19)

For ~ decay to occur, the mass of the decaying nucleus must be


greater than the mass of the product nucleus plus the mass of an
electron.

An atom which

is

heavier than the


.1

unit greater but with the

same

will

atom with Z one decay into that atom by


more complicated.
(17.20)

0- emission.

The condition
17.7

for

+ decay
'2m r c 3

is

slightly

BETA DECAY
/3

Q
where

nix

wiy

hi.

from a radioactive source are shown by There are good reasons to believe that, these electrons do not exist in the nucleus but are created by a rearrangement of the nucleus into a state of lower energy. Any excess of energy over thai required to provide one electron rest mass (m.c-) appeal's as kinetic energy of
particles emitted
deflection experiments to be high-energy electrons.

The

m\ and

m\- are the masses of the initial


is

and

final

atoms,
is

the emitted electron.

An argument
prior to emission,

against the existence of electrons in a nucleus,

makes use

of the uncertainty principle. If

an

more than two electron masses heavier than the atom with the same .1 and one less Z. There is still a third ($ decay process whose over-all result is the same as /J + decay. A nucleus may absorb one of its orbital electrons. This process is called A" capture since the elect Tons ill the nearest (re = 1) shell are most likely to be absorbed. The energy rule is the same as that for 0- decay: If the resulting atom
ftf

respectively, and + unstable if it

the rest

mass

of an electron.

An atom

is

electron were confined in a region of dimensions no larger than _ about 2r = 1.4 10 " tn, the electron would have momenta as

is

lighter than the original

atom,

it is

unstable to

capture.

The changes
often

resulting from

various nuclear processes are


17.4)
in
its

high as

represented in a proton-neutron diagram (Fig.


is

Ap =
ttt &,v

3.8

10

-'

kg-m/sec

= Um<c

which each nucleus


of the processes

plotted

in

terms of the number (Z) of


Z) of
its

protons versus the number (A


isobars (nuclei

neutrons.

It is

result,

and hence
E*
It

kinetic energy as high as

we have just discussed that no two adjacent with same mass number) can both be stable.
decay have

\/{Ap')*c s

m<c*

m.c'1

14m,c s

7.2

Mev

The heavier will #-decay into the lighter. The energies of electrons and positrons from

seems unlikely that there are attractive forces in a nucleus which are sufficiently strong to bind an electron having this much

been determined with various types of /3-ray spectrometers. In principle, they measure the momentum of an electron by (hiding
the curvature of
its

path

in a

known magnetic

field. It is

found

energy.

that electrons

in

a given type of 8 decay

may have any

energy up

248

Looking In: Atomic and Nuclear Physics

Radioactivity

249
it

but not observed! This particle shares the disintegration energy


&T,

is

called the neutrino. Since

with the electron, the continuous energy distribution observed for the ff particles (Fig. 17.5)

can be explained. The neutron


Orig.
~
nucleus

is

assumed to have zero


is

rest mass,

so the only change needed in our previous equations

to replace
reac-

Ek
K CQpt
It

by
is

Ek +

SfcneutrUo-

The neutrino
it

participates only in

tions. Since it

has no rest mass,

travels with the speed of light.

principle.

postulated to have spin $ and to obey Pauli's exclusion The neutrino lias no electric charge, and it is difficult to

detect! This remarkable particle has been

A-Z
Rg. 17.4

proton-neutron diagram.

assumed as necessary by physicists since about 1934. Its existence was first experimentally demonstrated in 1956, by detection of y rays produced in a planned sequence of events initiated by the neutrino.

to the calculated energy release Q (Fig. 17.5), Here is a difficult; with the hypothesis that & decay consists of the emission of an electron (or positron) and the conversion of a neutron to a proton (or proton to a neutron). Tor the nuclear change is from one state of definite energy to another state of definite energy. Yet the
electrons emitted carry varying

17.8

NATURAL RADIOACTIVE SERIES

In experiments which followed the discovery of radioactivity,

amounts

of energy,

up

to the

another difficulty. Consider the # decay of a nucleus containing an even number of nucleons. Its angular-momentum quantum number is an integer, since there is an even number of spin-i particles present. If a single electron is
available.
is

maximum

There

number of substances were found to show activity. It was found that certain of these substances were associated with each other in series, the successive members being formed by the disintegration of the preceding member, until a stable nucleus is
quite a
reached.

One can
classes,

predict that there should exist four separate decay

Fig.

17.5

continuous

spectrum.

series. A nucleus belongs to one of four depending on whether its mass number A has the form 4n, 4n -+- 1, 4 + 2, or 4n + 3, where n is an integer. Radioactive decay of a nucleus in one of these will result in the formation of daughter nuclei in the same class. This follows since there is no change in mass number in decay or in 7 decay, while

chains or radioactive

= 4. The four radioactive series are represented Each bears the name of its longest-lived element. The neptunium series is not observed naturally because gaNp ! " (T = 2.2 X 10 s year) has almost completely decayed
in
in

decay, A.l
17.6.

Fig.

since tin- formation of the elements (about

10'

years

tigo).

now
odd

created, there will be an


integer.

odd number
in

of spin- particles
will

and
is

the total angular-momentum

quantum number

be half an

But a spontaneous change


these difficulties,

angular

momentum

not possible.

end with stable isotopes of lead. A few radioactive isotopes which do not belong to the heavy-element chains are found in nature, Table 17.1. When the elements in a radioactive series are allowed to
of these four series

The decay schemes

To remove

we assume that along with


is

the

electron, another particle, also of spin4,

created and emitted,

accumulate, a steady state will be reached (if the parent atom has a long half-life) in which the number Nx\i of atoms of one isotope

250

Looking In: Atomic and Nuclear Physics

Radioactivity

251

Thorium series

N-A-Z -z,
140

(A = 4n)
J >Th" -

?
N = A-Z
140
Lrv."* Th

Table 17,1

Isolated natural radioisotopes

Neptunium

series
I)
\

Isotope

Decay

(A-4H +
\

NpJ "

Half-life (years)

y\

iH

r
r ,K r r r
a

12.4
5,590 10" 1.2

Created continuously

>
1

Ra

Ht

VA
'Ho

.C"
nK

by cosmic radiation in atmosphere

Li'

^Rb"
.lo

Jf
r

,li

6.2 6
2

stLo""

'

14

130

r; Ph
Tl

130

J"V

/A Ml
Pc
s

M Sm 147
7ito 176
76 Re"<

"

r
r

1.5 2.4

X X X X X X X

10">

10 14

10" 10"
10'

10 12

Pb*"^. r"
Pb
!0S

Tl
1

80

84
Uranium

88
series

93

SO

84
Actinium

88
series

92

isotope whose half-life is too large or too small to make a particlecounting experiment convenient.

(A = An +

2)

yJM

N=A-Z

(A = 4n +

3)

PROBLEMS
1.

-6
u
Th
iJ
'

Radium

has a

; j

partiele to

become radium
-J

positive charge? (b)


131

days. Radium E emits a 0Which nucleus (E or F) has the greater Starting with 1.0 gm of radium E, how long would
half-life of 5.0

P. (a)

140

it

take for
2.

gm

to decay into radium


vertically

F?
earth's

Ac'V
* r itoJ

particles shot
field in

upward arc deflected by the


(7*

Th'

37

magnetic

which direction?

C
Rr,*"
15

111

130

Pb
1

,u
.

s"
I

Pc-

11

Hb

mc. Ans. 4.0!) X 10-" gm 4. Five mg of IV '" {T - 140 days) are allowed to decay for 1.0 year. What is the activity of the sample at Hie end of that time? Ahx. 1.35 X 10" disintegrations per second 5. A sample of radioactive sodium (XaT = 14.8 hr) is assayed at 95 mc. It is administered to a patient 48 hr later. What is the activity at that time? Ans. 10 mc
of
1

3. Calculate the

mass

Au l,s

2.7 days) in a source of 1.0

6.

What
I

is

80
Fig.

84

88

92

80

84

88

92

17.6

Decoy schemes of

the four families of natural radioactivity.

! Ans. fi.fi X 10~" 7. Suggest a method for using data on the uranium-decay series to estimate the age of the earth, Suggest B waj of using the radioactive isotope of carbon C u (T = 5,600 years) to substantiate the age of cotton fabrics found in an Egyptian tomb.

at 0C and

atm

the volume of 1.0 pressure?

mc

of radon.

M Hn

m (T - 3.82 days),
m

of the* next isotope


JV.Xi

which decay per unit time is equal to the number which decay per unit time, or

A/oX* of

atoms

N \2
2

iVaXa

=
is

(equilibrium}

(17.21)

This equilibrium equation

often used to calculate X for an

Nuclear Reactions

253

The

first artificial

nuclear transformation was achieved by

18
Nuclear Reactions

Rutherford in 1919, in bombarding nitrogen with a particles Because of the imporfrom a natural radioactive source, Ha we shall depart from reactions, nuclear tance of neutrons in of the neutron by discovery first the historic sequence to discuss

Chadwick

in 1932.

Among the achievements of

nuclear studies are the production

of scores of valuable isotopes, the discovery of the neutron and other particles, and the release of energy in the processes of

nuclear

lis.sion

and

fusion.

18.1

DISCOVERY OF THE NEUTRON


particles

Bothe (1930) found that when a


No man
the
will

from polonium

fell

on

ever comprehend

the

a beryllium foil, a penetrating radiation was emitted. Irene and Frederic Joliot observed (1931) that the intensity of this radiation

real secret of the difference

between

ancient world

and our present

time, unless he has learned to see the difference

which

the

late

develophas

ment

of physical science

made

between the thought


the thought of that.

of this

day and

T.

H. Huxley

was apparently increased by passage through paraffin. They suggested that Bothe's radiation was y radiation which knocked out fast protons from paraffin and other hydrogen-rich substances. Chadwick (1932) applied the equations for the Compton effect to the head-on collision of the assumed y ray and proton (mass m) and showed that the maximum energy given to the proton by a photon (hv) would be 2hv/(2 +- mc*/hv). Experimentally the recoil protons from paraffin were found to have a

maximum

energy of 5.7 Mev, requiring thai the y ray from Be


").">

particle directed at a nucleus

may undergo

a collision (elastic

scattering) which leaves the struck nucleus unaffected. A second possibility is that a nuclear reaction takes place producing sonic

change

in the struck nucleus. The incident particle may be absorbed into the struck nucleus. A rearrangement may occur in which the incident particle remains in the nucleus and another particle emerges. The incident particle may emerge but leave the nucleus in a different energy state. There are other possibilities. Nuclear reactions may be caused by individual nucleons, photons,

Mev. Hut when aifcrogen was subotitvted have energy hv for paraffin as a target, the i.'2-Mev recoil nitrogen ions which were observed required that the same y ray have an energy of 90 Mev. Chadwick resolved this contradiction by suggesting that the "rays" from Be were actually neutrons, whose existence had been proposed by Rutherford in his mode! of the nuclear atom. The fact that atomic masses (beyond i\V) are roughly twice the atomic number suggests that the two types of particle neutron and proton which constitute a nucleus have approximately equal mass. Chadwick confirmed this expectation by
calculations
5

made on
IIe<->
,'

the reaction

B"

+ NM + Q
7

08.1)

deuterons, a particles, and heavier particles.


252

Three of the four masses were known. The energy of the incoming a particle (from Po) was known. The value of Q was determined


254
Looking In: Atomic and Nuclear Physics
of tlic

Nuclear Reactions

255

from the observed increase in kinetic energy. The mass neutron was thus found to ho 1,00(57 amu.

proportional to the

number

of nucleons

added;

K H /A

does not

change appreciably.
protons
these

18.2

NUCLEAR FORCES; STABILITY OF NUCLEI

Present evidence indicates that the nuclear force between two is the same as the force between two neutrons and that

The hypothesis thai atomic nuclei sire composed of neutrons and protons is now well established, and the term "nucleons" is used to refer to these nuclear particles collectively. The size of the
nucleus
electrons
is

equal to the force between neutron and proton. property of nuclear forces which we shall mention is pairing. The stable nuclei usually have even numbers of protons

may be
last

The

estimated by bombarding atoms with high-enerLiy and counting Imw many of them score direct hits. The
.1

radius of a nucleus containing approximately

nucleons

is

found to

be

10

Iin, n

1.2

ID

,!'

(is. 2*

/
f-

An atom is stable because of the Coulomb force of attraction which binds the electrons to the nucleus. Within the nucleus, however, the Coulomb forces exerted by the protons are forces
repulsion which tend to
of

<>]'

make

the nucleus unstable.


fission

The

emission

particles

from nuclei and nuclear

(Chap. 20) are

evidence of

this. Somehow the repulsive Coulomb forces within a nucleus must be counterbalanced by strong attractive forces,

different from electrical

and gravitational

forces.

The nature

of

these nuclear forces

is

only partly understood.

We

shall discuss 20

some of the facts which arc known about nuclear forces. An important, distinctive property of unclear forces is (heir short range. The nuclear force between two nucleons becomes
negligible
if

40

60

80

00

20

40

60

80

200

220

240

they are separated by more than about

1,4

10 -16 m.

Fig. 18.1

Binding energy per nudeon as a function of mass number A.

In contrast, gravitational and electrical forces have no upper limit on the distances over which they may act. A second property of nucleus forces may lie deduced from a graph of the binding energy per nucleoli /;,, .1 against the number of nucleons A (Fig. IS. I). Kxccpt for the lightest nuclei. EB .1 is

and

Only the four light elements iH s sB ", and 7 X U have odd numbers of both neutrons and a Li, protons, and for these elements the numbers of neutrons and
of neutrons (Table 18.1),
1

protons are equal.


Table 18,1
Neutron
Evidence for pairing
Proton number
Z)

approximately constant, about 8


the number of nucleons
for a

Mev

per micleon. Thus the

total binding energy increases approximately in proportion to

Coulomb

force

in the nucleus: K a A. (The relation would be B = A 2 .) This relation implies

number (A
Even

Even

Odd
52
4

that a given nucleoli

is bound not to every other nucleoli present, but only to its nearest neighbors. Then the addition of more nucleons increases the total binding energy only by an amount

Odd

160 56

256

Looking In: Atomic and Nuclear Physics

Nuclear Reactions

257

When
made

a plot of neutron

number versus proton number

is

one observes a gradual increase m the neutron/proton ratio with increasing Z. This is explained by the fact that the Coulomb (repulsion) force between protons increases more rapidly as the number of protons in the nucleus increases than does the effect of the nuclear force between protons. This difference in the behavior of the Coulomb pp force and the nuclear pp force accounts for the gradual decrease in E B/A from
for all nuclei (Fig. 18.2),
160

stand for the incoming and outgoing particles, respectively, and the symbol following the parentheses represents the residual nucleus. The reaction associated with Chadwick's discovery of the neutron, Eq. (18.1), may thus be abbreviated as Be 9 (a,n)C.
Before artificially accelerated particles became available, about
1932, only 10 nuclear reactions were
It

known,

all

of the (a,p) type.

seems probable that


first

in

the majority of artificially produced


is

unclear reactions the


nucleus.

step

the formation of a

The

projectile

and the target nucleus

coalesce.

compound The com-

pound nucleus
one
or,
ity.

is unstable, because of its excess energy. It emits sometimes, more particles of high energy to regain stabil-

140

emitted by
120
i

Rutherford bombarded nitrogen with a particles (li)li)), he initiated the first nuclear transmutation by artificial means. The equation describing it in terms of a

When

Ra

"*

compound nucleus
100
-t

is
l

a
E

/
80

/
s

Fig.

,He<
18.2

+ ,!?"- [F

*J-0"

,11'

(18.1)
flic

/ ^
p 60

Neutron -proton plot

for stoble nuclei.

The same compound nucleus (but

not in

same energy

state)

could be produced by other reactions

/
/*

40

20

The breakup
only on

its

duced
80 100

it.

of the unstable compound nucleus usually depends energy state, not directly upon the particle that proThere are often several possibilities; for example,
l

20

40

60

Proton number,

U*Zn 6i

-^

w&l

+ +

T ,H J
ill
2
,

about 8.8 Me? for A near 50 to approximately 7.0 A = 240 (Fig, 18.1).

Mev

for

-+, Cu"
The 3 o*Zn Si may
n',

also eject other particles;

iH*,

sHe or two
1

but the probabilities of these reactions are low. Present

18.3

NUCLEAR-REACTION EQUATIONS
shall consider
,r

nuclear theory does not permit prediction of the

way

a particular

We
?/

compound nucleus
some
possible

will

break up.

outcomes when a

particle or

nucleus

strikes a nucleus

bike chemical-reaction equations, nuclear-reaction equations

resulting ha the emission of particle


J":

and the obtaining of nucleus


z

}
is

+
symbols
in

(18.3)
first

The

notation

often abbreviated as X(.c,y)Y, where the

symbol stands

for the struck nucleus, the

parentheses

must be balanced. The total electric charge (the number of protons) must be the same before and after the reaction. The total number of nucleons (neutrons and protons) must be the same, before and after the reaction. Together, these requirements mean that the number of neutrons must be the same before and after the reaction, likewise the number of protons. (There are two

258

Looking

In:

Atomic and Nuclear Physics

Nuclear Reactions

259

If we regard ft* decay as a "reaction," then since there no incoming particle, the number of neutrons changes by and the number of protons changes by + I. At extremely high energies, greater than 2 Hcv, it becomes possible to create micleou pairs. In such reactions, which we shall not discuss, the number of nucleoli* docs not remain constant.)

exceptions:
is

minimum

value of A"*.., which makes the reaction possible is called the threshold energy. The minimum value of /;**. z which satisfies

the equations for both conservation of energy and conservation of momentum is found to be

Threshold

(*.,)

ni n

(l

(18.0)

18.4

THRESHOLD ENERGY
4- .Y

Example. Find the threshold energy

for the reaction

In a nuclear reaction .r >j, the net increase in kinetic energy is called the disintegration energy Q. This Q is the net
1"

4-

,|jm

)H _*
i

,()!*

i
p

(q

= _3.4 S
1

m,. v )

decrease

in rest

mass, expressed as

Threshold

its

equivalent energy:

Q =

".v/

Mev = + ^1)3.48 14.00//

3.72

Mev

Q =
Q =
Since

H+m
initial

x ) - (m v + Tn.u )]c l rest energy final rest energy

(18.5)

PROBLEMS
1.

State the
,[,i*

number
fi

of protons
1S

and neutrons

in

each of the following

Q is the amount of rest energy eon veiled into kinetic energy, Q is often called the energy release of the nuclear reaction. For an encounter which results in elastic scattering, Q = 0, If
the

nuclei:
2.
,l.i

6 I!e",

C 13

S 3B and
,

n Ui tm

The nuclear read ion

,II->2-.Hc*

+Q

value of a reaction

is

positive, the reaction

is

called exo-

thermic.

Such a reaction can occur

for incident particles of


is

any

kinetic energy. If

has a negative value, the reaction

called

emlolhermic.

Example. Calculate Hie

value for the read ion


15.011)512

X +
14

n'

- 7 ,V l * 4-

,V
n'

liberates 22.4 Mev. Calculate the mas-, of JLa* in amu. (I)eutcron = 2.014180 amu, a particle = 4.00:3873 amu.) 3. Imagine that a free neutron gives off an electron and changes into a proton. Calculate the energy Q which is consumed or liberated in this process. What does your answer suggest about the stability of free Ins, Q = 6.79 Mev neutrons? 4. When neutrons :ire produced by bombarding deuterons with

i.odt.vji;

dcutcrons, the reaction

is

represented by
o"
1

= m = 16.016512 Q = 931(0.01 KM) Mev =


1.00898(5

X' 6

i;-).illMs7s

amu -H0.K Mev


O.OlKiS-i

,H*+
energy?

,II i

-.

! lle

Q
have at
least

The neutrons produced

in

this reaction will

how uiurh

imposes a condition on induced other collisions. This condition is particularly important for reactions with negative Q value. Prom energy considerations alone, one would think that ir the incident particle x approached the target nucleus (at rest) with a kinetic energy A'*.* = Q, then the reaction would occur. But then the momentum would not be conserved. The initial momentum is greater than zero, but the final kinetic energy, and thus the
nuclear reactions, as
it

Conservation of

momentum
does on

all

bombarding deuteron. he energy radiated by stars, it has been suggested that a series of nuclear reactions such as this carbon cycle occurs:
15
plus the kinetic energy of the
I

Am.

Mev

.">.

As the source of

C" + H' ..V + 7 X - C + e + + neutrino C" + H' X 14 4 7 \u + H'^0" + 7 O lb -* N" + e* + neutrino


la
1

Q =+l.o Mev
(K t $) , = 1.20 Mev Q = +7.58 Mev Q = +7.34 Mev (A\ a),,,.,, = .UN Mev Q = 4-4.98 Mev
'

'

momentum, would be zero. So, actually the incident particle must have enough kinetic energy B** so that the outgoing particles can have the same total momentum as the incident particle. The
final

K' B

II

-*

C 12 +

lb'

Write the equation which represents the net result of this whole cycle. v Ans. 4H * He* 4- 2e 2 neutrinos 4- energy
l

Absorption of Radiation

261

carries an electric charge (as

do the electron, positron, proton,

deuteron, and a

particle) will exert a force on each electron near

19
Absorption of Radiation

which

it

passes.

charged particle collides with


is

in traveling even a short distance in matter. In

collisions,

knocked out kinetic energy as it leaves behind a trail of ion pairs (ejected electron and ionized atom). A stream of charged particles is referred to as an ionizing radiation. Photons and neutrons which carry no charge do not necessarily collide with every electron near their paths. Streams of uncharged
the struck electron
incident charged particle loses
its

many electrons many of those of its atom. The

particles are called nonionizing radiation.

19.2

DETECTORS

Science has a social value, and the

man

of science cannot
It is

wash
his

his

hands

Ionizing particles are easy to detect electrically. In an ionization

of his discoveries.

duty to see

chamber, a metal cylinder


cylinder along the axis.

has a wire
is filled

II'

insulated from the

that they are used for the betterment of

The tube

with gas at low pressure,

mankind, and not for

its

destruc-

and a potential

tion,

Fournier

slightly less than that reiumed for a discharge is maintained between cylinder and wire. A thin window allows particles, say, a particles, to enter the chamber. Kach particle ionizes the gas, producing a rush of charge and a fall of potential at P which actuates a counter circuit. Thus one can count the number of a particles. The behavior of the ion pairs created can be studied by plotting a curve of the size of the current pulse

versus the voltage applied to the tube.

The

ionization

chamber

To

interpret experiments in nuclear physics and to apply the knowledge gained from them, it is necessary to know how the high-energy particles behave as they pass through mutter. For this discussion, high-energy particle means one whose kinetic energy is much greater than the ionization energy of the atoms or molecules of the material in which it is passing. We shall discuss

Capacitor

#
resistor

To amplifier

and counter

Bottery

the absorption of radiation chiefly in relation to the identification


of particles, the

1
Fig. 19,1

measurement

of radiation dost;,

and the probIonization

lems of

human

health.

chamber

particle counter.

19.1

TYPES OF RADIATION
an
electric charge.

(Fig. 19.1), the proportional counter, and the Geiger-.Muller counter are ionization instruments designed to operate on dif-

Jn the behavior of a high-energy particle the most important fact


is

ferent regions of the curve.

whether or not

it

carries

particle

which
260

scintillation counter

makes use

of

one of several substances

262

Looking In: Atomic and Nuclear Physics

Absorption of Radiation

263

which, when struck by a single particle, convert some of the energy received in the collision into visible tight. About. ])()(
investigators
light
l!)-l
I

depresses the temperature of the vapor below its "dew point." Some of the vapor will now condense. A vapor condenses prefer-

<rf radioactivity watched and counted the flashes of which individual a particles produced in zinc sulfide. Since a scintillator or phosphor such as a clear crystal of naph-

on charged particles, as nuclei for droplets, if there are any present. So, if the gas has been traversed by a particle which
entially

ionized molecules along

its

path, the vapor will condense on these

ions and the path of the particle will be visible as a trail of liquid
droplets.

of radioactivity

Al

foil reflectors

Photo cathode
semi transparent

Photographic plates were used by Bccquerel in his discovery (1886). Recently the manufacture of special emulsions for nuclear research has revived the use of this type of detector. Nuclear emulsions contain about 10 times the concentration of silver halide as do ordinary photographic emulsions,

and are much

thicker. Xuclear emulsions

can be made sensitive


(I

to slow neutrons by incorporating small amounts


First

per cent) of

dynode

lithium or boron, which undergo an (n,a) reaction. Emulsions may be "loaded" with other elements (such as uranium) to study specific reactions. In film badges, the general darkening of the

photographic emulsion, on development, measures cumulative exposure to radiation. In autoradiography, the distribution of radioactive material in a tissue or mineral section is determined
Tenth dynode JJ

"

-".-.j-

"-

Col lector grid

Output
Fig. 19.2
Scintillation counter.

by placing the specimen in contact with a photographic plate, in the dark, and developing the resulting pattern. The bubble chamber, invented by D. A. Glaser in 1952, takes advantage of the instability of superheated liquids for bubble formation, much as the Wilson cloud chamber uses the instability of supercooled vapors for droplet formation. The cloud chamber and the bubble chamber have similar general characteristics as
particle detectors.

The

resetting time

is

longer than lor counters.


lie

thalene has been used

in

conjunction with a

The
pilot onmlfiplier, for

advantages of the bubble


its

chamber

in

the high density

automatic counting. A particle or a -y-ray photon entering the phosphor causes a flash of light which is reflected by the aluminum foil onto the photocallmde. Klcctrons are emitted from it, and
these are subsequently multiplied to produce a relatively large pulse at the output of the tube.

(greater absorption) of
recycle
in

sensitive material

and

its ability

to

a few seconds.

Bubble chambers

filled

with liquid

hydrogen offer simplicity in interpreting without contaminating elements.

collisions with protons,

A cloud chamber, invented by C. T. It. Wilson in 18117, permits us to see the path of a particle through a gas. It consists of an enclosure filled with air and some vapor at a temperature just above, the condensing temperature. The chamber is designed so that its volume may be suddenly increased. This expansion

19.3

DETECTION OF NEUTRONS

neutron is attracted to other near nucleous by the nuclear force, but it is neither attracted nor repelled by an electric charge. Since a neutron and an electron exert no forces on each other, they do not collide. (We can neglect for practical reasons the

264

Looking In: Atomic and Nuclear Physics

Absorption of Radiation

265

extremely small gravitational force between an electron and a neutron and also a small electromagnetic force associated with the magnetic moments of the two particles.) Since nuclei occupy only a small fraction of the volume of matter, neutrons are penetrating radiation, traveling relatively large distances between collisions. When a collision does take place, either the neutron is scattered or a nuclear reaction occurs. Since neutrons do not betray their presence directly in
detectors (Sec. 19.2), they
results

19.4

ABSORPTION OF PHOTONS

Photons can interact directly with the electrons of the material through which they pass. But for high-energy photons, the cross
(probability) of such interact ions is so small that the photons constitute an extremely penetrating radiation. The energy of photons can lie dissipated in three different kinds of

section

collision.
effect a photon is absorbed by an atom; its eject an electron and to impart kinetic energy used to energy section for the photoelectric effect cross The electron. to the atomic number (Z) and deincreasing with rapidly increases

must he detected by the ionization which

In the photoelectric
is

from some nuclear reaction of scattering. For slow neutrons (having kinetic energy less than I ev) it is convenient to
use the reaction

JB-f oNi-
If

Ji-|- ,He
is filled

creases rapidly with increasing energy (hr) of 6he photon.

a counter tube
is

the wall

with a gas containing boron, BK or if 3 coated with boron, then some neutrons will he captured
,

positron and an electron

In pair production, the energy of the photon is converted into and their kinetic energies. The cross

section for pair production increases rapidly with increasing

to give fast

particles,

which

will

cause ionizations in the gas


of

and give counts. Another method used to detect slow neutrons makes use
the reaction
on 1

of the absorber and with increasing energy of the photon, above Mev (= 2m c 2 ). the threshold value of Campion In the effect, photons are in effect scattered, not
1

absorbed.
16

A photon

is still

in

play after the collision.

The

cross

^In'

-* win" 6

The radioactivity of an indium foil after exposure to a neutron beam is a measure of the number of neutrons which passed through the foil. The (n,y) cross section, or probability of capture, is sharply higher for neutrons of l.4(S-ev energy. detector favors or picks out those neutrons.

section is a slowly varying function of (hv) and Z. The detection of photons is relatively simple; for any type of collision described above gives a fast electron: a photoelectron,

Thus

this

The

detection of fast neutrons, and the initiation of certain

important reactions, often requires first that the neutrons be slowed down. This is accomplished by arranging for the neutrons to pass into a moderatora material such as graphite or D,,0 in which the probability (cross section) for scattering is much larger than that for a nuclear reaction. The neutrons then bounce around among the nuclei until both reach an average energy of !i/,-r, where k is the Boltzmaun constant.

an electron-positron pair. The electrons are ionizing particles and may be counted directly. The variation of photon "absorption" by each of these processes is represented in Fig. U)M, where for each process, an absorption coefficient a is defined as the product of the cross section a of the reaction and the number n of atoms per unit, volume, a rur. If the Compton effect were strictly an absorption, a total absorption coefficient a, could be defined for photon absorption
a

Compton

electron, or

Ctt

OfphutM "T" G^air

^Complin

ami the attenuation of a beam of x rays or 7 rays could be represented by the exponents! equation

Bxampk. Find
22

the energy of a "thermal neutron"

in

n moderator at

Bk =
=

10-" joulc/K)(295K) |(1.3H 0,0382 ev

6.11

10~" joule

While this relation has practical usefulness, it must be applied with care, since eeoinpton does not relate to a true absorption.

266

Looking In: Atomic and Nuclear Physics

Absorption of Radiation

267

a, cm"
|.

1.4

i
\
^
^

a niol
^*m
1

1
1

1.2 1.0

\ \

'

\ V

A
\

J* /?

in aluminum; a 10- Mev a particle energy travels only 0.0 in aluminum. travels only 0.00(> The decrease in the kinetic energy of a charged parlislc with distance traveled is indicated schematically in Fig. 19.4 as

mm

mm

occurring

in

many

small steps.

The distance

traveled before the

Jya. ra

kinetic energy

is all lost is

called the range of the particle.


its

Range

0.8

0.6 0.4 0,2

\%~4
V

A
--_
50
500 Mev

depends on the
material.

particle,

initial

energy, and the absorbing

When the kinetic energy of the charged particle has been reduced to a small value (about 100 ev for a proton), it becomes increasingly probable that the ion will capture an electron and end as a neutral atom.

v^
0.5

5
Photon energy

19.6

ABSORPTION OF ELECTRONS AND POSITRONS

Fig.

19,3

Variation of photon absorption coefficient, a,

in

The path

load, with photon energy.

19.5

RANGES OF HEAVY CHARGED PARTICLES


particles

of an electron or positron is longer than that of a heavy charged particle of the same energy, but it is a path full of bends because of scattering. Electrons, like other charged particles, lose their energy in a very small region of space; they do not constitute

a penetrating radiation.

heavier than electrons experience frequent, collisions with electrons in passing through matter. The heavier
particle cannot

Charged

appreciably deflected, and il can lose only a small fraction of its energy in collision with an electron. Vet the
lie

19.7

RADIATION DOSE

collisions are so frequent that

charged particles are slowed down

to thermal energies in very short distances.

Charged

particles are
of kinetic

not a penetrating radiation.

The dose of any kind of radiation received by an object is the amount of energy that the object absorbs from the radiation. One might try to use a calorimeter to measure the energy absorbed by a specimen in terms of the resulting rise in its temperature. It turns out that- even a lethal dose of radiation produces an undetectable rise in the temperature of a biological specimen.
Radiation produces
ical,

proton with 10

Mev

many

specific effects

on physical, chem-

and

biological systems.

Many

of these effects

related to the ability of the ionization caused

promote particular chemical


devised to specify dose
in

reactions.

seem closely by the radiation to Hence methods have been

(1

terms or ionization. A beam of x rays or y rays is said to give a dose of one roentgen r)* if it will cause 2.08:{ X 10" ionizations in cm 3 of dry air at
J
1

Distance traveled,
Fig. 19.4

Kinetic

energy

vs.

distance troveled for a charged

particle.

National Bureau of Standards Handbook H47 gives the defishall be the quantity of x or y radiation such that he associated corpuscular emission per 0,001293 gin of air produces, in air, ions carrying 1 esu (if quantity of either sign," The figure 0.001293
nition:
i

"The

"The roentgen

268

Looking In: Atomic and Nuclear Physics


1

Absorption of Radiation

269

atm. An ionization chamber is used to measure the 0C and dose from the radiation. The radiation passes through the air between the plates, and the ionization occurring in the air is collected. The chamber and its electrometer can be calibrated to
read directly
in

damage from external sources will be confined to a thin layer of emitters become internal hazards when introtissue. But a and duced into the body in foods or otherwise. The various kinds of radiation damage seem to he statistical
with no threshold or "safe" minimum exposure below which no injury occurs. Hence it seems prudent, to avoid all unnecessary radiation exposure. Since some exposure may be
in nature,

roentgens.

dose rate

is

0.3 r per week.


is

widely accepted human tolerance The dose from cosmic rays at the
of this tolerance dose.

surface of the earth

about 2 per cent

To extend the unit to permit measurement of radiation dose from other particles, and in living tissue, the roentgen equivalent physical (rep) is desigdefined for photons.

The roentgen was

necessary for

some

people, responsible agencies have suggested

nated as the radiation which produces the same energy as one roentgen of x- or 7-radiation. This amounts to 97 ergs per gram of tissue. This value is based on the observation that for any
particle particle

whole-body exposure of 0.3 r per week when continued over a long time. I'or hands and feet the tolerance may be 1.0 r/ week. A single exposure of 25 in an accident can probtolerances, such as a
1-

ably he accepted.

probably be
exposed.

fatal,

whole-body exposure of about 500 r would statistically, to 50 per cent of persons so

and any gas the average energy lost by a fast charged per ion pair formed is about 33.5 ev, A third unit for
is

radiation dose

the red: the radiation which produces LOO ergs


19.9

per gram of tissue.

ATMOSPHERIC CONTAMINATION FROM NUCLEAR

WEAPONS TESTS
19.8

BIOLOGICAL EFFECTS OF RADIATION


is

The probable

Living tissue

damaged

>.V

exposure to high-energy radiation.

The danger

is

insidious, for the observed biological effects

may

effects on the health of the world population of atmospheric contamination arising from nuclear weapons tests cannol be assessed reliably from data known at present. Vet on the basis of incomplete information and conflicting interests,
political decisions

be delayed for periods ranging from a few days to years, depending upon the type of radiation and the dose received. Among the
effects of
of

vitally affect our national defense

overexposure to radiation are a decrease in the number


cells,

generations to
If

about nuclear detonations must be made which and the freedom and health of come.

white blood

loss

of hair,

sterility,

cancer, cataracts

from neutrons), and destruction of bones. In addition to the damage to the person receiving the radiation, there may be genetic effects extending through many generations of offspring. Penetrating radiations are effective in producing mutations or changes in heredity.
(chiefly

rays, y rays, and particles from supervoltage accelerators penetrate tissue readily and constitute externa! radiation hazards. In general, and /S particles have low penetrating power, and
the muss of

one examines, in addition to research reports, some 10 statements made since !>.">(> by the Congressional Joint Committee on Atomic Energy, the United Nations Scientific Committee on the Effects of Atomic Radiation, The National Research Council, and the (British) Medical Research Council, one finds that these responsible bodies are in agreement on the
official
1

following points:
1.

Kin

is

cm 3
I

of charge

coul,

of dry air at 0C and produces


1

atm. Since 3

10 s esu

Radiation exposure of the world population from fallout (including Si'"") as a result of tests through mid-1963 is small compared to natural background radiation and other man-

2.

made radiation (such as diagnostic x rays). Any amount of radiation, however small, may
but
finite risk of

carry a small

10 statcoul/coul 1.6

10-" coul/ion

increasing the genetic mutation rate of the

2.083

10 ion pairs/cm'

population.

270
3.

Looking In: Atomic and Nuclear Physics


Tt is unknown whether or not there exists! a threshold radiation dose for the production of somatic effects, including leukemia,

Absorption of Radiation

271

SUGGESTED READING
Articles in the Bulletin of the Atomic Scientists.

bone cancer, and general


4.

life

shortening.

Calculations of biospheric contamination in the event of continued testing of nuclear weapons are intelligent guesses at
best, since conclusions

The Milk We Drink, Consumer Reports, March, 1959. Fallout, in Our Milk, Consumer Reports, February, 1960. The Huge and Kver-iiiereushig Problem of Radioactive Wastes, ConFallout

depend on the many assumptions that

must be made.
5.

sumer Reports. February, !)(!(). an interim report, Consumer Reports, September, 1963
I .
. .

Continued testing of nuclear weapons will increase biospheric contamination and consequent risk to the world population.
Accelerated testing as more nations become nuclear powers, and (he touching off of nuclear war, could result in a serious radiation hazard to world health.

19(iH.

I^utgham, Wright, and B. 0. Anderson; "Biospheric Contamination from Nuclear Weapons Tests through 1968," Los Alamos Scientific Laboratory, University of California, I.os Alamos, X.Mex. 100 pp. Contain.* bibliography of 7 ilems.
I

19.10

DISPOSAL OF NUCLEAR WASTES


I

Nuclear power ranuol be developed by present techniques without also producing radioactive waste materials which are harmful to man. The safe disposal of such radioactive wastes is far more
difficult
ti;5

often say that


it

when you can measure what you


is

are speaking about and


it;

express express
kind;
it

in in

numbers, you know something about


numbers, your knowledge
of a

but

when you cannot

It

meagre and unsatisfactory

than that of ordinary industrial wastes.

million gal of highly radioactive

More than nuclear wastes are now con-

may be

the beginning of knowledge, but you have scarcely, in your

thoughts, advanced to the stage of science, whatever the matter

may

be.

underground tanks because they are too "hot" to dump. Although the concrete and steel tanks are expected to last several decades, their contents will still be too radioactive to dump when the (auks have deteriorated! There has been increasing local public protest against the

fined in million-gallon

Lord Kelvin

Life

would be stunted and narrow

if

we

could feel no significance

in

the

world around us beyond that which can be weighed and measured with the
tools of the physicist or described by the metrical

symbols of the mathe-

dumping
shore
It
;

of nuclear wastes into the oceans, relatively close to the

matician.

Sir Arthur

Eddington

Cape Cod, Texas, and Mexico. has also been pointed out that it may even be dangerous to dump nuclear wastes in remote and deep trenches of the oceans because (I) experiments increasingly indicate thai there is conand (2) marine organisms tend to build up small and nearly harmless radioactive levels in sea water to potentially dangerous levels in the food supply. At the present time there are four general sources of radiation which can harm the present and future generations. In order of
intensity, these are (1) medical

particularly by citizens ul

Accurate and minute measurement seems

to

the non -scientific imagination

a less lofty and dignified work than looking for something new. But nearly
all

siderable circulation of ocean waters

the grandest discoveries of science have been but the rewards of accurate
patient long-continued labor in the minute sifting of

measurement and
numerical results.

Lord Kelvin

It

does not take an idea so long


the arts.
K. K.

to

become

"classical" in physics as

it

does

and dental

x rays, (2) radioactive

in

Darrow

sources naturally present in the earth, (3) radioactive fallout from nuclear testing, and (4) waste products from nuclear reactors. Within a decade or two, the latter two sources of radiation

exposure

may become

the most important.

Unconventional Energy Sources

273

reserved for those untapped sources ahout which enough is understood today so that one may reasonably predict that engineering refinements will soon make of them practical energy

20
Unconventional Energy Sources

sources, important in our


electric, thermionic,
cells,

and

fuel cells

economy. Nuclear reactors, thermoami magnetobydrodynamic generators, solar give promise of becoming increasingly impor-

tant practical sources of energy.

20.1

NUCLEAR FISSION

When, in 1042, the book "Applied Nuclear Physics" (K. Pollard and W. L, Davidson) was published, its title sounded visionary. Since then we have witnessed important and varied applications
of nuclear physics.

The nuclear

reactor has heen developed into a

the discovery with which

we

are

dealing involves forces of a nature too

dangerous
concepts. T87S,

to

fit

into

any of our usual


Record,
gasoline

may become the ultimate source of power for space travel.) With particle accelerators and nuclear reactors, a host of new isotopes have been
practical source of electric power. (A reactor

Congressional

commenting

on

the

engine

A physicist, like other persons, often finds living more purposeful and satisfying when he haw both short- and long-range goals.

Some

physicists seek to relate their goals to

some

of civilization's

long-range problems: food production, world peace, education, and the exploitation of new sources of energy. It would seem that
physics could contribute most directly in finding new sources of energy to supplant depleted reserves of coal and oil and to meet the ever increasing demand for power for industry, transportation,

These have been important in further fundamental also found diverse practical applications. In 1934, Fermi and his collaborators attempted to produce elements beyond the normal limit at uranium. In bombardment of the lighter elements by slow neutrons, the element after the capture is usually transformed by electron emission into the element of next higher atomic number. Therefore, one might expect that a similar bombardment of uranium (Z = 92) would produce a new element (93). This reaction has been produced with neptunium (93) as the resulting product. Neptunium also disintegrates by emitting a (i particle to produce plutonium (94). Plutonium is a rather stable clement having a half-life of 24,400 years. From 1944 to 1950, four other new elements were produced in the cyclotron: americium (95), curium (96), berkclium (97), and californium (98). More recently elements einsteinium (99), fermium (100), mcndelevium (101), and nobelium (102) have
created.
studies.

They have

and the home. Since we never create energy, it might be more precise to speak of a search for new and practical energy-

conversion devices.

Some

possible sources of energy are so speculative that they

been reported. In 1939, Halm and Strassmann found one of the products of neutron bombardment of uranium to be a radioactive barium 139 sijBa There must then be another fragment such as 36 Kr associated the barium fragment to make the charges equal. Ncir separated the isotopes of uranium in a mass spectrograph and
.

are referred to as esoteric sources.

The term "unconventional"

is

found that

U s,b

is

the one that undergoes the splitting process

272

274

Looking In: Atomic and Nuclear Physics


is

Unconventional Energy Sources

275

called fission. Fission

a new type of radioactive process, the first that produced particles more massive than a particles. In the process of fission of uranium there is a decrease in total

a process the two positively charged nuclei must come into contact even though there are strong electrical forces of repulsion. This requires thai lie particles he moving with high speeds. With
I

a reaction then

mass, and therefore there is a corresponding gain in energy. Such is a possible source of energy. This energy is controllable since the process can be started at will and its rate can be governed.

artificial

accelerating apparatus, a few nuclei are given very high

speeds.

Only occasionally
it

will

nucleus before

has

lost

too

much

such a particle strike another of its energy to make contact.

Thus

Among the products of fission one finds one to three neutrons. These neutrons are faster than the ones used to start the fission, but if they strike uranium nuclei, they can cause fission. Since
the fission produces the starting particles and releases energy, the reaction can perpetuate itself, provided there is enough uranium present so that the neutrons produced will hit other

the process is extremely inefficient, and more energy must be supplied to initiate the fusion process than is realized from the
reaction.

The necessary
is

condition for a controlled nuclear-fusion process

the attainment of high particle energies for a time interval long


to bring

uranium

nuclei.

Thus a chain
is

reaction can be set up.

The

smallest

amount
flux)

of material in

which a chain reaction (constant neutron

can be set up

called the critical mass.

20.2

NUCLEAR REACTOR
is

about kinetic equilibrium. Knergy must be supabout 2 X 10 7 K (at which thermal fusion occurs in stars). At the same time reactants must be confined. Ordinary walls will not suffice, for they would vaporize under bombardment of high-energy particles, and these would be quickly cooled below their fusion temperature. These problems of heating and confinement must be solved in any con-

enough

plied initially to attain temperatures

trolled-fusion reactor.

nuclear reactor

a device for utilizing a chain reaction for


:

The

choice of fuel for a eon t rolled-fusion reactor

is

made on

any

of several purposes

to produce power, to supply neutrons,

to induce nuclear reactions, to prepare isotopes, or to make fissionable material from certain "fertile" materials. Typical

the basis of availability and the probability of attaining with it the necessary high temperature. One would prefer elements of

components of a reactor are: the fissionable fuel (LI or Pu), the moderator (graphite or D a O to slow down the fission-producing
neutrons), the control rods (usually Cd strips, whose insertion captures neutrons and slows the fission rate), and the coolant (water, air, hydrogen, or liquid metal, such as \a).

low atomic number because of the low Coulomb barrier to be overcome in the fusion reaction. Possible fusion reactions are

shown

in Fig. 20.1.

In power reactors, the coolant, through a heat exchanger, furnish steam to operate a conventional turbine and electrical generator. Breeder reactors make new nuclear fuel from

heating first strips the electrons from the atoms to produce a "fourth state of matter," a fully ionized gas, or plasma. Further heating of the plasma is done by adding electric energy, in part by using the resistance of the plasma to produce familiar
Initial

may

Ohmic

(or Joule) heating.


fields

Suitably designed magnetic


drical current
(10

provide a sort of magnetic

substances which cannot themselves sustain a chain reaction but which can be converted into fissionable material. One
fertile

bottle to confine the ions at I0*K. In the pinch effect, a cylin-

amp)

contracts because of electro magnet it-

possible breeding reaction


T -,
*

is

forces (parallel currents attract each other).

The plasma

inside

is

t^l.
2'A

ruin

iNP^^MPO**
'2:.i

duy

(20-1)

thus compressed, producing very high temperatures. The simple pinch is unstable, but with suitable stabilizing fields thermonuclear temperatures have been attained for confinement time
of

20.3

FUSION
lie

Nuclear energy can also


larger nuclei
if

released by fusion of small nuclei into


is

about 0.001 sec. Thus far, however, the power required for these devices has exceeded the useful power gained from the
fusion process.

in this

process there

a decrease in mass. In such

THE FOUR STATES


1-Solid

OF MATTER
3- Gas
4-Plosrao

Unconventional Energy Sources


20.4

277

2- Liquid

THERMOELECTRIC CONVERSION

The
is

direct conversion of heat to electricity on a commercial scale a prospect that has fascinated scientists and engineers for

tlili
First

.hres itafei of roaMer vory with arrongenien.


ima'lleir parr.c1.ev

about within limiti.


(coflered Qnd

In

a got, moleculei ore

man
it

and movement of maleculei, ihe


C K roc t >
lii
;

movv

Foiier,

Fooith lfoie^ ploinna,

c of a
1

rrva

if io I
trill

tn to I id ,
In liquid

mo lee u

ei

or* cfoYe-packec ond

they tnovt

wholly '"ionized" 901. Molecule* break into aTorm, alonm into poiilive ion* and rega-ive elecrron>>.

decades. In 1821, Thomas Sccbeck noted thai heal -applied to one junction of a circuit containing dissimilar metals would cause a small electric current in the connected circuit. The physical median ism can be understood, qualitatively, in terms of the freeelectron picture of conduction.
electrons.

Proton

-THE FUSION REACTION-

O Neutron

Deuteriurn Fusion

3,25
Energy

field

Kach metal contains some free These electrons can be made to move by an electric or by a thermal field. If heat is applied at one end of the

He3

Mev
4

Mev

conductor, the electrons will rearrange to become somewhat more sparse in the warmer regions of the .specimen and more dense in
the colder regions. This leads to an electrical gradient.

En ergy

To

take

P
Deuterium -tritium fusion

advantage

of

it,

the circuit

is

closed through a dissimilar metal

Pi^rC^
He*
fusion con take piece within a plasma,
certain lighl element!.
rl

^^5 M^
energy
is

Fuiian

ii

from hydrogen fusion

On

earth

combination of nuclei (atom* minus electrons} of

most likely such reaction involves Twtopes


(voiiants)

Man of

the Fuiion product!

of hydrogen
In

let*

than that of orioinal nuclei; the difference

tritium.

deuterium and o plasma heated to millions of

Then, as long as the temperature difference is maintwo conductors will cause an electron flow, here clockwise. The efficiency of conversion, using the best metal combinations, was only 1 to 3 per cent. Thus, until recently the only
(Fig. 20.2).

tained, the difference in electrical gradient in the

h
1

radiated os energy, mojlly heat.

The

fcjn"

voit

degrees, they

may

fuse, as in the

H-bomb.

HEATING THE PLASMA


;'-..:
-

THE PINCH EFFECT

Direction of current-.
.

-....
A
it

To get controlled ihermonucleai reaction instead of explosion, small quonliriei of plasma

tuirenl eieaies o magnetic field around itself.

This Field exerts pressure

on plasma,
St,

"pinching,"
it

must be contained and heated.

Process begins

toward center,, compressing


But this

making

hotter

with passage 0! a current through the plasma


inside a Straight nr doughnut -shaped tube.

and preventing plasma


walls af tube
.

pari ides from touching


is

theoretical behavior.

-PROBLEM OF INSTABILITY-

-CONTROLLING INSTABILITY-

was in thermocouples to measure temperatures. Recent discoveries in the field of semiconductors have led to substantial improvement in thermoelectric conversion efficiency and foreshadow practical thermoelectric generators of power. One arm of the thermocouple may be made of an -type semiconductor, in which the voltage difference is established by the flow of negatively charged electrons. The other arm may be a p-type semiconductor in which the voltage difference occurs by the flow of positively charged voids (holes) vacated by the electrons.
practical application of Seebeck's effect

The

attractiveness of materials for thermoelectric converters

mm
In

can be specified by a figure of merit

defined as
(20.2)

Z =
Powige of new current (A) around rube create! a linear meaner ic field in column/ giving il "backbane/' Currenli induced in wo 111 of lube (B) help uraighren column. Pinch can then be mointoined
longer.
r/

4
temperature,

practice pinched column of ploimo develops

"kinky,"

Pinch wandert llighHy;

distortion af

where

he

magneric Held create* new forcer and diirorn

column further. Pinch eilher rouchei walk of r^re rub* and loiei energy (A) or ii broken or or (B)

T = S = = =

Seebeck coefficient, volt/K (i.e., emf developed per unit temperature difference in the specimen)
electrical conductivity,

Fig. 20.1

Principles of a thermonuclear reaction,

f Copyright

by

Trie

New/ York

(ohm-cm) -1

(i.e.,

reciprocal

Times. Reproduced with permission.)

of resistivity p)

k
276

thermal conductivity, watts/ C

cm

278

Looking In: Atomic and Nuclear Physics

mutators

Semiconductors

Metals

Both 8 and a depend on the density of conduction electrons in the specimen, as shown in Fig. 20M. It is apparent that for intermediate- and low- temperature use, semiconductors will provide the highest efficiency in thermoelectric converters. Pairs of
semiconducting comp<
ds

which have high conversion

effi-

10"
Electron density,
Fig.
tric

no./cm*

20.3 Properties that govern the choice of materials for thermoelecdevices, (Courtesy John C. Kelly, VVesfinghouse Research laboratories.)

40
Central station
Practical limits of thermoelectricity

- 30
c HI 9
esel or

marine

a.

o c
.2 'o

20
Present

^^

^S Automobile

Fig.

20.2
8.

A thermocouple

circuit

of dissimilar metals,

LU

and

The migration of electrons from regions of higher

10

density toward regions of lower density produces

o conAuxiliary power

ventional current

in

the counterclockwise sense.

ciencies

have been found by making binary ami ternary compounds of materials in groups I, III, and VIj or the periodic table: AgSbSe^, CuTiSt, etc. The numerous combinations possible make the task of screening and developing the most favorable thermoelectric materials a formidable one. Vet exciting progress

J
10

-L.

-L.

100

1000

10,000

100,000

Power rating, kilowatts


Fig. 20.4 Thermoelectric power devices con be competitive with other sources. {Courtesy John C. Kelty, Weslinghouse Research laboratories.)

power

279


Unconventional Energy Sources
281

has been made. Seebeck's original thermocouples (1821) could convert heat into electric power with an efficiency of only 2 per cent. Study of the PbS-ZnSb couple by Maria Telkes in 1833
raised the efficiency to 4 per cent. Further work with semiconductors has given the present efficiency of about 17 per cent. Theoretical considerations (using quantum mechanics) suggest that it will be possible to attain efficiencies as high as 35 per cent.

existing

make thermoelectric power devices competitive with power sources (fig. 20.4). Each of the germanium-silicon thermoelectric elements shown in Fig. 20.5 is capable of generating about -i watts upon exposure to heat at about 1000C. A
This
will

s<]uare-foot platelike

arrangement

of

snch elements could generate

up to

10 kilowatts, nearly three times the usual electric


in

power
the
in

demand
Fig. 20.0.
Fig.

a home.

Some

alternatives to be explored in

development

of a thermoelectric

power system are suggested

20.5

Power- producing

thermoelectric

elements

mode

of

germonium20.5

silicon

semiconductors.

(RCA

laboratories, Princeton, N.J,)

THERMIONIC CONVERTER

Heat source Nuclear Nuclear heat transFer


Fossil Fuel

Thermionic emission was noticed by Edison in 1883. In 1956 V. C. Wilson designed a converter in which electrons are "boiled
Thermoelectric
materials

Junction technology

^"Waste"

heat

J^Xv. Cooling
1

f
Insulator

MM*
"*-ia
Anode
Electrons
|

Load

Cathode

KS
Controls

Heat

Fig. 20,7

thermionic converter.

DC-motching voltage/
current inverters

Fig.

20.6

Thermoelectric

power system

alternatives.

{Adapted from the Genera/

Electric

brochure GEZ-3Q79B.}

out" of a hot metal and used to produce an electric current directly. One obvious difference between the thermionic converter (Fig. 20.7) and the thermocouple is that in Wilson's device the metals arc separated by a vacuum or a gas at low pressure. There is electrical Row between the electrodes, but there

280

282
is less

Looking In: Atomic and Nuclear Physics

Unconventional Energy Sources

283

flow of heat in this space than through a metal.

Thus ho
t

unit has the additional advantage of smaller weight per unit of

electrodes can be at different temperatures,


increased.

and the
20.8,

efficiency

is

power:

-!

versus

2.">

li>

kilowatt.

The conversion
energy
is

process

is

shown

in

l'"ig.

where electron

plotted against distance from cathode to anode.

The

20.6

MAGNETOHYDRODYNAMICS
Mill.) generator utilizes the principle discovered
in

base line corresponds to the energy of the electrons in the cathode. Heating the cathode "lifts" some of these electrons over the workfunction barrier
at.

An

by

l-'araday

that an ion moving


(Sees. 10.8

a magnetic held experiences a side push

the surface of the cathode,

wn

into the space

between electrodes. If the electrons can follow path a to the anode with only a small loss of energy, there will be a potential
rs
I
I

of

and 10.9), Hot ionized gas is forced between the poles an electromagnet (Fig. 20.9), producing a voltage difference
To regenerator

\ \

b
V \

~~
>
Cathode 140QK

^- -

^
< |

.1
Plasma drop

Hot gos Flow

T
J"

Anode

~ 700

Fermi level

a
gas
Fermi level
'

Output
voltage

Load

Flow

77777777777777^
Fig. 20.8 to

JV

Field

Current
electron energy vs. distance (cothode

A plot of
in

anode)

a thermionic converter.

difference between the electrodes, capable of doing

work

in

an
Fig, 20.9

external circuit. In

vacuum

devices, the electrons entering the

-VW
A magnetohydrodynamic
generator,

interelectrode space soon form a space-charge barrier, represented

by path

h.

This would increase the cathode electron energy neces-

sary to electrons to cross to the anode, so the space charge is neutralized by adding an ionizable gas, such as cesium. Or
alternatively a
{0.001 in.) spacing

vacuum-type converter is made with a very small between cathode and anode to minimize space-

charge

effects.

Current models of thermionic converters are stated by Gear eral Electric to have these characteristics: vacuum type, efficiency 5 per cent, cathode temperature 1100C; gas-filled type, efficiency 17 per cent, cathode temperature 15:!0 C. The gas-lillcd

between the electrodes, at right angles to the magnet. By connecting the elect rudes, power may be delivered to an external load. A regenerator is used to recover energy from the emerging Kas stream which may still be as hot as 2000C when its ionization has dropped to levels insufficient for effective energy conversion. generator might be operated as part of a convenAn tional gas or combined gas and steam turbine cycle. Few data exist today on which to calculate efficiencies attainable with such a combination Some estimates suggest that addit ion of an M H D

MUD

284

Looking In: Atomic and Nuclear Physics


tlio

generator could raise


to

over-all efficiency of a generating station

55 per cent.

20.7

FUEL CELLS

A fuel cell is a continuous-feed electrochemical device in which the chemical energy of reaction of a fuel and air (oxygen) is converted directly and usefully into electrical energy. A fuel cell
from a battery in that (1) its electrolyte remains unchanged and (2) it can operate continuously as long as an externa! supply of fuel and air is available. Sir William CSrove, an Englishman distinguished in electrochemistry and the law, used a hydrogen fuel cell in his experidiffers

-2
.2 -

I K

Chemieol
energy

r
Heat
is

4)

5
I

91

a.'-*

0.

c
l

CD >-

K
t

*
-*

Thermoelectric

Thermionic

S3

Thermogolvanic

\
Fig.

Fuel cell

/
most
efficient

$MWiW AW Mi
'"
''

o.

20.10 Fuel cells convert chemical energy directly into electric energy, thereby avoiding the thermodynamic limitation on the efficiency of heot engines.

IV*

'if

'.I:

'r

lit.
1

M
1

',]

\\Ai\i
I.

ments as early as 1839. By the end of the last century, Wilhelm Ostwald and others came to appreciate, through thermodynamic
analysis, that the fuel cell

potentially the

simple

^F

way

of converting chemical energy into electrical energy.

Heat engines are subject to the Carnot limitation of thermodynamics which says that the maximum theoretical efficiency with which heat can be converted into another form of energy is determined by the inlet and exhaust temperatures of the engine:

Maximum
It
is

efficiency

7>
J
i

nlet
7',,,

71 / outlet
i,-i

on

rt\

'v

,1

an attractive feature of the fuel cell that its efficiency is not subject to the Carnot limitation, for the energy being converted never deteriorates into the random motion of heat. The fuel cell,

p
1 I

I,

"<

III

('"ill

when compared with

familiar

methods

of generating electric

if-. i! f 'if jf 1 li 1! , 1. llil'.i,li.l.l,r |l.,.il)|l:M l,'lt,ll.r t'^L


. l l
l

MMii

hi

285

286

Looking

In

Atomic and Nuclear Physics

Unconventional Energy Sources

287

The

electron does useful


in

work

for

its

in

passing from anode to


ion completes the

cathode
circuit

the external circuit.

The hydrogen

by going from anode

to cathode through the electrolyte.

The

electrons are urged through the external circuit

by the

thermodynamic driving
over-all reaction.

force called the Ciibbs free energy of the

The major

difficulty

in the design of fuel cells:

noted by Grove in 18W) is still a problem how to obtain sufficient fuel-electrode

(catalyst)-eleetrolyte reaction sites in

a given volume. In many

Fuel cell
Fig.

20.13

Unlike other conver-

sion systems, fuel cells


efficient at

ore more

tow output.

50
Rated bod, per cent
Fig.

100

20.12

75-wott 4-cell Allis-Chalmers fuel


"jsero gravity" conditions.

cell

system designed

for

and tested under

cells,

fuel

(gas), electrolyte

(liquid),

and electrode

(solid)

are

brought into effective contact by a porous electrode structure which depends on surface tension forces to get reasonable contact
energy (Fig. 20.10), is very direct in its conversion of chemical energy into electrical energy. Partly because of this incentive, fuel cells are probably the most highly developed of the unconventional energy-conversion methods discussed in this chapter.
stability.

In theory a fuel

cell

can be

built

in

almost any

size

and

Under favorable conditions, efficiencies of 80 and even 5)0 per cent have been reported with hydrogen fuel. A fuel cell, like any other electrochemical cell, contains two electrodes: anode and cathode. These are joined externally by a metallic circuit, through which the valence electrons from the fuel flow, and internally by an electrolyte, through which ions flow to complete the circuit (Fig. 20.1 1). These are the electrode
reactions

capacity. Practically, fuel cells are packaged in small modules or "batteries" to be connected in series or parallel as needed for it particular application (Fig. 20.12). While conventional generating devices hei
ie less efficient

as they so front design load to

idling, the fuel cell is

more

efficient at lighter loads (Fig. 20.13).

Anode
Cathode
Over-all

2H 2 Oj O*
4-

411+

4H++

ier

= ee~ = 2H 4

+ 211,

= 2H aO

APPENDIX
Reaction Thrust

The concept
recoil

of reaction

Hi nisi

may

lie

clarified

by considering the

produced by a parallel si ream of particles. Prom Newton's laws it follows that for any system <>f objects or particles tin- center of mass of the sy-iem moves according to the equation

F =
where

mv
net external force applied to system
total

at

(1)

F = m =
v
/

mass

of

system

= velocity = time

vector of the center of mass

matter how complicated the system or how inncli force one of its parts exerts on any other, if the net external force is zero (as in fieldfree space), then

Xo

It
i|ii:inl ity.

il

(2)

which stales thai (he total moment urn of Hie system

is

a constant vector

Consider a system of two particles, a "rocket" of mass m ami velocity particle of (jas of mass 8m which is just leaving the nozzle with rclalive velocity t.. The uel momentum of this system is mv + 8m{r v,). From Eq. (2)

and a

j-

[mv

6m (v

iv)]

289

290

Appendix

A
t

Rut 8m(di</dt) is negligible, and d(6m)/dt = -ilm ill. since he mass of exhaust gas equals the decrease of the mikei max. Also for the exhaust velocity r, ilr, ill = 0, and m is a small quantity which approaches sera
.

in the limit.

We
dt

have the result


v.

m
or

dl

ilr

dm

(3)

(4)
lit

APPENDIX

the reaction force on the rocket. The mass flow leaving the rocket dm/<lt is re presented by a positive Dumber. The negative sign in the equation expresses the fact that Fand ', are in opposite directions.

where

is

Burnout Velocity and Range

In differentia] notation, Kq. (:i.bs) of A><-. :i7

may

be written

du

rfflll

m)
(i)

Kven

if

the thrust
!>,

is

not constant-, this equation can be integrated to

give the velocity

at

burnout

i'o

ffu/,

In
flit

gtt,

cos 8

(2)

If we assume that the rocket starts from rest. c = and R = Wo/i&, the ratio of initial mass t" final

0, set

/.

i.\.

"g,

or burnout

mass.

Kq, (2}
i'

may
'"-tr

be put

in

the form
eos 9
(3)

In

gtt.

Here 6, is the duration of burning in seconds. The two averages f, (( and ;/ are necessary since the values of both effective exhaust velocity and gravitational acceleration are dependent on altitude. The altitude reached at burnout for a rocket in drag-free vertical flight with practically constant thrust (dttt/dt = const) turns out to be

h=
291

gI,k

- p _

il?'i

<Vb

Ita

292

Appendix B

where Ao

is the initial altitude at the start of burning. After burnout, the rocket will coast upward to its maximum hoi^Iii h m Again assuming vertical nielli and negligible (has. hut taking into account the variation
,

of g with altitude

during coasting,
(r.

(lie

masting distance

is

Ac

>;
2{?d r,
5

ft*)'

t-*(r,

h b)/2g

()
tt

of

where r r is the radius of the earth. For a rocket which reaches a summit no more than a few hundred miles, h, is much smaller than r, ami \i\. (5) rednees to a familiar form
lu

APPENDIX
Schrodinger Wave Equation

M
altitude A reached in this vertical flight
is

(6)

The summit
hm

A*

Ac

^j

the range <>f a ballistic rocket, one may treat the powered portion of the trajectory as vertical ami the coasting portion a< elliptic. The coasting range a, along the surface of a nonrotating earth

To approximate

has been determined as

rf
2rf sin1

If

is

the amplitude of the de ftroglic wave,

2gr,

-**

(8)

The range
for
i>i

W W
Ei

**

calculation can be corrected for the earth's rotation by using the vector sum of relative burnout velocity and the velocity of

the launching site and by adding veclorially to h the distance the l landing point move's while the rocket is in flight. If small, Bq. (8) reduces to he familiar equation for the range of an ideal parabolic trajectoryon a Hat earth:

The X in this equation is to be found from the momentum of the particles we are discussing. The momentum /' can be related to the kinetic energy

I '

mV ^
in

. JL

2m

lir

V^B,
kinetic energy K, plus
:

<2)

0u
If r b is large,

(9)

The

but less than

)i, (2ff r (

total energy energy E, so

B of a
a

particle

is its

its

potential

zero

and

sr

becomes

rf.

he denominator of Fq. Hence a burnout velocitv of


t

(S)

approaches
is

(2ffur,.)J

just

sufficient for the rocket to enter into a circular satellite orbit. The optimum angle of elevation f the trajectory at

~
burnout

p~

(3)

V2m"c^re7)

vanes with the desired range


tan

*r

according to the relation

and the wave equation becomes


(10) aso, x-iy

* -

sin (sr /2r r )

^ity

JU-1

ooa (sJ2r,)

dx-

dy*

^^

(4)

A*

For short ranges,

+ =

46", For longer ranges,

is

Jess

than

t.V

E. Schrodinger showed, in I92(i, that Bohr's rules of quantisation could be explained on the basis ,f the solutions of this equation. The quantity
(

ty

(jisi)

is

called the

"wave function" or

Although
293

+ may

be negative (or even complex),

the "probability amplitude." it turns out that its

294

Appendix C

are applied to theeteetrons, they move with constant velocity. Their potential energy W the same at all pointe; we may take /' equal to zero. The solution of he wave equation in tins ease will be a plane wave, expressive in terms of Bmea and cosmos, just as for an electromagnetic wave.

We may ask what sort of eolations this equation would have foe electrons moving m the +x direction. Sinee no forces

for

APPENDIX

1.

BOOKS FOR A PHYSICS TEACHER'S REFERENCE SHELF


Ilijdi

for the Advancement of Science: "The Traveling School Science Library." AAAS and National Science Foundation, Washington, D.C., 1961. American Institute of Physics: "Physics in Your High School," McGrawHill Book Company, Inc.. New York, I960.

American Association

Hrown, Thomas II. (edL): "The Taylor Manual of Advanced Undergraduate Experiments in Physics," Addison- Wesley Publishing
Heading, Mass., 1959. "A Guide to Science Beading," The New American Library of World Literature, Inc.. New York, 1963. Glasstone, Samuel: "Sourcebook on Atomic Energy," D. Van Nostrand Company, Inc. Princeton, N..L, 195K.
Inc.,

Company,

Deason,

11. J. (ed.):

Hodgman. CI),
cal

(ed.): "Handbook of Chemistry and Physics," ChemiUubber Publishing Company, Inc., Cleveland, 1963. [(niton, Gerald, and 1). 11. >. Poller: Foundations of Modern Physical Science," Addison- Wesley Publishing Company, Inc., Heading,
I

Mass..
Miehols.

]!)oS.

W,

C. (ed.):
I).

Electronics,"

'The International Dictionary of Physics ami Van Nostrand Company, Inc., Princeton, N..L,

1956. National Science Teachers Association: "New Developments in High School Science Teaching." Washington, D.C.. I960. neludes 9-page list, "Additional science program materials available." Orear, Jay: "Fundamental Physics," John Wiley & Sons, Inc.,, Now York^ 1961. Parke, N. G.: "Guide to the Literature of Mathematics and Physics,"
I

Dover Publications,
295

lue.,

New

York, 1958.

296

Appendix

D
Committee: "Fhyaes,"
for Physics," J).

Appendix D.
C.

297

Physical

Science Study

Heath and

Company, Boston,
:

!%().

"Laboratory Guide

C. Heath and

Company

Boston, IWiO.

Derek John deSollu: '.Science since Babylon," Yale University New Haven. Conn,, 1961. Kesuick, R., and I). Halliday: "Physics for Students of Science and Engineering," John Wiley & Sons. Inc., New York. I960. Rogers, Eric M,: "Physics for the Inquiring Mind: The Methods, Nature and Philosophy of Physical Science." Princeton University
Price.

Press,

Press. Princeton, N.J., HltiO.

(Publishers), Ltd.. London, 195(5. W. White. :iud K. V. Manning: "College Phvsies.'* Hook Company. Inc. New York, 1959, White. M. W., K. V. Manning, and R. L. Weber, "Practical Physics," McC raw-Hill Book Company, Inc., New York, 1955. Includes 33

L J., and John Murray Weber, R. I.., M. MeCraw-Hil]


Rouse.
experiments.

American Backet Society. 500 Fifth Ave,. Xew York 36, N.Y, (Ask for latest Book List.) American Society for Engineering Education, W. L. Collins, National Secretary, University of Illinois, Frbana. 111. Astronomical League, 310 Livingston Terr.. BE, Washington 20, D.C. Commission on Mathematics, College Entrance Examination Board, 425 West 17 St., New York 27, N.Y. Committee on School Mathematics. University of Illinois. Urbana, 111, Educational Testing Service, Princeton, N.J. (The Cooperative Test Division publishes a loose leaf binder, 805 pp., of Questions and Problems in Science, Text Item Folio no. 1. 195ft.)
1

R. J. ISarllc: "Experiments for

Modern Schools,"

National Association of Biology Teachers, Paul Webster. SecretaryTreasurer, Bryan City Schools. Bryan, Ohio. National Education Association, 1201 Hi St., NW. Washington (i, D.C. National Science Teachers Association, 1201 16 St., NW, Washington ft, D.C. School Mathematics Study Group, Drawer 2502A, Yale Station, New

Haven. Conn.
Master's Association, John Murray Albemarle St., London, Wl, England. Smithsonian Inst it uf ion, Washington 25, D.C.
Science
(Publishers),
Ltd.,

50

2.

SOME PERIODICALS FOR A SCHOOL SCIENCE LIBRARY

American Journal of Physics. American Institute of Plivsies. 335 Last 45 St., New York 17. N.Y. Xature, Macmillan & Co. Ltd., St. Martin's St., London, 2, England, and St .Martin's Press, inc., 103 Park Ave., New York 17,

WC

4.

SOME SUPPLIERS OF PHYSICS APPARATUS FOR TEACHING

Central Scientific Division, Cenco Instruments Corp., 1700 Irving Park Road, Chicago 13. III., and (it Hi Telegraph Rd.. Los Angeles 22,
Calif.

The Physic* Teacher. American Institute of Phvsies, 335 East 45 St.

X.Y. Physics Today, American Institute of Physics, 335 East 45 St., New York 17, X.Y. The School Science Renew, The Science Master's Association, 52 Bateman St., Cambridge, England. Science, American Association for the Advancement of Science, 1515 Massachusetts Ave., XW, Washington 5, IXC. The Science Teacher, Journal of the National Science Teachers Associ17,

New York

The Ealing

Corp., 33 University Rd., Cambridge 3S, Mass. Macalaster Bicknell Co., 243 Broadway at Windsor St., Cambridge, Mass. (Suppliers of PSSC apparatus.) Science Materials Center. 5!* [-'mirth Ave., Xew York 3, N.Y. The W. M. Welch Scientific Co.. 1515 Sedwick St.. Chicago 10, III.

5.

GREEK ALPHABET

ation, 1201 16 St., XW, Washington (i, D.C. Scientific American, (15 Madison Ave.. New York 17. N.Y. Sky and Telescone, Sky Publishing Co.. Harvard College Observatory,

A
Ii

a
fi

alpha
beta

nu
xi

Cam
3.

I)

ridge 3M, Mass.

7
a
e

gamma
delta
cpsilott
ii

omieron
TC
l'i

a E
SOME PROFESSIONAL ORGANIZATIONS OF INTEREST TO THE PHYSICS TEACHER
Z

H
n
1

r
n
I

seta eta
1

P V

rho

sigma
tau
upsilon
phi
chi
psi

T
T

r
V
<P

liela

Association of Physics Teachers. American Institute. of Physics. 335 East 45 St., New York 17. N.I erican Chemical Society. 1155 16 St., XW, Washington 25, D.C. American Meteorological Society, 3 Joy St.. Boston S, Mass.
.

American

iota

Am

K
A

X n

kappa lambda
inn

X
*
Q

*
w

omega

298

Appendix

D
Appendix

299

6.

SYMBOLS

under the
the
to

hairline.

= means equal

"C"

scale.

Head the answer on the "D" seale, under the index of Determine the decimal point by rough mental approxi-

means is defined as, or is identical to ^ means is not equal to = means varies as, or is proportional to 2 means the sum of * means average value of j: means is approximately equal to > means is greater than "( means much greater than) < means less than ( means much less than)
"
{hiir

mation.

EXAMPLE: Divide

by

3.

See Fig. D.2.


<hr) Set 3 or." C"

Over 6 on "D"

Vof-lln 12,600 ik stated


,

V, P <!ifii,) '*&**** fiwt doubtful digit; e.g. to only three signifieant figures: 1.20
'

i-

rt

'

T
*?

-V

h'K

1
1

iJi
i

u
i

7.

BRIEF INSTRUCTIONS ON USE OF A SLIDE RULE*


11

(2nd)

Under Left "C" Index Read 2 on "D"


Fig.

li

I'

lT
D.2

*% performed on ^P^H? irtwL?a&' S caes he " um! " " on the end of the seale
?
I

the
is

"C"
t

-,?

,r

left

,,

|, ( |

Su%TS!

^"l-attherigluemlofthescalei!
index of

flufe /or multiplication: Set

"C"

seale over cither f th

second fac or on the "C" scale. Read the answer on the <!>" under the ha,rhe. Determine the location of the decimal point rough mental approximation.
'

J..
I,

flow to Find a 8quctre (too'.. Problems involving square roots are, worked on the "A" and "B" scales in conjmietion with the "C" and wo "I)'' scales. Note llial the "A" and "li" scales are divided into identical parts, which will he referred to as "A-left" and "A-fight." Rule for square roots: If the number is greater than unity, and has an
I

"i

odd number of figures before the decimal point, set the hairline over the number on "A-left" and read the square root under the hairline on the
scale. If the number has an even number of figures before the decimal point, use "A-right" instead of "A-left." Locate the decimal point in the answer by mental approximation. If the number is less than unity, move the decimal point an even numami 100 is obtained. ber of places to the ri^ht until a number between Find the square root of the number thus obtained as explained above. To locate the decimal point, move it to the left one-half as many places

kxamplk: Multiply 17
(lit)

"D"
23.

See Kg. D.I.

Set Left "C" Index

Over

V on

"D" Scole

i:

as

it

was originally moved

to the right.
root of 507.

fo-r 1
1

> -Tr

Life?.t,v3
-a:

^i

..'.,i

^i.: >..;''
|

'

i| ii i

>:
i

Vt*

ii

Hbt -_.

kxamclk: Find the square


(lsl) Set

See Fig. D.3.

:^r
(2nd)

Under 23 on "C" Scole Read 391 on "D" Scale

Hairline to 567
Left

on

Ho If

of

"A"

Fig. D.l

TL
ii|iiii jm
i|i
i

//ow

(o

Dtafe. Division

ii

scales also.

generally performed on the


1

"C" and "D" "

|
[

iii|iii t} i|i

nji|

;
i

.c
o

i..V4.r-.Vi"
i

the^^^utS'', scale and


tin-

tte um ^tor (dividend) on bring^T the denominator (divisor) on the "C" scale

8-''
'

'T

""'

7i

~i

".?%'& tTwWWl
I

i),.

"

>

1 1 1

it

hii J w jhii|hii|h4
i

liK ^

\s~rs
(2nd)

StnU tbnS gen*Co.


'

"'"'

,,|)VriK!l1

iHu8**tiM <-"">!esy of Eugene Diets-

Under Hairline on "D" Read 238


Fig. D.3

300

Appendix

8.

TRIGONOMETRIC FUNCTIONS
[;:.]'..'.

l*sc "A4aft," since than is mi odd number of figures before the decimal point. By mental approximation, locate the decimal poinl after the second significant figure, making the answer 23.8.

Radians

Sine*

Cosine?

Tang ants

Cotangents

.0000 .0178

a
i

kxamplk: Find the square root of 0.0956. See


(1st)

Fig,

]>.-].

.(Will

2
if

0524 ,0698
Set Hairline

4
5
7

.0000 .0175 .0349 .0523 .0008 .0872 1046 1219 .1392 1504
. .

1.0000 ,9988
.9984 .9986 .9976

,0000 .0175 .0340 .0521 .0699

s 57.20
28 04 10,08 14.30
.

00 80 88 87 86
85 84 83
S2 81

5708 5533

,5359 1.5184
1

5010
.

Over
Half of "A"

9.56 on

Left

.0878
Ml 17
.

.9962 .9946
.

.0875
.1051
.

11.430
n 61
i

1835
(661

1222 1390
r

05)25

1228
105

''-.'
I

...r

W..I., .t,.

>

>

<

"!"

),...i...*..i...j

. p

t.i.ip

.l, >7]

8 9
10
11

mod3
.9877

.1
.

1581

8.144 7.115 0.314


5.671
5
!

1.4480 .4312 1.4137


1

.1

.1

.1-

n'~a

>

n'TT)

,k

im].|.l,,.Jl^,l,l|l.
(

..

1(

,ii

i;

~m
Fig.

.1745 .1920 .2091 2209


21 !3
.2(il8

.1736 ions
,21)70

.9848 .9810
.978! .9741

12 13

(2nd) Under Hairline

on

14
15

.2250 .2410

.9703

1703 .1914 .2120 .2300 .2493


.

15

4.705 4.332
I

SO 79 78 77
70

3963 1.3788
I

Oil

.3614 1.3439 1.3205


[

"D" Read 3.09


D.4

2588
J

0059
.9613 9563
,

.2798
.

2967

.Move the decimal point two places to the right, thus obtaining 9.56. Fse the "A-left," hecause there is now an odd number of figures before the decimal point. Take the square root of 9,r>6. !hen move the decimal poiul one place to the left, making the answer 0.309,

.3142 ,3310
.3491
,

16 17 18
19

7511

.2021 .3090 .3250

.9511

.0455 .9397 .9336

.2070 .2867 .3057 .3240 ,3443


.3640 .3839 .4040

3.732 3.487
3.271

75
74

1.3090 .2918
1.2741 .2666

3.078
2 904

73 72
71

1.2302

20
21

3605
38
1

H> 101 .-1189


. .

22 23 21 25
211

.3420 3584 .3746 .3907 .4007 .4220 .4384


.

2.748 2.606
2
175

70

69
08
67

9272
'.1205

.9136

4245 .4152
.

2.350 2.246
2 144

a 05
< 1

1,2217 1.2043 1.1808 1.1694 1.1519


1.1345 1.1170 .0990 1.0821 1. O047
1
1

7A. SLIDE
Bishop, C.

RULE BIBLIOGRAPHY
.

4363

('.:

"Slide

Rule-

How

to

Fse

It."

New York. Bshbaeh, 0. \V., and H. L Thompson: "Vector Type Log Log Slide Rule." .Manual no. 1725, llugene Dietisgen Co., 1009 Vine S(
Philadelphia
7.

Barnes & Xohle,

Inc..

.1538 .1712 .4887 .5081

27

4540
1695

2S 29 30
31

IMS
.5000

.9003 .8088 .8010 .8829 .8740


.

.4003 ,4877
.

5095

2.050 963
1
.

.5317 .5543
.5771

1.881 1.804

68 02
01

Pa.
for Slide

5236

Naming. M, L:"A Teaching Guide


I

Rule Instruction," Pieketl

.5411

5150
.5299 .5440

and Eckel Inc., 1109 South Fremonl Ave,, AJhamhis, Calif Harold, Don: "Slide Rule? May Help ," KeulTel and Baser Co., . . Adams and Third Sis., Hohoken, X.J. "Inirnducing the Slide Rule," Wabash Instrument & Specialties Company, [tic. Wabash, lud., 1943. "Ii'- Easy to Use Four Post Slide Rule." Educational Director, Frederick Post Co., 3050 North Avondale Ave., Chicago, 111. (A projec.

.5586 .5700 5934


.

32 33
34

8660 S572 S1S0

5592
.5736 .5878 .0018
11157
.112!):!

.8387 .8200

.0009 0249 .0494


.

1.732 1.664 .000


1 1

00

.1)172

59 58
57

1.0297 1.0123

54(1
is:;

0745
7002 7266

56
55
54

0.9948 0.9774 0.9599


(1

Jill)!)

35
j
:

.8102
SOOt)

.6283 .0458 .6632 .0807


.0081
.715(1
.

,r,

37

.7980

7530

38
39 40
II

7SS0
.7771

.7813 .8098
.

1.428 370 1.327 280 1.235


1

1)125

53

52
51

0.9250 0.9076
o 8901

tion slide rule is expected to be available soon for classroom use.) Johnson. L. H.: "The Slide Rule," I). Van Xostrand Company. Inc.,

lltiS

Princeton.

X..1.

-Macliovina. P. K.:

"A Manual

Company, foe, 330 Weal

for the Slide Rule," McGraw-Hill 12 St.. New Ym-k 30, N.Y., 1950.

Book

7330 7605 7079


78, )4
r

42 43
44

.0501 .0091

7660 .7547
.

839 8693

.7431
.

.0820 .0047
.7071

73
7
1

93
1

.9004 ,9325 .0057

"Mathematics, .Mechanics, and Physio." Engineers Council for Professional Development, 29 West 39 St., New York, N.Y.

45

.7071

0000

192 150 I. Ill 1.072 1.030 1.000


. .

50 49

48
47

46
45

0.8727 0.8552 0.8378 0,8203 0.8029 0.7854


Rudiufis.

Coiinei

Sinfti

Colon genii

Tongont?

Degree*

301

302

Appendix

D
s

Appendix

303

9.

LOGARITHMS TO THE BASE


These two pages give the
I

LOG, (BASE e
(hy1

2.718284)
Tenrht

rial lira!

iierbohe, or Napierian) logarithms of tnniibera between and m, correcl in four places. Moving the decimal point places to the right (or left) fa tfie number is equivalent to adding ,, limes 2,:<02(i (or n tunes 3.6974) to the logarithm.

'2

3
1

5 6
i

2.8026 6052 6 B078 8.2103 11.6129 13.8165


i

6974-3
'.HUH
."i

2
3 4 G

05)22-7

of the Tabular
Difference

7897-10 4871-12
I

9
5.0
G.1

I 6134 6332 66J5 0715 8901


7084

1
0154 6351

4
0174 6371 6563

6
0214 8409
6601

7 6233 8429 6620 6808 8993


7174 7351 7527

10

1234

6
7

Sir,

IS

1181

18.4207

20.7233

8 9

8819-17 6793-19
27(17-21

1.8094
112! 12

0)14

6194

8.2
S.J 6.4

6487

6677 6864
7047

8311 6508 0696 8882 7060 7246 7422 7690 7760 7934 8090 8262 8421 8579
8733

6544 6734 6910 7102 7281 "457 7630 7800 7967 6132 8294 8453 8810 8784 8918
'.Win;

6390 8582
6771

0752 6938 7120 7199 7475 7647 7817 7984 8148 8310 8460 6025

MM
7138 7317 7492 7864 7834
8001

6700 6974 7156 7334 7609


7681

6263 8448 6630 6327 7011 7192 7370 7544 7716 7884

0273 6487 6668 6845 7029 7210 7387


7561

6292 6487 6677 6864 7047 7128 7405 7579 7760


1.7618

2 4 6 8 10 2 4 6 8 10
2 4 6 8 10

2 4 6 7 14 6 7

Tflnrhf of the

6.5
6.6 6.7

24 57
2 2 2 2 4 3 3 3 5 7 5 7 5 7
6 7
7 7

Tabular
Difference

19
1.0
i.i

12
10

6.8
5.9

0.00OQ

0953
1823

0100 1044

0108
1133

iiair,

0392
1310 2151

0488
1398
2231

0583
1484 2311

0077
1570 2390 3148 3853
4S11

0770
1055 2469 3221 3920

0862
1740

0.0053
1823

i.j
i.

mm
2700 1436
4121

1222

10 29 38 48

7228 7406 7679 7760


1.7016

7J63 7440 7813 7783


7951

9
9

7851

7099 7867 8034 6197 8358 8516 K67J

7733 7901 8060


,j,,l

9 8 8 8 8 S 8

IMS
2770 3607 4187 4824 5423 5988 0523
7031

1.4

1624 3305 4055


470(1

J070 2852 3577 4253 4836 6481 8043 6675 7080


7561 8020

2927 3640 4318 4947 SS39 6098 6627 71JS 7608 8065 850J 8020 9322 9708 0080 0438 0784
1119
I44J
1756

3001

3710 43S3 5008


.i,W,

3075 3784

JS46 3293 3088 4837 5J47 5822 0366


6SS1

2024 3365 4055


4700 5306

17 20 35 44 8 15 24 32 40 7 15 22 30 37 7 14 Jl 28 34
13 19 26 32 8 12 18 24 30 8 II 17 23 J8 5 II 18 22 27 5 10 15 21 26

CD
6.1

6.2 6.3 6.4

l.S 1.6 1.7 l.S 1.9

5300
5S7.V

4762 53S5 5933


8471

4447 5068
56.53

0419
0.8931

6152 6678 7178

6208 0729
7227
7701

5IJ8 5710 0259 0780 7275


7747

4574 SI8S 5766 0313


6831

8083 6245 8405 8563 8718 8S71 9021 0109 0315


1.9459 96UI

8116 8178 8437 8594

8185 8326
S4S",

8017 8181 8342 8500


silSft

8050 82)3 8374 6532


v ( ;s:

8083 8245
-41')-,

8041

8390 8647 8703

8563 8718
8871 0011

2 3 6 2 3 5 2 3 5 2 3 5 13 5

8 6

5878 6419
0.6931

6.5 6.6
0.7

8749
8901

8779
8931
iw-ii

8795
-8940

6.8 2.0
2.1

J.J
2.3

J.4

7419 7885 8329 8755 9ISJ 9555 0.9933


1.0296

698t 7467

7514 797S 8416 8838

7930 S372 8700 9203 9504

8450 8S70 92*2 0670 0043 0403 0750


1086 1410 1725

7665 8109 8644


8901 9361

8154 8587 0002 9400 9783 0152 0508 0952


1184

8198 8829 9042 9439


9821

7324 7793 8242 8671 9083 9478 98S8 0225 0578 0918
1249
L500

7372 7839 8286 8713 9123 gsi7 9806 0260 0513 0953
1282

7419 7885 8320 8755 9103


9565 0.9g33
1.0296

5 10 15 20 24 5 9 14 19 23 4 9 13 IS 22
4 9

6.9

8886 9036 9184 0330 0473 0615 9755 9802 0028 0102 0295 0425 0554 0681 0807 0031 10S4 1175
1204 1412

0051 9100

9344 948S 0629 0769 9900 004!

9213 9369

9228 9373

0095 9142 93S7


0530 0671 0810 9947 0082

8810 8961 9110 9257 9402 9544 0686 0824


998)

8825 8976 9125 9272 9410


9560 9600 0838 9974 0109

8840
8991

MM
9008 9155 9301 9445 9587 9727 9385

9140 9280 9430 9573 9713 9851

9109 9315
1.9459

2 3 5 2 3 5 6 13 4 13 4 6 13 4

S
8
7

7
7

T.O
7.1

9502 0643

0516
0857

9601 0741
1

13 17 21

8 12 16 20 8 II 10 20 8 II 15 19
7 11 7 It

7.1
7.3
7.4

9741

emg
9920 0055
(1I.1SI

th
9933 0069 B202 0334 0464 0592
071!l

',-7'.'

13 13 13
13 13 13

4 6

4
4 8

7 7 7
7 7 7

1J870
2.0015

0B88/0O0I
0122 0255 0386 0516 0643
O70II

2.0015

4 5

J.S
2.0 J.7

0243 9632 0367 0710


1053

0000 0229 0360 0490 0618 0744


OS00 0002
1)14

OI30 0268 0399 0528 0656 0762 0906


1020 1150 1270 13SH 1506 1822 1730 1849
1961

0149
0281

4 5 4 5 4 5
4 5 4 5 4 6 4 5

0746
0111,

9960/0006
033J 0682
1019

2.8
2.6 3.0
3.1

0473
IIS

0647

IS

0188 0543 0886


1217

7.5
T.fl

15 18
14 18

0647
1.09S6

7.7

7 10 14 17
7 10 13 18

7.8
7.9

0149 0281 0412 0541


IlW'.i

1161

0176 0308 043K 0567 0604 0810 0843


1080 1187
1300 1424 1541 1660

0311

0461 0580 0707

0215 0347 0477 0805 0732


0867 0080 1101
1223 1342 1469

0241 0373 0503 0831 0757


0882
1005 1126
1247 1305 1483

0412 0541 0660


2.07114

13
13

7
1

13
13

6 6 6 6 6 5 6
6

1314 1632
10811
>>$<

1346 1063 1009

1378 1094

1474

1506
1817 21 19

1537 1B48 2149

3.2

1600
1009

1314 1632

J.S 3.4
3.5 3.0 J.7 3.8 S.9

2267 2556 2137

2000 2206
2585 2S5 3137 3403 3661

2030 2320 2613 2M)2 3164 3429 3680

2060 2355
2641

1787 2000 J3S4

1878

24 13

J442
2720 2002
3271 3633

2170 2470 2754 3020 3297 3558 3813


4001

JJ08 2499
2792 3056 3324 3584 3838 4085 4327 4563
471)3

1939 2238 2526 2800 3083 3350 3610


1

6 10 13 16 6 II 15 6 9 12 15 6 9 12 14 8
II

1.0
8.1

2.0704

0010
1041

0832 0058
1078 1199 1318 1436 1562
1668

S.2 8.3 8.4

0844 096s 1090


1211 1330

0894
1017

ll'.llll

1041

1138 1158 1377 1494 1610 1726


I83S

1163

2528 1809 3083 3350 JO 10


1.3883

2M|
3191

3110 3376 3635 3888 4134 4375 4600 4839


5063 5282 5497 5707 6013

2669 2947 3216


3481

MM
2976 3244 3507 3702
4012 4255 4403 47J5
4!>. ,l

1163 1282
1401

1235
1353
1471

1282
1401

12 12 12 12 12
12 12

4 5

4 8 4 5 4 6
4 5

14

3455 3712 3962 4J07 4446 4670 4907


5120 6347 5560 5769 6974

3737

3788
4036 4279 4510 474s 4074 5195 5412 5023
5831 8034

3m;;i

8 II 14 8 II 13 8 10 13 8 10 13
2

8.S

1448
1564
16711

1618
1623

8.6
8.7

1518
1833

1529 1645 1759 1872


1083

1576
1601

1587 1702 1815 1028

1590 1713
1827 1039

1748
1861

J .8
8.9

1748
1861 2.1971

1770
1883

M
4.1

1781 1894

1793

1804 1917

4.2 4.3 4.4 4.5 4.0 4.7 4,6


4
LI

4110 436!
!>,,

3013 4159 4398 4633


4861

1906

1050 2061

2.1972

12 12 12 12 12
12

3 3 3 3

5 5 5
4

6 6 6 8 6 5
5

4810
5041 6201

3938 4183 4422 1666 4884


5107

3987
4281 4469

4110
435)

4303 4540
4770 4090

4702 4929
51SI

5019
5230 5464 5865 5872 8074

4586 4816 6041


5261 5476

2 2 2 2 J 2 J J 2

5 5 5 5
4

7 7 7

10

12

10 12

J.O
9.1

1904

II

7
7

9 9

11 11

1.2
9.3 9.4

2083 1192 2300 2407 2513 2'Us


2721

2094 2103 2311 2418 2523 2628 2732 IS34 2935

2105 2214 2322 2428


2534 2638 2742 2844 1948

2006 2116 2225 2332 2439 2544 3649 2752 2854 2966

1017 2127 2235 2343 2450


1.555
21159

2028 1138 2240 2354 2460 2565 2670 2773 2875 2978

2039 2148 2257 2364


2471

2050 2159 2288 2376 1481

2072
2181 2 2 Mi

2170 2270 2386 2492


2597 2701 2803 2906 3006

2396 2502
2607 2711 2814 1915 3016

2083 2102 2300 1407 2513 2616 2721 2v>4


2
'.:.'.

3 4
3 4

12
12
1

3 4 3 4
3 4

5 5 F 6 5

5476 5688 6892

5085 5304 5518 5728 5033

5320 5530 5748 5953

6309 5581 5790 5994

5173 6390 5602 S8I0 6014

5217 5433 5844 5851 8054

4
4 4 4

5680 6802
1.6094

6 8 6

9 II 9 II 8 11 8 10
8 10

9.5 9.8
S.7

0.8 9.9

2824 2925

2702 2865 1966

2576 2680 2783 2886 2980

2586 209O 2703 2895 2996

12 12
1

2 3 4 3 4 3 4 2 3 4 3 4

S
5

2.3026

12

304

Appendix

D
11.

Appendix

305

10.

VALUES OF PHYSICAL CONSTANTS

CONVERSIONS OF ELECTRICAL UNITS


Quantity

As experimental data improve, "best values" of the physical constants are recomputed by statistical methods. See, for example, K, It, Cohen, J. \V. M. Do Mond. 'I". \V. Lay Ion, and J. S. Hollelt. "Analysis of Variance of the 1052. Data on the Atomic Constants and a New Adjustment, 1885" Review of Modern i'hysv-s, 27:303 380 (1955). The values listed below have been rounded off from those liste<l in the paper cited and have been expressed in inks units. The physical scale is used for all constants involving atomic 0)88868.

Symbol

Practical
unit, mfcs

Cgs-esu equiv.

Cgs-emu equiv.

Energy
Current
Electronic potential Electronic field

w
(

1
1

jouJe

10" ergs
3
J

10" ergs
0.1

ampere
volt

X X

10 9 jtotomp 10 -s statvolt

abomp
f'

10*
1

1
1

volt/m

10~ 4 iv/cm

ob volts abv/cm

Avogadro's number: A'.i = 6.0249 X 10 10 molecules kmole Gas constant per mote: R = 8,31 7 joules/(kmoie)(K) Standard volume of a perfect gas: V a = 22.420 m 3 atm. kmole Standard atmosphere: i> = 1.013 x 10* newtons/m* Speed of light in free space; c = 2.9979 X 10" m/sec
SO" 3 " joule-sec 10 7 coul/ kmole Charge/mass ratio for electron: e/m = 1.758" X 10" coul/kg Rest mass of electron: m = 9.1083 X 10~ 31 kg First. Uohr radius: = 5.2917 X 10 ll m Compton wavelength of electron: X = h/mc = 24.203 X 10 13 10 S3 joule, K Boltamann's constant: = 1.3804
Electronic charge: e = 1.0021 Planck's constant: A = 6.6252 Faraday constant: F = 9.652

Magnetic Magnetic

flux

a
B

induct.

weber weber /m 2

10^ maxwells 10' gauss

Permittivity of free

BBS

10" 11

statcoulomb

space

coulV newton -ni !


1.257

dyne cm 5

10"
unll

VM>

Permeability of free

10" 6

pole

X
X

10-

|!l

coul

space

newton/ omp-

9- 10"

V*wso

dyne cm 5

Note:

= C

A.-

=
.'lass-energy conversions:
I

8.617

X10

cv/"K

kg
electron mass

=
= = mass =

1
1

proton mass

amu

10 s * 5.610 0,51098 Mev 938.21 .Mev 931.14 Mev


939.51

Mev

Energy conversion

factor:

31 Rest masses: electron m = kg = ft.4870 X 10 proton t = .0724 X 10"" kg neutron i = 1.6747 X 10 " kg Proton mass electron mass ratio = 1,830.12 = 6.67 X 10 ll newton-mVkg* (iravitational constant:
1

neutron ev = 1.6021 9.1083 X 10

Mev

10 "joule

amu

Index

Absorption coefficient, 265


Acceleration cine to gravity, 41, 43 Acoustic waves, 1(11, 103
(See a/so Wave) Activity, 240
specific.

Autoradiography, 203
life, 24 Avogaclro's number, 78, 144

Average

Baker, K.

11..

IS,

19

242

Bnlmcr
7.

Series, 208, 212,

214
_M-">

Adams,
Actlu
i-

('.

C,

Hand theory
R.

of conduct inn.

theory, 139, 1st; Ampere, 110 Ampere's law, 131, 150, 161 Amplitude, !l(i, 106 Angle of ascending node, 51 Angle of inclination, 51

Harkla, C. G, 281 Barrier, energy, 220, 244


Bertie,
J.,
A..,

290
IS

Bauer. 0.

Beats, 197 BecquereJL H. A., 77, 203

Angular momentum, 55 Anode, 140 Apogee, BJ Apparatus, suppliers of, 297 Argument of perigee, 53

Benson, O.

().,

7
I'll

Bernoulli's theorem,
si

Wending node, angle of, 51 Asteroids, 10, 13 Astronautics, bibliography of, 7 careers in, 7 lilms on, 7 history of, 3
Astronomical unit, 9 Atmosphere, entry of, 72

Beta decay, 210 spectrum, continuous. 24S Bel Binding energy, 299, 242. 251 Bishop, C. ('.. 390 Blaekbody, 168 Blackbody radiation, 166 energy distribution in. lit) (See also Radiation) Blunchard. C. II.. 153 Bohr. N.. 1 18, 293 Bohr atom model, 293 204,297.222
(See
iitao

Atom,

7!i

Atom)

earlv concept of. 78

Hook
25:1

list.

205

models
radius

or,
of,

117.

203 205. 23\

K5 speed of, 86 Atomic Knergy Commission, 32 Atomic muss, 70, 153 Atomic mass unit, 70 Atomic number, 118, 183, 205, 211, 220 Atomic weight, 79 Auger effect, 175 307

Bore, 08, 9!) Hot he. W.. 253

Bragg

diffraction, electron

analogy

of, 21

Breeder reactor, 271


Breillat rahluug, 17li

Brown, T. IS., 295 Bubble chamber, 203


Budierer, A. II.. 198 Bnchheiin, It. YV., 7, 70

308

Index

Index
Burnett, C.
It.,

309

163

Burnout

Daltnn,

.speed, rocket, 20, 201 {See alxo Rocket

J.. 77. 7.s

Damped wave,

Cajori, !'., 64 Calorie, ss

Darwin, C, R. Davidson, U'. ].., 273 Davisson ami Germer cxia-riim-nt


2I.S

106 115

Electrification, 1 17 It Electrolysis,
I

field, electric, 121 deflection of particles bv, 125,

Electromagnetic wave, 103, 161 energy of, (66 gamma ray, 242
plane, 103. (66 of. 104 x-ray, 175 Electron, 10s. 127, 130, 144

Ml
gravitational, 42

magnetic, 125
deflection of particles by, 125, 120, 141 Field intensity, electric, 121 strength, magnetic, 105 Field

Careers

7 [See also Astronautics)


*

in astronautics,

Curncit efficiency. 32. 2x4

Cathode, 140

tube, 143 Cal lioiie rays, 1 30 Cavity radiation, L89

Cathode ray

205 I,., 216 De Broglie wave, 170, 222, 230 Decai constant, 211, 25<J Deflection of charged particles, 125,
J.,

Deason, H. De BrogUe,

speed

charge

or,

145

Film

lists, 7,

IS.

37

and

Center of mass, 20 ^ rotation about, 212 Chad wick. J., 253 Chain reaction, 274 Charge, of an electron, 145

Degree of freedom, S8
I

e/m

electrolysis, 111 ratio for, 142


Hi!)

Fission, nuclear,

273

Fitzgerald-Lorents contraction, 104


Flux, electric, 157

'elector, radiation, 2til

Do ^'auvenargues, Marquis, 138 Dewey, John, 40


Dill ruction, 107,

energy data for. free, 146, 232 in nucleus. 246 shells, 227, 230

magnetic, 135 Forbidden energies, 237

Charge /mass
Charging, 117

ratio, 127. 142

Chromosphere,

ISO of electrons, 2 IS of neutrons. 210 of photons. 2 IS


I

Electron configuration, 228, llecfroti (iilTraetion, 2 Is

230

II

Circular orbit, 46, 53 Clock paradox, 195 Cloud chamber, 263 Cohen, ]:. H., :)4
Collisions, molecular,

Diffraction grating, 108 Dilatation of lime, it Dirac, P. ,\. M., 216 Direction rules, for induced emf, 136

Electron (low, 127 Electron theory of conduction, 146 Section volt, 124 Hectrostatic units, 1 19

Force, gravitational, 41 magnetic. 134, 142 on a current, 120 nuclear, 206, 254 Fourier series, 07, 104

Founder.

(I,,

201)

86

demerits, periodic table of, 228 Elements of an orhil, 51 Jliot. C, 166

Franklin, YV. S., 138 Free electrons, 140. 232 Free fall. 43. 4li

nuclear, 252

Comets,

11),

i:j

Common
139,

Coulomb.

elect rieity in a tas 140 Conductivity, band theory of, 235 electrical and thermal. 233 of metals, 146 quantum theory of, 234 Conic orbits, 65 Conic sections, 64 Conservation of energy, 200, 244 Constants, physical, :mm Corona, 1 Correspuiidence principle, 183, 214 osmic rays, II, 14, 208
I

Condon, Conduction of

erf, 176, E. U., 210

ell

265

magnetic force, 134 magnetic induction, 134 Disintegration energy, 243 Kspucement, 06 Disraeli, Benjamin, lis
for for
I

Distances, to planets. HI
to stars, IS

64 Emerson, It. W., 77, 1S3 imf, induced, 135 Energy, binding. 20(1, 254 conservation of. 21 Ml, 244
jllipse. 61,

Freedom, degree Frequency. 114 Fuel cell, 284

of,

88

Fusion, unclear. 274


a,

Dobie,

disintegration, 243 distribution in blacklmdy radiain

(7,

gravitational acceleration, 41, 43 gravitational constant, 41 Galaxies, 17

.1.

Dopplcr

[''rank. ti7 effect, 112, 107

tion, 170 electromagnetic wave, 105

transverse, 1 14 Dose, radiation, 267 Dunne and Hunt law, 170

DnClaux,

lit)

Dulongand
Dyne.
Earth
21

oquipnrtilion of, SS forbidden, 237 in nuclear reactions, 243, 273. 270


potential, 44

25S'.

Camilla decay, 242 Gas, fully ionized. 275 ideal, 80 kinet ic henry of, S! Gas constant, so Gas discharge tube, 140, 141
I i

IViit law,

I4S

DuMoml.,1. U\ M., Duncan, .1. c. mi

las law,

so

:)4

quantization of, of satellite. sources of, 272


1

2(H),

220

It)

barrier. 220. 244 Coulomb's law, lis, 200

Coulomb

satellite, fit
.",1

Eccentricity,

Cou titer,

201 (leiger-MuUer, 261

Eddington, A.

tiergv barrier. 220, 244 uerg'y levels, 2IIX. 21(1, 235. 242 qua! ion of state. 81

Gauss, 120 Gauss's law, 157. 150 ( lav-Iaissac, .1.. 7s Geiger. H., 203
(ieiger-Mnller counler, 261 rator principle, 186 Glaser. D. A,, 263
(ilasstone. S., 205 Goddard, H. II., 4

8., 115.

271

scintillation, Crew, II., mi


< 'fit

202

Edison, T. A 2X1 Effective exhaust velocity. 25, 30


Efficiency of heal engine', 32. 284 Einstein, A., !t, 67, 77, 173, 175, 1X4, 104, 196 Einstein's mass-energy equation,

mass, 27 1 Cross product, vector, 56


teal

quilihrium, radioactive, 250 quipnrthinn of energy, 8S scape speed, 31, 45 shlmch, O. W., 301) xelusion principle, 227
Ixlinust

Gram
30

tuoieciilar

volume, 70

velocity. efTeclive, 25,

Curie, 242 Current, conventional, 127 direction of, 12s electric, (27
electron, 127

Exponential law of decay, 230


Falling body, 42 Faraday, ML 136, 144, 150, 283 Faraday, 144

199
Einstein's photoelectric equation, 173 ESectiio current, 127 in magnetic Meld, 130 in metals, 148, 235 Electric field intensity, [21 Electric potential, 122

Grating, optical, 108 Gravitation, universal, 41 Gravitational acceleration,

i/,

41

on planets. HI slandard, 25
Gravitational constant, 0, 41
(

iravitat iunal field.

42

induced, 136
in

Paradays law
Kit
I

of induct ion. 158,

Gravitational force, 41

magnet ie

field,

in metals,

Hti,

130 235

on planets, 10
Gravitational potential energy, 44,

Fermi, K., 273

Fermi distribution, 234

47

310

Index
Ionization potential, 2in, 211 Ionizing radial ion, 2(51 iHHtojws, 140, />:*
I

Index
Matter, composition
of. 117 four states' of. 27(i Matter wave, 170, 217, 230

311

Gravity. 41 Irsek alphabet, 207


(

Croup

Newton's laws Node, 51

of motion, 21,

43

velocity,

l(J(l

Croups, orbital, 227, 230 drove, W., 284


(iuidnnco of rocket,
"(I

Ives.

II.

i:..

Ml

Ives

and

Maxwell..).

C.

83, 87, 88. 103, 166,

Stilwell experiment, li)7

lid. 1114

Halm, a. 273
Half-life,

James,

J. N.,

Miixwell-iloltzinann distribution,
s:{. 87, 232 Maxwell's electromagnetic theory,

241 (See (i/.to Radioactivity) Hall effect. 233


I).. 2!lli

Jet .separation, 2!l L. 11., 300 Joliot. 1''.. 253

Johnson,
Jupiter,

186, Mil. 107

Maxwell's equations.

Mil

lit,

12

Ilalliday,

Mean

live path, 84

Hartung. M, I. 300 Heat engine, ellieienev


Ilcavisido,

of,

32

(I., 120 Heiscubcrg, W,. 2 It; Hciscnljerg a uncertainty principle,

A*-eapture, 217 Kelvin, Sir William Thomson, 271 Kepler's laws, 56, (HI

182

derivation of, (i2 Kinetic theory of gases, 81

Mechanics, principles of, 21 Mendeleev, 1). 1., 228 Mercury, HI. II Mesons, 107 Metals, conduction in, 232
Meteorites. HI, 13 and radio waves, 13 Miehels, W. ('.. 205 Micbelson interferometer,
Slilky Way, 17 Miliicurie. 242 Millikan, H. A.. 145 Mills, M. M-, 38 Missilery, chronology of, 4 Model rockets, 37

Henry,
Herald,

J..
]>.,

135

H err iik.

K.,

300 02

Kirchhoffs law, lli.s Kiwi engine, 32, 33 Krogdahl, W. S.. I!)


l-i

lst>

Hohbs. M 3S Hodgroan, (". 1),, Hull on, (i., 205


Horace.
I

Hertz, (i.. 157. KM High-ejicrgv particles. 260


2!>f>

Michelson-Morlev experiment, ISS


ert, B., St!.

S7

Launching speeds, 70
(See also space)

Nonionizing radiation, 261 Nozzle, rocket, 2S, 33 (See also Hocket) Nuclear atom model, 205, 238, 253 Nuclear landing energy, 200 Nuclear emulsions, 203 Nuclear fission, 273 Nuclear force, 206, 254 Nuclear propulsion, 31, 71 Nuclear reactions, energy from, 243. 25S. 273. 270 equations for. 25ti threshold energy for, 258 Nuclear reactor, 32, 273, 274 breeder, 274 Nuclear testing, 269 Nuclear wastes, 270 Nuclei, stable, 255 Nut icon. 17, 254 Nucleus, 17, 230 radius of, 254
1 1

Layton.
Life,

1'.

W., 304

Lens's law, 135

Oersted, B.C., 110 Orbit, circular, Hi, 53


electron,

Ill

lo vie, V.,

I!)

Hubble, !:. P.. go Huxley. T. H., 252 Hydraulic jump, SIM

on planets, is, 10 of radioisotope, 241 Light, speed of, |(>4, |8(i,

227,230
atmosphere, 72 atom. 2111), 222

1JI2

Hydrogen, Hulir model


energy levels for, spectrum of, 207
(See alao

207 208, 210


of,

Atom)

Line of force, gravilat imial, 42 Loeb, L. I).. s:i Logarithms, 3112 Lorents, H. A., 232 Lorentz transformation. 193

manufacturers of, 37 (Seeaiso Rocket) Models of molecules, 8(1

for entry o[ in hydrogen satellite, 47

Modern

Ideal ga law, SO
(u puke, specific, 25, 27, 32, 33 Inclination, angle of, 51 Induced current, 135 direction of. 135 Induced end. 135 direct ton of, 138
I

Much number,

2s, 102

Machoviaa. !'. K.. 300 McLaughlin. !l. .. Ml Magnetic deflection, I3ti, 141 Magnetic field strength. I(i5 Magnetic Mux, 135 Magnetic induction, I2K, 131
center of loop. 132 direction rule for. 131 Faraday's law of, 158 force due to, 134 near straight wire. 133
ill

physics, 77 Mole, 79 Molecular mass, 7'.i_ Molecular volume. 70 Molecule, 70. 117 mode! of. 88

conic, 66

elements

of,

precession

of,

61 57

Ordwnv.
Orear,
.1.,

1 I '.

L. * 63, 296

Oslwald, W., 281


Page, I.., S3 Pair production. 243, 266 Pairing of aueleons, 255 Parke, X. <',., 296
Pauli exclusion principle, 221 Performance of liquid propellents,

Momentum,
in

angular, 55 quantisation of, 209, 220 relativity theory, 198


HI,

Moon.

12

Induction, magnetic, 128, 131 at center of loop. 132 direction rule for, 134

Moslev's (aw, 231 Motion. Newton's laws of, 21, 43 uniformly accelerated, 22, 42 Motors, rocket. 27. 32 (See alxo Hockot
|

20
Perigee, 51

Faraday's law
force

argument

of,

53

of,

IjjK

due

to,

134

near Straight wire, 133


Insulator, 237 Intensity. ]{I5

M.'ignclohydi'odyiiariiics, 34, 283

wave, 165
(See alto Wave) Interference. 106, 1*7 Interferometer. iMi

Manning, K. V.. Marconi, (!., 157 Mars, HI, 12 Marsdon. E., 203

.".Id

(National Aeronauties and Space Administration), 7, 8, 32 National Association of Rocketry,

NASA

Period. 51. 54,04 Periodic table, 228 Periodicals, io astronautics, 8


list of,

Interplanetary travel, OR
Ion.
144.

Mas.s. atomic. 70 niolcnilar, 7'.) Mass-energy relation, HIS Mass number, IS


I

Mi)

Ion propulsion, 34, 3d, 71 Ionization chamber, 201 Ionization energy, 229

Mass rat io, 30 Mass spectrometer,


Dempster type,

37 Mangle, J. E., 14, 17. 19 Neptune, 10, 12 Neutrino, 240 Neutron, 118, 274 detection of, 263 discovery of, 253 Newell. H. K.. 14, 17. HI

296

131,

Mil

Uainbridge type, 152


151

Newton, Isaac. (HI Newton (unit), 21 Newton's law of gravitation.

II

Permeability, 131 Permittivity, 1 10 Phase veloeitv. 100 Photoelectric effect, 172, 266 Pholooleotron, 172,242,286 Photons, 172, 173, 179, ITS, 180,211 absorption of. 205 Photosphere, 1 Physical const ants, 304 Pinch effect, 270

312

Index
Radiation dose, 267 Radiation pressure, 13 Hadiai ion tolerances, 17 Radioactive equuibn 250 Radioactive scries, 240 Radioactivity, decav lav, for, 239
natural. 238. 249
series in, 2-10

Index

313
4

Planck, M.. 171 I'liini-k's constant. 182 Planck's law, 170

17-'.

173. I7(i

Rocket

Planets, flight between, 68 life on, 18 physical data for, 10 limes to reach, 70

Plasma, 275

Plasma propulsion, 35
Plato, 07

lypes

of,

239
I

Poinenre,

II.,

07, 139, 191

units of, 24 Radioisotopes, natural, 251

Haniu,

Pollard, !:.. 273 Positron, absorption of. 207 Positron -electron pair, 243, 205 Potential, electric, 122 Potential energy, gravitational,

74 ISAM) Corporation, 5, 7 Range, of charged particles, 266


S.,

trajectories, 60 Roentgen, w, C, 77 Roentgen, 267 Rogers, H. M., 64, 206 Holler, I). H. I)., 295 Hollett, J. S., 304 Root-in can -square speed (rtns), 83 Rouse, [..,!.. 296 Rowland, H. A., 2t)(i Russell. Hortrand, 183 Rutherford atom model, 205, 238, 2S3 Ryilbcrg constant, 207

Space vehicles, chronology Spec lie heat, 87


i

of,

of metals, 147 Specific impulse. 25. 27, 32, 33

Spectrum, I0S, 2<l( of hydrogen. 207 x-ray. 230 Speed, burnout, 201
of light. Hi.!. ISO. I!I2 of molecules. S3, SO

rms, 83 Spencer, II., 67


Spin, 225. 249

of rockets.
for
II.

2!

1.

30. 40, 201


1

Sarnoff.

!>..

149

atmospheric entry, 73
10

47
Potential well,
in

Rationalised units,

Satellite orbits, 47 Satellites, earth. 3

Sputniks, 5, 50, 05 Stable nuclei. 255 Stages, rocket, 31


(ate also Rocket Standing wave, (19,
|

gravitational Belda,

47 for hydrogen atom, 210 Pouudal. 21


Poyntnuj'a vector, 166 Pressure of radial ion, i:t Pressure thrust, 24
Price,
1).

2!iti

Hay. 93, !!4 Rayleigh-Jeans Jaw, 17(1 Reaction principle', 20, 22 Reaction thrust, 2so Reactor, nuclear. 273, 274 for rocket power. 32 Reduced mass, 213 Re-entry of earth's atmosphere 72
Reference systems, 185
Relativistic Doppler effect, 114 Relativity theory, Einstein's, 111 ma.vf ami energv in, IVx
I

energy of, 55 escape speed for, 31


reasons for, 0, 50 Saturn, 10, 12 .Savage, J. N 20 Scattering of alpha particles, 204 Schoolcy, J. S., 48 Sehrodingcr, [',., 216 Sehrodiiigcr wave equation, 222,
220, 245, 203 Scintillation counter, 262 Screening, electron. 220

Star distances, 18 State, equation of, SI


Stern,

Stefan-Boltsmann law, 170 ()., 86

Probability, wave. |8I) Product vector, 66 Project Hover, 32 Project Sherwood, 34 Projectile motion, 43
I'ropellants.

Storn-dei huh experiment. 224 SlMwell. 0. EL III Stake's law, 145 Stouer. R. <:.. 153 Stoney, G. J., 44
1

Strassmann, F 273
Strughold,
II.,

Newton's, 185

performance
3(1

and spaee
of,

travel, 201
in,

28

Propulsion, ion, 34, nuclear, 31


:,

win paradox

I!I5

Scebeek, T., 277 Sciferl, B. ., 8,88, 58 Seismic wave, 103

velocity addition in, 103

solar,

36
->|>(*

Proton, UK, 127

Rep, 2tl.s Resistance, of free space, 165 of metals, 147


Resistivity, 147

Semiconductor, 237, 277 Series, radioactive, 240

Suninierfeld, M., 38 Sun. 10 Superposition principle, 104. 109 Surge. 9S


P., 26 Symbols, mathematical, 208

Sutton. G.

Shaw,

J. H.,

10

Shells, electron. 227,

230

Proton-neutron diagram, 243,


front's hypothesis, 153

Resnick,

Shock wave, 102


Simultaneity, 103 Singer, ('Italics, 13N Slide rule, use of, 298 Slug, 21
Societies, professional.
ii
1

*R..
1

2116

Thermion ie converter, 281


Thermocouple, 278
Thermoelectricity. 277 power from, 279 Thomas, B, It., !K3

Resonance,

10

Q- value. 243, 25.S Quantization, energy, 208,

"242

momentum,

209,

220

apace, 224

Quantum,

172, 173, 170

Quantum mechanics, 1X4. 2 Hi. 219 Quantum numbers, 224. 227 Quantum theory, iu7
Rad, 268
liailialioa. atmospheric contamination by, 269 liiologieai effects of, 268

speed. 83 Roberta, Michael, 1K3 Hocket, burnout velocity for, 20 definition of, 20 flight theory of, 2 20 forces on, 29
1

R MS

HiKht-hiiiid rule, 134

296

ion, 34 mass ratio, 30 model, manufacturers motors for. 27. 32

of,

37

Solar const at. Solar propulsion, 30 Solar sail, 36 Solar system. 10. 18 Soli. stale, theory ..I'. 231 Sonic boom, 102 Sound wave. 100
I

Thompson, II. !.., 30(1 Thomson, J, J., 77, 131,


203. 288 Tli res hold energy, 25s

130, 149,

Thrust, decrease with momentum, 24 pressure. 24

alt

it

talc,

24

speed

of,

101

multiple stage, 31
oosale, 28, 33 nuclear, 31

0e oho Wave)
36
Space, environment of, gravitational fields in. 40, 47 radiation in, 14
vehicles 71
in, 4

Time Time

rocket, 24, 289 dilatation. 114. 195. 201 to reach planets. 711

blnckhody, 108
cavity, 169

electromagnetic theory
101, 167 in space, 14

performance plasma, 35
of,

of, 2ii.

156

types of, 20 Radiation holts, 14


I

propulsion of, 21, 22, 26, 32 range of. 2IJ, 30 specific impulse of, 25, 27 staging of, 31 Rocket guidance, 70

Space exploration, reasons Spaee quantization, 224

for,

li.

Tiros satellite. 58 Total energy of B parliele, 2(10 Transformations, Lorentz, 192 Transurauic elements, 273 Trigonometric functions, 301

Tunnel

effect

245

Space research, 74 Space travel, and relativity, 201

Twin paradox, 105


Tyndall,
J.,

116

314

Index

I'liceifainty principle. ISI


l.'nifoniily accelerated

Wave, sound, 100


speed
of, 104 square, 96

motion, 22,

42
("nils, electrostatic,

119

standing

tuks, 119, 120 for Newton's second law, 21

109, III
1

in u string, 95,

11

Utmma
Drams,

rationalized mks,
(film),
10,

li)

18

12

surge, !IS transverse, 92, 103 traveling, 95 x-ray, 17.5

16 Vector cross product, 50 Vector product, !2,s Velocities, iiddition of, 193 Velocity, burnout, 29 of escape, 45 in group,
1

\'-2 rocket, 24, 30 \an Allen belts, 14,

Wave
Wave Wave

aquation, 92, no

Schroilinger. 293 Wave forms, 95, 90, 104


front, 93.
:it

W ave speed, !(ll Waves, interference

mechanics, 219, 245, 293 \\.ni-|i;iniile duality, 179, 217


of,

Km

of molecules, phase, Hit)

H'A,

so

rms, 83 Venus, JO, II


Volt, 122

Von Goethe,
Wave,

J.

W., 115

soperposi'i f. KM, 109 Weber, R. I. 7, 153,290 Weiicr, 129 Weightlessness, \i\ Wells. II. 00 Whipple, V. L_ 3

245 damped, 106 in different mediums, 94


elastic,

acoustic, 101, 108 at a boundary, 04, 110,

White, M. \V., 290 Whitehead, A. \., 50 Whitney, W. \i., 20

Whole number
\\

rule-.

153

Wiedcnianu-Frani!
nil's law. 171

rule,

233

93

electromagnetic, 93, 103, 101 energy of, 105 group velocity in, 100 intensity of, 105 in a liquid, 07 longitudinal, 92, 103 panicle motion in. 99 phase velocity in, 100 saw-tool li, 90 seismic, 103 shock, 102
sine,

Wilson, V. C, 281 Wilson cloud chamber, 262

X-ray spectrum, characteristic, 230 continuous, 230

rays, 175

frequency limit
scattering of,
19
h\,
J

of,

176

76

ffin,

II.,

Zodiac, 9

96

Zwicky,

08

PHYSICAL DATA, EARTH

Mean
Mass

diameter

12,742.46
72.9

km

Angular velocity

10~ 6 radian/sec

5.975X10" kg Mean density 5,517 gm/cm 3 Normal gravity (p = geodetic g m 9.78049(1 + 5.22884 X 10m/sec
2

latitude)
sin
3

10 B

5.9

lO" 6 sin 2

2<p)

Standard atmosphere
PHYSICAL CONSTANTS

1.013

newton/m 2

Na = Avogadro's number = 6.0249 X 10 M molecules/kmole R = Gas constant per mole = 8317 joules/ (kmole)(K) 23 k - Boltzmann constant m 1.3804 X 1Q~ jou1e/K = 8.617 X
10- 5 ev/K

y = Standard volume of a perfect gas = 22.420 m afm/kmole s c - speed of light - 2.9979 X 10 m/sec 19 coul e m Electronic charge m 1.6021 X 10~
3

Planck's constant

6.6252
9.652
1

F = Faraday

constant

X 10~ 34 joule-sec X 10 coul/kmole


T

Energy conversions:

electron volt

1.6021

10- 19 joule

Mev m = Rest mass of electron - 9.1083 X 10~ 3I kg = 0.51098 Mev m p = Rest mass of proton = 1.6724 X 10"" kg - 938.21 Mev Mb - Rest mass of neutron m 1.6747 X 10-" kg - 939.51 Mev mjm s = 1836.12
1

atomic mass unit

931.14

Permittivity of free

space = 8.8542

10" 12

farad/m
^o

Permeability of free space

4tt

10" 7 henry/m

= (/*oAo)i = Impedance of free space = 376.73 ohm G = Universal gravitational constant = 6.67 X 10" n
Zo

newton-mVkg 2

: -

: = :

=-- =:

-"

*
f*
fii

a
3

T
(0

68806

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