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DENT F CAT ON OF THE

SPACE GROUP
OF PYR TE
FROM PED AND CBED PATTERNS
S MULATED PATTERNS: JEMS from P. STADELMANN
F RST STEP
denti fi cati on of the CRYSTAL SYSTEM from the ' NET" symmetry
Fi rst experi mental ZOLZ pattern wi th hi gh ' net' symmetry
(Posi ti on of the refl ecti ons onl y)
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
Fi rst experi mental ZOLZ pattern wi th hi gh ' net' symmetry
(Posi ti on of the refl ecti ons onl y)
ZOLZ ' Net" symmetry ?
ZOLZ WP

' NET' symmetry ? -
' DEAL' symmetry - -
Fi rst experi mental ZOLZ pattern wi th hi gh ' net' symmetry
(Posi ti on of the refl ecti ons onl y)
ZOLZ ' Net" symmetry
(6mm)
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
ZOLZ WP

' NET' symmetry (6mm) -
' DEAL' symmetry - -
Fi rst experi mental Whol e Pattern (WP) wi th hi gh 'net' symmetry
(Posi ti on of the refl ecti ons onl y)
Fi rst experi mental Whol e Pattern (WP) wi th hi gh 'net' symmetry
(Posi ti on of the refl ecti ons onl y)
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
WP ' Net" symmetry ?
ZOLZ WP

' NET' symmetry (6mm) ?
' DEAL' symmetry - -
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
ZOLZ WP

' NET' symmetry (6mm) ?
' DEAL' symmetry - -
WP ' Net" symmetry ?
Fi rst experi mental Whol e Pattern (WP) wi th hi gh 'net' symmetry
(Posi ti on of the refl ecti ons onl y)
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry - -
WP ' Net" symmetry ?
Fi rst experi mental Whol e Pattern (WP) wi th hi gh 'net' symmetry
(Posi ti on of the refl ecti ons onl y)
Second experi mental ZOLZ pattern wi th hi gh ' net' symmetry
(Posi ti on of the refl ecti ons onl y)
Second experi mental ZOLZ pattern wi th hi gh ' net' symmetry
(Posi ti on of the refl ecti ons onl y)
ZOLZ ' Net" symmetry ?
ZOLZ WP

' NET' symmetry ? -
' DEAL' symmetry - -
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
Second experi mental ZOLZ pattern wi th hi gh ' net' symmetry
(Posi ti on of the refl ecti ons onl y)
ZOLZ ' Net" symmetry
(2mm)
ZOLZ WP

' NET' symmetry (2mm) -
' DEAL' symmetry - -
Second experi mental Whol e Pattern (WP) wi th hi gh ' net' symmetry
(Posi ti on of the refl ecti ons onl y)
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
Second experi mental Whol e Pattern (WP) wi th hi gh ' net' symmetry
(Posi ti on of the refl ecti ons onl y)
WP ' Net" symmetry ?
ZOLZ WP

' NET' symmetry (2mm) ?
' DEAL' symmetry - -
Second experi mental Whol e Pattern (WP) wi th hi gh ' net' symmetry
(Posi ti on of the refl ecti ons onl y)
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry - -
WP ' Net" symmetry
2mm
denti fi cati on of the CRYSTAL SYSTEM from the ' net' symmetri es
1 m
2
2mm (4mm) (4mm)* 3m 6mm
or
and
absence
of
(6mm)
and
presence
of
(6mm)
and
absence
of
(4mm)
Hi ghest WP
"net" symmetry
observed
Crystal
system
Tri cI . Mono. Ortho. Tetra. Cub. Tri g. Hex.
Rhomb.
l atti ce
Hex.
l atti ce
*except for Pa3
denti fi cati on of the CRYSTAL SYSTEM from the ' net' symmetri es
1 m
2
2mm (4mm) (4mm)* 3m 6mm
or
and
absence
of
(6mm)
and
presence
of
(6mm)
and
absence
of
(4mm)
Hi ghest WP
"net" symmetry
observed
Crystal
system
Tri cI . Mono. Ortho. Tetra. Cub. Tri g. Hex.
Rhomb.
l atti ce
Hex.
l atti ce
*except for Pa3
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry - -
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry - -
denti fi cati on of the CRYSTAL SYSTEM from the ' net' symmetri es
1 m
2
2mm (4mm) (4mm)* 3m 6mm
or
and
absence
of
(6mm)
and
presence
of
(6mm)
and
absence
of
(4mm)
Hi ghest WP
"net" symmetry
observed
Crystal
system
Tri cI . Mono. Ortho. Tetra. Cub. Tri g. Hex.
Rhomb.
l atti ce
Hex.
l atti ce
*except for Pa3
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry - -
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry - -
denti fi cati on of the CRYSTAL SYSTEM from the ' net' symmetri es
1 m
2
2mm (4mm) (4mm)* 3m 6mm
or
and
absence
of
(6mm)
and
presence
of
(6mm)
and
absence
of
(4mm)
Hi ghest WP
"net" symmetry
observed
Crystal
system
Tri cI . Mono. Ortho. Tetra. Cub. Tri g. Hex.
Rhomb.
l atti ce
Hex.
l atti ce
*except for Pa3
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry - -
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry - -
denti fi cati on not cl ear
F RST STEP
denti fi cati on of the CRYSTAL SYSTEM
vi a the LAUE CLASS
from the ' DEAL" symmetry
ZOLZ ' Net' symmetry
(6mm)
ZOLZ ' deal ' symmetry ?
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry ? -
Fi rst experi mental ZOLZ pattern wi th hi gh ' i deal ' symmetry
(Posi ti on and i ntensi ty of the refl ecti ons)
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
m
m
m
m
m
m
m
m
m
ZOLZ ' deal ' symmetry ?
Fi rst experi mental ZOLZ pattern wi th hi gh ' i deal ' symmetry
(Posi ti on and i ntensi ty of the refl ecti ons)
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry (?) -
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
m
m
m
m
m
m
m
m
m
ZOLZ ' deal ' symmetry
(6)
Fi rst experi mental ZOLZ pattern wi th hi gh ' i deal ' symmetry
(Posi ti on and i ntensi ty of the refl ecti ons)
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry (6) -
m
m
m
m
m
m
Fi rst experi mental Whol e Pattern (WP) wi th hi gh 'i deal ' symmetry
WP ' Net' symmetry
3m
WP ' deal ' symmetry ?
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry (6) ?
m
m
m
m
m
m
Fi rst experi mental Whol e Pattern (WP) wi th hi gh 'i deal ' symmetry
WP ' deal ' symmetry ?
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry (6) ?
m
m
m
m
Fi rst experi mental Whol e Pattern (WP) wi th hi gh 'i deal ' symmetry
WP ' deal ' symmetry
3
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry (6) 3
Second experi mental ZOLZ pattern wi th hi gh ' i deal ' symmetry
(Posi ti on and i ntensi ty of the refl ecti ons)
ZOLZ ' net' symmetry
(2mm)
ZOLZ ' deal " symmetry ?
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry ? -
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
Second experi mental ZOLZ pattern wi th hi gh ' i deal ' symmetry
(Posi ti on and i ntensi ty of the refl ecti ons)
ZOLZ ' deal " symmetry
(2mm)
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry (2mm) -
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
Second experi mental Whol e Pattern (WP) wi th hi gh ' i deal ' symmetry
(Posi ti on and i ntensi ty of the refl ecti ons)
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry (2mm) ?
WP ' Net" symmetry
2mm
WP ' deal ' symmetry ?
Second experi mental Whol e Pattern (WP) wi th hi gh ' i deal ' symmetry
(Posi ti on and i ntensi ty of the refl ecti ons)
P
P
P
P
P
P
4mm 6mm
P
P
P
3m
P
P
P
P
2mm
P
P
m
6
P
P
P
P
P
P
P
P
4
P
P
P
P
P
P
3
P
2
P
P
1
2D fi ni te fi gure
1 0 2D poi nt groups
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry 2mm 2mm
WP ' deal ' symmetry
2mm
1
(2)
2
(2)
2mm
(2mm)
4
(4)
4mm
(4mm)
3
(6)
3m
(6mm)
Hi ghest
"i deal " symmetry
observed
Tri cI .
Mono.
Ortho.
6
(6)
6mm
(6mm)
3
(6)
3m
(6mm)
and
presence
of
2mm
(2mm)
and
presence
of
4mm
(4mm)
and
absence
of
3m
(6mm)
and
absence
of
4mm
(4mm)
Laue
cl ass
1 2/m 4/m 4/mmm 3 3m 6/m
6/mmm m3
m3m mmm
Tetra. Tri g. Hex. Cub.
Crystal
system
denti fi cati on of the LAUE CLASS from the ' i deal ' symmetri es
1
(2)
2
(2)
2mm
(2mm)
4
(4)
4mm
(4mm)
3
(6)
3m
(6mm)
Hi ghest
"i deal " symmetry
observed
Tri cI .
Mono.
Ortho.
6
(6)
6mm
(6mm)
3
(6)
3m
(6mm)
and
presence
of
2mm
(2mm)
and
presence
of
4mm
(4mm)
and
absence
of
3m
(6mm)
and
absence
of
4mm
(4mm)
Laue
cl ass
1 2/m 4/m 4/mmm 3 3m 6/m
6/mmm m3
m3m
mmm
Tetra. Tri g. Hex. Cub.
Crystal
system
denti fi cati on of the LAUE CLASS from the ' i deal ' symmetri es
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry (2mm) 2mm
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry (6) 3
1
(2)
2
(2)
2mm
(2mm)
4
(4)
4mm
(4mm)
3
(6)
3m
(6mm)
Hi ghest
"i deal " symmetry
observed
Tri cI .
Mono.
Ortho.
6
(6)
6mm
(6mm)
3
(6)
3m
(6mm)
and
presence
of
2mm
(2mm)
and
presence
of
4mm
(4mm)
and
absence
of
3m
(6mm)
and
absence
of
4mm
(4mm)
Laue
cl ass
1 2/m 4/m 4/mmm 3 3m 6/m
6/mmm m3
m3m
mmm
Tetra. Tri g. Hex. Cub.
Crystal
system
denti fi cati on of the LAUE CLASS from the ' i deal ' symmetri es
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry (2mm) 2mm
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry (6) 3
Laue cl ass
m3
Cubi c
crystal system
F RST STEP
denti fi cati on of the Zone Axes
from the ' NET" symmetri es
denti fi cati on of the Zone Axes from the ' Net' symmetri es
denti fi cati on of the Zone Axes from the ' Net' symmetri es
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry (6) 3
Fi rst pattern
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry (6) 3
<1 1 1 > ZAP
denti fi cati on of the Zone Axes from the ' Net' symmetri es
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry (2mm) 2mm
Second pattern
denti fi cati on of the Zone Axes from the ' Net' symmetri es
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry (2mm) 2mm
<001 > or <1 1 0> ZAP
denti fi cati on of the Zone Axes from the ' Net' symmetri es
F RST STEP
denti fi cati on of the Zone Axes
from the ' DEAL" symmetri es
denti fi cati on of the Zone Axes from the ' deal ' symmetri es
denti fi cati on of the Zone Axes from the ' deal ' symmetri es
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry (6) 3
Fi rst pattern
ZOLZ WP

' NET' symmetry (6mm) 3m
' DEAL' symmetry (6) 3
<1 1 1 > ZAP
denti fi cati on of the Zone Axes from the ' deal ' symmetri es
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry (2mm) 2mm
Second pattern
denti fi cati on of the Zone Axes from the ' deal ' symmetri es
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry (2mm) 2mm
<001 > ZAP
denti fi cati on of the Zone Axes from the ' deal ' symmetri es
SECOND STEP
denti fi cati on of the EXT NCT ON SYMBOL
denti fi cati on of the exti ncti on symbol
from el ectron di ffracti on
Perti nent zone axes ?
Crystal
system
Bravai s
l atti ce
Gl i de pl anes Screw axes
Zone axes useful for the
i denti fi cati on of the
exti ncti on symbol
TR CL N C
MONOCL N C
uni que axi s b
MONOCL N C
uni que axi s c
aP
mP mC
mA mI
mP mA
mB mI
can // (01 0)
abn // (001 )
2
1
// [01 0]
2
1
// [001 ]
[01 0]
b
WP
or
[01 0]
b
WP
[001 ]
c
WP
or
[001 ]
c
WP
TR GONAL
CUB C
HEXAGONAL
oP oC
oA oB oI
oF
hP hR
hP
cP cI cF
bcnd // (1 00)
cand // (01 0)
abnd // (001 )
bcn // (1 00)
can // (01 0)
abn // (001 )
cnd // (1 1 0)
cnd // (1 1 0)
c // {1 1 20}
c // {1 1 00}
tP tI
bcnd // (1 00)
cand // (01 0)
abnd // (001 )
cnd // (1 1 0) (1 1 0)
and // (01 1 ) (01 1 )
bnd // (1 01 ) (1 01 )
2
1
// [1 00]
21 // [01 0]
21 // [001 ]
2
1
// [1 00]
2
1
// [01 0]
4
1
4
2
4
3
// [001 ]
3
1
// [001 ]
3
2
// [001 ]
6
1
// [001 ]
6
2
// [001 ]
6
3
// [001 ]
6
4
// [001 ]
6
5
// [001 ]
2
1
4
2
4
1
4
3
//
[1 00]
[01 0 ] [001 ]
[1 00] WP [01 0] WP [001 ] WP
[001 ] WP
[1 00] WP
or
[01 0] WP
[1 1 0] WP
or
[1 1 0] WP
<1 1 20>
WP
<1 1 00>
WP
<001 > WP <1 1 0> WP
<1 1 1 > WP
opti onal
TETRAGONAL
ORTHORHOMB C
<u0w>
b

ZOLZ
<uv0>
c

ZOLZ
denti fi cati on of the exti ncti on symbol
from el ectron di ffracti on
Perti nent zone axes
Crystal
system
Bravai s
l atti ce
Gl i de pl anes Screw axes
Zone axes useful for the
i denti fi cati on of the
exti ncti on symbol
TR CL N C
MONOCL N C
uni que axi s b
MONOCL N C
uni que axi s c
aP
mP mC
mA mI
mP mA
mB mI
can // (01 0)
abn // (001 )
2
1
// [01 0]
2
1
// [001 ]
[01 0]
b
WP
or
[01 0]
b
WP
[001 ]
c
WP
or
[001 ]
c
WP
TR GONAL
CUB C
HEXAGONAL
oP oC
oA oB oI
oF
hP hR
hP
cP cI cF
bcnd // (1 00)
cand // (01 0)
abnd // (001 )
bcn // (1 00)
can // (01 0)
abn // (001 )
cnd // (1 1 0)
cnd // (1 1 0)
c // {1 1 20}
c // {1 1 00}
tP tI
bcnd // (1 00)
cand // (01 0)
abnd // (001 )
cnd // (1 1 0) (1 1 0)
and // (01 1 ) (01 1 )
bnd // (1 01 ) (1 01 )
2
1
// [1 00]
21 // [01 0]
21 // [001 ]
2
1
// [1 00]
2
1
// [01 0]
4
1
4
2
4
3
// [001 ]
3
1
// [001 ]
3
2
// [001 ]
6
1
// [001 ]
6
2
// [001 ]
6
3
// [001 ]
6
4
// [001 ]
6
5
// [001 ]
2
1
4
2
4
1
4
3
//
[1 00]
[01 0 ] [001 ]
[1 00] WP [01 0] WP [001 ] WP
[001 ] WP
[1 00] WP
or
[01 0] WP
[1 1 0] WP
or
[1 1 0] WP
<1 1 20>
WP
<1 1 00>
WP
<001 > WP <1 1 0> WP
<1 1 1 > WP
opti onal
TETRAGONAL
ORTHORHOMB C
<u0w>
b

ZOLZ
<uv0>
c

ZOLZ
SECOND STEP
denti fi cati on of the EXT NCT ON SYMBOL
<001 > ZAP
<001 > experi mental ZAP
Whol e Pattern (WP)
<001 > experi mental ZAP
Whol e Pattern (WP)
- FOLZ / ZOLZ shi ft ?
<001 > experi mental ZAP
Whol e Pattern (WP)
- No FOLZ / ZOLZ shi ft
<001 > experi mental ZAP
Whol e Pattern (WP)
- No FOLZ / ZOLZ shi ft
- FOLZ / ZOLZ
peri odi ci ty di fference ?
<001 > experi mental ZAP
Whol e Pattern (WP)
- No FOLZ / ZOLZ shi ft
- FOLZ / ZOLZ
peri odi ci ty di fference
<001 > experi mental ZAP
Whol e Pattern (WP)
- No FOLZ / ZOLZ shi ft
- FOLZ / ZOLZ
peri odi ci ty di fference
- Forbi dden refl ecti ons ?
<001 > experi mental ZAP
Whol e Pattern (WP)
- No FOLZ / ZOLZ shi ft
- FOLZ / ZOLZ
peri odi ci ty di fference
- Forbi dden refl ecti ons ?
<001 > experi mental ZAP
ZOLZ Pattern
- No FOLZ / ZOLZ shi ft
- FOLZ / ZOLZ
peri odi ci ty di fference
- Forbi dden refl ecti ons
<001 > experi mental ZAP
ZOLZ Pattern
- No FOLZ / ZOLZ shi ft
- FOLZ / ZOLZ
peri odi ci ty di fference
- Forbi dden refl ecti ons
<001 > experi mental ZAP
ZOLZ CBED Pattern
- No FOLZ / ZOLZ shi ft
- FOLZ / ZOLZ
peri odi ci ty di fference
- Forbi dden refl ecti ons
<001 > experi mental ZAP
ZOLZ CBED Pattern
- No FOLZ / ZOLZ shi ft
- FOLZ / ZOLZ
peri odi ci ty di fference
- Forbi dden refl ecti ons
Gj onnes and Moodi e l i nes
cP
<001 >
1
[001 ] ZOLZ
1 00
[001 ] FOLZ
e
2
e
1
e
1
=e
2
cP
<001 >
2
a
cP
<001 >
2
b
a
(cP
<001 >
2
b
)
cP
<001 >
2
b
b
(cP
<001 >
2
b
)
cP
<001 >
3
01 0
Compari son wi th theoreti cal patterns
<001 > ZAP - P Bravai s l atti ce
cP
<001 >
4
200
cP
<001 >
5
a
(cP
<001 >
5)
cP
<001 >
5
b
(cP
<001 >
5)
01 0
200
020
Compari son wi th theoreti cal patterns
<001 > ZAP - P Bravai s l atti ce
cP
<001 >
4
200
cP
<001 >
5
a
(cP
<001 >
5)
cP
<001 >
5
b
(cP
<001 >
5)
01 0
200
020
Compari son wi th theoreti cal patterns
<001 > ZAP - P Bravai s l atti ce
cI
<001 >
1
[001 ] ZOLZ
1 1 0
[001 ] FOLZ
e
2
e
1
e
1
=e
2
cI
<001 >
2
cI
<001 >
3
Al ternate
cI
<001 >
5
Al ternate
Shi ft
si mi l ar to cF
<001 >
1
a
-

(cF
<001 >
1 )
cI
<001 >
4
220
si mi l ar to cF
<001 >
3
1 1 0
220
Compari son wi th theoreti cal patterns
<001 > ZAP - Bravai s l atti ce
cF
<001 >
1
a
(cF
<001 >
1 )
[001 ] ZOLZ
200
020
[001 ] FOLZ
e
2
e
1
e
1
=e
2
cF
<001 >
2
Shi ft
cF
<001 >
1
b
(cF
<001 >
1 )
si mi l ar to cI
<001 >
1
si mi l ar to cI
<001 >
1
400
040
cF
<001 >
3
a
(cF
<001 >
3)
si mi l ar to cI
<001 >
4
cF
<001 >
3
b
(cF
<001 >
3)
si mi l ar to cI
<001 >
4
Compari son wi th theoreti cal patterns
<001 > ZAP - F Bravai s l atti ce
SECOND STEP
denti fi cati on of the EXT NCT ON SYMBOL
<1 1 0> ZAP
<1 1 0> experi mental ZAP
Whol e Pattern (WP)
ZOLZ WP

' NET' symmetry ? ?
' DEAL' symmetry - -
Check the zone axi s ?
ZOLZ and WP ' net' symmetri es ?
<1 1 0> experi mental ZAP
Whol e Pattern (WP)
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry - -
Check the zone axi s
ZOLZ and WP ' net' symmetri es
<1 1 0> experi mental ZAP
Whol e Pattern (WP)
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry ? ?
Check the zone axi s
ZOLZ and WP ' i deal ' symmetri es ?
<1 1 0> experi mental ZAP
Whol e Pattern (WP)
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry ? ?
Check the zone axi s
ZOLZ and WP ' i deal ' symmetri es ?
<1 1 0> experi mental ZAP
Whol e Pattern (WP)
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry (2mm) m
Check the zone axi s
ZOLZ and WP ' i deal ' symmetri es
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry (2mm) m
denti fi cati on of the Zone Axes from the ' deal ' symmetri es
ZOLZ WP

' NET' symmetry (2mm) 2mm
' DEAL' symmetry (2mm) m
denti fi cati on of the Zone Axes from the ' deal ' symmetri es
<1 1 0> or <uv0> ZAP
at 45 from <001 >
<1 1 0> experi mental ZAP
Whol e Pattern (WP)
- FOLZ / ZOLZ shi ft ?
<1 1 0> experi mental ZAP
Whol e Pattern (WP)
- FOLZ / ZOLZ shi ft
FOLZ / ZOLZ shi ft
<1 1 0> experi mental ZAP
Whol e Pattern (WP)
- FOLZ / ZOLZ shi ft
- FOLZ / ZOLZ
peri odi ci ty di fference ?
<1 1 0> experi mental ZAP
Whol e Pattern (WP)
- FOLZ / ZOLZ shi ft
- No FOLZ / ZOLZ
peri odi ci ty di fference
<1 1 0> experi mental ZAP
Whol e Pattern (WP)
- FOLZ / ZOLZ shi ft
- No FOLZ / ZOLZ
peri odi ci ty di fference
- Forbi dden refl ecti ons ?
<1 1 0> experi mental ZAP
ZOLZ Pattern at l arge precessi on angl e (3)
- FOLZ / ZOLZ shi ft
- No FOLZ / ZOLZ
peri odi ci ty di fference
- Forbi dden refl ecti ons ?
- FOLZ / ZOLZ shi ft
- No FOLZ / ZOLZ
peri odi ci ty di fference
- Forbi dden refl ecti ons
<1 1 0> experi mental ZAP
ZOLZ Pattern at l arge precessi on angl e (3)
<1 1 0> experi mental ZAP
ZOLZ CBED Pattern
- FOLZ / ZOLZ shi ft
- No FOLZ / ZOLZ
peri odi fi ty di fference
- Forbi dden refl ecti ons
[1 1 0] ZOLZ
[1 1 0] FOLZ
cP
<1 1 0>
1
e
2
e
1
e
2
=e
1
2
Shi ft
cP
<1 1 0>
2
b
a
(cP
<1 1 0>
2
b
)
cP
<1 1 0>
2
b
b
(cP
<1 1 0>
2
b
)
cP
<1 1 0>
3
si mi l ar to cI
<1 1 0>
1
cP
<1 1 0>
2
a
si mi l ar to cI
<1 1 0>
3
1 01
01 0
Compari son wi th theoreti cal patterns
<1 1 0> ZAP - P Bravai s l atti ce
cP
<1 1 0>
4
cP
<1 1 0>
5
a
(cP
<1 1 0>
5)
cP
<1 1 0>
5
b
(cP
<1 1 0>
5)
1 01
020
Compari son wi th theoreti cal patterns
<1 1 0> ZAP - P Bravai s l atti ce
cP
<1 1 0>
4
cP
<1 1 0>
5
a
(cP
<1 1 0>
5)
cP
<1 1 0>
5
b
(cP
<1 1 0>
5)
1 01
020
Compari son wi th theoreti cal patterns
<1 1 0> ZAP - P Bravai s l atti ce
020
[1 1 0] ZOLZ
[1 1 0] FOLZ
cI
<1 1 0>
1
e
2
e
1
e
2
=e
1
2
Shi ft
Shi ft
cI
<1 1 0>
2
cI
<1 1 0>
4
a
(cI
<1 1 0>
4)
202
040
cI
<1 1 0>
4
b
(cI
<1 1 0>
4)
si mi l ar to cP
<1 1 0>
1
cI
<1 1 0>
3
si mi l ar to cP
<1 1 0>
2
a
1 01
Compari son wi th theoreti cal patterns
<1 1 0> ZAP - Bravai s l atti ce
CUB C CRYSTAL SYSTEM - F Bravai s l atti ce - <1 1 0> ZAPs
020
202
[1 1 0] ZOLZ
[1 1 0] FOLZ
cF
<1 1 0>
1
e
2
e
1
e
2
=e
1
2
cF
<1 1 0>
2
a
(cF
<1 1 0>
2)
cF
<1 1 0>
2
b
(cF
<1 1 0>
2)
cF
<1 1 0>
3 cF
<1 1 0>
4
Al ternate
Compari son wi th theoreti cal patterns
<1 1 0> ZAP - F Bravai s l atti ce
SECOND STEP
denti fi cati on of the EXT NCT ON SYMBOL
Rel ati on between the pattern types and the exti ncti on symbol s
CUB C CRYSTAL SYSTEM
Number Exti ncti on
Symbol
-
Di ffracti on
Symbol
Laue cl ass m3 Laue cl ass m3m
Poi nt group
23 432 m3 43m <001 > <1 1 0> <1 1 1 >
(opti onal )
cP1
cP2
a
cP2
b
cP3
cP4
cP5
cP6
cP7
P---
m3 P---
P---
m3m P---
P2
1
--
m3 P2
1
--
P4
2
--
m3m P4
2
--
P4
1
--
m3m P4
1
--
P--n
m3m P--n
Pa--
m3 Pa--
Pn--
m3 Pn--
Pn--
m3m Pn--
Pn-n
m3m Pn-n
P23
(1 95)
P2
1
3
(1 98)
Pm3
(200)
Pa3
(205)
Pn3
(201 )
P432
(207)
P4
2
32
(208)
P4
1
32
(21 3)
P4
3
32
(21 2)
P43m
(21 5)
P43n
(21 8)
m3m
Pm3m
(221 )
Pm3n
(223)
Pn3m
(224)
Pn3n
(222)
cP
<001 >
1
cP
<001 >
2
a
cP
<001 >
2
a
b
(cP
<001 >
2
a
)
cP
<001 >
3
cP
<001 >
4
cP
<001 >
2
b
b
(cP
<001 >
2
b
)
cP
<001 >
5
a
(cP
<001 >
5)
cP
<001 >
5
b
(cP
<001 >
5)
cP
<1 1 0>
1
cP
<1 1 0>
2
a
cP
<1 1 0>
3
cP
<1 1 0>
4
cP
<1 1 0>
2
b
a
(cP
<1 1 0>
2
b
)
cP
<1 1 0>
5
a
(cP
<1 1 0>
5)
cP
<1 1 0>
2
b
b
(cP
<1 1 0>
2
b
)
cP
<1 1 0>
5
b
(cP
<1 1 0>
5)
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
b
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
d
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
2
Pattern type
Rel ati on between the pattern types and the exti ncti on symbol s
CUB C CRYSTAL SYSTEM
Number Exti ncti on
Symbol
-
Di ffracti on
Symbol
Laue cl ass m3 Laue cl ass m3m
Poi nt group
23 432 m3 43m <001 > <1 1 0> <1 1 1 >
(opti onal )
cP1
cP2
a
cP2
b
cP3
cP4
cP5
cP6
cP7
P---
m3 P---
P---
m3m P---
P2
1
--
m3 P2
1
--
P4
2
--
m3m P4
2
--
P4
1
--
m3m P4
1
--
P--n
m3m P--n
Pa--
m3 Pa--
Pn--
m3 Pn--
Pn--
m3m Pn--
Pn-n
m3m Pn-n
P23
(1 95)
P2
1
3
(1 98)
Pm3
(200)
Pa3
(205)
Pn3
(201 )
P432
(207)
P4
2
32
(208)
P4
1
32
(21 3)
P4
3
32
(21 2)
P43m
(21 5)
P43n
(21 8)
m3m
Pm3m
(221 )
Pm3n
(223)
Pn3m
(224)
Pn3n
(222)
cP
<001 >
1
cP
<001 >
2
a
cP
<001 >
2
a
b
(cP
<001 >
2
a
)
cP
<001 >
3
cP
<001 >
4
cP
<001 >
2
b
b
(cP
<001 >
2
b
)
cP
<001 >
5
a
(cP
<001 >
5)
cP
<001 >
5
b
(cP
<001 >
5)
cP
<1 1 0>
1
cP
<1 1 0>
2
a
cP
<1 1 0>
3
cP
<1 1 0>
4
cP
<1 1 0>
2
b
a
(cP
<1 1 0>
2
b
)
cP
<1 1 0>
5
a
(cP
<1 1 0>
5)
cP
<1 1 0>
2
b
b
(cP
<1 1 0>
2
b
)
cP
<1 1 0>
5
b
(cP
<1 1 0>
5)
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
b
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
d
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
2
Pattern type
cP
<001 >
4
cP
<1 1 0>
4
Rel ati on between the pattern types and the exti ncti on symbol s
CUB C CRYSTAL SYSTEM
Number Exti ncti on
Symbol
-
Di ffracti on
Symbol
Laue cl ass m3 Laue cl ass m3m
Poi nt group
23 432 m3 43m <001 > <1 1 0> <1 1 1 >
(opti onal )
cP1
cP2
a
cP2
b
cP3
cP4
cP5
cP6
cP7
P---
m3 P---
P---
m3m P---
P2
1
--
m3 P2
1
--
P4
2
--
m3m P4
2
--
P4
1
--
m3m P4
1
--
P--n
m3m P--n
Pa--
m3 Pa--
Pn--
m3 Pn--
Pn--
m3m Pn--
Pn-n
m3m Pn-n
P23
(1 95)
P2
1
3
(1 98)
Pm3
(200)
Pa3
(205)
Pn3
(201 )
P432
(207)
P4
2
32
(208)
P4
1
32
(21 3)
P4
3
32
(21 2)
P43m
(21 5)
P43n
(21 8)
m3m
Pm3m
(221 )
Pm3n
(223)
Pn3m
(224)
Pn3n
(222)
cP
<001 >
1
cP
<001 >
2
a
cP
<001 >
2
a
b
(cP
<001 >
2
a
)
cP
<001 >
3
cP
<001 >
4
cP
<001 >
2
b
b
(cP
<001 >
2
b
)
cP
<001 >
5
a
(cP
<001 >
5)
cP
<001 >
5
b
(cP
<001 >
5)
cP
<1 1 0>
1
cP
<1 1 0>
2
a
cP
<1 1 0>
3
cP
<1 1 0>
4
cP
<1 1 0>
2
b
a
(cP
<1 1 0>
2
b
)
cP
<1 1 0>
5
a
(cP
<1 1 0>
5)
cP
<1 1 0>
2
b
b
(cP
<1 1 0>
2
b
)
cP
<1 1 0>
5
b
(cP
<1 1 0>
5)
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
a
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
b
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
1
d
(cP
<1 1 1 >
1 )
cP
<1 1 1 >
2
Pattern type
cP
<001 >
4
cP
<1 1 0>
4
THE SPACE GROUP S UN QUELY DENT F ED
AS
Pa3 (205)
Exti ncti on and di ffracti on symbol s
m3 Pa--
CUB C CRYSTAL SYSTEM
P Bravai s l atti ce
cP5
m3 Pa--

CBED Precessi on
(ZOLZ), WP (ZOLZ), WP
Possi bl e
space groups
<1 1 0> symmetri es
Pa3 (205) (2mm), m (2mm), m
Pa3 (205)
Si mi l ar to
cI
<1 1 1 >
2
b
(cI
<1 1 1 >
2)
01 0
1 01
200
01 0
e
2
e
1
e
1
=e
2
[001 ] ZOLZ
e
2
e
1
e
2
=e
1
2
[001 ] FOLZ
[1 01 ] FOLZ
[1 01 ] ZOLZ
cP
<001 >
4

CBED Precessi on
(ZOLZ), WP (ZOLZ), WP
Possi bl e
space groups
<001 > symmetri es
Pa3 (205) (2mm), 2mm (2mm), 2mm

CBED Precessi on
(ZOLZ), WP (ZOLZ), WP
Possi bl e
space groups
<1 1 1 > symmetri es
Pa3 (205) (6), 3 (6), 3
1 1 0
[1 1 1 ] ZOLZ
[1 1 1 ] FOLZ
cP
<1 1 1 >
2
Si mi l ar to
cI
<1 1 1 >
2
b
(cI
<1 1 1 >
2)
01 1
cP
<1 1 0>
4
[01 0]
[1 00]
[1 01 ]
[1 1 1 ]
a
c
b
[001 ]
2
1
2
1
2
1
m3 Pa-- m3
Possi bl e
space groups
Di ffracti on and
exti ncti on symbol s
Laue cl ass
(opti onal )
<001 > <1 1 0> <1 1 1 >
cP
<001 >
4 cP
<1 1 1 >
2 cP
<1 1 0>
4
Exti ncti on and di ffracti on symbol s
m3 Pa--
CUB C CRYSTAL SYSTEM
P Bravai s l atti ce
cP5
m3 Pa--

CBED Precessi on
(ZOLZ), WP (ZOLZ), WP
Possi bl e
space groups
<1 1 0> symmetri es
Pa3 (205) (2mm), m (2mm), m
Pa3 (205)
Si mi l ar to
cI
<1 1 1 >
2
b
(cI
<1 1 1 >
2)
01 0
1 01
200
01 0
e
2
e
1
e
1
=e
2
[001 ] ZOLZ
e
2
e
1
e
2
=e
1
2
[001 ] FOLZ
[1 01 ] FOLZ
[1 01 ] ZOLZ
cP
<001 >
4

CBED Precessi on
(ZOLZ), WP (ZOLZ), WP
Possi bl e
space groups
<001 > symmetri es
Pa3 (205) (2mm), 2mm (2mm), 2mm

CBED Precessi on
(ZOLZ), WP (ZOLZ), WP
Possi bl e
space groups
<1 1 1 > symmetri es
Pa3 (205) (6), 3 (6), 3
1 1 0
[1 1 1 ] ZOLZ
[1 1 1 ] FOLZ
cP
<1 1 1 >
2
Si mi l ar to
cI
<1 1 1 >
2
b
(cI
<1 1 1 >
2)
01 1
cP
<1 1 0>
4
[01 0]
[1 00]
[1 01 ]
[1 1 1 ]
a
c
b
[001 ]
2
1
2
1
2
1
m3 Pa-- m3
Possi bl e
space groups
Di ffracti on and
exti ncti on symbol s
Laue cl ass
(opti onal )
<001 > <1 1 0> <1 1 1 >
cP
<001 >
4 cP
<1 1 1 >
2 cP
<1 1 0>
4

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