1

IIT-JEE 2002 Paper

IIT-JEE 2002 TEST PAPER

MAIN EXAMINATION
Time : 2.00 Hrs Max. Marks : 60

SUBJECT : PHYSICS
GENERAL INSTRUCTIONS
1. 2. 3. 1. There are 12 questions in this paper. Each question carries 5 Marks. The use of Arabic numerals (0,1,2,........9) only is allowed in answering the questions irrespective of the language in which you answer. Two narrow cylindrical pipes A and B have the same length. Pipe A is open at both ends and is filled with a monoatomic gas of molar mass MA. Pipe B is open at one end and closed at the other end , and is filled with a diatomic gas of molar mass MB. Both gases are at the same temperature. (a) If the frequency of the second harmonic of the fundamental mode in pipe A is equal to the frequency of MA the third harmonic of the fundamental mode in pipe B, determine the value of M . B (b) Now the open end of pipe B is also closed (so that the pipe is closed at both ends). Find the ratio of the fundamental frequency in pipe A to that in pipe B. A cubical box of side 1 meter contains helium gas (atomic weight 4) at a pressure of 100 N/m2. During an observation time of 1 second, an atom travelling with the root-mean-square speed parallel to one of the edges of the cube, was found to make 500 hits with a particular wall, without any collision with other atoms. Take R 25 = J/mol-K and k = 1.38 1023 J/K. 3 (a) Evaluate the temperature of the gas. (b) Evaluate the average kinetic energy per atom. (c) Evaluate the total mass of helium gas in the box. A uniform solid cylinder of density 0.8 g/cm3 floats in equilibrium in a combination of h AIR two non-mixing liquids A and B with its axis vertical. The densities of the liquids A and B are 0.7g/cm3 and 1.2 g/cm3 respectively. The height of liquid A is hA = 1.2 cm. The h A length of the part of the cylinder immersed in liquid B is hB = 0.8 cm. h
A

2.

3.

(a) Find the total force exerted by liquid A on the cylinder. (b) Find h, the length of the part of the cylinder in air. (c) The cylinder is depressed in such a way that its top surface is just below the upper surface of liquid A and is then released. Find the acceleration of the cylinder immediately after it is released. 4. A thin uniform wire AB of length 1m, an unknown resistance X and a resistance of 12 ! are connected by thick conducting strip, as shown in the figure. A battery and a galvanometer (with a sliding jockey connected to it) are also available. Connections are to be made to measure the unknown resistance X using the principle of Wheatstone bridge. Answer the following questions. (a) Are there positive and negative terminals on the galvanometer ? (b) Copy the figure in your answer book and show the battery and the galvanometer (with jockey) connected at appropriate points.

IIT-JEE 2002 Paper

(c)

5.

After appropriate connections are made, it is found that no deflection takes place in the galvanometer when the sliding 12! X jockey touches the wire at a distance of 60 cm from A, Obtain the value of the resistance X. B C D A A hydrogen " like atom (described by the Bohr model) is observed to emit six wavelengths, originating from all possible transitions between a group of levels. These levels have energies between " 0.85 eV and " 0.544 eV (including both these values): (a) (b) Find the atomic number of the atom. Calculate the smallest wavelength emitted in these transitions.

6.

[ Take hc = 1240 eV " nm, ground state energy of hydrogen atom = " 13.6 eV ] A point source S emitting light of wavelength 600 nm is placed at a very small height h above a flat reflecting surface AB as shown in figure. The intensity of the reflected light is 36 % of the incident intensity. Interference fringes are observed on a screen placed parallel to the reflecting surface at a very large distance D from it. (a) What is the shape of the interference fringes on the screen? (b) (c) Calculate the ratio of the minimum to the maximum intensities in the interference fringes formed near the point P. (Shown in the figure) If the intensity at point P corresponds to a maximum, calculate the minimum distance through which the reflecting surface AB should be shifted so that the intensity at P again becomes maximum.

7.

A rectangular loop PQRS made from a uniform wire has length a, width b and mass m. It is free to rotate about the ar m PQ, which r em ains hinged along a hor izontal line tak en as the y-axis as shown in figure. Take the vertically upward direction as the z " axis. A uniform magnetic field

! % i ) 4k B = ( & 3 # B0 exists in the region. The loop is held in the x " y plane ' $
and a current I is passed through it. The loop is now released and is found to stay in the horizontal position in equilibrium. (a) (b) (c) 8. What is the direction of the current I in PQ? Find the magnetic force on the arm RS. Find the expression for I in terms of B0, a, b and m.
4 2

Q y
a

S b

Two metallic plates A and B, each of area 5 10 m , are placed parallel to each other at a separation of 1 cm. Plate B carries a positive charge of 33.7 1012 C. A monochromatic beam of light, with photons of energy 5 eV each, starts falling on plate A at t = 0 so that 1016 photons fall on it per square meter per second. Assume that one photoelectron is emitted for every 106 incident photons. Also assume that all the emitted photoelectrons are collected by plate B and the work function of plate A remains constant at the value 2 eV. Determine (a) (b) (c) The number of photoelectrons emitted up to t = 10s. The magnitude of the electric field between the plates A and B at t = 10 s and The kinetic energy of the most energetic photoelectron emitted at t = 10s when it reaches plate B. Take * 0 = 8.85 1012 C2 /Nm 2.
A

9.

A metal bar AB can slide on two parallel thick metallic rails separated by a distance ". A resistance R and an inductance L are connected to the rails as shown in the figure. A long straight wire carrying a constant current +0 is placed in the plane of the rails and perpendicular to them as shown. The bar AB is held at rest at a distance x 0 from the long wire. At t = 0 , it is made to slide on the rails away from the wire. Answer the following questions.

I0

R L

"
B

x0

IIT-JEE 2002 Paper

(a)

di d, and , where i is the current in the circuit and , is the flux of the dt dt magnetic field due to the long wire through the circuit.

Find a relation among i,

(b)

It is observed that at time t = T, the metal bar AB is at a distance of 2x 0 from the long wire and the resistance R carries a current i1. Obtain an expression for the net charge that has flown through resistance R from t = 0 to t = T. The bar is suddenly stopped at time T. The current through resistance R is found to be i1/4 at time 2T. Find the value of L/R in terms of the other given quantities.

(c)

10.

On a frictionless horizontal surface, assumed to be the x " y plane a small trolley A is moving along a straight line parallel to the y " axis as shown in the figure with a constant velocity of

3 " 1 m/s. At a particular instant, when the line OA makes

an angle of 45 with the x " axis, a ball is thrown along the surface from the origin O. Its velocity makes an angle / with the x " axis it hits the trolley. (a) The motion of the ball is observed from the frame of the trolley. Calculate the angle 01 made by the velocity of the ball with the x " axis in this frame. (b) 11. Find the speed of the ball with respect to the surface, if / = 4 1/3.

A spherical ball of mass m is kept at the highest point in the space between two fixed, concentric spheres A and B (see figure). The smaller sphere A has a radius R and the space between the two spheres has a width d. The ball has a diameter very slightly less than d. All surfaces are frictionless. The ball is given a gentle push (towards the right in the figure). The angle made by the radius vector of the ball with the upward vertical is denoted by 1 (shown in figure) (a) (b)

Sphere B 1 d R o Sphere A

Express the total normal reaction force exerted by the spheres on the ball as a function of angle 1. Let NA and NB denote the magnitudes of the normal reaction force on the ball exerted by the spheres A and B, respectively. Sketch the variations of NA and NB as functions of cos1 in the range 0 2 1 2 3 by drawing two separate graphs in your answer book, taking cos1 on the horizontal axis.

12.

Three particles A, B and C each of mass m, are connected to each other by three massless rigid rods to form a rigid, equilateral triangular body of side ". This body is placed on a horizontal frictionless table (xy plane) and is hinged to it at the point A so that it can move without friction about the vertical axis through A (see figure). The y body is set into rotational motion on the table about A with a constant angular velocity 4. (a) (b) Find the magnitude of the horizontal force exerted by the hinge on the body.
A x

At time T, when the side BC is parallel to the x-axis , a force F is applied

4

on B along BC (as shown). Obtain the x-component and y-component of the force exerted by the hinge on the body, immediately after time T.
F B " C

IIT-JEE 2002 Paper

ANSWER KEY TO IIT-JEE 2002 TEST PAPER

MAIN EXAMINATION
1. 3. 5.

MA 400 (a) M = 189 B

(a) zero

fA 3 (b) f = 4 B

2.

(a) 160 K 4. 6.

(b) 3.312 1021 J

(c) 3 104 kg

(b) 0.25 cm

(c) g/6 (upwards).

X = 8! (a) Circular (b)

1 16

(a) n = 12, z = 3 (b) 620/153

5m

(c) 6 /2 = 300 nm
N C

7.

mg 4 (a) from P to Q (b) ibB0 (3 k i ) (c) 6bB 0

8.

(a) 5.0 107

(b) 2 103

(c) 23 eV

9. 10.

(a)

d/ di = iR + L dt dt

(b) 7q =

1 = 5 0I0 " In( 2) " Li : 18 ; R < 23 9

(c) >L =

T L = In (4) R

(a) 01 = 45

(b) 2 m/s

NA
mg
5mg

NB

11.

(a) N = 3mg cos1 - 2mg, (b)

cos1 cos1 =2/3 cos 1=1

cos 1

cos1=2/3 cos1=1

12.

(a) m"42

(b) Fx =

F , Fy = 3 m"42 4

IIT-JEE 2002 Paper

IIT-JEE 2002 TEST PAPER

MAIN EXAMINATION
Time : 2.00 Hrs Max. Marks : 60

SUBJECT : CHEMISTRY
GENERAL INSTRUCTIONS
(i) (ii) (iii) There are 12 questions in this paper. Each question carries 5 Marks. The use of Arabic numerals (0,1,2,........9) only is allowed in answering the questions irrespective of the language in which you answer.

Useful data : Gas constant, Avagardro number, Planck constant, Boltzmann constant, Atomic number : Atomic Weight : 1.

R = 0.082 L atm K1 mol1 = 8.314 J1 K1 mol1 NA = 6.02 1023 mol1 h = 6.626 1034 Js kB = 1.38 1023 JK1 B = 5 ; Al = 13 ; K = 19, Cr = 24, Fe = 26, Ni = 28, Cu = 29, Zn = 30 H = 1.00, B = 10.81, C = 12.00, O = 16.00, Ni = 58.69

500 ml of 0.2 M aqueous solution of acetic acid is mixed with 500 mL of 0.2 M HCl at 25 C. (a) Calculate the degree of dissociation of acetic acid in the resulting solution and pH of the solution. (b) If 6 g of NaOH is added to the above solution, determine final pH. Assume there is no change in volume on mixing. Ka of acetic acid is 1.75 10-5 M.

2.

Two moles of a perfect gas undergo the following process : (a) (b) (c) a reversible isobaric expansion from (1.0 atm, 20.0 L) to (1.0 atm, 40.0 L). a reversible isochoric change of state from (1.0 atm, 40.0 L) to (0.5 atm, 40.0 L). a reversible isothermal compression from (0.5 atm, 40.0 L) to (1.0 atm, 20.0 L). (i) Sketch with labels each of the processes on the same P-V diagram. (ii) Calculate the total work (w) and the total heat change (q) involved in the above processes. (iii) What will be the values of !U, !H and !S for the overall process.

3.

The density of the vapours of a substance at 1 atm pressure and 500 K is 0.36 Kg m3.The vapour effuses through a small hole at a rate of 1.33 times faster than oxygen under the same conditions. (a) Determine (i) molecular weight (ii) molar volume (iii) compression factor(z) of the vapours and (iv) which forces among gas molecules are dominating, the attractive or repulsive. (b) If the vapours behave ideally at 1000 K determine the average translational kinetic energy of a molecule.

4. 5.

64Cu (half

life = 12.8 hours) decays by " emission(38%), " + emission(19%) and electron capture(43%). Write the decay products and calculate partial half lives for each of the decay processes. Deduce the structure of [NiCl4]2 and [Ni(CN)4]2 considering the hybridisation of the metal ion. Calculate the magnetic moment (spin only) of the species.

6 6. 7. 8.

IIT-JEE 2002 Paper

Write balanced equations for the reactions of the following compounds with water. (i) Al4C3 (ii) CaNCN (iii) BF3 (iv) NCl3 (v) XeF4 How is boron obtained from borax. Give chemical equations with reaction conditions. Write the structure of B2H6 and its reaction with HCl. When a crystaline compound (X) is heated with K2Cr2O7 and concentrated H2SO4, a deep red gas (A) is evolved. On passing (A) into caustic soda solution, a yellow coloured solution of (B) is obtained. Neutralizing the solution of (B) with acetic acid and on subsequent addition of lead acetate a yellow precipitate (C) is obtained. When (X) is heated with NaOH solution, a colourless gas is evolved and on passing this gas into K2Hg#4 solution, a reddish brown precipitate (D) is formed. Identify (A), (B), (C), (D) and (X). Write the equations of reactions involved. Five isomeric para-disubstituted aromatic compounds A to E with molecular formula C8H8O2 were given for identification. Based on the following observations, give structures of the compounds. (i) Both A and B form a silver mirror with Tollens reagent; also B gives a positive test with FeCl3 solution. (ii) C gives positive iodoform test. (iii) D is readily extracted in aqueous NaHCO3 solution. (iv) E on acid hydrolysis gives 1, 4dihydroxybenzene.

9.

10.

Identify X, Y and Z in the following synthetic scheme and write their structures.
2 4 2 4 %%% % & X %% % & Z CH3CH2C $ C H % %%%% % & Y %% % % % % ( ii) CH CH Br 3 2

(i) NaNH

H / Pd .BaSO

alkaline KMnO

Is the compound Z optically active ? Justify your answer. 11. Write structures of the products A, B, C, D and E in the following scheme.
Na ' Hg / HCl
HNO / H SO

3 %& B %%2% % % % & A %% %% %

Cl / FeCl

3 2 4 %% % %% % % & C

2 E (% %% %% D

H / Pd / C

12.

A biologically active compound, Bombykol (C16H30O) is obtained from a natural source. The structure of the compound is determined by the following reactions. (i) On hydrogenation, Bombykol gives a compound (A), C16H34O, which reacts with acetic anhydride to give an ester. (ii) Bombykol also reacts with acetic anhydride to give another ester (B), which on oxidative ozonolysis (O3 /H2O2) gives a mixture of butanoic acid, oxalic acid and 10-acetoxy decanoic acid. Determine the number of double bonds in bombykol. Write the structures of compound A and B. How many geometrical isomers are possible for Bombykol ?

IIT-JEE 2002 Paper

ANSWER KEY TO IIT-JEE 2002 TEST PAPER MAIN EXAMINATION

1. (a) 0.0175%, 1 (b) 4.757

2.

(i)

; (ii) w = 621.9, q = + 621.9, (iii) !U = !H = !S = 0

3. 4. 5. 6.

(a) 18, 50.25 103 , 1.225 (t1/2)1 = 36.1 hr1,

(b) 2.07 1020 J.

(t1/2)2 = 72.2 hr1, (t1/2)3 = 27.44 hr1.

[NiCl4]2, tetrahedral geometry and magnetic moment 2.82 B.M. [Ni(CN)4]2, square palanr and magnetic moment zero.
%& 4 Al(OH)3 + 3CH4 ) (i) Al4C3 + H2O %
%& H3BO3 + 3 (iii) 4BF3 + 6H2O %

%& CaCO3 * + NH3 ) (ii) CaNCN + 3H2O %

[BF4]

3H3O+

%& NH3 + 3HOCl (iv) NCl3 + 3H2O %

%& 4Xe + 2XeO3 + 24HF + 3O2. (v) 6XeF4 + 12H2O %

7.

red hot Na2B4O7 + 2HCl + 5H2O % %& 4H3BO3 + 2NaCl ; 2H3BO 3 %% % %& B 2O 3 (boric anhydride ) + 3H2O

B 2O3 + 3Mg %% % %& 2B + 3MgO ; Reaction with HCl : B2H6 + HCl %& B2H5Cl + H2

fusion

Structure of B2H6 :

H................ B ................ H is hydrogen bridge i.e, 3 centre two electron bond. 8. (X) = NH4Cl, (A) = CrO2Cl2 , (B) = Na2CrO4 , (C) = PbCrO4 , (D) =

9.

(A)

(B)

(C)

(D)

(E)

IIT-JEE 2002 Paper

10.

OH OH | | CH3 ' CH2 ' C ' C ' CH2 ' CH3 (Optically inactive) | | H H ( Compound ' Z' )

O || CH2 CH2 CH3

11.

A = Cl
Cl 'A'

B=

C=

D=

E=

12.

Structure of Bombykol is CH3 CH2 CH2 CH = CH CH = CH(CH2)8CH2OH

IIT-JEE 2002 Paper

IIT-JEE 2002 TEST PAPER

MAIN EXAMINATION
Time : 2.00 Hrs Max. Marks : 60

SUBJECT : MATHEMATICS
GENERAL INSTRUCTIONS
(i) (ii) (iii) 1. 2. There are 12 questions in this paper. Each question carries 5 Marks. The use of Arabic numerals (0,1,2,........9) only is allowed in answering the questions irrespective of the language in which you answer. Find the area of the region bounded by the curves, y = x 2, y = !2 " x 2! & y = 2 which lies to the right of the line x = 1. Let a complex number #, # $ 1, be a root of the equation zp + q zp zq + 1 = 0, where p, q are distinct primes. Show that either 1 + # + #2 + ... + #p 1 = 0 or 1 + # + #2 + ... #q 1= 0 but can not be true together.
' x * a if Let f(x) = & %| x " 1 | if if ' x *1 and g(x) = & 2 ( x " 1 ) * b if x(0 % x)0 x)0 x(0

3.

, where a and b are non-negative real

numbers. Determine the composite function gof. If (gof) (x) is continuous for all real x, determine the values of a and b. Further, for these values of a and b, is gof differentiable at x = 0? 4. 5. Prove that in an ellipse, the perpendicular from a focus upon any tangent and the line joining the centre of the ellipse to the point of contact meet on the corresponding directrix. For any natural number m, evaluate,

+
6. 7.

,x

3m

* x2 m * x m

- ,2 x

2m

* 3x m * 6

1/ m

d x, x > 0.

Prove that, cos tan "1 sin cot "1 x =

x 2 *1 x 2 *2

A box contains N coins, m of which are fair and the rest are biased. The probability of getting a head when a fair coin is tossed is 1/2, while it is 2/3 when a biased coin is tossed. A coin is drawn from the box at random and is tossed twice. The first time it shows head and the second time it shows tail. What is the probability that the coin drawn is fair? Let a, b be positive real numbers. If a, A1, A2, b are in arithmetic progression, a, G1, G2, b are in geometric progression and a, H1, H2, b are in harmonic progression, then show that

8.

G1 G 2 A * A2 ( 2 a * b ) (a * 2 b ) = 1 = . 9ab H1 H 2 H1 * H 2

2 9.

IIT-JEE 2002 Paper

A straight line L through the origin meets the lines x + y = 1 and x + y = 3 at P and Q respectively. Through P and Q two straight lines L1 and L2 are drawn parallel to 2x y = 5 and 3x + y = 5 respectively. Lines L1 and L2 intersect at R. Show that the locus of R, as L varies, is a straight line. A straight line L with negative slope passes through the point (8, 2) and cuts the positive coordinate axes at points P and Q. Find the absolute minimum value of OP + OQ, as L varies, where O is the origin. Let V be the volume of the parallelopiped formed by the vectors,

10.

11.

! " i * a2 " j * a3 k a = a1 "

! " i * b2 " j * b3 k b = b1 "

3

! " c = c1 " i * c2 " j * c3 k

If ar, br, c r, where r = 1, 2, 3, are non-negative real numbers and show that V 0 L3. 12.

/
r .1

(ar + br + c r) = 3 L,

Use mathematical induction to show that, (25)n+1 24n + 5735 is divisible by (24)2 for all n = 1, 2, ... .

ANSWER KEY TO IIT-JEE 2002 TEST PAPER MAIN EXAMINATION

' x * a *1 1 2 1( x * a " 1) * b g(f(x)) = & x2 * b 1 2 1 % ( x " 2) * b if if if if x ) "a a0x)0 0 0 x 01 x 21

3.

, a = 1, (B) = 0, gof differentia(B)le at x = 0

m*1

5.

z m + c, where z = 2 x 3m + 3 x 2m + 6 x m 6 (m * 1)

7.

9m 8N* m

10.

18