U008 en

Flat Products
Coated Steel Sheets

Hot-dip Galvanized Sheets, Electrogalvanized Sheets
and Precoated Sheets
2-6-1 Marunouchi, Chiyoda-ku,Tokyo 100-8071 Japan
Tel: +81-3-6867-4111
Coated Steel Sheets
2012 NIPPON STEEL & SUMITOMO METAL CORPORATION
U008en_01_201211f
http://www.nssmc.com/
Hot-dip galvanized steel sheets
Electrogalvanized steel sheets
Precoated Sheets
Advanced control over the coating atmo-
sphere secures adhesion of the zinc to the
base metal, thereby ensuring good workabil-
ity. These products are used mainly in home
electric appliances and building materials.
Advanced control over the coating atmo-
sphere secures adhesion of the zinc to the
base metal, thereby ensuring good workabil-
ity. These products are used mainly in home
electric appliances and building materials.
The surface texture is uniform and beautiful.
The lack of heat treatment during the coat-
ing process helps to retain the properties of
the base metal. These products are used
mai nl y i n home el ectri c appl i ances for
indoor use.
Building
structural
member
Roof, wall
Housing
structural
member
Road fence
Deck plate
Ofce
equipment
AV equipment
Copying
machine
Ofce
equipment
Washing
machine
Copying
machine
Steel furniture
Greenhouse Steel furniture
Washing
machine
Refrigerator
Refrigerator
Battery cell Heater Kitchen stove Automobile
Air conditioner
(outdoor unit)
Air conditioner
(outdoor unit)
Building
structural
member
Housing
structural
member
Tank roof
Automatic
vending
machine
Air conditioner
(outdoor unit)
Washing
machine
Refrigerator Duct
Heater Microwave oven Kitchen stove
Automobile
AV equipment Precision
machine
Civil
engineering
structure
DURGRIP
TM
Hot-dip galvannealed steel sheet and strip
DURGRIP
TM
Hot-dip galvanized steel sheet and strip
SuperDyma
TM
Hot-dip zinc-aluminum-magnesium-silicon alloy coated steel sheet and strip
GALVALUME STEEL SHEET
TM
Hot-dip 55% aluminum-zinc alloy-coated steel sheet and strip
ALSHEET
TM
Hot-dip aluminum-coated steel sheet and strip
ECOKOTE
TM
-S
Sn-Zn coated steel sheet and strip
ZINKOTE
TM
Electrolytic zinc-coated steel sheet and strip
DURZINKLITE
TM
Electrolytic zinc-nickel
alloy-coated steel sheet and strip
ECOTRIO
TM
Zn-Si-Ni alloy coated steel sheet and strip
SUPERNICKEL
TM
Nickel Coated Steel Sheet and strip
ZINKOTE
TM
COLOR
Pre-Coating Steel Sheet and Strip
VIEWKOTE
TM

Building
structural
member
Roof, wall
Housing
structural
member
Road fence
Deck plate
Ofce
equipment
AV equipment
Copying
machine
Ofce
equipment
Washing
machine
Copying
machine
Steel furniture
Greenhouse Steel furniture
Washing
machine
Refrigerator
Refrigerator
Battery cell Heater Kitchen stove Automobile
Air conditioner
(outdoor unit)
Air conditioner
(outdoor unit)
Building
structural
member
Housing
structural
member
Tank roof
Automatic
vending
machine
Air conditioner
(outdoor unit)
Washing
machine
Refrigerator Duct
Heater Microwave oven Kitchen stove
Automobile
AV equipment Precision
machine
Civil
engineering
structure
Steel sheets are applied throughout a broad spectrum of
life and industryincluding automobiles, home electric
appliances, building materials, housing, beverage cans,
and transformers. Economic growth in the emerging
countries and other parts of the world has spurred an
expansion in steel sheet use.
By its speedy response to a wide range of needs and
its rich line-up of products, Nippon Steel & Sumitomo
Metal Corporation is renowned for its coated steel sheets.
Nippon Steel & Sumitomo Metal develops and markets
high-performance steel materials capable of responding to
increasingly stringent needs, such as growing concern for
the environment and energy conservation.
Coated steel sheets, in particular, are required to
possess not only rust resistance but press formability,
Coated Steel Sheets of Nippon Steel & Sumitomo Metal Corporation
weldability, paintability, and various other properties as
well. In addition to metallurgy, a growing diversity of other
technologies is indispensable for meeting these needs.
They include electro-chemistry, thin-lm engineering, paint
engineering, interface engineering, corrosion science,
thermal technol ogy, and al l oyi ng control (di f fusi on)
technology. In the case of coated steel sheets, if any of
these technologies is lacking, customer needs cannot be
fullled.
Nippon Steel & Sumitomo Metal has outstanding
command of these various elemental technologies and
continues to develop products that precisely meet the
performance requirements of its customers.
Noti ce: Whi l e ever y ef for t has been made to ensure the accuracy of the
information contained within this publication, the use of the information is at the
readers risk and no warranty is implied or expressed by Nippon Steel & Sumitomo
Metal Corporation with respect to the use of the information contained herein. The
information in this publication is subject to change or modication without notice.
Please contact the Nippon Steel & Sumitomo Metal Corporation ofce for the latest
information.
Please refrain from unauthorized reproduction or copying of the contents of this
publication.
The names of our products and services shown in this publication are trademarks
or registered trademarks of Nippon Steel & Sumitomo Metal Corporation, afliat-
ed companies, or third parties granting rights to Nippon Steel & Sumitomo Metal
Corporation or afliated companies. Other product or service names shown may
be trademarks or registered trademarks of their respective owners.
Hot-dip galvanizing line Electrogalvanizing line
1
Post treatment
No
treatment
Coating mass
g/m
2
Plate thickness
(mm)
Available sizes
Widthmm
Chromate-free treatment
General Lubricating
Other special
treatments
5
6
7
8
9
10
11
13
14
15
12
16
Zn
120g/m
2
(17m)
Base
metal
Zn-Al (11%)
-Mg (3%)
-Si (0.2%)
Base
metal
Zn-55%Al alloy
78g/m
2
(21m)
Base
metal
Zn
20g/m
2
(2.8m)
Base
metal
Zn-Ni alloy
20g/m
2
(2.8m)
Base
metal
Zn-Sn-Ni alloy
Base
metal
Fe-Ni alloy Base
metal
Zn-Fe alloyed
45g/m
2
(6m)
Base
metal
Al-Si alloy
50g/m
2
(18.5m)
Base
metal
20g/m2(2.8m)
Polyester, etc.
(25m)
Base
metal
Base
metal
Special lm
Ni layer
Zn
DURGRIP
TM
DURGRIP
TM
SuperDyma
TM
GALVALUME
STEEL SHEET
TM
ALSHEET
TM
ECOKOTE
TM
-S
ZINKOTE
TM
DURZINKLITE
TM
ECOTRIO
TM
SUPERNICKEL
TM
ZINKOTE
TM
COLOR
VIEWKOTE
TM
30
120
60
600
60
275
90
170
40
160
30
50
10
40
10
40
4
15
1
4m
10
40
0.5
4.5
0.23
6.0
0.27
9.0
0.25
1.6
0.3
2.5
0.3
2.0
0.4
3.2
0.4
2.3
0.15
1.0
0.15
0.8
0.4
0.8
0.3
1.2
610
1,850
580
1,840
580
1,700
610
1,230
610
1,250
610
1,250
600
1,650
600
1,650
580
1,024
25
1,000
600
1,650
25
1,300
EG type
10 40
CG type
60 150
Decorativeness, corrosion resistance, elimination
of coating process at user plant
(reduction of production process, cost cutting)
*Different properties depending on the type
Decorativeness, corrosion resistance, elimination
of coating process at user plant
*Preparation of a variety of product types: high heat
absorption, high reection, self cleaning, deep-drawable
metallic, antistatic, grainy, orange-peel-surfaced
Corrosion resistance
(30 times higher than common galvanized sheet)
Cut-edge surface corrosion resistance
Alkaline resistance
Scratch resistance
(3~6 times higher than common galvanized sheet)
Thermal resistance, heat reectivity
Decorativeness (spangle)
Press formability
Weldability
Paint adhesion
Chemical resistance
Decorativeness (aluminum)
Corrosion resistance (bio fuel)
Fuel non-permeable property
Corrosion resistance Conductivity
Lubricity, formability Fingerprint resistance
Scratch resistance Paint adhesion
*Diverse post-treatment menu
Weldability
Paint adhesion
Whisker resistance
Solder wettability
Corrosion resistance (particularly after forming)
Coating adhesion
Decorativeness (luster)
Structural member
(civil engineering/
road structure)
Automobile exhaust system parts
Heating equipment
Toaster, hot-water system
Fuel tank
AV equipment, electronic device
home appliance
OA equipment
Automobile outer and inner panels
home appliance
Housing equipment
OA equipment
Battery
Heating equipment
Main applications Features
Coating structure
(representative example)
Brand name Type
Hot-dip galvannealed
steel sheet and strip
Hot-dip galvanized
Hot-dip aluminum-coated steel
sheet and strip
Electrolytic zinc-coated
Electrolytic zinc-nickel alloy-coated
Zn-Si-Ni alloy coated
Nickel Coated
Steel Sheet and strip
Topcoat
Base
metal
Zn
Hot-dip zinc-aluminum-
magnesium-silicon alloy coated
Hot-dip 55% aluminum-zinc
alloy-coated
Sn-Zn layer
Special lm
Intro-
duction
page
home appliance
Structural member (shutter)
Steel furniture, automatic vending
machine
Structural member (house, civil
engineering structure, road member)
home appliance
Automatic vending machine
Structural member (house,
agriculture/stockbreeding structure,
solar panel supporting structure, civil
engineering/road structure),
home appliance, automobile parts
Automatic vending machine
home appliance
OA equipment
Housing equipment (interior,
steel furniture)
home appliance, AV equipment,
electronic device
Fuel cell
Housing equipment (steel
furniture, door, kitchen, bath)
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Information about environmental load chemical substances contained in the products
of Nippon Steel & Sumitomo Metal Corporation is supplied in the form shown below:
1) Material Safety Data Sheet (MSDS)
2) Information about specifed chemical substance content (supplementary MSDS)
3) Specifed Chemical Substances Data Sheet (SSDS)
For more details, please confrm by accessing our website: http://www.nssmc.com/.
Lineup of Coated Steel Sheets of Nippon Steel & Sumitomo Metal
2 3
Oxygen
blowing
Basic-oxygen
furnace
Molten iron
Continuous casting
Limestone
Sintering plant Iron ore
Coal Coking plant
Blast furnace
Continuous hot-rolling mill Pickling line
Pickled coil
Cold-rolled coil Cold-rolling mill
Welder
Cleaning
tank
Galvanizing
bath
Post
treatment
Drying Shear
Continuous annealing line
Reheating
Coil
Temper rolling mill
Secondary refning
Galvanizing
bath
Pay-off reel Heat
treatment
Welder
Skin pass
Post
treatment
equipment
Tension leveler
Tension reel
Main Characteristics
Production Process
Excellent paint adhesion and weldabilityprovided by reheating
the zinc-iron alloyed layer produced by heating
Exceptional post-painting corrosion resistance
Excellent press-formability, ranging from bending to deep
drawing
Availability of sheet with highly lubricative flm treatment
Base metal
Lubricative flm
Zn-Fe alloy layer
Typical Properties
Main Applications
DURGRIP has a finely textured yet rugged surface, ensuring good
paint adhesion.
The application of lubricative flm treatment imparts good press form-
ability.
3mm
5mm
Stretching
Treatment condition : Dip-type phosphate treatment

Cation ED 20 baking
Assessment test : After drawing grid pattern
Erichsen stretch forming, cellophane
tape peeling off
Galvanized sheet DURGRIP (Galvannealed) Cold-rolled sheet
DURGRIP (galvanized) DURGRIP (Galvannealed) Cold-rolled sheet
Examples of Paint Adhesion (Primary Adhesion)
Examples of Surface Appearance of Base Substrate Sheet before
Coating (Scanning Electron Microscope 1,000)
Base metal
Zn-Fe alloy layer
Non-treatment type
Lubricative
lm-treated type
Coating structure
GA (Lubricative flm treatment)
GA (no treatment)
Forming tolerance
Forming tolerance
(blank folding force)
25kN 20kN 15kN 10kN 7kN
25kN 15kN 10kN 7kN
: Split
: Split : Split : Pass : Creased
: Pass : Pass : Pass : Creased
Press Formability
Weldability
Paint Adhesion
The resistance weldability of galvanized steel sheet, in contrast to that
of cold-rolled steel sheet, generally requires appropriate welding con-
ditions in the region of high heat input. This is because zinc is a soft
metal that easily conforms to the partner metal and because zincs low
melting point causes it to melt and spread out during the initial welding
stage, thereby resulting in lower current density. Consequently, less
heat is generated in the overlapped areas.
Direct Spot Weldability
The appropriate welding conditions for coated steel sheets are shown
in the fgure below. Adequate welding current regions for coated steel
sheets are higher than those for cold-rolled steel sheets.
Example of Appropriate Welding Conditions for Galvanized Sheet
Welding pressure (Kg)
W
e
ld
in
g
c
u
r
r
e
n
t
(k
A
)
12
13
11
10
9
8
7
6
200 250 300 400
Shortage of strength
Occurrence of expulsion
DURGRIP
(galvanized)(90/90)
DURGRIP
(Galvannealed)(90/90)
Cold-rolled sheet
Appropriate range (base metal fracture)
t=0.8mm
Electrode: Circular type, 5.0 mm
Weld time: 10
t=0.8mm
Hood outer, inner Cowl panel
Trunk lid outer, inner
Quarter panel
Wheel house Outer
Front foor
Locker outer,
inner
Pillar outer
Door outer Front fender
Door inner
Electrogalvanizing line
Hot-dip galvanizing line
DURGRIP
TM
Hot-dip galvannealed steel sheet and strip
Electric appliances
Washing machine, refrigerator, air conditioner, automatic vending machine (outer
plate, side plate, back plate, bottom plate, parts)
Building and furniture
Signboard, door, sash, shutter, cabinet, steel furniture, ofce equipment
Automobile (outer, inner, parts)
4 5
Base metal
Lubricative flm
Zn-Fe alloy layer
Base metal
Zn-Fe alloy layer
Hot-dip galvanized sheet
Chromate-free hot-dip
galvanized sheet
Coating structure
Coating structure
Zn-Al-Mg-Si
Base metal
Chromate-free special flm
Zn-Al-Mg-Si
Base metal
Corrosion Protection Mechanism at Cut-end Surfaces
Bridge (cable rack)
Compost house (roof, frame)
Automobile parts
Air-conditioner
outer unit
(bottom plate)
Lapping of
coating layer
composition
In
it
ia
l p
e
r
io
d
(5
d
a
y
s
~
6
m
o
n
t
h
s
)
M
id
d
le
p
e
r
io
d
(6
m
o
n
t
h
s
~
s
e
v
e
r
a
l y
e
a
r
s
)
L
a
t
t
e
r
p
e
r
io
d
(S
e
v
e
r
a
l y
e
a
r
s
~
U
n
t
il z
in
c
a
r
o
u
n
d
t
h
e
c
u
t
-
e
n
d
s
u
r
fa
c
e
is
lo
s
t
)
Repaired section
Red rust
Coating layer
Iron
Coating layer
Protection flm
Iron Iron
Iron Iron
Iron Iron
Iron
Coating layer
Moisture
Iron
Coating layer
Moisture
Sacrifced corro-
sion-protection effect
Coating layer
composition
Lapping of coating
layer composition
C
o
r
r
o
s
io
n
lo
s
s
(g
/
m
2
/
s
id
e
)
20
40
60
80
100
120
0 2 4 6 8 10 12
12.5
14
pH
SuperDyma K18
GALVALUME STEEL SHEET AZ150
0
pH4~6 : Acid rain environment
pH9~14 : Cattle and compost shed environment
pH12.5 : Mortar and concrete environment
Hot-dip Zn-coated
sheet Z27
(5% NaCl solution, 24 hours)
0.028
1.02
0.100 0.000 0.200 0.300 0.400
0.034
0.060
Hot-dip zinc-coated sheet
Zn
SuperDyma
Zn-11%Al-3%Mg-0.2%Si
(Reference)
In case of no addition of Si
Zn-11%Al-3%Mg
Zn-55%Al
Corrosion loss rate (g/m2/hr)
Surface treatment: No treatment
Corrosion Protection Mechanism on Cut-end Surfaces and
at Welded Sections
Corrosion Resistance of Flat Surfaces
The corrosion resistance of SuperDyma (assessed by salt-spray tests to
determine corrosion rate) is extremely high about 30 times that of hot-dip
Zn-coated sheets.
140 120 100 80 60 40 20 0
Load: 0.098 N
Hot-dip Zn-coated
sheet
SuperDyma
GALVALUME
STEEL SHEET
Vichers hardness (Hv)
Zn
Base metal
Zn
Base metal
Typical Properties
As the zinc coating mass increases, the corrosion resistance of the hot-dip galvanized sheet is
extended.
The coating layer of SuperDyma is hard, thus offering high scratch
resistance.
Corrosion Resistance Mechanism of Conventional Chromate Treatment
and Chromate-free Coating Film
Zinc Coating Mass and Corrosion Resistance
Cold-rolled
sheet
Phosphate-treated sheet
ZINKOTE
DURGRIP
(galvanized)
Chromate Coating Film Chromate-free Coating Film
Corrosion Resistance Mechanism of Chromate-free
Coating Film : Chromate-free flm uses substances selected
because they provide the characteristic features of chromate
flm such as its barrier effect, self-restorative function and
paint adhesiveness. Chromate-free coated sheet has been
realized by use of this special coating flm.
When this flm is injured, soluble hexavalent chromium
leaches out to offer a self-restorative function that repairs
the flm.
Examp|e of Outdoor Exposure Weather|ng Tests (Sa|t Spray Tests|
1
100
200
300
2
Period (years)
3 4
C
o
r
r
o
s
io
n
lo
s
s
(g
/
m
2
)
Structure and Funct|on of Coat|ng F||ms
Function of Chromate Coating Film
Barrier effect
Self restoration function
Effects similar to those offered by
special coating lm containing corrosion-suppression agent
Shutting out of
corrosion factors
Self-restorative
function
Coating
adhesiveness
Chromate coating lm
Coating lm
Coating
adhesiveness
Coating flm
Processed/
injured section
Special coating lm
(containing corrosion-suppression agent)
Zinc coating layer
Steel sheet
Corrosion-
suppression
function
Shutting out of
corrosion factors
Corrosion factor
H2O O2
Zinc coating layer
Steel sheet
50
100
200
300
100
Coating mass (one side:g/m
2
)
150 200
T
im
e
u
p
t
o
o
c
c
u
r
r
e
n
c
e
o
f r
e
d
r
u
s
t
(H
r
s
)Testing condition (JIS Z 2371)
Room temperature : 35C
Saline solution : 5%
Zinc Coating Mass and Time up to Occurrence of Red Rust (Example) (Salt Spray Test)
Main Characteristics Main Characteristics
High corrosion, and rust resistance similar to that of
conventional chromate-treated sheet even with chromate-
free treatment
Excellent zinc adhesion and responsiveness to severe
fabrication conditions
Product lineup with excellent tribological properties by
means of chromate-free treatment
With remarkably high corrosion resistance compared to hot-dip galvanized
steel sheet, inhibits corrosion resistance in cut-end surfaces
Strong alkaline resistance even in direct contact with mortar and concrete
Superior substitute for stainless steel (weak in chlorine resistance) and
aluminum (weak in alkaline resistance)
Availability of chromate-free sheet having properties similar to those of
chromate-treated sheet
Typical Properties
Coating Layer Composition and Corrosion Resistance
(Salt Spray Tests)
Acid and Alkaline Resistance of Various Coated Sheets
Scratch Resistance
Main Applications
SuperDyma
TM
Hot-dip zinc-aluminum-magnesium-silicon alloy coated steel sheet and strip
DURGRIP
TM
Hot-dip galvanized steel sheet and strip
Civil engineering structure and building
construction
Guard rail, corrugated pipe, spiral pipe, deck plate,
duct, roofing material, fence, sound-insulation
wall, scaffolding pipe, light-gauge shape, shutter,
sash, door, housing structural member (column,
beam)
Automobile
Floor, various parts
Shipbuilding
Duct, panel
Electric appliance
Ref r i ger at or, washi ng machi ne, heat i ng
equipment, air conditioner, automatic vending
machine, showcase parts
Industrial machinery
Container for transporting agricultural product,
various parts requiring corrosion resistance
Main Applications
6 7
Coating structure
Coating structure
Zn-55%Al
Base metal
Zn-55%Al
Base metal
Materials
GALVALUME STEEL SHEET (no coating)
Prepainted sheet (light color, brightness 6.0 8.5)
Prepainted sheet (deep color, brightness 4.5 7.0)
Tile, slate (light color)
Tile, slate (dark color)
Concrete, cement
Heat Refectivity (%)
70 75
30 70
15 40
20 30
10 20
20 30
30 40
Note: Data of Bluescope Lysaght
GALVALUME STEEL SHEET Hot-dip galvanized sheet
Solar radiation
850W/m
2
(no wind)
Solar radiation
850W/m
2
(no wind)
0
50
100
150
W/m
2
0
50
100
150
W/m
2
Example of Heat Reectivity of Various Roong Materials 100 200 300 400 500 600 700 800 900
Hot-dip galvanized sheet [Z 25](400C)
0
1
2
3
4
5
6
7
8
9
10
Oxidation time (hours)
O
x
id
a
t
io
n
a
m
o
u
n
t
g
/
c
m
2
GALVALUME STEEL SHEET [AZ 150](400C)

Hot-dip galvanized sheet Z 25 300C
GALVALUME STEEL SHEET [AZ 150](300C)
0 1,000 2,000 3,000
Cut-end surface protection
1% red rust occurrence time (hours)
Z27
(AZ150)
(AZ150)
Excellent durability and corrosion resistance
Beautiful silvery white appearance with a fnely spangled
pattern
Excellent thermal resistance and high heat refectivity due to
aluminum contained in the coating
Available with chromate-free flm
Typical Properties
Main Applications
The surfaces of GALVALUME STEEL SHEET exhibit excellent heat
reflectivity, showing no substantial deterioration after long-term
exposure to high temperatures. Materials with high heat reflectivity
show a minimal rise in temperature. The use of materials with high
heat refectivity particularly in roofng subjected to large thermal loads
is highly effective in preventing increases in indoor temperature.
Because of t he combi nat i on of t hi s proper t y wi t h t he
aforementioned excellent heat refectivity, GALVALUME STEEL SHEET
is suitable for such applications as the heat shields and the heat
refectors for toasters and microwave ovens.
GALVALUME STEEL SHEET has high aluminum content, 55% of
mass and 80% of capacity, and shows better thermal resistance than
ordinary hot-dip galvanized steel sheets. Even when exposed to high
air temperatures, it shows neither signifcant increase of mass due to
oxidization nor any surface discoloration due to progressive alloying.
When used for many hours under temperatures around 350C, it
undergoes little change.
The fgure below shows the change in mass when steel sheets are
continuously heated in the atmosphere. It is evident that GALVALUME
STEEL SHEET undergoes less change due to oxidization than hot-dip
galvanized steel sheet.
Thermal Resistance
Corrosion Resistance
Heat Reectivity
Example of Oxidation Amount due to Continuous Heating
Example of Comparison of Heat Reectivity between GALVALUME
STEEL SHEET and Hot-dip Galvanized Sheet (3 years after construction)
Example of Red Rust Occurrence Time
Al-Si
Base metal
Al-Si
Base metal
ALSHEET
90
80
Heat
reectivity
95
30
Item
Test
condition
Material
( )
Measurement at room temperature after heating
D and S AERP emissivity meter (measurement wave 3 30m)
ALSHEET Hot-dip galvanized sheet Electrogalvanized sheet Cold-rolled sheet
* ( ): Corrosion loss
Cold-rolled sheet set as 100
Type
Corrosion rate (%)
22.9%
50 100
27.5%
30.1%16m*
92.8%80m
100%87m
18%Cr stainless steel
13%Cr stainless steel
ALSHEET 80g/m
2
Cold-rolled shee
Electrogalvanized sheet
20/20g/m
2
Outstanding weather resistance and corrosion resistance
Discoloration and high thermal resistance in high-temperature
application
Excellent high-temperature heat refectivity, compared to hot-
dip galvanized steel sheets
Typical Properties
The surface appearance of ALSHEET at high temperatures is far
superior to that of hot-dip galvanized steel sheet or that of cold-
rolled steel sheet. No surface discoloration occurs at 350C or under.
At temperatures above that, the surface becomes an Al-Fe alloy,
causing a discoloration. However, this conversion to an alloy prevents
oxidization of the base metal, helping to retain the steel sheets thermal
resistance.
An example of surface conditions after heating (300C 200 hours)
When heated at temperatures below 350C, ALSHEET undergoes no surface
discoloration, retaining its beautiful appearance.
Because ALSHEET, like aluminum, easily generates fine yet stable
oxide and hydroxide flms in the atmosphere and in water, its corrosion
resistance under various conditions is superior to that of galvanized
steel sheets. In application, however, it should be borne in mind that,
contrary to galvanized steel sheet, galvanic action (sacrifcial action)
cannot be expected of ALSHEET.
Cyclic wetting and drying tests (Resistance to exhaust gas corrosion)
As a result of corrosion tests using automobile exhaust gas-condensed
simulated fuids, ALSHEET demonstrates better corrosion resistance than do
electrogalvanized steel sheets and cold-rolled steel sheets.
Example of Mufer Test Result (Chrysler's Spec 461H-83)
Because of i ts extremel y beauti ful surface, ALSHEET shows
exceptional heat refectivitynearly 80% at temperatures of 450C or
below. Accordingly, ALSHEET is ideal for use in applications requiring
heat refectivity, including the inner heat shields for toasters and the
upper refectors for gas ovens and kerosene heaters.
Example of Heat Reectivity of Various Materials
Thermal Resistance Corrosion resistance
Heat reectivity
Main Applications
ALSHEET
TM
Hot-dip aluminum-coated steel sheet and strip
TM
Hot-dip 55% aluminum-zinc alloy-coated steel sheet and strip
Building construction and civil
engineering structure
Roong material, wall material, partition,
other structural metal ttings
Electric appliance
Ref ri gerat or, washi ng machi ne, ai r
conditioner, automatic vending machine,
showcase, range, stove, microwave oven
Unlike zinc, aluminum has the property of being resistant to weak
acidity and vulnerable to alkalinity.
Chemical resistance
Hot-water system
Oven toaster
Bread machine
Stove
Fan heater
Cloth dryer
Automobile
(muffler, manifold cover,
converter cover)
100C24Hrs
400C24Hrs
ZINKOTE
electrogalvanized
sheet Spangled
95
20
Non-spangled
95
20
(unit:%)
8 9
Coating structure
Coating structure
20
10
20
10
0
30 50
30 50 72
72
0
Test time (hr) Test time (hr)
QS1
QF1T1N
QM
QS1
QF1T1N
QM
QS1
QS1
QM
QF1
T1N
QM
QF1
T1N
QM
QF1
T1N
QM
QF1
T1N
100 90 80 70 60 50 40 30 20 10
TN
QS1
T1N
Loresta (4 Prove Type}
Constant current source
V
i
Test piece
Concept of Contact Resistance Measurement Device
(Loresta 4 Prove Type}
Examp|e of Contact Resistance Tests Loresta 4 Prove Type
Conducting=Les than 1m
Measurement
device
Measurement
system
Measurement
range
Probe
Assessment
Loresta EP type made
by Mitsubishi Chemical Corp.
4 contact/4 probe method,
constant current application system

10
-2
10
6
ESP probe
Pin tip 2 mm4 contacts, pin interval 5 mm
spring pressure 2.4 N/spring
Conducting rate% 100
Conducting cycle
20 cycles
R
u
s
t
o
c
c
u
r
r
e
n
c
e
a
r
e
a
r
a
t
e
(%
)
R
u
s
t
o
c
c
u
r
r
e
n
c
e
a
r
e
a
r
a
t
e
(%
)
Conducting rate (%)
Pretreatment
Base metal
Sn-Zn alloy layer
Regulation for upper limit
for fuel permeation
Promotion of recycling
Lighter weight
Regulation for environment
burden substance
Increasing use of eco-
friendly fuel
ECOKOTE
TM
-S (Sn-Zn coating)
ALSHEET
TM
(aluminum coating)
TERNESHEET (Pb-Sn coating)
Inferior permeation shut-off
performance
Inferior recyclability
No inclusion of environment
burden substance
Growing concerns about
permeation and deterioration
Use of lead
Concerns about corrosion resistance
in case of using common bio fuel
Outstandingly high
corrosion resistance
No fuel permeation because of steel sheet
High recyclability because of steel sheet
Lighter weight by use of steels rigidity instead of identical capacity
ECOKOTE
TM
-S
(Sn-Zn coating)
ALSHEET
TM
(Aluminum coating)
TERNESHEET
(Pb-Sn coating)
Resin
No inclusion of environment burden substance
Excellent
Excellent
Fair
Excellent
Fair
Excellent
Fair
Fair
Excellent
Fair
Excellent
Fair
Fair
Good
Excellent
Excellent
Excellent
Excellent
Excellent
Fair
Degraded
gasoline
Degraded
20%FAME-
mixed gasoline
Degraded
ethanol-mixed
gasoline
Inner surface corrosion resistance
Outer surface
corrosion
resistance
Press
formability
Weldability Paintability
ZEV regulations (US) Bio fuel
ELV regulations (Europe)
ECOKOTE
TM
-S ECOKOTE
TM
-S
Voluntary regulations
of Japan Automobile
Manufacturers
Association (Japan)
Regulation for upper
limit for fuel permeation
Emerging environmental
needs facing fuel tank
materials
Regulation for
environmental burden
substance
Increasing use of
eco-friendly fuel
Promotion of recycling
Lighter weight
Requirements of fuel tank
materials: total absence of
substances that add to
environmental burden,
resistance to new fuels, no
fuel permeation,
advantageous for recycling,
and light-weight design
Regulation for new
fuel effciency
Automobile
Recycling Law
Higher corrosion resistance than found in conventional fuel
tank metallic materials
High corrosion resistance, even when used with bio fuels
Meets hydrocarbon permeation regulations; is free of
environmental load substances
Highly recyclable
Typical Properties
Responsiveness to Environmental Preservation: ECOKOTE
TM
-S is most suitable for use as an eco-friendly fuel
tank material.
Zn
Base metal
Surface treatment
Corrosion Resistance Mechanism of Chromate-free Coating Film
Application (example)
Flat panel display
Copying machine, printer
Application member
Chassis, various parts
various parts
Main End Products Employing ZINKOTE
ZINKOTE is a chromate-free electrogalvanized
sheet used for fat panel displays, copying
machines, printers and other devices and
equipment.
Salt Spray Test: Flat Surface Section and Formed Section (Erichsen 7 mm Extruded Section)
Effects similar to those offered by special coating
lm containing corrosion-suppression agent
Corrosion Resistance Mechanism of Chromate-free
Coating Film : Chromate-free flm uses substances selected
because they provide the characteristic features of chromate
flm such as its barrier effect, self-restorative function and
paint adhesiveness. Chromate-free coated sheet has been
realized by use of this special coating flm.
When this flm is injured, soluble hexavalent chromium leaches out
to offer a self-restorative function that repairs the flm.
Function of Chromate Coating Film
Barrier effect
Self restoration function
Coating
adhesiveness
Coating flm
Processed/
injured section
Special coating lm
(containing corrosion-suppression agent)
Zinc coating
layer
Steel sheet
Corrosion-
suppression
function
Corrosion factor
H2O O2
Shutting out
of crrosion
factors
High formability and lubricity due to
surface flm action
Excellent conductivity and adhesion
because of thin flm thickness
Organic flm
Inorganic flm
Importance on conductivity
Importance on corrosion resistance
and scratch resistance
Importance on conductivity, paintability
and ironing property
Film Required performance
Example of Corrosion Resistance of Flat Surface Section
(A kind of typical surface treatments is shown)
Example of Corrosion Resistance of Formed Section
Demonstrates similar effects in application as chromate-treated sheet
due to ZINKOTEs special flm containing a corrosion inhibitor
Availability of characteristic properties that conform to respective
customer needs thanks to ZINKOTEs diverse post-treatment lineup
[Main Properties of ZINKOTE]
Corrosion resistance Lubricity Conductivity Spot weldability
Thermal resistance Alkaline resistance Solvent resistance
Fingerprint resistance Paint adhesion
ZINKOTE: Used for high-performance
electric appliances and OA equipment
Typical Properties Main Applications
ZINKOTE
TM
Electrolytic zinc-coated steel sheet and strip
ECOKOTE
TM
-S
Characteristic Properties of Fuel Tank Material
Conductivity (Grounding Property)
Fuel tank
Main Applications
Various Parts
Audio equipment, etc
Side Plate
Refrigerator, washing machine, etc
Chromate-free Coating Film
10 11
100
0
200
300
40 20 60
Coating mass (g/m
2
)
5
%
r
e
d
r
u
s
t
o
c
c
u
r
r
e
n
c
e
t
im
e
(h
o
u
r
s
)
80 100
DURZINKLITE
ZINKOTE
DURGRIP
(galvanized)
Base metal
Zn-Ni alloy
Reference: Time required for the occurrence of red rust in the salt spray test JIS Z 2371
Weldability
In commonly conducted salt spray testing, the bare corrosion resistance of
DURZINKLITE coated surfaces is more than 3 times greater than galvanized
sheets with equal coatings. This product shows favorable corrosion
resistance even with a thin coating mass, but the provision of a special
chromate treatment further improves corrosion resistance.
Individual spot or seam welding of DURZINKLITE can be conducted using
low welding current, and because the welding current range is wide, welding
is easy.
Examples of single spot welding at a range of welding currents for
both-side galvanized sheet are shown at right. In each case, adequate
nuggets are formed using a comparatively low welding current, and the
recommended range of welding currents is wide to allow easy welding.
DURZINKLITE
(20g/m
2
)
ZINKOTE
(20g/m
2
)
DURGRIP(galvannealed)
(45g/m
2
)
Cold-rolled sheet
Type
dn=4t
Welding current (KA)
6 7 8 9
Appropriate welding
current range
Shortage of
nugget diameter
Electrode welding
Example of Welding Current Range for Single Sport Welding of Both-
side Galvanized Sheet
Example of Corrosion Resistance Assessment of DURZINKLITE
(Non-treated Sheet Salt Spray Test)
Conductive flm
Zn (electrogalvanizing)
Base metal
Zn (electrogalvanizing)
Topcoat
Standard type
Improved
scratch-resistant type
Standard type
Improved
scratch-resistant type
Standard type
Standard
both-sided black type
Coating structure
Coating structure
KJ1
KJ2
SJ1
SJ2
HJ1
K1K1
K1KC
KJC
D (general)
D5 (high roughness)
D
D
D
D
D (general)
D5 (high roughness)
D (general)
D5 (high roughness)
D (general)
D5 (high roughness)
Excellent cost performance due to improved
topcoat performance; Preparation of two kinds of
surface roughness depending on appearance
general roughness and high roughness
Improved scratch resistance due to
addition of large-diameter beads to flm
Excellent cost performance due
to improved topcoat performance
Excellent cost performance due to improved
topcoat performance
Excellent cost performance due
to improved topcoat performance
Improved scratch resistance due to
addition of large-diameter beads to flm
Standard black flm (KJ1 flm) on one side, and
conductive heat-absorption black flm on the other
Conductive clear flm (QS flm) on one side, and
conductive heat-absorption black flm on the other
Color Type Heat treatment symbol Surface fnish
Black
Silver
White
Black
Conductive,
heat-absorbing
black
Standard conductive,
heat-absorbing black type
Conductive, heat-absorbing
type with conductive clear flm
Excellent cost performance and reduced manufacturing term at user
plant by coating only one side of ZINKOTE with a beautiful topcoat
Available colors (3): black, silver and white, and preparation of
improved scratch-resistant type
Black coated sheets (2): both-sided black coated type, and high-
conductivity/good heat-absorption type
Outstandingly high corrosion resistance even with conventional
electrolytic galvanizing mass
Fine appearance and fnishing after coating, similar to cold-rolled sheet
Easy spot and seam welding
Product Lineup Typical Properties
Main Applications
Home appliance
OA equipment
Housing equipment (interior, steel furniture)
Bare Corrosion Resistance
DURZINKLITE
TM
Electrolytic zinc-nickel alloy-coated steel sheet and strip
ZINKOTE
TM
COLOR
12 13
Coating structure
Coating structure
Base metal
Ni layer
Fe-Ni alloy layer
Binder
Battery
Portable cooking stove
Toaster
Stove refection plate
External appearances of the top and body parts of size C and AA
batteries made of SUPERNICKEL steel sheets and Ni-coated sheets
without alloy layer, after subjected to 60 minutes of salt spray tests are
shown below.
In both cases, batteries made of SUPERNICKEL steel sheet shows
better post-fabrication corrosion resistance.
SUPERNICKEL steel sheet shows better corrosion resistance than
Ni-coated steel sheet without alloy layer on both unfabricated and
fabricated parts due to reduced pinholes on the coating layer,
formation of an Fe-Ni alloy layer having good adhesion, and
improved ductility due to recrystallization and softening of the Ni
coating layer.
SUPERNICKEL steel sheet has heat resistance comparable to
stainless steel (SUS) that is normally used as a heat-resistant material
(heating temperature ~300C). As typical evaluation results of heat
resistance, changes in glossiness, changes in infrared-ray refectance
and changes in color tone on heating are shown below.
Post-fabrication Corrosion Resistance
Corrosion Resistance of As-coated Flat Sheet Without
Fabrication
SST: Pursuant to JIS Z 2371
Heat Resistance
Surface gloss
Coating Adhesion (workability)
External appearances after SST (coating thickness: 2m)
Ni-coated sheet
without alloy
layer
Comparative example:
Ni-coated sheet without alloy
layer (non-diffusion type)
Top Body
SUPERNICKEL
SUPERNICKEL
Glossiness of surface nish
An example of evaluation of coating adhesion (workability)

Coating
adhesion
(tape peeling)
Work follow
(SEM observation)
Test Methods
Bending test
Erichsen test
Cupping test
Bending test
Erichsen test
Bending test
Erichsen test
Cupping test
1 2 3 4 5
Coating thickness (m)
1000
900
800
700
600
500
400
300
200
100
G
lo
s
s
in
e
s
s
BM nish
BE nish
B nish
Evaluation method
Glossiness:Measured in transverse direction at an incidence angle
of 60 degrees with Nihon Denshoku Model VGS-ID glossmeter.
Base metal
Zn-Sn-Ni alloy layer
Switch metal ftting Flow regulating valve
Condenser case
Heat sink metal
ftting
Electrical equipment
metal ftting
Electrical equipment
metal ftting
Tuner cover
Shield cover
Chromate-free Coating Film
High in whisker resistance, solder wettability and corrosion resistance
Solder Wettability (Solder Wetting Time)
[Test condition]
Test piece:
Plate thickness 0.3 mm,
cup forming
Environment:60C 90%RH
Time:1000hrs
[Test condition]
Test piece:
0.3mm20mm7mm
Kind of solder:
Sn-Ag-Cu
Solder melting temperature
Flux applied:
Rosin alcohol active type
accleleration conditions:
100C (saturated humidity),
8 hrs
Without acceleration
After acceleration
10
8
6
4
2
0
B
a
d
G
o
o
d
8hrs
24hrs
48hrs
100
80
60
40
20
0
O
b
s
e
r
v
e
d
m
a
x
im
u
m
w
h
is
k
e
r le
n
g
th
(
m
)
S
o
ld
e
r
w
e
t
t
in
g
t
im
e
(Z
e
ro
c
ro
s
s
in
g
tim
e
) (s
e
c
)
ECOTRIO
3X/3X
ECOTRIO
8/8
Electrolytic tinplate
2.8g/m
2
ECOTRIO
3X/3X
ECOTRIO
8/8
2.8g/m
2
ECOTRIO
3X/3X
ECOTRIO
8/8
2.8g/m
2
200
160
120
80
40
0
Test Resu|t for Occurrence or No Occurrence of
Whisker under High Temperature and High Humidity Condition
Measurement Resu|ts for So|der Wetting Time
Corrosion Resistance (Sa|t Spray Test}
* The data shown here is an example
of test results, which therefore does
not mean any quality guarantee.
* In cases when the whisker resistance
under strict high-temperature condi-
tions (for example, high temperature
and high humidity surpassing 60C)
is required, the product with impor-
tance on whisker resistance can be
proposed. For details, please send
inquiries.
[Test condition]
Corrosion resistance:
(Salt spray test JIS Z2371)
Test piece:
Flat sheet with edge seal
B
a
d
G
o
o
d
R
a
t
io
o
f r
e
d
r
u
s
t
o
c
c
u
r
r
e
n
c
e
a
r
e
a
(%
)
Lead-free and chromate-free, and conforms to RoHS (Restriction of Hazardous Substances) Directive
Greater suppression of whiskers compared to electrolytic tinplate
Solderability and conductivity that are similar to electrolytic tinplate and higher than those
of galvanized steel sheet
Availability of thin-gauge products with a minimum thickness of 0.15 mm
NEW ECOTRIO even in thin coating mass specications: Taking over the basic properties of ECOTRIO
High-strength ECOTRIO: Cost-cutting substitute for nickel silver and stainless steel sheets
High adhesion and corrosion resistance due to formation of Fe-Ni alloy layer
Availability of material quality that conforms to the particular application and the degree of
fabrication
Diverse surface nishes are available, from an outstandingly ne mirror nish to a rough dull nish.
Availability of coatings from thin to heavy and of differential coatings on front and rear surfaces
Same thermal resistance as that of stainless steel
Cellophane tapes on the inside and outside are peeled after
a 30mm-deep cup is drawn.
A cellophane tape on the coating is peeled after a 7mm-
deep cup is formed.
Typical Properties Typical Properties Main Applications Main Applications
Main Applications
Fabricated
into
size C
batteries
Game console
Automobile AV equipment
TV set
Personal computer
Electric and electronic parts
Audio system
SUPERNICKEL
TM
Nickel Coated Steel Sheet and strip
ECOTRIO
TM
Zn-Si-Ni alloy coated steel sheet and strip
(No peeling found)
(No peeling found)
(No peeling found)
(Virtually no cracks found)
(Virtually no cracks found)
A cellophane tape on the coating is peeled after 0T bend.
(Peeling found)
(No peeling found)
(Peeling found)
(Many cracks found)
(Many cracks found)
14 15
Coating structure
Rear surface coating
Base metal
Primary coating
Surface treatment
Surface treatment
Topcoat
Lighting
equipment
Flat-panel TV
Digital recorder
Auto on-board
equipment
Outdoor
air-conditioner unit
Refrigerator,
washing machine
Automobile parts
Refecting
board
Back panel
Chassis
Chassis
Top, outside

panel
Side panel
Oil flter
Front side
Back side
Front side
Back side
Front side
Back side
Front side
Back side
Front side
Back side
Front side
Back side
Front side
Back side
VIEWKOTE Type
VIEWKOTE Type
VIEWKOTE Type
Electroconductivity Type
VIEWKOTE Type
Electroconductivity type
VIEWKOTE Type
Heat Absorption Type
VIEWKOTE Type
VIEWKOTE Type
VIEWKOTE Type
Rear surface coating
VIEWKOTE Type C
Lubrication Type
Self-Cleaning Type VIEWKOTE
Deep Drawable Metallic VIEWKOTE
Antistatic Type VIEWKOTE
Grainy VIEWKOTE
Orange-Peel-Surfaced VIEWKOTE
Hydrophilic coating vastly improves
resistance against rain drop stains.
Offers high workability thanks to
optimal substrate design.
Also offers excellent weatherability
and stain resistance in processed
areas.
A wide range of color variations,
including metallic tones.
Chromate-free and eco-friendly.
Offers attractive appearances.
Suitable for processing applications
that require bending or drawing.
Add f uncti ons by sel ecti ng the
appropriate back coating.
Prevents static electricity caused by
friction from conveyors and rubber
suction disks in the processing/
production process.
Reduces dust adhesion caused by
static electricity.
Reduces electric shocks caused by
static electricity.
By adding beads with large particle
diameters to the coating,this type of
VIEWKOTE features highly decora-
tive designs,much better than those
of conventional prepainted steel
sheets.
The decorative designs can be
improved further by combining
embossing and/or press forming.
A pebbled surface like that of an orange
peel is achieved by special beads in the
coating. These beads then melt during
heating when the coating is enameled.
This coating improves processing
yield by making handling scratches
less visible.
Its workability, chemical resistance,
and other basic properties are the
same as conventional VIEWKOTE.
(Can also include antistatic property.)
Coating Structure(Example)
Primer coating
Chemical treatment
Galvanized steel sheet
Chemical treatment
Back coating
Self-Cleaning Type
Coating
Primer coating
Chemical treatment
Galvanized steel sheets
Chemical treatment
Back coating
Deep Drawable
Metallic Type
Coating
Antistatic Type
VIEWKOTE
Coating
Primer coating
Chemical treatment
Chemical treatment
Back coating
Primer coating
Chemical treatment
Chemical treatment
Back coating
Grainy
VIEWKOTE
Coating
Orange-Peel-
Surfaced
VIEWKOTE
Coating
Primer coating
Chemical treatment
Chemical treatment
Back coating
How self-cleaning works
Processing Examples of Deep Drawable Metallic Type
Example: Comparison of charged voltage
Example:Appearance after embossing 1mm
Example:Orange-Peel-Surfaced VIEWKOTE
Beige color Brick colored
Hydrophilic coating
The hydrophilic
coating allows drops
of water to penetrate
under stains
The stains are
then washed
away
Stain
Water
Outdoor exposure for
1.5 years at Kimitsu City,
Chiba, Japan (industrial
zone)
Self-
Cleaning
Type
Conventional
VIEWKOTE for
outdoor air-
conditioner
units
Experiment conditions
Measurement of the charged voltage of the coating surface by non-contact type static
electricity measuring apparatus immediately after VIEWKOTE sample (70150mm)
makes contact with a piece of neoprene resin (50100mm) and is then detached.
0
0.1
0.2
0.3
C
h
a
rg
e
d
v
o
lta
g
e
(k
V
)
Antistatic Type VIEWKOTE Conventional VIEWKOTE
82
Zn standards
Indicated thickness
Coating mass
Back coating
Top coating
EGC
0.55mm
20/20
VIEWKOTE
E type
Silver metallic
(VIEWKOTE
Type $ )
High Heat Absorption Type VIEWKOTE
High Reection Type VIEWKOTE
Heat absorption type VIEWKOTE
di scharges heat f rom devi ces/
equipment.
Heat absorption coating inside the
device enclosure facilitates heat
absorpti on and di scharge. The
broad VIEWKOTE menu allows
VI EWKOTE s t eel s heet s ar e
chromate-free and eco-friendly.
Diffuse reectivity of 92-98%.
Can be deep drawn.
Has excel l ent basi c properti es
including corrosion and chemical
resistance.
Both electromagnetic shielding and
temperature control can be achieved
by selecting heat absorption types
with good electroconductivity in the
back coating.
Atmospheric thermometry result of the interior of the
Box (example)
Measurement of diffuse reection factor (example)
Colored top coating
Primer coating
Chemical treatment
Chemical treatment
Heat Absorption
Coating
Primer coating
Chemical treatment
Chemical treatment
Back coating
High Reflection
Coating
T
e
m
p
e
ra
tu
re
(
C
)
Measurement time (min)
80
70
60
50
40
0 20 40 60 80 100 120
ZINKOTE
Heat Absorption
Drop about
10C
Under these experimental conditions, steel
sheets with an endothermic flm can reduce
the atmospheric temperature of the interior
of the Box by about 10C in comparison to
the bare specifcations of ZINKOTE.
80 82 84 86 88 90 92 94 96 98 100
Diffuse Reflectivity (Wavelength 555nm)
General white
PCM
High Reflection
VIEWKOTE
(92% type)
High Reflection
VIEWKOTE
(98% type)
Reflection film
Improved to diffuse reflectivity of 10% or more.
Can be designed with reflectivity of 92 or 98%,
depending on the application.
H
ig
h
R
e
fle
c
t
io
n
T
y
p
e
V
IE
W
K
O
T
E
VIEWKOTE
recommended specifcations
VIEWKOTE
recommended specifcations
Application parts/
materials
Application parts/
materials
Application Application
Smooth and fne painted surface
Selection of colors and material properties that meet specifc needs,
through the combined use of diverse paints and base substrates
Improved such factors as process, space, energy and load savings at user plant
[Paint type of VIEWKOTE]
Type/ Highly workable type Type / Balanced type in workability surface physical properties
Type/ Stain-resistance type Type / Highly workable, stain-resistant type(universal type)
Type/ Highly corrosion-resistant type
Home appliance
Fuel Cell
Housing equipment (door, kitchen, bath)
Typical Properties
Premium Series
VIEWKOTE
TM
Example: To discharge internal heat,
select high heat absorption
type coating.
16 17

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