C H E M I S T R Y

MOLE CONCEPT QUESTION BANK -1

Mole Concept

Q1. A certain compound has the molecular formula X
4
O
6
. If 10.0 g of a compound contains 5.62 gm of X, the atomic mass of X
is
(a) 30.8 amu (b) 37 amu (c) 42 amu (d) 48 amu

Q2. One atomic mass unit is equivalent to
(a) 1.66 x 10
27
g (b) 1.66 x 10
27
kg (c) 1.66 x 10
27
mg (d) 1.66 x 10
27
cg

Q3. One mole of K
4
Fe(CN)
6
produces 17 mol of total species in solution (T/F)

Q4. One mole of potash alum contains a total _______ mol of the independent species

Q5. One mole of K
3
Fe(CN)
6
contains a total _______ mol of the independent species

Q6. The chloride of a metal contains 71% chlorine by weight and the vapour density of it is 50. The atomic weight of the metal
will be
(a) 29 (b) 58 (c) 35.5 (d) 71

Q7. what will be volume of 100 moles of CO
2
in litres at 1000 K and 100 bar pressure ?
(a) 82 lit (b) 83.066 lit (c) 89 lit (d) 8 lit

Q8. what is the sp. Gravity of 96% by moles of ethanol in water ? (Given molar volume of the solution 50 ml)
(a) 0.8878 (b) 0.7788 (c) 1.528 (d) 0.8976

Q9. A mixture of CuO and Cu
2
O contains 88% Cu. What is the percentage of CuO present in the mixture ?
(a) 91.35 % (b) 9.0767 % (c) 18.8 % (d) 20 %

Q10. Out of 1.0 g dioxygen 1.0 g of oxygen and 1.0 g of ozone, the maximum number of the oxygent atoms are contained in
(a) 1.0 g of atomic oxygen (b) 1.0 g of ozone
(c) 1.0 g of oxygen gas (d) all contain same number of atoms

Q11. Mass of H
2
O in 1000 kg CuSO
4
. 5H
2
O is
(a) 360.5 kg (b) 36.05 kg (c) 3605 kg (d) 3.605 kg

Q12. Weight of oxygen in Fe
2
O
3
and FeO in the ratio for the same amount of iron is
(a) 3 : 2 (b) 1 : 2 (c) 2 : 1 (d) 3 : 1

Q13. The hydrated salt Na
2
SO
4
. nH
2
O undergoes 55% loss in weight on heating and becomes anhydrous . The value of n will be
(a) 5 (b) 3 (c) 7 (d) 10

Q14. 18 g of water contains
(a) 1 g atom of hydrogen (b) 2 g atom of hydrogen (c) 3 g atoms of hydrogen (d) none of these

Q15. If 20% of nitrogen is present in compound, its molecular weight will be
(a) 144 (b) 28 (c) 100 (d) 140

Q16. How many gram atoms of S are present in 80.25 g of S ?
(a) 2.5 (b) 32 (c) 5 (d) 80.25 x 32

Q17. 4.4 gm of an unknown gas occupies 2.24 litre of volume of STP . The gas may be
(a) carbon dioxide (b) carbon monoxide (c) oxygen (d) sulphurdioxide

Q18. Which has the highest mass ?
(a) 50 g of iron (b) 5 moles of N
2
(c) 0.1 g atom of Ag (d) 10
23
atoms of carbon

Q19. How many moles of electron weight one kilogram ?
(a) 6.023 x 10
23
(b)
31
1
10
9.108
(c)
54
6.023
10
9.108
(d)
8
1
10
9.108 6.023

POAC

Q20. Calculate the number of g of CO
2
which can be produced by burning 90.0 g of ethane, C
2
H
6
, in excess oxygen
(a) (b) (c) (d)

Q21. What mass of AgCl can be obtained from 100 g of [Ag(NH
3
)
2
]Cl be means of the reaction
( )
3 3 4 3
2
2 2 Ag NH Cl HNO AgCl NH NO ( + +



Q22. CaC
2
is made in an electric furnace by the reaction CaO +3C CaC
2
+CO. How much CaO is to be added to the furnace
charge for each 40 tons of CaC
2
produced ?

Q23. How much 83.4 %pure salt cake (Na
2
SO
4
) could be produced from 250 kg to 94.5 % pure salt in the reaction 2NaCl +H
2
SO
4

Na
2
SO
4
+2HCl ?

Q24. How many kg of H
2
SO
4
can be prepared from 3.00 kg of cuprite, Cu
2
S, if each atom of S in Cu
2
S is converted into 1
molecule of H
2
SO
4
?
2 2 2 3 2
4FeS O Fe O SO + + ;
2 2 3
SO O SO + ;
3 2 2 4
SO H O H SO +

Q25. Polyethylene can be produced from calcium carbide according to the following sequence of reactions :
2 2
; CaC H O CaO HC CH + +
2 2 2
HC CH H H C CH + = ; ( )
2 2 2 2
n
nH C CH CH CH =

Q26. The roasting of 100.0 g of copper ore yeilded 75.4 g of 89.5% pure copper. If the ore is composed of Cu
2
S and CuS with 11.0
% inert impurity, calculate the percent if Cu
2
S in the ore. The equation are Cu
2
S +O
2
2Cu +SO
2
and CuS +O
2
Cu +
SO
2


Q27. What mass of CO would be produced by the reaction of 16.0 g of O
2
with excess carbon according to the equation 2C +O
2

2CO

Q28. Carbon disulfide, CS
2
can be made from byproduct SO
2
. The overall reaction is 5C +2SO
2
CS
2
+4CO. How much CS
2

can be poroduced from 540 kg of waste SO
2
conversion is 82.0 % ?

Q29. How many kg of pure H
2
SO
4
could be obtained from 2.00 kg of pure iron pyrites (FeS
2
) according to the following reaction

Q30. Find the no. of mol of chloride ion needed to react with sufficient silver nitrate to make 10.0 g of AgCl. What mass of CaCl
2

is required to provide this number of mol of Cl
1


Q31. A 1.2048 g smaple of impure Na
2
CO
3
is dissolved and allowed to react with a solution of CaCl
2
. The resulting CaCO
3
, after
precipitation, filteration and drying , was found to weight 1.0362 g. Assuming that the impurities do not contribute to weight
of the precipitate, calculate the percent purity of the Na
2
CO
3


Q32. How much bismuth nitrate. Bi(NO
3
)
3
. 5H
2
O , would be formed from a solution of 15.0 g of bismuth in nitric acid.

Q33. Most commerical hydrochloric acid is prepared by heating NaCl with concentrated H
2
SO
4
. How much sulphuric acid
containing 90.0 % H
2
SO
4
by weight is needed for the production of 2000 kg concentrated hydrochloric acid containing 42.0
% HCl by weight ?

Q34. A 1.00 g total sample of a mixture of CaCO
3
(s) (FW =100) glass beads liberates 0.220 g of CO
2
(MW =44.0) upon
treatement with excess HCl (MW =36.5) Glass does not react with HCl (a) calculate the weight of CaCO
3
in the original
mixture (b) Calculate the weight percent of calcium in the original mixture

Q35. A carbonate. MCO
3
of an unknown metal is treated with HCl to produce CO
2
. Upon treating 1.00 g of MCO
3
with excess
HCl 0.522 gm of CO
2
is produced . Find the weight percnt of calciumin the original mixture

Q36. Four grams of a mixture of calcium carbonate and sand is treated with an excess of hydrochloric acid and 0.880 g of CO
2
is
produced. What is the percent of CaCO
3
in the original mixture ?

Q37. A mixture containing only FeCl
3
and AlCl
3
weights 5.95 g. The chlorides are converted in the hyudrous oxides and ignited to
Fe
2
O
3
and Al
2
O
3
. The oxide mixture weights 2.62 g. Calculate percent Fe and Al in the original mixture

Q38. An impure sample of zinc blende contains 40% zinc; the impurity being silica . If 100 grams of the sample is roasted to
oxidise all the ZnS to ZnO, what will be the weight of the roasted sample ? (At.. Weight of zinc =65.38)
(a) 78.3 grams (b) 87.3 grams (c) 83.7 grams (d) 90.2 grams

Q39. The plastics induxtry uses large amunts of phthalic anhydride, C
8
H
4
O
3
, made by the controlled oxidation of napthalene
10 8 2 8 4 3 2
2 9 2 4 C H O C H O H O + + . Since come of the napthalene is oxidised to other products, only 70.0 % of the
maximum yeild predicted by the equation is actually obtained. How many phthalic anhydride would be produced in practice
by the oxidation of 200 gm of C
10
H
8
?

Q40. A mixture of NaHCO
3
and Na
2
CO
3
weighed 1.0235g. The dissolved mixture was reacted with excess Ba(OH)
2
to form
2.1028 g BaCO
3
, by the reaction ( )
2 3 3
2
2 Na CO Ba OH BaCO NaOH + + ;
( )
3 3 2
2
NaHCO Ba OH BaCO NaOH H O + + + What was the percentage NaHCO
3
in the original mixture ?