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Institute / School of Engineering Program Name Course Code Course Name Lecture / Tutorial (per week) Course Coordinator

Name

School of Applied Sciences BE CHL4101 Engg Chemistry 3-1-0 3.5 s. !"r#n" "nch"nd"

Course Credits

! Scope and "#$ecti%es of the Course 1. !his co#rse $ill introd#ce to st#dents% engineering m"teri"ls #sed in d"ily life s#ch "s pl"stics% composites% cer"mic% l#&ric"nts% polymers% their prep"r"tion% properties "nd "pplic"tions. '. !his co#rse $ill pl"ce emph"sis on those "re"s considered most rele("nt in "n engineering conte)t s#ch "s $"ter "nd its tre"tment for ("rio#s p#rposes "nd corrosion "nd control of met"llic m"teri"ls. 3. !his co#rse $ill "lso te"ch elements of electrochemic"l processing "nd its "pplic"tions to electro refining% electropl"ting "nd electrochemic"l po$er so#rces *&"tteries "nd f#el cells+. 4. !his co#rse $ill pro(ide engineering st#dents $ith " &"c,gro#nd in green chemistry import"nce for en(ironment friendly chemic"l design "nd m"n#f"ct#ring. &! Te't#ooks T( ) *Engineering Chemistry- &y B. Si("s"n,"r% '00.% !"t" T(&) *Engineering Chemistry- &y 0. /.1"l"nn"% '002% !"t" +eference (ooks +( ) 31hysic"l Chemistry- &y 1eter At,in "nd 4#lio de 1"#l"% 5 th edition% 0)ford 6ni(ersity 1ress. +(&7 31hysic"l Chemistry- &y /il&ert 8. C"stell"n 3rd edition% 9"ros" 1#&lishing Ho#se. c/r"$- Hill p#&lishing ho#se. c/r"$- Hill p#&lishing ho#se.

,! +ele%ant we#sites

S!No! 1 . ' 3

Link of -ournals. /aga0ines. we#sites and +esearch Papers http7::$$$.sigm""ldrich.com:chemistry:greener-"ltern"ti(es:greenchemistry.html http7::oc$.mit.ed#:co#rses:chemistry:5-111-principles-of-chemic"l-sciencef"ll-'00.:re"dings-"nd-lect#re-notes:lecnotes'5.pdf http7::oc$.mit.ed#:co#rses:m"teri"ls-science-"nd-engineering:3-021scintrod#ction-to-solid-st"te-chemistry-f"ll-'010:33-#n"ry-ph"sedi"gr"ms: ;!3<021SC=02<lec33.pdf http7::oc$.mit.ed#:co#rses:m"teri"ls-science-"nd-engineering:3-021scintrod#ction-to-solid-st"te-chemistry-f"ll-'010:34-&in"ry-ph"se-di"gr"ms-

Salient 1eatures /reen Chemistry Electrochemis try 6n"ry 1h"se >i"gr"ms Bin"ry 1h"se

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complete-sol#&ility: ;!3<021SC=02<lec34.pdf 5 http7::$$$.chemistry.$#stl.ed#:?ed#de(:L"&!#tori"ls:8"ter:=resh8"ter:h"r dness.html

>i"gr"ms 8"ter H"rdness

2!Course plan Lecture Topics Num#er Te't (ook/ +eference (ook / "ther reading material !B' !B' !B1 Page num#ers of Te't (ook(s) '52-'@' '@4-'50 511-513

1. ' 3

4-5 @ 5-.

2 10 11

;ntrod#ction% So#rces of $"ter% ;mp#rities in $"ter H"rd "nd soft $"ter% 6nits of h"rdness *9#meric"ls incl#ded+ Specific"tion for &oiler feed $"ter Boiler pro&lems) Sc"le "nd sl#dge form"tion% c"#stic em&rittlement% priming% forming% &oiler corrosion d#e to o)ygen "nd c"r&on dio)ide% E)tern"l tre"tment7 Lime Asod" process *9#meric"ls incl#ded+% Beolite process ;on e)ch"nge process% ;ntern"l tre"tment *different types of conditioning+ Specific"tion of $"ter for domestic #se% !re"tment for domestic #se*&re", point chlorin"tion+C !re"tment of &r"c,ish $"ter* re(erse osmosis% electrodi"lysis #sing ion selecti(e mem&r"ne+ ;ntrod#ction% C"#ses of corrosion% effects of corrosion% !ypes "nd mech"nism of corrosion% >irect chemic"l *dry+corrosion. Electrochemic"l *$et+corrosion% Comp"rison of Chemic"l "nd electrochemic"l corrosion !ypes of electrochemic"l corrosion% 0ther forms of corrosion *6ndergro#nd or soil corrosion% icro&i"l corrosion% Erosion% ;ntergr"n#l"r %Cre(ice% "tmospheric corrosion+ 1"ssi(ity of corrosion% ="ctors infl#encing corrosion% 9"t#re of the met"l% 9"t#re of corroding en(ironment 1re(ention of corrosion% 6se of protecti(e me"s#rements7 C"thodic protection ;ntrod#ction% /i&&s ph"se r#le% Applic"tion of ph"se r#le in one component system% 8"ter system% C"r&on dio)ide system% S#lf#r system Condensed ph"se r#le% !$o component system% E#tectic mi)t#re% Le"d sil(er system !$o component system7 1ot"ssi#m iodide -$"ter system% =erric chloride $"ter system

!B' !B1 !B1 Lin,5 !B1 !B'

'24-'2. 505-50. '22-30' 514%500505%'21'23 114-115 4@5-4@. 11@-11. 4@2 11.-1'5

!B' !B1 !B' !B1 !B'

1' 13 14-15 1@-15 1.

!B' !B' !B' Lin,3 !B' !B1 DB' !B1 DB1 Lin,4

1'.-130 131-14' 453-45@ 45.-4.0 30-31 3'4 4.'-4.@ 13.%'04

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12-'0

SESSIONAL TEST-1(11th-15th Feb,2013) ;ntrod#ction - Electrolysis% Electrochemic"l !B1 cell.Electrode potenti"l% St"nd"rd electrode DB1 potenti"l% C"lc#l"tion of cell E =. =#el cell*hydrogen-o)ygen "l,"line f#el cell% molten c"r&on"te f#el cell +%Sol"r cell*photo(olt"ic cell% $or,ing of sol"r cell $ith p-n E#nction only+ 1rim"ry cell *dry cell A Bn n0' +% second"ry cell*le"d "cid &"ttery % 9i ACd cell+% Lithi#m cells: &"tteries*prim"ry lithi#m &"tteries7 Sol#&le c"thode cells% Solid c"thode cells% Solid electrolyte cells %second"ry lithi#m &"tteries7 liF#id org"nic electrolyte cells% lithi#m ion cells+ Del"tionship &et$een emf "nd thermodyn"mic properties*GH% GS% G/+ "nd rel"ted n#meric"ls B"sic process of electropl"ting "nd Electroless pl"ting $ith reference to copper% "nd their comp"rison. 1rep"r"tion of printed circ#it &o"rd *1CB+ &y electroless pl"ting% Electrochemic"l Etching !B' !B1 Lin, ' !B'

'1

.5..%110% 101-103 '50 103-105% '@-'2 13@-141 .@-2'%2@10'

''-'3

!B1 !B1 DB1 !B1 !B' 1'2-134 105%'53 '.0 1'@-1'5 15@155%1.01.'%1.51.. 1551@0%1@3121-12' 40'-404

'4 '5

'@

!B1 !B'

'5 '.-'2 30 31-3' 33-34

35 3@

35-3. 32

;ntrod#ction to Engineering "teri"ls% Cementing !B1 "nd Binding m"teri"ls% Lime "nd gyps#m Cement7 m"n#f"ct#ring of 1ortl"nd cement% setting !B1 405-402 "nd h"rdening of cement% $e"thering of cement "nd concrete% Admi)t#res for concrete ;ntrod#ction to Cer"mics% cl"y7 $hite$"re "nd stone !B1 402-41' $"re prod#cts Composites7 constit#tions% cl"ssific"tion7 p"rticle !B1 4'1-4'5 reinforced% fi&er reinforced% str#ct#r"l composite L#&ric"nts7 properties of liF#id l#&ric"nts* clo#d "nd !B1 43@-440 po#r point% fl"sh "nd fire point% ne#tr"liH"tion n#m&er% s"ponific"tion n#m&er% "niline point% Acid I"l#e+ !ypes of polymeriH"tion* "ddition "nd condens"tion !B1 ''1 polymeriH"tion+%thermopl"stics "nd thermosetting polymer !hermosetting resin7 n"t#r"l resins% 1IC% 1!=E% !B1 '32- '44 1olyc"r&on"te% phenolic resin SESSI"N3L TEST4&(& st /arch4,5th /arch. &5 ,) ;ntrod#ction% 1rinciples of green chemistry% /reen !B1 551 chemistry in ;ndi" *e)"mples of icro$"(e Lin,1 55'%553 "ssisted synthesis+ !r"dition"l "nd "ltern"ti(e synthesis of ;&#profen% !B1 554 !r"dition"l "nd "ltern"ti(e feedstoc, in the synthesis of "dipic "cid SESSI"N3L TEST4,(&&th4&6th 3pril.&5 ,)

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6! E%aluation Scheme) Component 1 Component 'K Component 3KK J#iH:!#tori"l sheet test:1resent"tion:S#rprise test:Assignment test Session"l !ests *S!s+K End !erm E)"min"tionKK Total 7 !here "re three Session"l !ests *S!s+ for "ll theory p"pers% the first t$o "re comp#lsory "nd the third one is the non-m"nd"tory m",e #p : mercy test. !he "(er"ge of &est t$o is considered. 77 !he End !erm Comprehensi(e e)"min"tion $ill &e held "t the end of semester. !he m"nd"tory reF#irement of 55L "ttend"nce in "ll theory cl"sses is to &e met for &eing eligi&le to "ppe"r in this component 8! 9etails of e%aluation component 9uratio n 15 min /ark s '0 To #e held in week 4th $ee, +emarks !his $ill &e " center"liHed process "nd $ill &e cond#cted online : test sheet *h"rd copy+ of CJs. J#estions $ill &e "n"lytic"l. =or 1resent"tion7 /ro#p consisting of 4 st#dents $ill gi(e " present"tion on ho$ the concepts of chemistry c"n &e "pplied in d"ily life "nd ind#stry% the topic for e"ch gro#p $ill &e decided &y cons#lting the te"cher. =or S#rprise !est:Assignment !est7 0ne concept#"l F#estion "nd one pro&lem &"sed F#estion '0 '0 @0 55

9escription J#iH

!#tori"l Sheet !est 1resent"tion:S#rpri se !est:Assignment test

30 min 10 min

'0 '0

.th 8ee, 5th $ee, on$"rds : 14th $ee,

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