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37th IChO Practical Examination Answer Sheets

Experiment 1. The Synthesis of D !"Phenyl#lycine an$ Its Optical %esol&tion Total Scores: 100 points
1-1 Total Points %ecei+e$ () 1-2 1) 1-3 () 1-4 ) 1-5 3* ' 1**

Experiment (. I$entification of ,n-nown Inor#anic Samples Total Scores: 100 points

2-1 Total Points %ecei+e$ ./ 2-2 0 ' 1**

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Experiment 1 The Synthesis of D !"Phenyl#lycine an$ Its Enantiomeric %esol&tion

Total Scores1 1** points 1-1 Total Points %ecei+e$ () 1-2 1) 1-3 () 1-4 ) 1-5 3* ' 1**

Step 1. Preparation of 2D !3"phenyl#lycine

1-1

Confirmed and signed by lab assistant g g g/ g/

Weight of benzoylformic acid used: Weight of fritted glass funnel: After complete dryness: Product weight + fritted glass funnel:

g/

[Weigh on a balance that reads to the nearest centigram ( ! "g#$! Weight of %&'(phenylglycine obtained: Chemical yield: ) g

Calculate the chemical yield () yield* show the calculations#!

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1-2 +urn in the sample (in the ,ial with blue label#! -ignature of student: -ignature of the lab assistant: [+he organization committee will weigh an appropriate amount of sample ( ! "g# for ". /01 spectroscopic analysis!$ Step (. Enantiomeric resol&tion of D !"phenyl#lycine 4y 253"camphors&lfonic aci$ 6253"CSA7 1-3 Confirmed and signed by lab assistant g g/

Weight of %&'(phenylglycine used:

Weight of fritted glass funnel:

g/

After complete dryness: Product weight + fritted glass funnel: g g/ [Weigh on a balance that reads to the nearest centigram ( ! "g#$! Weight of the resol,ed phenylglycine (+#(C-A salt: Chemical yield: ) g

Calculate the chemical yield () yield* show the calculations#!

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1-4 %raw the correct absolute stereochemical structure of the isolated phenylglycine!

1-5 -pecific rotation of the enantiomeric phenylglycine (+# C-A salt (to be determined by the organization committee# +urn in the sample (in the ,ial with pin2 label#! -ignature of student:

-ignature of the lab assistant: [+he organization committee will weigh an appropriate amount of sample ( ! 33 4 ! 53g# for measurement of optical purity!$

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Experiment ( I$entification of ,n-nown Inor#anic Samples

Total Scores: 100 points
2-1 Total Points %ecei+e$ 2-1 6n2nown Compound .Cl /a9. /a8C9> /a8-9> Code /umber77 & & & & 6n2nown Compound .8-9: ;aCl8 ?nCl8 .898 Code /umber77 & & & & 6n2nown Compound /.:-C/ <:=e(C/#5 Code /umber77 & & ./ 2-2 0 ' 1**

77-econd column is for duplicates! 2-2 A! Write the electrolysis e@uation that would help you confirm that an un2nown sample is ?nCl8!

;! Write one e@uation that shows how to clean the deposit of ?n on the electrode (limited to the items pro,ided in this tas2#!