Vidyamandir Classes

VMC/Hydrocarbons 21 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : HDC [1]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. 2-chloro-3-methylbutane is treated with sodium in ethereal solution, then it will give
(A) 2, 4-dimethylhexane (B) 3, 5-dimethylhexane
(C) 2, 3, 5, 5-tetramethylhexane (D) 2, 6-dimethyloctane
2. Wet ether is not used as a solvent in Wurtz reaction, because the water present in it.
(A) hydrolyses RX to ROH (B) reduces RX to RH
(C) destroy the Na metal (D) reacts with R R
3. A mixture of 1-chlorobutane and 2-chlorobutane when treated with alcoholic KOH gives.
(A) 1-butene (B) 2-butene (C) iso-butylene (D) mixture of 1-butene + 2-butene
4. The major product formed when a 3, 3-dimethyl butan-2-ol is heated with concentrated sulphiric acid, is :
(A) 2, 3-dimethyl-2-butene (B) 2, 3-dimethyl-1-butene
(C) 3, 3-dimethyl-1-butene (D) cis and trans isomers of 2, 3-dimethy-1-butene
5. Aqueous solution of an organic compound, A on electrolysis liberates acetylene and CO
2
at anode. A is
(A) potassium acetate (B) potassium succinate (C) potassium citrate (D) potassium maleate
6. Pure methane can be produced by
(A) Wurtz reaction (B) Kolbes electrolytic method
(C) soda lime decarboxylation (D) reduction with H
2
7. What would be the product formed when 1-bromo-3-chlorocyclobutane reacts with two equivalents of metallic sodium in ether?
(A) (B) (C) (D)
8. Acetylene can be obtained by the reaction
(A)
Electrolysis
HCOOK (B)
3
CHI Ag
A
+
(C)
2 4
Conc. H SO
3 2
443 K
CH CH OH (D)
2 2
Be C H O +
9. Ozonolyis of an organic compounds gives formaldehyde as one of the products. This confirms the presence of
(A) two ethylenic double bonds (B) a vinyl group
(C) an iso-propyl group (D) an acetylenic triple bond
10. Ozonolysis of an organic compound A produces acetone and propionaldehyde in equimolar mixture. Identify A from the following
compounds.
(A) 2-methyl-1-pentene (B) 1-pentene (C) 2-pentene (D) 2-methyl-2-pentene
Vidyamandir Classes
VMC/Hydrocarbons 22 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : HDC [2]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Identify B and D in the following sequence of reactions.
(A) Methanol and bromoethane (B) Ethyl hydrogen sulphate and alcoholic KOH
(C) Ethyl hydrogen sulphate and aqueous KOH (D) Ethanol and alcoholic KOH
2. One mole of a symmetrical alkene on ozonolysis gives two moles of an aldehyde having a molecular mass of 44 u. The alkene is:
(A) propene (B) 1-butene (C) 2-butene (D) ethene
3. Which of the following is the predominant product in the reaction of HOBr with propene?
(A) 2-bromo-1-propanol (B) 3-bromo-1-propanol
(C) 2-bromo-2-propanol (D) 1-bromo-2-propanol
4. In the series,
3 2 4
2 4 2
CH I NaNH HgSO
2 2
H SO , H O
C H X Y Z
the compound Z is :
(A) CH
3
CH
2
CH = CH
2
(B) CH
3
COCH
3
(C) CH
3
CHO (D) CH
3
CH
2
CH
2
CHO
5. In the following sequence of reactions, the alkene affords the compound B
3 2
O H O
3 3
Zn
CH CH CHCH A B =
The compound B is :
(A) CH
3
CH
2
CHO (B) CH
3
COCH
3
(C) CH
3
CH
2
COCH
3
(D) CH
3
CHO
6. The treatment of CH
3
Mg X with
3
CH C C H produces :
(A)
3 2
CH CH CH = (B)
3 3
CH C C CH (C)
3 3
H H
| |
CH C C CH =
(D) CH
4
7. In the reactions,
2 3
2
Lindlar catalyst / H Na / NH
H
B RC CR A
A and B are geometrical isomers. Then,
(A) A is cis and B is trans (B) A is trans and B is cis
(C) A and B are cis (D) A and B are trans
Vidyamandir Classes
VMC/Hydrocarbons 23 HWT/Chemistry
8. Which one of the following gives, on ozonolysis, both aldehydes and ketones?
(A) Me
2
C = CHMe (B) Me
2
C = CMe
2
(C) , )
2 2
MeCH C Me CMe = (D) , ) MeCH Me CH CHMe =
9. An alkene on vigorous oxidation with KMnO
4
gives only acetic acid. The alkene is :
(A) CH
3
CH
2
CH = CH
2
(B) CH
3
CH = CHCH
3
(C) (CH
3
)
2
C = CH
2
(D) CH
3
CH = CH
2
10. Which of the following reactions will yield, 2, 2-dibromopropane?
(A)
3
CH C CH 2HBr + (B)
3
CH CH CHBr HBr +
(C) CH CH 2HBr + (D)
3 2
CH CH CH HBr = +
Vidyamandir Classes
VMC/Hydrocarbons 24 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : HDC [3]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Ozonolysis products of an olefin are
2
2
CHO CH CHO
| and |
CHO CH CHO
Olefin is :
(A) (B) (C) (D)
2. Propene on reaction with hypochlorous acid to give :
(A) (B) (C) (D)
3. 2-methylbutane on reacting with bromine in the presence of sunlight gives mainly :
(A) 1-bromo 3-methylbutane (B) 2-bromo 3-methylbutane
(C) 2-bromo 2-methylbutane (D) 1-bromo 2-methylbutane
4. A is :
(A) meso diol (B) racemic diol (C) Both (A) and (B) (D) None of these
5. The non-aromatic compound among the following is :
(A) (B) (C) (D)
6. Which one of these is not true of benzene?
(A) It forms only one type of monosubstituted product
(B) There are three carbon-carbon single bonds and three carbon-carbon double bonds
(C) The heat of hydrogenation of benzene is less than the theoretical value
(D) The bond angle between the carbon-carbon bonds is120

.
7. Which of the following species is aromatic?
(A) (B) (C) (D)
Vidyamandir Classes
VMC/Hydrocarbons 25 HWT/Chemistry
8. According to Huckels rule an aromatic compound must possess :
(A) (4n 1) electrons + t (B) (4n 2) electrons + t
(C) 4n electrons t (D) (4n 3) electrons + t
9. Identify the substitute group, that acts as ortho-para director, during electrophilic substitution in aromatic compounds.
(A)
2
NH (B)
2
NO (C)
3
SO H (D) N
2
10. Phenyl magnesium bromide reacts with methanol to give :
(A) a mixture of anisol and Mg(OH)Br (B) a mixture of benzene and Mg(OMe)Br
(C) a mixture of toluene and Mg(OH)Br (D) a mixture of phenol and Mg(Me)Br
Vidyamandir Classes
VMC/Hydrocarbons 26 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : HDC [4]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Both methane and ethane may be obtained by a suitable one-step reaction from :
(A) CH
3
I (B) C
2
H
5
I (C) CH
3
OH (D) C
2
H
5
OH
2. Which of the following liberates methane on treatment with water?
(A) Silicon carbide (B) Calcium carbide (C) Beryllium carbide (D) Magnesium carbide
3. Which of the following will give three mono-bromo derivatives?
(A) CH
3
CH
2
CH
2
CH(CH
3
)CH
3
(B) CH
3
CH
2
C(CH
3
)
2
CH
3
(C) CH
3
CH(CH
3
)CH(CH
3
)CH
3
(D) All the above can give
4. On halogenation, an alkane (C
5
H
12
) gives only one monohalogenated product. The alkane is :
(A) n-pentane (B) 2-methyl butane (C) 2, 2-dimethyl propane (D) cyclopentane
5. Which of the following reactions can be used to prepare methane?
(A) Clemmensen reduction (B) Wurtz reaction
(C) Reduction of CH
2
= CH
2
by LiAlH
4
(D) Reduction of methyl iodide by using a zinc-copper couple
6. Hydrocarbon which is liquid at room temperature is :
(A) Pentane (B) Butane (C) Propane (D) Ethane
7. On mixing a certain alkane with chlorine and irradiating it with UV light, it form one monchloro alkane. The alkane could be :
(A) neopentane (B) propane (C) pentane (D) isopentane
8. Position of double bond in alkenes is identified by :
(A) ozonolysis (B) bromine water
(C) ammoniacal silver nitrate (D) None of these
9. Alkenes undergo :
(A) addition reactions (B) substitution reactions
(C) Both (A) and (B) (D) None of these
10. Cyclopentadienyl anion is :
(A) aromatic (B) non-aromatic (C) non-planar (D) aliphatic
Vidyamandir Classes
VMC/Hydrocarbons 27 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : HDC [5]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. What are the produces obtained upon the ozonolysis of pent-2-ene?
(A) CH
3
CH
2
CHO (B) CH
3
CHO (C) CH
3
COCH
3
(D) Both (A) and (B)
2. Alkene is :
(A) (B)
(C) (D)
3. on-ozonolysis gives :
(A) (B) (C) (D) None of these
4. Which one of the following has the smallest heat of hydrogenation per mole?
(A) 1-butene (B) Trans-but-2-ene (C) Cis-but-2-ene (D) Buta-1, 3-diene
5. Which of the following compounds is the most stable?
(A) (B) (C) (D)
6. Which of the following reactions are not expected to give :
3
3 2
3
CH
|
CH C CH CH
|
CH
=
in yields of more than 50% ?
(A)
2 4
3
H SO
3 3
3
CH
|
CH C CH CH
| |
CH OH
A

(B)
, )
3
3
3
CH CO K
3 3
3
CH
|
CH C CH CH
| |
CH Br
+
A

(C)
3
Zn
3 3
acetone
3
CH
|
CH C CH CH
| |
CH Br

(D) None of the above
Vidyamandir Classes
VMC/Hydrocarbons 28 HWT/Chemistry
7. The reduction of 4-octyne with H
2
in the presence of Pd/CaCO
3
quinoline gives :
(A) trans-4-octene (B) cis-4-octene
(C) a mixture of cis-and trans-4-octene (D) A completely reduced product C
8
H
18
8. Which of the following reactions will give an alkyne?
(A)
Zn / alc.
3 2 2
CH CBr CHBr (B)
alc. KOH
3 2 2
CH CH CHBr
(C)
2
NaNH
3 2 2
CH CHBr CH Br (D) All of the above
9. The product(s) obtained via oxymercuration (HgSO
4
+ H
2
SO
4
) of but-1-yne would be :
(A) CH
3
CH
2
COCH
3
(B) CH
3
CH
2
CH
2
CHO
(C) CH
3
CH
2
CHO + HCHO (D) CH
3
CH
2
COOH + HCOOH
10. The final product in following sequence of reaction is :
2 3
NaNH CH Br
CH CH A B =
(A)
2 2
CH CH CH CH = = (B)
3
HC C CH =
(C)
2 3
CH CH CH = (D)
3 2 2
CH CH CH
Vidyamandir Classes
VMC/Hydrocarbons 29 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : HDC [6]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Which of the following form alkynide?
(A) (B)
(C) (D)
2.
2
Hg / H
3
Ph C C CH A,
+ +

(A) (B) (C) (D)
3. Alkyne, C
7
H
12
, when reacted with alkanline KMnO
4
followed by acidification with HCl gives a mixture of
(CH
3
)
2
CHCOOH + CH
3
CH
2
COOH
The alkyne C
7
H
12
is :
(A) 3-hexyne (B) 2-methyl-2-hexene
(C) 2-methyl-3-hexene (D) 3-methyl-2-hexyne
4. Which of the following statement is correct?
(A) Benzene has a tetrahedral geometry like an alkane
(B) Benzene is aromatic while naphthalene is not
(C) Benzene is and cyclohexane are both aromatic
(D) Benzene behaves more like and alkane than an alkene
5. Which among the following is aromatic?
(A) (B) (C) (D)
6. Which of the following species will be aromatic?
(A) (B) (C) (D) None of these
Vidyamandir Classes
VMC/Hydrocarbons 30 HWT/Chemistry
7. Which of the following is expected to be aromatic?
(A) (B) (C) (D)
8. C
4
H
6
may contain :
(A) one double bond (B) two double bond (C) one triple bond (D) Both (B) and (C)
9. Compound (A) on oxidation with OsO
4
/NaIO
4
gives Hexanedial. Structure of compound. (A) will be :
(A) (B) (C) (D)
10. Cyclobutadiene is said to be :
(A) aromatic (B) aliphatic (C) non-aromatic (D) None of these
Vidyamandir Classes
VMC/Hydrocarbons 31 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : HDC [7]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct. However, questions marked with * may have More than One
correct option.
1. Acetylene reacts with hypochlorous acid to form :
(A) Cl
2
CH CHO (B) ClCH
2
COOH (C) CH
3
COCl (D) ClCH
2
CHO
2.
2
(I) X
3 3 3 3
(II) H O/ Zn
CH C C CH CH C C CH
|| ||
O O

In the above reaction, X is :
(A) HNO
3
(B) O
2
(C) O
3
(D) KMnO
4
3. In the reaction
Oxidation NaOH Soda lime
6 5 3
C H CH A B C .
Identify C is :
(A) C
6
H
5
OH (B) C
6
H
6
(C) C
6
H
5
COONa (D) C
6
H
5
ONa
4. Gem dihalides on treatment with alcoholic KOH give :
(A) alkyne (B) alkene (C) alkane (D) All of these
5.
3 4
2 4
2 2
(I) BH (THF) HgSO
3
H SO
(II) H O , OH
A CH C CH B

Identify A and B.
(A) CH
3
CHO, CH
3
COCH
3
(B) CH
3
CH
2
CHO, CH
3
COCH
3
(C) CH
3
CH
2
CHO, CH
3
COCH
2
CH
3
(D) HCHO, CH
3
COCH
3
6. Degree of unsaturation in the following compound is :
(A) 1

(B) 2

(C) 3

(D) 4

7. , ) , )
2 3 2
H , Ni O / H O/ Zn
4 6 4 8 3
1mole
A C H B C H CH CHO .
Thus, A and B are :
(A) (B)
(C)
2 2 3 3
CH CH C CH, CH CH CHCH = (D)
2 2 3 3
CH CH CH CH , CH CH CH CH = = =
Vidyamandir Classes
VMC/Hydrocarbons 32 HWT/Chemistry
8. , )
3 2
O / Zn, H O
3
2
CHO
A CH CO HCHO |
CHO
+ + +
Thus, A is.
(A) (CH
3
)
2
CHCH = CHCH = CH
3
(B) (CH
3
)
2
C = CH CH = CH
2
(C)
3 2
CH CH CH CH CH CH CH = = = (D) None of the above
*9. The reagent/s required for the conversion
1 2 1 2
R CH CHR R COOH HOOCR = + is(are) :
(A) O
3
followed by treatment with H
2
O (B) Bayers reagents
(C) Hot KMnO
4
/KOH followed by acidification (D) Lemieux reagent
10. Ethylidene dichloride is obtained by the reaction of excess of HCl with :
(A) ethylene (B) acetylene (C) propene (D) methane
Vidyamandir Classes
VMC/Hydrocarbons 33 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : HDC [8]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The hydrocarbon which can react with sodium in liquid ammonia is :
(A)
3 2 2 2 2 2 3
CH CH CH CH C CCH CH CH (B)
3 2
CH CH C CH
(C) CH
3
CH = CHCH
3
(D)
3 2 2 2
CH CH C CCH CH
2. A compound (X) on ozonolysis followed by reduction gives an aldehyde C
2
H
4
O and 2-butanone, compound (X) is :
(A) 3-methyl pentene-2 (B) 3-methyl pentene-3 (C) 3-methyl hexane-3 (D) 3-ethyl pentene-3
3. How many t bonds are present in naphthalene?
(A) 4 (B) 5 (C) 6 (D) 7
4. An organic compound with molecular formula C
6
H
12
upon ozonolysis give only acetone as the product. The compound is :
(A) 2, 3-dimethyl-1-butene (B) 3-hexane
(C) 2-hexene (D) 2, 3-dimethyl-2-butene
(E) 3-methyl-1-pentene
5. The compound formed as a result of oxidation of ethyl benzene by KMnO
4
is :
(A) benzophenone (B) acetophenone (C) benzoic acid (D) benzyl alcohol
6. Which of the following reactions will yield, 2, 2-dibromopropane?
(A)
3
CH C CH 2HBr + (B)
3
CH CH CHBr HBr = +
(C) CH CH 2HBr + (D)
3 2
CH CH CH HBr = +
7. An alkene on reductive ozonolysis gives 2-molecules of cH
2
(CHO)
2
. The alkene is :
(A) 2, 4-hexadiene (B) 1, 3-cychlohexadiene
(C) 1, 4-cyclohexadiene (D) 1-methyl-1, 3-cyclopentadiene
8. Of the five isomeric hexanes, the isomer which can give two monochlorinated compound is :
(A) 2-methylpentane (B) 2, 2-dimethylbutane
(C) 2, 3-dimethylbutane (D) n-hexane
9. An alkene having the molecular formula C
9
H
18
on ozonolysis gives 2, 2-dimethyl propanal and 2-butanone. The alkene is :
(A) 2, 2, 2-trimethyl-3-hexene (B) 2, 2, 6-trimethyl-3-hexane
(C) 2, 3, 4-trimethyl-2-hexene (D) 2, 2, 4-trimethyl-3-hexene
(E) 2, 2-dimethyl 1-3 heptene
10. Acid catalyzed hydration of alkenes except ethane lead to the formation of :
(A) mixture of secondary and tertiary alcohols (B) mixture of primary and secondary alcohols
(C) secondary or tertiary alcohol (D) primary alcohol
Vidyamandir Classes
VMC/Hydrocarbons 34 HWT/Chemistry
DATE : IITJEE :
MARKS :
| |
|
\ .
10
TIME : 25 MINUTES
NAME : TEST CODE : HDC [9]
ROLL NO. START TIME : END TIME : TIME TAKEN:
STUDENTS SIGNATURE : PARENTS SIGNATURE :
This test contains a total of 10 Objective Type Questions.
Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The number of di-substituted products of benzene is :
(A) 2 (B) 3 (C) 4 (D) 5
2. The reaction of toluene with chlorine in presence of ferric chloride gives predominantly :
(A) benzoyl chloride (B) m-chlorotoluene (C) benzyl chloride (D) o-and p-chlorotoluene
3. The treatment of benzene with benzoyl chloride in the presence of AlCl
3
gives :
(A) benzaldehyde (B) benzophenone (C) diphenyl (D) cyclohexane
4. Toluene can be converted into benzaldehyde by oxidation with :
(A) KMnO
4
/alkali (B) CrO
2
Cl
2
(C) K
2
Cr
2
O
7
/H
2
SO
4
(D) O
2
/V
2
O
5
5. , A is :
(A) (B) (C) (D)
6. Predict structure of X in following reaction is :
(A) (B) (C) (D)
7.
Identify A and B.
(A)
(B)
(C)
(D)
Vidyamandir Classes
VMC/Hydrocarbons 35 HWT/Chemistry
8. Friedel-Crafts acylation can be given by
, X is :
(A) R C Cl
||
O
(B) R C R
||
O
(C) R C H
||
O
(D) R O R
9. Following compound is treated with NBS
Compound formed A is :
(A) (B)
(C) (D)
10. Propyne on passing through red hot copper tube forms :
(A) benzene (B) toluene (C) mesitylene (D) None of these