Vidyamandir Classes

VMC/ Oxygen Containing Organic Compounds - II 11 HWT-7/Chemistry

DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : ALD K [1]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. Which of the following gives an aldehyde on dry distillation?
(A) Calcium formate + calcium acetate (B) Calcium acetate + calcium benzoate
(C) Calcium acetate (D) Calcium benzoate
2. Which set of products is expected on reductive ozonolysis of the following diolefin?
3
3 2
CH
|
CH CH C CH CH = =
(A) CH
3
CHO ; CH
3
COCH = CH
2
(B) CH
3
CH = C(CH
3
)CHO ; CH
2
O
(C) CH
3
CHO ; CH
3
COCHO ; CH
2
O (D) CH
3
CHO ; CH
3
COCH
3
; CH
2
O
3. The compound which is not formed during the dry distillation of a mixture of calcium formate and calcium acetate is :
(A) Methanal (B) Propanal (C) Propanone (D) Ethanal
4.
Identify the reactant :
(A) H
2
O (B) HCHO (C) CO (D) CH
3
CHO
5.
(A) (B) (C) (D)
6. When a mixture of calcium benzoate and calcium acetate is dry distilled, the resulting major compound is :
(A) acetophenone (B) benzaldehyde (C) benzophenone (D) acetaldehyde
7. 3-pentanol on reaction with aluminum tertiary butoxide in the presence of acetone gives :
(A) 3-pentanal (B) 2-petntanal (C) 3-pentanone (D) 2-pentanone
8. A is :
(A) (B) (C) (D)
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - II 12 HWT-7/Chemistry
9. Calcium fomate on distillation gives.
(A) HCOOH (B) CH
3
COOH (C) CH
3
CHO (D) HCHO
10. The best reagent to convert pent-3-en-2-ol into pent-3-en-2-one is :
(A) pyridinium chloro-chromate (B) chromatic anhydride in glacial acetic acid
(C) acidic dichromate (D) acidic permanganate
11. By combining the two calcium salts of carboxylic acids, we are preparing 2-butanone. Find the correct pair of the following
(A) calcium formate + calcium propanoate (B) calcium acetate + calcium propanoate
(C) calcium acetate + calcium acetate (D) calcium formate + calcium acetate
12. Aldehyde which is formed during photosynthesis of plants is :
(A) Methanal (B) Acetaldehyde (C) Propanal (D) Phenylmethanl
13.
2
Hg / H
3
Ph C C CH A, A
+ +
is :
(A) (B) (C) (D)
14. An organic compound X gives a red precipitate on heating with Fehlings solution. Which one of the following reactions yields X
as a major product?
(A)
3
2
(i) CH MgI
(ii) H O
HCHO (B)
2 5
C H Br AgOH
A
+
(C)
2 5 2
2C H Br Ag O
A
+ (D)
2 4
4
60 C
40% H SO
2 2 2
1% HgSO
C H H O +

15. Trichloroacetaldehyde are was subjectd to Cannizaros reaction by using NaOH. The mixture of the products contains sodium
trichloroacetate ion and another compound. The other compound is :
(A) 2, 2, 2-trichloropropanol (B) trichloromethanol
(C) 2, 2, 2-trichloropropanol (D) chloroform
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - II 13 HWT-7/Chemistry
DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : ALD K [2]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. The compound obtained when acetaldehyde reacts with dilute aqueous sodium hydroxide exhibits :
(A) geometrical isomerism (B) optical isomerism
(C) neither optical nor geometrical isomerism (D) both optical and geometrical isomerism
2. Benzaldehyde and acetone can be best distinguished using.
(A) Fehlings solution (B) sodium hydroxide solution
(C) 2, 4-DNP (D) Tollens reagent
3.
3
Dil. NaOH HCN
3
Heat
H O
CH CHO HCHO A B
+
+ . The structure of compound B is :
(A)
2
CH CH CH COOH
|
OH
=
(B)
2
CH CH CH OH
|
CN
=
(C)
3 2
CH CH CH COOH
|
OH

(D)
3
CH CH COOH
|
OH

4. The most reactive compound towards formation of cyanohydrin on treatment with HCN followed by acidification is :
(A) benzaldehyde (B) p-nitrobenzaldehyde
(C) phenylacetaldehyde (D) p-hydroxybenzaldehyde
5. Identify the reaction which is used to obtain hydroxy | carbonyl compounds.
(A) Condensation reaction (B) Aldol condensation (C) Cross aldol condensation (D) Cannizaro reaction
6. An aromatic compound X with molecular formula C
9
H
10
O gives the following chemical tests.
I. Forms 2, 4-DNP derivative II. Reduces Tollens reagent
III. Undergoes Cannizaro reaction and
IV. On vigorous oxidation 1, 2-benzenedicarboxylic acid is obtained X is :
(A) (B) (C) (D)
7. Which of the following compounds would be the main product of an aldol condensation of acetaldehyde and acetone?
(A)
3
CH CH CHCHO = (B)
3 3
CH CH CHCOCH = (C)
3 2
(CH ) C CHCHO = (D) (CH
3
)
2
C = CHCOCH
3
8. Which factor/s will increase the reactivity of > C = O group?
I. Presence of a group with positive inductive effect.
II. Presence of a group with negative inductive effect.
III. Presence of large alkyl group.
(A) Only I (B) Only II (C) I and III (D) II and III
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - II 14 HWT-7/Chemistry
9. An organic compound X is oxidised by using acidified K
2
Cr
2
O
7
. The product obtained reacts with phenyl hydrazine but does not
answer silver mirror test. The possible structure of X is :
(A) CH
3
CH
2
OH (B)
3 3
CH C CH
||
O

(C) (CH
3
)
2
CHOH (D) CH
3
CHO
10.
4
LiAlH Cu Dilute
3
NaOH
3000 C
CH COOH X Y Z

. In the above reaction Z is :

(A) butanol (B) aldol (C) ketol (D) acetal
11. What is the oxidation number of carbonyl carbon in acetophenone?
(A) +3 (B) +1 (C) +2 (D) Zero
12. An organic compound of molecular formula C
3
H
6
O did not give a silver mirror with Tollens reagent, but gave an oxime with
hydroxylamine, it may be :
(A)
3 3
CH CO CH (B) C
2
H
5
CHO (C)
2 2
CH CH CH OH = (D)
3 2
CH O CH CH =
13. In the following reaction sequence, the correct structures of E, F and G are :
(A) (B)
(C) (D)
14. A compound X undergoes reduction with LiAlH
4
to yield Y. When vapours of Y are passed over freshly reduced copper at
300 C

, X is formed. What is Y?
(A) CH
3
COCH
3
(B) CH
3
CHO (C) CH
3
CH
2
OH (D) CH
3
OCH
3
15. Acetone on addition to methyl magnesium bromide forms a complex, which on decomposition with acid gives X and Mg(OH)Br.
Which one of the following is X?
(A) CH
3
OH (B) (CH
3
)
3
COH (C) (CH
3
)
2
CHOH (D) CH
3
CH
2
OH
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - II 15 HWT-7/Chemistry
DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : ALD K [3]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. p-cresol reacts with chloroform in alkaline medium to give the compound A which adds hydrogen cyanide to form the compound
B. The latter on acidic hydrolysis gives chiral carboxylic acid. The structure of the carboxylic acid is :
(A) (B) (C) (D)
2.
(A) (B) (C) (D)
3. Claisen condensation is not given by :
(A) (B)
(C) (D)
4. Which reaction intermediate is formed during the condensation reaction between acetaldehyde and formaldehyde?
(A)
2
: CH CHO (B)
2
CH CHO
+
(C)
2
CH OH
+
(D) : CHCHO
5.
(A) (B)
(C) (D)
6. is :
(A) an ester (B) an anhydride (C) acetal (D) hemiacetal
7. The Cannizaro reaction is not given by :
(A) trimethyl acetaldehyde (B) acetaldehyde
(C) benzaldehyde (D) formaldehyde
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - II 16 HWT-7/Chemistry
8. The increasing order of the rate of HCN addition to compound A D is :
(a) HCHO (b) CH
3
COCH
3
(c) PhCOCH
3
(d) PhCOPh
(A) a < b < c < d (B) d < b < c < a (C) d < c < b < a (D) c < d < b < a
9. When acetaldehyde is heated with Fehling solution, a red precipitate is formed. Which of the following is that?
(A) Cu
2
O (B) Cu (C) CuO (D) CuSO
4
10. Match the following Column 1 and Column 2.
Column 1 Column 2
(A) Grignard reagent 1. H
2
/Pd-BaSO
4
(B) Clemmensen reduction 2.
2 4 2
2
N H | KOH| CH OH
|
CH OH

(C) Rosenumund reduction 3. CH

3
MgX
(D) Wolff-Kishner reduction 4. Zn Hg|conc. HCl
5. H
2
|Ni
Codes :
A B C D A B C D
(A) 3 4 2 1 (B) 3 4 1 2
(B) 2 1 4 5 (D) 5 3 2 1
11. Compound (A) (molecular formula C
3
H
6
O). B in forms a shining silver mirror on warming with ammonical silver nitrate. A
when treated with an aqueous solution of H
2
NCONHNH
2
in HCl and sodium acetate gives a product B. Identify the structure of
B.
(A) CH
3
CH
2
CH = NNHCONH
2
(B) (CH
3
)
2
C = NNHCONH
2
(C) (CH
3
)
2
C = NCONHNH
2
(D) CH
3
CH
2
CH = NCONHNH
2
12. The end products in the Cannizaro reaction of benzaldehyde on acidification are:
(A) PhCO
2
H, PhCH
2
OH (B) PhCO
2
H, PhCH
2
CO
2
H
(C) PhCH
2
OH, PhCOCH
3
(D) PhCO
2
H, PhCOCH
3
13. How will you convert butan-2-one to propanoic acid?
(A) Tollens reagent (B) Fehling solution
(C) NaOH/I
2
/H
+
(D) NaOH/NaI/H
+
14.
the compound (X) is :
(A)
3
CH COOH (B)
2
BrCH COOH (C)
3 2
(CH CO) O (D) CHO COOH
15. Which of the following does not undergo Cannizaros reaction?
(A) Benzaldehyde (B) 2-methylpropanal
(C) p-methoxybenzaldehyde (D) 2, 2-dimethylpropanal
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - II 17 HWT-7/Chemistry
DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : ALD K [4]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. In the reaction sequence,
3 2 3
CH CH MgBr H O
5 12
A B C H O

compound A is :
(A) 1-propanol (B) propanal (C) ethanal (D) 2-propanol
2. 3-hydroxybutanal is formed when (X) reacts with (Y) in dilute (Z) solution. What are X, Y and Z?
X Y Z
(A) CH
3
CHO, (CH
3
)
2
CO, NaOH
(B) CH
3
CHO, CH
3
CHO, NaCl
(C) (CH
3
)
2
CO, (CH
3
)
2
CO, HCl
(D) CH
3
CHO, CH
3
CHO, NaOH
3. The order or reactivity of phenyl magnesium bromide with the following compound is :
(A) (II) > (III) > (I) (B) (I) > (III) > (II) (C) (II) > (I) > (III) (D) all are equally reactive
4. Acetaldehyde cannot show :
(A) Iodoform test (B) Lucas test (C) Benedicts test (D) Tollens test
5. Which of the following cannot reduce Fehling solution?
(A) HCOOH (B) H
3
CCOOH (C) HCHO (D) H
3
CCHO
6. Which gives lactic acid on hydrolysis after reacting with HCN?
(A) HCNO (B) CH
3
CHO (C) C
6
H
5
CHO (D) CH
3
COCH
3
7. In the reaction,
3
HCHO NH X, X + is :
(A) meta-formaldehyde (B) para-formaldehyde
(C) urotropine (D) None of these
8. Which of the following give an explosive RDX, on nitration?
(A) Toluene (B) Benzene (C) Guanidine (D) Urotropine
9. When benzaldehyde reacts with acetophenone in presence of sodium hydroxide, then product on heating is :
(A) C
6
H
5
CH = CHCOC
6
H
5
(B) C
6
H
5
COCH
2
C
6
H
5
(C) C
6
H
5
CH = CHC
6
H
5
(D) C
6
H
5
CH(OH)COC
6
H
5
10. The number of aldol reaction(s) that occurs in the given transformation is :
(A) 1 (B) 2 (C) 3 (D) 4
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - II 18 HWT-7/Chemistry
11. The compound that undergoes decarboxylation most readily under mild condition is :
(A) (B) (C) (D)
12. Iodoform can be prepared from all except :
(A) ethyl methyl ketone (B) iso-propyl alcohol
(C) 3-methyl-2-butanone (D) iso-butyl alcohol
13. In the given transformation, which of the following is the most appropriate reagent ?
(A)
2 2
NH , NH , OH

(B) Zn Hg / HCl
(C) Na, Liq. NH
3
(D) NaBH
4
14. Upon treatment with Al(OEt)
3
followed by usual reactions (work up) CH
3
CHO will produce :
(A) Only CH
3
COOCH
2
CH
3
(B) A mixture of CH
3
COOH and EtOH
(C) Only CH
3
COOH (D) Only EtOH
15. An organic compound A burns with a soaty flame. It is negative towards Tollens reagent test and positive for Bradys reagent
test. The compound A is : (Bradys reagent : 2, 4-DNP hydrazine)
(A) Acetophenone (B) Acetone (C) Salicyclic acid (D) Benzaldehyde
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - II 19 HWT-7/Chemistry
DATE : TIME : 25 Minutes MARKS : [ ___ /15] TEST CODE : ALD K [5]
START TIME : END TIME : TIME TAKEN: PARENTS SIGNATURE :
This test contains a total of 15 Objective Type Questions. Each question carries 1 mark. There is NO NEGATIVE marking.
Choose the correct alternative. Only one choice is correct.
1. In the reaction sequence,
3 2 3
CH CH MgBr H O
5 12
A B C H O

compound A is :
(A) 1-propanol (B) propanal (C) ethanal (D) 2-propanol
2. 3-hydroxybutanal is formed when (X) reacts with (Y) in dilute (Z) solution. What are X, Y and Z?
X Y Z
(A) CH
3
CHO, (CH
3
)
2
CO, NaOH
(B) CH
3
CHO, CH
3
CHO, NaCl
(C) (CH
3
)
2
CO, (CH
3
)
2
CO, HCl
(D) CH
3
CHO, CH
3
CHO, NaOH
3. The order or reactivity of phenyl magnesium bromide with the following compound is :
(A) (II) > (III) > (I) (B) (I) > (III) > (II) (C) (II) > (I) > (III) (D) all are equally reactive
4. Acetaldehyde cannot show :
(A) Iodoform test (B) Lucas test (C) Benedicts test (D) Tollens test
5. Which of the following cannot reduce Fehling solution?
(A) HCOOH (B) H
3
CCOOH (C) HCHO (D) H
3
CCHO
6. Which gives lactic acid on hydrolysis after reacting with HCN?
(A) HCNO (B) CH
3
CHO (C) C
6
H
5
CHO (D) CH
3
COCH
3
7. In the reaction,
3
HCHO NH X, X + is :
(A) meta-formaldehyde (B) para-formaldehyde
(C) urotropine (D) None of these
8. Which of the following give an explosive RDX, on nitration?
(A) Toluene (B) Benzene (C) Guanidine (D) Urotropine
9. When benzaldehyde reacts with acetophenone in presence of sodium hydroxide, then product on heating is :
(A) C
6
H
5
CH = CHCOC
6
H
5
(B) C
6
H
5
COCH
2
C
6
H
5
(C) C
6
H
5
CH = CHC
6
H
5
(D) C
6
H
5
CH(OH)COC
6
H
5
10. The number of aldol reaction(s) that occurs in the given transformation is :
(A) 1 (B) 2 (C) 3 (D) 4
Vidyamandir Classes
VMC/ Oxygen Containing Organic Compounds - II 20 HWT-7/Chemistry
11. The compound that undergoes decarboxylation most readily under mild condition is :
(A) (B) (C) (D)
12. Iodoform can be prepared from all except :
(A) ethyl methyl ketone (B) iso-propyl alcohol
(C) 3-methyl-2-butanone (D) iso-butyl alcohol
13. In the given transformation, which of the following is the most appropriate reagent ?
(A)
2 2
NH , NH , OH

(B) Zn Hg / HCl
(C) Na, Liq. NH
3
(D) NaBH
4
14. Upon treatment with Al(OEt)
3
followed by usual reactions (work up) CH
3
CHO will produce :
(A) only CH
3
COOCH
2
CH
3
(B) a mixture of CH
3
COOH and EtOH
(C) only CH
3
COOH (D) only EtOH
15. An organic compound A burns with a soaty flame. It is negative towards Tollens reagent test and positive for Bradys reagent
test. The compound A is : (Bradys reagent : 2, 4-DNP hydrazine)
(A) Acetophenone (B) Acetone (C) Salicyclic acid (D) Benzaldehyde