Hydrogen Age Hydrogen Age 2 CONTENTS CONTENTS 1.!ntroduction to Hydrogen 1.!ntroduction to Hydrogen 2. Fuel Cells 2. Fuel Cells a) a) Principle Principle b) b) Types Of Fuel Cell Types Of Fuel Cell c) c) Automotive Application Automotive Application 3. Hydrogen in !C Engines 3. Hydrogen in !C Engines a) a) Properties Properties b) b) Safety Safety c) c) Performance of H!CE Performance of H!CE +. Conclusions +. Conclusions - - ." ."! believe that water will one day be ! believe that water will one day be employed as fuel, that hydrogen and oxygen employed as fuel, that hydrogen and oxygen which constitute it, used singly or together will which constitute it, used singly or together will furnish an inexhaustible source of heat and furnish an inexhaustible source of heat and light of an intensity of which coal is not light of an intensity of which coal is not capable..water will be coal of the future" capable..water will be coal of the future" Hydrogen Cleanest of the Clean Hydrogen Cleanest of the Clean Fuels Fuels 3 Why Hydrogen Why Hydrogen - - Potentially an inexhaustible supply of energy Potentially an inexhaustible supply of energy can be produced from many available can be produced from many available primary energy sources on petroleum primary energy sources on petroleum imports produced from coal or renewable. imports produced from coal or renewable. 4 Sources of Hydrogen Sources of Hydrogen Generation Generation 5 Hydrogen AvailabilityfProduction Hydrogen AvailabilityfProduction - - Hydrogen is most plentiful element in universe but does not Hydrogen is most plentiful element in universe but does not occur as a pure gas on the earth. occur as a pure gas on the earth. - - Nearly all H2 production is based on fossil fuels at present. Nearly all H2 production is based on fossil fuels at present. - - Hydrogen can also be produced from renewable sources such Hydrogen can also be produced from renewable sources such as bio as bio- -mass, windfsolar energy. mass, windfsolar energy. HYDROGEN GENERATION HYDROGEN GENERATION From Conventional Sources{Fossil Fuels) From Conventional Sources{Fossil Fuels) Natural gas, Oil, Coal Natural gas, Oil, Coal - - Steam reforming of Natural gas Steam reforming of Natural gas - - Partial Oxidation Partial Oxidation - - Thermal cracking of Natural Gas Thermal cracking of Natural Gas - - Coal Coal gasification From Renewable Sources From Renewable Sources - - Bio mass Bio mass- -Gasification Gasification - - Electrolysis Electrolysis- -Electricity from renewable sources like Electricity from renewable sources like solar,wind,hydle solar,wind,hydle etc. etc. - - In India possibilities of producing hydrogen in sugar In India possibilities of producing hydrogen in sugar mills from Bagasse mills from Bagasse cogen cogen power power- -electrolytic plant exist. electrolytic plant exist. - - Chloro Chloro- -alkali units also have surplus hydrogen. alkali units also have surplus hydrogen. 6 7 ELECTROLYSIS ELECTROLYSIS Electrodes in conductive water Electrodes in conductive water {with an electrolyte) produce {with an electrolyte) produce H2 at the H2 at the - - & O at the + & O at the + - - ADVANTAGES: ADVANTAGES: - - Produces almost pure H2 {electricity through water) Produces almost pure H2 {electricity through water) - - Could be powered with cool Could be powered with cool renewables renewables - - Hydrogen is abundant Hydrogen is abundant - - No moving parts; servicing rarely necessary No moving parts; servicing rarely necessary - - DISADVANTAGES: DISADVANTAGES: - - Currently not cost competitive Currently not cost competitive - - Fossil fuel Fossil fuel- -powered electrolysis powered electrolysis - - Amount of energy needed to divide H2O = amount Amount of energy needed to divide H2O = amount given off when H2 burns given off when H2 burns Solar Solar - - Powered Powered Electrolysis Electrolysis - -Honda doing this in Torrance, Honda doing this in Torrance, California California - -HYSOLAR: began making H2 HYSOLAR: began making H2 in 1994 in 1994 - -Solar Solar- -Wasserstoff Wasserstoff- -Bayern Bayern in in Bavaria Bavaria - -CAN project CAN project 8 Nuclear Nuclear- -powered powered Electrolysis Electrolysis - - It's a feasible alternative It's a feasible alternative - - Anti Anti- -nuclear sentiment nuclear sentiment may prevent nuclear H2 may prevent nuclear H2 production production - - NRDC opposed; spent fuel NRDC opposed; spent fuel Making H2 from Natural Making H2 from Natural Gas Gas - - Stripping H2 from natural gas is Stripping H2 from natural gas is called 'reforming' called 'reforming' - - Reforming natural gas emits CO2 Reforming natural gas emits CO2 - - Outfitting a gas station with a Outfitting a gas station with a machine to reform natural gas machine to reform natural gas would cost $400,000 {building a would cost $400,000 {building a conventional gas station costs conventional gas station costs $1,500,000) $1,500,000) 9 10 Getting H2 from Coal Getting H2 from Coal - - Coal Coal- -fired fired utilities can utilities can power power electrolysis electrolysis 11 H2 Production from Bacteria H2 Production from Bacteria - - Some anaerobic bacteria can Some anaerobic bacteria can produce H2 at 20 times their produce H2 at 20 times their volume per minute volume per minute - - When starved of sulfur, When starved of sulfur, Chlamydomonas Chlamydomonas Reinhardtii Reinhardtii makes H2, one of ten most makes H2, one of ten most important discoveries in 2000 important discoveries in 2000 {popular science magazine) {popular science magazine) 12 HYDROGEN STORAGE HYDROGEN STORAGE HYDROGEN STORAGE HYDROGEN STORAGE ALTERNATIVES ALTERNATIVES - - Storage as gas under pressure{250 Storage as gas under pressure{250- -350 bar) 350 bar) - - Cryogenic storage as liquid hydrogen{20K) Cryogenic storage as liquid hydrogen{20K) - - Storage as metallic hydrides Storage as metallic hydrides - - Carbon adsorption& carbon Carbon adsorption& carbon microsphere microsphere under under development. development. 13 14 15 HYDROGEN FUEL CELLS HYDROGEN FUEL CELLS 16 Hydrogen Fuel Cell Hydrogen Fuel Cell - - Converts hydrogen and Converts hydrogen and oxygen into water and oxygen into water and an electric current. an electric current. - - Benefits Benefits - - +0 +0- -50 efficient 50 efficient - - Reduction in noise Reduction in noise - - No emission of greenhouse No emission of greenhouse gases gases - - Reduced dependence on Reduced dependence on fossil fuels fossil fuels 17 18 19 Hydrogen Fuel Cell (cont.) Hydrogen Fuel Cell (cont.) - - Hurdles to overcome Hurdles to overcome - - Storage tank size Storage tank size - - Operation in cold weather Operation in cold weather - - Consumer cost Consumer cost - - Scarcity of fuel stations Scarcity of fuel stations - - Safety Safety - - Environmental problems Environmental problems 20 Storage Tank Size Storage Tank Size - - Low density of hydrogen means a larger Low density of hydrogen means a larger tank size to achieve driving range similar tank size to achieve driving range similar to petrol. to petrol. - - Reduction of trunk space Reduction of trunk space Operation in cold weather Operation in cold weather - - Fuel cells contain water for Fuel cells contain water for - - Humidifying the cell Humidifying the cell - - As byproduct of reaction As byproduct of reaction - - Fuel cells need to reach a critical Fuel cells need to reach a critical temperature for full performance temperature for full performance 21 Consumer Cost Consumer Cost - - Narket price of fuel cell vehicles must be Narket price of fuel cell vehicles must be comparable to that of petrol comparable to that of petrol - - Price of the fuel must also be comparable Price of the fuel must also be comparable Scarcity of fuel stations Scarcity of fuel stations - - Refueling stations must exist before Refueling stations must exist before consumers will by the vehicles consumers will by the vehicles - - Neetings between the nations top car Neetings between the nations top car manufacturers, fuel distributors, and manufacturers, fuel distributors, and airlines are currently underway airlines are currently underway 22 Safety Safety - - Public must be Public must be educated in the use educated in the use of hydrogen as a fuel of hydrogen as a fuel - - Preliminary Preliminary experiments: experiments: - - Leak simulation (Dr. Leak simulation (Dr. Swain) Swain) - - Results Results - - Petrol car is destroyed Petrol car is destroyed - - Hydrogen car never Hydrogen car never reached above 67 reached above 67 F F Hydrogen Leaks Hydrogen Leaks - - Cal Tech estimates 10 Cal Tech estimates 10- -20 hydrogen leak from 20 hydrogen leak from cars and refueling stations. cars and refueling stations. - - Results Results - - Cooling of upper stratosphere Cooling of upper stratosphere - - Disturbing of ozone chemistry Disturbing of ozone chemistry - - President of !nternational Association of President of !nternational Association of Hydrogen for energy believes percentage of Hydrogen for energy believes percentage of leaked gas would be leaked gas would be much less than they are much less than they are considering. considering." " 23 FUEL CELL vEH!CLES FUEL CELL vEH!CLES FUEL CELL vEH!CLE FUEL CELL vEH!CLE CONF!GURAT!ON CONF!GURAT!ON FUEL FUEL CELL BATTER!ES POWER COND!T!ONER ACCESSOR!ES WHEELS ACfDC DR!vE NOTOR WHEELS 24 Hydrogen Car Nodels Hydrogen Car Nodels - - GN GN Hy Hy- -Wire Wire - - BNW 750hL BNW 750hL - - Toyota FCHv Toyota FCHv - - Toyota F!NE Toyota F!NE- -S S GN GN Hy Hy- -Wire Wire - - Features Features - - Hydrogen fuel cell Hydrogen fuel cell - - Drive Drive- -By By- -Wire technology Wire technology - - Ability to switch the X Ability to switch the X- - drive from the left side to drive from the left side to the right the right 25 GN GN Hy Hy- -Wire (cont.) Wire (cont.) - - Technical Technical Specifications Specifications - - Notor Nax Power: 60 Notor Nax Power: 60 kW kW - - Notor Nax Torque: Notor Nax Torque: 215 Nm 215 Nm - - Nax RPN: 12000 Nax RPN: 12000 - - Nax Torque: 186+ Nm Nax Torque: 186+ Nm BNW 750hL BNW 750hL - - !nteresting Features !nteresting Features - - Capable of running Capable of running petrol or hydrogen petrol or hydrogen - - Capable of running Capable of running the air conditioner the air conditioner even when engine even when engine is off is off 26 BNW 750hL (cont.) BNW 750hL (cont.) - - Technical Specifications Technical Specifications - - 0 to 100 kmfh in 9.6 seconds 0 to 100 kmfh in 9.6 seconds - - Naximum speed of 226 kmfh Naximum speed of 226 kmfh - - Range of 350 km Range of 350 km - - Safety Tests Safety Tests - - Destruction of tanks under high pressure Destruction of tanks under high pressure - - Fire tests where tank was consumed in excess of Fire tests where tank was consumed in excess of 1000 1000 C C - - Tank deformation tests Tank deformation tests - - Side collision tests Side collision tests Toyota FCHv Toyota FCHv Permanent Permanent Nagnet Nagnet Notor Type Notor Type PEN PEN Fuel Cell Stack Fuel Cell Stack Type Type Over 250 km Over 250 km Cruising Distance Cruising Distance 90 kW 90 kW Output Output 5 5 Seating Capacity Seating Capacity Over 150 kmfh Over 150 kmfh Nax Speed Nax Speed 27 Toyota F!NE Toyota F!NE- -S S - - Concept Car Concept Car - - Seats up to + Seats up to + - - Futuristic look Futuristic look - - Featured at the 2003 Detroit Auto Show Featured at the 2003 Detroit Auto Show Hydrogen InternaI Hydrogen InternaI Combustion Combustion Engines Engines ("HICEs") ("HICEs") 28 Why HICE,s Why HICE,s - - HICEs are a viable alternative for bridging HICEs are a viable alternative for bridging the gap to the H2 fuel cell economy the gap to the H2 fuel cell economy - - HICEs may be a viable long HICEs may be a viable long- -term term possibility as the ICE has undergone 100 possibility as the ICE has undergone 100 years of refinement years of refinement - - To lessen greenhouse gases and foreign To lessen greenhouse gases and foreign oil dependence, the government should oil dependence, the government should encourage the transition to the H2 encourage the transition to the H2 economy with large investments in R&D, economy with large investments in R&D, subsidies and tax incentives, subsidies and tax incentives, Foreign Oil Dependence Foreign Oil Dependence 29 EARLY HISTORY OF H2 EARLY HISTORY OF H2 - - 1S00 1S00: Electrolysis : Electrolysis - - 1S20 1S20: Reverend W. : Reverend W. Cecil proposes Cecil proposes HICE HICE - - 1S74 1S74: Jules Verne : Jules Verne - - 1S60 1S60- -70's 70's: N.A. Otto : N.A. Otto uses uses ICEs ICEs and mixed H and mixed H fuel fuel - - 1930 1930- -40's 40's: Rudolf : Rudolf Erren Erren develops HICEs develops HICEs - - 1950 1950: Francis T. Bacon : Francis T. Bacon 30 BIGGEST SETBACK BIGGEST SETBACK Military Research into H Vehicles Military Research into H Vehicles - - 1943: Air Force investigates LH2 fuel 1943: Air Force investigates LH2 fuel - - 1956: Lockheed 1956: Lockheed - - 1960's: 'Nuclear Powered Energy Depot' 1960's: 'Nuclear Powered Energy Depot' A B-57B airplane that flew with one engine fueled by liquid hydrogen 31 The Modern Era of HICEs The Modern Era of HICEs - - 1972 1972: Urban Vehicle Design : Urban Vehicle Design Competition Competition - - UCLA Gremlin wins UCLA Gremlin wins - - 1972 1972- -3 3: International H2indenburg : International H2indenburg society society - - 19S0's 19S0's: H : H- -fueled airplanes {NASA fueled airplanes {NASA continues to study continues to study FC airplanes) FC airplanes) MODERN H2 VEHICLES MODERN H2 VEHICLES - - 1993 1993: Ballard FC bus developed : Ballard FC bus developed - - 1995+ 1995+ - - CTA FC buses CTA FC buses - - Royal DutchJ Shell Royal DutchJ Shell - - FC prototype cars FC prototype cars - - BMW HICE vehicles BMW HICE vehicles - - H refueling stations H refueling stations open open Ballard phase 3 FC buses, in Vancouver and Chicago 32 Companies making HICE prototypes Companies making HICE prototypes - - Daimler Daimler- -Benz: Benz: hydride HICEs, hydride HICEs, 19S4 19S4- -S S - - GM GM has created a has created a HICE prototypes HICE prototypes - - Mazda, Cadillac: Mazda, Cadillac: HICEs and HICEs and hydride HICEs hydride HICEs Mazda hydride HR-X prototype Cadillac prototype HICE Ford & BMW HICEs Ford & BMW HICEs - - BMW: BMW: 1999 fifth 1999 fifth generation generation prototype, LH2 prototype, LH2 commercially commercially available available Ford: 1999 announced P2 HICE (H2, LH2) 33 How HICEs Work How HICEs Work - - 2H2+02= 2H20 + heat 2H2+02= 2H20 + heat - - H behaves like octane H behaves like octane - - Compressed H2 takes Compressed H2 takes up more room than up more room than gas gas - - Unlike gasoline, which Unlike gasoline, which needs strict air needs strict air- -fuel fuel ratio ratio - - More explosive than More explosive than gas, timing critical gas, timing critical - - Injected fuel delivery Injected fuel delivery BMW HICE bus engine BMW Hydrogen 7 Series IC Engine NODE OF OPERAT!ON !N !.C. NODE OF OPERAT!ON !N !.C. ENG!NES ENG!NES Neat Hydrogen Hydrogen Supplementation {Petrol+ Hydrogen) Hydrogen+CNG Dual Fuelling {Diesel +Hydrogen) H2 34 Hydrogen Storage Hydrogen Storage STORAGE OF HYDROGEN ONBOARD STORAGE OF HYDROGEN ONBOARD - - Netal hydrides Netal hydrides- - special alloys incorporate special alloys incorporate hydrogen atom in their crystalline structure hydrogen atom in their crystalline structure - - Hydrogen is released when heat is applied to Hydrogen is released when heat is applied to alloys alloys - - A tank with 120kg metal hydride could store A tank with 120kg metal hydride could store 6kg of H 6kg of H2 2 which can have vehicle range of about which can have vehicle range of about +80 km in a car. +80 km in a car. - - 3 wheeler can given 3 wheeler can given upto upto 150km with 500gm 150km with 500gm hydrogen. hydrogen. 35 H Onboard Storage Issues H Onboard Storage Issues - - Hydride Hydride - - gas compression, gas compression, - - cryogenic cooling cryogenic cooling - - No consensus No consensus Infrastructure cost vs. Infrastructure cost vs. onboard extraction onboard extraction Metal Hydride Hydride Storage Hydride Storage 1960`s R&D in the U.S. & Netherlands Metal alloys, absorb H2 at higher temp./ pressures Heat released when H2 absorbed, same heat required to release H2 D-B used radiator heat to de-bond H2 36 Hydride Viability Hydride Viability Advantages: Advantages: - - Storage: Storage: the H takes up the H takes up no extra room no extra room - - Efficiency: Efficiency: hydrides carry hydrides carry more energy per volume more energy per volume than LH2 {'compressed' than LH2 {'compressed' >1000x) & carry 2.2X >1000x) & carry 2.2X more than compressed more than compressed H2 at 5,000 H2 at 5,000 psi psi - - Safety: Safety: no onboard tank no onboard tank of H2 or LH2 of H2 or LH2 Disadvantages: Disadvantages: - - Weight: Weight: a 100 a 100- -liter liter titanium titanium- -iron tank iron tank has 1.2 has 1.2- -1.5X energy 1.5X energy as 100 liters of LH2 as 100 liters of LH2 but weighs 25X but weighs 25X FC & iron-titanium-magnesium hydride 37 Compressed Gas Compressed Gas Onboard Storage Onboard Storage Compressed H2 Compressed H2 storage has been storage has been used in: used in: - - Mercedes NECAR Mercedes NECAR- -2 2 - - Ford FC concept car Ford FC concept car - - Daimler Daimler- -Chrysler FC Chrysler FC buses buses - - Neoplan Neoplan vehicles vehicles Compressed Compressed Onboard Storage Onboard Storage ADVANTAGES: ADVANTAGES: - - Easiest form of H Easiest form of H storage storage DISADVANTAGES: DISADVANTAGES: - - Backfire, engine Backfire, engine knock are knock are problematic problematic - - Despite extreme Despite extreme pressure, pressure, compressed tanks compressed tanks occupy so much occupy so much space that they are space that they are only practical for only practical for buses or vans buses or vans 38 Cryogenic Liquid Hydrogen Cryogenic Liquid Hydrogen {LH2) Onboard Storage {LH2) Onboard Storage - - Cryogenically Cryogenically- - cooled LH2 is cooled LH2 is BMW's preference BMW's preference - - The The Musashi Musashi Institute of Institute of Technology has Technology has also investigated also investigated this this - - Requires an Requires an extremely extremely pressurized tank pressurized tank to keep the LH2 in to keep the LH2 in liquid form liquid form A BMW, A BMW, ~ ~in operation since 1990, in operation since 1990, equipped with an aluminum alloy equipped with an aluminum alloy tank that carries 120 liters of LH2 tank that carries 120 liters of LH2 with a capacity of about 120 liters with a capacity of about 120 liters of LH2 of LH2 Viability of onboard LH2 storage Viability of onboard LH2 storage ADVANTAGES: ADVANTAGES: - - Lowest costJ unit Lowest costJ unit energy energy - - Lowest weightJ unit Lowest weightJ unit energy energy - - Easier supply Easier supply logistics logistics - - Fast refueling Fast refueling DISADVANTAGES: DISADVANTAGES: - - Loss of fuel when not Loss of fuel when not operational operational - - Large tank needed Large tank needed - - Cryogenic Cryogenic engineering engineering obstacles obstacles - - Energy to cool LH2 Energy to cool LH2 39 Hydrogen Refueling Stations Hydrogen Refueling Stations 2003: 2003: Shell plans a H2 refueling station Shell plans a H2 refueling station in Luxemburg; others in in Luxemburg; others in California, Iceland, Japan, California, Iceland, Japan, Holland, Norway Holland, Norway - - California, Arizona, Nevada, California, Arizona, Nevada, Illinois H2 refueling stations Illinois H2 refueling stations - - Washington, D.C. demo refueling Washington, D.C. demo refueling project planned project planned - - EC International EC International Hydrofueler Hydrofueler Project Project - - Reykjavik, Iceland H2 bus Reykjavik, Iceland H2 bus refueling station opens refueling station opens - - 1999: Hamburg, Munich, 1999: Hamburg, Munich, Dearborn Dearborn LH2 reIueling station, Munich airport Honda solar H2 station in Torrance, Ca. ARE FUEL CELLS BETTER? ARE FUEL CELLS BETTER? - - Fuel cells are more Fuel cells are more efficient than HICEs efficient than HICEs but less efficient when but less efficient when operated on methane operated on methane - - Barriers exist to Barriers exist to FCs FCs as as 'dual fuel' vehicles, and 'dual fuel' vehicles, and thus may be less thus may be less feasible than HICEs in feasible than HICEs in the near future unless the near future unless H2 onboard conversion H2 onboard conversion materializes materializes FCs cars are the best for zero emissions FC cars average 60 more mpg than BMW`s HICEs FCs cars are far more costly than HICE vehicles 40 What if What if FCs FCs are the future? are the future? - - BMW's future could be adversely affected BMW's future could be adversely affected - - Unlikely soon: Unlikely soon: - - FC engines 3x as heavy as FC engines 3x as heavy as ICEs ICEs - - No transport FC mass production No transport FC mass production - - Most H2 vehicles produced are HICEs Most H2 vehicles produced are HICEs - - HICEs offer a good opportunity to HICEs offer a good opportunity to improve the H2 infrastructure as HICEs improve the H2 infrastructure as HICEs are "comparatively easy to produce" are "comparatively easy to produce" - - HICEs can bridge the gap to H2 HICEs can bridge the gap to H2- -fueled fueled transport that eventually incorporates transport that eventually incorporates fuel cells fuel cells Fuel cell is a very costly technology Fuel cell is a very costly technology- -about 10 times than IC about 10 times than IC engines. engines. - - !t will take atleast 10 year to become affordable !t will take atleast 10 year to become affordable. . H2 can be used in existing I.C engines H2 can be used in existing I.C engines - - !C engine is a 100 years established technology and will require !C engine is a 100 years established technology and will require some some modifications in tooling to make it adaptable for using hydrogen modifications in tooling to make it adaptable for using hydrogen as a as a fuel. fuel. H2 is clean burning fuel in IC engine H2 is clean burning fuel in IC engine - - !t gives only Nox emission which can be minimised to negligible. !t gives only Nox emission which can be minimised to negligible. - - No after treatment needed,hence no deterioration of emissions No after treatment needed,hence no deterioration of emissions H2 can be used as admixture to CNG H2 can be used as admixture to CNG - - H2 has a very high burning rate while CNG has slower burning rat H2 has a very high burning rate while CNG has slower burning rate e - - !t can improve fuel economy 8 emission of CNG engine !t can improve fuel economy 8 emission of CNG engine H2 can be used competitive with CNG H2 can be used competitive with CNG - - With the infrastructure existing for CNG usage.H2 can replace CN With the infrastructure existing for CNG usage.H2 can replace CNG G except of additional cost for reforming facility except of additional cost for reforming facility Hydrogen in IC engines Hydrogen in IC engines 41 CONPART!vE PROPERT!ES CONPART!vE PROPERT!ES 1.05 1.05 1.30S 1.30S 1.3S3 1.3S3 Specific heat ratio {v) of Specific heat ratio {v) of NTP gas NTP gas 4S 4S 55.53 55.53 141.S6 141.S6 HEAT OF HEAT OF COMBUSTION{high)kjg COMBUSTION{high)kjg- - 1 1 44.5 44.5 50.02 50.02 119.93 119.93 HEAT OF HEAT OF COMBUSTION{LOW)kjg COMBUSTION{LOW)kjg - -1 1 4400 4400 651.19 651.19 S3.764 S3.764 DENSITY OF GAS AT DENSITY OF GAS AT NTP {GM NTP {GM- -1) 1) 107.0 107.0 16.043 16.043 2.016 2.016 MOLECULAR WEIGHT MOLECULAR WEIGHT GASOLINE GASOLINE METHANE METHANE HYDROGEN HYDROGEN PROPERTY PROPERTY CONPART!vE PROPERT!ES CONPART!vE PROPERT!ES 1.7 1.7 1.7 1.7 1.00 1.00 Normalized flame Normalized flame emissivity emissivity 2000k, 2000k, 1 1 atm atm 0.0S 0.0S 0.2 0.2 0.63 0.63 Diffusivity in air, Diffusivity in air, cm2s cm2s 30 30- -42 42 23 23- -32 32 17 17- -25 25 Percentage of Percentage of thermal energy thermal energy radited radited from from flame to surround flame to surround 0.2 0.2 0.203 0.203 0.064 0.064 Quenching gap in Quenching gap in NTP air cms NTP air cms- -1 1 37 37- -43 43 37 37- -45 45 265 265- -325 325 Burning velocity Burning velocity in NTP air,cm in NTP air,cm GASOLINE GASOLINE METHANE METHANE HYDROGEN HYDROGEN PROPERTY PROPERTY 42 CONPART!vE PROPERT!ES CONPART!vE PROPERT!ES 2470 2470 214S 214S 231S 231S Flame Flame temperature K temperature K 501 501- -744 744 S13 S13 S5S S5S Autoignition Autoignition temperature K temperature K 0.24 0.24 0.29 0.29 0.02 0.02 Minimum energy Minimum energy for ignition in air . for ignition in air . MJ MJ 1.76 1.76 9.47S 9.47S 29.53 29.53 Stoichiometric Stoichiometric composition in air composition in air vol vol % % 1.0 1.0- -7.6 7.6 5.3 5.3- -15.0 15.0 4.0 4.0- -75.0 75.0 Limit of Limit of flammability in air flammability in air vol vol % % GASOLINE GASOLINE METHANE METHANE HYDROGEN HYDROGEN PROPERTY PROPERTY Hydrogen vehicles Based on Hydrogen vehicles Based on IC engine IC engine - - Energy content of 9.5 kg of H Energy content of 9.5 kg of H2 2 is equivalent to is equivalent to 25kg of petrol. 25kg of petrol. - - Storing of 9.5kg of H Storing of 9.5kg of H2 2 require a 55kg tank vfs require a 55kg tank vfs 25kg of petrol of 17 kg tank. 25kg of petrol of 17 kg tank. - - H2 fuel typically takes + times space than H2 fuel typically takes + times space than petrol for same energy. petrol for same energy. 43 !ND!A'S ADvANTAGES FRON !ND!A'S ADvANTAGES FRON HYDROGEN HYDROGEN - - Potential to build a National Hydrogen !ndustry" at Potential to build a National Hydrogen !ndustry" at aggressive pace using exiting oil 8 natural gas aggressive pace using exiting oil 8 natural gas infrastructure produce at refineries or locally supply infrastructure produce at refineries or locally supply through existing distribution 8 retail network. through existing distribution 8 retail network. ENERGY SECUR!TY ENERGY SECUR!TY - - Hydrogen vehicles 8 Hydrogen vehicles 8 gensets gensets can replace diesel, can replace diesel, gasoline 8 kerosene, fueled polluted power units. gasoline 8 kerosene, fueled polluted power units. ENv!RONNENT PROTECT!ON ENv!RONNENT PROTECT!ON - - Allow !ndia to leap frog" in technological Allow !ndia to leap frog" in technological advancement. advancement. ECONON!C ADvANCENENT ECONON!C ADvANCENENT - - Will enable smooth transition to use of more efficient Will enable smooth transition to use of more efficient energy conversion fuel cells. energy conversion fuel cells. - - Limiting the equivalence ratio Limiting the equivalence ratio - - Adopting exhaust gas recirculation (EGR) Adopting exhaust gas recirculation (EGR) - - Avoding Avoding hot spots on sharp edges and hot spots on sharp edges and protrusions and using spark protrusions and using spark pluges pluges with narrow with narrow gap settings. gap settings. - - Water induction. Water induction. - - Fuel injection Fuel injection RENED!ES OF BACKF!RE RENED!ES OF BACKF!RE 44 - - Fuel injection Fuel injection - - optimum performance 8 low optimum performance 8 low emmision emmision (Nanifold !njectionf (Nanifold !njectionf !ncylinder !ncylinder !njection) !njection) - - Exhaust gas recirculation Exhaust gas recirculation- - avoid back fire 8 avoid back fire 8 limits limits Nox Nox - - Ultra lean operation( =0.28 achieved) Ultra lean operation( =0.28 achieved) - - Water injection Water injection- - back fire control back fire control - - Timed manifold injection has been Timed manifold injection has been experimentally found to be most effective experimentally found to be most effective CURAT!vEfPREvENT!vE STEP CURAT!vEfPREvENT!vE STEP - - Hydraulically operated Hydraulically operated - - Cam actuated Cam actuated - - Solenoid Solenoid- -actuated electronically actuated electronically- - controlled controlled Positive Features of !njection System Positive Features of !njection System- - - - Eliminate pre ignition backfire and rapid rate of Eliminate pre ignition backfire and rapid rate of pressure rise pressure rise - - Reduces Reduces Nox Nox emissions drastically emissions drastically - - no other no other pollutant in hydrogen engine exhaust. pollutant in hydrogen engine exhaust. !NJECTOR ACTUAT!ON !NJECTOR ACTUAT!ON NECHAN!SNS NECHAN!SNS 45 FUEL !NDUCT!ON TECHN!QUES FUEL !NDUCT!ON TECHN!QUES - - Carburetion Carburetion - - Continuous manifold injection (CN!) Continuous manifold injection (CN!) - - Timed manifold injection (TN!) Timed manifold injection (TN!) - - Low pressure direct cylinder injection (LPD!) Low pressure direct cylinder injection (LPD!) - - High pressure direct cylinder injection(HPD!) High pressure direct cylinder injection(HPD!) SYSTEN HARDWARE: SYSTEN HARDWARE: Nost appropriate Nost appropriate 1.+ 1.+- -5.5 kgffcm2 5.5 kgffcm2 Timed manifold Timed manifold injection (TN!) injection (TN!) Not recommended Not recommended Slightly greater Slightly greater than atmospheric than atmospheric Continuous manifold Continuous manifold injection (CN!) injection (CN!) Unsuitable Unsuitable A little above A little above atm atm. . Continuous carburetion Continuous carburetion (cc) (cc) Comments Comments Supply pressure Supply pressure Nixture formation Nixture formation 46 - - As combustion fuel directly in !C As combustion fuel directly in !C engine engine - - !n ad !n ad- -mixture with CNG and LPG. mixture with CNG and LPG. - - As a fuel for fuel cell. As a fuel for fuel cell. - - !n hybrid electric vehicles(H2 to run !n hybrid electric vehicles(H2 to run small generator for on small generator for on- -board charging board charging of batteries). of batteries). Hydrogen for Auto Application Hydrogen for Auto Application OPT!NUN ENG!NE OPT!NUN ENG!NE PERFORNANCE DEPENDS ON PERFORNANCE DEPENDS ON - - Equivalence ratio Equivalence ratio- -ultra lean to slightly rich ultra lean to slightly rich mixture. mixture. - - !gnition timing !gnition timing - - Compression ratio Compression ratio - - Nethod of fuel introduction timed manifold Nethod of fuel introduction timed manifold injection. injection. 47 PERFORNANCE OF HYDROGEN PERFORNANCE OF HYDROGEN vEH!CLES vEH!CLES - - There is a tradeoff power and efficiency and There is a tradeoff power and efficiency and Nox Nox emissions:very lean operation increases efficiency and emissions:very lean operation increases efficiency and reduces reduces Nox Nox but also reduces the volumetric heating but also reduces the volumetric heating valve of the airffuel mixture (because there is less fuel ) valve of the airffuel mixture (because there is less fuel ) and thus reduces power. and thus reduces power. - - Late direct injection of cryogenic hydrogen increases Late direct injection of cryogenic hydrogen increases power output and efficiency, it eliminates pre ignition, power output and efficiency, it eliminates pre ignition, backfiring and reduces backfiring and reduces Nox Nox formation. For these formation. For these reasons, many hydrogen researchers feel that it is the reasons, many hydrogen researchers feel that it is the most desirable form of hydrogen injection. most desirable form of hydrogen injection. Power Power Output Output of HICEs of HICEs Challenges facing HICEs: Challenges facing HICEs: - - Backfiring common Backfiring common - - premature premature ignition near the fuel intake valve ignition near the fuel intake valve - - To reduce To reduce Nox Nox, the airJfuel ratio , the airJfuel ratio can be increased, reducing power can be increased, reducing power output to half a gasoline engine's output to half a gasoline engine's - - To compensate for lost power To compensate for lost power, , HICE engines are usually larger or HICE engines are usually larger or have superchargers have superchargers - - Ford claims that Ford claims that superchargers superchargers provide near provide near- -zero emissions and zero emissions and power equal to a gas engine power equal to a gas engine 48 - - A hydrogen operated engine adopting TN! system embraces A hydrogen operated engine adopting TN! system embraces the benefit of both the C! as well as S! engine. the benefit of both the C! as well as S! engine. - - TN! designed so that the intake manifold does not contain TN! designed so that the intake manifold does not contain any combustible mixtures thus eliminates the undesirable any combustible mixtures thus eliminates the undesirable combustion phenomena combustion phenomena - - TN! provides a pre TN! provides a pre- -cooling effect and thus renders the pre cooling effect and thus renders the pre- - ignition sources ineffective. ignition sources ineffective. - - !n TN! system, hydrogen air mixing can be sufficiently rapid !n TN! system, hydrogen air mixing can be sufficiently rapid to ensure burning of hydrogen gas soon after it enters the to ensure burning of hydrogen gas soon after it enters the cylinder cylinder - - TN! is free from constraints such as injection pressure and TN! is free from constraints such as injection pressure and charge mixing time. charge mixing time. D!ST!NCT!vE FEATURES OF D!ST!NCT!vE FEATURES OF TN! TN! TN! vS LPD! TN! vS LPD! - - Both TN! and LPD! showed the possibility of eliminating Both TN! and LPD! showed the possibility of eliminating backfire by the method of delaying fuel delivery. backfire by the method of delaying fuel delivery. - - Compared to LPD!, the TN! required a less sophisticated Compared to LPD!, the TN! required a less sophisticated design of the injection valve. design of the injection valve. - - There is a possibility of flow starvation for both hydrogen There is a possibility of flow starvation for both hydrogen and air in case of LPD! whereas such a situation never and air in case of LPD! whereas such a situation never arises in TN!. arises in TN!. - - LPD! seemed to have problems of incomplete combustion LPD! seemed to have problems of incomplete combustion due to very brief time allowed for the mixing of hydrogen due to very brief time allowed for the mixing of hydrogen and air after injection. Such a problem is intrinsically and air after injection. Such a problem is intrinsically avoided in TN! system. avoided in TN! system. - - Flow controllability seemed to be main stumbling obstacle in Flow controllability seemed to be main stumbling obstacle in achieving higher speed in LPD! as compared to TN! achieving higher speed in LPD! as compared to TN! operation. operation. 49 LEAN BURN HYDROGEN LEAN BURN HYDROGEN ENG!NE ENG!NE - - A way to reduce emissions from internal combustion engines is A way to reduce emissions from internal combustion engines is through lean burn combustion. through lean burn combustion. - - Use excess combustion air to reduce flame temperature Use excess combustion air to reduce flame temperature (consequently, reduce (consequently, reduce Nox Nox). ). - - Carbon monoxide emissions from lean burn engines are also very Carbon monoxide emissions from lean burn engines are also very low. low. - - Hydrocarbon fuels have lean limits less than an airffuel ratio, Hydrocarbon fuels have lean limits less than an airffuel ratio, l*=1.7 l*=1.7 - - The lean limit for air breathing hydrogen engines is around l=5 The lean limit for air breathing hydrogen engines is around l=5 - - A pure hydrogen engine may be operated at ultra lean conditions A pure hydrogen engine may be operated at ultra lean conditions without concern for unburned fuel emission (hydrogen is not toxi without concern for unburned fuel emission (hydrogen is not toxic c or an ozone producer). or an ozone producer). - - The maximum brake thermal efficiency ever measurement at HC! The maximum brake thermal efficiency ever measurement at HC! with a lean burn hydrogen engine is 38. with a lean burn hydrogen engine is 38. - - Cv! is a robust mechanicalffluidic injection system that Cv! is a robust mechanicalffluidic injection system that is controlled by electronics, much like a modern diesel is controlled by electronics, much like a modern diesel injection system. injection system. - - !ts fundamental operating principle is to maintain an !ts fundamental operating principle is to maintain an approximately constant AfF ratio over a wide rage of approximately constant AfF ratio over a wide rage of engine operating conditions. engine operating conditions. - - No injection valves are big enough to serve the flow No injection valves are big enough to serve the flow requirements of hydrogen engines and none can requirements of hydrogen engines and none can enhance the breathing capacity of an engine as Cv! enhance the breathing capacity of an engine as Cv! does (fuel does (fuel- - to air momentum transfer). to air momentum transfer). - - Cv! shares the advantage of sequential multi port fuel Cv! shares the advantage of sequential multi port fuel injected gasoline engines enhanced breathing, quick injected gasoline engines enhanced breathing, quick throttle response and good cylinder to cylinder throttle response and good cylinder to cylinder distribution of airffuel mixture. distribution of airffuel mixture. CONSTANT vOLUNE FUEL CONSTANT vOLUNE FUEL !NJECT!ON OF H !NJECT!ON OF H2 2 50 PARALLEL !NDUCT!ON: A S!NPLE PARALLEL !NDUCT!ON: A S!NPLE FUEL CONTROL NETHOD FOR FUEL CONTROL NETHOD FOR HYDROGEN ENG!NES HYDROGEN ENG!NES - - Hydrogen and air enters the engine through separate, Hydrogen and air enters the engine through separate, parallel paths parallel paths - - The basic objective of parallel induction mixture control The basic objective of parallel induction mixture control system are to separate and control the flow of fuel and system are to separate and control the flow of fuel and air into the engine air into the engine - - Each of the parallel system has its own throttle, its own Each of the parallel system has its own throttle, its own manifold, and its own valve system. manifold, and its own valve system. - - Parallel induction is conceptually similar to intake port Parallel induction is conceptually similar to intake port injection in that fuel and air enter the cylinder during the injection in that fuel and air enter the cylinder during the intake stroke. intake stroke. - - A sleeve valve" delays the induction of H A sleeve valve" delays the induction of H2 2 HYDROGEN ADD!T!ON !N HYDROGEN ADD!T!ON !N NATURAL GAS NATURAL GAS - - Hydrogen when burnt with other fuels makes emission Hydrogen when burnt with other fuels makes emission reductions that are greater than the percentage of reductions that are greater than the percentage of hydrogen energy in the fuel. hydrogen energy in the fuel. - - The addition of hydrogen to natural gas amplifies the The addition of hydrogen to natural gas amplifies the clean burning properties of both fuels in a way that clean burning properties of both fuels in a way that produces a large leverage factor. produces a large leverage factor. - - Hythan Hythan bus fuel is a blend of 7 hydrogen by energy bus fuel is a blend of 7 hydrogen by energy content in natural gas (20 h2 by volume). content in natural gas (20 h2 by volume). - - Hytane Hytane is a registered is a registered trademarke trademarke of hydrogen of hydrogen components, !nc. components, !nc. - - The most effective way to get started with hydrogen The most effective way to get started with hydrogen energy is in highly lever aged applications with other energy is in highly lever aged applications with other fuels. fuels. 51 LEAN BURN HYTHANE ENG!NES LEAN BURN HYTHANE ENG!NES - - Adding hydrogen to natural gas allow leaner Adding hydrogen to natural gas allow leaner operation with less spark advance. operation with less spark advance. - - Both of these tuning variable reduce Both of these tuning variable reduce Nox Nox emissions. emissions. - - Non Non- -methane hydrocarbon (NNHC) emission methane hydrocarbon (NNHC) emission increase with leaner mixtures in natural gas increase with leaner mixtures in natural gas engines. engines. - - NNHC emission are reduced by adding hydrogen. NNHC emission are reduced by adding hydrogen. EN!SS!ONS EN!SS!ONS - - No HC,CO,Sox and particulates etc. No HC,CO,Sox and particulates etc. - - Nox Nox is the only pollutant of concern is the only pollutant of concern - - Ultra lean operation achievable with hydrogen Ultra lean operation achievable with hydrogen engine drastically reduces engine drastically reduces Nox Nox. . 52 Is Hydrogen Fuel Safer? Is Hydrogen Fuel Safer? Former Lockheed Manager: maintains air crashes Former Lockheed Manager: maintains air crashes involving kerosene fuel would have resulted in involving kerosene fuel would have resulted in fewer deaths if H2 were the fuel: fewer deaths if H2 were the fuel: H2 volatile/ burns quickly H2 vaporizes/ disperses quickly Less fire area
Radiated fire heat is less
with H2 No smoke from H2 fires LH2 safer upon impact than kerosene Are HICEs unsafe at any Are HICEs unsafe at any speed? speed? - - H2 is volatile and is 10x more H2 is volatile and is 10x more explosive than gasoline explosive than gasoline - - H leaks and static present risks H leaks and static present risks - - Special sensors and ducts that pull in Special sensors and ducts that pull in fresh air may be necessary whenever fresh air may be necessary whenever HICEs are parked indoors HICEs are parked indoors - - Stringent, universal safety Stringent, universal safety regulations are needed for storage, regulations are needed for storage, handling, and disposal of H2 handling, and disposal of H2 53 BMW Tests indicate BMW Tests indicate HICEs are Safe HICEs are Safe - - ' '94 BMW: safety valves of 94 BMW: safety valves of double double- -walled LH2 tanks walled LH2 tanks were blocked, cooked, were blocked, cooked, shaken, rammed with pole; shaken, rammed with pole; slow LH2 leak, no explosion slow LH2 leak, no explosion - - H2 escaped after 10 H2 escaped after 10 minutes in open fire; minutes in open fire; burned with no effect on burned with no effect on tank tank - - OTHER TESTS: some tanks OTHER TESTS: some tanks burst under extreme burst under extreme pressure buildup pressure buildup Ford's 2000 H2, Ford's 2000 H2, LH2 vehicles LH2 vehicles - - Model U concept car: Model U concept car: 3 millimeter aluminum barrier 3 millimeter aluminum barrier tank, carbon tank, carbon- -fiber structural casing, rated to a pressure fiber structural casing, rated to a pressure of 10,000 of 10,000 psi psi - - P2000 FUEL system P2000 FUEL system - - redundancy for safety: redundancy for safety: - - fueling system under trunk fueling system under trunk - - Triple redundant system based on natural gas, Triple redundant system based on natural gas, designed to use H2 natural dispersion designed to use H2 natural dispersion - - H2 ventilators H2 ventilators - - Sensors in engine, passenger and trunk Sensors in engine, passenger and trunk compartments compartments - - Alarms triggered at concentrations below Alarms triggered at concentrations below flammability flammability - - H2 detected = fuel systemJengine starter disable, H2 detected = fuel systemJengine starter disable, roof opens, ventilation fans activate roof opens, ventilation fans activate 54 ADVANTAGES: ADVANTAGES: - - Emissions are a Emissions are a fraction of convention fraction of convention ICE emissions ICE emissions - - Ford HICEs emit Ford HICEs emit almost no pollutants almost no pollutants and are 25% more and are 25% more fuel efficient than gas fuel efficient than gas ICEs ICEs - - H2J CH4 mixed fuel H2J CH4 mixed fuel emits extremely low emits extremely low NOx NOx DISADVANTAGES: DISADVANTAGES: - - High temperature H2 High temperature H2 combustion makes combustion makes Nox Nox - - NOx emissions = NOx emissions = that of gas, can be that of gas, can be lessened with lessened with additional control additional control equipment equipment - - Even without after Even without after- - treatment, NOx treatment, NOx emissions are low emissions are low - - Fossil fuel electrolysis Fossil fuel electrolysis lessens pollution gains lessens pollution gains HICEs & POLLUTION HICEs & POLLUTION Barriers to CommerciaI Barriers to CommerciaI AvaiIabiIity AvaiIabiIity H2/ LH2 H2/ LH2 infrastructure infrastructure needed needed Low cost H2 Low cost H2 production needed production needed Economics of H2 Economics of H2 cars are iII cars are iII- -defined defined ICE-HICE conversion avaiIabiIity Like current vehicIes, H2/LH2 vehicIe designs wiII IikeIy vary Lack of uniform reguIations of H2 55 Commercial HICE Availability Commercial HICE Availability - - Shell: Shell: "marathon, not a sprint, and the race has "marathon, not a sprint, and the race has just begun," just begun," H2 fuel network by 2030 H2 fuel network by 2030- -2050. 2050. Others estimate 10 Others estimate 10- -50 years to the H2 economy 50 years to the H2 economy - - BMW's HICE cars are available today BMW's HICE cars are available today - - John C. Anderson, Pres. & CEO of AFS says: John C. Anderson, Pres. & CEO of AFS says: {1) the existing ICE infrastructure {1) the existing ICE infrastructure {2) the demand for clean emissions; & {2) the demand for clean emissions; & {3) H2's flammability characteristics {3) H2's flammability characteristics make H2 the make H2 the "ultimate low cost fuel" "ultimate low cost fuel" which, which, when widely available, can be adapted to when widely available, can be adapted to conventional autos and diesel engine vehicles conventional autos and diesel engine vehicles - - Rev.w.cecil Rev.w.cecil {1S20) "hydrogen gas as a moving {1S20) "hydrogen gas as a moving power in machinery" paper presented before power in machinery" paper presented before Cambridge Philosophical Society Cambridge Philosophical Society - - "Hydrogen engine prototype " by "Hydrogen engine prototype " by Benini Benini in 1S56 in 1S56 {Refereed in I.C. engine text book by {Refereed in I.C. engine text book by Lichty Lichty ) ) - - Ricardo, h.f., "Further Note on Fuel s Committee, Ricardo, h.f., "Further Note on Fuel s Committee, Proc. IAC, vol. 1S, {1923 Proc. IAC, vol. 1S, {1923- -24). 24). - - Rudolf Rudolf Erren Erren " Hydrogen : A commercial Fuel fro " Hydrogen : A commercial Fuel fro internal combustion engines and other internal combustion engines and other purposes" journal of the Institute of fuel purposes" journal of the Institute of fuel - -1933. 1933. - - R.O king et al in R.O king et al in Candada Candada Exhaustive combustion Exhaustive combustion studies studies P!ONEER!NG HYDROGEN P!ONEER!NG HYDROGEN ENG!NE RESEARCHERS ENG!NE RESEARCHERS 56 !ND!A'S ADvANTAGES FRON !ND!A'S ADvANTAGES FRON HYDROGEN HYDROGEN - - Potential to build a National Hydrogen !ndustry" at Potential to build a National Hydrogen !ndustry" at aggressive pace using exiting oil 8 natural gas aggressive pace using exiting oil 8 natural gas infrastructure produce at refineries or locally supply infrastructure produce at refineries or locally supply through existing distribution 8 retail network. through existing distribution 8 retail network. ENERGY SECUR!TY ENERGY SECUR!TY - - Hydrogen vehicles 8 Hydrogen vehicles 8 gensets gensets can replace diesel, can replace diesel, gasoline 8 kerosene, fueled polluted power units. gasoline 8 kerosene, fueled polluted power units. ENv!RONNENT PROTECT!ON ENv!RONNENT PROTECT!ON - - Allow !ndia to leap frog" in technological Allow !ndia to leap frog" in technological advancement. advancement. ECONON!C ADvANCENENT ECONON!C ADvANCENENT - - Will enable smooth transition to use of more efficient Will enable smooth transition to use of more efficient energy conversion fuel cells. energy conversion fuel cells. STATUS OF HYDROGEN STATUS OF HYDROGEN DEvELOPNENT !N !ND!A DEvELOPNENT !N !ND!A - - NETAL HYDR!DE STORAGE NETAL HYDR!DE STORAGE BHU has developed metal hydride storage system for storage and BHU has developed metal hydride storage system for storage and release of hydrogen which can be used in release of hydrogen which can be used in gensets gensets and two and two wheelers wheelers- - technology at demonstration stage. technology at demonstration stage. USE OF HYDROGEN !N !C ENG!NES USE OF HYDROGEN !N !C ENG!NES !!T, Delhi has developed hydrogen gas induction system for !C en !!T, Delhi has developed hydrogen gas induction system for !C engine gine which can be used from small which can be used from small genset genset to large capacity spark to large capacity spark ignition engines. ignition engines. Development of fuel cells. Agencies working are Development of fuel cells. Agencies working are BHEL BHEL- -Hyderabad Hyderabad SP!C Science Foundation SP!C Science Foundation- - Chennai Chennai Glass 8 Ceramic Research !nstitute Glass 8 Ceramic Research !nstitute- -Kolkata Kolkata. . !!CT !!CT- -Hyderabad Hyderabad DRDO DRDO- -Naval Naterial research Lab. Naval Naterial research Lab. TER! TER!- -Delhi are working on. Delhi are working on.