Escolar Documentos
Profissional Documentos
Cultura Documentos
COMBUSTION THEORY
COMBUSTION THEORY
Downloaded and Presented by Ly Ngoc Minh lyngocminh61@yahoo.com.vn
Energy exists in many forms, such as mechanical energy, heat, light, chemical energy, and electrical energy. Energy is the ability to bring about change or to do work. Thermodynamics is the study of energy.
Surroundings System
The frontier of the system is arbitrarily chosen
The system can interchange mass and energy through the frontier with the environment. An example of closed system - no mass flow- is the gas confined in a cylinder. The frontier in this case physical- is made by the cylinder and the piston walls.
The First Law of Thermodynamics. Heat, Work and Internal Energy Joules Experiment and the First Law of Thermodynamics. Equivalence between work and heat
Energy can be changed from one form to another, but it cannot be created or destroyed. The total amount of energy and matter in the Universe remains constant, merely changing from one form to another.
The First Law of Thermodynamics (Conservation) states that energy is always conserved, it cannot be created or destroyed. In essence, energy can be converted from one form into another. The energy balance of a system as a consequence of FLT- is a powerful tool to analyze the interchanges of energy between the system and its environment. We need to define the concept of internal energy of the system, Eint as an energy stored in the system. Warning: It is no correct to say that a system has a large amount of heat or a great amount of work
5 http://www.emc.maricopa.edu/faculty/farabee/BIOBK/BioBookEner1.html
Schematic diagram for Joules experiment. Insulating walls to prevent heat transfer enclose water. As the weights fall at constant speed, they turn a paddle wheel, which does work on water. If friction in mechanism is negligible, the work done by the paddle wheel on the water equal the change of potential energy of the weights.
The sum of the heat transfer into the system and the work done on the system equals the change in the internal energy of the system
1
PDF created with pdfFactory Pro trial version www.pdffactory.com
PV = n R T
How the confined gas interchange energy (heat and work) with the surroundings?. What is the value of the internal energy for the gas in the cylinder First Law How can we calculate the energy heat and/or worktransferred, added of subtracted, to the system?
Quasi static processes: a type of processes where the gas moves through a
7
series of equilibrium states. Then, we can apply the IGL. In practice, if we move 8 slowly the piston, will be possible to approximate quasi-static processes fairly well.
First Law of Thermodynamics. Fluxes of energy and mass on the earth surface. Energy balance.
Rn = Rns + Rnl ET H CO2
The First Law of Thermodynamics. Application to a particular case: A gas confined in a cylinder with a movable piston. Internal Energy
!E
Ph Ph
Energy fluxes: Rn : Net gain of heat energy from radiation ET Latent heat, Energy associated to the flux of water vapor leaving from the system H Sensible Heat. G Heat energy by conduction to the D soil Ph: Net photosynthesis Eint: Change of the internal energy of the system D: Advection
What is the value of the internal energy for the gas in the cylinder?
Experiment: Free expansion. For a gas at low density an ideal gas-, a free expansion does not change the temperature of the gas.
If heat is added at constant volume, no work is done, so the heat added equals the increase of thermal energy
Rn H ET G D - Ph = !Eint
9
dEint = CV dT = n cV dT
Internal Energy is a state function, i.e. it is not dependent on the 10 process, only it depends of the initial and final temperature
The First Law of Thermodynamics. Application to a particular case: A gas confined in a cylinder with a movable piston. Heat
The First Law of Thermodynamics. Application to a particular case: A gas confined in a cylinder with a movable piston
If heat is added at constant pressure the heat energy transferred will be used to expand the substance and to increase the internal energy.
QP = CP T QP = CP dT
If the substance expands, it does work on its surroundings. Applying the First Law of Thermodynamics If heat is added at constant volume, no work is done, so the heat added equals the increase of thermal energy
QV = CV T ; QV = CV dT QP = CP T ; Q P = CP dT CP CV = n R
Relationship of Mayer
Ideal Gas
From the Kinetic theory, for monoatomic gases for biatomic gases
Qin ,V = CV dT = n cV dT Qin ,V = CV T = n cV T
For solids and liquids, as the expansion at constant pressure is usually negligible CP ~ CV.
CP CV = n R
11 The expansion is usually negligible for solids
2
PDF created with pdfFactory Pro trial version www.pdffactory.com
The First Law of Thermodynamics. Application to a particular case: A gas confined in a cylinder with a movable piston. Work
Work done on the system, Won , is the energy transferred as work to the system.
When this energy is added to the system its value will be positive. The work done on the gas in an expansion is
P- V diagrams
Won gas = P dV
V1
V2
P- V diagrams
Constant pressure
Conecting an initial state and a final state by three paths Constant pressure Constant Volume
13
Isothermal
V2
V2
If 5 L of an ideal gas at a pressure of 2 atm is cooled so that it contracts at constant pressure until its volume is 3 l, what is the work done on the gas? [405.2 J]
Won gas = P dV = 0
V1
V2
Constant Temperature
Won gas =
V2
V1
n RT V dV = n R T ln 2 V V1
14
16
The First Law of Thermodynamics. Processes. P-V Diagrams A polytropic process is a thermodynamic process that obeys the relation: PVn = C,
where P is pressure, V is volume, n is any real number (the polytropic index), and C is a constant. This equation can be used to accurately characterize processes of certain systems, notably the compression or expansion of a gas, but in some cases, possibly liquids and solids.
Adiabatic Processes. No heat flows into or out of the system Qin = 0 Adiabatic process then Eint = Won ,adiabatic = n cV T
The equation of curve describing the adiabatic process is
CP CV
adiabatic coefficient
For certain indices n, the process will be synonymous with other processes: if n = 0, then PV0=P=const and it is an isobaric process (constant pressure) if n = 1, then for an ideal gas PV= const and it is an isothermal process (constant temperature) if n = = cp/cV, then for an ideal gas it is an adiabatic process (no heat transferred)
We can use the ideal gas to rewrite the work done on the gas in an adiabatic process in the form
Won gas,adiab =
Pf V f Pi Vi 1
17 18
3
PDF created with pdfFactory Pro trial version www.pdffactory.com
Two moles of an ideal monoatomic gas have an initial pressure P1 = 2 atm and an initial volume V1 = 2 L. The gas is taken through the following quasi-static cycle: A.- It is expanded isothermally until it has a volume V2 = 4 L. B.- It is then heated at constant volume until it has a pressure P 3= 2 atm C.- It is then cooled at constant pressure until it is back to its initial state. (a) Show this cycle on a PV diagram. (b) Calculate the head added and the work done by the gas during each part of the cycle. (c) Find the temperatures T1, T2, T3
Solve the above problem considering the STEP A is an adiabatic expansion. Determine the efficiency of the both cycles. Determine the efficiency of a Carnot cycle operating between the temperature extremes of the both cycles..
19 20
21
22
23
A steamboat or steamship, sometimes called a steamer, is a ship in which the primary method of propulsion is steam power
24
4
PDF created with pdfFactory Pro trial version www.pdffactory.com
A heat engine is a cyclic device whose purpose is to convert as much heat input into work as possible. Working substance (water in steam engine, air and gasoline vapor in internal-combustion engine), that absorbs a quantity of heat, Qh, does work on its surroundings, and gives an amount of heat, Qc, as it returns to initial state.
Several hundreds atmospheres and water vaporizes at about 500 C
25
26
Heat Engines.
No system can take energy as heat from a single source and convert it completely into work without additional net changes in the system or in the surroundings. SECOND LAW, KELVIN STATEMENT Efficiency of a heat engine
=
Otto cycle representing the internal-combustion engine
W Qh Qc Q = =1 c Qh Qh Qh
It is impossible to make a heat engine with a efficiency of 100 per cent It is impossible for a heat engine working in a cycle to produce only the effect of extracting heat from a single reservoir and performing an equivalent amount of work
27
28
Refrigerators.
A process whose only net result is to transfer energy as heat from a cooler object to a hotter one is impossible. SECOND LAW, CLAUSIUS STATEMENT
It is impossible for a refrigerator working in a cycle to produce only the effect of extracting heat from a cold object and reject the same amount of heat to a hot object
COP =
Qc W
COP =
Qc W
30
5
PDF created with pdfFactory Pro trial version www.pdffactory.com
COPHP =
Heat Pump
Qh W
31
32
Maximum efficiency for a heat engine. Carnot cycle is a reversible cycle between only two heat reservoirs
Carnot engine: A reversible engine working in a cycle between two heat reservoirs. The cycle is called a Carnot cycle
W Qh Qc Q = =1 c Qh Qh Qh
33
34
Maximum efficiency for a heat engine. Carnot cycle is a reversible cycle between two heat reservoirs
Isothermal processes
C = V3 V4
Qh = Wby gas =
V2
V1
V P dV = n R Th ln 2 V1
V4 V3
Qc = Won gas = P dV = n R Tc ln
Adiabatic processes
Th V2 1 = Tc V3 1 Th V1 1 = Tc V4 1 V Tc ln 2 Qc V1 Tc = = Qh T ln V3 Th h V4
V2 1 V3 1 V V = 2= 3 V1 1 V4 1 V1 V4
A steam engine works between a hot reservoir at 100 C and a cold reservoir at 0C. (a) What is the maximum possible efficiency of this engine? If the engine is run backwards as refrigerator, what is its maximum coefficient of performance? If the engine is running as heat pump, what is the maximum coefficient of performance?
W Qh Qc Q T = = 1 c =1 c Qh Qh Qh Th
35 36
6
PDF created with pdfFactory Pro trial version www.pdffactory.com
Irreversibility, desorder:
The free expansion of an idealgas: No work, no heat, no change of internal energy, But, is it the same state after and before of the free expansion?
Entropy
Entropy, S: a physical magnitude whose net increment (system + surroundings) indicates the irreversibility of a process: In a irreversible process, the entropy of the universe increases For any process, the entropy of the universe never decrease A spontaneous heat transfer (from hotter body to a colder one) implies an increment of entropy (It is a irreversible process) Entropy: a thermodynamic function of disorder
dS =
Qrev T
37
7
PDF created with pdfFactory Pro trial version www.pdffactory.com