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O=C HO
C=O OH
difunctionality
flexible structure
HOOC
COOH
HO
OH
PRIPLAST polyesters made with PRIPOL dimer acid or HO- ..... dimer diol
E.....E
.... - OH
non-crystallinity
PRIPOL and PRIPLAST technology provide a unique combination of resistance against moisture, chemicals, heat, oxidation, radiation
PT
po ly ca rb
po ly ca pr
100
20
0 0 5 10 Days 15 20
10% H2SO4 @ 23 C
% Retention 60 of strength 40
20 0
100 80
% Retention 60 of strength 40
20 0
100 80
EGadipate
BDadipate
Priplast 3192
Priplast 3196
EGadipate
BDadipate
Priplast 3192
Priplast 3196
5% NaOH @ 60 C
120 100 90 80 70 60 50 40 30 20 10 0
Methanol
% 80 Retention 60 of strength 40
20 0
EGadipate
BDadipate
Priplast 3192
Priplast 3196
120
100
BD-adipate HD-adipate Polycapro- lacton MPD- Terephthalate HD-carbonate PTMEG Priplast 1838
20
0 0 5 10 15 Days 20 25 30 35
100 90 80 70 60 retention of tensile 50 strength (%) 40 30 20 10 0 HDO-adipate Priplast 3192 Priplast 3195 Priplast 1838 PTMEG PPG
100 90 80 70 60 50 40 30 20 10 0
95
38
PP G
PP G
te
EG
EG
95
38
te
PB -d io
PT M
-a d
-a d
as t
as t
as t
DO
Pr ip l
Pr ip l
Pr ip l
1 polyol (MW 2000), 2 butane diol, 3 MDI exposure to 140 for 4 weeks polyethers are destroyed within days
Pr ip l
DO
as t
PT M
PB -d io
ip a
ip a
31
31
18
18
Weather resistance
120
100
20
PRIPOL and PRIPLAST technology gives polyurethanes with good mechanical properties
recipe:
200
50
0
-a di po pa ly te ca pr ol ac H D to O n -c ar bo na te PT M EG PP Pr G ip la st 31 Pr 95 ip la st 31 Pr 92 ip la st 31 Pr 90 ip la st 18 Pr 38 ip la st 31 po 96 ly B D di ol ip at e O -a d D B H D
-a d
-a d
PT
Pr ip la st
Pr ip la st
po ly ca pr
Pr ip la st
Pr ip la st
Pr ip la st
500 450 400 350 300 tensile strength, kg/cm2 250 200 150 100 50 0
ip po at ly e ca pr ol ac to n 31 95 Pr ip la st 31 92 Pr ip la st 31 90 Pr ip la st 18 38 Pr ip la st 31 96 po ly B D di ol M EG ip at e PP G
-a d
-a d
PT
Pr ip la st
700 600 500 400 300 200 100 0 Modulus 100% Modulus 300% Tensile Strength Hardness Elongation
weigh polyol plus isocyanate in the desired quantities (depending on recipe), mix and heat to 60C reaction causes temperature increase to about 75C keep the mix at 80C for one hour, then cool back to 60C add the chain extender in the required ratio, keep mixing as long as possible at about 70C, the mixture looses transparency, then quickly pour out keep at 100C overnite to complete reaction
The prepolymer route is crucial, because of the polarity difference between hydrophobic dimerate ester and the polar chain extender
The resulting product has about 35% solids, and can be used for coatings and adhesives
the adhesive can be used for many applications, with particular benefits in the areas of adhesion to low-energy surfaces, and in applications that require both resistance against hydrolytic attack (moisture, alkali, acid, methanol) and radical attack (heat, oxygen, UV, chlorine)
. .
0.7 0.6 0.5 stress at 0.4 maximum load (MPa) 0.3 0.2 0.1 0 PTMEG HDO-AD P 3192 P 3196
specifications: acid value saponification value hydroxyl value color APHA moisture monomer alcohol dimer alcohol trimer alcohol viscosity max. 0.20 mg KOH/g max. 2.0 mg KOH/g 200-215 mg KOH/g max. 50 max. 0.10 % max. 2.0 % min. 94.5 % max. 1.5 % typically 2500 mPa.s
elastomers with low- temperature impa needs, elastic coatings, primers, seala water-repellant foam
solid, MW 2000, OH-value 52-60 PU coatings and adhesives (textile, hydrolytic/thermal /oxidative stability wood, leather), leather finishing liquid, MW 2000, OH value 52-60 elastomers, sealants, bitumen extreme hydrolytic stability, thermal/oxidative stability,modification low polarity, hydrocarbon compatibility liquid, MW 3000, OH-value 34-40 elastomers, sealants, bitumen extreme hydrolytic stability, low polarity, hydrocarbon modification compatibility, elastomers, sealants, soft products liquid, MW 2000, OH-value 52-60 extreme hydrolytic stability, low polarity, hydrocarbon compatibility
liquid, MW 1300 extreme hydrolytic stability, low polarity
Priplast 3196*
Priplast 3197*
Priplast 3198