CHEM 1100/ 1110 ; EXAM 3 Overview and Review session Chapter 4,15,18 6 5 TOTAL Easy 2 2 3 7 Medium 5 4 4 13 Hard 2 2 1 5 Total 9 8 8 25

Exam Three Content Topics Chapter 4/15 Acid Base Reactions o Definition of acids and bases Conjugate Acids and bases Titration (M1V1= M2V2) pH and pOH Chapter 4/18 Redox Reactions o Oxidation reactions Be able to pick out the oxidizing agent and the reducing agent How to determine oxidation states (oxidation numbers) o Half reactions o Balancing redox reaction in acidic media o Balancing redox reactions in basic media Chapter 6 Thermochemistry o Internal Energy and the 1st law of Thermodynamics (conservation of energy) o Heat Capacity and specific heat o Calorimetry o Hesss Law o Heat of Formation Chapter 5 Gas Laws o Simple gas Laws Boyles Law Charles Law Avogadros Law o Ideal Gas Law o Daltons Law of Partial Pressures o Kinetic Molecular theory o Diffusion and Effusion o Real Gasses (under what conditions are gasses not ideal) *** LIMITING REACTANTS MIGHT SHOW UP IN CHAPTER 5***

CHAPTER 4/15 Acid/ Base reactions Definitions of acid and bases

CHEM 1100/ 1110 ; EXAM 3 Overview and Review session There are three, but we only use two. All three are listed here Arrehenius Acids and Bases Acids are substances that produce H+ ions in solution Bases are substance that produce OH- ions in solution o i.e HCl +H2O H3O+ + Cl (Acid) NaOH + H2O Na+(aq) + OH-(aq) (Base) Brnsted- Lowry Acids are substances that are proton donors Bases are Substances that are proton acceptors Lewis Acids are substances that are electron pair acceptors Bases are substances that are electron pair donors Conjugate acids and conjugate Bases o NH3 + H2O NH4 + OH NH3= Base (accepts proton) H2O= Acid (loses proton) NH4+ = Conjugate Acid OH- = Conjugate Base Titration o #Mole of H+ = # mole of OHo Pitfalls 100 ML * .1 M HCL with 100 ML .1 M NaOH nHCl= .01 Mol = nNaOH What Is concentration of NaCl o CNaCL = .01mole / 200 ml = .005 M o Polyprotic Acids H2SO4 (n H2SO4 = 2n H+) Example 2 = Ca(OH2) o pH and pOH pH= -log[H+] pOH = -log[OH-] pH +pOH =14 o

Chapter 4/18 Redox Reactions Redox Reactions o Recognize Redox Reaction o Oxidation States Cu2+ = 2+ K2Cr2O7 2K+ + Cr2O7-2 ((-2*7) (2x) = -2 x= +6 o Oxidation Reaction

CHEM 1100/ 1110 ; EXAM 3 Overview and Review session Lose electrons (e- on the right hand side) Zn (s) Zn 2+ + 2eo Reduction Reaction Gain Electrons (electrons on the left hand side) Cu2+ + 2e- Cu (s) o In General LEO goes GER LEO= Lose electrons Oxidation GER= Gain electrons Reduction Oxidizing and Reducing Agents o Oxidizing agent is reduced (gains e-) o Reducing Agent in oxidized (loses e-) Balancing Redox Reactions o Problem 3(a) from Chapter 18 (page 738) PbO2 + 2I- PB2+ + I2 Balance in Acids and then in basic conditions Identify reactions Write down the reactions o Reduction = Lead Oxide into Lead two Plus o Oxidation= Two Iodine minus into Iodide Balance E- ( for Iodine on the right) For PbO2 on the left o At least 2 questions on this

Chapter 6 Thermo Chemistry First Law o E = q+ w o E sys > 0 if q is gained from the surrounding o E sys > 0 if q is done on the system q=mcT W= -PV o T >0 , q> 0 o T <0, q< 0 o V > 0, w <0 o V < 0, w> 0 Calorimetry o Bomb Calorimeter V = 0 q = E o Solution Calorimetry H = E + (PV) = E + PV = E

CHEM 1100/ 1110 ; EXAM 3 Overview and Review session P = 0 o P is constant

Hess Law o HRxn = HRxn1 + HRxn2 +.. Reverse reaction = change sign Multiple a rxn multiple H rxn by the same factor o Hrxn = Ho f products - Ho f reactants o Ho f H2O (g) doesnt equal Ho f (l) o See Sample Problem in video

Chapter 5 Gas laws Monometer o Open ended Measures relative pressure compared to the atmosphere Pgas = Patm + PHg o Closed P gas = P Hg Simple Gas laws o Boyles p1v1= p2v2 o Charles V1/T1 = V2/ T2 o Avogadros V1/ n1 = V2/ n2 o Ideal Gas law (p1v1)/(n1t1) = (p2v2)/(n2t2) = Constant R = 0.08206 (L*atm)/(mol*K) Limiting Reagent problems o Mix 5g H2 w/ 20 g of O2 Find Ptotal product when t =