This document consists of 18 printed pages and 2 blank pages.

MML 5269 3/03 S60199/1

CIE 2003 [Turn over
CAMBRIDGE INTERNATIONAL EXAMINATIONS
General Certificate of Education Ordinary Level
CHEMISTRY 5070/01
Paper 1 Multiple Choice
October/November 2003
1 hour
Additional Materials: Multiple Choice Answer Sheet
Soft clean eraser
Soft pencil (type B or HB is recommended)
READ THESE INSTRUCTIONS FIRST
Write in soft pencil.
Do not use staples, paper clips, highlighters, glue or correction fluid.
Write your name, Centre number and candidate number on the answer sheet in the spaces provided
unless this has been done for you.
There are forty questions on this paper. Answer all questions. For each question there are four possible
answers A, B, C, and D.
Choose the one you consider correct and record your choice in soft pencil on the separate answer sheet.
Read the instructions on the Answer Sheet very carefully.
Each correct answer will score one mark. A mark will not be deducted for a wrong answer.
Any rough working should be done in this booklet.
A copy of the Periodic Table is printed on page 20.
UNIVERSITY of CAMBRIDGE
Local Examinations Syndicate
1 What is the most suitable way of investigating the different food colourings in some drinks?
A crystallisation
B filtration
C fractional distillation
D paper chromatography
2 A gas, X, is less dense than air and insoluble in water.
Which method cannot be used to collect the gas?
water
X
X
X
X
A B
C
D
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3 The apparatus shown in the diagram was set up.
Over a period of time how will the water level at X change?
A It will fall, then rise and return to X.
B It will fall and remain at a lower level.
C It will rise, then fall then return to X.
D It will rise and remain at a higher level.
4 A salt is dissolved in water. The results of two separate tests on it are shown in the table.
What is the salt?
A aluminium chloride
B aluminium sulphate
C zinc chloride
D zinc sulphate
hydrogen
air
water
X
gas jar
porous pot
3
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test result
1 add aqueous ammonia a white precipitate which dissolves when
an excess of aqueous ammonia is added
2 add dilute nitric acid then a white precipitate
aqueous barium nitrate
5 A researcher notices that atoms of an element X are releasing energy.
Why does this happen?
A The atoms are affected by light.
B The atoms are radioactive.
C The atoms react with argon in the air.
D The atoms are evaporating.
6 An atom of element X is represented by
7
3
X.
Which statement about an atom of X is correct?
A It is in Group III of the Periodic Table.
B It is in Group VII of the Periodic Table.
C The total number of protons and electrons is 6.
D The total number of protons and neutrons is 10.
7 In which pair of substances, does each have a giant molecular structure?
A diamond, iodine
B diamond, silica (sand)
C iodine, methane
D methane, silica (sand)
8 In which substance is each carbon atom covalently bonded to only three other atoms?
A carbon dioxide
B diamond
C graphite
D methane
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9 How many electrons are shared in the covalent bonding of a methane molecule?
A 2
B 4
C 6
D 8
10 The table gives information about the ability of four substances to conduct electricity.
What could these four substances be?
11 What is the mass of magnesium which completely reacts with 250 cm
3
of 1.0 mol / dm
3
sulphuric
acid?
A 6g B 12 g C 48 g D 96 g
12 A volume of ethane, C
2
H
6
, at r.t.p. has a mass of 20 g.
What is the mass of an equal volume of propene, C
3
H
6
, at r.t.p.?
A 20 g B 21 g C 28 g D 42 g
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substance
W does not conduct under any conditions
X conducts only in aqueous solution
Y conducts when molten and when solid
Z conducts when molten and when in aqueous solution
W X Y Z
A Pb HCl NaCl S
B S HCl NaCl Pb
C S HCl Pb NaCl
D S NaCl HCl Pb
13 Apparatus is set up as shown in the diagram.
What occurs at electrode X?
A Chloride ions are oxidised.
B Chloride ions are reduced.
C Nickel ions are oxidised.
D Nickel is deposited.
14 Which of the following, when added to water, makes a solution that is a good conductor of
electricity?
A calcium carbonate
B copper
C ethanol
D sodium hydroxide
concentrated
aqueous
nickel (II)
chloride
carbon
electrode
X
carbon
electrode
Y
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15 The diagram shows an energy profile diagram for a chemical reaction.
Which energy change is the activation energy for the catalysed reaction?
16 The formation of hydrogen iodide from hydrogen and iodine is an endothermic reaction.
HH + I I

HI + HI
What may be deduced from this information?
A The number of bonds broken is greater than the number of bonds formed.
B The formation of H I bonds absorbs energy.
C The products possess less energy than the reactants.
D The total energy change in bond formation is less than that in bond breaking.
A
B
C
D
energy
reactants
products
7
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17 Calcium carbonate was reacted with an excess of dilute hydrochloric acid at room temperature.
CaCO
3
+ 2HCl

CaCl
2
+ H
2
O + CO
2
Two experiments were carried out.
Experiment 1 100 g of calcium carbonate in large lumps.
Experiment 2 50 g of calcium carbonate as a fine powder.
Which of the graphs is correct?
18 When acidified potassium manganate(VII) is reduced, which colour change occurs?
A from colourless to purple
B from green to orange
C from orange to green
D from purple to colourless
A B
C D
volume
of gas
volume
of gas
volume
of gas
volume
of gas
time time
time time
1
2
1
2
1
2
1
2
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19 The pH of an aqueous solution of hydrochloric acid is 2.
What will be the pH of the acid after the addition of 10 g of sodium chloride?
A 1
B 2
C 7
D 9
20 An acid, X, was added to a solution of the nitrate of metal Y. A dense white precipitate was
formed.
What are X and Y?
21 Aluminium sulphate is used in water treatment. Aqueous aluminium sulphate is acidic.
The table shows the results of tests on four different samples of treated water.
To which sample had an excess of aluminium sulphate been added?
22 Which statement about the alkali metals is true?
A they form covalent bonds with Group VII elements
B they form oxides on reacting with water
C their melting points decrease on descending Group I
D their reactivities decrease on descending Group I
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acid X metal Y
A hydrochloric calcium
B nitric zinc
C sulphuric aluminium
D sulphuric barium
sample
pH of reaction with an excess
sample of aqueous ammonia
A 3 white precipitate
B 3 no reaction
C 7 no reaction
D 11 white precipitate
23 Which gas is present in the light bulb?
A argon
B krypton
C nitrogen
D oxygen
24 Which shows the correct catalyst for each industrial process?
tungsten
filament
gas
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manufacture of manufacture of manufacture of
sulphuric acid ammonia margarine
A nickel iron
vanadium(V)
oxide
B nickel
vanadium(V)
iron
oxide
C
vanadium(V)
iron nickel
oxide
D
vanadium(V)
nickel iron
oxide
25 Which statement is not a reason for the importance of recycling aluminium?
A Aluminium is a rare metal in the Earths crust.
B The demand for aluminium continues to rise annually.
C The extraction of aluminium from its ore is expensive.
D The properties of aluminium make it one of the most useful of all metals.
26 Three types of steel have different properties.
steel 1 easily shaped
steel 2 brittle
steel 3 resistant to corrosion
What are the names of these three types of steel?
27 Four experiments on rusting are shown.
Which two experiments can be used to show that air is needed for iron to rust?
A 1 and 3
B 1 and 4
C 2 and 3
D 2 and 4
3
oil
paper-clip paper-clip paper-clip
boiled tap
water 15C
2 4 1
dry air
15C
tap water
15C
tap water
25C
paper-clip
not rusty
after 1 week
rusts
after 1 week
not rusty
after 1 week
rusts
after 1 week
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steel 1 steel 2 steel 3
A high carbon mild stainless
B high carbon stainless mild
C mild high carbon stainless
D mild stainless high carbon
28 The metals iron, lead and zinc can each be manufactured by the reduction of the oxides with
coke.
What is the correct order of the ease of reduction of the metal oxides?
29 The diagram shows the structure of brass.
Why is brass harder than pure copper?
A The zinc atoms form strong covalent bonds with copper atoms.
B The zinc atoms prevent layers of copper atoms from slipping over each other easily.
C The zinc atoms prevent the sea of electrons from moving freely in the lattice.
D Zinc atoms have more electrons than copper atoms.
zinc atom
copper atom
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oxides becoming more
difficult to reduce
A iron, lead, zinc
B iron, zinc, lead
C lead, iron, zinc
D zinc, iron, lead
30 Which of the following methods would not produce ammonia?
A heating concentrated aqueous ammonia
B heating ammonium chloride with calcium hydroxide
C heating ammonium sulphate with sodium hydroxide
D heating ammonium sulphate with dilute hydrochloric acid
31 Aqueous copper(II) sulphate is electrolysed using carbon electrodes.
What happens to the electrolyte?
A It becomes more acidic.
B It becomes more alkaline.
C It turns deeper blue.
D It remains unchanged.
32 The water in a lake showed signs of eutrophication.
What could be the cause of this?
A increasing the amount of dissolved fertiliser
B increasing the amount of dissolved oxygen
C decreasing the amount of dissolved mineral salts
D decreasing the number of bacteria
33 Methane, sulphur dioxide and carbon dioxide are gases which affect the atmosphere and the
environment.
In what way do these gases affect the environment?
13
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methane sulphur dioxide carbon dioxide
A depletion of the ozone layer acid rain global warming
B global warming photochemical smog acid rain
C photochemical smog global warming depletion of the ozone layer
D global warming acid rain global warming
34 The macromolecules of proteins, fats and carbohydrates can all be broken down into their simple
units by a similar process.
What is the process called?
A esterification
B hydrolysis
C oxidation
D reduction
35 The repeating units of two polymers, X and Y, are shown below.
What are X and Y?
C
O
C
O
C
O
C
O
N
H H
N
O O
X
Y
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X Y
A nylon Terylene
B starch Terylene
C protein starch
D nylon protein
36 The table shows the results of tests carried out on compound X.
Which formula represents compound X?
37 Butane and methylpropane are isomers.
Which formula is different for the two isomers?
A empirical formula
B general formula
C molecular formula
D structural formula
C
H
O
H
H
H
C C C
O
O
H
H
H
H
H H O
H H
C C
H
H
H
H
C
O
C C O C O H
H
H
H
H
C
H
H H
H
C C C
O
O
H
A B
C D
15
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test result
bromine water added decolourised
sodium carbonate added colourless gas evolved
38 What is the general formula of the homologous series of carboxylic acids?
methanoic acid HCO
2
H
ethanoic acid CH
3
CO
2
H
propanoic acid C
2
H
5
CO
2
H
butanoic acid C
3
H
7
CO
2
H
A CHO
B C
n
H
2n
O
C C
n
H
n
O
n
D C
n
H
2n
O
2
39 A section of a polymer is shown.
The monomer is
The monomer undergoes condensation polymerisation. What is made each time a monomer
adds to the polymer?
A hydrogen molecules, H
2
B hydroxide ions, OH

C oxygen atoms, O
D water molecules, H
2
O
O H O H
O O O O
16
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40 The experiment shown is carried out.
What process occurs?
A cracking
B dehydrogenation
C distillation
D polymerisation
water
liquid alkane
on mineral
fibre
aluminium
oxide
very strong
heat
ethene
17
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BLANK PAGE
18
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BLANK PAGE
19
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7
A
u
G
o
l
d
7
9
2
0
1
H
g
M
e
r
c
u
r
y
8
0
2
0
4
T
l
T
h
a
l
l
i
u
m
8
1
2
0
7
P
b
L
e
a
d
8
2
2
0
9
B
i
B
i
s
m
u
t
h
8
3
P
o
P
o
l
o
n
i
u
m
8
4
A
t
A
s
t
a
t
i
n
e
8
5
R
n
R
a
d
o
n
8
6
F
r
F
r
a
n
c
i
u
m
8
7
2
2
6
R
a
R
a
d
i
u
m
8
8
2
2
7
A
c
A
c
t
i
n
i
u
m
8
9

1
H
H
y
d
r
o
g
e
n
1
I
I
I
I
I
I
V
V
V
I
V
I
I
0