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units.
Ans :- a. 2.19 x 10
8
cm/sec b. 3.32 c. h/2
22. Calculate the wavelength of moving electron having 4.55 x 10
25
joule of kinetic energy.
Ans :- 7.27 x 10
7
metre
23. Calculate the wavelength of helium atom whose speed is equal to its rms speed at 27C.
Ans :- 7.29 x 10
11
m
24. An electron beam can undergo diffraction by crystals. Through what potential should a beam of
electrons be accelerated so that its wavelength becomes equal to 1.54 ?
Ans :- 63.3 volt
25. An electron moves in an electric field with a kinetic energy of 2.5 eV. What is the associated de
Broglie wavelength?
Ans :- 7.7 x 10
8
cm
26. Calculate the uncertainty in velocity of an electron if the uncertainty in its position is of the order of
1 .
Ans :- 5.8 x 10
24
m sec
1
27. Calculate the uncertainty in velocity of a cricket ball (mass = 0.15 kg) if its uncertainty in position
is of the order of 1 .
Ans :- 3.51 x 10
24
m sec
1
28. An electron has a total energy of 2 MeV. Calculate the effective mass of the electron in kg and its
speed. Assume rest mass of electron 0.511 MeV.
Ans :- 2.9 x 10
10
cm sec
1
29. On the basis of Heisenbergs uncertainty principle, show that the electron cannot exist within the
nucleus.
Ans :- Do Yourself
30. The binding energy of electrons in a metal is 250 kJ mol
1
. What is the threshold frequency of
metal?
Ans :- 6 x 10
14
sec
1
31. What is the significance of
4, 2, 0
?
Ans :- 4d
z
2
32. Suggest the angular and spherical nodes in
a. 4p b. 3p c. 3s
Ans :- a. 1,2 b. 1,1 c. 0,2
33. The atomic masses of two isotopes of O are 15.9936 and 17.00.36. Calculate in each atom :
PHYSICAL CHEMISTRY By: Shai l endra Kumar
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Page No.: 4
a. No. of neutrons
b. No. of protons
c. No. of electrons
d. Mass no.
Ans :- Do Yourself
34. Write down electronic configuration of the following and report no. of unpaired electron in each.
a. Mn
+4
b. Cr
2+
c. Fe
+3
d. Ni
+2
e. Cl
f. Zn
+2
g. Fe
+2
h. Na i. Mg
j. Cr
+3
Ans :- Do Yourself
35. A compound of vanadium has a magnetic moment of 1.73 BM. Work out the electronic configuration
of the vanadium ion in the compound.
Ans :- Do Yourself
36. Point out the angular momentum of an electron in
a. 4s orbital b. 3 p orbital c. 4th orbit
Ans :- a. 0 b. h/ 2 c. 2h/
37. Calculate total spin, magnetic moment for the atoms having at.no. 7, 24, 34, and 36.
Ans :- Do Yourself
38. Write down the four quantum numbers for V and VI electrons of carbon atom.
Ans :- Do Yourself
39. What values are assigned to quantum number n, l, m for
a. 2s b.2p
z
c. 4d
x
2
-y
2
d. 4d
z
2?
Ans :- Do Yourself
40. An oxide of N has vapour density 46. Find the total number of electrons in its 92 g.
Ans :- Do Yourself
41. Calculate the total number of electrons in
a. 1.6 g CH
4
b. one molecule of CO
2
c. N
2
molecule.
Ans :- a. N electrons b. 22 c. 14
42.
4
Be
7
captures a K electron into its nucleus. What is the mass number and at. no. of the nucleoid
formed
Ans :- At. No. = 3; Mass no. = 7