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1. A particle is in uniform circular motion in a horizontal plane. Its angular momentum is constant when
the origin is taken at :
(A) centre of the circle (B) any point on the circumference of the circle
(C) any point inside the circle (D) any point outside the circle
2. Two particles, each of mass M, are connected a rod of negligible mass
and length L. The system is lying on a horizontal frictionless surface. An
impulse Mv, perpendicular to the rod, is given at one end of the rod as
shown in the figure. The angular velocity acquired by the rod is
(A)
L
v 4
(B)
L
v 2
(C)
L
v
(D)
L 4
v
3. A platform is revolving in horizontal plane about a fixed axis and a boy is
sitting at centre. The initial kinetic energy of system is K. If the boy stretches
his arms then moment of inertia of system becomes double. Final kinetic energy of system is :
(A) K (B)
2
K
(C)
4
K
(D) 2K
4. A disc is moving without slipping on ground then the relation between magnitude
of velocity of points P, C and Q is [distance CP =CQ]
(A) Q >C >P (B) P >C >Q
(C) C >Q >P (D) All will be same
5. A block of mass m is held fixed against a wall by a applying a horizontal
force F. Which of the following option is incorrect.
(A) friction force =mg (B) normal will not produce torque
(C) F will not produce torque (D) normal reaction =F
6. A disc has mass 9m. A hole of radius
3
R
is cut from it as shown in the figure.
The moment of inertia of the remaining part about an axis passing through the
centre O of the disc and perpendicular to the plane of the disc is :
(A) 8 mR
2
(B) 4 mR
2
(C)
9
40
mR
2
(D)
9
37
mR
2
7. A particle moves in circular path with decreasing speed. Which of the following is correct
(A) L

is constant
(B) only direction of L

is constant
(C) acceleration a

is towards the centre

(D) it will move in a spiral and finally reach the centre
8. A solid sphere of radius R has moment of inertia I about its
geometrical axis. If it is melted into a disc of radius r and thickness
t. If it's moment of inertia about the tangential axis (which is
perpendicular to plane of the disc), is also equal to I, then the value
of r is equal to :
(A)
15
2
R (B)
5
2
R
(C)
15
3
R (D)
15
3
R
e
P C
Q
a
F
2a
2a
Physics
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9. One quarter sector is cut from a uniform circular disc of radius R. This sector
has mass M . It is made to rotate about a line perpendicular to its plane and
passing through the centre of the original disc. Its moment of inertial about the
axis of rotation is :
(A)
2
1
MR
2
(B)
4
1
MR
2
(C)
8
1
MR
2
(D) 2 MR
2
10. A cubical block of side a is moving with velocity v on a horizontal smooth
plane, as shown It hits a ridge at point O. The angular speed of the block
after it hits O is .
(A)
a 4
v 3
(B)
a 2
v 3
(C)
a 2
v 3
(D) zero
11. A cubical block of side L rests on a rough horizontal surface with
coefficient of friction . A horizontal force F is applied on the block as
shown If the coefficient of friction is sufficiently high so that the block
does not slide before toppling, the minimum force required to topple the
block is L F (toppling) -
(A) Infinitesimal (B)
4
mg
(C) mg/2 (D) mg

(1 )
12. A thin wire of length L and uniform density is bent into a circular loop
with centre at O as shown. The moment of inertia of the loop about the
axis XX is
(A)

t
L
3
2
8
(B)

t
L
3
2
16
(C)
5
16
3
2

t
L
(D)
3
8
3
2

t
L
13. An equilateral triangle ABC formed from a uniform wire has two small
identical beads initially located at A. The triangle is set rotating about the
vertical axis AO. Then the beads are released from rest simultaneously
and allowed to slide down, one along AB and the other along AC as shown.
Neglecting frictional effects, the quantities that are conserved as the beads
slide down, are
(A) Angular velocity and total energy (kinetic energy and potential energy)
(B) Total angular momentum and total energy
(C) Angular velocity and moment of inertia about the axis of rotation
(D) Total angular momentum and moment of inertia about the axis of rotation
14. A smooth sphere 'A' is moving on a frictionless horizontal plane with angular speed e and centre
of mass velocity 'v'. It collides elastically and head on with an identical sphere 'B' at rest. Neglect
friction everywhere. After the collision, their angular speeds are e
A
and e
B
, respectively. Then
(A) e
A
< e
B
(B) e
A
= e
B
(C) e
A
= e (D) e
B
= e
15. A disc of mass M and radius R is rolling with angular speed e on a horizontal
plane as shown. The magnitude of angular momentum of the disc about
the origin O is
(A) (1/2)MR
2
e (B) MR
2
e (C) (3/2)MR
2
e (D) 2MR
2
e
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16. Let I be the moment of inertia of a uniform square plate about an axis AB
that passes through its centre and is parallel to two of its sides. CD is a
line in the plane of the plate that passes through the centre of the plate
and makes an angle u with AB. The moment of inertia of the plate about
the axis CD is then equal to
(A) I (B) I sin
2
u (C) I cos
2
u (D) I cos
2
(u/2)
17. A mass m is moving with a constant velocity along a line parallel to the, x-axis, away from the
origin. Its angular momentum with respect to the origin :
(A) Is zero (B) Remains constant
(C) Goes on increasing (D) Goes on decreasing
18. A hollow smooth uniform sphere A of mass m rolls without sliding on a smooth horizontal surface. It
collides elastically and headon with another stationary smooth solid sphere B of the same mass m
and same radius. The ratio of kinetic energy of B to that of A just after the collision is :
(A) 5 : 2 (B) 1 : 1 (C) 2 : 3 (D) 3 : 2
19. As shown in the figure, a disc of mass m is rolling without slipping
a angular velocity e. When it crosses point B disc will be in :
(A) translational motion only (B) pure rolling motion
(C) rotational motion only (D) none of these
20. A disc of radius R rolls on a rough horizontal surface. The linear distance
covered by the point A in one complete revolution is:
(A) 8 R (B) 4 3 R (C) 2 3 R (D) none of these
21. A large spool of rope lies on the ground as shown in the fig. The
end, labelled X is pulled a distance S in the horizontal direction.
The spool rolls without slipping. The centre of mass of the spool
moves a distance
(A) 2

S (B) S (C) S/2 (D) S/4
22. In the pulley system shown, if radii of the bigger and smaller
pulley are 2

m and 1

m respectively and the acceleration of block
A is 5 m/s
2
in the downward direction, then the acceleration of
block B will be:
(A) 0 m/s
2
(B) 5 m/s
2
(C) 10 m/s
2
(D*) 5/2 m/s
2
23. A uniform rod of length is placed symmetrically on two walls as
shown in figure. The rod is in equilibrium. If N
1
and N
2
are the
normal forces exerted by the walls on the rod then
(A) N
1
> N
2
(B) N
1
> N
2
(C) N
1
= N
2
(D) N
1
and N
2
would be in the vertical directions. N
1
N
2
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24. Four forces tangent to the circle of radius R are acting on a
wheel as shown in the figure. The resultant equivalent one force
system will be :
(A) (B) (C) (D)
25. A square plate of edge a/2 is cut out from a uniform square
plate of edge 'a' as shown in figure. The mass of the
remaining portion is M. The moment of inertia of the
shaded portion about an axis passing through 'O' (centre
of the square of side a) and perpendicular to plane of the
plate is :
(A)
64
9
Ma
2
(B)
16
3
Ma
2
(C)
12
5
Ma
2
(D)
6
Ma
2
26. Moment of inertia of a disc about O

O' is:
(A)
3
2
2
mr
(B)
mr
2
2
(C)
5
2
2
mr
(D)
5
4
2
mr
O O
m
r
27. A uniform rectangular plate of mass m which is free to rotate
about the smooth vertical hinge passing through the centre and
perpendicular to the plate, is lying on a smooth horizontal surface.
A particle of mass m moving with speed 'u' collides with the plate
and sticks to it as shown in figure. The angular velocity of the
plate after collision will be :
(A)
a
u
5
12
(B)
a
u
19
12
(C)
a
u
2
3
(D)
a
u
5
3
28. A body of mass m and radius r is rotated with angular velocity e
as shown in the figure & kept on a surface that has sufficient
friction then the body will move :
(A) backward first and then move forward
(B) forward first and then move backward
(C) will always move forward
(D) none of these
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29. A sphere of mass '

m' is given some angular velocity about a
horizontal axis through its centre and gently placed on a plank of
mass '

m'. The co-efficient of friction between the two is . The
plank rests on a smooth horizontal surface. The initial acceleration
of the centre of sphere relative to the plank will be :
(A) zero (B) g (C) (7/5) g (D) 2 g
30. A small block of mass m is rigidly attached at P to a ring of mass 3m
and radius r. The system is released from rest at u = 90 and rolls
without sliding. The angular acceleration of ring just after release is
(A)
r 4
g
(B)
r 8
g
(C)
r 3
g
(D)
r 2
g
31. An ellipse and a hyperbola have the same centre origin, the same foci and the minor-axis of the
one is the same as the conjugate axis of the other. If e
1
, e
2
be their eccentricities respectively,
then
1 1
1
2
2
2
e e
+ =
(A) 1 (B) 2 (C) 4 (D) none
32. The line 5x + 12y = 9 touches the hyperbola x
2
9y
2
= 9 at the point
(A) ( 5, 4/3) (B) (5, 4/3) (C) (3, 1/2) (D) none of these
33. If the foci of the ellipse
x y
b
2 2
2
25
+
= 1 & the hyperbola
x y
2 2
144 81
=
1
25
coincide then the value of b
2
is :
(A) 4 (B) 9 (C) 16 (D) none
34. If hyperbola
2
2
b
x

2
2
a
y
=1 passes through the focus of ellipse se
2
2
a
x
+
2
2
b
y
=1 then eccentricity of
hyperbola is
(A)
2
(B)
3
2
(C)
3
(D) None of these
35. Two conics
2
2
a
x

2
2
b
y
=1 and x
2
=
b
1
y intersect if
(A) 0 < b s
2
1
(B) 0 < a <
2
1
(C) a
2
< b
2
(D) a
2
> b
2
Mathematics
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36. If both roots of the quadratic equation x
2
+ x + p = 0 exceed p where p e R then p must lie in
the interval:
(A) (

, 1) (B) (

,

2) (C) (

,

2) (0, 1/4) (D) (

2, 1)
37. If o, | & are the roots of the equation, x
3
x 1 = 0 then,
o
o +
1
1
+
|
| +
1
1
+

+
1
1
has the value
equal to:
(A) zero (B)

1 (C)

7 (D) 1
38. If the distance between the focii of an ellipse is equal to the length of its latus rectum, the
eccentricity of the ellipse is :
(A)
2
1 5 +
(B)
2
1 5
(C)
2
2 5
(D)
3
2
39. An ellipse has OB as semi-minor axis, F and F' its foci and the angle FBF' is a right angle. Then, the
eccentricity of the ellipse is
(A)
4
1
(B)
3
1
(C)
2
1
(D)
2
1
40. The angle between the tangents drawn from the point (1, 4) to the parabola y
2
=4x is
(A)
2
t
(B)
3
t
(C)
4
t
(D)
6
t
41. Let P be the point (1, 0) and Q a point of the locus y
2
= 8x. The locus of mid point of PQ is
(A) x
2
+4y +2 =0 (B) x
2
4y +2 =0 (C) y
2
4x +2 =0 (D) y
2
+4x +2 =0
42. The set of values of 'b' for which the origin and the point (1, 1) lie on the same side of the
straight line, a
2
x + a

by + 1 = 0 a e R, b > 0 are :
(A) b e (2, 4) (B) b e (0, 2) (C) b e [0, 2] (D) (2, )\
43. The lines ax + by + c = 0, where 3a + 2b + 4c = 0 are concurrent at the point :
(A)
|
.
|

\
|
4
3
,
2
1
(B) (1, 3) (C) (3, 1) (D)
|
.
|

\
|
2
1
,
4
3
44. Drawn from the origin are two mutually perpendicular straight lines forming an isosceles trian
gle together with the straight line, 2x + y = a. Then the area of the triangle is :
(A)
a
2
2
(B)
a
2
3
(C)
a
2
5
(D) none
45. If
B sin
A sin
=
2
3
and
B cos
A cos
=
2
5
, 0 < A, B <t/2, then tan A + tan B is equal to
(A) 5 / 3 (B) 3 / 5 (C) 1 (D) 5 / ) 3 5 ( +
46. If sin 2u = k, then the value of
u +
u
2
3
tan 1
tan
+
u +
u
2
3
cot 1
cot
is equal to
(A)
k
k 1
2

(B)
k
k 2
2

(C) k
2
+ 1 (D) 2 k
2
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47.
290 cos
1
+
250 sin 3
1
=
(A)
3
3 2
(B)
3
3 4
(C)
3
(D) none
48.
n
Limit
( )! ( ) !
( )!
n n
n
+ + +
+
2 1
3
, n e N =
(A) 0 (B) 1 (C) 2 (D) 1
49.
3 x
Limit

) 9
2
x (
) 2 x ( ln ) 27 x (
3

+
=
(A) 8 (B) 8 (C) 9 (D) 9
50.
1 x
Limit

1 x
100 x
100
1 k
k

=
=
(A) 0 (B) 5050 (C) 4550 (D) 5050
51. The value of
|
|
.
|

\
|
0
50
|
|
.
|

\
|
1
50
+
|
|
.
|

\
|
1
50
|
|
.
|

\
|
2
50
+...........+
|
|
.
|

\
|
49
50
|
|
.
|

\
|
50
50
is, where
n
C
r
=
|
|
.
|

\
|
r
n
(A)
|
|
.
|

\
|
50
100
(B)
|
|
.
|

\
|
51
100
(C)
|
|
.
|

\
|
25
50
(D)
2
25
50
|
|
.
|

\
|
52. (1 + x) (1 + x + x
2
) (1 + x + x
2
+ x
3
)...... (1 + x + x
2
+...... + x
100
) when written in the ascending
power of x then the highest exponent of x is
(A) 505 (B) 5050 (C) 100 (D) 50
53. If
|
.
|

\
|
a
1
, a
,
|
.
|

\
|
b
1
, b
,
|
.
|

\
|
c
1
, c
&
|
.
|

\
|
d
1
, d
are four distinct points on a circle of radius 4 units then, abcd
is equal to:
(A) 4 (B) 16 (C) 1 (D) none
54. The centre of a circle passing through the points (0, 0), (1, 0) & touching the circle x
2
+ y
2
= 9 is:
(A)
|
.
|

\
|
2
1
,
2
3
(B)
|
.
|

\
|
2
3
,
2
1
(C)
|
.
|

\
|
2
1
,
2
1
(D) |
.
|

\
|
2 ,
2
1
55.
}

n x
x n x
| |
| | 1+
dx equals :
(A)
2
3
1+ n x
(n|x| 2) + c (B)
2
3
1+ n x
(n|x|

+ 2) + c
(C)
1
3
1+ n x
(n|x| 2) + c (D) 2 1+ n x (3 n|x| 2) + c
56.
}
' ' ' ' )] x ( g ) x ( f ) x ( g ) x ( f [ dx is equal to
(A)
) x ( g
) x ( f
'
(B) f'(x) g(x) f(x) g'(x)
(C) f(x) g'(x) f'(x) g(x) (D) f(x) g'(x) + f'(x) g'(x)
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57. If a
1
, a
2
,... a
n
are in A.P. with common difference d 0, then the sum of the series
(sin d) [cosec a
1
cosec a
2
+ cosec a
2
cosec a
3
+ ... + cosec a
n1
cosec a
n
]
(A) sec a
1
sec a
n
(B) cosec a
1
cosec a
n
(C) cot a
1
cot a
n
(D) tan a
1
tan a
n
58. The sum of the series
4 log
1
2
+
4 log
1
4
+
4 log
1
8
+ ...... +
4 log
1
n
2
is
(A)
2
1
n (n + 1) (B)
12
1
n (n + 1) (2n + 1)
(C)
) 1 n ( n
1
+
(D)
4
1
n (n + 1)
59. Let z
1
, z
2
, z
3
be three distinct complex numbers satisfying z
1
- 1 =z
2
- 1 =z
3
- 1.
If z
1
+z
2
+z
3
=3 then z
1
, z
2
, z
3
must represent the vertices of :
(A) an equilateral triangle (B) an isosceles triangle which is not equilateral
(C) a right triangle (D) nothing definite can be said
60. 1 1 1....... is equal to :
(A) w or w
2
(B) - w or - w
2
(C) 1 +i or 1 - i (D) - 1 +i or - 1 - i
where

w

is the imaginary cube root of unity and i = 1
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62. The reaction CH
4
(g) +Cl
2
(g)

CH
3
Cl(g) +HCl(g) has DH =25 kCal.
From the given data, what is the bond energy of ClCl bond
(A) 70 kCal (B) 80 kCal (C) 67.75 kCal (D) 57.75 kCal
63. If x
1
, x
2
and x
3
are enthalpies of HH, O=O and OH bonds respectively, and x
4
is the enthalpy
of vaporisation of water, estimate the standard enthalpy of combustion of hydrogen
(A) x
1
+
2
x
2
2x
3
+x
4
(B) x
1
+
2
x
2
2x
3
x
4
(C) x
1
+
2
x
2
x
3
+x
4
(D) 2x
3
x
1

2
x
2
x
4
64. D
r
H of which of the following reactions is zero?
(A) H
2
(g) 2H
+
(g) +2e

(B) 2H(g) +aq 2H

+
(aq) +2e

(C) 2H(g) 2H
+
(g) +2e

(D) H
2
(g) +aq 2H
+
(aq) +2e

65. Ethanol can undergoes decomposition to form two sets of products

C
2
H
5
OH (g)
if the molar ratio of C
2
H
4
to CH
3
CHO is 8 : 1 in a set of product gases, then the energy
involved in the decomposition of 1 mole of ethanol is
(A) 65.98 kJ (B) 48.137 kJ (C) 48.46 kJ (D) 57.22 kJ
61. From the following data at 25C
Reaction D
r
H kJ/mol
2
1
H
2
(g) +
2
1
O
2
(g) OH (g) 42
H
2
(g) +
2
1
O
2
(g) H
2
O(g) 242
H
2
(g) 2H(g) 436
O
2
(g) 2O(g) 495
Which of the following statement(s) is/are correct:
Statement (a) : D
r
H for the reaction H
2
O (g) 2H(g) +O(g) is 925.5 kJ /mol
Statement (b) : D
r
H for the reaction OH(g) H(g) +O(g) is 502 kJ /mol
Statement (c) : Enthalpy of formation of H(g) is 218 kJ /mol
Statement (d) : Enthalpy of formation of OH(g) is 42 kJ /mol
(A) Statement c (B) Statement a, b, d (C) Statement b, c (D) Statement a, d
Chemistry
Bond
Bond
Energy
kCal
|CCl 84
|HCl 103
|CH x
|ClCl y
x : y =9 : 5
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67. The bond order of nitric oxide is
(A)
1
2
2
(B) 2
(C) 3 (D)
1
1
2
68. Hydrogen fluoride is a liquid unlike other hydrogen halides because
(A) HF molecules combine by hydrogen bonding
(B) F
2
is highly reactive
(C) F atom has a high electron affinity
(D) HF is a weak acid
69. A NH
3
molecule attaches itself to a hydrogen ion leading to the formation of NH
4
+
by
(A) an electrovalent bond (B) a coordinate bond
(C) a covalent bond (D) a hydrogen bond
70. A molecule will be stable if the value of bond order is
(A) zero (B) positive
(C) negative (D) bond order has no correlation with stability
71. Which of the following does not show resonance?
(A) NO
3

(B) C
6
H
6
(C) CO
3
2
(D) SiO
2
72. Which of the following has the smallest bond length?
(A) O
2
(B) N
2
(C) Cl
2
(D) HCl
73. Which of the following bonds can be dissociated most easily?
(A) OO (B) CC
(C) NN (D) HH
74. Two atoms X and Y have an electronegativity difference equal to 2.0. What will be the percentage of
covalent character in the molecule?
(A) 46% (B) 54%
(C) 72% (D) 23%
75. The dipole moment of a XY molecule is 1.03 D. If the XY bond distance is 1.26A, what is the
percentage of ionic character in the XY bond?
(A) 39% (B) 60%
(C) 17% (D) 29%
76. In which of the following molecules resonance is equivalent :
(A) HCOO
Q
(B) CH
2
=CH CH =CH
2
(C) (D)
66.
0
f
H A of water is 285.8 kJ mol
1
. If enthalpy of neutralisation of monoacid strong base is
57.3 kJ mol
1
,
0
f
H A of OH

ion will be
(A) 228.5 kJ mol
1
(B) 228.5 kJ mol
1
(C) 114.25 kJ mol
1
(D) 114.25 kJ mol
1
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77. CH
3
O CH =CH NO
2
I
CH
2
=CH NO
2
II
CH
2
=CH Cl III
CH
2
=CH
2
IV
Which of the following is the correct order of C C bond lengths among these compounds :
(A) I >II >III >IV (B) IV >III >II >I (C) I >III >II >IV (D) II >III >I >IV
78. Which of the following has longest C O bond :
(A) (B) (C) (D)
79. The IUPAC name of CH
2
CHC(CH
3
)
2
OH
CH(CH
3
)
2
is
(A) 1-phenyl-3, 4, dimethyl butanol (B) 4-phenyl-3-di-2-methyl butanol
(C) 3-benzyl-2, 4-dimethyl -2-pentanol (D) 4-benzyl-3di-2 methyl-2-butanol
80. Which of the following compounds can exhibit tautoimerism :
(A) (B) (C) (D)
81. In a compound
C =C
the number of sigma and pi bonds respectively are
(A) 19, 11 (B) 19, 5 (C) 13, 11 (D) 7, 3
82. Which of the following arrangements of electrons in mostly likely to be stable:
(A) (B)
(C) (D)
83. The electrons, identified by quantum by numbers n and
l
, (i) 1 , 4 = = l n (ii) 0 , 4 = = l n
(iii) 2 , 3 = = l n (iv) 1 , 3 = = l n can be placed in order of increasing energy, from the lowest to highest,
as
(A) (iv) <(ii) <(iii) <(i) (B) (ii) <(iv) <(i) <(iii)
(C) (i) <(iii) <(ii) <(iv) (D) (iii) <(i) <(iv) <(ii)
84. Which electron level would allow the hydrogen atom to absorb a photon but not emit a photon
(A) 3s (B) 2p (C) 2s (D*) 1s
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85.
Hydrogenation of the above compound in the presence of poisoned paladium catalyst gives
(A) An optically active compound (B) An optically inactive compound
(C) A racemic mixture (D) A diastereomeric mixture
86. Consider the following reactions
3
3 3
CH D
| |
CH CH CH C H + X +HBr
Identify the structure of the major product X
(A)
3
2

3
CH D
| |
H C CH CH C H
(B)
3
3

3
CH D
| |
CH C CH C H
(C)
3
3

3
CH D
| |
CH CH C C H (D)
2
3

3
CH
|
CH CH H C C H
87. Which one of the following alkenes will react fastest with H
2
under catalytic hydrogenation condition
(A) (B) (C) (D)
88. According to Graham's law , at a given temperature the ratio of the rates of diffusion
B
A
r
r


of gases A A
and B is given by :
(A)
B
A
P
P

2 / 1
B
A
M
M
|
|
.
|

\
|
(B)
|
|
.
|

\
|
B
A
M
M

2 / 1
B
A
P
P
|
|
.
|

\
|
(C)
B
A
P
P

2 / 1
A
B
M
M
|
|
.
|

\
|
(D)
B
A
M
M

2 / 1
A
B
P
P
|
|
.
|

\
|
89. Which one of the following V, T plots represents the behaviour of one mole of an ideal gas at one
atmp?
(A) (B) (C) (D)
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90.
where Z =
nRT
PV
,
a =Van der Waal's constant for pressure correction
b =Van der Waal's constant for volume correction
Pick the only incorrect statement
(A) for gas A, if a =0, the compressibility factor is directly proportional to pressure
(B) for gas B, if b =0, the compressibility factor is directly proportional to pressure
(C) for gas C, a 0, b 0, it can be used to calculate a and b by giving lowest P value and its
intercept with Z =1.
(D) slope for all three gases at high pressure (not shown in graph) is positive.
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