ANACHEM (Analytical Chemistry Lecture)

LONG EXAM #1 REVIEWER

Name: _______________________________________________ ID Number: _________________
Section: ___________________________ Degree Program: CHE Professor: Dr. Julita C. Robles

INSTRUCTIONS:
1. Do not criticize the creator of this reviewer for his intention is only to help the students (as well as
himself) in ANACHEM LE 1. Do not hesitate to tell me if there are discrepancies or mistakes.
2. Answer all items as fast as you can.
3. Follow all instructions announced or taught in the lecture class.
4. Do not distribute in any way (electronically or manually) without the permission of the creator of
the reviewer.
5. The reviewer only focuses on concepts. Answer the problems in book to gain confidence for the
exam.
Good luck to us guys!
Bernard Jomari B. Razote
--START OF REVIEWER--
1. In classifying the chemicals used in the laboratory, how would you determine if it is an AR
Grade? What are the requirements? (3 pts)

2. What is the purpose of the primary standard grade in the titrimetic method of analysis?
a. It will catalyze the reaction
b. It will serve as the indicator in the reaction
c. It will serve as a reference material
d. None of the above
3. The reagents used for pharmaceutical purposes are called USP Grade Reagents. What
does the USP stand for?
a. United States Pharmacopoeia
b. United States Pharmacies
c. United States Pharmaceutical
d. Universal Sovereign of Pharmacists
4. It is the type of glassware used for the preparation of standard solutions. It cannot be
used for storing solutions.
a. Analytical Balance
b. TC Glassware
c. TD Glassware
d. Auxiliary Balance
5. Enumerate at least three apparatuses used for the precise measurement of volume (3
pts).

6. It refers to the number of moles of solute dissolved per liter of solution.
a. Molarity
b. Density
c. Specific Gravity
d. Normality
7. In the Experiment 2 in LBYCH26, you were asked to obtain a 25.00-mL sample of acetic
and dilute to 250-mL in the volumetric flask. If you were to follow instructions, what
should be the volume inside the volumetric flask?
a. 225 mL
b. 250 mL
c. 275 mL
d. 300 mL
8. What is the correct representative unit if you were asked the percentage weight per
volume of the sample?
a. mg/mL
b. g/mL
c. g/L
d. mg/L
9. It is defined as the ratio of the mass of a substance to the mass of an equal volume of
water.
a. Molarity
b. Density
c. Specific Gravity
d. Normality
10. It refers to the decrease in the concentration of the solution by a certain factor.
a. Dilution
b. N-fold Dilution
c. Dilute Sample Solution
d. Aliquot Portion
For items 11-13, please refer to the given problem.
Potassium hydrogen phthalate, KHC
8
H
4
O
4
(M.M=204.23), is a primary standard acid that
reacts with sodium hydroxide on a 1:1 molar basis. Results show that 0.5893 g of primary
standard grade KHC
8
H
4
O
4
required 22.49 mL to reach the phenolphthalein end point. Find
the molarity of the NaOH solution.
11. The analyte in the problem is _________.
a. Sodium Hydroxide
b. Potassium Hydrogen Phthalate
c. Phenolphthalein
d. Unknown Acid
12. The titrant in the problem is _________.
a. Sodium Hydroxide
b. Potassium Hydrogen Phthalate
c. Phenolphthalein
d. Unknown Acid
13. The given problem is an example of what type of titration?
a. Direct
b. Indirect
c. Back
d. Kjeldahl
14. How many significant figures should the final answer contain?
a. 2 sig. figs
b. 3 sig. figs
c. 4 sig. figs
d. 5 sig. figs
15. Volumetric Titrimetry: Buret; ____________: Analytical Balance
a. Gravimetric Titrimetry
b. Coulometric Titrimetry
c. Potentiometry
d. Iodometry
16. It is the type of titrimetry in which the quantity of charge required to complete a reaction
with the analyte is measured.
a. Potentiometry
b. Gravimetric Titrimetry
c. Volumetric Titrimetry
d. Coulometric Titrimetry
17. True or False: The equivalence point of the titration is the one obtained from the actual
experiment.
a. True
b. False
c. The argument is invalid.
d. Not enough information given
18. It is the point in a titration when a physical change occurs that is associated with the
condition of chemical equivalence.
a. End point
b. Equivalent point
c. Equivalence point
d. Equipotential point
19. It is added to the analyte solution to give an observable physical change at or near the
equivalence point.
a. Colorant
b. Indicator
c. pH meter
d. KHP
20. What are the important requirements for a primary standard? Name at least three. (5 pts).
21. Why is sodium hydroxide not suitable to be a primary standard? Give at least two
conditions that show NaOH is not a primary standard (5pts).
22. It is a compound whose purity has been established by chemical analysis and that serves
as the reference material for a titrimetric method of analysis.
a. Primary standard
b. Secondary stand
c. Standard solution
d. Tertiary standard
23. It is a reagent of known concentration that is used in a titrimetric analysis.
a. Primary standard
b. Secondary standard
c. Standard solution
d. Tertiary standard
24. Convert 0.100 M H
2
SO
4
to normality.
a. 0.100 N
b. 0.050 N
c. 0.200 N
d. 1.00 N
25. Which of the following describes an indirect titration reaction?
a. aA + Tt pP
b. aA + rR pP
dP + tT fF
c. rR + aA pP
xR + tT nN
d. None of the above
26. In Kjeldahl method, what should be contained in the acid-trap solution for it to be
classified as an indirect titration?
a. Boric Acid
b. Hydrogen Peroxide
c. Sulfuric Acid
d. Hydrochloric Acid
27. From the aliquot portion obtained from the DSS, what conversion factor should be used
in order to calculate the total moles present in the volumetric flask (VF),?
a.



b.



c.



d.



28. What do you call the mark present in the volumetric flask which serves as the indicator
on where you should stop adding distilled water?
a. Neck mark
b. Aliquot mark
c. Etched mark
d. Superimposed mark
29. What element is being analyzed in the Kjeldahl method?
a. Sulfur
b. Nitrogen
c. Boron
d. Iodine
30. True or false: The concentration of the analyte in the volumetric flask is the same as the
concentration of the analyte in the aliquot portion.
a. True
b. False
c. The argument is invalid.
d. Not enough information given
--END OF REVIEWER--