10 VMC/Theory of Solutions Solutions to HWT-4 /Chemistry

Vidyamandir Classes
1.(C) Total mass = 120 + 1000 = 1120 g
mL
1120
V
1.15
| |
=
|
\ .
Molarity =
120 60
1000 2.05M
1120 1.15
=
2.(C) CH OH
3
n 5.2 =
Weight (g) of water = 1000 g H O
2
1000
n
18
=

CH OH
3
5.2
0.086
1000
5.2
18
_ = =
+
3.(B)
3 3
water
1kg/ dm 0.3dm 0.3kg = =
Also urea
0.01
n
60
| |
=
|
\ .
Molarity =
4
0.01 1
5.55 10
60 (0.3)

=
4.(C) PV = n
T
RT
T
41 1 n 0.082 500 =
n
T
= 1
2 6 2 2 2
7
C H O 2CO 3H O
2
+ +
x (7/2x)
2 4 2 2 2
C H 3O 2CO 2H O + +
(1 x) (1 x)
3
7 10
x 3 3x
2 3
+ =
Moles of ethane
2
x
3
= Moles of ethane
1
3
=
% _
Ethane
=
2
0.67
3
=
_
Ethene
= 1 0.67 = 0.33
5.(D) Non-polar Benzene in water
6.(A) _H = 1.0 10
5
atm.
N H N
2 2
P ( ) = _ _ Dissolved
0.8 5 = 1.0 10
5
N
2
( ) _
5
N
2
4 10

_ =
H
2
n 10 =

N
5 4 2
N
2
4 10 n 4 10
10

_
= =
7.(B) 500 g solution contain 10% of NaOH
8.(A) Compare it by formula
0
100 M
m
1000d M
=

9.(C) With | on + in temperature neither moler or mass of solvent

changes.
10.(C)
29 1000
3.6
98 100
| |
=
|
| |
\ .
|

\ .
= 1.22
11.(C) n = 2.05 V = 1000 ml
Mass = V = 1020 gm
3
CH COOH
M 60 = ;
3
CH COOH
m 60 2.05 = = 123 gm
Molality =
2.05
2.28 mol / kg
0.897
=
12.(C) For
3
3
3
25 10 gm
CaCO 5 ppm
5 10 ml

= =

13.(D) 17.4 ppm means.

17.4 gm per 10
6
parts
17.4 mg per 10
3
parts of 1 L
3
4
17.4 10 1
M 2 2 10
174 1

= =
14.(B) M
1
V
1
+ M
2
V
2
= M
T
V
T
M
T
1000 = 480 1.5 + 1.2 520
M
T
= 1.344 M
15.(B) Moles = 10
3 3 2
1000
M 10 10
100

= =
HWT - 1 Theory of Solutions
2-SOLUTIONS-HWT-4-Theory of Solutions.pmd 18-06-2014, 17:08 10
11 VMC/Theory of Solutions Solutions to HWT-4 /Chemistry
Vidyamandir Classes
1.(D) Theory 2.(A) A B > A ~ A of B ~ B
3.(A) n
Heptane
=
25
0.25
100
=
n
Octane
=
35
0.30
114
=
_
Heptane
=
0.25
0.448
0.30 025
=
+
P = 105(0.448) + (1 0.448) 45
= 45 + 60 0.448 = 71.92 ~ 72
4.(C)
x Y
P 3P
550
4 4

+ =
X
Y
P 4
P 560
5 5

+ =
6
X Y
P 400 P 600

= , =
5.(B) n - Heptane breaker H - bonds b/w C
2
H
5
OH molecules.
6.(D) Has to be ideal solution.
7.(C) 520 _
A
+ 1000(1 _
A
) = 760
240 = 480 _
A
_
A
= 1/2 or 50%
8.(C)
X Y
P P
400
2 2

= + ;
X Y
P 2P
350
3 3

= +
6
X Y
P 550 mm P 250

= , =
HWT - 2 Theory of Solutions
9.(A) 0.6 P + 0.4 200 = 290
P = 350
10.(C) Apply Hesss Law
11.(D)
Ben
78
n 1
78
= =
Tol
46
n 0.5
94
= ~
Banzene
75 1
P 50
1.5

= =
12.(A) Let Weight = x.

x x
P
MA 4MA
+ =
x P
4MA 5
=
13.(A) Refer theory
14.(B) Benzene breaks H-bonds in methanol
15.(A) Refer theory
1.(A) AT
f
= ik
f
m =
0.1/ m
4 1.86
100
1000

= 2.3 10
2
K
HWT - 3 Theory of Solutions
2.(A) Use AT
f
= ik
f
m
m
6 i 1.86
62
4

m = 804 . 32 g.
3.(C) t = iCRT
t
1
= t
2
4.(A) Adding a non-volatile solute increase the Boiling point and
decrease the freezing point.
5.(A) Use t = iCRT
i = max for Al
2
(SO
4
)
3
7.(D) AT
b
= iK
b
m
i = 5 for K
4
[Fe(CN)
6
]. Hence the boiling point will be
highest
9.(D) Calculate relative lowering and hence AP.
Use
B
A
P
i
P

A
= _
12.(B) AT
f
= iK
f
m
0.37 = 2 K
f
0.01
x = 2 K
f
0.02
0.37 1
x 2
=
x = 0.74C
13.(B) Blood cells do not shrink in blood because blood is isotonic.
14.(A) Use t = iCRT
15.(A) Highest boiling point will be for 0.1M FeCl
3
Use ATb = iK
b
m.
2-SOLUTIONS-HWT-4-Theory of Solutions.pmd 18-06-2014, 17:08 11
12 VMC/Theory of Solutions Solutions to HWT-4 /Chemistry
Vidyamandir Classes
HWT - 4 Theory of Solutions
1.(B) As we know lowering of V.P. will be proportional to i.
So maximum lowerting will be observed when i is maximum.
2.(B) Use AT
f
= iK
f
m.
4.(B) P = iCRT
P = C 600 RT
2 = C/2 700 RT
P 6
2
2 7
=
24
P atm
7
=
5.(B) t = iCRT
68.4
1 0.082 273
342
1
= = 4.48 atm
9.(D) AT
f
= iK
f
m
There will be some lowering hence freezing point will be
below 0C
10.(D) Equimolar solutions have same boiling and same freezing
points.
11.(C) Use strength = MM
0
Use t = CRT
Hence osmotic pressure of solution B is greater than A
13.(A) Adding a non-voltatile solute decrease the F.P. and increase
the B.P.
14.(A) i = 4 for FeCl
3
.
15.(A) Maximum freezing point falls in comphor.
HWT - 5 Theory of Solutions
1.(B) Since t = iCRT
i will have a larger value for KNO
3
. Since it is a strong
electrlyte, while CH
3
COOH is a weak acid.
Hence P
1
> P
2
2.(A) As we know
B
A
P
P

A
=_
3.(C) AT
f
= iK
f
m
i = 1 for glucose. So depression in freezing point will be
lowest.
Hence freezing point will be highest.
4.(A)
x y
A B xA yB
1 0 0
1 x y
+
o o o

i = 1 o + xo + yo
i = 1 + o | x + y 1)

i 1
x y 1

o =
+
5.(B) Use AT
f
= iK
f
m
K
f
= 1.86
m = 1 mole
i = 3
6.(A)
7.(A) Use AT
f
= i K
f
m
8.(D)
2
2(Ph OH) (Ph(OH)
1 0
1
2

o
o

i 1
2
o
=
10.(B)
2
2 4 4
Na SO 2Na SO
1 0 0
1 2
+
+
o o o
11.(A) i
1
C
1
= i
2
C
2
(1 + 2o) 0.004 = 1 0.01
o = 0.75
13.(D) Intermolecular forces after mixity are weaker than before
mixing.
14.(D) nA An
1 0
1
n
o
o

i 1
n
1
i 1 1
n
o
= o +
| |
= +
|
\ .
2-SOLUTIONS-HWT-4-Theory of Solutions.pmd 18-06-2014, 17:08 12