5.

3 questions ms

1. (a) gains electrons (1) 1
[1]

2. (a) (i) Fe
2+
1
(ii) F
2
O 1
(iii) Fe
2+
1
Cl

1
Use list principle if more than two answers
(b) (i) e.m.f. = E(rhs) E(lhs) 1
= 1.52 0.77 = 0.75
(0.75 scores first mark also) 1
(ii) Fe
2+
Fe
3+
+ e

1
(iii) ecrease 1
(Increase is CE, no further marks)
!"#ilibri#m (or reaction) shifts to $ 1
(or L if refers to half equation in tale)
(or in fa!our of more "e
#$
)
(or more "e
#$
forme%)
(or more electrons forme%)
!lectro%e &otential (for Fe
3+
'Fe
2+
) less &ositi(e (or

%ecreases) 1
[10]
3. (a) Fe
2+
or Fe())) 1
(b) (i) * or (+)) 1
(ii) 3 or ()))) 1
(c) (i) 0.5 1
(ii) 2,n
2+
+ -.
2
O + 5/
2
O
2
-
10/O
2
0
+ 2,nO

0
+ 1*.
+
1oth /O
2
0
an% ,nO

0
on right 1
1alance% 1
[13]
4. (a) (i) 0.*0 + 1
(ii)
2
0 3 2 2
2e 0. /O /O . O . + + +
+
1

Mill Hill High School 1
(b) (i)
O *. ) 5O O 5. 2. )O 2
2 2 2 2 2

3
+ + +
+
Species 1
1alance% 1
(ii) 2he concentration of the ions change or are no longer stan%ar% or
the e.m.f is %etermine% 3hen no c#rrent flo3s 1
(iii) 4nchange% 1
(i() )ncrease% 1
!"#ilibri#m
2

3
') )O
%is&lace% to the right 1
!lectrons more rea%il5 acce&te% or more re%#ction occ#rs
or electro%e becomes more &ositi(e (6 o 7) 1
(c)
+
2
+O
1
5 or + 1

2 2
2
3e 0. +O O 2. +
+ + +
+ +
1
[12]

5. (a) Oxidising agents take/remove/accept/gain electrons (1)
&ot 'electron pair( 1
(b) (i) Cl
2
(g) at 100 89a ' 1 bar ' 1atm (1)
:Cl

; = 1 molar ' 1, (1)

)llow *+ ,Cl
2em&erat#re = 2<-= ' 25>C (1)
o not #se list &rinci&le for other incorrect s&ecies
(ii) 7o3er :Cl

; or re%#ce tem&erat#re
)ncrease &ress#re or concentration of Cl
2
(1)
CE if chan-e incorrect
!"#ilibri#m %is&lace to right (1)
or if re%#ce% tem&erat#re gi(en? reaction e@othermic
Allo3 a correct e@&lanation 3hen no change gi(en 5
(c) (i) Cl

(1)
(ii) Fe
3+
B (1) CO
3

(1)
.enalise / list principle
&ote0 ,
$
is incorrect
(iii) +
2+
? (1) Fe
2+
(1)
.enalise / list principle 5
[11]
6. (a) (/tan%ar%) h5%rogen (electro%e) (1) 1

Mill Hill High School 2
(b) (i) To allow transfer of electrons / provide a reaction surface (1)
(ii) 2<- = (1)
1oth F
3+
(a") an% Fe
2+
(a") ha(e a concentration of 1 mol %m
3
(1) (6o7)
O$ :.
+
; = 1 mol %m
3

NOT zero current or 100 kPa
3
(c) +1.30 + (1)
2 ,nO
0

+ 5 .
2
/O
3
2 ,n
2+
+ 5 /O
0
2
+ 3 .
2
O +0 .
+
Correct s&ecies ' or%er (1)
1alance% an% cancelle% (1)
Allow one for 2 MnO
4

+ 5 H
2
O
3
2 Mn
2+
+ 5 O
4
2
3
(%) (i) Ce
0+
(a") (1)
(ii) +O
2
+
(a") (1)B Cl
2
(1)
Penal!"e a##!t!onal an"wer" to zero
3
(e) 9t D Fe
2+
(a")? Fe
3+
(a") DD Ce
0+
(a")? Ce
3+
(a") D 9t
Correct s&ecies (1)
Correct or%er (1)
$e#uct one %ark for eac& error
2
[12]

7. (a) Cell e.m.f.E 1.<3 (() C! if negati(e (al#e gi(en (1)
,alf equationE ,g ,g
2+
+ 2 e

(1)
or
'(nore "tate ")%*ol"
Mark on after an A+
2
(b) Chan-e in e.m.f.E increases (1)
Mark on e,en !f !ncorrect
E1planationE !"#ilibri#m %is&lace% to ,g
2+
or to the left (1)
cell react!on or o,erall react!on (oe" to t&e r!(&t
+lectro#e !" %ore ne(at!,e or + #ecrea"e"
or (!,e" %ore electron
or for%" %ore M(
2+
!on"
Mark "e-aratel)
3
Mill Hill High School 3
(c) Cell e.m.f. : !"# ($) (1)
E1planationE Fe is gi(ing electrons or forming Fe
2+
or reaction goes in the re(erse %irection (1)
Mark on after A+
2
N./. 'n 0a1 an# 0c1 %ark on !f no ,alue (!,en2
*ut 3+ !n *ot& 0a1 an# 0c1 !f e.%.f. 4 0
[5]
8. (a) (i) (stan%ar%) h5%rogen (electro%e) ' h5%rogen half cell not
h5%rogen cell (1)
reference electro%e ' electro%e to 3hich others are com&are% (1) 2
(ii) 0.00(+) ' 0 ' Fero (1) 1

(b) (i) emf = 0. 10 (0.25)
= + 0.11 + ' allo3 0.11+ not 0.11+ (1)
1
(ii) electro%e ' /n
2+
'/n 'tin ' right han% electro%e (1) 1
(iii) Ci + /n
2+
Ci
2+
+ /n (ignore state s5mbols) (1) 1
(c) (i) e.m.f = 0.00 (0.10) = 0.30 (+) ' emf for cell is (e
com&arison of stan%ar% electro%e &otentials (1)
+(e e.m.f for feasible reaction ' tin is a 3ea8er re%#cing agent
3o#l% not occ#r (1)
if correct 2 arg#ment #se%? allo3 both mar8s 2

(ii) manganese 3ill %ecrease in siFe ' %isa&&ear ' eaten a3a5 ' %issol(es '
sol#tion t#rns (&ale) &in8 (1)
effer(escence ' b#bbles (of colo#rless gas) ' fiFFing not gas
gi(en off (1)
reaction li8el5 to occ#r is ,n + (2).
+
,n
2+
+ .
2
(1)
or the same i%eas e@&resse% in 3or%s
+(e e.m.f. ' +1.1- + ' ,n is strong re%#cing agent ' has
large (e E
( )
(1)
(not G#st ,n is more reacti(e) 0
[12]
9. (a) o@i%ising agent acce&ts electrons (1) 1
Mill Hill High School 4
(b) Stronger oxidising agent %
&
(1)
Equation ( ) ( ) ( ) ( ) g . a" g a" .
(g) e (a")
(g) . e (a") .
2
2
1
2
2
1
2 2
1

2 2
1

+
+
+
+ +
+
+
(1)
e.m.f. 0.000 (0.000) = + 0.000 + (1)
3

(c) Equation AgF(s) + Cl

(a") AgCl(s) + F

(a") (1)
e.m.f. = + 0.7- 0.22 = +0.5* + (1)
2
(%) (i) /il(er lies abo(e h5%rogen in the electrochemical series
Or Ag
+
(a") is a stronger o@i%ising agent than .
+
(a") (1)
(ii) ,/%ro-en hali%e .l (1)
Equation .
+
(a") + 1

(a") + Ag(s) Agl(s) +

2
1
.
2
(g) (1)
e.m.f. 00.00 (0.15) = + 0.15 + (1)
0
[10]
10. (a) 3e%ucin- a-ent 1r
2
(1)
,alf equation 1r
2
+ *.
2
O 21rO

3
+ 12.
+
+ 10e

(1)
2
(b) (i) 4emperature 2<- = or 25>C (1)
Concentration 1.00 , or 1.00 mol %m
3
(1)
(ii) 5econ%ar/ stan%ar% electro%e calomel
or Ag'AgCl (1)
3eason !asier to #se
or h5%rogen electro%e (1)
%iffic#lt to #se
0
(c) (i) :Co(.
2
O)
*
;
3+
(1)
(ii) :Co(.
2
O)
*
;
2+
(1)
(iii) ! for :Co(CC)
*
;
3
':Co(CC)
*
;
0
is negati(e 3ith res&ect to .
+
'.
2
(1)
!lectrons flo3 to .
+
'.
2
an% .
+
re%#ce% (1) 0
[10]
11. (a) Fe + C#
2+
C# + Fe
2+
(1)
allo3 #se of sol#ble C# salt eg C#/O
0
ignore state s5mbols 1
Mill Hill High School 5
(b) (i)
2 + 2 +
F e ( s ) F e ( a " ) C # ( a " ) C # ( s )
G#nctions correct (1)
ignore state s5mbols
allo3 alternati(e s5mbols for salt bri%ge
allo3 if G#nctions are correct b#t or%er is 3rong &ro(i%ing
metals on each si%e of salt bri%ge are the same ie Fe | Fe
2+
not Fe | C#
2+
or%er of s&ecies correct (1)
%o not gi(e this mar8 if cell re(erse% 2
(ii) e.m.f. = + 0.30 (0.00)
= + 0.7- + (1)
m#st ha(e + sign
allo3 0.7- (+) if re(erse cell gi(en in (i) 1
(c) (i) e.m.f for cell m#st be &ositi(e for reaction to occ#r ' be feasible ' (1)
s&ontaneo#s or 2 m#st be negati(e)
C#(s) + 2.
+
&ro%#cts
e.m.f = 0.303onHt ha&&en '
sensible com&arison of the magnit#%e of E for the electro%es
eg IC# electro%e more &ositi(e than h5%rogen electro%e3onHt 3or8H (1)
C#(s) + CO

3
+ 0.
+
&ro%#cts
e.m.f = + 0.<* 0.30 = +0.*2can occ#r '
similar sensible com&arison (1) 3
(ii) 3C# + 2 CO

3
+ -.
+
3C#
2+
+ 2CO +0.
2
O
s&ecies (1)
balance% this mar8 %e&en%ent on first mar8 (1) 2
(%) (i) 2Fe + O
2
+ 2.
2
O 2Fe
2+
+ 0O.

or 2Fe(O.)
2
(1)
ignore state s5mbols 1
(ii) ano%e (onl5 gi(e this mar8 if e@&lanation attem&te%) (1)
Fe loses e

( negati(e &ole) ' o@i%ation occ#rs (1)

this mar8 %e&en%ent on ano%e for first mar8 2
(iii) e.m.f. = + 0.0* + or reference to E for electro%es (1)
reasone% arg#ment (1)
eg &ositi(esho#l% occ#r ' %ifference so small that reaction #nli8el5 2
[14]

Mill Hill High School 6
12. (a) Name '(drogen electrode (1)
Con%itions 1 , .
+
(a") or 1 , .Cl(a") or 0.5 , .
2
/O
0
(a") (1)
2<- = (1)
.5%rogen gas at 1 bar or 100 89a (1)
0
(b) (i) E !alue 1.21 ( (1)
Equation /
2
O
2
-
+ 2Ag 2/O
2
0
+ 2Ag
+
[2]
(ii) Chan-e, if an/, in electro%e potential 7ess &ositi(e or %ecrease (1)
E1planation
!"#ilibri#m %is&lace% to the left (1)
,ore electrons release% (1)
*
[10]
13. (i) O@i%ising agents
C#
2+
(a") (1)? .
2
O
2
(a") (1)? C1
2
(a") (1) (3)
if Cr
2
O
2
7
(a") is incl#%e%? %e%#ct one mar8
(ii) 2)

)
2
)(1) )(0) (1)
,n
2+
,nO

0
,n())) ,n(+))) (1)
Cr
2
O
2
7
2CrO

0
no change (&enalise% abo(e)
Cl
2
ClO

Cl(0) Cl(1) (1)

(iii) C#
2
(a") + )

(a") + e

C#
+
(s) (1)
)

(a") J )
2
(a") + e

(not re(erse) (1)

.
2
O
2
(a") + 2.
+
(a") + 2e

2.
2
O (1) (1)
,n
2+
(a") + 0.
2
O (1) ,nO

0
(a") + -.
+
(a") + 5e

(not re(erse) (1)

2
1
Cl
2
(a") + e

Cl

(a") (1)
J Cl
2
(a") + 2O.

(a") ClO

(a") + .
2
O(l) + e

(not re(erse) (1)

9enalise missing or incorrect state s5mbols once onl5
(12 MAX)
11
[11]
Mill Hill High School 7