Chemical Accident

PART 68CHEMICAL ACCIDENT
PREVENTION PROVISIONS
Subpart AGeneral
Sec.
68.1 Scope.
68.2 Stayed provi si ons.
68.3 Defi ni ti ons.
68.10 Appl i cabi l i ty.
68.12 General requi rements.
68.15 Management.
Subpart BHazard Assessment
68.22 Offsi te consequence anal ysi s param-
eters.
68.25 Worst-case rel ease scenari o anal ysi s.
68.28 Al ternati ve rel ease scenari o anal ysi s.
68.30 Defi ni ng offsi te i mpactspopul ati on.
68.33 Defi ni ng offsi te i mpactsenvi ron-
ment.
68.36 Revi ew and update.
68.39 Documentati on.
68.42 F i ve-year acci dent hi story.
Subpart CProgram 2 Prevention Program
68.48 Safety i nformati on.
68.50 Hazard revi ew.
68.52 Operati ng procedures.
68.54 Trai ni ng.
68.56 Mai ntenance.
68.58 Compl i ance audi ts.
68.60 I nci dent i nvesti gati on.
Subpart DProgram 3 Prevention Program
68.65 Process safety i nformati on.
68.67 Process hazard anal ysi s.
68.69 Operati ng procedures.
68.71 Trai ni ng.
68.73 Mechani cal i ntegri ty.
68.75 Management of change.
68.77 Pre-startup revi ew.
68.79 Compl i ance audi ts.
68.81 I nci dent i nvesti gati on.
68.83 Empl oyee parti ci pati on.
68.85 Hot work permi t.
68.87 Contractors.
Subpart EEmergency Response
68.95 Emergency response program.
Subpart FRegulated Substances for
Accidental Release Prevention
68.100 Purpose.
68.115 Threshol d determi nati on.
68.120 Peti ti on process.
68.125 Exempti ons.
68.130 L i st of substances.
Subpart GRisk Management Plan
68.150 Submi ssi on.
68.151 Asserti on of cl ai ms of confi denti al
busi ness i nformati on.
68.152 Substanti ati ng cl ai ms of confi denti al
busi ness i nformati on.
68.155 Executi ve summary.
68.160 Regi strati on.
68.165 Offsi te consequence anal ysi s.
68.168 F i ve-year acci dent hi story.
68.170 Preventi on program/Program 2.
68.175 Preventi on program/Program 3.
68.185 Certi fi cati on.
68.190 Updates.
Subpart HOther Requirements
68.200 Recordkeepi ng.
68.210 Avai l abi l i ty of i nformati on to the
publ i c.
68.215 Permi t content and ai r permi tti ng
authori ty or desi gnated agency requi re-
ments.
68.220 Audi ts.
APPENDI X A TO PART 68TABL E OF TOXI C
ENDPOI NTS
AUTHORI TY : 42 U.S.C. 7412(r), 7601(a)(1),
76617661f.
SOURCE: 59 F R 4493, J an. 31, 1994, unl ess
otherwi se noted.
Subpart AGeneral
68.1 Scope.
Thi s part sets forth the l i st of regu-
l ated substances and threshol ds, the
peti ti on process for addi ng or del eti ng
substances to the l i st of regul ated sub-
stances, the requi rements for owners or
operators of stati onary sources con-
cerni ng the preventi on of acci dental
rel eases, and the State acci dental re-
l ease preventi on programs approved
under secti on 112(r). The l i st of sub-
stances, threshol d quanti ti es, and acci -
dent preventi on regul ati ons promul -
gated under thi s part do not l i mi t i n
any way the general duty provi si ons
under secti on 112(r)(1).
68.2 Stayed provisions.
(a) Notwi thstandi ng any other provi -
si on of thi s part, the effecti veness of
the fol l owi ng provi si ons i s stayed from
March 2, 1994 to December 22, 1997.
(1) I n Sec. 68.3, the defi ni ti on of sta-
ti onary source, to the extent that
such defi ni ti on i ncl udes natural l y oc-
curri ng hydrocarbon reservoi rs or
transportati on subj ect to oversi ght or
1
68.3
regul ati on under a state natural gas or
hazardous l i qui d program for whi ch the
state has i n effect a certi fi cati on to
DOT under 49 U.S.C. 60105;
(2) Secti on 68.115(b)(2) of thi s part, to
the extent that such provi si on requi res
an owner or operator to treat as a regu-
l ated fl ammabl e substance:
(i ) Gasol i ne, when i n di stri buti on or
rel ated storage for use as fuel for i nter-
nal combusti on engi nes;
(i i ) Natural l y occurri ng hydrocarbon
mi xtures pri or to entry i nto a petro-
l eum refi ni ng process uni t or a natural
gas processi ng pl ant. Natural l y occur-
ri ng hydrocarbon mi xtures i ncl ude any
of the fol l owi ng: condensate, crude oi l ,
fi el d gas, and produced water, each as
defi ned i n paragraph (b) of thi s secti on;
(i i i ) Other mi xtures that contai n a
regul ated fl ammabl e substance and
that do not have a Nati onal F i re Pro-
tecti on Associ ati on fl ammabi l i ty haz-
ard rati ng of 4, the defi ni ti on of whi ch
i s i n the NF PA 704, Standard System
for the I denti fi cati on of the F i re Haz-
ards of Materi al s, Nati onal F i re Pro-
tecti on Associ ati on, Qui ncy, MA, 1990,
avai l abl e from the Nati onal F i re Pro-
tecti on Associ ati on, 1 Batterymarch
Park, Qui ncy, MA 022699101; and
(3) Secti on 68.130(a).
(b) F rom March 2, 1994 to December
22, 1997, the fol l owi ng defi ni ti ons shal l
appl y to the stayed provi si ons de-
scri bed i n paragraph (a) of thi s secti on:
Condensate means hydrocarbon l i qui d
separated from natural gas that con-
denses because of changes i n tempera-
ture, pressure, or both, and remai ns
l i qui d at standard condi ti ons.
Crude oil means any natural l y occur-
ri ng, unrefi ned petrol eum l i qui d.
Field gas means gas extracted from a
producti on wel l before the gas enters a
natural gas processi ng pl ant.
Natural gas processing plant means
any processi ng si te engaged i n the ex-
tracti on of natural gas l i qui ds from
fi el d gas, fracti onati on of natural gas
l i qui ds to natural gas products, or
both. A separator, dehydrati on uni t,
heater treater, sweeteni ng uni t, com-
pressor, or si mi l ar equi pment shal l not
be consi dered a processi ng si te un-
l ess such equi pment i s physi cal l y l o-
cated wi thi n a natural gas processi ng
pl ant (gas pl ant) si te.
40 CFR Ch. I (7199 Edition)
Petroleum refining process unit means
a process uni t used i n an establ i shment
pri mari l y engaged i n petrol eum refi n-
i ng as defi ned i n the Standard I ndus-
tri al Cl assi fi cati on code for petrol eum
refi ni ng (2911) and used for the fol -
l owi ng: Produci ng transportati on fuel s
(such as gasol i ne, di esel fuel s, and j et
fuel s), heati ng fuel s (such as kerosene,
fuel gas di sti l l ate, and fuel oi l s), or l u-
bri cants; separati ng petrol eum; or sep-
arati ng, cracki ng, reacti ng, or reform-
i ng i ntermedi ate petrol eum streams.
Exampl es of such uni ts i ncl ude, but are
not l i mi ted to, petrol eum based sol vent
uni ts, al kyl ati on uni ts, catal yti c
hydrotreati ng, catal yti c hydrorefi ni ng,
catal yti c hydrocracki ng, catal yti c re-
formi ng, catal yti c cracki ng, crude di s-
ti l l ati on, l ube oi l processi ng, hydrogen
producti on, i someri zati on, pol ymeri za-
ti on, thermal processes, and bl endi ng,
sweeteni ng, and treati ng processes. Pe-
trol eum refi ni ng process uni ts i ncl ude
sul fur pl ants.
Produced water means water ex-
tracted from the earth from an oi l or
natural gas producti on wel l , or that i s
separated from oi l or natural gas after
extracti on.
(c) Notwi thstandi ng any other provi -
si on of thi s part, the effecti veness of
part 68 i s stayed from J une 21, 1999 to
December 21, 1999 wi th respect to regu-
l ated fl ammabl e hydrocarbon sub-
stances when the substance i s i ntended
for use as a fuel and does not exceed
67,000 pounds i n a process that i s not
manufacturi ng the fuel , does not con-
tai n greater than a threshol d quanti ty
of another regul ated substance, and i s
not col l ocated or i nterconnected to an-
other covered process.
[59 F R 4493, J an. 31, 1994, as amended at 61
F R 31731, J une 20, 1996; 64 F R 29170, May 28,
1999]
68.3 Definitions.
F or the purposes of thi s part:
Accidental release means an unanti ci -
pated emi ssi on of a regul ated sub-
stance or other extremel y hazardous
substance i nto the ambi ent ai r from a
stati onary source.
Act means the Cl ean Ai r Act as
amended (42 U.S.C. 7401 et seq.)
Administrative controls mean wri tten
procedural mechani sms used for hazard
control .
2
Environmental Protection Agency, EPA
Administrator means the admi ni s-
trator of the U.S. Envi ronmental Pro-
tecti on Agency.
AI ChE/CCPS means the Ameri can I n-
sti tute of Chemi cal Engi neers/Center
for Chemi cal Process Safety.
API means the Ameri can Petrol eum
I nsti tute.
Article means a manufactured i tem,
as defi ned under 29 CF R 1910.1200(b),
that i s formed to a speci fi c shape or de-
si gn duri ng manufacture, that has end
use functi ons dependent i n whol e or i n
part upon the shape or desi gn duri ng
end use, and that does not rel ease or
otherwi se resul t i n exposure to a regu-
l ated substance under normal condi -
ti ons of processi ng and use.
ASME means the Ameri can Soci ety
of Mechani cal Engi neers.
CAS means the Chemi cal Abstracts
Servi ce.
Catastrophic release means a maj or
uncontrol l ed emi ssi on, fi re, or expl o-
si on, i nvol vi ng one or more regul ated
substances that presents i mmi nent and
substanti al endangerment to publ i c
heal th and the envi ronment.
Classified information means cl assi -
fi ed i nformati on as defi ned i n the
Cl assi fi ed I nformati on Procedures Act,
18 U.S.C. App. 3, secti on 1(a) as any
i nformati on or materi al that has been
determi ned by the Uni ted States Gov-
ernment pursuant to an executi ve
order, statute, or regul ati on, to requi re
protecti on agai nst unauthori zed di scl o-
sure for reasons of nati onal securi ty.
Condensate means hydrocarbon l i qui d
separated from natural gas that con-
denses due to changes i n temperature,
pressure, or both, and remai ns l i qui d at
standard condi ti ons.
Covered process means a process that
has a regul ated substance present i n
more than a threshol d quanti ty as de-
termi ned under 68.115.
Crude oil means any natural l y occur-
ri ng, unrefi ned petrol eum l i qui d.
Designated agency means the state,
l ocal , or F ederal agency desi gnated by
the state under the provi si ons of
68.215(d) .
DOT means the Uni ted States De-
partment of Transportati on.
Environmental receptor means natural
areas such as nati onal or state parks,
forests, or monuments; offi ci al l y des-
i gnated wi l dl i fe sanctuari es, preserves,
68.3
refuges, or areas; and F ederal wi l der-
ness areas, that coul d be exposed at
any ti me to toxi c concentrati ons, radi -
ant heat, or overpressure greater than
or equal to the endpoi nts provi ded i n
68.22(a) , as a resul t of an acci dental
rel ease and that can be i denti fi ed on
l ocal U. S. Geol ogi cal Survey maps.
Field gas means gas extracted from a
producti on wel l before the gas enters a
natural gas processi ng pl ant.
Hot work means work i nvol vi ng el ec-
tri c or gas wel di ng, cutti ng, brazi ng, or
si mi l ar fl ame or spark-produci ng oper-
ati ons.
I mplementing agency means the state
or l ocal agency that obtai ns del egati on
for an acci dental rel ease preventi on
program under subpart E, 40 CF R part
63. The i mpl ementi ng agency may, but
i s not requi red to, be the state or l ocal
ai r permi tti ng agency. I f no state or
l ocal agency i s granted del egati on,
EPA wi l l be the i mpl ementi ng agency
for that state.
I njury means any effect on a human
that resul ts ei ther from di rect expo-
sure to toxi c concentrati ons; radi ant
heat; or overpressures from acci dental
rel eases or from the di rect con-
sequences of a vapor cl oud expl osi on
(such as fl yi ng gl ass, debri s, and other
proj ecti l es) from an acci dental rel ease
and that requi res medi cal treatment or
hospi tal i zati on.
Major change means i ntroducti on of a
new process, process equi pment, or reg-
ul ated substance, an al terati on of proc-
ess chemi stry that resul ts i n any
change to safe operati ng l i mi ts, or
other al terati on that i ntroduces a new
hazard.
Mechanical integrity means the proc-
ess of ensuri ng that process equi pment
i s fabri cated from the proper materi al s
of constructi on and i s properl y i n-
stal l ed, mai ntai ned, and repl aced to
prevent fai l ures and acci dental re-
l eases.
Medical treatment means treatment,
other than fi rst ai d, admi ni stered by a
physi ci an or regi stered professi onal
personnel under standi ng orders from a
physi ci an.
Mitigation or mitigation system means
speci fi c acti vi ti es, technol ogi es, or
equi pment desi gned or depl oyed to cap-
ture or control substances upon l oss of
contai nment to mi ni mi ze exposure of
3
68.3
the publ i c or the envi ronment. Passi ve
mi ti gati on means equi pment, devi ces,
or technol ogi es that functi on wi thout
human, mechani cal , or other energy
i nput. Acti ve mi ti gati on means equi p-
ment, devi ces, or technol ogi es that
need human, mechani cal , or other en-
ergy i nput to functi on.
NAI CS means North Ameri can I ndus-
try Cl assi fi cati on System.
NFPA means the Nati onal F i re Pro-
tecti on Associ ati on.
Natural gas processing plant (gas plant)
means any processi ng si te engaged i n
the extracti on of natural gas l i qui ds
from fi el d gas, fracti onati on of mi xed
natural gas l i qui ds to natural gas prod-
ucts, or both, cl assi fi ed as North Amer-
i can I ndustri al Cl assi fi cati on System
(NAI CS) code 211112 (previ ousl y Stand-
ard I ndustri al Cl assi fi cati on (SI C) code
1321).
Offsite means areas beyond the prop-
erty boundary of the stati onary source,
and areas wi thi n the property bound-
ary to whi ch the publ i c has routi ne and
unrestri cted access duri ng or outsi de
busi ness hours.
OSHA means the U.S. Occupati onal
Safety and Heal th Admi ni strati on.
Owner or operator means any person
who owns, l eases, operates, control s, or
supervi ses a stati onary source.
Petroleum refining process unit means
a process uni t used i n an establ i shment
pri mari l y engaged i n petrol eum refi n-
i ng as defi ned i n NAI CS code 32411 for
petrol eum refi ni ng (formerl y SI C code
2911) and used for the fol l owi ng: Pro-
duci ng transportati on fuel s (such as
gasol i ne, di esel fuel s, and j et fuel s),
heati ng fuel s (such as kerosene, fuel
gas di sti l l ate, and fuel oi l s), or l ubri -
cants; Separati ng petrol eum; or Sepa-
rati ng, cracki ng, reacti ng, or reform-
i ng i ntermedi ate petrol eum streams.
Exampl es of such uni ts i ncl ude, but are
not l i mi ted to, petrol eum based sol vent
uni ts, al kyl ati on uni ts, catal yti c
hydrotreati ng, catal yti c hydrorefi ni ng,
catal yti c hydrocracki ng, catal yti c re-
formi ng, catal yti c cracki ng, crude di s-
ti l l ati on, l ube oi l processi ng, hydrogen
producti on, i someri zati on, pol ymeri za-
ti on, thermal processes, and bl endi ng,
sweeteni ng, and treati ng processes. Pe-
trol eum refi ni ng process uni ts i ncl ude
sul fur pl ants.
Population means the publ i c.
Process means any acti vi ty i nvol vi ng
a regul ated substance i ncl udi ng any
use, storage, manufacturi ng, handl i ng,
or on-si te movement of such sub-
stances, or combi nati on of these acti vi -
ti es. F or the purposes of thi s defi ni -
ti on, any group of vessel s that are
i nterconnected, or separate vessel s
that are l ocated such that a regul ated
substance coul d be i nvol ved i n a poten-
ti al rel ease, shal l be consi dered a si n-
gl e process.
Produced water means water ex-
tracted from the earth from an oi l or
natural gas producti on wel l , or that i s
separated from oi l or natural gas after
extracti on.
Public means any person except em-
pl oyees or contractors at the sta-
ti onary source.
Public receptor means offsi te resi -
dences, i nsti tuti ons (e.g., school s, hos-
pi tal s), i ndustri al , commerci al , and of-
fi ce bui l di ngs, parks, or recreati onal
areas i nhabi ted or occupi ed by the pub-
l i c at any ti me wi thout restri cti on by
the stati onary source where members
of the publ i c coul d be exposed to toxi c
concentrati ons, radi ant heat, or over-
pressure, as a resul t of an acci dental
rel ease.
Regulated substance i s any substance
l i sted pursuant to secti on 112(r)(3) of
the Cl ean Ai r Act as amended, i n
68.130.
Replacement in kind means a repl ace-
ment that sati sfi es the desi gn speci -
fi cati ons.
RMP means the ri sk management
pl an requi red under subpart G of thi s
part.
Stationary source means any bui l d-
i ngs, structures, equi pment, i nstal l a-
ti ons, or substance emi tti ng stati onary
acti vi ti es whi ch bel ong to the same i n-
dustri al group, whi ch are l ocated on
one or more conti guous properti es,
whi ch are under the control of the
same person (or persons under common
control ), and from whi ch an acci dental
rel ease may occur. The term sta-
ti onary source does not appl y to trans-
portati on, i ncl udi ng storage i nci dent
to transportati on, of any regul ated
substance or any other extremel y haz-
ardous substance under the provi si ons
of thi s part. A stati onary source i n-
cl udes transportati on contai ners used
4
for storage not i nci dent to transpor-
tati on and transportati on contai ners
connected to equi pment at a stati onary
source for l oadi ng or unl oadi ng. Trans-
portati on i ncl udes, but i s not l i mi ted
to, transportati on subj ect to oversi ght
or regul ati on under 49 CF R parts 192,
193, or 195, or a state natural gas or
hazardous l i qui d program for whi ch the
state has i n effect a certi fi cati on to
DOT under 49 U.S.C. secti on 60105. A
stati onary source does not i ncl ude nat-
ural l y occurri ng hydrocarbon res-
ervoi rs. Properti es shal l not be consi d-
ered conti guous sol el y because of a
rai l road or pi pel i ne ri ght-of-way.
Threshold quantity means the quan-
ti ty speci fi ed for regul ated substances
pursuant to secti on 112(r)(5) of the
Cl ean Ai r Act as amended, l i sted i n
68.130 and determi ned to be present at
a stati onary source as speci fi ed i n
68.115 of thi s part.
Typical meteorological conditions
means the temperature, wi nd speed,
cl oud cover, and atmospheri c stabi l i ty
cl ass, prevai l i ng at the si te based on
data gathered at or near the si te or
from a l ocal meteorol ogi cal stati on.
Vessel means any reactor, tank,
drum, barrel , cyl i nder, vat, kettl e,
boi l er, pi pe, hose, or other contai ner.
Worst-case release means the rel ease
of the l argest quanti ty of a regul ated
substance from a vessel or process l i ne
fai l ure that resul ts i n the greatest di s-
tance to an endpoi nt defi ned i n
68.22(a).
[59 F R 4493, J an. 31, 1994, as amended at 61
F R 31717, J une 20, 1996; 63 F R 644, J an. 6, 1998;
64 F R 979, J an. 6, 1999]
68.10 Applicability.
(a) An owner or operator of a sta-
ti onary source that has more than a
threshol d quanti ty of a regul ated sub-
stance i n a process, as determi ned
under 68.115, shal l compl y wi th the re-
qui rements of thi s part no l ater than
the l atest of the fol l owi ng dates:
(1) J une 21, 1999;
(2) Three years after the date on
whi ch a regul ated substance i s fi rst
l i sted under 68.130; or
(3) The date on whi ch a regul ated
substance i s fi rst present above a
threshol d quanti ty i n a process.
(b) Program 1 el i gi bi l i ty requi re-
ments. A covered process i s el i gi bl e for
68.10
Program 1 requi rements as provi ded i n
68.12(b) i f i t meets al l of the fol l owi ng
requi rements:
(1) F or the fi ve years pri or to the
submi ssi on of an RMP, the process has
not had an acci dental rel ease of a regu-
l ated substance where exposure to the
substance, i ts reacti on products, over-
pressure generated by an expl osi on i n-
vol vi ng the substance, or radi ant heat
generated by a fi re i nvol vi ng the sub-
stance l ed to any of the fol l owi ng off-
si te:
(i ) Death;
(i i ) I nj ury; or
(i i i ) Response or restorati on acti vi -
ti es for an exposure of an envi ron-
mental receptor;
(2) The di stance to a toxi c or fl am-
mabl e endpoi nt for a worst-case rel ease
assessment conducted under Subpart B
and 68.25 i s l ess than the di stance to
any publ i c receptor, as defi ned i n
68.30; and
(3) Emergency response procedures
have been coordi nated between the sta-
ti onary source and l ocal emergency
pl anni ng and response organi zati ons.
(c) Program 2 el i gi bi l i ty requi re-
ments. A covered process i s subj ect to
Program 2 requi rements i f i t does not
meet the el i gi bi l i ty requi rements of ei -
ther paragraph (b) or paragraph (d) of
thi s secti on.
(d) Program 3 el i gi bi l i ty requi re-
ments. A covered process i s subj ect to
Program 3 i f the process does not meet
the requi rements of paragraph (b) of
thi s secti on, and i f ei ther of the fol -
l owi ng condi ti ons i s met:
(1) The process i s i n NAI CS code
32211, 32411, 32511, 325181, 325188, 325192,
325199, 325211, 325311, or 32532; or
(2) The process i s subj ect to the
OSHA process safety management
standard, 29 CF R 1910.119.
(e) I f at any ti me a covered process
no l onger meets the el i gi bi l i ty cri teri a
of i ts Program l evel , the owner or oper-
ator shal l compl y wi th the requi re-
ments of the new Program l evel that
appl i es to the process and update the
RMP as provi ded i n 68.190.
(f) The provi si ons of thi s part shal l
not appl y to an Outer Conti nental
Shel f (OCS) source, as defi ned i n 40
CF R 55.2.
[61 F R 31717, J une 20, 1996, as amended at 63
F R 645, J an. 6, 1998; 64 F R 979, J an. 6, 1999]
5
68.12
68.12 General requirements.
(a) General requi rements. The owner
or operator of a stati onary source sub-
j ect to thi s part shal l submi t a si ngl e
RMP, as provi ded i n 68.150 to 68.185.
The RMP shal l i ncl ude a regi strati on
that refl ects al l covered processes.
(b) Program 1 requi rements. I n addi -
ti on to meeti ng the requi rements of
paragraph (a) of thi s secti on, the owner
or operator of a stati onary source wi th
a process el i gi bl e for Program 1, as pro-
vi ded i n 68.10(b), shal l :
(1) Anal yze the worst-case rel ease
scenari o for the process(es), as provi ded
i n 68.25; document that the nearest
publ i c receptor i s beyond the di stance
to a toxi c or fl ammabl e endpoi nt de-
fi ned i n 68.22(a); and submi t i n the
RMP the worst-case rel ease scenari o as
provi ded i n 68.165;
(2) Compl ete the fi ve-year acci dent
hi story for the process as provi ded i n
68.42 of thi s part and submi t i t i n the
RMP as provi ded i n 68.168;
(3) Ensure that response acti ons have
been coordi nated wi th l ocal emergency
pl anni ng and response agenci es; and
(4) Certi fy i n the RMP the fol l owi ng:
Based on the cri teri a i n 40 CF R 68.10,
the di stance to the speci fi ed endpoi nt
for the worst-case acci dental rel ease
scenari o for the fol l owi ng process(es) i s
l ess than the di stance to the nearest
publ i c receptor: [l i st process(es)]. Wi th-
i n the past fi ve years, the process(es)
has (have) had no acci dental rel ease
that caused offsi te i mpacts provi ded i n
the ri sk management program rul e (40
CF R 68.10(b)(1)). No addi ti onal meas-
ures are necessary to prevent offsi te
i mpacts from acci dental rel eases. I n
the event of fi re, expl osi on, or a rel ease
of a regul ated substance from the proc-
ess(es), entry wi thi n the di stance to
the speci fi ed endpoi nts may pose a dan-
ger to publ i c emergency responders.
Therefore, publ i c emergency respond-
ers shoul d not enter thi s area except as
arranged wi th the emergency contact
i ndi cated i n the RMP. The undersi gned
certi fi es that, to the best of my knowl -
edge, i nformati on, and bel i ef, formed
after reasonabl e i nqui ry, the i nforma-
ti on submi tted i s true, accurate, and
compl ete. [Si gnature, ti tl e, date
si gned].
(c) Program 2 requi rements. I n addi -
a process subj ect to Program 2, as pro-
vi ded i n 68.10(c), shal l :
(1) Devel op and i mpl ement a manage-
ment system as provi ded i n 68.15;
(2) Conduct a hazard assessment as
provi ded i n 68.20 through 68.42;
(3) I mpl ement the Program 2 preven-
ti on steps provi ded i n 68.48 through
68.60 or i mpl ement the Program 3 pre-
venti on steps provi ded i n 68.65
through 68.87;
(4) Devel op and i mpl ement an emer-
gency response program as provi ded i n
68.90 to 68.95; and
(5) Submi t as part of the RMP the
data on preventi on program el ements
for Program 2 processes as provi ded i n
68.170.
(d) Program 3 requi rements. I n addi -
a process subj ect to Program 3, as pro-
vi ded i n 68.10(d) shal l :
(1) Devel op and i mpl ement a manage-
ment system as provi ded i n 68.15;
(2) Conduct a hazard assessment as
provi ded i n 68.20 through 68.42;
(3) I mpl ement the preventi on re-
qui rements of 68.65 through 68.87;
(4) Devel op and i mpl ement an emer-
gency response program as provi ded i n
68.90 to 68.95 of thi s part; and
(5) Submi t as part of the RMP the
data on preventi on program el ements
for Program 3 processes as provi ded i n
68.175.
[61 F R 31718, J une 20, 1996]
68.15 Management.
(a) The owner or operator of a sta-
ti onary source wi th processes subj ect
to Program 2 or Program 3 shal l de-
vel op a management system to oversee
the i mpl ementati on of the ri sk man-
agement program el ements.
(b) The owner or operator shal l as-
si gn a qual i fi ed person or posi ti on that
has the overal l responsi bi l i ty for the
devel opment, i mpl ementati on, and i n-
tegrati on of the ri sk management pro-
gram el ements.
(c) When responsi bi l i ty for i mpl e-
menti ng i ndi vi dual requi rements of
thi s part i s assi gned to persons other
than the person i denti fi ed under para-
graph (b) of thi s secti on, the names or
6
posi ti ons of these peopl e shal l be docu-
mented and the l i nes of authori ty de-
fi ned through an organi zati on chart or
si mi l ar document.
[61 F R 31718, J une 20, 1996]
Subpart BHazard Assessment
SOURCE: 61 F R 31718, J une 20, 1996, unl ess
otherwi se noted.
The owner or operator of a sta-
ti onary source subj ect to thi s part
shal l prepare a worst-case rel ease sce-
nari o anal ysi s as provi ded i n 68.25 of
thi s part and compl ete the fi ve-year
acci dent hi story as provi ded i n 68.42.
The owner or operator of a Program 2
and 3 process must compl y wi th al l sec-
ti ons i n thi s subpart for these proc-
esses.
68.22 Offsite consequence analysis
parameters.
(a) Endpoi nts. F or anal yses of offsi te
consequences, the fol l owi ng endpoi nts
shal l be used:
(1) Toxi cs. The toxi c endpoi nts pro-
vi ded i n appendi x A of thi s part.
(2) F l ammabl es. The endpoi nts for
fl ammabl es vary accordi ng to the sce-
nari os studi ed:
(i ) Expl osi on. An overpressure of 1
psi .
(i i ) Radi ant heat/exposure ti me. A ra-
di ant heat of 5 kw/m
2
for 40 seconds.
(i i i ) L ower fl ammabi l i ty l i mi t. A
l ower fl ammabi l i ty l i mi t as provi ded i n
NF PA documents or other general l y
recogni zed sources.
(b) Wi nd speed/atmospheri c stabi l i ty
cl ass. F or the worst-case rel ease anal -
ysi s, the owner or operator shal l use a
wi nd speed of 1.5 meters per second and
F atmospheri c stabi l i ty cl ass. I f the
owner or operator can demonstrate
that l ocal meteorol ogi cal data appl i ca-
bl e to the stati onary source show a
hi gher mi ni mum wi nd speed or l ess sta-
bl e atmosphere at al l ti mes duri ng the
previ ous three years, these mi ni mums
may be used. F or anal ysi s of al ter-
nati ve scenari os, the owner or operator
may use the typi cal meteorol ogi cal
condi ti ons for the stati onary source.
(c) Ambi ent temperature/humi di ty.
F or worst-case rel ease anal ysi s of a
68.25
regul ated toxi c substance, the owner or
operator shal l use the hi ghest dai l y
maxi mum temperature i n the previ ous
three years and average humi di ty for
the si te, based on temperature/humi d-
i ty data gathered at the stati onary
source or at a l ocal meteorol ogi cal sta-
ti on; an owner or operator usi ng the
RMP Offsi te Consequence Anal ysi s
Gui dance may use 25 C and 50 percent
humi di ty as val ues for these vari abl es.
F or anal ysi s of al ternati ve scenari os,
the owner or operator may use typi cal
temperature/humi di ty data gathered at
the stati onary source or at a l ocal me-
teorol ogi cal stati on.
(d) Hei ght of rel ease. The worst-case
rel ease of a regul ated toxi c substance
shal l be anal yzed assumi ng a ground
l evel (0 feet) rel ease. F or an al ternati ve
scenari o anal ysi s of a regul ated toxi c
substance, rel ease hei ght may be deter-
mi ned by the rel ease scenari o.
(e) Surface roughness. The owner or
operator shal l use ei ther urban or rural
topography, as appropri ate. Urban
means that there are many obstacl es i n
the i mmedi ate area; obstacl es i ncl ude
bui l di ngs or trees. Rural means there
are no bui l di ngs i n the i mmedi ate area
and the terrai n i s general l y fl at and
unobstructed.
(f) Dense or neutral l y buoyant gases.
The owner or operator shal l ensure
that tabl es or model s used for di sper-
si on anal ysi s of regul ated toxi c sub-
stances appropri atel y account for gas
densi ty.
(g) Temperature of rel eased sub-
stance. F or worst case, l i qui ds other
than gases l i qui fi ed by refri gerati on
onl y shal l be consi dered to be rel eased
at the hi ghest dai l y maxi mum tem-
perature, based on data for the pre-
vi ous three years appropri ate for the
stati onary source, or at process tem-
perature, whi chever i s hi gher. F or al -
ternati ve scenari os, substances may be
consi dered to be rel eased at a process
or ambi ent temperature that i s appro-
pri ate for the scenari o.
68.25 Worst-case release scenario
analysis.
(a) The owner or operator shal l ana-
l yze and report i n the RMP:
(1) F or Program 1 processes, one
worst-case rel ease scenari o for each
Program 1 process;
7
68.25
(2) F or Program 2 and 3 processes:
(i ) One worst-case rel ease scenari o
that i s esti mated to create the greatest
di stance i n any di recti on to an end-
poi nt provi ded i n appendi x A of thi s
part resul ti ng from an acci dental re-
l ease of regul ated toxi c substances
from covered processes under worst-
case condi ti ons defi ned i n 68.22;
(i i ) One worst-case rel ease scenari o
that i s esti mated to create the greatest
di stance i n any di recti on to an end-
poi nt defi ned i n 68.22(a) resul ti ng from
an acci dental rel ease of regul ated fl am-
mabl e substances from covered proc-
esses under worst-case condi ti ons de-
fi ned i n 68.22; and
(i i i ) Addi ti onal worst-case rel ease
scenari os for a hazard cl ass i f a worst-
case rel ease from another covered proc-
ess at the stati onary source potenti al l y
affects publ i c receptors di fferent from
those potenti al l y affected by the worst-
case rel ease scenari o devel oped under
paragraphs (a)(2)(i ) or (a)(2)(i i ) of thi s
secti on.
(b) Determination of worst-case release
quantity. The worst-case rel ease quan-
ti ty shal l be the greater of the fol -
l owi ng:
(1) F or substances i n a vessel , the
greatest amount hel d i n a si ngl e vessel ,
taki ng i nto account admi ni strati ve
control s that l i mi t the maxi mum quan-
ti ty; or
(2) F or substances i n pi pes, the great-
est amount i n a pi pe, taki ng i nto ac-
count admi ni strati ve control s that
l i mi t the maxi mum quanti ty.
(c) Worst-case release scenariotoxic
gases. (1) F or regul ated toxi c sub-
stances that are normal l y gases at am-
bi ent temperature and handl ed as a gas
or as a l i qui d under pressure, the owner
or operator shal l assume that the
quanti ty i n the vessel or pi pe, as deter-
mi ned under paragraph (b) of thi s sec-
ti on, i s rel eased as a gas over 10 mi n-
utes. The rel ease rate shal l be assumed
to be the total quanti ty di vi ded by 10
unl ess passi ve mi ti gati on systems are
i n pl ace.
(2) F or gases handl ed as refri gerated
l i qui ds at ambi ent pressure:
(i ) I f the rel eased substance i s not
contai ned by passi ve mi ti gati on sys-
tems or i f the contai ned pool woul d
have a depth of 1 cm or l ess, the owner
or operator shal l assume that the sub-
stance i s rel eased as a gas i n 10 mi n-
utes;
(i i ) I f the rel eased substance i s con-
tai ned by passi ve mi ti gati on systems
i n a pool wi th a depth greater than 1
cm, the owner or operator may assume
that the quanti ty i n the vessel or pi pe,
as determi ned under paragraph (b) of
thi s secti on, i s spi l l ed i nstantaneousl y
to form a l i qui d pool . The vol ati l i za-
ti on rate (rel ease rate) shal l be cal -
cul ated at the boi l i ng poi nt of the sub-
stance and at the condi ti ons speci fi ed
i n paragraph (d) of thi s secti on.
(d) Worst-case release scenariotoxic
liquids. (1) F or regul ated toxi c sub-
stances that are normal l y l i qui ds at
ambi ent temperature, the owner or op-
erator shal l assume that the quanti ty
i n the vessel or pi pe, as determi ned
under paragraph (b) of thi s secti on, i s
spi l l ed i nstantaneousl y to form a l i qui d
pool .
(i ) The surface area of the pool shal l
be determi ned by assumi ng that the
l i qui d spreads to 1 centi meter deep un-
l ess passi ve mi ti gati on systems are i n
pl ace that serve to contai n the spi l l
and l i mi t the surface area. Where pas-
si ve mi ti gati on i s i n pl ace, the surface
area of the contai ned l i qui d shal l be
used to cal cul ate the vol ati l i zati on
rate.
(i i ) I f the rel ease woul d occur onto a
surface that i s not paved or smooth,
the owner or operator may take i nto
account the actual surface characteri s-
ti cs.
(2) The vol ati l i zati on rate shal l ac-
count for the hi ghest dai l y maxi mum
temperature occurri ng i n the past
three years, the temperature of the
substance i n the vessel , and the con-
centrati on of the substance i f the l i q-
ui d spi l l ed i s a mi xture or sol uti on.
(3) The rate of rel ease to ai r shal l be
determi ned from the vol ati l i zati on rate
of the l i qui d pool . The owner or oper-
ator may use the methodol ogy i n the
RMP Offsi te Consequence Anal ysi s
Gui dance or any other publ i cl y avai l -
abl e techni ques that account for the
model i ng condi ti ons and are recogni zed
by i ndustry as appl i cabl e as part of
current practi ces. Propri etary model s
that account for the model i ng condi -
ti ons may be used provi ded the owner
or operator al l ows the i mpl ementi ng
8
agency access to the model and de-
scri bes model features and di fferences
from publ i cl y avai l abl e model s to l ocal
emergency pl anners upon request.
(e) Worst-case release scenarioflam-
mable gases. The owner or operator
shal l assume that the quanti ty of the
substance, as determi ned under para-
graph (b) of thi s secti on and the provi -
si ons bel ow, vapori zes resul ti ng i n a
vapor cl oud expl osi on. A yi el d factor of
10 percent of the avai l abl e energy re-
l eased i n the expl osi on shal l be used to
determi ne the di stance to the expl osi on
endpoi nt i f the model used i s based on
TNT equi val ent methods.
(1) F or regul ated fl ammabl e sub-
stances that are normal l y gases at am-
bi ent temperature and handl ed as a gas
or as a l i qui d under pressure, the owner
or operator shal l assume that the
ti on, i s rel eased as a gas over 10 mi n-
utes. The total quanti ty shal l be as-
sumed to be i nvol ved i n the vapor
cl oud expl osi on.
(2) F or fl ammabl e gases handl ed as
refri gerated l i qui ds at ambi ent pres-
sure:
(i ) I f the rel eased substance i s not
contai ned by passi ve mi ti gati on sys-
tems or i f the contai ned pool woul d
have a depth of one centi meter or l ess,
the owner or operator shal l assume
that the total quanti ty of the sub-
stance i s rel eased as a gas i n 10 mi n-
utes, and the total quanti ty wi l l be i n-
vol ved i n the vapor cl oud expl osi on.
(i i ) I f the rel eased substance i s con-
tai ned by passi ve mi ti gati on systems
i n a pool wi th a depth greater than 1
centi meter, the owner or operator may
assume that the quanti ty i n the vessel
or pi pe, as determi ned under paragraph
(b) of thi s secti on, i s spi l l ed i nstanta-
neousl y to form a l i qui d pool . The vol a-
ti l i zati on rate (rel ease rate) shal l be
cal cul ated at the boi l i ng poi nt of the
substance and at the condi ti ons speci -
fi ed i n paragraph (d) of thi s secti on.
The owner or operator shal l assume
that the quanti ty whi ch becomes vapor
i n the fi rst 10 mi nutes i s i nvol ved i n
the vapor cl oud expl osi on.
(f) Worst-case release scenarioflam-
mable liquids. The owner or operator
shal l assume that the quanti ty of the
substance, as determi ned under para-
68.25
graph (b) of thi s secti on and the provi -
si ons bel ow, vapori zes resul ti ng i n a
vapor cl oud expl osi on. A yi el d factor of
10 percent of the avai l abl e energy re-
l eased i n the expl osi on shal l be used to
determi ne the di stance to the expl osi on
endpoi nt i f the model used i s based on
TNT equi val ent methods.
(1) F or regul ated fl ammabl e sub-
stances that are normal l y l i qui ds at
ambi ent temperature, the owner or op-
erator shal l assume that the enti re
ti on, i s spi l l ed i nstantaneousl y to form
a l i qui d pool . F or l i qui ds at tempera-
tures bel ow thei r atmospheri c boi l i ng
poi nt, the vol ati l i zati on rate shal l be
cal cul ated at the condi ti ons speci fi ed
i n paragraph (d) of thi s secti on.
(2) The owner or operator shal l as-
sume that the quanti ty whi ch becomes
vapor i n the fi rst 10 mi nutes i s i n-
vol ved i n the vapor cl oud expl osi on.
(g) Parameters to be applied. The
owner or operator shal l use the param-
eters defi ned i n 68.22 to determi ne di s-
tance to the endpoi nts. The owner or
operator may use the methodol ogy pro-
vi ded i n the RMP Offsi te Consequence
Anal ysi s Gui dance or any commer-
ci al l y or publ i cl y avai l abl e ai r di sper-
si on model i ng techni ques, provi ded the
techni ques account for the model i ng
condi ti ons and are recogni zed by i ndus-
try as appl i cabl e as part of current
practi ces. Propri etary model s that ac-
count for the model i ng condi ti ons may
be used provi ded the owner or operator
al l ows the i mpl ementi ng agency access
to the model and descri bes model fea-
tures and di fferences from publ i cl y
avai l abl e model s to l ocal emergency
pl anners upon request.
(h) Consideration of passive mitigation.
Passi ve mi ti gati on systems may be
consi dered for the anal ysi s of worst
case provi ded that the mi ti gati on sys-
tem i s capabl e of wi thstandi ng the re-
l ease event tri ggeri ng the scenari o and
woul d sti l l functi on as i ntended.
(i ) Factors in selecting a worst-case sce-
nario. Notwi thstandi ng the provi si ons
of paragraph (b) of thi s secti on, the
owner or operator shal l sel ect as the
worst case for fl ammabl e regul ated
substances or the worst case for regu-
l ated toxi c substances, a scenari o based
9
68.28
on the fol l owi ng factors i f such a sce-
nari o woul d resul t i n a greater di stance
to an endpoi nt defi ned i n 68.22(a) be-
yond the stati onary source boundary
than the scenari o provi ded under para-
graph (b) of thi s secti on:
(1) Smal l er quanti ti es handl ed at
hi gher process temperature or pres-
sure; and
(2) Proxi mi ty to the boundary of the
stati onary source.
F R 28700, May 26, 1999]
68.28 Alternative release scenario
analysis.
(a) The number of scenari os. The
owner or operator shal l i denti fy and
anal yze at l east one al ternati ve rel ease
scenari o for each regul ated toxi c sub-
stance hel d i n a covered process(es) and
at l east one al ternati ve rel ease sce-
nari o to represent al l fl ammabl e sub-
stances hel d i n covered processes.
(b) Scenarios to consider. (1) F or each
scenari o requi red under paragraph (a)
of thi s secti on, the owner or operator
shal l sel ect a scenari o:
(i ) That i s more l i kel y to occur than
the worst-case rel ease scenari o under
68.25; and
(i i ) That wi l l reach an endpoi nt off-
si te, unl ess no such scenari o exi sts.
(2) Rel ease scenari os consi dered
shoul d i ncl ude, but are not l i mi ted to,
the fol l owi ng, where appl i cabl e:
(i ) Transfer hose rel eases due to
spl i ts or sudden hose uncoupl i ng;
(i i ) Process pi pi ng rel eases from fai l -
ures at fl anges, j oi nts, wel ds, val ves
and val ve seal s, and drai ns or bl eeds;
(i i i ) Process vessel or pump rel eases
due to cracks, seal fai l ure, or drai n,
bl eed, or pl ug fai l ure;
(i v) Vessel overfi l l i ng and spi l l , or
overpressuri zati on and venti ng through
rel i ef val ves or rupture di sks; and
(v) Shi ppi ng contai ner mi shandl i ng
and breakage or puncturi ng l eadi ng to
a spi l l .
(c) Parameters to be appl i ed. The
owner or operator shal l use the appro-
pri ate parameters defi ned i n 68.22 to
determi ne di stance to the endpoi nts.
The owner or operator may use ei ther
the methodol ogy provi ded i n the RMP
Offsi te Consequence Anal ysi s Gui dance
or any commerci al l y or publ i cl y avai l -
abl e ai r di spersi on model i ng tech-
ni ques, provi ded the techni ques ac-
count for the speci fi ed model i ng condi -
ti ons and are recogni zed by i ndustry as
appl i cabl e as part of current practi ces.
Propri etary model s that account for
the model i ng condi ti ons may be used
provi ded the owner or operator al l ows
the i mpl ementi ng agency access to the
model and descri bes model features and
di fferences from publ i cl y avai l abl e
model s to l ocal emergency pl anners
upon request.
(d) Consi derati on of mi ti gati on. Ac-
ti ve and passi ve mi ti gati on systems
may be consi dered provi ded they are
capabl e of wi thstandi ng the event that
tri ggered the rel ease and woul d sti l l be
functi onal .
(e) F actors i n sel ecti ng scenari os.
The owner or operator shal l consi der
the fol l owi ng i n sel ecti ng al ternati ve
rel ease scenari os:
(1) The fi ve-year acci dent hi story
provi ded i n 68.42; and
(2) F ai l ure scenari os i denti fi ed under
68.50 or 68.67.
68.30 Defining offsite impactspopu-
lation.
(a) The owner or operator shal l esti -
mate i n the RMP the popul ati on wi thi n
a ci rcl e wi th i ts center at the poi nt of
the rel ease and a radi us determi ned by
the di stance to the endpoi nt defi ned i n
68.22(a).
(b) Population to be defined. Popu-
l ati on shal l i ncl ude resi denti al popu-
l ati on. The presence of i nsti tuti ons
(school s, hospi tal s, pri sons), parks and
recreati onal areas, and maj or commer-
ci al , offi ce, and i ndustri al bui l di ngs
shal l be noted i n the RMP.
(c) Data sources acceptable. The owner
or operator may use the most recent
Census data, or other updated i nforma-
ti on, to esti mate the popul ati on poten-
ti al l y affected.
(d) L evel of accuracy. Popul ati on shal l
be esti mated to two si gni fi cant di gi ts.
68.33 Defining offsite impactsenvi-
ronment.
(a) The owner or operator shal l l i st i n
the RMP envi ronmental receptors
wi thi n a ci rcl e wi th i ts center at the
poi nt of the rel ease and a radi us deter-
mi ned by the di stance to the endpoi nt
defi ned i n 68.22(a) of thi s part.
10
(b) Data sources acceptabl e. The
owner or operator may rel y on i nfor-
mati on provi ded on l ocal U.S. Geol ogi -
cal Survey maps or on any data source
contai ni ng U.S.G.S. data to i denti fy
envi ronmental receptors.
68.36 Review and update.
(a) The owner or operator shal l re-
vi ew and update the offsi te con-
sequence anal yses at l east once every
fi ve years.
(b) I f changes i n processes, quanti ti es
stored or handl ed, or any other aspect
of the stati onary source mi ght reason-
abl y be expected to i ncrease or de-
crease the di stance to the endpoi nt by
a factor of two or more, the owner or
operator shal l compl ete a revi sed anal -
ysi s wi thi n si x months of the change
and submi t a revi sed ri sk management
pl an as provi ded i n 68.190.
68.39 Documentation.
The owner or operator shal l mai ntai n
the fol l owi ng records on the offsi te
consequence anal yses:
(a) F or worst-case scenari os, a de-
scri pti on of the vessel or pi pel i ne and
substance sel ected as worst case, as-
sumpti ons and parameters used, and
the rati onal e for sel ecti on; assump-
ti ons shal l i ncl ude use of any admi ni s-
trati ve control s and any passi ve mi ti -
gati on that were assumed to l i mi t the
quanti ty that coul d be rel eased. Docu-
mentati on shal l i ncl ude the anti ci -
pated effect of the control s and mi ti ga-
ti on on the rel ease quanti ty and rate.
(b) F or al ternati ve rel ease scenari os,
a descri pti on of the scenari os i denti -
fi ed, assumpti ons and parameters used,
and the rati onal e for the sel ecti on of
speci fi c scenari os; assumpti ons shal l
i ncl ude use of any admi ni strati ve con-
trol s and any mi ti gati on that were as-
sumed to l i mi t the quanti ty that coul d
be rel eased. Documentati on shal l i n-
cl ude the effect of the control s and
mi ti gati on on the rel ease quanti ty and
rate.
(c) Documentati on of esti mated
quanti ty rel eased, rel ease rate, and du-
rati on of rel ease.
(d) Methodol ogy used to determi ne
di stance to endpoi nts.
(e) Data used to esti mate popul ati on
and envi ronmental receptors poten-
ti al l y affected.
68.48
68.42 Five-year accident history.
(a) The owner or operator shal l i n-
cl ude i n the fi ve-year acci dent hi story
al l acci dental rel eases from covered
processes that resul ted i n deaths, i nj u-
ri es, or si gni fi cant property damage on
si te, or known offsi te deaths, i nj uri es,
evacuati ons, shel teri ng i n pl ace, prop-
erty damage, or envi ronmental dam-
age.
(b) Data required. F or each acci dental
rel ease i ncl uded, the owner or operator
shal l report the fol l owi ng i nformati on:
(1) Date, ti me, and approxi mate dura-
ti on of the rel ease;
(2) Chemi cal (s) rel eased;
(3) Esti mated quanti ty rel eased i n
pounds and, for mi xtures contai ni ng
regul ated toxi c substances, percentage
concentrati on by wei ght of the rel eased
regul ated toxi c substance i n the l i qui d
mi xture;
(4) F i ve- or si x-di gi t NAI CS code that
most cl osel y corresponds to the proc-
ess;
(5) The type of rel ease event and i ts
source;
(6) Weather condi ti ons, i f known;
(7) On-si te i mpacts;
(8) Known offsi te i mpacts;
(9) I ni ti ati ng event and contri buti ng
factors i f known;
(10) Whether offsi te responders were
noti fi ed i f known; and
(11) Operati onal or process changes
that resul ted from i nvesti gati on of the
rel ease.
(c) L evel of accuracy. Numeri cal esti -
mates may be provi ded to two si gni fi -
cant di gi ts.
F R 979, J an. 6, 1999]
Subpart CProgram 2 Prevention
Program
otherwi se noted.
68.48 Safety information.
(a) The owner or operator shal l com-
pi l e and mai ntai n the fol l owi ng up-to-
date safety i nformati on rel ated to the
regul ated substances, processes, and
equi pment:
(1) Materi al Safety Data Sheets that
meet the requi rements of 29 CF R
1910.1200(g);
11
68.50
(2) Maxi mum i ntended i nventory of
equi pment i n whi ch the regul ated sub-
stances are stored or processed;
(3) Safe upper and l ower tempera-
tures, pressures, fl ows, and composi -
ti ons;
(4) Equi pment speci fi cati ons; and
(5) Codes and standards used to de-
si gn, bui l d, and operate the process.
(b) The owner or operator shal l en-
sure that the process i s desi gned i n
compl i ance wi th recogni zed and gen-
eral l y accepted good engi neeri ng prac-
ti ces. Compl i ance wi th F ederal or state
regul ati ons that address i ndustry-spe-
ci fi c safe desi gn or wi th i ndustry-spe-
ci fi c desi gn codes and standards may be
used to demonstrate compl i ance wi th
thi s paragraph.
(c) The owner or operator shal l up-
date the safety i nformati on i f a maj or
change occurs that makes the i nforma-
ti on i naccurate.
68.50 Hazard review.
(a) The owner or operator shal l con-
duct a revi ew of the hazards associ ated
wi th the regul ated substances, process,
and procedures. The revi ew shal l i den-
ti fy the fol l owi ng:
(1) The hazards associ ated wi th the
process and regul ated substances;
(2) Opportuni ti es for equi pment mal -
functi ons or human errors that coul d
cause an acci dental rel ease;
(3) The safeguards used or needed to
control the hazards or prevent equi p-
ment mal functi on or human error; and
(4) Any steps used or needed to detect
or moni tor rel eases.
(b) The owner or operator may use
checkl i sts devel oped by persons or or-
gani zati ons knowl edgeabl e about the
process and equi pment as a gui de to
conducti ng the revi ew. F or processes
desi gned to meet i ndustry standards or
F ederal or state desi gn rul es, the haz-
ard revi ew shal l , by i nspecti ng al l
equi pment, determi ne whether the
process i s desi gned, fabri cated, and op-
erated i n accordance wi th the appl i ca-
bl e standards or rul es.
(c) The owner or operator shal l docu-
ment the resul ts of the revi ew and en-
sure that probl ems i denti fi ed are re-
sol ved i n a ti mel y manner.
(d) The revi ew shal l be updated at
l east once every fi ve years. The owner
or operator shal l al so conduct revi ews
whenever a maj or change i n the proc-
ess occurs; al l i ssues i denti fi ed i n the
revi ew shal l be resol ved before startup
of the changed process.
68.52 Operating procedures.
(a) The owner or operator shal l pre-
pare wri tten operati ng procedures that
provi de cl ear i nstructi ons or steps for
safel y conducti ng acti vi ti es associ ated
wi th each covered process consi stent
wi th the safety i nformati on for that
process. Operati ng procedures or i n-
structi ons provi ded by equi pment man-
ufacturers or devel oped by persons or
organi zati ons knowl edgeabl e about the
process and equi pment may be used as
a basi s for a stati onary sources oper-
ati ng procedures.
(b) The procedures shal l address the
fol l owi ng:
(1) I ni ti al startup;
(2) Normal operati ons;
(3) Temporary operati ons;
(4) Emergency shutdown and oper-
ati ons;
(5) Normal shutdown;
(6) Startup fol l owi ng a normal or
emergency shutdown or a maj or change
that requi res a hazard revi ew;
(7) Consequences of devi ati ons and
steps requi red to correct or avoi d devi -
ati ons; and
(8) Equi pment i nspecti ons.
(c) The owner or operator shal l en-
sure that the operati ng procedures are
updated, i f necessary, whenever a
maj or change occurs and pri or to start-
up of the changed process.
68.54 Training.
(a) The owner or operator shal l en-
sure that each empl oyee presentl y op-
erati ng a process, and each empl oyee
newl y assi gned to a covered process
have been trai ned or tested competent
i n the operati ng procedures provi ded i n
68.52 that pertai n to thei r duti es. F or
those empl oyees al ready operati ng a
process on J une 21, 1999, the owner or
operator may certi fy i n wri ti ng that
the empl oyee has the requi red knowl -
edge, ski l l s, and abi l i ti es to safel y
carry out the duti es and responsi bi l -
i ti es as provi ded i n the operati ng pro-
cedures.
(b) Refresher trai ni ng. Refresher
trai ni ng shal l be provi ded at l east
every three years, and more often i f
12
necessary, to each empl oyee operati ng
a process to ensure that the empl oyee
understands and adheres to the current
operati ng procedures of the process.
The owner or operator, i n consul tati on
wi th the empl oyees operati ng the proc-
ess, shal l determi ne the appropri ate
frequency of refresher trai ni ng.
(c) The owner or operator may use
trai ni ng conducted under F ederal or
state regul ati ons or under i ndustry-
speci fi c standards or codes or trai ni ng
conducted by covered process equi p-
ment vendors to demonstrate compl i -
ance wi th thi s secti on to the extent
that the trai ni ng meets the requi re-
ments of thi s secti on.
(d) The owner or operator shal l en-
sure that operators are trai ned i n any
updated or new procedures pri or to
startup of a process after a maj or
change.
68.56 Maintenance.
(a) The owner or operator shal l pre-
pare and i mpl ement procedures to
mai ntai n the on-goi ng mechani cal i n-
tegri ty of the process equi pment. The
owner or operator may use procedures
or i nstructi ons provi ded by covered
process equi pment vendors or proce-
dures i n F ederal or state regul ati ons or
i ndustry codes as the basi s for sta-
ti onary source mai ntenance proce-
dures.
(b) The owner or operator shal l trai n
or cause to be trai ned each empl oyee
i nvol ved i n mai ntai ni ng the on-goi ng
mechani cal i ntegri ty of the process. To
ensure that the empl oyee can perform
the j ob tasks i n a safe manner, each
such empl oyee shal l be trai ned i n the
hazards of the process, i n how to avoi d
or correct unsafe condi ti ons, and i n the
procedures appl i cabl e to the empl oy-
ees j ob tasks.
(c) Any mai ntenance contractor shal l
ensure that each contract mai ntenance
empl oyee i s trai ned to perform the
mai ntenance procedures devel oped
under paragraph (a) of thi s secti on.
(d) The owner or operator shal l per-
form or cause to be performed i nspec-
ti ons and tests on process equi pment.
I nspecti on and testi ng procedures shal l
fol l ow recogni zed and general l y accept-
ed good engi neeri ng practi ces. The fre-
quency of i nspecti ons and tests of proc-
ess equi pment shal l be consi stent wi th
68.60
appl i cabl e manufacturers rec-
ommendati ons, i ndustry standards or
codes, good engi neeri ng practi ces, and
pri or operati ng experi ence.
68.58 Compliance audits.
(a) The owner or operator shal l cer-
ti fy that they have eval uated compl i -
ance wi th the provi si ons of thi s sub-
part at l east every three years to
veri fy that the procedures and prac-
ti ces devel oped under the rul e are ade-
quate and are bei ng fol l owed.
(b) The compl i ance audi t shal l be
conducted by at l east one person
knowl edgeabl e i n the process.
(c) The owner or operator shal l de-
vel op a report of the audi t fi ndi ngs.
(d) The owner or operator shal l
promptl y determi ne and document an
appropri ate response to each of the
fi ndi ngs of the compl i ance audi t and
document that defi ci enci es have been
corrected.
(e) The owner or operator shal l retai n
the two (2) most recent compl i ance
audi t reports. Thi s requi rement does
not appl y to any compl i ance audi t re-
port that i s more than fi ve years ol d.
68.60 Incident investigation.
(a) The owner or operator shal l i nves-
ti gate each i nci dent whi ch resul ted i n,
or coul d reasonabl y have resul ted i n a
catastrophi c rel ease.
(b) An i nci dent i nvesti gati on shal l be
i ni ti ated as promptl y as possi bl e, but
not l ater than 48 hours fol l owi ng the
i nci dent.
(c) A summary shal l be prepared at
the concl usi on of the i nvesti gati on
whi ch i ncl udes at a mi ni mum:
(1) Date of i nci dent;
(2) Date i nvesti gati on began;
(3) A descri pti on of the i nci dent;
(4) The factors that contri buted to
the i nci dent; and,
(5) Any recommendati ons resul ti ng
from the i nvesti gati on.
promptl y address and resol ve the i nves-
ti gati on fi ndi ngs and recommenda-
ti ons. Resol uti ons and correcti ve ac-
ti ons shal l be documented.
(e) The fi ndi ngs shal l be revi ewed
wi th al l affected personnel whose j ob
tasks are affected by the fi ndi ngs.
(f) I nvesti gati on summari es shal l be
retai ned for fi ve years.
13
68.65
Subpart DProgram 3 Prevention
Program
otherwi se noted.
68.65 Process safety information.
(a) I n accordance wi th the schedul e
set forth i n 68.67, the owner or oper-
ator shal l compl ete a compi l ati on of
wri tten process safety i nformati on be-
fore conducti ng any process hazard
anal ysi s requi red by the rul e. The com-
pi l ati on of wri tten process safety i nfor-
mati on i s to enabl e the owner or oper-
ator and the empl oyees i nvol ved i n op-
erati ng the process to i denti fy and un-
derstand the hazards posed by those
processes i nvol vi ng regul ated sub-
stances. Thi s process safety i nforma-
ti on shal l i ncl ude i nformati on per-
tai ni ng to the hazards of the regul ated
substances used or produced by the
process, i nformati on pertai ni ng to the
technol ogy of the process, and i nforma-
ti on pertai ni ng to the equi pment i n the
process.
(b) I nformati on pertai ni ng to the
hazards of the regul ated substances i n
the process. Thi s i nformati on shal l
consi st of at l east the fol l owi ng:
(1) Toxi ci ty i nformati on;
(2) Permi ssi bl e exposure l i mi ts;
(3) Physi cal data;
(4) Reacti vi ty data:
(5) Corrosi vi ty data;
(6) Thermal and chemi cal stabi l i ty
data; and
(7) Hazardous effects of i nadvertent
mi xi ng of di fferent materi al s that
coul d foreseeabl y occur.
NOTE TO PARAGRAPH (b): Materi al Safety
Data Sheets meeti ng the requi rements of 29
CF R 1910.1200(g) may be used to compl y wi th
thi s requi rement to the extent they contai n
the i nformati on requi red by thi s subpara-
graph.
(c) I nformati on pertai ni ng to the
technol ogy of the process.
(1) I nformati on concerni ng the tech-
nol ogy of the process shal l i ncl ude at
l east the fol l owi ng:
(i ) A bl ock fl ow di agram or si mpl i fi ed
process fl ow di agram;
(i i ) Process chemi stry;
(i i i ) Maxi mum i ntended i nventory;
(i v) Safe upper and l ower l i mi ts for
such i tems as temperatures, pressures,
fl ows or composi ti ons; and,
(v) An eval uati on of the consequences
of devi ati ons.
(2) Where the ori gi nal techni cal i n-
formati on no l onger exi sts, such i nfor-
mati on may be devel oped i n conj unc-
ti on wi th the process hazard anal ysi s
i n suffi ci ent detai l to support the anal -
ysi s.
(d) I nformati on pertai ni ng to the
equi pment i n the process.
(1) I nformati on pertai ni ng to the
equi pment i n the process shal l i ncl ude:
(i ) Materi al s of constructi on;
(i i ) Pi pi ng and i nstrument di agrams
(P&I Ds);
(i i i ) El ectri cal cl assi fi cati on;
(i v) Rel i ef system desi gn and desi gn
basi s;
(v) Venti l ati on system desi gn;
(vi ) Desi gn codes and standards em-
pl oyed;
(vi i ) Materi al and energy bal ances for
processes bui l t after J une 21, 1999; and
(vi i i ) Safety systems (e.g. i nterl ocks,
detecti on or suppressi on systems).
(2) The owner or operator shal l docu-
ment that equi pment compl i es wi th
recogni zed and general l y accepted good
engi neeri ng practi ces.
(3) F or exi sti ng equi pment desi gned
and constructed i n accordance wi th
codes, standards, or practi ces that are
no l onger i n general use, the owner or
operator shal l determi ne and document
that the equi pment i s desi gned, mai n-
tai ned, i nspected, tested, and operati ng
i n a safe manner.
68.67 Process hazard analysis.
(a) The owner or operator shal l per-
form an i ni ti al process hazard anal ysi s
(hazard eval uati on) on processes cov-
ered by thi s part. The process hazard
anal ysi s shal l be appropri ate to the
compl exi ty of the process and shal l
i denti fy, eval uate, and control the haz-
ards i nvol ved i n the process. The owner
or operator shal l determi ne and docu-
ment the pri ori ty order for conducti ng
process hazard anal yses based on a ra-
ti onal e whi ch i ncl udes such consi der-
ati ons as extent of the process hazards,
number of potenti al l y affected empl oy-
ees, age of the process, and operati ng
hi story of the process. The process haz-
ard anal ysi s shal l be conducted as soon
as possi bl e, but not l ater than J une 21,
1999. Process hazards anal yses com-
pl eted to compl y wi th 29 CF R
14
1910.119(e) are acceptabl e as i ni ti al
process hazards anal yses. These process
hazard anal yses shal l be updated and
reval i dated, based on thei r compl eti on
date.
(b) The owner or operator shal l use
one or more of the fol l owi ng meth-
odol ogi es that are appropri ate to deter-
mi ne and eval uate the hazards of the
process bei ng anal yzed.
(1) What-I f;
(2) Checkl i st;
(3) What-I f/Checkl i st;
(4) Hazard and Operabi l i ty Study
(HAZOP);
(5) F ai l ure Mode and Effects Anal ysi s
(F MEA);
(6) F aul t Tree Anal ysi s; or
(7) An appropri ate equi val ent meth-
odol ogy.
(c) The process hazard anal ysi s shal l
address:
(1) The hazards of the process;
(2) The i denti fi cati on of any previ ous
i nci dent whi ch had a l i kel y potenti al
for catastrophi c consequences.
(3) Engi neeri ng and admi ni strati ve
control s appl i cabl e to the hazards and
thei r i nterrel ati onshi ps such as appro-
pri ate appl i cati on of detecti on meth-
odol ogi es to provi de earl y warni ng of
rel eases. (Acceptabl e detecti on meth-
ods mi ght i ncl ude process moni tori ng
and control i nstrumentati on wi th
al arms, and detecti on hardware such as
hydrocarbon sensors.);
(4) Consequences of fai l ure of engi -
neeri ng and admi ni strati ve control s;
(5) Stati onary source si ti ng;
(6) Human factors; and
(7) A qual i tati ve eval uati on of a
range of the possi bl e safety and heal th
effects of fai l ure of control s.
(d) The process hazard anal ysi s shal l
be performed by a team wi th experti se
i n engi neeri ng and process operati ons,
and the team shal l i ncl ude at l east one
empl oyee who has experi ence and
knowl edge speci fi c to the process bei ng
eval uated. Al so, one member of the
team must be knowl edgeabl e i n the
speci fi c process hazard anal ysi s meth-
odol ogy bei ng used.
(e) The owner or operator shal l estab-
l i sh a system to promptl y address the
teams fi ndi ngs and recommendati ons;
assure that the recommendati ons are
resol ved i n a ti mel y manner and that
the resol uti on i s documented; docu-
68.69
ment what acti ons are to be taken;
compl ete acti ons as soon as possi bl e;
devel op a wri tten schedul e of when
these acti ons are to be compl eted; com-
muni cate the acti ons to operati ng,
mai ntenance and other empl oyees
whose work assi gnments are i n the
process and who may be affected by the
recommendati ons or acti ons.
(f) At l east every fi ve (5) years after
the compl eti on of the i ni ti al process
hazard anal ysi s, the process hazard
anal ysi s shal l be updated and reval i -
dated by a team meeti ng the requi re-
ments i n paragraph (d) of thi s secti on,
to assure that the process hazard anal -
ysi s i s consi stent wi th the current
process. Updated and reval i dated proc-
ess hazard anal yses compl eted to com-
pl y wi th 29 CF R 1910.119(e) are accept-
abl e to meet the requi rements of thi s
paragraph.
(g) The owner or operator shal l re-
tai n process hazards anal yses and up-
dates or reval i dati ons for each process
covered by thi s secti on, as wel l as the
documented resol uti on of recommenda-
ti ons descri bed i n paragraph (e) of thi s
secti on for the l i fe of the process.
68.69 Operating procedures.
(a) The owner or operator shal l de-
vel op and i mpl ement wri tten operati ng
procedures that provi de cl ear i nstruc-
ti ons for safel y conducti ng acti vi ti es
i nvol ved i n each covered process con-
si stent wi th the process safety i nfor-
mati on and shal l address at l east the
fol l owi ng el ements.
(1) Steps for each operati ng phase:
(i ) I ni ti al startup;
(i i ) Normal operati ons;
(i i i ) Temporary operati ons;
(i v) Emergency shutdown i ncl udi ng
the condi ti ons under whi ch emergency
shutdown i s requi red, and the assi gn-
ment of shutdown responsi bi l i ty to
qual i fi ed operators to ensure that
emergency shutdown i s executed i n a
safe and ti mel y manner.
(v) Emergency operati ons;
(vi ) Normal shutdown; and,
(vi i ) Startup fol l owi ng a turnaround,
or after an emergency shutdown.
(2) Operati ng l i mi ts:
(i ) Consequences of devi ati on; and
(i i ) Steps requi red to correct or avoi d
devi ati on.
(3) Safety and heal th consi derati ons:
15
68.71
(i ) Properti es of, and hazards pre-
sented by, the chemi cal s used i n the
process;
(i i ) Precauti ons necessary to prevent
exposure, i ncl udi ng engi neeri ng con-
trol s, admi ni strati ve control s, and per-
sonal protecti ve equi pment;
(i i i ) Control measures to be taken i f
physi cal contact or ai rborne exposure
occurs;
(i v) Qual i ty control for raw materi al s
and control of hazardous chemi cal i n-
ventory l evel s; and,
(v) Any speci al or uni que hazards.
(4) Safety systems and thei r func-
ti ons.
(b) Operati ng procedures shal l be
readi l y accessi bl e to empl oyees who
work i n or mai ntai n a process.
(c) The operati ng procedures shal l be
revi ewed as often as necessary to as-
sure that they refl ect current oper-
ati ng practi ce, i ncl udi ng changes that
resul t from changes i n process chemi -
cal s, technol ogy, and equi pment, and
changes to stati onary sources. The
owner or operator shal l certi fy annu-
al l y that these operati ng procedures
are current and accurate.
(d) The owner or operator shal l de-
vel op and i mpl ement safe work prac-
ti ces to provi de for the control of haz-
ards duri ng operati ons such as l ockout/
tagout; confi ned space entry; openi ng
process equi pment or pi pi ng; and con-
trol over entrance i nto a stati onary
source by mai ntenance, contractor,
l aboratory, or other support personnel .
These safe work practi ces shal l appl y
to empl oyees and contractor empl oy-
ees.
68.71 Training.
(a) I nitial training. (1) Each empl oyee
presentl y i nvol ved i n operati ng a proc-
ess, and each empl oyee before bei ng i n-
vol ved i n operati ng a newl y assi gned
process, shal l be trai ned i n an overvi ew
of the process and i n the operati ng pro-
cedures as speci fi ed i n 68.69. The
trai ni ng shal l i ncl ude emphasi s on the
speci fi c safety and heal th hazards,
emergency operati ons i ncl udi ng shut-
down, and safe work practi ces appl i ca-
bl e to the empl oyees j ob tasks.
(2) I n l i eu of i ni ti al trai ni ng for those
empl oyees al ready i nvol ved i n oper-
ati ng a process on J une 21, 1999 an
owner or operator may certi fy i n wri t-
i ng that the empl oyee has the requi red
knowl edge, ski l l s, and abi l i ti es to safe-
l y carry out the duti es and responsi bi l -
i ti es as speci fi ed i n the operati ng pro-
cedures.
(b) Refresher training. Refresher trai n-
i ng shal l be provi ded at l east every
three years, and more often i f nec-
essary, to each empl oyee i nvol ved i n
operati ng a process to assure that the
empl oyee understands and adheres to
the current operati ng procedures of the
process. The owner or operator, i n con-
sul tati on wi th the empl oyees i nvol ved
i n operati ng the process, shal l deter-
mi ne the appropri ate frequency of re-
fresher trai ni ng.
(c) Training documentation. The owner
or operator shal l ascertai n that each
empl oyee i nvol ved i n operati ng a proc-
ess has recei ved and understood the
trai ni ng requi red by thi s paragraph.
The owner or operator shal l prepare a
record whi ch contai ns the i denti ty of
the empl oyee, the date of trai ni ng, and
the means used to veri fy that the em-
pl oyee understood the trai ni ng.
68.73 Mechanical integrity.
(a) Application. Paragraphs (b)
through (f) of thi s secti on appl y to the
fol l owi ng process equi pment:
(1) Pressure vessel s and storage
tanks;
(2) Pi pi ng systems (i ncl udi ng pi pi ng
components such as val ves);
(3) Rel i ef and vent systems and de-
vi ces;
(4) Emergency shutdown systems;
(5) Control s (i ncl udi ng moni tori ng
devi ces and sensors, al arms, and i nter-
l ocks) and,
(6) Pumps.
(b) Written procedures. The owner or
operator shal l establ i sh and i mpl ement
wri tten procedures to mai ntai n the on-
goi ng i ntegri ty of process equi pment.
(c) Training for process maintenance
activities. The owner or operator shal l
trai n each empl oyee i nvol ved i n mai n-
tai ni ng the on-goi ng i ntegri ty of proc-
ess equi pment i n an overvi ew of that
process and i ts hazards and i n the pro-
cedures appl i cabl e to the empl oyees
j ob tasks to assure that the empl oyee
can perform the j ob tasks i n a safe
manner.
16
(d) I nspection and testing. (1) I nspec-
ti ons and tests shal l be performed on
process equi pment.
(2) I nspecti on and testi ng procedures
shal l fol l ow recogni zed and general l y
accepted good engi neeri ng practi ces.
(3) The frequency of i nspecti ons and
tests of process equi pment shal l be con-
si stent wi th appl i cabl e manufacturers
recommendati ons and good engi neeri ng
practi ces, and more frequentl y i f deter-
mi ned to be necessary by pri or oper-
ati ng experi ence.
(4) The owner or operator shal l docu-
ment each i nspecti on and test that has
been performed on process equi pment.
The documentati on shal l i denti fy the
date of the i nspecti on or test, the name
of the person who performed the i n-
specti on or test, the seri al number or
other i denti fi er of the equi pment on
whi ch the i nspecti on or test was per-
formed, a descri pti on of the i nspecti on
or test performed, and the resul ts of
the i nspecti on or test.
(e) Equipment deficiencies. The owner
or operator shal l correct defi ci enci es i n
equi pment that are outsi de acceptabl e
l i mi ts (defi ned by the process safety i n-
formati on i n 68.65) before further use
or i n a safe and ti mel y manner when
necessary means are taken to assure
safe operati on.
(f) Quality assurance. (1) I n the con-
structi on of new pl ants and equi pment,
the owner or operator shal l assure that
equi pment as i t i s fabri cated i s sui t-
abl e for the process appl i cati on for
whi ch they wi l l be used.
(2) Appropri ate checks and i nspec-
ti ons shal l be performed to assure that
equi pment i s i nstal l ed properl y and
consi stent wi th desi gn speci fi cati ons
and the manufacturers i nstructi ons.
(3) The owner or operator shal l as-
sure that mai ntenance materi al s, spare
parts and equi pment are sui tabl e for
the process appl i cati on for whi ch they
wi l l be used.
68.75 Management of change.
(a) The owner or operator shal l estab-
l i sh and i mpl ement wri tten procedures
to manage changes (except for re-
pl acements i n ki nd) to process chemi -
cal s, technol ogy, equi pment, and proce-
dures; and, changes to stati onary
sources that affect a covered process.
68.77
(b) The procedures shal l assure that
the fol l owi ng consi derati ons are ad-
dressed pri or to any change:
(1) The techni cal basi s for the pro-
posed change;
(2) I mpact of change on safety and
heal th;
(3) Modi fi cati ons to operati ng proce-
dures;
(4) Necessary ti me peri od for the
change; and,
(5) Authori zati on requi rements for
the proposed change.
(c) Empl oyees i nvol ved i n operati ng a
process and mai ntenance and contract
empl oyees whose j ob tasks wi l l be af-
fected by a change i n the process shal l
be i nformed of, and trai ned i n, the
change pri or to start-up of the process
or affected part of the process.
(d) I f a change covered by thi s para-
graph resul ts i n a change i n the process
safety i nformati on requi red by 68.65 of
thi s part, such i nformati on shal l be up-
dated accordi ngl y.
(e) I f a change covered by thi s para-
graph resul ts i n a change i n the oper-
ati ng procedures or practi ces requi red
by 68.69, such procedures or practi ces
shal l be updated accordi ngl y.
68.77 Pre-startup review.
(a) The owner or operator shal l per-
form a pre-startup safety revi ew for
new stati onary sources and for modi -
fi ed stati onary sources when the modi -
fi cati on i s si gni fi cant enough to re-
qui re a change i n the process safety i n-
formati on.
(b) The pre-startup safety revi ew
shal l confi rm that pri or to the i ntro-
ducti on of regul ated substances to a
process:
(1) Constructi on and equi pment i s i n
accordance wi th desi gn speci fi cati ons;
(2) Safety, operati ng, mai ntenance,
and emergency procedures are i n pl ace
and are adequate;
(3) F or new stati onary sources, a
process hazard anal ysi s has been per-
formed and recommendati ons have
been resol ved or i mpl emented before
startup; and modi fi ed stati onary
sources meet the requi rements con-
tai ned i n management of change,
68.75.
(4) Trai ni ng of each empl oyee i n-
vol ved i n operati ng a process has been
compl eted.
17
68.79
68.79 Compliance audits.
(a) The owner or operator shal l cer-
ti fy that they have eval uated compl i -
ance wi th the provi si ons of thi s sub-
part at l east every three years to
veri fy that procedures and practi ces
devel oped under thi s subpart are ade-
quate and are bei ng fol l owed.
(b) The compl i ance audi t shal l be
conducted by at l east one person
knowl edgeabl e i n the process.
(c) A report of the fi ndi ngs of the
audi t shal l be devel oped.
promptl y determi ne and document an
appropri ate response to each of the
fi ndi ngs of the compl i ance audi t, and
document that defi ci enci es have been
corrected.
(e) The owner or operator shal l retai n
the two (2) most recent compl i ance
audi t reports.
F R 979, J an. 6, 1999]
68.81 Incident investigation.
(a) The owner or operator shal l i nves-
ti gate each i nci dent whi ch resul ted i n,
or coul d reasonabl y have resul ted i n a
catastrophi c rel ease of a regul ated sub-
stance.
(b) An i nci dent i nvesti gati on shal l be
i ni ti ated as promptl y as possi bl e, but
not l ater than 48 hours fol l owi ng the
i nci dent.
(c) An i nci dent i nvesti gati on team
shal l be establ i shed and consi st of at
l east one person knowl edgeabl e i n the
process i nvol ved, i ncl udi ng a contract
empl oyee i f the i nci dent i nvol ved work
of the contractor, and other persons
wi th appropri ate knowl edge and experi -
ence to thoroughl y i nvesti gate and
anal yze the i nci dent.
(d) A report shal l be prepared at the
concl usi on of the i nvesti gati on whi ch
i ncl udes at a mi ni mum:
(1) Date of i nci dent;
(2) Date i nvesti gati on began;
(3) A descri pti on of the i nci dent;
(4) The factors that contri buted to
the i nci dent; and,
(5) Any recommendati ons resul ti ng
from the i nvesti gati on.
(e) The owner or operator shal l estab-
l i sh a system to promptl y address and
resol ve the i nci dent report fi ndi ngs and
recommendati ons. Resol uti ons and cor-
recti ve acti ons shal l be documented.
(f) The report shal l be revi ewed wi th
al l affected personnel whose j ob tasks
are rel evant to the i nci dent fi ndi ngs i n-
cl udi ng contract empl oyees where ap-
pl i cabl e.
(g) I nci dent i nvesti gati on reports
shal l be retai ned for fi ve years.
68.83 Employee participation.
vel op a wri tten pl an of acti on regard-
i ng the i mpl ementati on of the em-
pl oyee parti ci pati on requi red by thi s
secti on.
(b) The owner or operator shal l con-
sul t wi th empl oyees and thei r rep-
resentati ves on the conduct and devel -
opment of process hazards anal yses and
on the devel opment of the other el e-
ments of process safety management i n
thi s rul e.
(c) The owner or operator shal l pro-
vi de to empl oyees and thei r representa-
ti ves access to process hazard anal yses
and to al l other i nformati on requi red
to be devel oped under thi s rul e.
68.85 Hot work permit.
(a) The owner or operator shal l i ssue
a hot work permi t for hot work oper-
ati ons conducted on or near a covered
process.
(b) The permi t shal l document that
the fi re preventi on and protecti on re-
qui rements i n 29 CF R 1910.252(a) have
been i mpl emented pri or to begi nni ng
the hot work operati ons; i t shal l i ndi -
cate the date(s) authori zed for hot
work; and i denti fy the obj ect on whi ch
hot work i s to be performed. The per-
mi t shal l be kept on fi l e unti l compl e-
ti on of the hot work operati ons.
68.87 Contractors.
(a) Application. Thi s secti on appl i es
to contractors performi ng mai ntenance
or repai r, turnaround, maj or renova-
ti on, or speci al ty work on or adj acent
to a covered process. I t does not appl y
to contractors provi di ng i nci dental
servi ces whi ch do not i nfl uence process
safety, such as j ani tori al work, food
and dri nk servi ces, l aundry, del i very or
other suppl y servi ces.
(b) Owner or operator responsibilities.
(1) The owner or operator, when sel ect-
i ng a contractor, shal l obtai n and
18
eval uate i nformati on regardi ng the
contract owner or operators safety
performance and programs.
(2) The owner or operator shal l i n-
form contract owner or operator of the
known potenti al fi re, expl osi on, or
toxi c rel ease hazards rel ated to the
contractors work and the process.
(3) The owner or operator shal l ex-
pl ai n to the contract owner or operator
the appl i cabl e provi si ons of subpart E
of thi s part.
(4) The owner or operator shal l de-
vel op and i mpl ement safe work prac-
ti ces consi stent wi th 68.69(d), to con-
trol the entrance, presence, and exi t of
the contract owner or operator and
contract empl oyees i n covered process
areas.
(5) The owner or operator shal l peri -
odi cal l y eval uate the performance of
the contract owner or operator i n ful -
fi l l i ng thei r obl i gati ons as speci fi ed i n
paragraph (c) of thi s secti on.
(c) Contract owner or operator respon-
sibilities. (1) The contract owner or op-
erator shal l assure that each contract
empl oyee i s trai ned i n the work prac-
ti ces necessary to safel y perform hi s/
her j ob.
(2) The contract owner or operator
shal l assure that each contract em-
pl oyee i s i nstructed i n the known po-
tenti al fi re, expl osi on, or toxi c rel ease
hazards rel ated to hi s/her j ob and the
process, and the appl i cabl e provi si ons
of the emergency acti on pl an.
shal l document that each contract em-
pl oyee has recei ved and understood the
trai ni ng requi red by thi s secti on. The
contract owner or operator shal l pre-
pare a record whi ch contai ns the i den-
ti ty of the contract empl oyee, the date
of trai ni ng, and the means used to
veri fy that the empl oyee understood
the trai ni ng.
shal l assure that each contract em-
pl oyee fol l ows the safety rul es of the
stati onary source i ncl udi ng the safe
work practi ces requi red by 68.69(d).
shal l advi se the owner or operator of
any uni que hazards presented by the
contract owner or operators work, or
of any hazards found by the contract
owner or operators work.
68.95
Subpart EEmergency Response
otherwi se noted.
(a) Except as provi ded i n paragraph
(b) of thi s secti on, the owner or oper-
ator of a stati onary source wi th Pro-
gram 2 and Program 3 processes shal l
compl y wi th the requi rements of 68.95.
(b) The owner or operator of sta-
ti onary source whose empl oyees wi l l
not respond to acci dental rel eases of
regul ated substances need not compl y
wi th 68.95 of thi s part provi ded that
they meet the fol l owi ng:
(1) F or stati onary sources wi th any
regul ated toxi c substance hel d i n a
process above the threshol d quanti ty,
the stati onary source i s i ncl uded i n the
communi ty emergency response pl an
devel oped under 42 U.S.C. 11003;
(2) F or stati onary sources wi th onl y
regul ated fl ammabl e substances hel d i n
a process above the threshol d quanti ty,
the owner or operator has coordi nated
response acti ons wi th the l ocal fi re de-
partment; and
(3) Appropri ate mechani sms are i n
pl ace to noti fy emergency responders
when there i s a need for a response.
vel op and i mpl ement an emergency re-
sponse program for the purpose of pro-
tecti ng publ i c heal th and the envi ron-
ment. Such program shal l i ncl ude the
fol l owi ng el ements:
(1) An emergency response pl an,
whi ch shal l be mai ntai ned at the sta-
ti onary source and contai n at l east the
fol l owi ng el ements:
(i ) Procedures for i nformi ng the pub-
l i c and l ocal emergency response agen-
ci es about acci dental rel eases;
(i i ) Documentati on of proper fi rst-ai d
and emergency medi cal treatment nec-
essary to treat acci dental human expo-
sures; and
(i i i ) Procedures and measures for
emergency response after an acci dental
rel ease of a regul ated substance;
(2) Procedures for the use of emer-
gency response equi pment and for i ts
i nspecti on, testi ng, and mai ntenance;
(3) Trai ni ng for al l empl oyees i n rel -
evant procedures; and
19
68.100
(4) Procedures to revi ew and update,
as appropri ate, the emergency response
pl an to refl ect changes at the sta-
ti onary source and ensure that empl oy-
ees are i nformed of changes.
(b) A wri tten pl an that compl i es wi th
other F ederal conti ngency pl an regul a-
ti ons or i s consi stent wi th the ap-
proach i n the Nati onal Response
Teams I ntegrated Conti ngency Pl an
Gui dance (One Pl an) and that,
among other matters, i ncl udes the el e-
ments provi ded i n paragraph (a) of thi s
secti on, shal l sati sfy the requi rements
of thi s secti on i f the owner or operator
al so compl i es wi th paragraph (c) of thi s
secti on.
(c) The emergency response pl an de-
vel oped under paragraph (a)(1) of thi s
secti on shal l be coordi nated wi th the
communi ty emergency response pl an
devel oped under 42 U.S.C. 11003. Upon
request of the l ocal emergency pl an-
ni ng commi ttee or emergency response
offi ci al s, the owner or operator shal l
promptl y provi de to the l ocal emer-
gency response offi ci al s i nformati on
necessary for devel opi ng and i mpl e-
menti ng the communi ty emergency re-
sponse pl an.
Subpart FRegulated Substances
for Accidental Release Prevention
SOURCE: 59 F R 4493, J an. 31, 1994, unl ess
otherwi se noted. Redesi gnated at 61 F R 31717,
J une 20, 1996.
68.100 Purpose.
Thi s subpart desi gnates substances
to be l i sted under secti on 112(r)(3), (4),
and (5) of the Cl ean Ai r Act, as amend-
ed, i denti fi es thei r threshol d quan-
ti ti es, and establ i shes the requi rements
for peti ti oni ng to add or del ete sub-
stances from the l i st.
68.115 Threshold determination.
(a) A threshol d quanti ty of a regu-
l ated substance l i sted i n 68.130 i s
present at a stati onary source i f the
total quanti ty of the regul ated sub-
stance contai ned i n a process exceeds
the threshol d.
(b) F or the purposes of determi ni ng
whether more than a threshol d quan-
ti ty of a regul ated substance i s present
at the stati onary source, the fol l owi ng
exempti ons appl y:
(1) Concentrations of a regulated toxic
substance in a mixture. I f a regul ated
substance i s present i n a mi xture and
the concentrati on of the substance i s
bel ow one percent by wei ght of the
mi xture, the amount of the substance
i n the mi xture need not be consi dered
when determi ni ng whether more than a
threshol d quanti ty i s present at the
stati onary source. Except for ol eum,
tol uene 2,4-di i socyanate, tol uene 2,6-
di i socyanate, and tol uene di i socyanate
(unspeci fi ed i somer), i f the concentra-
ti on of the regul ated substance i n the
mi xture i s one percent or greater by
wei ght, but the owner or operator can
demonstrate that the parti al pressure
of the regul ated substance i n the mi x-
ture (sol uti on) under handl i ng or stor-
age condi ti ons i n any porti on of the
process i s l ess than 10 mi l l i meters of
mercury (mm Hg), the amount of the
substance i n the mi xture i n that por-
ti on of the process need not be consi d-
ered when determi ni ng whether more
than a threshol d quanti ty i s present at
the stati onary source. The owner or op-
erator shal l document thi s parti al pres-
sure measurement or esti mate.
(2) Concentrations of a regulated flam-
mable substance in a mixture. (i ) General
provision. I f a regul ated substance i s
present i n a mi xture and the con-
centrati on of the substance i s bel ow
one percent by wei ght of the mi xture,
the mi xture need not be consi dered
threshol d quanti ty of the regul ated
substance i s present at the stati onary
source. Except as provi ded i n para-
graph (b)(2) (i i ) and (i i i ) of thi s secti on,
i f the concentrati on of the substance i s
one percent or greater by wei ght of the
mi xture, then, for purposes of deter-
mi ni ng whether a threshol d quanti ty i s
present at the stati onary source, the
enti re wei ght of the mi xture shal l be
treated as the regul ated substance un-
l ess the owner or operator can dem-
onstrate that the mi xture i tsel f does
not have a Nati onal F i re Protecti on
Associ ati on fl ammabi l i ty hazard rat-
i ng of 4. The demonstrati on shal l be i n
accordance wi th the defi ni ti on of fl am-
mabi l i ty hazard rati ng 4 i n the NF PA
704, Standard System for the I denti -
fi cati on of the Hazards of Materi al s for
Emergency Response, Nati onal F i re
Protecti on Associ ati on, Qui ncy, MA,
20
1996. Avai l abl e from the Nati onal F i re
Protecti on Associ ati on, 1
Batterymarch Park, Qui ncy, MA 02269
9101. Thi s i ncorporati on by reference
was approved by the Di rector of the
F ederal Regi ster i n accordance wi th 5
U.S.C. 552(a) and 1 CF R part 51. Copi es
may be i nspected at the Envi ronmental
Protecti on Agency Ai r Docket (6102),
Attn: Docket No. A96O8, Watersi de
Mal l , 401 M. St. SW., Washi ngton DC;
or at the Offi ce of F ederal Regi ster at
800 North Capi tol St., NW, Sui te 700,
Washi ngton, DC. Boi l i ng poi nt and
fl ash poi nt shal l be defi ned and deter-
mi ned i n accordance wi th NF PA 30,
F l ammabl e and Combusti bl e L i qui ds
Code, Nati onal F i re Protecti on Asso-
ci ati on, Qui ncy, MA, 1996. Avai l abl e
from the Nati onal F i re Protecti on As-
soci ati on, 1 Batterymarch Park, Qui n-
cy, MA 022699101. Thi s i ncorporati on
by reference was approved by the Di -
rector of the F ederal Regi ster i n ac-
cordance wi th 5 U.S.C. 552(a) and 1 CF R
part 51. Copi es may be i nspected at the
Envi ronmental Protecti on Agency Ai r
Docket (6102), Attn: Docket No. A96
O8, Watersi de Mal l , 401 M. St. SW.,
Washi ngton DC; or at the Offi ce of F ed-
eral Regi ster at 800 North Capi tol St.,
NW., Sui te 700, Washi ngton, DC. The
owner or operator shal l document the
Nati onal F i re Protecti on Associ ati on
fl ammabi l i ty hazard rati ng.
(i i ) Gasoline. Regul ated substances i n
gasol i ne, when i n di stri buti on or re-
l ated storage for use as fuel for i nter-
nal combusti on engi nes, need not be
consi dered when determi ni ng whether
more than a threshol d quanti ty i s
present at a stati onary source.
(i i i ) Naturally occurring hydrocarbon
mixtures. Pri or to entry i nto a natural
gas processi ng pl ant or a petrol eum re-
fi ni ng process uni t, regul ated sub-
stances i n natural l y occurri ng hydro-
carbon mi xtures need not be consi dered
threshol d quanti ty i s present at a sta-
ti onary source. Natural l y occurri ng
hydrocarbon mi xtures i ncl ude any
combi nati on of the fol l owi ng: conden-
sate, crude oi l , fi el d gas, and produced
water, each as defi ned i n 68.3 of thi s
part.
(3) Articles. Regul ated substances con-
tai ned i n arti cl es need not be consi d-
ered when determi ni ng whether more
68.120
than a threshol d quanti ty i s present at
the stati onary source.
(4) Uses. Regul ated substances, when
i n use for the fol l owi ng purposes, need
not be i ncl uded i n determi ni ng whether
more than a threshol d quanti ty i s
present at the stati onary source:
(i ) Use as a structural component of
the stati onary source;
(i i ) Use of products for routi ne j ani -
tori al mai ntenance;
(i i i ) Use by empl oyees of foods, drugs,
cosmeti cs, or other personal i tems con-
tai ni ng the regul ated substance; and
(i v) Use of regul ated substances
present i n process water or non-contact
cool i ng water as drawn from the envi -
ronment or muni ci pal sources, or use
of regul ated substances present i n ai r
used ei ther as compressed ai r or as part
of combusti on.
(5) Activities in laboratories. I f a regu-
l ated substance i s manufactured, proc-
essed, or used i n a l aboratory at a sta-
ti onary source under the supervi si on of
a techni cal l y qual i fi ed i ndi vi dual as de-
fi ned i n 720.3(ee) of thi s chapter, the
quanti ty of the substance need not be
consi dered i n determi ni ng whether a
threshol d quanti ty i s present. Thi s ex-
empti on does not appl y to:
(i ) Speci al ty chemi cal producti on;
(i i ) Manufacture, processi ng, or use
of substances i n pi l ot pl ant scal e oper-
ati ons; and
(i i i ) Acti vi ti es conducted outsi de the
l aboratory.
[59 F R 4493, J an. 31, 1994. Redesi gnated at 61
F R 31717, J une 20, 1996, as amended at 63 F R
645, J an. 6, 1998]
68.120 Petition process.
(a) Any person may peti ti on the Ad-
mi ni strator to modi fy, by addi ti on or
del eti on, the l i st of regul ated sub-
stances i denti fi ed i n 68.130. Based on
the i nformati on presented by the peti -
ti oner, the Admi ni strator may grant or
deny a peti ti on.
(b) A substance may be added to the
l i st i f, i n the case of an acci dental re-
l ease, i t i s known to cause or may be
reasonabl y anti ci pated to cause death,
i nj ury, or seri ous adverse effects to
human heal th or the envi ronment.
(c) A substance may be del eted from
the l i st i f adequate data on the heal th
and envi ronmental effects of the sub-
stance are avai l abl e to determi ne that
21
68.125
the substance, i n the case of an acci -
dental rel ease, i s not known to cause
and may not be reasonabl y anti ci pated
to cause death, i nj ury, or seri ous ad-
verse effects to human heal th or the
envi ronment.
(d) No substance for whi ch a nati onal
pri mary ambi ent ai r qual i ty standard
has been establ i shed shal l be added to
the l i st. No substance regul ated under
ti tl e VI of the Cl ean Ai r Act, as amend-
ed, shal l be added to the l i st.
(e) The burden of proof i s on the peti -
ti oner to demonstrate that the cri teri a
for addi ti on and del eti on are met. A pe-
ti ti on wi l l be deni ed i f thi s demonstra-
ti on i s not made.
(f) The Admi ni strator wi l l not accept
addi ti onal peti ti ons on the same sub-
stance fol l owi ng publ i cati on of a fi nal
noti ce of the deci si on to grant or deny
a peti ti on, unl ess new data becomes
avai l abl e that coul d si gni fi cantl y af-
fect the basi s for the deci si on.
(g) Peti ti ons to modi fy the l i st of
regul ated substances must contai n the
fol l owi ng:
(1) Name and address of the peti -
ti oner and a bri ef descri pti on of the or-
gani zati on(s) that the peti ti oner rep-
resents, i f appl i cabl e;
(2) Name, address, and tel ephone
number of a contact person for the pe-
ti ti on;
(3) Common chemi cal name(s), com-
mon synonym(s), Chemi cal Abstracts
Servi ce number, and chemi cal formul a
and structure;
(4) Acti on requested (add or del ete a
substance);
(5) Rati onal e supporti ng the peti -
ti oners posi ti on; that i s, how the sub-
stance meets the cri teri a for addi ti on
and del eti on. A short summary of the
rati onal e must be submi tted al ong
wi th a more detai l ed narrati ve; and
(6) Supporti ng data; that i s, the peti -
ti on must i ncl ude suffi ci ent i nforma-
ti on to sci enti fi cal l y support the re-
quest to modi fy the l i st. Such i nforma-
ti on shal l i ncl ude:
(i ) A l i st of al l support documents;
(i i ) Documentati on of l i terature
searches conducted, i ncl udi ng, but not
l i mi ted to, i denti fi cati on of the data-
base(s) searched, the search strategy,
dates covered, and pri nted resul ts;
(i i i ) Effects data (ani mal , human, and
envi ronmental test data) i ndi cati ng
the potenti al for death, i nj ury, or seri -
ous adverse human and envi ronmental
i mpacts from acute exposure fol l owi ng
an acci dental rel ease; pri nted copi es of
the data sources, i n Engl i sh, shoul d be
provi ded; and
(i v) Exposure data or previ ous acci -
dent hi story data, i ndi cati ng the po-
tenti al for seri ous adverse human
heal th or envi ronmental effects from
an acci dental rel ease. These data may
i ncl ude, but are not l i mi ted to, phys-
i cal and chemi cal properti es of the sub-
stance, such as vapor pressure; mod-
el i ng resul ts, i ncl udi ng data and as-
sumpti ons used and model documenta-
ti on; and hi stori cal acci dent data, ci t-
i ng data sources.
(h) Wi thi n 18 months of recei pt of a
peti ti on, the Admi ni strator shal l pub-
l i sh i n the F EDERAL REGI STER a noti ce
ei ther denyi ng the peti ti on or granti ng
the peti ti on and proposi ng a l i sti ng.
68.125 Exemptions.
Agricultural nutrients. Ammoni a used
as an agri cul tural nutri ent, when hel d
by farmers, i s exempt from al l provi -
si ons of thi s part.
68.130 List of substances.
(a) Regul ated toxi c and fl ammabl e
substances under secti on 112(r) of the
Cl ean Ai r Act are the substances l i sted
i n Tabl es 1, 2, 3, and 4. Threshol d quan-
ti ti es for l i sted toxi c and fl ammabl e
substances are speci fi ed i n the tabl es.
(b) The basi s for pl aci ng toxi c and
fl ammabl e substances on the l i st of
regul ated substances are expl ai ned i n
the notes to the l i st.
TABLE 1 TO 68.130.L IST OF REGULATED
TOXIC SUBSTANCES AND THRESHOLD QUAN-
TITIES FOR ACCIDENTAL RELEASE PREVENTION
[Alphabetical Order77 Substances]
Chemical name CAS No.
Threshold
quantity
(lbs)
Basis for
listing
Acrolein [2- 107028 5,000 b
Propenal].
Acrylonitrile [2- 107131 20,000 b
Propenenitrile].
Acrylyl chloride 814686 5,000 b
[2-Propenoyl
chloride].
Allyl alcohol [2- 1071861 15,000 b
Propen-l-ol].
Allylamine [2- 107119 10,000 b
Propen-l-
amine].
22
Environmental Protection Agency, EPA 68.130
TABLE 1 TO 68.130.L IST OF REGULATED TABLE 1 TO 68.130.L IST OF REGULATED
TOXIC SUBSTANCES AND THRESHOLD QUAN- TOXIC SUBSTANCES AND THRESHOLD QUAN-
TITIES FOR ACCIDENTAL RELEASE PREVEN- TITIES FOR ACCIDENTAL RELEASE PREVEN-
TIONContinued TIONContinued
[Alphabetical Order77 Substances] [Alphabetical Order77 Substances]
Threshold
quantity
(lbs)
Basis for
listing
Ammonia (anhy- 7664417 10,000 a, b
drous).
Ammonia (conc 7664417 20,000 a, b
20% or greater).
Arsenous tri- 7784341 15,000 b
chloride.
Arsine ................. 7784421 1,000 b
Boron trichloride 10294345 5,000 b
[Borane,
trichloro-].
Boron trifluoride 7637072 5,000 b
[Borane,
trifluoro-].
Boron trifluoride 353424 15,000 b
compound with
methyl ether
(1:1) [Boron,
trifluoro [oxybis
[metane]]-, T-4-.
Bromine .............. 7726956 10,000 a, b
Carbon disulfide 75150 20,000 b
Chlorine .............. 7782505 2,500 a, b
Chlorine dioxide 10049044 1,000 c
[Chlorine oxide
(ClO2)].
Chloroform 67663 20,000 b
[Methane,
trichloro-].
Chloromethyl 542881 1,000 b
ether [Methane,
oxybis[chloro-].
Chloromethyl 107302 5,000 b
methyl ether
[Methane,
chloromethoxy-
].
Crotonaldehyde 4170303 20,000 b
[2-Butenal].
Crotonaldehyde, 123739 20,000 b
(E)- [2-Butenal,
(E)-].
Cyanogen chlo- 506774 10,000 c
ride.
Cyclohexylamine 108918 15,000 b
[Cyclohexana-
mine].
Diborane ............. 19287457 2,500 b
Dimethyldichloro- 75785 5,000 b
silane [Silane,
dichlorodimeth-
yl-].
1,1- 57147 15,000 b
Dimethylhydra-
zine [Hydra-
zine, 1,1-di-
methyl-].
Epichlorohydrin 106898 20,000 b
[Oxirane,
(chloromethyl)-].
Ethylenediamine 107153 20,000 b
[1,2-
Ethanediamine].
Ethyleneimine 151564 10,000 b
[Aziridine].
Threshold
quantity
(lbs)
Basis for
listing
Ethylene oxide 75218 10,000 a, b
[Oxirane].
Fluorine .............. 7782414 1,000 b
Formaldehyde 50000 15,000 b
(solution).
Furan .................. 110009 5,000 b
Hydrazine ........... 302012 15,000 b
Hydrochloric acid 7647010 15,000 d
(conc 37% or
greater).
Hydrocyanic acid 74908 2,500 a, b
Hydrogen chlo- 7647010 5,000 a
ride (anhy-
drous) [Hydro-
chloric acid].
Hydrogen fluo- 7664393 1,000 a, b
ride/
Hydrofluoric
acid (conc 50%
or greater)
[Hydrofluoric
acid].
Hydrogen sele- 7783075 500 b
nide.
Hydrogen sulfide 7783064 10,000 a, b
Iron, 13463406 2,500 b
pentacarbonyl-
[Iron carbonyl
(Fe(CO)5),
(TB-5-11)-].
Isobutyronitrile 78820 20,000 b
[Propanenitrile,
2-methyl-].
Isopropyl 108236 15,000 b
chloroformate
[Carbonochlori-
dic acid, 1-
methylethyl
ester].
Methacrylonitrile 126987 10,000 b
[2-
Propenenitrile,
2-methyl-].
Methyl chloride 74873 10,000 a
[Methane,
chloro-].
Methyl 79221 5,000 b
chloroformate
[Carbonochlori-
dic acid,
methylester].
Methyl hydrazine 60344 15,000 b
[Hydrazine,
methyl-].
Methyl isocyanate 624839 10,000 a, b
[Methane,
isocyanato-].
Methyl mercaptan 74931 10,000 b
[Methanethiol].
Methyl 556649 20,000 b
thiocyanate
[Thiocyanic
acid, methyl
ester].
23
68.130 40 CFR Ch. I (7199 Edition)
TABLE 1 TO 68.130.L IST OF REGULATED TABLE 1 TO 68.130.L IST OF REGULATED
TOXIC SUBSTANCES AND THRESHOLD QUAN- TOXIC SUBSTANCES AND THRESHOLD QUAN-
TITIES FOR ACCIDENTAL RELEASE PREVEN- TITIES FOR ACCIDENTAL RELEASE PREVEN-
TIONContinued TIONContinued
[Alphabetical Order77 Substances] [Alphabetical Order77 Substances]
Threshold
quantity
(lbs)
Basis for
listing
Methyltrichlorosil- 75796 5,000 b
ane [Silane,
trichloromethyl-
].
Nickel carbonyl ... 13463393 1,000 b
Nitric acid (conc 7697372 15,000 b
80% or greater).
Nitric oxide [Nitro- 10102439 10,000 b
gen oxide
(NO)].
Oleum (Fuming 8014957 10,000 e
Sulfuric acid)
[Sulfuric acid,
mixture with
sulfur trioxide]
1
.
Peracetic acid 79210 10,000 b
[Ethaneperoxoi-
c acid].
Perchloromethyl- 594423 10,000 b
mercaptan
[Methanesulfe-
nyl chloride,
trichloro-].
Phosgene [Car- 75445 500 a, b
bonic dichlo-
ride].
Phosphine .......... 7803512 5,000 b
Phosphorus 10025873 5,000 b
oxychloride
[Phosphoryl
chloride].
Phosphorus tri- 7719122 15,000 b
chloride [Phos-
phorous tri-
chloride].
Piperidine ........... 110894 15,000 b
Propionitrile 107120 10,000 b
[Propanenitrile].
Propyl 109615 15,000 b
chloroformate
[Carbonochlori-
dic acid,
propylester].
Propyleneimine 75558 10,000 b
[Aziridine, 2-
methyl-].
Propylene oxide 75569 10,000 b
[Oxirane, meth-
yl-].
Sulfur dioxide 7446095 5,000 a, b
(anhydrous).
Threshold
quantity
(lbs)
Basis for
listing
Sulfur tetra- 7783600 2,500 b
fluoride [Sulfur
fluoride (SF4),
(T-4)-].
Sulfur trioxide ..... 7446119 10,000 a, b
Tetramethyllead 75741 10,000 b
[Plumbane,
tetramethyl-].
Tetranitro- 509148 10,000 b
methane [Meth-
ane, tetranitro-].
Titanium tetra- 7550450 2,500 b
chloride [Tita-
nium chloride
(TiCl4) (T-4)-].
Toluene 2,4- 584849 10,000 a
diisocyanate
[Benzene, 2,4-
diisocyanato-1-
methyl-]
1
.
Toluene 2,6- 91087 10,000 a
diisocyanate
[Benzene, 1,3-
diisocyanato-2-
methyl-]
1
.
Toluene 26471625 10,000 a
diisocyanate
(unspecified
isomer) [Ben-
zene, 1,3-
diisocyanatom-
ethyl-]
1
.
Trimethylchlorosi- 75774 10,000 b
lane [Silane,
chlorotrimethyl-
].
Vinyl acetate 108054 15,000 b
monomer [Ace-
tic acid ethenyl
ester].
1
The mixture exemption in 68.115(b)(1) does not apply to
the substance.
NOTE: Basis for Listing:
a Mandated for listing by Congress.
b On EHS list, vapor pressure 10 mmHg or greater.
c Toxic gas.
d Toxicity of hydrogen chloride, potential to release hydro-
gen chloride, and history of accidents.
e Toxicity of sulfur trioxide and sulfuric acid, potential to
release sulfur trioxide, and history of accidents.
TABLE 2 TO 68.130.L IST OF REGULATED TOXIC SUBSTANCES AND THRESHOLD QUANTITIES FOR
ACCIDENTAL RELEASE PREVENTION
[CAS Number Order77 Substances]
CAS No. Chemical name
Threshold
quantity
(lbs)
Basis for
listing
50000 .....................
57147 .....................
60344 .....................
67663 .....................
74873 .....................
Formaldehyde (solution) ....................................................................................
1,1-Dimethylhydrazine [Hydrazine, 1,1-dimethyl-] .............................................
Methyl hydrazine [Hydrazine, methyl-] ...............................................................
Chloroform [Methane, trichloro-] ........................................................................
Methyl chloride [Methane, chloro-] ....................................................................
15,000
15,000
15,000
20,000
10,000
b
b
b
b
a
24
ACCIDENTAL RELEASE PREVENTIONContinued
Threshold
quantity
(lbs)
Basis for
listing
74908 .....................
74931 .....................
75150 .....................
75218 .....................
75445 .....................
75558 .....................
75569 .....................
75741 .....................
75774 .....................
75785 .....................
75796 .....................
78820 .....................
79210 .....................
79221 .....................
91087 .....................
106898 ...................
107028 ...................
107119 ...................
107120 ...................
107131 ...................
107153 ...................
107186 ...................
107302 ...................
108054 ...................
108236 ...................
108918 ...................
109615 ...................
110009 ...................
110894 ...................
123739 ...................
126987 ...................
151564 ...................
302012 ...................
353424 ...................
506774 ...................
509148 ...................
542881 ...................
556649 ...................
584849 ...................
594423 ...................
624839 ...................
814686 ...................
4170303 .................
7446095 .................
7446119 .................
7550450 .................
7637072 .................
7647010 .................
7647010 .................
7664393 .................
7664417 .................
7664417 .................
7697372 .................
7719122 .................
7726956 .................
7782414 .................
7782505 .................
7783064 .................
7783075 .................
7783600 .................
7784341 .................
7784421 .................
7803512 .................
8014957 .................
10025873 ...............
10049044 ...............
10102439 ...............
Hydrocyanic acid ................................................................................................
Methyl mercaptan [Methanethiol] .......................................................................
Carbon disulfide .................................................................................................
Ethylene oxide [Oxirane] ....................................................................................
Phosgene [Carbonic dichloride] .........................................................................
Propyleneimine [Aziridine, 2-methyl-] ................................................................
Propylene oxide [Oxirane, methyl-] ...................................................................
Tetramethyllead [Plumbane, tetramethyl-] .........................................................
Trimethylchlorosilane [Silane, chlorotrimethyl-] .................................................
Dimethyldichlorosilane [Silane, dichlorodimethyl-] .............................................
Methyltrichlorosilane [Silane, trichloromethyl-] ...................................................
Isobutyronitrile [Propanenitrile, 2-methyl-] .........................................................
Peracetic acid [Ethaneperoxoic acid] ................................................................
Methyl chloroformate [Carbonochloridic acid, methylester] ...............................
Toluene 2,6-diisocyanate [Benzene, 1,3-diisocyanato-2-methyl-]
1
...................
Epichlorohydrin [Oxirane, (chloromethyl)-] .........................................................
Acrolein [2-Propenal] .........................................................................................
Allylamine [2-Propen-1-amine] ...........................................................................
Propionitrile [Propanenitrile] ...............................................................................
Acrylonitrile [2-Propenenitrile] ............................................................................
Ethylenediamine [1,2-Ethanediamine] ...............................................................
Allyl alcohol [2-Propen-1-ol] ...............................................................................
Chloromethyl methyl ether [Methane, chloromethoxy-] .....................................
Vinyl acetate monomer [Acetic acid ethenyl ester] ...........................................
Isopropyl chloroformate [Carbonochloridic acid, 1-methylethyl ester] ...............
Cyclohexylamine [Cyclohexanamine] ................................................................
Propyl chloroformate [Carbonochloridic acid, propylester] ................................
Furan ..................................................................................................................
Piperidine ...........................................................................................................
Crotonaldehyde, (E)- [2-Butenal, (E)-] ...............................................................
Methacrylonitrile [2-Propenenitrile, 2-methyl-] ...................................................
Ethyleneimine [Aziridine] ....................................................................................
Hydrazine ...........................................................................................................
Boron trifluoride compound with methyl ether (1:1) [Boron,
trifluoro[oxybis[methane]]-, T-4-.
Cyanogen chloride .............................................................................................
Tetranitromethane [Methane, tetranitro-] ...........................................................
Chloromethyl ether [Methane, oxybis[chloro-] ...................................................
Methyl thiocyanate [Thiocyanic acid, methyl ester] ...........................................
Toluene 2,4-diisocyanate [Benzene, 2,4-diisocyanato-1-methyl-]
1
...................
Perchloromethylmercaptan [Methanesulfenyl chloride, trichloro-] .....................
Methyl isocyanate [Methane, isocyanato-] ........................................................
Acrylyl chloride [2-Propenoyl chloride] ...............................................................
Crotonaldehyde [2-Butenal] ...............................................................................
Sulfur dioxide (anhydrous) .................................................................................
Sulfur trioxide .....................................................................................................
Titanium tetrachloride [Titanium chloride (TiCl4) (T-4)-] ....................................
Boron trifluoride [Borane, trifluoro-] ....................................................................
Hydrochloric acid (conc 37% or greater) ...........................................................
Hydrogen chloride (anhydrous) [Hydrochloric acid] ...........................................
Hydrogen fluoride/Hydrofluoric acid (conc 50% or greater) [Hydrofluoric acid]
Ammonia (anhydrous) ........................................................................................
Ammonia (conc 20% or greater) .......................................................................
Nitric acid (conc 80% or greater) .......................................................................
Phosphorus trichloride [Phosphorous trichloride] ..............................................
Bromine ..............................................................................................................
Fluorine ..............................................................................................................
Chlorine ..............................................................................................................
Hydrogen sulfide ................................................................................................
Hydrogen selenide .............................................................................................
Sulfur tetrafluoride [Sulfur fluoride (SF4), (T-4)-] ...............................................
Arsenous trichloride ...........................................................................................
Arsine .................................................................................................................
Phosphine ..........................................................................................................
Oleum (Fuming Sulfuric acid) [Sulfuric acid, mixture with sulfur trioxide]
1
.......
Phosphorus oxychloride [Phosphoryl chloride] ..................................................
Chlorine dioxide [Chlorine oxide (ClO2)] ............................................................
Nitric oxide [Nitrogen oxide (NO)] ......................................................................
2,500
10,000
20,000
10,000
500
10,000
10,000
10,000
10,000
5,000
5,000
20,000
10,000
5,000
10,000
20,000
5,000
10,000
10,000
20,000
20,000
15,000
5,000
15,000
15,000
15,000
15,000
5,000
15,000
20,000
10,000
10,000
15,000
15,000
10,000
10,000
1,000
20,000
10,000
10,000
10,000
5,000
20,000
5,000
10,000
2,500
5,000
15,000
5,000
1,000
10,000
20,000
15,000
15,000
10,000
1,000
2,500
10,000
500
2,500
15,000
1,000
5,000
10,000
5,000
1,000
10,000
a, b
b
b
a, b
a, b
b
b
b
b
b
b
b
b
b
a
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
b
c
b
b
b
a
b
a, b
b
b
a, b
a, b
b
b
d
a
a, b
a, b
a, b
b
b
a, b
b
a, b
a, b
b
b
b
b
b
e
b
c
b
25
68.130 40 CFR Ch. I (7199 Edition)
ACCIDENTAL RELEASE PREVENTIONContinued
Threshold
quantity
(lbs)
Basis for
listing
10294345 ...............
13463393 ...............
13463406 ...............
19287457 ...............
26471625 ...............
Boron trichloride [Borane, trichloro-] ..................................................................
Nickel carbonyl ...................................................................................................
Iron, pentacarbonyl- [Iron carbonyl (Fe(CO)5), (TB-5-11)-] ...............................
Diborane .............................................................................................................
Toluene diisocyanate (unspecified isomer) [Benzene, 1,3-diisocyanatomethyl-
1]
1
.
5,000
1,000
2,500
2,500
10,000
b
b
b
b
a
1
The mixture exemption in 68.115(b)(1) does not apply to the substance.
b On EHS list, vapor pressure 10 mmHg or greater.
c Toxic gas.
d Toxicity of hydrogen chloride, potential to release hydrogen chloride, and history of accidents.
e Toxicity of sulfur trioxide and sulfuric acid, potential to release sulfur trioxide, and history of accidents.
TABLE 3 TO 68.130.L IST OF REGULATED FLAMMABLE SUBSTANCES AND THRESHOLD QUANTITIES
FOR ACCIDENTAL RELEASE PREVENTION
Threshold
quantity
(lbs)
Basis for
listing
Acetaldehyde ..................................................................................................................
Acetylene [Ethyne] .........................................................................................................
Bromotrifluorethylene [Ethene, bromotrifluoro-] .............................................................
1,3-Butadiene .................................................................................................................
Butane ............................................................................................................................
1-Butene .........................................................................................................................
2-Butene .........................................................................................................................
Butene ............................................................................................................................
2-Butene-cis ...................................................................................................................
2-Butene-trans [2-Butene, (E)] .......................................................................................
Carbon oxysulfide [Carbon oxide sulfide (COS)] ...........................................................
Chlorine monoxide [Chlorine oxide] ...............................................................................
2-Chloropropylene [1-Propene, 2-chloro-] .....................................................................
1-Chloropropylene [1-Propene, 1-chloro-] .....................................................................
Cyanogen [Ethanedinitrile] .............................................................................................
Cyclopropane .................................................................................................................
Dichlorosilane [Silane, dichloro-] ....................................................................................
Difluoroethane [Ethane, 1,1-difluoro-] ............................................................................
Dimethylamine [Methanamine, N-methyl-] .....................................................................
2,2-Dimethylpropane [Propane, 2,2-dimethyl-] ..............................................................
Ethane ............................................................................................................................
Ethyl acetylene [1-Butyne] .............................................................................................
Ethylamine [Ethanamine] ...............................................................................................
Ethyl chloride [Ethane, chloro-] ......................................................................................
Ethylene [Ethene] ...........................................................................................................
Ethyl ether [Ethane, 1,1-oxybis-] ...................................................................................
Ethyl mercaptan [Ethanethiol] ........................................................................................
Ethyl nitrite [Nitrous acid, ethyl ester] ............................................................................
Hydrogen ........................................................................................................................
Isobutane [Propane, 2-methyl] .......................................................................................
Isopentane [Butane, 2-methyl-] ......................................................................................
Isoprene [1,3-Butadinene, 2-methyl-] .............................................................................
Isopropylamine [2-Propanamine] ...................................................................................
Isopropyl chloride [Propane, 2-chloro-] ..........................................................................
Methane .........................................................................................................................
Methylamine [Methanamine] ..........................................................................................
3-Methyl-1-butene ..........................................................................................................
2-Methyl-1-butene ..........................................................................................................
Methyl ether [Methane, oxybis-] .....................................................................................
Methyl formate [Formic acid, methyl ester] ...................................................................
2-Methylpropene [1-Propene, 2-methyl-] .......................................................................
1,3-Pentadinene .............................................................................................................
Pentane ..........................................................................................................................
1-Pentene .......................................................................................................................
2-Pentene, (E)- ...............................................................................................................
2-Pentene, (Z)- ...............................................................................................................
75070
74862
598732
106990
106978
106989
107017
25167673
590181
624646
463581
7791211
557982
590216
460195
75194
4109960
75376
124403
463821
74840
107006
75047
75003
74851
60297
75081
109955
1333740
75285
78784
78795
75310
75296
74828
74895
563451
563462
115106
107313
115117
504609
109660
109671
646048
627203
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
g
f
f
f
f
f
f
f
f
f
f
f
g
g
f
f
f
f
f
f
f
f
f
f
f
g
g
f
f
f
g
g
g
g
f
f
f
g
f
g
f
f
g
g
g
g
26
FOR ACCIDENTAL RELEASE PREVENTIONContinued
Threshold
quantity
(lbs)
Basis for
listing
Propadiene [1,2-Propadiene] .........................................................................................
Propane ..........................................................................................................................
Propylene [1-Propene] ...................................................................................................
Propyne [1-Propyne] ......................................................................................................
Silane .............................................................................................................................
Tetrafluoroethylene [Ethene, tetrafluoro-] ......................................................................
Tetramethylsilane [Silane, tetramethyl-] .........................................................................
Trichlorosilane [Silane, trichloro-] ...................................................................................
Trifluorochloroethylene [Ethene, chlorotrifluoro-] ...........................................................
Trimethylamine [Methanamine, N,N-dimethyl-] ..............................................................
Vinyl acetylene [1-Buten-3-yne] .....................................................................................
Vinyl chloride [Ethene, chloro-] ......................................................................................
Vinyl ethyl ether [Ethene, ethoxy-] .................................................................................
Vinyl fluoride [Ethene, fluoro-] ........................................................................................
Vinylidene chloride [Ethene, 1,1-dichloro-] ....................................................................
Vinylidene fluoride [Ethene, 1,1-difluoro-] ......................................................................
Vinyl methyl ether [Ethene, methoxy-] ...........................................................................
463490
74986
115071
74997
7803625
116143
75763
10025782
79389
75503
689974
75014
109922
75025
75354
75387
107255
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
f
f
f
f
f
f
g
g
f
f
f
a, f
g
f
g
f
f
f Flammable gas.
g Volatile flammable liquid.
FOR ACCIDENTAL RELEASE PREVENTION
CAS No. Chemical name CAS No.
Threshold
quantity
(lbs)
Basis for
listing
60297 .....................
74828 .....................
74840 .....................
74851 .....................
74862 .....................
74895 .....................
74986 .....................
74997 .....................
75003 .....................
75014 .....................
75025 .....................
75047 .....................
75070 .....................
75081 .....................
75194 .....................
75285 .....................
75296 .....................
75310 .....................
75354 .....................
75376 .....................
75387 .....................
75503 .....................
75763 .....................
78784 .....................
78795 .....................
79389 .....................
106978 ...................
106989 ...................
196990 ...................
107006 ...................
107017 ...................
107255 ...................
107313 ...................
109660 ...................
109671 ...................
109922 ...................
109955 ...................
Ethyl ether [Ethane, 1,1-oxybis-] ..........................................
Methane .................................................................................
Ethane ...................................................................................
Ethylene [Ethene] ..................................................................
Acetylene [Ethyne] ................................................................
Methylamine [Methanamine] .................................................
Propane .................................................................................
Propyne [1-Propyne] .............................................................
Ethyl chloride [Ethane, chloro-] .............................................
Vinyl chloride [Ethene, chloro-] .............................................
Vinyl fluoride [Ethene, fluoro-] ...............................................
Ethylamine [Ethanamine] ......................................................
Acetaldehyde .........................................................................
Ethyl mercaptan [Ethanethiol] ...............................................
Cyclopropane ........................................................................
Isobutane [Propane, 2-methyl] ..............................................
Isopropyl chloride [Propane, 2-chloro-] .................................
Isopropylamine [2-Propanamine] ..........................................
Vinylidene chloride [Ethene, 1,1-dichloro-] ...........................
Difluoroethane [Ethane, 1,1-difluoro-] ...................................
Vinylidene fluoride [Ethene, 1,1-difluoro-] .............................
Trimethylamine [Methanamine, N, N-dimethyl-] ....................
Tetramethylsilane [Silane, tetramethyl-] ................................
Isopentane [Butane, 2-methyl-] .............................................
Isoprene [1,3,-Butadiene, 2-methyl-] .....................................
Trifluorochloroethylene [Ethene, chlorotrifluoro-] ..................
Butane ...................................................................................
1-Butene ................................................................................
1,3-Butadiene ........................................................................
Ethyl acetylene [1-Butyne] ....................................................
2-Butene ................................................................................
Vinyl methyl ether [Ethene, methoxy-] ..................................
Methyl formate [Formic acid, methyl ester] ...........................
Pentane .................................................................................
1-Pentene ..............................................................................
Vinyl ethyl ether [Ethene, ethoxy-] ........................................
Ethyl nitrite [Nitrous acid, ethyl ester] ...................................
60297
74828
74840
74851
74862
74895
74986
74997
75003
75014
75025
75047
75070
75081
75194
75285
75296
75310
75354
75376
75387
75503
75763
78784
78795
79389
106978
106989
106990
107006
107017
107255
107313
109660
109671
109922
109955
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
g
f
f
f
f
f
f
f
f
a, f
f
f
g
g
f
f
g
g
g
f
f
f
g
g
g
f
f
f
f
f
f
f
g
g
g
g
f
27
68.150 40 CFR Ch. I (7199 Edition)
FOR ACCIDENTAL RELEASE PREVENTIONContinued
CAS No. Chemical name CAS No.
Threshold
quantity
(lbs)
Basis for
listing
115071 ...................
115106 ...................
115117 ...................
116143 ...................
124403 ...................
460195 ...................
463490 ...................
463581 ...................
463821 ...................
504609 ...................
557982 ...................
563451 ...................
563462 ...................
590181 ...................
590216 ...................
598732 ...................
624646 ...................
627203 ...................
646048 ...................
689974 ...................
1333740 .................
4109960 .................
7791211 .................
7803625 .................
10025782 ...............
25167673 ...............
Propylene [1-Propene] ..........................................................
Methyl ether [Methane, oxybis-] ............................................
2-Methylpropene [1-Propene, 2-methyl-] ..............................
Tetrafluoroethylene [Ethene, tetrafluoro-] .............................
Dimethylamine [Methanamine, N-methyl-] ............................
Cyanogen [Ethanedinitrile] ....................................................
Propadiene [1,2-Propadiene] ................................................
Carbon oxysulfide [Carbon oxide sulfide (COS)] ..................
2,2-Dimethylpropane [Propane, 2,2-dimethyl-] .....................
1,3-Pentadiene ......................................................................
2-Chloropropylene [1-Propene, 2-chloro-] .............................
3-Methyl-1-butene .................................................................
2-Methyl-1-butene .................................................................
2-Butene-cis ..........................................................................
1-Chloropropylene [1-Propene, 1-chloro-] .............................
Bromotrifluorethylene [Ethene, bromotrifluoro-] ....................
2-Butene-trans [2-Butene, (E)] ..............................................
2-Pentene, (Z)- ......................................................................
2-Pentene, (E)- ......................................................................
Vinyl acetylene [1-Buten-3-yne] ............................................
Hydrogen ...............................................................................
Dichlorosilane [Silane, dichloro-] ...........................................
Chlorine monoxide [Chlorine oxide] ......................................
Silane .....................................................................................
Trichlorosilane [Silane,trichloro-] ...........................................
Butene ...................................................................................
115071
115106
115117
116143
124403
460195
463490
463581
463821
504609
557982
563451
563462
590181
590216
598732
624646
627203
646048
689974
1333740
4109960
7791211
7803625
10025782
25167673
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
10,000
f
f
f
f
f
f
f
f
f
f
g
f
g
f
g
f
f
g
g
f
f
f
f
f
g
f
Note: Basis for Listing: a Mandated for listing by Congress. f Flammable gas. g Volatile flammable liquid.
[59 F R 4493, J an. 31, 1994. Redesi gnated at 61 F R 31717, J une 20, 1996, as amended at 62 F R 45132,
Aug. 25, 1997; 63 F R 645, J an. 6, 1998]
Subpart GRisk Management
Plan
otherwi se noted.
68.150 Submission.
(a) The owner or operator shal l sub-
mi t a si ngl e RMP that i ncl udes the i n-
formati on requi red by 68.155 through
68.185 for al l covered processes. The
RMP shal l be submi tted i n a method
and format to a central poi nt as speci -
fi ed by EPA pri or to J une 21, 1999.
(b) The owner or operator shal l sub-
mi t the fi rst RMP no l ater than the
l atest of the fol l owi ng dates:
(1) J une 21, 1999;
(2) Three years after the date on
whi ch a regul ated substance i s fi rst
l i sted under 68.130; or
(3) The date on whi ch a regul ated
substance i s fi rst present above a
threshol d quanti ty i n a process.
(c) Subsequent submi ssi ons of RMPs
shal l be i n accordance wi th 68.190.
(d) Notwi thstandi ng the provi si ons of
68.155 to 68.190, the RMP shal l ex-
cl ude cl assi fi ed i nformati on. Subj ect to
appropri ate procedures to protect such
i nformati on from publ i c di scl osure,
cl assi fi ed data or i nformati on excl uded
from the RMP may be made avai l abl e
i n a cl assi fi ed annex to the RMP for re-
vi ew by F ederal and state representa-
ti ves who have recei ved the appro-
pri ate securi ty cl earances.
(e) Procedures for asserti ng that i n-
formati on submi tted i n the RMP i s en-
ti tl ed to protecti on as confi denti al
busi ness i nformati on are set forth i n
68.151 and 68.152.
F R 979, J an. 6, 1999]
68.151 Assertion of claims of con-
fidential business information.
(a) Except as provi ded i n paragraph
(b) of thi s secti on, an owner or oper-
ator of a stati onary source requi red to
report or otherwi se provi de i nforma-
ti on under thi s part may make a cl ai m
28
of confi denti al busi ness i nformati on
for any such i nformati on that meets
the cri teri a set forth i n 40 CF R 2.301.
(b) Notwi thstandi ng the provi si ons of
40 CF R part 2, an owner or operator of
a stati onary source subj ect to thi s part
may not cl ai m as confi denti al busi ness
i nformati on the fol l owi ng i nformati on:
(1) Regi strati on data requi red by
68.160(b)(1) through (b)(6) and (b)(8),
(b)(10) through (b)(13) and NAI CS code
and Program l evel of the process set
forth i n 68.160(b)(7);
(2) Offsi te consequence anal ysi s data
requi red by 68.165(b)(4), (b)(9), (b)(10),
(b)(11), and (b)(12).
(3) Acci dent hi story data requi red by
68.168;
(4) Preventi on program data requi red
by 68.170(b), (d), (e)(1), (f) through (k);
(5) Preventi on program data requi red
by 68.175(b), (d), (e)(1), (f) through (p);
and
(6) Emergency response program data
requi red by 68.180.
(c) Notwi thstandi ng the procedures
speci fi ed i n 40 CF R part 2, an owner or
operator asserti ng a cl ai m of CBI wi th
respect to i nformati on contai ned i n i ts
RMP, shal l submi t to EPA at the ti me
i t submi ts the RMP the fol l owi ng:
(1) The i nformati on cl ai med con-
fi denti al , provi ded i n a format to be
speci fi ed by EPA;
(2) A sani ti zed (redacted) copy of the
RMP, wi th the notati on CBI sub-
sti tuted for the i nformati on cl ai med
confi denti al , except that a generi c cat-
egory or cl ass name shal l be sub-
sti tuted for any chemi cal name or
i denti ty cl ai med confi denti al ; and
(3) The document or documents sub-
stanti ati ng each cl ai m of confi denti al
busi ness i nformati on, as descri bed i n
68.152.
[64 F R 979, J an. 6, 1999]
68.152 Substantiating claims of con-
fidential business information.
(a) An owner or operator cl ai mi ng
that i nformati on i s confi denti al busi -
ness i nformati on must substanti ate
that cl ai m by provi di ng documentati on
that demonstrates that the cl ai m
meets the substanti ve cri teri a set forth
i n 40 CF R 2.301.
(b) I nformati on that i s submi tted as
part of the substanti ati on may be
cl ai med confi denti al by marki ng i t as
68.160
confi denti al busi ness i nformati on. I n-
formati on not so marked wi l l be treat-
ed as publ i c and may be di scl osed wi th-
out noti ce to the submi tter. I f i nforma-
ti on that i s submi tted as part of the
substanti ati on i s cl ai med confi denti al ,
the owner or operator must provi de a
sani ti zed and unsani ti zed versi on of the
substanti ati on.
(c) The owner, operator, or seni or of-
fi ci al wi th management responsi bi l i ty
of the stati onary source shal l si gn a
certi fi cati on that the si gner has per-
sonal l y exami ned the i nformati on sub-
mi tted and that based on i nqui ry of the
persons who compi l ed the i nformati on,
the i nformati on i s true, accurate, and
compl ete, and that those porti ons of
the substanti ati on cl ai med as confi den-
ti al busi ness i nformati on woul d, i f di s-
cl osed, reveal trade secrets or other
confi denti al busi ness i nformati on.
[64 F R 980, J an. 6, 1999]
68.155 Executive summary.
The owner or operator shal l provi de
i n the RMP an executi ve summary that
i ncl udes a bri ef descri pti on of the fol -
l owi ng el ements:
(a) The acci dental rel ease preventi on
and emergency response pol i ci es at the
stati onary source;
(b) The stati onary source and regu-
l ated substances handl ed;
(c) The worst-case rel ease scenari o(s)
and the al ternati ve rel ease scenari o(s),
i ncl udi ng admi ni strati ve control s and
mi ti gati on measures to l i mi t the di s-
tances for each reported scenari o;
(d) The general acci dental rel ease
preventi on program and chemi cal -spe-
ci fi c preventi on steps;
(e) The fi ve-year acci dent hi story;
(f) The emergency response program;
and
(g) Pl anned changes to i mprove safe-
ty.
68.160 Registration.
(a) The owner or operator shal l com-
pl ete a si ngl e regi strati on form and i n-
cl ude i t i n the RMP. The form shal l
cover al l regul ated substances handl ed
i n covered processes.
(b) The regi strati on shal l i ncl ude the
fol l owi ng data:
(1) Stati onary source name, street,
ci ty, county, state, zi p code, l ati tude
and l ongi tude, method for obtai ni ng
29
68.165
l ati tude and l ongi tude, and descri pti on
of l ocati on that l ati tude and l ongi tude
represent;
(2) The stati onary source Dun and
Bradstreet number;
(3) Name and Dun and Bradstreet
number of the corporate parent com-
pany;
(4) The name, tel ephone number, and
mai l i ng address of the owner or oper-
ator;
(5) The name and ti tl e of the person
or posi ti on wi th overal l responsi bi l i ty
for RMP el ements and i mpl ementati on;
(6) The name, ti tl e, tel ephone num-
ber, and 24-hour tel ephone number of
the emergency contact;
(7) F or each covered process, the
name and CAS number of each regu-
l ated substance hel d above the thresh-
ol d quanti ty i n the process, the max-
i mum quanti ty of each regul ated sub-
stance or mi xture i n the process (i n
pounds) to two si gni fi cant di gi ts, the
fi ve- or si x-di gi t NAI CS code that most
cl osel y corresponds to the process, and
the Program l evel of the process;
(8) The stati onary source EPA i denti -
fi er;
(9) The number of ful l -ti me empl oy-
ees at the stati onary source;
(10) Whether the stati onary source i s
subj ect to 29 CF R 1910.119;
(11) Whether the stati onary source i s
subj ect to 40 CF R part 355;
(12) I f the stati onary source has a
CAA Ti tl e V operati ng permi t, the per-
mi t number; and
(13) The date of the l ast safety i n-
specti on of the stati onary source by a
F ederal , state, or l ocal government
agency and the i denti ty of the i nspect-
i ng enti ty.
(14) Source or Parent Company E-
Mai l Address (Opti onal );
(15) Source Homepage address (Op-
ti onal )
(16) Phone number at the source for
publ i c i nqui ri es (Opti onal );
(17) L ocal Emergency Pl anni ng Com-
mi ttee (Opti onal );
(18) OSHA Vol untary Protecti on Pro-
gram status (Opti onal );
F R 980, J an. 6, 1999]
68.165 Offsite consequence analysis.
(a) The owner or operator shal l sub-
mi t i n the RMP i nformati on:
(1) One worst-case rel ease scenari o
for each Program 1 process; and
(2) F or Program 2 and 3 processes,
one worst-case rel ease scenari o to rep-
resent al l regul ated toxi c substances
hel d above the threshol d quanti ty and
one worst-case rel ease scenari o to rep-
resent al l regul ated fl ammabl e sub-
stances hel d above the threshol d quan-
ti ty. I f addi ti onal worst-case scenari os
for toxi cs or fl ammabl es are requi red
by 68.25(a)(2)(i i i ), the owner or oper-
ator shal l submi t the same i nformati on
on the addi ti onal scenari o(s). The
owner or operator of Program 2 and 3
processes shal l al so submi t i nformati on
on one al ternati ve rel ease scenari o for
each regul ated toxi c substance hel d
above the threshol d quanti ty and one
al ternati ve rel ease scenari o to rep-
resent al l regul ated fl ammabl e sub-
stances hel d above the threshol d quan-
ti ty.
mi t the fol l owi ng data:
(1) Chemi cal name;
(2) Percentage wei ght of the chemi cal
i n a l i qui d mi xture (toxi cs onl y);
(3) Physi cal state (toxi cs onl y);
(4) Basi s of resul ts (gi ve model name
i f used);
(5) Scenari o (expl osi on, fi re, toxi c gas
rel ease, or l i qui d spi l l and evapo-
rati on);
(6) Quanti ty rel eased i n pounds;
(7) Rel ease rate;
(8) Rel ease durati on;
(9) Wi nd speed and atmospheri c sta-
bi l i ty cl ass (toxi cs onl y);
(10) Topography (toxi cs onl y);
(11) Di stance to endpoi nt;
(12) Publ i c and envi ronmental recep-
tors wi thi n the di stance;
(13) Passi ve mi ti gati on consi dered;
and
(14) Acti ve mi ti gati on consi dered (al -
ternati ve rel eases onl y);
F R 980, J an. 6, 1999]
68.168 Five-year accident history.
The owner or operator shal l submi t
i n the RMP the i nformati on provi ded
i n 68.42(b) on each acci dent covered by
68.42(a).
30
68.170 Prevention program/Program
2.
(a) F or each Program 2 process, the
owner or operator shal l provi de i n the
RMP the i nformati on i ndi cated i n
paragraphs (b) through (k) of thi s sec-
ti on. I f the same i nformati on appl i es to
more than one covered process, the
owner or operator may provi de the i n-
formati on onl y once, but shal l i ndi cate
to whi ch processes the i nformati on ap-
pl i es.
(b) The fi ve- or si x-di gi t NAI CS code
that most cl osel y corresponds to the
process.
(c) The name(s) of the chemi cal (s)
covered.
(d) The date of the most recent re-
vi ew or revi si on of the safety i nforma-
ti on and a l i st of F ederal or state regu-
l ati ons or i ndustry-speci fi c desi gn
codes and standards used to dem-
onstrate compl i ance wi th the safety i n-
formati on requi rement.
(e) The date of compl eti on of the
most recent hazard revi ew or update.
(1) The expected date of compl eti on
of any changes resul ti ng from the haz-
ard revi ew;
(2) Maj or hazards i denti fi ed;
(3) Process control s i n use;
(4) Mi ti gati on systems i n use;
(5) Moni tori ng and detecti on systems
i n use; and
(6) Changes si nce the l ast hazard re-
vi ew.
(f) The date of the most recent revi ew
or revi si on of operati ng procedures.
(g) The date of the most recent re-
vi ew or revi si on of trai ni ng programs;
(1) The type of trai ni ng provi ded
cl assroom, cl assroom pl us on the j ob,
on the j ob; and
(2) The type of competency testi ng
used.
(h) The date of the most recent re-
vi ew or revi si on of mai ntenance proce-
dures and the date of the most recent
equi pment i nspecti on or test and the
equi pment i nspected or tested.
(i ) The date of the most recent com-
pl i ance audi t and the expected date of
compl eti on of any changes resul ti ng
from the compl i ance audi t.
(j ) The date of the most recent i nci -
dent i nvesti gati on and the expected
date of compl eti on of any changes re-
sul ti ng from the i nvesti gati on.
68.175
(k) The date of the most recent
change that tri ggered a revi ew or revi -
si on of safety i nformati on, the hazard
revi ew, operati ng or mai ntenance pro-
cedures, or trai ni ng.
F R 980, J an. 6, 1999]
68.175 Prevention program/Program
3.
(a) F or each Program 3 process, the
owner or operator shal l provi de the i n-
formati on i ndi cated i n paragraphs (b)
through (p) of thi s secti on. I f the same
i nformati on appl i es to more than one
covered process, the owner or operator
may provi de the i nformati on onl y
once, but shal l i ndi cate to whi ch proc-
esses the i nformati on appl i es.
(b) The fi ve- or si x-di gi t NAI CS code
that most cl osel y corresponds to the
process.
(c) The name(s) of the substance(s)
covered.
(d) The date on whi ch the safety i n-
formati on was l ast revi ewed or revi sed.
(e) The date of compl eti on of the
most recent PHA or update and the
techni que used.
(1) The expected date of compl eti on
of any changes resul ti ng from the PHA;
(2) Maj or hazards i denti fi ed;
(3) Process control s i n use;
(4) Mi ti gati on systems i n use;
(5) Moni tori ng and detecti on systems
i n use; and
(6) Changes si nce the l ast PHA.
(f) The date of the most recent revi ew
or revi si on of operati ng procedures.
(g) The date of the most recent re-
vi ew or revi si on of trai ni ng programs;
(1) The type of trai ni ng provi ded
cl assroom, cl assroom pl us on the j ob,
on the j ob; and
(2) The type of competency testi ng
used.
(h) The date of the most recent re-
vi ew or revi si on of mai ntenance proce-
dures and the date of the most recent
equi pment i nspecti on or test and the
equi pment i nspected or tested.
(i ) The date of the most recent
change that tri ggered management of
change procedures and the date of the
most recent revi ew or revi si on of man-
agement of change procedures.
(j ) The date of the most recent pre-
startup revi ew.
31
68.180
(k) The date of the most recent com-
pl i ance audi t and the expected date of
compl eti on of any changes resul ti ng
from the compl i ance audi t;
(l ) The date of the most recent i nci -
dent i nvesti gati on and the expected
date of compl eti on of any changes re-
sul ti ng from the i nvesti gati on;
(m) The date of the most recent re-
vi ew or revi si on of empl oyee parti ci pa-
ti on pl ans;
(n) The date of the most recent re-
vi ew or revi si on of hot work permi t
procedures;
(o) The date of the most recent re-
vi ew or revi si on of contractor safety
procedures; and
(p) The date of the most recent eval -
uati on of contractor safety perform-
ance.
F R 980, J an. 6, 1999]
(a) The owner or operator shal l pro-
vi de i n the RMP the fol l owi ng i nforma-
ti on:
(1) Do you have a wri tten emergency
response pl an?
(2) Does the pl an i ncl ude speci fi c ac-
ti ons to be taken i n response to an ac-
ci dental rel eases of a regul ated sub-
stance?
(3) Does the pl an i ncl ude procedures
for i nformi ng the publ i c and l ocal
agenci es responsi bl e for respondi ng to
acci dental rel eases?
(4) Does the pl an i ncl ude i nformati on
on emergency heal th care?
(5) The date of the most recent re-
vi ew or update of the emergency re-
sponse pl an;
(6) The date of the most recent emer-
gency response trai ni ng for empl oyees.
(b) The owner or operator shal l pro-
vi de the name and tel ephone number of
the l ocal agency wi th whi ch emergency
response acti vi ti es and the emergency
response pl an i s coordi nated.
(c) The owner or operator shal l l i st
other F ederal or state emergency pl an
requi rements to whi ch the stati onary
source i s subj ect.
F R 980, J an. 6, 1999]
68.185 Certification.
(a) F or Program 1 processes, the
owner or operator shal l submi t i n the
RMP the certi fi cati on statement pro-
vi ded i n 68.12(b)(4).
(b) F or al l other covered processes,
the owner or operator shal l submi t i n
the RMP a si ngl e certi fi cati on that, to
the best of the si gners knowl edge, i n-
formati on, and bel i ef formed after rea-
sonabl e i nqui ry, the i nformati on sub-
mi tted i s true, accurate, and compl ete.
68.190 Updates.
(a) The owner or operator shal l re-
vi ew and update the RMP as speci fi ed
i n paragraph (b) of thi s secti on and
submi t i t i n a method and format to a
central poi nt speci fi ed by EPA pri or to
J une 21, 1999.
(b) The owner or operator of a sta-
ti onary source shal l revi se and update
the RMP submi tted under 68.150 as
fol l ows:
(1) Wi thi n fi ve years of i ts i ni ti al sub-
mi ssi on or most recent update requi red
by paragraphs (b)(2) through (b)(7) of
thi s secti on, whi chever i s l ater.
(2) No l ater than three years after a
newl y regul ated substance i s fi rst l i st-
ed by EPA;
(3) No l ater than the date on whi ch a
new regul ated substance i s fi rst
present i n an al ready covered process
above a threshol d quanti ty;
(4) No l ater than the date on whi ch a
regul ated substance i s fi rst present
above a threshol d quanti ty i n a new
process;
(5) Wi thi n si x months of a change
that requi res a revi sed PHA or hazard
revi ew;
that requi res a revi sed offsi te con-
sequence anal ysi s as provi ded i n 68.36;
and
that al ters the Program l evel that ap-
pl i ed to any covered process.
(c) I f a stati onary source i s no l onger
subj ect to thi s part, the owner or oper-
ator shal l submi t a revi sed regi strati on
to EPA wi thi n si x months i ndi cati ng
that the stati onary source i s no l onger
covered.
32
Subpart HOther Requirements
otherwi se noted.
68.200 Recordkeeping.
The owner or operator shal l mai ntai n
records supporti ng the i mpl ementati on
of thi s part for fi ve years unl ess other-
wi se provi ded i n subpart D of thi s part.
68.210 Availability of information to
the public.
(a) The RMP requi red under subpart
G of thi s part shal l be avai l abl e to the
publ i c under 42 U.S.C. 7414(c).
(b) The di scl osure of cl assi fi ed i nfor-
mati on by the Department of Defense
or other F ederal agenci es or contrac-
tors of such agenci es shal l be con-
trol l ed by appl i cabl e l aws, regul ati ons,
or executi ve orders concerni ng the re-
l ease of cl assi fi ed i nformati on.
68.215 Permit content and air per-
mitting authority or designated
agency requirements.
(a) These requi rements appl y to any
stati onary source subj ect to thi s part
68 and parts 70 or 71 of thi s chapter.
The 40 CF R part 70 or part 71 permi t for
the stati onary source shal l contai n:
(1) A statement l i sti ng thi s part as
an appl i cabl e requi rement;
(2) Condi ti ons that requi re the source
owner or operator to submi t:
(i ) A compl i ance schedul e for meet-
i ng the requi rements of thi s part by
the date provi ded i n 68.10(a) or;
(i i ) As part of the compl i ance certi fi -
cati on submi tted under 40 CF R
70.6(c)(5), a certi fi cati on statement
that the source i s i n compl i ance wi th
al l requi rements of thi s part, i ncl udi ng
the regi strati on and submi ssi on of the
RMP.
mi t any addi ti onal rel evant i nforma-
ti on requested by the ai r permi tti ng
authori ty or desi gnated agency.
(c) F or 40 CF R part 70 or part 71 per-
mi ts i ssued pri or to the deadl i ne for
regi steri ng and submi tti ng the RMP
and whi ch do not contai n permi t condi -
ti ons descri bed i n paragraph (a) of thi s
secti on, the owner or operator or ai r
permi tti ng authori ty shal l i ni ti ate per-
mi t revi si on or reopeni ng accordi ng to
the procedures of 40 CF R 70.7 or 71.7 to
68.220
i ncorporate the terms and condi ti ons
consi stent wi th paragraph (a) of thi s
secti on.
(d) The state may del egate the au-
thori ty to i mpl ement and enforce the
requi rements of paragraph (e) of thi s
secti on to a state or l ocal agency or
agenci es other than the ai r permi tti ng
authori ty. An up-to-date copy of any
del egati on i nstrument shal l be mai n-
tai ned by the ai r permi tti ng authori ty.
The state may enter a wri tten agree-
ment wi th the Admi ni strator under
whi ch EPA wi l l i mpl ement and enforce
the requi rements of paragraph (e) of
thi s secti on.
(e) The ai r permi tti ng authori ty or
the agency desi gnated by del egati on or
agreement under paragraph (d) of thi s
secti on shal l , at a mi ni mum:
(1) Veri fy that the source owner or
operator has regi stered and submi tted
an RMP or a revi sed pl an when re-
qui red by thi s part;
(2) Veri fy that the source owner or
operator has submi tted a source cer-
ti fi cati on or i n i ts absence has sub-
mi tted a compl i ance schedul e con-
si stent wi th paragraph (a)(2) of thi s
secti on;
(3) F or some or al l of the sources sub-
j ect to thi s secti on, use one or more
mechani sms such as, but not l i mi ted
to, a compl eteness check, source au-
di ts, record revi ews, or faci l i ty i nspec-
ti ons to ensure that permi tted sources
are i n compl i ance wi th the requi re-
ments of thi s part; and
(4) I ni ti ate enforcement acti on based
on paragraphs (e)(1) and (e)(2) of thi s
secti on as appropri ate.
68.220 Audits.
(a) I n addi ti on to i nspecti ons for the
purpose of regul atory devel opment and
enforcement of the Act, the i mpl e-
menti ng agency shal l peri odi cal l y
audi t RMPs submi tted under subpart G
of thi s part to revi ew the adequacy of
such RMPs and requi re revi si ons of
RMPs when necessary to ensure com-
pl i ance wi th subpart G of thi s part.
(b) The i mpl ementi ng agency shal l
sel ect stati onary sources for audi ts
based on any of the fol l owi ng cri teri a:
(1) Acci dent hi story of the stati onary
source;
(2) Acci dent hi story of other sta-
ti onary sources i n the same i ndustry;
33
68.220
(3) Quanti ty of regul ated substances
present at the stati onary source;
(4) L ocati on of the stati onary source
and i ts proxi mi ty to the publ i c and en-
vi ronmental receptors;
(5) The presence of speci fi c regul ated
substances;
(6) The hazards i denti fi ed i n the
RMP; and
(7) A pl an provi di ng for neutral , ran-
dom oversi ght.
(c) Exempti on from audi ts. A sta-
ti onary source wi th a Star or Meri t
ranki ng under OSHAs vol untary pro-
tecti on program shal l be exempt from
audi ts under paragraph (b)(2) and (b)(7)
of thi s secti on.
(d) The i mpl ementi ng agency shal l
have access to the stati onary source,
supporti ng documentati on, and any
area where an acci dental rel ease coul d
occur.
(e) Based on the audi t, the i mpl e-
menti ng agency may i ssue the owner
or operator of a stati onary source a
wri tten prel i mi nary determi nati on of
necessary revi si ons to the stati onary
sources RMP to ensure that the RMP
meets the cri teri a of subpart G of thi s
part. The prel i mi nary determi nati on
shal l i ncl ude an expl anati on for the
basi s for the revi si ons, refl ecti ng i ndus-
try standards and gui del i nes (such as
AI ChE/CCPS gui del i nes and ASME and
API standards) to the extent that such
standards and gui del i nes are appl i ca-
bl e, and shal l i ncl ude a ti metabl e for
thei r i mpl ementati on.
(f) Written response to a preliminary de-
termination. (1) The owner or operator
shal l respond i n wri ti ng to a prel i mi -
nary determi nati on made i n accord-
ance wi th paragraph (e) of thi s secti on.
The response shal l state the owner or
operator wi l l i mpl ement the revi si ons
contai ned i n the prel i mi nary deter-
mi nati on i n accordance wi th the ti me-
tabl e i ncl uded i n the prel i mi nary de-
termi nati on or shal l state that the
owner or operator rej ects the revi si ons
i n whol e or i n part. F or each rej ected
revi si on, the owner or operator shal l
expl ai n the basi s for rej ecti ng such re-
vi si on. Such expl anati on may i ncl ude
substi tute revi si ons.
(2) The wri tten response under para-
graph (f)(1) of thi s secti on shal l be re-
cei ved by the i mpl ementi ng agency
wi thi n 90 days of the i ssue of the pre-
l i mi nary determi nati on or a shorter
peri od of ti me as the i mpl ementi ng
agency speci fi es i n the prel i mi nary de-
termi nati on as necessary to protect
publ i c heal th and the envi ronment.
Pri or to the wri tten response bei ng due
and upon wri tten request from the
owner or operator, the i mpl ementi ng
agency may provi de i n wri ti ng addi -
ti onal ti me for the response to be re-
cei ved.
(g) After provi di ng the owner or oper-
ator an opportuni ty to respond under
paragraph (f) of thi s secti on, the i mpl e-
menti ng agency may i ssue the owner
or operator a wri tten fi nal determi na-
ti on of necessary revi si ons to the sta-
ti onary sources RMP. The fi nal deter-
mi nati on may adopt or modi fy the re-
vi si ons contai ned i n the prel i mi nary
determi nati on under paragraph (e) of
thi s secti on or may adopt or modi fy
the substi tute revi si ons provi ded i n the
response under paragraph (f) of thi s
secti on. A fi nal determi nati on that
adopts a revi si on rej ected by the owner
or operator shal l i ncl ude an expl a-
nati on of the basi s for the revi si on. A
fi nal determi nati on that fai l s to adopt
a substi tute revi si on provi ded under
paragraph (f) of thi s secti on shal l i n-
cl ude an expl anati on of the basi s for
fi ndi ng such substi tute revi si on unrea-
sonabl e.
(h) Thi rty days after compl eti on of
the acti ons detai l ed i n the i mpl emen-
tati on schedul e set i n the fi nal deter-
mi nati on under paragraph (g) of thi s
secti on, the owner or operator shal l be
i n vi ol ati on of subpart G of thi s part
and thi s secti on unl ess the owner or
operator revi ses the RMP prepared
under subpart G of thi s part as requi red
by the fi nal determi nati on, and sub-
mi ts the revi sed RMP as requi red
under 68.150.
(i ) The publ i c shal l have access to the
prel i mi nary determi nati ons, responses,
and fi nal determi nati ons under thi s
secti on i n a manner consi stent wi th
68.210.
(j ) Nothi ng i n thi s secti on shal l pre-
cl ude, l i mi t, or i nterfere i n any way
wi th the authori ty of EPA or the state
to exerci se i ts enforcement, i nvesti ga-
tory, and i nformati on gatheri ng au-
thori ti es concerni ng thi s part under
the Act.
34
Environmental Protection Agency, EPA Pt. 68, App. A
A
P
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35
Pt. 68, App. A 40 CFR Ch. I (7199 Edition)
36
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Chemical Accident

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Chemical Accident

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PART 68CHEMICAL ACCIDENT

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